Alkali Metal Hydroxide Component Patents (Class 510/225)
  • Patent number: 11572532
    Abstract: An antimicrobial cleaning composition having a pH of from about 9 to about 14 wherein the composition comprises a bispyridinium alkane antimicrobial active and the composition is substantially free of a quaternary ammonium antimicrobial active.
    Type: Grant
    Filed: July 20, 2020
    Date of Patent: February 7, 2023
    Assignee: The Procter & Gamble Company
    Inventors: Abigail Mary Konya, Adam Simon Hayward, Eva Maria Perez-Prat Vinuesa
  • Patent number: 11447908
    Abstract: A washing machine appliance, as provided herein, may include a fluid additive dispenser and a controller. The fluid additive dispenser may include a housing, a dispenser drawer, a water supply conduit, a first water valve, a shower plate, and a second water valve. The water supply conduit may be directed to the pod compartment defined by the dispenser drawer and define a water inlet. The shower plate may be disposed upstream from a primary compartment and the pod compartment. The controller may be configured to initiate a washing operation that includes initiating a wetting water flow at the second water valve to the pod compartment through the shower plate, initiating a break water flow to the pod compartment through the water supply conduit following the wetting water flow, and initiating a fill water flow through the shower plate following the break water flow.
    Type: Grant
    Filed: February 13, 2020
    Date of Patent: September 20, 2022
    Assignee: Haier US Appliance Solutions, Inc.
    Inventors: Fikreadam Abebe Damtew, Troy Marshall Wright, James Quentin Pollett, Ryan Ellis Leonard
  • Patent number: 11441107
    Abstract: Powder and cast solid alkaline cleaning compositions are disclosed. Powders and/or solidification of a highly alkaline detergent composition are provided including sodium hydroxide beads and/or liquid and sodium carbonate in combination with water conditioning polymers. Methods of cleaning for soil removal of baked on, greasy soils, including those found in ovens, are also disclosed.
    Type: Grant
    Filed: June 25, 2019
    Date of Patent: September 13, 2022
    Assignee: Ecolab USA Inc.
    Inventors: Devon Beau Hammel, Grace Marie Rapp
  • Patent number: 11206826
    Abstract: Low foaming, highly acidic peroxycarboxylic acid sanitizing compositions are disclosed as having both improved antimicrobial efficacy in comparison to conventional peroxyoctanoic acid and peroxyacetic acid compositions for sanitizing applications. The compositions include a combination of a low-foaming surfactant and an aluminum sulfate (or other metal salt) defoaming agent that is compatible with the highly acidic peroxycarboxylic acid sanitizing compositions. In particular, the sanitizing peroxycarboxylic acid compositions are also low odor and low/no VOC dual functioning acid wash and sanitizing compositions.
    Type: Grant
    Filed: November 6, 2018
    Date of Patent: December 28, 2021
    Assignee: Ecolab USA Inc.
    Inventors: Junzhong Li, Richard Staub, David D. McSherry
  • Patent number: 10165774
    Abstract: Low foaming, highly acidic peroxycarboxylic acid sanitizing compositions are disclosed as having both improved antimicrobial efficacy in comparison to conventional peroxyoctanoic acid and peroxyacetic acid compositions for sanitizing applications. The compositions include a combination of a low-foaming surfactant and an aluminum sulfate (or other metal salt) defoaming agent that is compatible with the highly acidic peroxycarboxylic acid sanitizing compositions. In particular, the sanitizing peroxycarboxylic acid compositions are also low odor and low/no VOC dual functioning acid wash and sanitizing compositions.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: January 1, 2019
    Assignee: Ecolab USA Inc.
    Inventors: Junzhong Li, Richard Staub, David D. McSherry
  • Patent number: 9023779
    Abstract: A dishwashing detergent composition is provided for consumer use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorus containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, a phosphinosuccinic acid oligomer or mixture thereof is used as a corrosion inhibitor and can be included for aluminum protection in a number of different detergent compositions.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: May 5, 2015
    Assignee: Ecolab USA Inc.
    Inventor: Altony J. Miralles
  • Publication number: 20150119312
    Abstract: The invention includes ware detergent compositions which prevent buildup of precipitates and also surprisingly provides significant metal protection of items exposed to alkaline detergent composition. According to the invention alkaline ware detergents may include an effective amount of amino carboxylate. Surprisingly, detergents which included amino carboxylate also provided significant metal protection against corrosion, even when traditional corrosion inhibiting components are reduced.
    Type: Application
    Filed: October 29, 2013
    Publication date: April 30, 2015
    Inventors: Lisa Maureen Sanders, Andrew M. Jensen, Kristopher Hodgson
  • Patent number: 8876982
    Abstract: Disclosed is a method of washing ware in an automatic institutional warewashing machine wherein the method includes contacting ware with a cleaning composition containing a surfactant and further includes contacting the washed ware in a rinse step with a potable aqueous rinse, the aqueous rinse being substantially free of an intentionally added rinse agent. A surfactant is employed in the wash step in an amount not to exceed 15 wt % based on weight of the detergent. The amount of surfactant is sufficient to provide a layer of surfactant on the ware so as to afford a sheeting action in an aqueous rinse step without any added rinse agent.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: November 4, 2014
    Assignee: Diversey, Inc.
    Inventors: Antonius Maria Neplenbroek, Bouke Suk, Petrus Adrianus Angevaare, Perrino Marie Portier, Bérengère Idelon
  • Patent number: 8871699
    Abstract: Detergent compositions effective for controlling hard water scale accumulation are disclosed. Detergent compositions employing phosphinosuccinic acid and mono-, bis- and oligomeric phosphinosuccinic acid (PSO) derivatives with alkali metal carbonate and/or alkali metal hydroxide reduce had water scale accumulation on treated surfaces at alkaline conditions between about pH of 9 and 12.5. Methods employing the detergent compositions and preventing hard water scale accumulation are also provided.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: October 28, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Carter Martin Silvernail, Erik C. Olson
  • Patent number: 8809249
    Abstract: A detergent composition for preventing scale on various surfaces includes a threshold system, a caustic and a surfactant system. The threshold system includes a sulfonate/acrylate copolymer, an acrylate homopolymer and a phosphonoalkane carboxylic acid with a sulfonate/acrylate copolymer to acrylate homopolymer weight ratio of between about 2:1 to about 1:2. The pH of the detergent composition is between about 10 and about 13.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: August 19, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Carter M. Silvernail, Erik C. Olson, Elizabeth R. Kiesel
  • Patent number: 8802611
    Abstract: A system for cleaning ware includes a detergent composition and a rinse solution. The detergent composition includes an alkali metal hydroxide, a corrosion inhibitor and a surfactant. The detergent includes less than about 1% of an alkali metal carbonate by weight. The rinse solution includes water and a chelating acid.
    Type: Grant
    Filed: May 3, 2010
    Date of Patent: August 12, 2014
    Assignee: Ecolab USA Inc.
    Inventor: Altony Miralles
  • Patent number: 8748364
    Abstract: Detergent compositions including at least one aminocarboxylate, at least one maleic/methylvinyl ether copolymer, an alkaline agent and optional additives. Embodiments of the present invention include reduced concentrations of aminocarboxylate compared to conventional compositions, while preventing scale accumulation and providing stain removal capability.
    Type: Grant
    Filed: December 23, 2010
    Date of Patent: June 10, 2014
    Assignee: Ecolab USA Inc.
    Inventor: Carter Silvernail
  • Patent number: 8481473
    Abstract: A detergent composition for preventing scale on various surfaces includes a threshold system, a caustic and a surfactant system. The threshold system includes a sulfonate/acrylate copolymer, an acrylate homopolymer and a phosphonoalkane carboxylic acid with a sulfonate/acrylate copolymer to acrylate homopolymer weight ratio of between about 2:1 to about 1:2. The pH of the detergent composition is between about 10 and about 13.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: July 9, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Carter Silvernail, Erik C. Olson, Elizabeth Kiesel
  • Patent number: 8420586
    Abstract: Cleaner compositions, associated cleaners, and associated methods are disclosed. The cleaner compositions are capable for use in making thickened cleaners that are capable of removing from vertical and inverted surfaces fresh, greasy soils and baked-on soils encountered in the food service industry. The cleaner compositions include one or more alkalinity sources, one or more chelants, one or more surfactants, one or more thickening agents, one or more buffers, and as a remainder, water. Cleaner compositions of the invention are substantially free of phosphates and have a low caustic content making them user and environmentally friendly. Yet the cleaners of the invention are surprisingly effective at removing tenacious baked-on soils encountered in the food service industry. Compositions of the invention have a viscosity of about 700 cps and are applied using a foaming or misting dispenser.
    Type: Grant
    Filed: September 2, 2010
    Date of Patent: April 16, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Thomas J. Vinson, Karen O. Rigley, Tami J. Tadrowski
  • Patent number: 8399393
    Abstract: A warewashing detergent composition is provided including an alkalinity source, a corrosion inhibitor and optionally, a cleaning agent. The glass corrosion inhibitor includes at least a soluble lithium salt and optionally includes a soluble aluminum salt and/or a soluble silicate salt. The warewashing detergent composition has a pH of at least about 8.
    Type: Grant
    Filed: May 3, 2010
    Date of Patent: March 19, 2013
    Assignee: Ecolab USA Inc.
    Inventor: Altony Miralles
  • Patent number: 8389463
    Abstract: A solid detergent composition includes an ethoxylated and propoxylated surfactant, an alkalinity source, a solidification agent and a chelating agent. The ethoxylated and propoxylated surfactant can include a surfactant blend of naturally sourced ethoxylated and propoxylated surfactants.
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: March 5, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Thomas R. Mohs, Jennifer L. Bergerson, Amanda R. Blattner, Charles A. Hodge, Steven E. Lentsch, Jacob Pitt
  • Patent number: 8329630
    Abstract: Cleaner compositions, methods of making cleaners, and methods of use are disclosed. Disclosed is a method of formulating a ready-to-use degreaser composition that has extended to infinite cling time. The method of making the cleaner results in thickened compositions that are capable of removing from vertical and inverted surfaces fresh, greasy and baked-on soils encountered in the food industry. The compositions include one or more alkalinity sources, one or more chelants, one or more surfactants, one or more thickening agents, one or more solvents, one or more buffers, and as a remainder, water. Compositions prepared according to the method of the invention are substantially free of phosphorous and have a low caustic content making them user friendly, having a lower pH than commercially available cleaners. Yet the cleaners prepared according to the method of the invention are surprisingly effective at removing tenacious baked-on soils encountered in the food service industry.
    Type: Grant
    Filed: January 26, 2012
    Date of Patent: December 11, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Jeremy B. Finison, Daniel L. Moran, Stephen T. Smith, Thomas J. Vinson, Karen O. Rigley
  • Patent number: 8252122
    Abstract: The invention relates to the use of an agent that contains 5 to 99.9% in weight of carbamide and/or at least a derivative thereof, as a cleaning agent for closed systems, in particular as a dishwasher detergent, as a laundry detergent for washing machines, as an agent for cleaning, sanitizing and/or disinfecting for equipment in the food processing industry and for medical equipment, the use as a hand dishwashing detergent or sanitary cleaner or as a hand cleaner. In addition, the invention relates to a method for reducing or avoiding enzymes in cleaning agents for closed systems, in hand dishwashing detergents or in sanitary cleaning agents as well as an enzyme-free dishwashing detergent or enzyme-free sanitary cleaning agent that contain 5 to 99.9% in weight of carbamides or derivates thereof. Finally, the invention relates to the use of percarbamide as a bleaching agent in particular in dishwashing detergents and in sanitary toilet cleaning agents.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: August 28, 2012
    Assignee: BBT Bergedorfer Biotechnik GmbH
    Inventors: Manfred Haake, Klaus Becker
  • Patent number: 8216989
    Abstract: A composition is provided for removing protein soil and preventing redeposition of soils onto a surface. The composition includes between about 1% and about 90% by weight sugar, between about 1% and about 80% by weight alkalinity source and between about 15 and about 10% by weight surfactant composition. The sugar may be a saccharide or a non-saccharide based sugar. The composition is substantially free of phosphorus-containing compounds and includes less than about 0.05% by weight alkali earth metal.
    Type: Grant
    Filed: August 26, 2009
    Date of Patent: July 10, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Carter Silvernail, Erik Olson, Devon Beau Hammel
  • Patent number: 8192553
    Abstract: A soaking composition including an alkalinity source, a metal protector, a surfactant, water, a threshold agent, a binding agent, and a polymer blend that functions as a binding agent and a hard water modifier. The polymer blend includes a polymaleic acid, a polycarboxylic acid and a sodium polyacrylate.
    Type: Grant
    Filed: May 26, 2010
    Date of Patent: June 5, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Edward J. Snodgrass, Jaclyn J. Steep
  • Patent number: 8063265
    Abstract: A hydrogel having a floatability where from 40% to 90% of a solution and/or suspension to be thickened are thickened starting from the surface of the liquid and the rest of the solution and/or suspension to be thickened is thickened starting from the bottom of the container, a process for preparing the hydrogel and also its use for absorbing blood and/or body fluids, especially in hygiene articles, or for thickening aqueous solutions and/or suspensions, especially for thickening medical wastes.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: November 22, 2011
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Beck, Volker Frenz, Anna Kowalski, Elisabeth Selzer, Ernst Jürgen Bauer, Harald Keller, Bernhard Steinmetz
  • Patent number: 7964547
    Abstract: Cleaner concentrates, associated cleaners, and associated methods are disclosed. The cleaner concentrates are capable for use in making cleaners that are capable of removing from surfaces fresh, greasy soils and polymerized soils more recently encountered in the food service industry originating from non-trans-fat oils. The cleaner concentrates include one or more alkalinity sources, one or more chelants, one or more surfactants, and as a remainder, water. The one or more alkalinity sources may be present in an amount sufficient to provide a free alkalinity (expressible as Na2O) of greater than about 3.6 wt % and a total alkalinity (expressible as Na2O) of greater than about 6.1 wt %, based on the total weight of the cleaner concentrate. The one or more chelants may be present in an amount sufficient to permit a use of a water having a hardness number up to about 600 ppm (600 mg/L) or more.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: June 21, 2011
    Assignee: Ecolab USA Inc.
    Inventors: Danielle E. Underwood, Tami J. Tadrowski, Karen O. Rigley
  • Patent number: 7922827
    Abstract: The present invention relates to cleaning compositions and methods employing a water soluble magnesium compound. Such compositions can be used for reducing scale, rinsing, hard surface cleaning, ware washing, and corrosion inhibition.
    Type: Grant
    Filed: May 24, 2010
    Date of Patent: April 12, 2011
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Michael E. Besse, Brenda L. Tjelta, Lisa M. Sanders, Keith E. Olson
  • Patent number: 7922828
    Abstract: The present invention relates to cleaning compositions and methods employing a water soluble magnesium compound. Such compositions can be used for reducing scale, rinsing, hard surface cleaning, ware washing, and corrosion inhibition.
    Type: Grant
    Filed: September 30, 2010
    Date of Patent: April 12, 2011
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Brenda L. Tjelta, Lisa M. Sanders, Keith E. Olson
  • Patent number: 7858574
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and at least one of a source of calcium ion or a source of magnesium ion. The amounts of calcium ion or magnesium ion can be selected depending upon the hardness of the water of dilution. Methods for using a warewashing detergent composition are provided.
    Type: Grant
    Filed: June 8, 2010
    Date of Patent: December 28, 2010
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Michael J. Bartelme, Keith E. Olson
  • Publication number: 20100323940
    Abstract: Solid block alkaline detergent compositions are disclosed comprising a source of alkalinity, and other detergent additives including sequestrants. The solid block detergents of the invention used a mixed inorganic and organic sequestrant composition that successfully softens service water used in manufacturing aqueous detergents from the composition, but also obtains substantially improved organic soil removal on dishware or flatware. The solid block detergents of the invention comprise large masses of the chemical ingredients having a weight of greater than about 500 grams in a solid block product format that is typically dispensed using a spray on water dispenser that creates an aqueous concentrate that is used in a washing machine.
    Type: Application
    Filed: August 11, 2010
    Publication date: December 23, 2010
    Applicant: Ecolab Inc.
    Inventors: Steven E. Lentsch, Keith E. Olson
  • Patent number: 7838484
    Abstract: Cleaner concentrates, associated cleaners, and associated methods are disclosed. The cleaner concentrates are capable for use in making cleaners that are capable of removing from surfaces fresh, greasy soils and polymerized soils more recently encountered in the food service industry originating from non-trans-fat oils. The cleaner concentrates include one or more alkalinity sources, one or more chelants, one or more surfactants, and as a remainder, water. The one or more alkalinity sources may be present in an amount sufficient to provide a free alkalinity (expressible as Na2O) of greater than about 3.6 wt % and a total alkalinity (expressible as Na2O) of greater than about 6.1 wt %, based on the total weight of the cleaner concentrate. The one or more chelants may be present in an amount sufficient to permit a use of a water having a hardness number up to about 600 ppm (600 mg/L) or more.
    Type: Grant
    Filed: April 18, 2008
    Date of Patent: November 23, 2010
    Assignee: Ecolab Inc.
    Inventors: Danielle Elise Underwood, Tami Jo Tadrowski, Karen Odom Rigley
  • Patent number: 7838485
    Abstract: An aqueous, alkaline cleaning composition for use on hard-to-clean soils, encountered in pharmaceutical, personal care, food and cosmetic manufacturing, comprising a source of alkalinity, a biodegradable surfactant system further comprising one or more surfactants, one or more hydrotropes, and a UV-analyzable surfactant, and a biodegradable chelating agent. The composition offers unique advantages of stability over the expected shelf life, low-foaming property, phosphate-free and biodegradable components, and unexpectedly enhanced antimicrobial, including virucidal, activity in one cleaning composition. The UV-analyzable surfactant allows for validation of cleaning processes using known techniques for manufacturers who are required or desire to do so.
    Type: Grant
    Filed: March 8, 2007
    Date of Patent: November 23, 2010
    Assignee: American Sterilizer Company
    Inventors: Christopher C. Heisig, Shahin Keller, John Macauley, Gurusamy Manivannan, Daniel Klein, Michael Ebers
  • Patent number: 7829516
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: November 12, 2009
    Date of Patent: November 9, 2010
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Keith E. Olson, Howie Kestell, Michael J. Bartelme, Steven E. Lentsch, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7828905
    Abstract: The present invention relates to cleaning compositions and methods employing a water soluble magnesium compound. Such compositions can be used for reducing scale, rinsing, hard surface cleaning, ware washing, and corrosion inhibition.
    Type: Grant
    Filed: October 31, 2008
    Date of Patent: November 9, 2010
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Brenda L. Tjelta, Lisa M. Sanders, Keith E. Olson
  • Patent number: 7759299
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and at least one of a source of calcium ion or a source of magnesium ion. The amounts of calcium ion or magnesium ion can be selected depending upon the hardness of the water of dilution. Methods for using a warewashing detergent composition are provided.
    Type: Grant
    Filed: July 24, 2006
    Date of Patent: July 20, 2010
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Michael J. Bartelme, Keith E. Olson
  • Patent number: 7749329
    Abstract: The present invention relates to cleaning compositions and methods employing a water soluble magnesium compound. Such compositions can be used for reducing scale, rinsing, hard surface cleaning, ware washing, and corrosion inhibition.
    Type: Grant
    Filed: May 2, 2008
    Date of Patent: July 6, 2010
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Michael E. Besse, Brenda L. Tjelta, Lisa M. Sanders, Keith E. Olson
  • Publication number: 20100139705
    Abstract: New solid detergent compositions and methods of forming and using those compositions are provided. The compositions for forming the solid detergents comprise a copolymer, scale inhibiting agent, and non-phosphate builder dispersed or dissolved in a solvent system. Advantageously, the inventive solid detergents provide dramatically improved cleaning performance and drying time without the use of a separate rinse additive. The detergents are especially suited to commercial dishmachine processes. The solid detergents are also in the form of a solid, homogeneous, self-sustaining body for improved handling and use.
    Type: Application
    Filed: December 10, 2008
    Publication date: June 10, 2010
    Inventor: Michael Oberlander
  • Patent number: 7671006
    Abstract: The present invention relates to the use of phosphated 2-propylheptanol or a phosphated 2-propylheptanol alkoxylate as a hydrotrope in aqueous alkaline solutions for a C8-C18-alcohol alkoxylate containing 1-20 ethyleneoxy units. It also relates to a phosphated 2-propylheptanol alkoxylate per se, and an alkaline cleaning composition comprising a C8-C18-alcohol alkoxylate containing 1-20 ethyleneoxy units and phosphated 2-propylheptanol and/or a phosphated 2-propylheptanol alkoxylate as a hydrotrope. The cleaning compositions may be used for industrial cleaning of hard surfaces, for example for vehicle cleaning or machine dishwashing.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: March 2, 2010
    Assignee: Akzo Nobel N.V.
    Inventors: Mahnaz Company, Magnus Franck, Anette Thyberg
  • Patent number: 7638473
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: October 13, 2008
    Date of Patent: December 29, 2009
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Keith E. Olson, Howie Kestell, Michael J. Bartelme, Steven E. Lentsch, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7578968
    Abstract: Processes for effecting biocidal activity in subterranean oil and gas wells being drilled, completed, worked over or produced are described. In general the process comprises blending with aqueous well fluid a biocidally-effective amount of a sulfamate stabilized, bromine-based biocide. Compositions comprised of aqueous well fluid blended with such aqueous biocides are also described.
    Type: Grant
    Filed: May 3, 2002
    Date of Patent: August 25, 2009
    Assignee: Albemarle Corporation
    Inventors: Christopher J. Nalepa, Joel F. Carpenter
  • Patent number: 7531490
    Abstract: The present invention relates to a detergent composition containing (a) 2 to 30% by weight of an inorganic alkali, (b) 0.5 to 20% by weight of at least one surfactant selected from an anionic surfactant and a nonionic surfactant, (c) 0.01 to 2% by weight (based on calcium ion) of a calcium salt, (d) 0.1 to 15% by weight of a calcium ion-sequestering agent, (e) 1 to 30% by weight of a water-soluble organic solvent and (f) 20 to 95% by weight of water.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: May 12, 2009
    Assignee: Kao Corporation
    Inventors: Junji Kondo, Yasunori Horio
  • Patent number: 7524803
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use solution having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: April 28, 2009
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Michael J. Bartelme, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7517848
    Abstract: A multiuse cleaning device in a solid state containing a homogeneous quantity of cleaning agent configured to dissolve and release a substantially consistent quantity of cleaning agent over a plurality of wash and rinse cycles. The cleaning agent includes a gas-releasing component and potassium silicate as a solubility control component to limit the solubility of the cleaning agent. The cleaning agent may include other ingredients such as an alkalinity agent as a pH regulator, a water softener to solvate metal ions in a solution of water, an optical brightener, an anti-redeposition agent, fragrances, surfactants, and other ingredients. Controlled dissolution of the cleaning agent composition releases a desired quantity of cleaning agent in each cleaning cycle over a plurality of cycles. A porous enclosure may be disposed around the solid cleaning agent.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: April 14, 2009
    Assignee: Eco-Safe Technologies, LLC
    Inventors: K Donald Evans, Cory E. Cook
  • Patent number: 7517846
    Abstract: The invention is a solid chemical concentrate system of at least two cooperative shapes. The first shape is an inwardly curved bar having an inner opening. The second shape is an insert which is capable of interlocking with the bar by insertion into the bar inner opening. The solid chemical concentrate provides chemical systems having active constituents which may be the same, different but compatible or functionally and chemically incompatible combined within one matrix to provide at least one substantially continuous surface. The system may also comprise an aqueous soluble or dispersible polymeric film cover.
    Type: Grant
    Filed: October 20, 2005
    Date of Patent: April 14, 2009
    Assignee: Ecolab Inc.
    Inventors: Elizabeth J. Gladfelter, Tina O. Outlaw, James L. Copeland, Rhonda K. Schulz, Daniel K. Boche, Jeff W. Peterson
  • Patent number: 7456144
    Abstract: The present invention relates to the use of phosphated 2-propylheptanol or a phosphated 2-propylheptanol alkoxylate as a hydrotrope in aqueous alkaline solutions for a C8-C18-alcohol alkoxylate containing 1-20 ethyleneoxy units. It also relates to a phosphated 2-propylheptanol alkoxylate per se, and an alkaline cleaning composition comprising a C8-C18-alcohol alkoxylate containing 1-20 ethyleneoxy units and phosphated 2-propylheptanol and/or a phosphated 2-propylheptanol alkoxylate as a hydrotrope. The cleaning compositions may be used for industrial cleaning of hard surfaces, for example for vehicle cleaning or machine dishwashing.
    Type: Grant
    Filed: July 8, 2005
    Date of Patent: November 25, 2008
    Assignee: Akzo Nobel N.V.
    Inventors: Mahnaz Company, Magnus Franck, Anette Thyberg
  • Patent number: 7452853
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: August 7, 2006
    Date of Patent: November 18, 2008
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Keith E. Olson, Howie Kestell, Michael J. Bartelme, Steven E. Lentsch, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Publication number: 20080274932
    Abstract: A composition useful in hard surface treatment and particularly useful in automatic warewashing is provided according to the invention. The composition may comprise a pretreatment composition, a detersive composition, a rinse agent composition or a combination thereof. The composition includes water-soluble cation and a source of alkalinity. The anionic alkaline source is selected from at least one of hydroxide anion or carbonate anion or a combination thereof. The cation is selected from magnesium, titanium, and aluminum, or combinations thereof. The source of alkalinity is provided in an amount effective to provide a use composition having a pH of greater than about 7. The cation is present in sufficient amount to form an in situ conversion agent. A conversion agent is a water-insoluble hydroxide precipitate that causes calcium in hard water to precipitate as aragonite thereby softening the water.
    Type: Application
    Filed: May 2, 2008
    Publication date: November 6, 2008
    Applicant: ECOLAB INC.
    Inventors: Kim R. Smith, Keith E. Olson, Lee J. Monsrud, Kristen A. Mills, Michael Rischmiller
  • Patent number: 7196045
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use solution having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: February 2, 2006
    Date of Patent: March 27, 2007
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Michael J. Bartelme, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7196044
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: March 27, 2007
    Assignee: Ecolab, Inc.
    Inventors: Kim R. Smith, Keith E. Olson, Howie Kestell, Michael J. Bartelme, Steven E. Lentsch, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7091166
    Abstract: An aqueous liquid composition comprising water; at least one acid selected from the group consisting of carboxylic acids, hydroxycarboxylic acids, and inorganic acids other than phosphoric acid wherein the at least one acid is present in an amount from about 1.0 to about 30 milliequivalents per kilogram of total composition (“mEq/kg”); and an amphoteric surfactant wherein the amphoteric surfactant is present in an amount from about 0.01 to about 20 grams per kilogram of total composition (“g/kg”), the aqueous liquid composition having a pH from about 2.0 to about 6.1 and having a reduced etch attack on metal as compared to an aqueous composition comprising from about 1.0 to about 30 milliequivalents per kilogram of total composition (“mEq/kg”) of acids selected from the group consisting of carboxylic, hydroxycarboxylic, and inorganic acids, and not containing the amphoteric surfactant.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: August 15, 2006
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Theodore D. Held, III
  • Patent number: 6984614
    Abstract: A composition for removing paraffin, wax, or asphaltine deposits from the surface of a crude oil transmission system, such as a downhole tubular, a pipeline, or a surface tank, includes an aqueous sodium hydroxide solution containing from 18% to 25% by weight sodium hydroxide. The composition further includes an acetic acid solution containing from 30% to 55% by weight acetic acid compared to the sodium hydroxide, and a liquid aromatic hydrocarbon having from 6 to 10 carbon atoms and from 15% to 40% by weight compared to the sodium hydroxide. According to the method of the invention, the aqueous sodium hydroxide solution may be metered in a downhole tubular or a pipeline separate from the acetic acid solution, such that heat generated by the mixed composition is generated within the downhole tubular or the pipeline.
    Type: Grant
    Filed: January 10, 2005
    Date of Patent: January 10, 2006
    Inventor: Jerome S. Als
  • Patent number: 6956019
    Abstract: An alkaline detergent composition is provided including a source of alkalinity and an effective soil removing amount of a nonionic surfactant blend. The nonionic surfactant blend includes a monionic surfactant having a hydrophobic and an (EO) group and a nonionic silicone surfactant. The detergent composition provides for the removal of waxy-fatty soil.
    Type: Grant
    Filed: July 19, 2004
    Date of Patent: October 18, 2005
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Victor F. Man, Deborah A. Ihns, Helmut K. Maier, Rhonda K. Schulz
  • Patent number: 6911422
    Abstract: A process of imparting transparency or translucency to a liquid or gel type automatic dishwashing detergent product is disclosed. The process includes the steps of providing a liquid or gel type automatic dishwashing detergent composition expressly free from (i) potassium tripolyphosphate and (ii) mixture of sodium tripolyphosphate and potassium tripolyphosphate, adding one or more of potassium sources to the liquid or gel type automatic dishwashing detergent composition, the potassium sources being expressly free of potassium tripolyphosphate, and maintaining a K:Na weight ratio greater than at least about 0.5:1.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: June 28, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Brian Xiaoqing Song, Peter Robert Foley, Melissa Dee Aquino
  • Patent number: 6812195
    Abstract: The present invention is directed to a grease-cutting detergent composition that exhibits a stable foaming profile when used with non-enclosed automatic dishwashers. The composition can be sold in a concentrated form or in ready-to-use (RTU) diluted form. The concentrated compositions are formulated to be diluted with water before use. The RTU formulas are intended for as-is usage. In one embodiment the concentrated compositions comprises a) from about 0.25% to about 10% of a surfactant, b) from about 4% to about 8% of an alkalinity source, c) from about 0.1% to about 4.0% of a hydrotrope, d) from about 0.001% to about 2.0% of a builder, and e) from about 0.01% to about 3.0% of a thickener. In another embodiment an RTU formulation comprises a) from about 50 ppm to about 80 ppm of a surfactant, b) from about 45 ppm to about 75 ppm of an alkalinity source, c) from about 20 ppm to about 45 ppm of a hydrotrope, d) from about 0.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: November 2, 2004
    Assignee: The Procter & Gamble Co.
    Inventors: Thomas James Wierenga, James August Weikel