Amine, Carboxamide, Or Metal Hydroxide Or Alkoxide Component (e.g., Pyrrolidone, Pyridine, Etc.) Patents (Class 510/212)
  • Patent number: 5994282
    Abstract: Stripping compositions based on a polar aprotic solvent, an ether and water. The composition is characterized in that it comprises at least the following: 1) a polar aprotic solvent, especially dimethyl sulfoxide (DMSO) or N-methyl pyrrolidinone (NMP); 2) an ether chosen from anisole and tetrahydrofuran (THF); 3) water.
    Type: Grant
    Filed: May 30, 1997
    Date of Patent: November 30, 1999
    Assignee: Elf Atochem, S.A.
    Inventor: Jean-Pierre Lallier
  • Patent number: 5977054
    Abstract: Disclosed are mildly acidic liquid compositions for use in cleaning hard surfaces. The compositions contain from about 1% to about 60% of an amine oxide detergent surfactant, an aqueous carrier liquid, and an acidifying agent having a pK.sub.a of less than about 6.0. The compositions contain enough of the acidifying agent to protonate at least about 10% of the amine oxide species within the compositions and to provide a composition pH of between about 3 and 7. These no-rinse liquid hard surface cleaning compositions have excellent cleaning properties, they do not leave a visible residue when they dry, and they cause minimal or no staining of vinyl surfaces. Also disclosed are a method for cleaning vinyl surfaces using the liquid compositions, and non-liquid compositions from which the mildly acidic liquid compositions can easily be obtained by adding an aqueous liquid.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: November 2, 1999
    Assignee: The Procter & Gamble Company
    Inventor: Thomas James Wierenga
  • Patent number: 5977042
    Abstract: The present invention is directed to a composition for stripping coatings from a surface, the composition including:a. A solvent mixture composed of a phenyl substituted alkyl alcohol and an alkyl or aryl glycol ether or an alkyl or aromatic alcohol;b. A coupler composed of a salt formed from a water soluble organic amine and an acid comprising at least one C7-C18 ethoxylated anionic surfactant;c. Optionally water.The use of the C7-C18 ethoxylated anionic surfactant provides a stripper which can be diluted in water of various compositions yet provide an effective stripping/cleaning agent.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: November 2, 1999
    Assignee: S. C. Johnson Commercial Markets, Inc.
    Inventors: Paul M. Hernandez, Lance D. Brown
  • Patent number: 5972865
    Abstract: A purge concentrate for purging paint spraying and other coating equipment has about 20%-60% by weight water; about 10%-40% by weight of an active solvent; about 10%-50% by weight of a co-solvent; about 1-9% by weight of a penetrant; and about 0.2-2.0% by weight wetting agent. It need not be heated to the curing temperature of heat curing paints and thus purges these paints more effectively.
    Type: Grant
    Filed: April 30, 1998
    Date of Patent: October 26, 1999
    Assignee: Dalco Industries, Ltd.
    Inventors: Richard E. Knipe, Jr., Savarimuthu M. Jacob, Sheldon Green
  • Patent number: 5954890
    Abstract: Compositions and methods for removal of polymeric coatings from nonporous surfaces are provided. The method comprises the mixing of two stock solutions, a peroxide/acid solution and an alkaline solution, and immediate application to the surface to be stripped of coating. The applied mixture produces a controlled peroxide oxidation reaction causing the coating to become softened-to-release. A further step of washing or blowing with water, air, cornstarch, or plastic media will remove the softened-to-release coating. The two stock solutions are stable to storage and, when in use, are continuously mixed in a volume so as to control reaction rate, pH, corrosivity of the coating remover, and reaction rate with the coating.
    Type: Grant
    Filed: September 26, 1997
    Date of Patent: September 21, 1999
    Assignee: Eldorado Chemical Co., Inc.
    Inventors: Pat E. Smith, John M. Jasper, William R. Zinnecker, Joe R. Fredricksen
  • Patent number: 5952277
    Abstract: A synergistic paint removing composition is disclosed which comprises a particular selection of a plurality of known solvents in very specific proportions, namely: from 20 to 45% of aromatic hydrocarbons; from 15 to 25% of dimethylformamide; from 15 to 25% of N-methyl pyrrolidone; from 5 to 15% of a water-immiscible compound selected from the group consisting of terpene derivatives, oleoresins and mixtures thereof; and from 0.5 to 4% of at least one wetting agent, all the above percentages being expressed by weight. This composition is partially miscible in water even though some of its constituents are not water miscible, thereby making the composition easy to wash and thus preventing oily film to be left on the treated substrate. The composition according to the invention is normally in a liquid form. If desired, for some applications, a thickening agent can be added thereto to convert it to a gel.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: September 14, 1999
    Assignees: Asahipen Corporation, E.QU.I.P. International, Inc.
    Inventors: Georges Radu, Shizuo Maruyama
  • Patent number: 5932530
    Abstract: A synergistic paint removing composition is disclosed which comprises a plurality of known solvents in very specific proportions, namely: 5 to 55% of N-methyl pyrrolidone, 6 to 45% of a dibasic ester, 5 to 40% of a terpene derivative, 2 to 15% of ethylene glycol monoethyl ether acetate and 1 to 5% of a wetting agent, all of the above percentages being expressed by weight. This composition is partially miscible in water even though some of its constituents are not water miscible, thereby making the composition easy to wash and thus preventing oily film to be left on the treated substrate. The composition according to the invention is normally in liquid form. If desired, for some applications, a thickening agent can be added thereto to convert it to a gel.
    Type: Grant
    Filed: October 11, 1996
    Date of Patent: August 3, 1999
    Assignee: E.QU.I.P. International Inc.
    Inventors: Georges Radu, Shizuo Maruyama
  • Patent number: 5929005
    Abstract: This invention provides graffiti removers for removing permanent ink stains from painted surfaces. The graffiti removers include an active solvent for dissolving the stains, which are organic in nature, an optional secondary solvent for concentrated attack on the stain without being adversely affected by dilution with water, an emollient for maintaining a uniform dispersion of particulates in the remover and on the graffiti-stained painted surfaces, and an amorphous, particulate, mildly abrasive filler for imbibing the solvents, the filler being selected to permit the slow release of the active solvent.
    Type: Grant
    Filed: December 4, 1998
    Date of Patent: July 27, 1999
    Assignee: Decora, Incorporated
    Inventor: John Ralph Smith
  • Patent number: 5916860
    Abstract: A stripping and/or cleaning composition is disclosed, which contains, by volume: (a) 1 to 90% of at least one C.sub.1 -C.sub.4 dialkyl ester of at least one C.sub.4 -C.sub.6 aliphatic diacid; and (b) 99 to 1% of at least one ether selected from the group consisting of ethers with a flash point above 5.degree. C., at least one methoxy group per molecule and a molecular weight of less than 200.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: June 29, 1999
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Luc Joye, Marle-Madeleine Vincent
  • Patent number: 5911838
    Abstract: Oil-based paint containing lead compounds, acrylic-based or other latex paint or a combination of paints in which acrylic-based or other latex paint covers an oil-based paint is removed from a substrate on which the paint is deposited by application of an aqueous solution thereto. The solution comprises a solvent that does not dissolve the oil-based paint and is compatible with water; a film former for retarding evaporation; a viscosity builder to fortify the solution and prevent slumping thereof during application to vertical and overhead horizontal surfaces; an alkaline compound for reacting with the pigment portion of the paint. Advantageously, the solution penetrates the deposited paint, which coagulates and separates from the substrate. Stripping procedures are facilitated, and neutralization of the substrate prior to repainting is avoided. A safe and effective treatment of materials covered with lead-containing paint is carried out in an economical, cost efficient manner.
    Type: Grant
    Filed: September 18, 1997
    Date of Patent: June 15, 1999
    Inventor: Irvin Barnett
  • Patent number: 5854190
    Abstract: An apparatus, method and purge concentrate are capable of purging water-based and non-water-based paints and other coatings from automated and manual equipment using non-VOC containing aqueous purge solutions. Purge solutions of the invention contain water, detergent builder and wetting agents. The solution is maintained at a selected concentration and at a selected elevated temperature range by continuously recirculating the solution through the automated coating equipment. For manual equipment the solution is set at the correct concentration and maintained at the correct temperature range. For an automated system, spent purge solution can be reconditioned and recirculated to avoid waste.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: December 29, 1998
    Assignee: DALCO Industries, Ltd.
    Inventors: Richard E. Knipe, Jr., Savarimuthu M. Jacob, Thomas Mancini
  • Patent number: 5854188
    Abstract: Improvements in the rate of stripping of alkaline water-in-oil emulsions by incorporating in the organic phase thereof an effective amount of pyrrole.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: December 29, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventors: John Distaso, Azucena G. De Guzman
  • Patent number: 5851972
    Abstract: Improvements in the rate of stripping of benzyl alcohol containing water-in-oil emulsions by incorporating in the organic phase thereof an effective amount of anisole.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: December 22, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventors: John Distaso, Azucena G. De Guzman
  • Patent number: 5830836
    Abstract: Compositions and methods for removal of polymeric coatings from nonporous surfaces are provided. The method comprises the mixing of two stock solutions, a peroxide/acid solution and an alkaline solution, and immediate application to the surface to be stripped of coating. The applied mixture produces a controlled peroxide oxidation reaction causing the coating to become softened-to-release. A further step of washing or blowing with water, air, cornstarch, or plastic media will remove the softened-to-release coating. The two stock solutions are stable to storage and, when in use, are continuously mixed in a volume so as to control reaction rate, pH, corrosivity of the coating remover, and reaction rate with the coating.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: November 3, 1998
    Assignee: Eldorado Chemical Co., Inc.
    Inventors: Pat E. Smith, John M. Jasper, William R. Zinnecker, Joe R. Fredricksen
  • Patent number: 5821209
    Abstract: Improvements in the retardation of water evaporation from benzyl alcohol containing water-in-oil emulsions by incorporating in the organic phase thereof an effective amount of a terpene.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: October 13, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventors: John Distaso, Azucena G. De Guzman
  • Patent number: 5804541
    Abstract: A floor stripper composition is provided, having a pH-value above 9.0, and comprising a soap, water and a glycine-N,N-diacetic acid compound, which is preferably methylglycine diacetic acid (MGDA). The diacetic acid is desirably in the form of a divalent metal complex thereof. A process is also provided for removing a zinc containing acrylate polymer film from a floor surface, wherein a floor stripper composition of the invention is applied. A good floor stripper performance could be obtained with this composition owing to its low foaming behaviour.
    Type: Grant
    Filed: June 19, 1997
    Date of Patent: September 8, 1998
    Assignee: Diversey Lever, Inc.
    Inventor: Josef Jans
  • Patent number: 5798325
    Abstract: An improved aqueous liquid composition for power washing of paint masks contains: organic film-forming polymer, preferably polyacrylamide; inorganic salts, preferably a combination of alkali metal pyrophosphate, metaborate, and tetraborate; and dissolved organic molecules that (i) are hydrocarbons except for having hydroxyl substituents and, optionally, having one or more other types of substituents selected from halogen atoms, keto groups, and aldehydo groups and (ii) have a number ratio of oxygen atoms to carbon atoms that is at least 0.5; and, optionally but preferably, free boric acid.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: August 25, 1998
    Assignee: Henkel Corporation
    Inventor: Scott J. Beleck
  • Patent number: 5769959
    Abstract: Insoluble polymer formed during the distillation of N-vinylformamide is removed by contacting the insoluble polymer with an aqueous weakly basis solution in a closed system at elevated temperature. Polymer (up to 50 wt % polymer gel or 5.5 wt % dry polymer in reaction mixture) is treated with an aqueous solution of an amine, alkanolamine or weak inorganic base having a concentration of at least 1 molar. Solvents like alcohols, glycol ethers or amides may be added as a cosolvent in an amount of from 0 to about 85% by weight.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: June 23, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Thomas Albert Johnson, Malee Leeaphon
  • Patent number: 5763377
    Abstract: Methods and compositions useful for removing a titanium dioxide-containing material located on a surface, for example, a surface of a piece of process equipment, are disclosed. In one embodiment, the present methods provide for contacting the titanium dioxide-containing material located on the surface with a composition comprising at least about 20% by weight of water, an acid component in an amount effective to reduce the adhesion between the titanium dioxide-containing material and the surface; and an organic component in an amount effective to disperse the titanium dioxide-containing material in the composition.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: June 9, 1998
    Assignee: Dober Chemical Corporation
    Inventors: Daniel J. Dobrez, Mark R. Lalinsky, Robert J. Rybarski
  • Patent number: 5753603
    Abstract: Inexpensive paint stripper compositions containing neither chlorinated nor alkaline solvents and well adapted for removing paints such as glycerophtalic, alkyd-urethane or acrylic urethane paints on a variety of substrates, e.g. wood and metal substrates comprise (a) 1 to 99% by volume of an aprotic polar solvent chosen from the group comprising: dimethyl sulfoxide, dimethyl formamide, N-methylpyrrolidone, N-methylmorpholine, .gamma.-butyrolactone, acetonitrile and mixtures thereof; and (b) 99 to 1% by volume of an ether selected from the family of ethers having a flash point higher than 0.degree. C. a molar volume less than 160 and a molecule that includes one or several methoxy groups.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: May 19, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Jean-Pierre Lallier, Stephane Fouquay
  • Patent number: 5718841
    Abstract: A novel organophilic clay comprising the reaction product of:(a) a smectite-type clay; and(b) a quaternary ammonium compound or compounds selected from the group consisting of: ##STR1## wherein R.sub.1 is an unsaturated alkyl-ester group having 8 to 30 carbon atoms as described below and R.sub.2, R.sub.3 and R.sub.4 are independently selected from the group consisting of (i) R.sub.1, (ii) long chain linear or branched alkyl (including methyl), aliphatic or aromatic groups having 1 to 30 carbon atoms (such groups can also include hydroxylated groups); (iii) aralkyl groups, which are benzyl and substituted benzyl moieties, including such groups having fused ring moieties having linear chains or branches of 1 to 30 carbon atoms; (iv) aryl groups such as phenyl and substituted phenyl including fused ring aromatic substituents; (v) beta, gamma unsaturated groups having six or less carbon atoms or hydroxyalkyl groups having 2 to 6 carbon atoms; and (vi) hydrogen and M.sup.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: February 17, 1998
    Assignee: Rheox, Inc.
    Inventors: Wilbur Mardis, Jose Sanchez, Henry Basson
  • Patent number: 5712234
    Abstract: Graffiti removers particularly useful for removing permanent ink from painted surfaces are disclosed. The graffiti removers include a dye solvent (a pyrrolidone or a lactone), a dye non-solvent (a glycol ether ester or a glycol diether), and a dye bleaching agent (an oxidizing agent, reducing agent, or base). The dye bleaching agent is the key to eliminating the problem of "ghosting" that is observed when conventional graffiti removers are used to remove permanent marker ink graffiti.
    Type: Grant
    Filed: March 7, 1996
    Date of Patent: January 27, 1998
    Assignee: Arco Chemical Technology, L.P.
    Inventor: Daniel B. Pourreau
  • Patent number: 5696072
    Abstract: A paint-stripper composition is described which comprises a mixture of(A) from about 5% to about 90% by weight of at least one organic solvent selected from the group consisting of benzyl alcohol, alkyl-substituted benzyl alcohols, furfuryl alcohol, alkyl-substituted furfuryl alcohol and acetylenic alcohols containing from 3 to about 5 carbon atoms;(B) from about 0.05% to about 5% by weight of at least one inorganic clay thickener;(C) from about 0.05% to about 5% by weight of at least one organic thickener; and(D) up to about 94.9% by weight of water.A method of stripping paint from a surface also is described, and the method comprises(A) contacting the paint with a paint stripper composition as described above; for a period of time sufficient to reduce the adhesion of the paint to the surface; and(B) removing said paint and paint-stripper composition from said surface.
    Type: Grant
    Filed: September 19, 1995
    Date of Patent: December 9, 1997
    Assignee: McGean-Rohco, Inc.
    Inventors: Ara Z. Nercissiantz, Harvey Hans
  • Patent number: 5691290
    Abstract: A cleaning composition to remove unwanted paint, graffiti or other coatings from a substrate comprises 40-90 wt. % of a five-membered ring lactam, such as N-methyl-2-pyrrolidone, and 10-60 wt. % of a glycerol triester of a C1-C4 saturated aliphatic monocarboxylic acid. Additionally, up to 25 wt. % of the composition of diethylphthalate, diisopropyl adipate and/or a C1-C4 alkyl lactate may be present. Also a method of cleaning substrates and woven or non-woven tissue impregnated with the cleaning composition has been claimed.
    Type: Grant
    Filed: September 21, 1995
    Date of Patent: November 25, 1997
    Assignee: Unichema Chemie B.V.
    Inventors: Pieter Vonk, Anette Heymann
  • Patent number: 5637559
    Abstract: The present invention is drawn toward compositions and methods of using same, the compositions comprising (in diluted form):a) an effective amount of a phenyl substituted alkyl alcohol having a water solubility of at least 0.1 weight percent (preferably benzyl alcohol);b) a coupler; andc) water,wherein the amount of the coupler is at least 3.0 times the amount necessary to completely solubilize the phenyl substituted alkyl alcohol in the water. Preferred couplers are the salt of a monofunctional water-soluble amine and an organic acid comprising at least one water-insoluble organic acid having from 6-10 carbon atoms. Methods of removing coatings such as standard urethane/acrylic sealer finishes from floors using the inventive compositions are also described.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: June 10, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Francis J. Koreltz, James A. McDonell, Fidelis C. Onwumere, Toshihiro Funabiki
  • Patent number: 5609678
    Abstract: Solvent formulations used in thinning oil-based resins and in cleaning equipment contaminated with oil-based resins include mixtures of constituents with low-, or no-toxicity and flash points generally considered to be above flammability levels. The formulations are compatible with such resins and further have drying characteristics suitable for most users. The solvating power and drying characteristics of these formulations are equivalent to turpentine and mineral spirits, but without the safety concerns associated with those thinners. The formulation components of the present invention include propylene glycol ethers comprising no more than 60% by weight of the solvent mixture, no more than 10% by weight of an isoalkane compound, and no more than 30% by weight of an oxidizing oil, and no more than 30% by weight of an odor-masking compound, preferably d-limonene.
    Type: Grant
    Filed: May 9, 1995
    Date of Patent: March 11, 1997
    Assignee: American Color Company
    Inventor: Leo M. Bergman
  • Patent number: 5604193
    Abstract: A composition useful for removing adhesives and enamels from surfaces consists of d-limonene, dibasic acid ester, and N-methyl pyrrolidone.
    Type: Grant
    Filed: December 8, 1994
    Date of Patent: February 18, 1997
    Assignee: Dotolo Research Corporation
    Inventor: Jack T. Vlasblom
  • Patent number: 5597788
    Abstract: The present invention relates to light and heat reactive paint or polymer stripping compositions preferably employing biodegradable components such as conjugated terpenes and related polyenes in combination with an alcohol such as a phenyl substituted benzyl alcohol for use in removing polymeric materials from substrates, in particular, cured paint from hard and/or flexible surfaces. The compositions avoid the use of methylene chloride, phenol, corrosives and caustics, methanol, toluol or acetone. Compositions according to the present invention preferably have flash points above about 49.degree. C. (about 120.degree. F.) and a pH which is preferably neutral.Methods of stripping polymeric coatings from surfaces and methods of making these compositions are also described.
    Type: Grant
    Filed: June 19, 1995
    Date of Patent: January 28, 1997
    Inventor: Edwin Stevens
  • Patent number: 5597420
    Abstract: The invention teaches an aqueous stripping composition that is essentially free of any hydroxylamine compounds. The composition consists essentially of an aqueous mixture of monoethanolamine and preferably includes an inhibitor. The composition is particularly useful for cleaning substrates containing organic residues.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: January 28, 1997
    Assignee: Ashland Inc.
    Inventor: Irl E. Ward
  • Patent number: 5597787
    Abstract: Oil based paint containing lead compounds is removed from a substrate on which it is deposited by application of an aqueous solution thereto. The solution comprises a solvent that does not dissolve the paint and is compatible with water; a film former for retarding evaporation; a viscosity builder to fortify the solution and prevent slumping thereof during application to vertical and overhead horizontal surfaces; an alkaline compound for reacting with the pigment portion of the paint. Advantageously, the solution penetrates the deposited paint, which coagulates and separates from the substrate. Stripping procedures are facilitated, and neutralization of the substrate prior to repainting is avoided. A safe and effective treatment of materials covered with lead-containing paint is carried out in an economical, cost efficient manner.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: January 28, 1997
    Inventor: Irvin Barnett
  • Patent number: 5565136
    Abstract: This invention relates to water-based coating remover compositions comprising a substantially stable and homogeneous mixture of (a) from about 16 to about 55 percent by weight of N-methyl-2-pyrrolidone; (b) from about 11 to about 32 percent by weight of a dibasic ester; (c) from about 4 to about 20 percent by weight of a propylene glycol or glycol ether; (d) an effective amount of a hydroxypropyl cellulose thickener; and (e) from about 25 to about 65 percent by weight water. Exemplary dibasic esters useful in the present invention include at least one C.sub.1-4 dialkyl ester of at least one C.sub.4-6 aliphatic dibasic acid. Suitable glycol ethers include propylene glycol, propylene glycol oligomers or monoalkyl ether of monophenyl ether derivatives of said glycols and oligomers.
    Type: Grant
    Filed: June 3, 1994
    Date of Patent: October 15, 1996
    Assignee: BASF Corporation
    Inventor: William C. Walsh
  • Patent number: 5563119
    Abstract: The invention teaches an aqueous stripping composition that is essentially free of any hydroxylamine compounds. The composition is an aqueous mixture of an alkanolamine, tetraalkylammonium hydroxide, and an inhibitor. The composition is particularly useful for cleaning substrates containing organic residues.
    Type: Grant
    Filed: January 26, 1995
    Date of Patent: October 8, 1996
    Assignee: Ashland Inc.
    Inventor: Irl E. Ward
  • Patent number: 5545353
    Abstract: A non-corrosive photoresist composition containing:(a) 20-70% by weight of an organic polar solvent having a dipole moment of more than 3.5;(b) 70-20% by weight of selected amine compounds;(c) 0.1-10% by weight of (2-benzothiozolylthio)succinic acid.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: August 13, 1996
    Assignee: OCG Microelectronic Materials, Inc.
    Inventors: Kenji Honda, Taishih Maw
  • Patent number: 5536439
    Abstract: A cleaning composition for removing paint deposits includes, by weight, 20-80% of a solution of 2-30% of an alkali metal hydroxide dissolved in a glycol ether together with 80-20% of an organic solvent selected from the group consisting of ketones, alcohols, esters, aromatic solvents, and combinations thereof. The composition is essentially free of water and may further include thickening agents, surfactants, defoamers and colors.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: July 16, 1996
    Assignee: Gage Products Company
    Inventor: Raymond H. Harbin