Carbonyl Single Bonded To Nitrogen In The Activator Or Precursor (e.g., Amide, Imide, Etc.) Patents (Class 510/313)
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Patent number: 9023783Abstract: The present application relates to encapsulated, solid, water soluble benefit agents and products comprising such encapsulates, as well as processes for making and using such encapsulates and products comprising such encapsulates. In one aspect, the present application relates to a melamine formaldehyde and/or urea formaldehyde encapsulation process that offers as solution to the dissolution of solid, water soluble benefit agents during the process's emulsification step.Type: GrantFiled: August 5, 2014Date of Patent: May 5, 2015Assignee: The Procter & Gamble CompanyInventors: Johan Smets, Susana Fernandez Prieto, Sandra Jacqueline Guinebretiere
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Patent number: 8927478Abstract: The invention relates to the use of manganese oxalates in detergents and cleaning agents, in particular in cleaning agents containing peroxy compounds for hard surfaces.Type: GrantFiled: August 26, 2009Date of Patent: January 6, 2015Assignee: Clariant International Ltd.Inventors: Gerd Reinhardt, Michael Best, Joachim Erbes
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Patent number: 8883704Abstract: The invention relates to co-granules containing a) at least one bleach activator, b) at least one metal-containing bleach catalyst, and c) at least 5 wt. % of at least one organic acid. The co-granules are easy to produce, have a high stability in storage and are advantageously suitable for producing cleaning products and detergents and especially products for cleaning crockery in a machine.Type: GrantFiled: April 1, 2010Date of Patent: November 11, 2014Assignee: Clariant International Ltd.Inventors: Georg Borchers, Gerd Reinhardt, Andreas Schottstedt
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Patent number: 8858650Abstract: A method of treating a fabric using an effective amount of a two component system comprising: i) a source of peroxy bleach; and ii) a source of peroxy bleach activator in liquid form where the two components are mixed at the time and location of use to form an activated peroxy bleaching system.Type: GrantFiled: July 14, 2008Date of Patent: October 14, 2014Assignee: Sunburst Chemicals, Inc.Inventor: William Scepanski
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Patent number: 8822402Abstract: The present application relates to encapsulated, solid, water soluble benefit agents and products comprising such encapsulates, as well as processes for making and using such encapsulates and products comprising such encapsulates. In one aspect, the present application relates to a melamine formaldehyde and/or urea formaldehyde encapsulation process that offers as solution to the dissolution of solid, water soluble benefit agents during the process's emulsification step.Type: GrantFiled: December 16, 2013Date of Patent: September 2, 2014Assignee: The Procter & Gamble CompanyInventors: Johan Smets, Susana Fernandez Prieto, Sandra Jacqueline Guinebretiere
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Patent number: 8637441Abstract: The present invention discloses a non-foaming detergent, including a sodium alginate, an amylum, a sodium silicate, a citric acid, a sodium citrate, a sea salt, a sodium peroxyborate, a TAED and a borax. Herein, the non-foaming detergent further includes a sodium bicarbonate and a soapnut saponin. The preparation method of the non-foaming detergent comprises the following steps: mixing a sodium silicate and a sodium peroxyborate under stirring, mixing a soapnut saponin, a sodium alginate, an amylum, a sodium citrate, a sea salt, a sodium bicarbonate, a TAED and a borax under stirring, mixing such two mixtures, adding a citric acid therein and further mixing to obtain the non-foaming detergent. In the present invention, the prepared detergent has good solubility, strong activity at low temperature, high washing power and thorough detergency. Besides, the detergent is non-foaming and non-flavoring and the exhaust water during washing can be bio-degraded effectively.Type: GrantFiled: December 3, 2012Date of Patent: January 28, 2014Assignee: Newer World International Company LimitedInventor: Shu Feng Chen
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Patent number: 8633148Abstract: The present application relates to encapsulated, solid, water soluble benefit agents and products comprising such encapsulates, as well as processes for making and using such encapsulates and products comprising such encapsulates. In one aspect, the present application relates to a melamine formaldehyde and/or urea formaldehyde encapsulation process that offers as solution to the dissolution of solid, water soluble benefit agents during the process's emulsification step.Type: GrantFiled: April 5, 2011Date of Patent: January 21, 2014Assignee: The procter & Gamble CompanyInventors: Johan Smets, Susana Fernandez Prieto, Sandra Jacqueline Guinebretiere
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Patent number: 8586521Abstract: The present invention relates to a method of laundering fabric comprising the step of contacting a laundry detergent composition to water to form a wash liquor, and laundering fabric in said wash liquor, wherein the wash liquor has a temperature of above 0° C. to 20° C., and wherein the laundry detergent composition comprises greater than 1 wt % detersive surfactant and other detergent ingredients.Type: GrantFiled: February 13, 2012Date of Patent: November 19, 2013Assignee: The Procter & Gamble CompanyInventors: Alan Thomas Brooker, Philip Frank Souter
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Publication number: 20130261041Abstract: The present invention relates to specific acylhydrazone compounds, their use as oxidation catalysts and to a process for removing stains and soil on textiles and hard surfaces. The compounds are substituted with a specific cyclic ammonium group adjacent to the acyl group. Further aspects of the invention are compositions or formulations comprising such compounds.Type: ApplicationFiled: December 8, 2011Publication date: October 3, 2013Applicants: HENKEL AG & CO. KGAA, BASF SEInventors: Hauke Rohwer, Barbara Wagner, Frederique Wendeborn, Katherina Misteli
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Patent number: 8524646Abstract: A multi-compartment pouch comprising a first compartment and a second compartment, wherein, the first compartment comprises a solid composition, wherein the solid composition comprises; an oxygen bleach source; a bleach activator; a polycarboxylate polymer; and the second compartment comprises a liquid composition, wherein the liquid composition comprises; a low molecular weight solvent.Type: GrantFiled: May 26, 2011Date of Patent: September 3, 2013Assignee: The Procter & Gamble CompanyInventors: Carlo Ricci, Luca Sarcinelli
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Patent number: 8486881Abstract: The invention relates to co-granules containing a granule core and a sheath or coating layer surrounding the granule core. Said co-granules are characterized in that the granule core contains a) at least one bleach activator, a2) between 0 and 20 wt. % of the total quantity of at least one bleach catalyst contained in the co-granule, and c) at least one binding agent, and the sheath or coating layer contains d) between 80 and 100 wt. % of the total quantity of the at least one bleach catalyst contained in the co-granule, and e) at least one coating agent. The co-granules are advantageously suitable for producing cleaning products and detergents and especially products for washing crockery in a machine.Type: GrantFiled: April 1, 2010Date of Patent: July 16, 2013Assignee: Clariant Finance (BVI) LimitedInventors: Georg Borchers, Gerd Reinhardt, Andreas Schottstedt
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Patent number: 8431519Abstract: A process for preparation of co-granules including one or more bleach activators and one or more bleach agent compounds is described. The bleach component is mixed and coated with a binder selected from the group of fatty acids, fatty acid polyol esters, polyglycols and fatty alcohol oxalkylates. One or more bleach activators is added to this mixture followed by granulation or agglomeration in a mixer, resulting in a bleach co-granule composition including the bleach activator and peroxide components.Type: GrantFiled: April 29, 2010Date of Patent: April 30, 2013Assignee: OCI Chemical Corp.Inventors: Robert Scarella, Georg Borchers
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Publication number: 20120302487Abstract: A composite includes: one or more core units comprising a bleach activating agent; and an alkali soluble polymer coating on the surface of said one or more core units.Type: ApplicationFiled: October 28, 2010Publication date: November 29, 2012Applicant: REVOLYMER LIMITEDInventors: Stephen Armstrong, Terence Cosgrove, John Jeffrey Gerrard, Melaine Jane Hughes, David Alan Pears
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Publication number: 20120083437Abstract: A solid detergent composition is disclosed including a alcohol ethoxylate surfactant and a sole hardening agent consisting of polyethylene glycol 4000 wherein the composition does not include any free water or alkali metal hydroxides and may include a chlorine-free bleaching agent and activator. The detergent composition may further include citrate, a water conditioner, a sequestrant. The solid detergent composition may be formed into an amorphous solid. Compositions of the invention may further include a crystal modifier consisting of sodium xylene sulfonate. The detergent composition may further optionally include an optical brightener, defoamer, enzyme, antiredeposition agent, buffering agent, stabilizer or combinations thereof.Type: ApplicationFiled: September 30, 2010Publication date: April 5, 2012Applicant: ECOLAB USA INC.Inventors: Barbara G. Choczaj, Steven E. Lentsch
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Patent number: 8093198Abstract: The production of bleaching agent granulates, wherein a particulate peroxide compound and a water soluble polymer which can be ionotropically cross-linked are granulated into a primary granulate using a liquid binding agent containing water, and the primary granulate is brought into contact with a cross-linking agent for the water soluble polymer which can be ionotropically cross-linked. A particle so obtained can be worked into liquid detergents and cleaning agents containing water and remain stable.Type: GrantFiled: July 8, 2009Date of Patent: January 10, 2012Assignee: Henkel AG & Co. KGaAInventors: Matthias Sunder, Peter Schmiedel, Heinz-Juergen Voelkel
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Patent number: 7906472Abstract: The present invention provides a bleach activator which is at least one macrocyclic manganese complex selected from the group consisting of [MnIII(rac-14-decane)X2]Y, [MnIII(mes-14-decane)X2]Y.H2O and [MnIII(mes-14-decane)X2]Y represented by Formulas 1-3, as well as a preparation method thereof. Also, the invention provides a bleaching composition and bleaching detergent composition comprising the bleach activator. The bleach activator comprising the manganese complex is used in a granulated form. wherein X is at least one selected from chlorine (—Cl) and acetate (—OOCCH3), and Y is an anion selected from Cl?, Br?, F?, NO3?, ClO4?, OH?, NCS?, N3?, and PF6?.Type: GrantFiled: November 3, 2006Date of Patent: March 15, 2011Assignee: AE Kyung Industrial Co., Ltd.Inventors: Han Woong Park, Sang Yun Lee, In Sik Cho, Won Jong Kim, In Sub Baik
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Publication number: 20110009304Abstract: Compositions that contain a co-particle, a bleach catalyst, and optionally, a detergent adjunct material are disclosed. The disclosed co-particles contain a binder, a hydrogen peroxide source, such as sodium percarbonate or the like, and a bleach activator such as TAED. Methods of making and using these compositions are also disclosed.Type: ApplicationFiled: July 8, 2010Publication date: January 13, 2011Inventors: Nigel Patrick Somerville-Roberts, Alan Thomas Brooker, David James Parmley, Victor Stuart Reid, Colin Ure, Kim Keltie, Carly Pickering
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Patent number: 7708905Abstract: A method for preparing an ester bleach activator compound is disclosed. The method includes (A) preparing fatty acid monoester; (B) making chloroformate by reacting the fatty acid monoester with at least one selected from the group consisting of phosgene, diphosgene and triphosgene in the presence of base; and (C) reacting the chloroformate with hydroxybenzene, its derivatives, or its salts in solvent. According to the method, the ester bleach activator compound can be made in a simple and economic way.Type: GrantFiled: May 25, 2004Date of Patent: May 4, 2010Assignee: LG Household & Health Care Ltd.Inventors: Chang-Woo Lee, Wan-Goo Cho, Jin-Young Hyun, Kyung-Hee Oh
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Patent number: 7709437Abstract: A process for preparation of co-granules including one or more bleach activators and one or more bleach agent compounds is described. The bleach component is mixed and coated with a binder selected from the group of fatty acids, fatty acid polyol esters, polyglycols and fatty alcohol oxalkylates. One or more bleach activators is added to this mixture followed by granulation or agglomeration in a mixer, resulting in a bleach co-granule composition including the bleach activator and peroxide components.Type: GrantFiled: April 27, 2006Date of Patent: May 4, 2010Assignee: OCI Chemical Corp.Inventors: Robert Scarella, Georg Borchers
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Patent number: 7541324Abstract: What are claimed are synergistically active bleach activator mixtures consisting of a) a hydroxybenzoic acid derivative of the formula 1 in which R is C8-C11-alkyl, and b) tetraacetylethylenediamine and/or 1,5-diacetyl-2,4-dioxo-1,3,5-hexahydrotriazine.Type: GrantFiled: September 3, 2005Date of Patent: June 2, 2009Assignee: Clariant Produkte (Deutschland) GmbHInventors: Gerd Reinhardt, Georg Borchers
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Patent number: 7425527Abstract: The present invention relates to organic activators having the following general formula: Wherein R1 is a substituted or unsubstituted alkyl or aryl moiety comprising at least five carbons, R2 is a substituted or unsubstituted alkyl moiety comprising less than five carbons, R3 is a suitable bridging moiety, R4 is a charged moiety, N is nitrogen, each G is, independently, an oxygen containing moiety and Z, when present, is a charge balancing counter ion. The present invention also relates to cleaning compositions comprising said organic activators, and processes for making and using the aforementioned organic activators and cleaning compositions.Type: GrantFiled: April 28, 2005Date of Patent: September 16, 2008Assignee: The Procter & Gamble CompanyInventors: Gregory Scot Miracle, Robert Richard Dykstra, George Douglas Hiler, II
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Patent number: 7323437Abstract: The invention provides a process for producing a bleaching activator composition, which includes removing a solvent and/or water from a mixture of a bleaching activator and a surfactant dispersed in a non-aqueous solvent, a bleaching activator composition produced by the process and a bleaching activator granule obtained by further granulating the bleaching activator composition.Type: GrantFiled: December 22, 2004Date of Patent: January 29, 2008Assignee: Kao CorporationInventors: Shigeaki Fujinami, Hiroshi Noro, Masakazu Furukawa, Hiroyuki Yamashita
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Publication number: 20070173428Abstract: The present invention relates to a composition comprising: (i) a pre-formed peroxyacid or salt thereof in molecularly encapsulated form; and (ii) a bleach catalyst that is capable of accepting an oxygen atom from a peroxyacid and transferring the oxygen atom to an oxidizeable substrate.Type: ApplicationFiled: January 23, 2007Publication date: July 26, 2007Inventors: Doris Appleby, Andrew Paul Nelson, Alan Thomas Brooker
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Patent number: 7179779Abstract: A novel cationic bleach activator having an enhanced hydrolytic stability is provided. The novel cationic bleach activator also leads to a reduction in strength loss of cotton fibers compared to conventional hot peroxide bleaching, and achieves this reduction in strength loss without a loss of whiteness. Bleaching compositions and detergent compositions comprising the novel cationic bleach activator also are provided. A method of bleaching cellulosic fibers, such as cotton fibers, and a method for removing a stain or discoloration from an article are further provided.Type: GrantFiled: January 6, 2006Date of Patent: February 20, 2007Assignee: North Carolina State UniversityInventors: Peter J. Hauser, David Hinks, Jung Jin Lee, Sang-Hoon Lim
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Patent number: 7094745Abstract: The use of compounds of the formula (1) M(L)nXm??(1) in which M is a metal atom from the group consisting of Mn, Fe, Co, Ni, Mo and W, L is a ligand from the group consisting of the cyclic carboxamides (lactams), X is chloride, bromide, nitrate, perchlorate, citrate, hexafluorophosphate or anions of organic acids having C1–C22 carbon atoms and n is a number from 2 to 4 and m is a number from 0 to 4, as catalysts for peroxygen compounds, in particular in detergents, bleaches and cleaning agents, is claimed.Type: GrantFiled: September 30, 2004Date of Patent: August 22, 2006Assignee: Clariant GmbHInventors: Ekaterina Jonas, Gerd Reinhardt, Daniel Kewitz, Aylin Karadag
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Patent number: 6833343Abstract: A bleaching detergent formulation comprising the components of: (A) particles comprising 0.Type: GrantFiled: March 29, 2002Date of Patent: December 21, 2004Assignee: Kao CorporationInventors: Muneo Aoyagi, Hiroshi Danjo, Masakazu Furukawa, Kazuyoshi Ozaki
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Patent number: 6797196Abstract: A bleaching formulation comprising (a) a peroxy bleaching agent selected from hydrogen peroxide and a peroxide or an organic peracid capable of generating hydrogen peroxide in an aqueous solution, (b) an anionic bleaching catalyst containing a metal, and (c) a cationic compound, and a bleaching method comprising using the bleaching formulation wherein pretreatment with component (c) precedes treatment with components (a) and (b), or components (a), (b), and (c) are used simultaneously.Type: GrantFiled: January 2, 2002Date of Patent: September 28, 2004Assignee: Kao CorporationInventor: Hiroshi Danjo
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Patent number: 6740126Abstract: A method for the application of durable press to textiles via the pre-treatment bleaching of a non-finished textile component followed by the application of a durable press finish is provided. The method comprises the steps of treating a non-finished textile component in an aqueous bleaching solution of hydrogen peroxide and a hydrophobic activator or hydrophobic peracid for a time sufficient to bleach the textile component followed by application of the durable press finish preferably via immersion in an aqueous solution of formaldehyde, a cross lining catalyst and a silicone elastomer forming material or a solution of alkylene urea and a crosslinking catalyst. Preferred bleach activators include the alkanoyloxybenzene sulfonates and in particular noanoyloxybenzene sulfonate. The method allows significant savings in both energy and time due to the lower bleaching temperatures possible via the present method as opposed to conventional peroxide processing.Type: GrantFiled: February 15, 2001Date of Patent: May 25, 2004Assignee: Strike Investments, LLCInventors: Jiping Wang, Robert William Johnston
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Publication number: 20040033916Abstract: The invention relates to the preparations used for disinfecting and applied in national economy, medicine, laboratories of all types. The preparation contains a chelating metal complex compound with a monodentate ligand, which exhibits affinity to hydrogen ion, an ionogenic surfactant and a solvent. The preparation displays antiseptic properties and effectiveness of the content. The preparation affects gram positive and gram negative bacteria, viruses, spores. The preparation can be applied in a broad temperature interval.Type: ApplicationFiled: June 28, 2002Publication date: February 19, 2004Inventors: Vladimir Semenovich Kuzmin, Oleg Ivanovich Lukashov, Viktor Stanislavovich Polyakov, Valeriy Vasilievich Ermilov
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Publication number: 20040014625Abstract: The present invention provides a ligand, L, and transition metal complex thereof having the formula (I): 1Type: ApplicationFiled: June 4, 2003Publication date: January 22, 2004Applicant: Unilever Home & Personal Care USA, Division of Conopco, Inc.Inventors: Peter Comba, Jean Hypolites Koek, Joachim Lienke, Michael Merz, Lydmyla Tsymbal
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Publication number: 20030232732Abstract: The present invention provides a bleaching composition comprising a [3.3.1] bicyclo compound carrying at least one tertiary amine group the bleaching composition substantially devoid of a peroxygen source.Type: ApplicationFiled: June 4, 2003Publication date: December 18, 2003Applicant: Unilever Home & Personal Care USA, Division of Conopco, Inc.Inventors: Ronald Hage, Joachim Lienke, Patricia Petersen
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Publication number: 20030216275Abstract: Compositions comprising at least one N&agr;,N&ohgr;-dialkyl aminomethylenephosphonic acid having formula (I) or N-oxide thereof having formula (II) or formula (III) wherein R is an alkylene group having from 2 to 6 carbon atoms; R1 and R2 are each independently an alkyl group having from 1 to 6, preferably 1 to 4, carbon atoms, a hydroxyalkyl group having alkyl of from 1 to 6, preferably 1 to 4, carbon atoms, or carboxyalkyl group having alkyl of from 1 to 6, preferably from 1 to 4, carbon atoms; M is, independently in each occurrence, selected from the group consisting of H, NH4, amine, alkali metal, alkaline earth metal, or a linear or branched alkyl group having from 1 to 4 carbon atoms; and n is an integer from 1 to 6; are surprisingly found to have superior performance in peroxide bleaching of cellulosic materials, corrosion and scale inhibition or scale removal in water treatment and oil field applications, detergent applications, and chelation of metal ions.Type: ApplicationFiled: October 17, 2002Publication date: November 20, 2003Inventors: Druce K Crump, David A Wilson
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Patent number: 6645927Abstract: A process for producing coated bleach activator granules in which bleach activator base granules are coated with a coating substance and are simultaneously and/or subsequently thermally conditioned.Type: GrantFiled: July 21, 2000Date of Patent: November 11, 2003Assignee: Clariant GmbHInventors: Johannes Himmrich, Georg Borchers
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Patent number: 6617300Abstract: A granular bleach activator extrudate that has a size and shape that is within a relatively narrow distribution range. The bleach activator exhibits improved solubility, and reduced product separation when incorporated into a granular detergent composition. Also provided are granular detergent compositions comprising a detersive surfactant and the bleach activator extrudates. Methods for forming the extruded bleach activator particles are also provided.Type: GrantFiled: August 30, 2001Date of Patent: September 9, 2003Assignee: Procter & Gamble CompanyInventors: Scott William Capeci, Michael Steven Gibson, Victoria Ann Majerczak
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Patent number: 6613726Abstract: The present invention provides a stable composition in the form of an emulsion comprising a diacyl peroxide and a surfactant system.Type: GrantFiled: May 7, 2001Date of Patent: September 2, 2003Inventors: Leo Gagliardi, Stefano Scialla, Vincentius Henricus Adrianus Maria Van Spaendonk, Silvia Zanazzi
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Patent number: 6610752Abstract: Defoamer granules containing support materials and silicones for solid laundry detergent, dishwashing detergent and cleaning compositions, obtainable by applying silicones in the form of aqueous emulsions to an added intermediate product of support materials and simultaneously drying and granulating the products in a fluidized bed, with the proviso that at least 85% by weight of the particles have a mean diameter below 1.5 mm, are described.Type: GrantFiled: October 10, 2000Date of Patent: August 26, 2003Assignee: Cognis Deutschland GmbHInventors: Karl Heinz Schmid, Michael Neuss, Detlef Stanislowski, Karin Koren, Andrea Borntraeger
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Patent number: 6583095Abstract: The present invention relates to an improved process for synthesizing organic compounds for use as bleach activators.Type: GrantFiled: May 7, 2001Date of Patent: June 24, 2003Assignee: Procter & Gamble CompanyInventors: Jeffrey Scott Dupont, Robert Richard Dykstra
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Patent number: 6566318Abstract: Laundry or cleaning composition comprising: (a) an effective amount, preferably from about 0.0001% to about 99.9%, more typically from about 0.1% to about 25%, of a bleach activator and/or organic percarboxylic acid; (b) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (c) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts in combination with bleach activators and/or organic percarboxylic acids.Type: GrantFiled: March 7, 2002Date of Patent: May 20, 2003Inventors: Christopher Mark Perkins, Regine Labeque, Barbara Kay Williams, James Pyott Johnston, David Johnathan Kitko, James Charles Theophile Roger Burckett-St. Laurent, Michael Eugene Burns
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Patent number: 6559113Abstract: Detergent compositions comprise a water-soluble builder, an enzyme and a polymeric dye transfer inhibiting agent, wherein a means is provided for delaying the release of the enzyme relative to the release of the water-soluble builder to the wash solution. The time to achieve a concentration that is 50% of the ultimate concentration of the water-soluble builder is less than 60 seconds, and the time to achieve a concentration that is 50% of the ultimate concentration of the enzyme is more than 90 seconds.Type: GrantFiled: October 15, 1996Date of Patent: May 6, 2003Assignee: The Procter & Gamble CompanyInventors: Janice Jeffrey, John Scott Park, Barry Stoddart
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Patent number: 6548467Abstract: The invention relates to compositions comprising a peroxyacid bleach precursor, a peroxide source, at least about 15% by weight of a carbonate source, which may comprise the hydrogen peroxide source or part thereof, and at least about 7% by weight of an organic carboxylic acid whereby a 1% solution of the composition in demineralised water provides a pH from 8.8 to 9.9. The compositions are useful to provide sanitization of fabrics, in particular to reduce the activity of certain bacteria groups.Type: GrantFiled: February 28, 2002Date of Patent: April 15, 2003Assignee: The Procter & Gamble CompanyInventors: Ashley Sutherland Baker, Kristien Greta Govers, Tiffany Alice Hensman, Peter Gerard Gray
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Patent number: 6514925Abstract: N,N diacyl O-substituted imide bleach activators and compositions employing them are provided. The activators have the general formula: wherein X is selected from O, NR16 and S; e is 0 or 1; f is 0 or 1; R16 is selected from H and C1-C4 linear or branched, saturated or unsaturated alkyl groups; and R1 is preferably phenyl or C7-C13 linear or branched chain, saturated or unsaturated alkyl; R2 is preferably C1-C10 branched or unbranched, saturated or unsaturated alkyl and R3 is preferably C1-C12 linear or branched chain, saturated or unsaturated alkyl. Bleach additive and bleaching compositions including the bleach activators and methods of cleaning fabrics are also provided.Type: GrantFiled: May 23, 2002Date of Patent: February 4, 2003Assignee: The Procter & Gamble CompanyInventors: Gregory Scot Miracle, Robert Richard Dykstra
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Patent number: 6509308Abstract: The present invention relates to a bleaching comprising a pre-formed peroxycarboxylic acid having solubility in an aqueous composition of from 50 ppm to 800 ppm. These compositions are suitable to deliver improved bleaching performance whilst also being safe to color and fabric. Furthermore the compositions herein are also chemically and physically stable upon prolonged periods of storage time.Type: GrantFiled: May 7, 2001Date of Patent: January 21, 2003Assignee: The Procter & Gamble CompanyInventors: Francesco De Buzzaccarini, Michael Eugene Burns, Pierre Antoine Dresco, Stefano Scialla
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Publication number: 20030008796Abstract: The invention relates to catalytically bleaching substrates, especially laundry fabrics, with a bleaching composition using either air or a peroxyl source.Type: ApplicationFiled: February 5, 2002Publication date: January 9, 2003Applicant: Unilever Home & Personal Care USA, Division of Conopco, Inc.Inventors: Riccardo Filippo Carina, Michel Gilbert Jose Delroisse, Ronald Hage, David Tetard
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Publication number: 20020198128Abstract: Laundry or cleaning composition comprising: (a) an effective amount, preferably from about 0.0001% to about 99.9%, more typically from about 0.1% to about 25%, of a bleach activator and/or organic percarboxylic acid; (b) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (c) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts in combination with bleach activators and/or organic percarboxylic acids.Type: ApplicationFiled: March 7, 2002Publication date: December 26, 2002Applicant: The Procter & Gamble CompanyInventors: Christopher Mark Perkins, Regine Labeque, Barbara Kay Williams, James Pyott Johnston, David Johnathan Kitko, James Charles Theophile Roger Burckett-St Laurent, Michael Eugene Burns
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Publication number: 20020160925Abstract: The invention relates to catalytically bleaching substrates, especially laundry fabrics, with a transition metal catalyst that bleaches tea type stains in the presence of atmospheric oxygen.Type: ApplicationFiled: February 11, 2002Publication date: October 31, 2002Applicant: Unilever Home & Personal Care USA, Division of Conopco, Inc.Inventors: Ronald Hage, Maria Johanna Lagerwaard-Lier, Joachim Lienke, Cynthia Margaret Ligeon, Patricia Petersen
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Patent number: 6455485Abstract: There is provided a liquid nonaqueous detergent composition comprising an alcohol alkoxylate nonionic surfactant and a bleach precursor having a Krafft point of at least 10° C., said surfactant and said precursor being present in a molar ratio of nonionic surfactant to bleach precursor of at least 2:1.Type: GrantFiled: December 22, 1998Date of Patent: September 24, 2002Assignee: The Procter & Gamble CompanyInventors: Steven Jozef Louis Coosemans, Axel Meyer, Jean-Pol Boutique, James Pyott Johnston
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Publication number: 20020117649Abstract: The use of cyclic sugar ketones of the formula 1Type: ApplicationFiled: November 16, 2001Publication date: August 29, 2002Applicant: Clariant GmbHInventors: Gerd Reinhardt, Nicole Reichardt
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Patent number: 6440922Abstract: A detergent composition comprises a zeolite builder having a particle size, expressed as a d50 value, of less than 1.0 micrometers, an amylase enzyme, and an alkoxylated nonionic surfactant having a hydrophilic lipophilic balance value of less than 9.5 selected from the group consisting of alkoxylated adducts of fatty alcohols containing an average of less than 5 alkylene oxide groups per molecule. The detergent composition has been found to reduce white residue formation on fabrics washed with detergent containing small particle size zeolite.Type: GrantFiled: July 14, 1997Date of Patent: August 27, 2002Assignee: The Procter & Gamble CompanyInventors: Carolyn Jayne Garnett, Jonathan Richard Clare, Johan Juliaan Serafin Wauben
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Patent number: 6440921Abstract: The present invention relates to a bleaching composition comprising a pre-formed peroxycarboxylic acid and a surfactant system comprising at least two surfactants. These compositions are stable to deliver improved bleaching performance while also being safe to color and fabric. Furthermore, the compositions herein are also chemically and physically stable upon prolonged periods of storage time.Type: GrantFiled: May 7, 2001Date of Patent: August 27, 2002Assignee: The Procter & Gamble CompanyInventors: Gloria Di Capua, Pierre Antoine Dresco, Stefano Scialla
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Patent number: 6432900Abstract: The invention relates to ligands or complexes useful as catalysts for catalytically bleaching substrates with atmospheric oxygen, and as catalysts in the of treatment of textiles such as laundry fabrics whereby bleaching by atmospheric oxygen is catalysed after the treatment. The ligand is of the general formula: wherein R1, R2, and R3 independently represent a group selected from hydrogen, hydroxyl, halogen, —NH—C(NH)NH2, —R and —OR, wherein R=alkyl, alkenyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl or a carbonyl derivative group, R being optionally substituted by one or more functional groups, and provided that two of R1, R2 and R3 are coordinating groups and one of R1, R2 and R3 is a non-coordinating group; Q independently represents a group selected from C2-3-alkylene optionally substituted by H, benzyl or C1-8-alkyl; and Q1, Q2 and Q3 independently represent specified linking groups.Type: GrantFiled: August 29, 2000Date of Patent: August 13, 2002Assignee: Unilever Home & Personal Care USA, Division of Conopco, Inc.Inventors: Adrianus Cornelis Appel, Ronald Hage, David Tetard, Robin Stefan Twisker