Alkali Metal Hydroxide Component Patents (Class 510/225)
  • Patent number: 6812202
    Abstract: The invention relates to a highly alkaline or mildly alkaline detergent composition having enhanced cleaning properties. The detergent combines a source of alkalinity and a blend of nonionic surfactants that enhances cleaning starchy soils. The blend of nonionic surfactants preferably includes an alkyl polyglycoside surfactant and a silicon surfactant having a hydrophobic silicon group and a pendant hydrophilic group. Preferably, the blend of nonionic surfactants includes a surfactant having a hydrophobic group and an ethylene oxide residue containing group and a polymer additive. A method for removing soil from an article is provided.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: November 2, 2004
    Assignee: Ecolab Inc.
    Inventors: Victor F. Man, Terrence P. Everson, Steven E. Lentsch
  • Patent number: 6800600
    Abstract: A paste-form to solid detergent composition is provided consisting of a) 21 to 70 percent by weight of an aqueous lye solution having a concentration of 42 to 55 percent by weight of lye; b) 0.5 to 40 percent by weight of one or more alcoholates of ethanol, propanol, isopropanol, glycerol or butyleneglycol, and c) 10 to 35 percent by weight of water. The detergent is a high alkaline detergent, useful for cleaning hard surfaces.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: October 5, 2004
    Assignee: Ecolab GmbH & Co. oHG
    Inventors: Werner Strothoff, Dieter Hemm, Guenter Hellmann
  • Patent number: 6664219
    Abstract: An alkaline detergent composition is provided including a source of alkalinity and an effective soil removing amount of a nonionic surfactant blend. The nonionic surfactant blend includes a nonionic surfactant having a hydrophobic and an (EO) group and a nonionic silicone surfactant. The detergent composition provides for the removal of waxy-fatty soil.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: December 16, 2003
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Victor F. Man, Deborah A. Ihns, Helmut K. Maier, Rhonda K. Schulz
  • Patent number: 6649586
    Abstract: The invention relates to a highly alkaline or mildly alkaline detergent composition having enhanced cleaning properties. The detergent combines a source of alkalinity and a blend of nonionic surfactants that enhances cleaning starchy soils. The blend of nonionic surfactants preferably includes an alkyl polyglycoside surfactant and a silicon surfactant having a hydrophobic silicon group and a pendant hydrophilic group. Preferably, the blend of nonionic surfactants includes a surfactant having a hydrophobic group and an ethylene oxide residue containing group and a polymer additive. A method for removing soil from an article is provided.
    Type: Grant
    Filed: January 30, 2003
    Date of Patent: November 18, 2003
    Assignee: Ecolab Inc.
    Inventors: Victor F. Man, Terrence P. Everson, Steven E. Lentsch
  • Patent number: 6608023
    Abstract: A solid block detergent composition is described which can be dispensed with a water spray to form an aqueous detergent for cutting and removing grease, removing and suspending soils and rinsing easily leaving cleaned ware. The aqueous detergent concentrate can be used in a cleaning liquid having exceptional soil, particularly grease removing properties with stable foam properties. The solid block detergent contains a package of surfactants including a neutralized anionic surfactant with either one or a mixture of an alkali and alkaline earth metal salt thereof and an alkylpolyglycoside. The active ingredients and polyethylene glycol as a hardening agent are dispersed in a matrix which hardens to form a solid block.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: August 19, 2003
    Assignee: Ecolab Inc.
    Inventors: Karen G. Klaers, Helen B. Bailly
  • Publication number: 20030114329
    Abstract: The present invention is directed to a grease-cutting detergent composition that exhibits a stable foaming profile when used with non-enclosed automatic dishwashers. The composition can be sold in a concentrated form or in ready-to-use (RTU) diluted form. The concentrated compositions are formulated to be diluted with water before use. The RTU formulas are intended for as-is usage. In one embodiment the concentrated compositions comprises a) from about 0.25% to about 10% of a surfactant, b) from about 4% to about 8% of an alkalinity source, c) from about 0.1% to about 4.0% of a hydrotrope, d) from about 0.001% to about 2.0% of a builder, and e) from about 0.01% to about 3.0% of a thickener. In another embodiment an RTU formulation comprises a) from about 50 ppm to about 80 ppm of a surfactant, b) from about 45 ppm to about 75 ppm of an alkalinity source, c) from about 20 ppm to about 45 ppm of a hydrotrope, d) from about 0.
    Type: Application
    Filed: September 16, 2002
    Publication date: June 19, 2003
    Inventors: Thomas James Wierenga, James August Weikel
  • Patent number: 6525015
    Abstract: The invention relates to a highly alkaline or mildly alkaline detergent composition having enhanced cleaning properties. The detergent combines a source of alkalinity and a blend of nonionic surfactants that enhances cleaning starchy soils. The blend of nonionic surfactants preferably includes an alkyl polyglycoside surfactant and a silicon surfactant having a hydrophobic silicon group and a pendant hydrophilic group. Preferably, the blend of nonionic surfactants includes a surfactant having a hydrophobic group and an ethylene oxide residue containing group and a polymer additive. A method for removing soil from an article is provided.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: February 25, 2003
    Assignee: Ecolab Inc.
    Inventors: Victor F. Man, Terrence P. Everson, Steven E. Lentsch
  • Patent number: 6506261
    Abstract: Organic compositions, used neat or in concentrate, are effective in removing complex organic soils from wood, metal and other hard surfaces. The compositions comprise nonionic surfactants, silicone surfactants, anionic surfactants, hydrotropes and other optional functional materials including sequestrants. Substrates such as laundry and heavily soiled hard surfaces containing a substantial proportion of organic/inorganic soils such as greases, oils and other hard to remove soil materials are readily cleaned by the cleaner compositions of the invention.
    Type: Grant
    Filed: September 26, 2000
    Date of Patent: January 14, 2003
    Assignee: Ecolab Inc.
    Inventor: Victor F. Man
  • Patent number: 6503879
    Abstract: Solid block alkaline detergent compositions are disclosed comprising a source of alkalinity, and other detergent additives including sequestrants. The solid block detergents of the invention used a mixed inorganic and organic sequestrant composition that successfully softens service water used in manufacturing aqueous detergents from the composition, but also obtains substantially improved organic soil removal on dishware or flatware. The solid block detergents of the invention comprise large masses of the chemical ingredients having a weight of greater than about 500 grams in a solid block product format that is typically dispensed using a spray on water dispenser that creates an aqueous concentrate that is used in a washing machine.
    Type: Grant
    Filed: March 15, 2001
    Date of Patent: January 7, 2003
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Keith E. Olson, Victor F. Man
  • Patent number: 6489278
    Abstract: The invention relates to a A highly alkaline or mildly alkaline detergent composition having enhanced cleaning properties. The detergent which combines a source of alkalinity and with a blend of nonionic surfactants that enhances cleaning waxy-fatty soils. This blend of surfactants shows surprising cooperation in reducing surface tension and comprises a nonionic or amphoteric surfactant and a silicone containing surfactant.
    Type: Grant
    Filed: January 13, 1997
    Date of Patent: December 3, 2002
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Victor F. Man, Deborah A. Ihns, Helmut K. Maier, Rhonda K. Schulz
  • Patent number: 6455484
    Abstract: The invention is a solid chemical concentrate system of at least two cooperative shapes. The first shape is an inwardly curved bar having an inner opening. The second shape is an insert which is capable of interlocking with the bar by insertion into the bar inner opening. The solid chemical concentrate provides chemical systems having active constituents which may be the same, different but compatible or functionally and chemically incompatible combined within one matrix to provide at least one substantially continuous surface. The system may also comprise an aqueous soluble or dispersible polymeric film cover.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: September 24, 2002
    Assignee: Ecolab Inc.
    Inventors: Elizabeth J. Gladfelter, Tina O. Outlaw, James L. Copeland, Rhonda K. Schulz, Daniel K. Boche, Jeff W. Peterson
  • Patent number: 6436893
    Abstract: Solid block alkaline detergent compositions are disclosed comprising a source of alkalinity, and other detergent additives including sequestrants. The solid block detergents of the invention used a mixed inorganic and organic sequestrant composition that successfully softens service water used in manufacturing aqueous detergents from the composition, but also obtains substantially improved organic soil removal on dishware or flatware. The solid block detergents of the invention comprise large masses of the chemical ingredients having a weight of greater than about 500 grams in a solid block product format that is typically dispensed using a spray on water dispenser that creates an aqueous concentrate that is used in a washing machine.
    Type: Grant
    Filed: October 18, 2000
    Date of Patent: August 20, 2002
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Keith E. Olson, Victor F. Man
  • Patent number: 6425959
    Abstract: Organic compositions, used neat or in concentrate, are effective in removing complex organic soils from wood, metal and other hard surfaces. The compositions comprise nonionic surfactants, silicone surfactants, hydrotropes and other optional functional materials including sequestrants. Substrates such as laundry and heavily soiled hard surfaces containing a substantial proportion of organic/inorganic soils such as greases, oils and other hard to remove soil materials are readily cleaned by the cleaner compositions of the invention.
    Type: Grant
    Filed: June 24, 1999
    Date of Patent: July 30, 2002
    Assignee: Ecolab Inc.
    Inventor: Victor F. Man
  • Patent number: 6368420
    Abstract: A chemical cleaning system for a multi-tank or a single-tank mechanical warewashing machine is provided, having at least two separate components for aqueous dissolution or dilution to respective use concentrations, a first component comprising an enzyme or a mixture of an enzyme and a cleaning agent, and a second component comprising a bleach, wherein the first component is introduced into a wash zone or step and wherein the second component is introduced into a post-rinse zone or step.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: April 9, 2002
    Assignee: Diversey Lever, Inc.
    Inventors: Petrus Adrianus Angevaare, Paul Flu, John Richard Nicholson, Frederik Jan Schepers
  • Patent number: 6367487
    Abstract: A novel anti-etch and cleaning solution is described. The solution comprises a hetero functionalized polymer, caustic and optionally, an anti-etch component and unexpectedly results in glassware that is substantially free of contaminants and etching after washing.
    Type: Grant
    Filed: August 11, 1999
    Date of Patent: April 9, 2002
    Assignee: Diversey Lever, Inc.
    Inventors: Carol Anne Rouillard, Charles Allen Crawford, David Cole, Michael Howell
  • Patent number: 6369021
    Abstract: The invention relates to a highly alkaline or mildly alkaline detergent composition having enhanced cleaning properties. The detergent combines a source of alkalinity and a blend of nonionic surfactants that enhances cleaning starchy soils. The blend of nonionic surfactants preferably includes an alkyl polyglycoside surfactant and a silicon surfactant having a hydrophobic silicon group and a pendant hydrophilic group. Preferably, the blend of nonionic surfactants includes a surfactant having a hydrophobic group and an ethylene oxide residue containing group and a polymer additive. A method for removing soil from an article is provided.
    Type: Grant
    Filed: May 7, 1999
    Date of Patent: April 9, 2002
    Assignee: Ecolab Inc.
    Inventors: Victor F. Man, Terrence P. Everson, Steven E. Lentsch
  • Patent number: 6331518
    Abstract: A water-containing solid detergent having a delayed, controllable and variable hardening time after addition of all the components produced by providing a) aqueous 42 to 55% lye, in a quantity of 21 to 70% by weight, b) mixing with the aqueous lye a compound selected from the group corresponding to formula (I): HOCH2CH(R1)OR2  (I) in which R1 is a hydrogen atom or a methyl group and R2, independent of R1, is a hydrogen atom, a C1-4 alkyl group, a group CH2CH(R3)0R4 or a group CH2CH(R5)OCH2—CH(R6)OR7, where R3, R5, and R6 represent hydrogen atoms or methyl groups and R4and R7 represent hydrogen atoms or C1-4 alkyl groups, and compounds corresponding to formula II: [HOCH2CH(R8)3−xNHx  (II) in which R8 is a hydrogen atom or a methyl group and x is the number 0, 1 or 2, in a total quantity of 0.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: December 18, 2001
    Assignee: Henkel-Ecolab GmbH & Co. OHG
    Inventors: Dieter Hemm, Guenter Hellmann
  • Patent number: 6303554
    Abstract: A method for pretreating a plastic surface in a coating process. The plastic surface is immersed in a solution containing iso-propanol, or another light alcohol, and potassium hydroxide (KOH). The method and the solution according to the present invention are particularly useful for cleaning and etching plastic surfaces (e.g. PU or PVC) with a heavy organic chemical contamination (e.g. silicone).
    Type: Grant
    Filed: June 13, 2000
    Date of Patent: October 16, 2001
    Assignee: International Business Machines Corporation
    Inventors: Donato Casati, Fabio Mauri, Silvano Passagrilli
  • Patent number: 6277801
    Abstract: Highly alkaline caustic cleaners used in large scale industrial applications are stabilized and enhanced with improved surface tension reduction and decreased foaming properties through the incorporation of minor amounts of a surfactant composition comprising a alkylether hydroxypropyl sultaine surfactant and a nonionic ethoxylated surfactant.
    Type: Grant
    Filed: October 4, 1999
    Date of Patent: August 21, 2001
    Assignee: Rhodia Inc.
    Inventors: Manilal S. Dahanayake, Mark E. Ventura
  • Patent number: 6204231
    Abstract: An aqueous alkaline composition for cleaning equipment used in the food industry wherein the composition contains potassium hydroxide or a mixture of potassium hydroxide and sodium hydroxide and wherein the potassium hydroxide is present in an amount of at least 20% by weight, based on the weight of hydroxide present in the composition. A process for regenerating the cleaning solution is also disclosed.
    Type: Grant
    Filed: September 1, 1998
    Date of Patent: March 20, 2001
    Assignee: Henkel Kommandigesellschaft Auf Aktien
    Inventors: Anja Patten, Ralf Krack, Dietmar Rossner
  • Patent number: 6191086
    Abstract: Non-corrosive cleaning compositions that are aqueous based and useful for removing photoresist, plasma etch and CMP residues from a substrate. One preferred cleaning composition comprises: (i) a hydroxylamine or a hydroxylamine salt compound; (ii) at least one fluorine-containing compound; and (iii) water. Another cleaning composition comprises: (i) a compound selected from the group consisting of: an amine, a quatenary ammonium hydroxide, and ammonium hydroxide; (ii) at least one fluorine-containing compound; and (iii) water.
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: February 20, 2001
    Assignee: Arch Specialty Chemicals, Inc.
    Inventors: Vincent G. Leon, Kenji Honda, Eugene F. Rothgery
  • Patent number: 6180578
    Abstract: A water-containing compact detergent composition having a controllably variable strength containing an aqueous lye solution, a viscosity increasing agent selected from a compound corresponding to formula I or formula II HOCH2CH(R1)OR2   (I) [HOCH2CH(R8)3-xNHx  (II) and a solid alkali metal hydroxide. The product is useful in domestic or institutional dishwashing machines.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: January 30, 2001
    Assignee: Henkel Kommanditgesellschaft Auf Aktien
    Inventors: Dieter Hemm, Guenter Hellmann, Klaus Wilbert
  • Patent number: 6164296
    Abstract: A highly alkaline or mildly alkaline detergent composition having enhanced cleaning properties is provided. The detergent combines a source of alkalinity and a blend of nonionic surfactants that enhances cleaning waxy-fatty soils.
    Type: Grant
    Filed: January 11, 1999
    Date of Patent: December 26, 2000
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Victor F. Man, Deborah A. Ihns, Helmut K. Maier, Rhonda K. Schulz
  • Patent number: 6150324
    Abstract: Solid block alkaline detergent compositions are disclosed comprising a source of alkalinity, and other detergent additives including sequestrants. The solid block detergents of the invention used a mixed inorganic and organic sequestrant composition that successfully softens service water used in manufacturing aqueous detergents from the composition, but also obtains substantially improved organic soil removal on dishware or flatware. The solid block detergents of the invention comprise large masses of the chemical ingredients having a weight of greater than about 500 grams in a solid block product format that is typically dispensed using a spray on water dispenser that creates an aqueous concentrate that is used in a washing machine.
    Type: Grant
    Filed: January 13, 1997
    Date of Patent: November 21, 2000
    Assignee: Ecolab, Inc.
    Inventors: Steven E. Lentsch, Keith E. Olson
  • Patent number: 6017864
    Abstract: We have found that long standing problems relating to the stability of organic materials in alkaline detergents, including the reversion or hydrolysis of condensed phosphate sequestrants in alkaline solid detergent compositions can be alleviated by the use of an organic composition having vicinal hydroxyls. Such a solid block detergent can be manufactured by a process in which a source of alkalinity, a functional material including a condensed phosphate sequestering agent, an organic compound having two vicinal hydroxyl groups, are combined in a pourable composition or liquid. Such a liquid can be introduced into a plastic capsule and solidified. During manufacture and solidification, we have found that the vicinal hydroxyl compound prevents substantial hydrolysis or reversion of the condensed phosphate maintaining effective hardness ion sequestration during the use of the detergent. The stabilizer can also stabilizes color, chlorine content and dispensing properties.
    Type: Grant
    Filed: December 30, 1997
    Date of Patent: January 25, 2000
    Assignee: Ecolab Inc.
    Inventors: Kent R. Brittain, Bernard J. Heile, Helmut K. Maier, Charles A. Hodge, G. Jason Wei
  • Patent number: 5942481
    Abstract: The caustic cleaner of the present invention has a freezing point of no more than about 40.degree. F. The caustic cleaner is a mixture of aqueous sodium hydroxide and an organic salt derived from the reaction of sodium hydroxide and gluconic acid at elevated temperatures.
    Type: Grant
    Filed: June 12, 1997
    Date of Patent: August 24, 1999
    Assignee: Charvid Limited Liability Co.
    Inventor: Charles Bullick Talley
  • Patent number: 5876514
    Abstract: We have found an alkaline warewashing detergent composition that can contain a critical amount of a nonionic rinse agent that when used in automatic warewashing machines permits the use of a potable water rinse without the addition of a separate rinse agent. Sufficient residual nonionic surfactant from the alkaline detergent remains on the surface ware and internal machine and rack surfaces after washing to promote adequate sheeting in the rinse cycle. The residual nonionic surfactant on internal surfaces dissolves in the rinse water to create an effective aqueous rinse agent. The nonionic rinse agents can be a single nonionic for both foam reduction cleaning and sheeting or can be a blend of nonionic materials providing these functions. The detergent can be in the form of a particulate, pelletized or block solid.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: March 2, 1999
    Assignee: Ecolab Inc.
    Inventors: John J. Rolando, Terry J. Klos
  • Patent number: 5786314
    Abstract: Automatic dishwashing detergent compositions comprising a weight to weight ratio of calcium complexing component to carbonate source of at least 0.9 and having a pH between about 7 and about 11 are disclosed. The compositions exhibit enhanced filming performance, particularly preferred compositions additionally contain polymer dispersant and silicate.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: July 28, 1998
    Assignee: The Procter & Gamble Company
    Inventor: Eugene Steven Sadlowski
  • Patent number: 5786315
    Abstract: Automatic dishwashing detergent compositions comprising a carbonate source and a pH from about 5.0 to about 9.5 for enhanced filming performance are disclosed. Particularly preferred compositions contain polymer dispersant and silicate.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: July 28, 1998
    Assignee: The Procter & Gamble Company
    Inventor: Eugene Steven Sadlowski
  • Patent number: 5759988
    Abstract: There is provided an environmentally stable detergent article. Normally, hygroscopic caustic detergent materials can be made resistant to absorption of ambient humidity or water by introducing a barrier coating onto the caustic detergent. The barrier also renders the highly active alkaline material safe for human handling. The coated detergent article can further be enclosed in a film enclosure or wrapping which provides further protection for handling during production, shipment, storage and final end use. The coated article can be removed from any packaging material, inserted into a water spray-on dispenser and used to create a concentrated aqueous detergent for use in ware washing machines. In order to obtain control over dispensing, hydrophobic coatings can be nicked, split, peeled or partially removed using other means to provide an initial surface of caustic detergent exposed to the water spray.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: June 2, 1998
    Assignee: Ecolab Inc.
    Inventors: Bernard Joseph Heile, James John Tarara
  • Patent number: 5759976
    Abstract: Tableted detergents are formed from a hydrated phosphate sequestrant, caustic, free water and, optionally, fillers by combining the products and tableting the components without permitting the tablets or detergent to exceed 50.degree. C. In a preferred embodiment where fillers are incorporated, all free water is combined with the phosphate sequestrants, both anhydrous and hydrated. After the water has been absorbed by the sequestrants, the filler and caustic can be added and the detergent tableted. The free water is bound sufficiently tightly to the phosphate sequestrant that it does not rapidly react with the anhydrous caustic, maintaining the temperature at less than 50.degree. C., which in turn prevents the water of hydration in the phosphates from reacting and thereby weakening the formed tablets. The tablets can also be formed by combining the filler with the phosphate sequestrants and water and subsequently adding caustic if the detergent is cooled and its temperature maintained below 50.degree. C.
    Type: Grant
    Filed: July 22, 1997
    Date of Patent: June 2, 1998
    Assignee: Diversey Lever, Inc.
    Inventors: Kenneth James Roach, Patricia Anderson
  • Patent number: 5698507
    Abstract: An automatic dishwashing compositions containing a mixture of an acid resistant protease enzyme and an acid resistant amylase enzyme have been found to be very useful in the removal of protein and carbohydrate soils from dishware at operating temperatures of 100.degree. F. to 140.degree. F.
    Type: Grant
    Filed: September 10, 1996
    Date of Patent: December 16, 1997
    Assignee: Colgate-Palmolive Co.
    Inventors: Philip A. Gorlin, Divaker Kenkare, Steve Phillips
  • Patent number: 5693601
    Abstract: The present invention is an aqueous liquid detergent composition comprising a short chain surfactant for improved cleaning performance. Said composition further comprises a mixture of long chain amide oxides to restore viscosity. Said composition provides outstanding soil removal when used as a dish pretreatment composition as well as outstanding cleaning performance when used in hard-surface applications including toilet bowl cleaning.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: December 2, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Panos Iakovides, Rita De Berardinis, Anna Lucia D'Orazio, Andrea Soddu
  • Patent number: 5670467
    Abstract: Stratified solid cast alkaline detergent compositions are disclosed in which the concentrations of an active alkalinity source and water of hydration which contain at least one granular material in varying concentration throughout the composition. Methods of making and using the disclosed compositions are also disclosed.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: September 23, 1997
    Inventor: Howard Fleisher
  • Patent number: 5670473
    Abstract: A method for forming solid cleaning agents starts with hydrated forms of salts that generally have considerably lower melting points in their hydrated forms. The hydrated salt cleaning agents are heated to form a melted cleaning suspension. Additional ingredients can be mixed into the melted cleaning suspension. These additional ingredients can be selected from the group consisting of nonionic surfactants, anionic surfactants, alkaline builders, multivalent metal sequestering agents, active enzymes, soil suspending agents, defoamers, oxygenated solvents, fragrances, optical brighteners and colorants. An alternative method involves the formation of a mixture of powder or granular cleaning composition components. These components include at least 15 percent by weight of a moderate melting point cleaning additive. A receptacle with the cleaning components is heated to a temperature above the melting point of the moderate melting point cleaning additive.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 23, 1997
    Assignee: Sunburst Chemicals, Inc.
    Inventor: William H. Scepanski
  • Patent number: 5534178
    Abstract: Uniform, microscopic perforated water soluble film is herein described, and its use in packaging solid, pelletized or particulate detersire compositions containing strong acids, strong bases or a source of halogen whereby the package provides air to pass through without leakage of its contents. Also described is a method of manufacture of a sealed, water soluble, detersire package with microscopic perforations and an apparatus for said manufacture.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: July 9, 1996
    Assignee: Ecolab Inc.
    Inventors: Helen Bailly, Arthur Luedtke, Paul Pankratz, Joy Allen, Tina O. Outlaw, Lance K. Fisher, Kelvin D. Sundeen
  • Patent number: RE38262
    Abstract: We have found an alkaline warewashing detergent composition that can contain a critical amount of a nonionic rinse agent that when used in automatic warewashing machines permits the use of a potable water rinse without the addition of a separate rinse agent. Sufficient residual nonionic surfactant from the alkaline detergent remains on the surface ware and internal machine and rack surfaces after washing to promote adequate sheeting in the rinse cycle. The residual nonionic surfactant on internal surfaces dissolves in the rinse water to create an effective aqueous rinse agent. The nonionic rinse agents can be a single nonionic for both foam reduction cleaning and sheeting or can be a blend of nonionic materials providing these functions. The detergent can be in the form of a particulate, pelletized or block solid.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: October 7, 2003
    Assignee: Ecolab Inc.
    Inventors: John J. Rolando, Terry J. Klos