Abstract: Described are novel synthetic detergent base materials having a pH from 5 to 8 and consisting essentially of from 45 to 70 weight percent of mild synthetic surfactant, salts thereof, or a mixture of the mild synthetic surfactant and salts thereof; from 20 to 30 weight percent of C8-C22 fatty acid; from 1.5 to 10 weight percent of C8-C22 n-acyl sarcosine, salts thereof, or a mixture of the sarcosine and salts thereof; from 0.5 to 5 weight percent of C1-C22 alkyl aryl sulfonic acid, salts thereof, or a mixture of the sulfonic acid and salts thereof; and from 1 to 5 weight percent soap, e.g., salts of C8-C22 fatty acid. Also described are syndet bars prepared from the synthetic detergent base material.

Abstract: A shaped soap composition is presented having 60 to 85 percent of an alkali metal soap of linear C12-22 fatty acid, 1 to 10 percent alkyl oligoglycoside and 5 to 20 percent talcum. The shaped soap as a smooth surface and exhibits improved washing properties and lime soap dispersion power.

Abstract: The invention discloses process for making bars comprising fatty acid soaps, free fatty acid, polyalkylene glycol and specific salts of protic acid (i.e., having pKa1 less than 6, preferably less than 5.5). Using specific equivalent molar ratios of fatty acid to protic acid salt and specific wt. ratio of PAG and salt of protic acid to free fatty acid, applicants obtain bars having sensory feel of soap and which improve skin condition in Controlled Application Wash Tests.

Abstract: The present invention relates to synthetic bar compositions comprising amphoteric surfactants (e.g., betaine) in which, by using floor levels of fatty acid soap and floor ratios (minimum amounts) of saturated to unsaturated soap, enhanced processing (i.e., measured as rates of extrusion) is obtained at higher levels of amphoteric.

Abstract: The invention is a solid chemical concentrate system of at least two cooperative shapes. The first shape is an inwardly curved bar having an inner opening. The second shape is an insert which is capable of interlocking with the bar by insertion into the bar inner opening. The solid chemical concentrate provides chemical systems having active constituents which may be the same, different but compatible or functionally and chemically incompatible combined within one matrix to provide at least one substantially continuous surface. The system may also comprise an aqueous soluble or dispersible polymeric film cover.

Abstract: A composite article comprising a solid cosmetic formulation core, preferably of transparent glycerin soap, and a foamed polymer skin, preferably a sponge. The solid soap-core is preferably formulated to mimic the meat of a fruit such as an orange. The sponge-skin is preferably formulated to mimic the skin appropriate to the meat, for example, an orange peel. At least the meat and preferably also the skin part includes dyes and fragrances to impart the color and smell of the fruit being imitated. The composite article is produced either by forming the soap core, coating a sponge forming polymeric composition onto the soap core, and foaming and curing the coating to form a sponge skin on the soap core, or by first forming a hollow foamed polymer shell, introducing liquefied soap into the shell, and hardening the soap.

Abstract: The use of 2-methyl-3-cyclohexylpropanol, esters thereof or mixtures thereof as fragrance materials is disclosed. The subject materials possess unique fragrance notes and are cost-effective materials. The esters are novel compounds.

Abstract: Disclosed are hair styling shampoo compositions which comprise from about 5% to about 50% by weight of a surfactant selected from the group consisting of anionic surfactants, zwitterionic or amphoteric surfactants, and combinations thereof; from about 0.1% to about 10% by weight of an organic or silicone-grafted hair styling polymer; and from about 40% to about 94.9% by weight of water; wherein the Hair Feel Index (HFI) is at least about 0.65 and the Curl Retention Value (CRV) is at least about 70. The composition provides improved styling performance and improved hair feel from a shampoo composition.

Abstract: The present invention relates to bar compositions in which an emollient composition comprising thickened entrapped emollient is added to a base bar composition at or during time of extrusion to form macroscopic, concentrated domains of emollient droplets. Addition of entrapped droplets allows far greater deposition than if the non-trapped emollients had been mixed in directly to form chips which are then extruded to form final bar.

Abstract: Disclosed are compositions suitable for formation into mild personal cleansing or laundry detergent bars, as well as other uses. The compositions generally comprise: (a) from about 30% to about 99% by weight of a mixture of anionic surfactants comprising: i) an alpha sulfonated alkyl ester; and ii) a sulfonated fatty acid; (a) from about 0.5% to about 50% by weight of a fatty acid; and (b) from about 0.1% to about 50% by weight water; wherein the ratio of i) to ii) is from about 10:1 to about 0.5:1, and wherein the ratio of (a) to (b) is about 1:1 to about 11:1.

Abstract: The use of 3-methyl-5-cyclohexylpentanol, 3-methyl-5-cyclohexylpentanal or mixtures thereof as fragrance materials is disclosed. The subject materials possess unique fragrance notes and are advantageous in that they are cost-effective.

Abstract: A liquid aqueous composition comprising:(a) a skin cleansing effective amount of a surfactant or mixture thereof;(b) a silicone fluid in quantities of from about 0.1 to about 8 wt % of the composition;(c) a hydrocarbonaceous material in quantities of from about 0.1 to about 8 wt % of the composition;(d) a cationic polymer in quantities of from about 0.02 to about 1 wt % of the composition;(e) a combination of a hydroxy alkyl cellulose and a copolymer of a long chain alkylacrylate monomer and one or more monomers of acrylic acid, methacylic acid and one or more of a methyl, ethyl or propyl ester of said acid(s) wherein the copolymer is crosslinked with an allylic ether of a polyol, said combination in sufficient quantities to bring about a stabilized composition as visually evaluated, and(f) the remainder water.

Abstract: A transparent solid soap or transparent soap material which comprises mainly of a salt of the fatty acid, is obtained by saponifying fatty acid or animal/vegetable oil with alkali, wherein1) the alkali is sodium hydroxide and organic amine, and a molar ratio of sodium hydroxide to organic amine is from 1:0.8 to 1:2, and2) a quantity of the alkali is 2 to 3 saponifying equivalents to the fatty acid or the animal/vegetable oil.The transparent solid soap and the transparent soap material according to the present invention can be easily produced without requiring a fine control of moisture content, and a maturing period till reduction in weight is settled, and, besides, good in stabilities of transparency and of weight with a passage of time.

Abstract: A solid translucent or transparent soap composition comprising a cleansing effective amount of soap and an antidiscoloration effective amount of the benzotriazole 2-(5-chloro-2H-benzotriazole-2-yl)-6-(1,1-dimethyl)-4-methyl-phenol.

Abstract: A transparent toilet bar with an embedded decorative concentric pattern comprised of colored transparent soap formulations, and a method for producing the bar. The preferred embodiment of the bar is a transparent semi-circular rainbow pattern of three or more colors embedded in a transparent rectangular bar with a glittering agent. The preferred method of producing the rainbow is to pour a first color into a small circular mold and then to place that circular soap article into a larger mold and pour a second color around the soap article. A third concentric ring is created by repeating the process with a larger third mold. The finished disk is cut in half to create two rainbow soap articles. In the preferred embodiment of the method, all soap compositions are identical except for color or glitter additives.

Abstract: A bar composition comprising about 50-80% soap, about 4 to 35% by wt. free fatty acid and less than 5% synthetic surfactant. Addition of 1% to 10% organic salt has been found to allow use of little or no surfactant while maintaining consumer desirable properties.

Abstract: There is provided a bar soap having an improved resistance to cracking after exposure to repeated cycles of moistening and drying. The bar soap, which contain greater than 3 wt % glycerin, is prepared from an initial blend of about 60 wt % to about 85 wt % tallow, about 10 wt % to about 40 wt % coconut oil and about 15 wt % to about 35 wt % fatty acid. The present invention also relates to the process of transforming the initial blend into a bar soap having an improved resistance to wet cracking.

Abstract: The present invention relates to synthetic bar compositions comprising amphoteric surfactants (e.g., betaine) in which, by using floor levels of fatty acid soap and floor ratios (minimum amounts) of saturated to unsaturated soap, enhanced processing (i.e., measured as rates of extrusion) is obtained at higher levels of amphoteric.

Abstract: The present invention relates to skin cleansing bar composition in which polyalkylene glycols of very specific molecular weights are used to define compositions which are mild, foam well and provide consumer-desired sensory profiles. A significant amount of these specific PEGs must be incorporated into the bar to deliver these desired effects. To properly process such a bar composition, the cast-melt method is the preferred technique.

Abstract: A "single-use" personal care product designed to replace conventional single use products such as small bars of soap, mini-bottles of shampoo, etc. A water soluble foamed polymer structure, such as produced by freeze drying acemannan derived from aloe vera, serves as the carrier for the personal care active ingredient, and provides the bulk to the structure. The dry foamed product has high void volume, good dimensional stability, high surface area, dissolves easily and completely upon exposure to water and hand mechanical action, and leaves no adverse residue on the skin. The product does not require bottling or complex wrapping, and is much more economical and environmentally friendly than the conventional single use products it replaces. The product can be conveniently carried in a purse or pocket, so that a consumer need never be without his/her favorite personal care products.

Abstract: A process for making a superfatted personal cleansing bar involving the steps of: (a) providing a solid-form superfatting agent consisting of: (i) a fatty component selected from the group consisting of C.sub.6 -C.sub.22 free fatty acids, C.sub.6 -C.sub.22 fatty alcohols, and mixtures thereof; and (ii) a nonionic sugar surfactant selected from the group consisting of an alkyl polyglycoside of formula I:R.sub.1 O(Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; and a is a number having a value from 1 to about 6, a polyhydroxy fatty acid amide, and mixtures thereof; (b) providing a solid-form neutralized tallow/coco fatty acid soap mixture; (c) mixing components (a) and (b) to form a superfatted soap bar stock; and (d) stamping the superfatted soap bar stock into a finished personal cleansing bar.

Abstract: A translucent personal cleansing bar containing: (a) an alkyl polyglycoside of formula I:R.sub.1 O(Z).sub.a (I)wherein R.sub.1 is a monovalent organic radical having from about 8 to 10 carbon atoms, and a is a number having a value of from about 1.40 to 1.55; (b) a soap component; and (c) water.

Abstract: A bar composition in which use of specific ratio of cationic to surfactant as been found to remarkably enhance deposition of oil/emollient benefit agent.

Abstract: Cleansing bars are formed from compositions containing an oil phase, particulate silica and a cleansing agent. The particulate silica is present in an amount to provide sufficient hardness to the composition to facilitate processing into a bar while maintaining good foaming despite a high oil content.

Abstract: A surfactant composition consisting essentially of: (a) from about 20 to about 63% by weight of an acyl isethionate; (b) from about 3 to about 52% by weight of a nonionic sugar surfactant selected from the group consisting of alkyl glucose esters, aldobionamides, gluconamides, glyceramides, glyceroglycolipids, polyhydroxy fatty acid amides, alkyl polyglycosides having the general formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is a divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6, and mixtures thereof; (c) from about 7 to about 23% by weight of a free fatty acid; and (d) remainder, water, all weights being based on the weight of the surfactant composition.

Abstract: A detergent composition which is suitable for making into bars for personal washing comprises:(a) 10 to 60% wt. of a synthetic, non-soap detergent;(b) 20 to 60% wt. of water soluble material which is neither soap nor a non-soap detergent and which has a melting point in the range 40.degree. C. to 100.degree. C.; and(c) 5 to 50% wt. of water insoluble material which is neither soap nor a non-soap detergent and which has a melting point in the range 40.degree. C. to 100.degree. C. The content of water, if any does not exceed 20% wt. of the composition and better is less than 15% wt. The materials (b) and (c) serve to give structure to the bars. The compositions can be prepared by melting together the above mentioned components at a temperature of 50-100.degree. C., without the conventional energetic working. Desirably the molten mixture contains less than 20% wt. material, other than synthetic, non-soap detergent, which does not enter the liquid phase.

Abstract: The present invention relates to cleaning compositions comprising protease enzyme which is a carbonyl hydrolase variant having an amino acid sequence not found in nature, which is derived by replacement of a plurality of amino acid residues of a precursor carbonyl hydrolase with different amino acids, wherein said plurality of amino acid residues replaced in the precursor enzyme correspond to position +76 in combination with one or more of the following residues: +99, +101, +103, +104, +107, +123, +27, +105, +109, +126, +128, +135, +156, +166, +195, +197, +204, +206, +210, +216, +217, +218, +222, +260, +265, and/or +274, where the numbered positions corresponds to naturally-occurring subtilisin from Bacillus amyloliquefaciens or to equivalent amino acid residues in other carbonyl hydrolases or subtilisins (such as Bacillus lentus subtilisin).

Abstract: A personal cleansing composition which comprisesa. a skin cleansing effective amount of a surfactant or mixture of surfactants,b. a hydrophobic active component in quantities which brings about a perceived effect on the skin, said effect selected from the group consisting of skin conditioning, skin protection from irritants and antibacterial agents,c. a hydrocarbon containing component, andd. a cationic polymerthe quantities of c and d selected so that the effect on the skin by component b is enhanced over the additive effects of c and d alone.

Abstract: A personal use soap bar composition containing alkali metal soaps of fatty acids having alkyl chain lengths of C.sub.8 -C.sub.22 which include an unhydrated cationic guar gum polymer as a skin feel and mildness additive. Prior to incorporating the polymer into the soap, it is mixed with an anhydrous polyglycol ether such as PEG-6 methyl ether. This eliminates the need to hydrate the cationic polymers to achieve uniform distribution of the polymer in the bar.

Abstract: A composition for personal or fabric washing comprises:(i) 25 to 70% by weight of surfactant active;(ii) 0.05 to 5% by weight of water soluble anionic polymer and/or copolymer having a molecular weight of from 500 to 30,000;(iii) 15 to 50% by weight of water; and(iv) other additives making up the total balance.Such a composition is particularly suited for producing bars with high water content whilst retaining structural properties and processability. Enhanced physical properties such as higher yield stress, lathering and lower mush are also attained.

Abstract: Transparent soap bars having improved lathering and foaming characteristics contain (1) an alkanolamine; (2) an alkyl polyglycoside of the formula IR.sub.1 (R.sub.2 O).sub.b (Z).sub.a (I)wherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6: (3) a polyol; (4) a fatty acid which is at least 70% neutralized by sodium hydroxide, and; (5) water wherein the water to free alkanolamine weight ratio is greater than 1.0 and the ratio of the weight of the polyol to the sum of the weights of free alkanolamine+alkyl polyglycoside+polyol+water is less than about 0.4.

Abstract: The present invention relates to personal wash bar compositions, particuly compositions comprising (1) lathering anionic surfactants (e.g., sodium acyl isethionate or fatty acid soap); (2) specific solid, less hygroscopic amphoteric surfactants (e.g., disodium N-lauryl iminodipropionate). The invention relates to the incorporation of significant levels of said solid amphoteric surfactant into the specific bar compositions to achieve superior skin mildness and bar user properties. The invention especially addresses the advantages of using solid, less hygroscopic amphoteric surfactants to reduce the processing difficulties in extrusion and modified extrusion processes.

Abstract: Cleansing and moisturizing personal cleansing compositions which contain from about 5% to about 50% of a surfactant; from about 3% to about 40% of an insoluble, nonionic oil or wax or mixture thereof; from about 0.1% to about 8% by weight of a fatty acid having an average chain length of from about 10 to about 18 carbon atoms; from about 1.5% to about 10% by weight of citric acid or water soluble citrate salt or mixture thereof; and water are disclosed.

Abstract: A process for producing soap which comprises blending soaps, water, and glycerin prepared froma. the neutralization of at least one free fatty acid with a strong alkali to produce soap and water, andb. the saponification of at least one triglyceride with a strong alkali to produce soap and glycerin, the amount of glycerin from step b being sufficient to provide up to about 6 wt. % of glycerin to the finished soap product.A process for producing soap from a mixed feedstock of at least one triglyceride and at least one free fatty acid which comprises contacting at least one triglyceride and at least one free fatty acid with strong alkali at an elevated temperature, the quantity of triglyceride present so that the glycerine produced from its saponification with strong alkali does not exceed about 6 wt. % of the finished soap product.

Abstract: The present invention is directed to specific synthetic bar compositions wherein relatively small amounts of specified alkoxylated nonionic surfactant has been found to enhance mildness of bar compositions without sacrificing processability and desired user properties, such as lather and bar smoothness.

Abstract: A method for increasing surface deposition of silicone from soap and improving processing characteristics of soap and a corresponding composition are disclosed. The composition includes a fatty alkyl silicone, a fatty silicate ester, a high viscosity lower alkyl silicone fluid, a silicone surfactant, and an organic surfactant. The organic surfactant is one or more of a nonionic, cationic or anionic surfactant, a fatty ester sulfonate, sorbitan monostearate, and sodium lauryl sulfate.

Abstract: Novel compositions are prepared in a non-molten process. In particular, compositions comprise optional fillers with both soap and high levels of synthetic surfactants. When high levels of soap and surfactant are normally used in such process, there is a significant "grittiness" problem. Pre-processing the surfactant containing chip (e.g., "DEFI" chip) has been unexpectedly found to remedy this problem.

Abstract: Novel chip compositions comprise alkylene glycol, benefit agent and thickening agent (e.g., fumed silica). Use of chips comprising excess of alkylene glycol over benefit agent and thickening agent has been found to allow significant deposition of benefit agent without compromising processing. In a second embodiment, the invention comprises bar compositions comprising mixtures of the chips of the invention and chips containing defined surfactant systems. A process for forming the chips of the invention and a method of enhancing deposition without compromising processing using the chips of the invention are also disclosed.

Abstract: A hand laundry detergent and composition includes a surfactant mixture containing a base soap and one or more fatty acid methyl ester sulfonates (MES) having the formula: ##STR1## wherein R is a fatty alkyl chain having 6-20 carbon atoms, M+ is a monovalent or divalent salt. A method for cleaning soiled fabrics and/or laundry which includes treating the laundry and/or fabrics with this detergent composition is also provided.

Abstract: A framed soap composition comprises (a) from 20 to 50% by weight of a fatty acid soap, (b) from 1 to 15% by weight of a nonionic surfactant, and (c) from 0.1 to 5% by weight of an inorganic salt. A framed soap composition incorporated with air bubbles is produced by melting a mixture containing these components while heating the mixture in the presence of water, subjecting the resultant molten material to aeration treatment to incorporate air bubbles, and pouring the resultant molten material incorporated with air bubbles, into a frame followed by cooling to harden the molten material.

Abstract: Basic cleaning compositions using toxicologically-acceptable ingredients for cleaning fruits and vegetables are provided. Liquid formulations comprising carbonates, detergent surfactant, such as oleate, alcohol ethoxylates, etc., and neutralized phosphoric acid are sprayed onto apples, lettuce and the like to remove soil and unwanted deposits, especially wax. Articles for applying the compositions to produce by spraying are disclosed.

Abstract: Disclosed are compositions suitable for formation into mild personal cleansing or laundry detergent bars, as well as other uses. The compositions generally comprise:(a) from about 30% to about 99% by weight of a mixture of anionic surfactants comprising:i) an alpha sulfonated alkyl ester; andii) a sulfonated fatty acid;(a) from about 0.5% to about 50% by weight of a fatty acid; and(b) from about 0.1% to about 50% by weight water;wherein the ratio of i) to ii) is from about 10:1 to about 0.5:1, and wherein the ratio of (a) to (b) is about 1:1 to about 11:1.

Abstract: The present invention relates to a clear colorless soap bar with superior mildness, lathering and discoloration resistance. The clear colorless soap consists of a blend of C12-C18 fatty acids neutralized with sodium hydroxide (NaOH) and triethanolamine (TEA). Excess TEA acts as a co-solvent and is responsible for clarity of the soap bar. The bar also contains a branched chain acid such as isostearic acid to break up crystallinity and add to product clarity. Low color and color stability are obtained by removing unsaturated fatty acids, and by the use of antioxidants (BHT and Vitamin E). Low levels of C6 to C10 fatty acids provide exceptional mildness.

Abstract: Adjuvant powder compositions contain a benefit agent or benefit agents and enhance the delivery of these benefit agent or agents when used as a separate adjuvant during preparation of bar compositions. Carriers used in the formation of the adjuvants must have a melting point high enough to survive a spray-drying process.

Abstract: A composition for a soap bar comprises:(i) from about 0.5% to about 5%, by weight, of silicone;(ii) from about 0.5% to about 5%, by weight, of a first emollient selected from polyols, selected from glycerin, sorbitol, or mixtures thereof;(iii) up to about 5%, by weight, of a second emollient selected from vegetable, animal or mineral oils, or free fatty acids, or mixtures thereof.

Abstract: Novel chip compositions comprise specifically defined carriers; benefit agent; and thickening agent (e.g., fumed silica). Use of chips comprising excess of these carriers over benefit agent and thickening agent has been found to allow significant deposition of benefit agent without compromising processing. In a second embodiment, the invention comprises bar compositions comprising mixtures of the chips of the invention and chips containing defined surfactant systems. A process for forming the chips of the invention and a method of enhancing deposition without compromising processing using the chips of the invention are also disclosed.

Abstract: Liquid personal cleansing compositions which comprise from about 1% to about 35% of encapsulated lipophilic skin moisturizing agents, from about 0.1% to about 5% of a stabilizer, from about 5% to about 30% of a lathering surfactant and water are disclosed. The encapsulated lipophilic skin moisturizing agent comprises a lipophilic skin moisturizing agent encapsulated within a complex coascervate comprising a polycation and a polyanion. The lipophilic skin moisturizing agent comprises droplets having a particle size distribution such that at least about 10% by weight of the droplets have a diameter of at least about 100 microns. The encapsulated lipophilic skin moisturizing agent is essentially free of cross-linking agent.

Abstract: A transparent/translucent dishwashing composition in bar/paste form containing: (a) an alkyl polyglycoside of the formula IR.sub.1 (R.sub.2 O).sub.b (Z).sub.a (I)wherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6; (b) a short-chain alcohol; (c) a fatty acid; (d) an amide; and (e) a polyol.

Abstract: Wet-like cleaning wipes and similar articles are described. These wipes comprise a carrier that provides controlled fluid absorbency and an emulsion applied to the carrier. The emulsion comprises a continuous external lipid phase and a polar (e.g., water) internal phase. The emulsion is sufficiently brittle that it ruptures when subjected to low shear pressures during use to release the dispersed polar phase. The carrier allows the released internal phase to initially reach and remain on the surface being cleaned, but then absorbs the material at the end of the wiping process.

Abstract: Disclosed is a solid, floating soap which has a formulation density greater than water or a liquid of like density, and which has an overall physical density less than water or a liquid of like density, and a method of making the floating soap.