With Nitrogen Or Oxygen Containing Bleach Precursor Or Activator (e.g., Ester, Acid Anhydride, Etc.) Patents (Class 510/312)
  • Patent number: 11879112
    Abstract: The present invention is in the field of fabric cleaning compositions; in particular powder detergent compositions having foaming and cleaning characteristics in the main wash, yet significant foam reduction during rinse. Accordingly the present inventors have investigated ways of improving the defoaming ingredient such that the defoaming ingredient has improving foam-subsiding effects in the rinse stage. However they found that incorporating a monoester of glycerol of unsaturated fatty acids in a cleaning composition has adverse effects on the perfume impact of the cleaning composition. The inventors have found that the disadvantages of the prior art can be overcome, if a monoester of glycerol and unsaturated fatty acid is sorbed by a porous carrier material having a specific pore size and pH ranges. The inventive defoaming ingredient did not masked and/or altered the perfume delivery of the detergent composition.
    Type: Grant
    Filed: July 16, 2018
    Date of Patent: January 23, 2024
    Assignee: Conopco, Inc.
    Inventors: Koushik Acharya, Sujitkumar Suresh Hibare, Panchanan Bhunia
  • Patent number: 11090247
    Abstract: The present invention provides a composition for protecting the skin from heavy metals and formaldehyde, comprising at least one selected from the group consisting of trientine or trientine derivative of Formula (1), cyclen or cyclen derivative of Formula (2), cyclam or cyclam derivative of Formula (3), and a salt thereof.
    Type: Grant
    Filed: June 2, 2017
    Date of Patent: August 17, 2021
    Assignee: FNG RESEARCH CO., LTD.
    Inventors: Young Sam Goo, Ki Nam Son
  • Patent number: 10876076
    Abstract: A method for use of substituted dihydroxyterephthalic acid amides in detergents and cleaning agents, for improving detergent or cleaning performance with respect to bleachable stains.
    Type: Grant
    Filed: February 7, 2019
    Date of Patent: December 29, 2020
    Inventors: Christian Kropf, Rainer Jeschke, Sascha Schaefer, Christian Umbreit, Alexander Schulz, Michael Strotz
  • Patent number: 9410110
    Abstract: The invention meets the needs above by providing a surfactant system, mixture or blend that can be used as a part of a soaking composition. The surfactant system is capable of forming emulsions with, and thus removing, oily and greasy stains. In a preferred embodiment the surfactant compositions of the invention can remove non-trans fat and fatty acid stains. The invention involves foaming soaking compositions that have some or part of the anionic surfactant present in the same replaced with an extended chain anionic surfactant.
    Type: Grant
    Filed: April 15, 2015
    Date of Patent: August 9, 2016
    Assignee: Ecolab USA Inc.
    Inventors: Victor Fuk-Pong Man, Yvonne Marie Killeen, Derrick Richard Anderson
  • Patent number: 9023783
    Abstract: The present application relates to encapsulated, solid, water soluble benefit agents and products comprising such encapsulates, as well as processes for making and using such encapsulates and products comprising such encapsulates. In one aspect, the present application relates to a melamine formaldehyde and/or urea formaldehyde encapsulation process that offers as solution to the dissolution of solid, water soluble benefit agents during the process's emulsification step.
    Type: Grant
    Filed: August 5, 2014
    Date of Patent: May 5, 2015
    Assignee: The Procter & Gamble Company
    Inventors: Johan Smets, Susana Fernandez Prieto, Sandra Jacqueline Guinebretiere
  • Patent number: 8993504
    Abstract: The present invention provides an oxidation catalyst for bleaching containing a component (a) which is an anion caused from a chelating agent having less than or equal to coordination position 5 and/or the chelating agent, and a component (b) which is a copper and/or manganese compound; and a binder compound (c); a hydrogen peroxide-based compound (d) which dissolves in water and generates hydrogen peroxide, the bleaching composition containing a granulated product or a molded product in which at least the component (b) and the component (c) are granulated or molded together. According to the invention, an oxidation catalyst that promotes the oxidation effect of hydrogen peroxide-based compounds with a trace amount of the composition, and has excellent effects of suppressing the decomposition of hydrogen peroxide-based compounds and suppressing coloration of the catalyst itself, and a bleaching composition containing the oxidation catalyst can be utilized.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: March 31, 2015
    Assignee: LION Corporation
    Inventors: Takayasu Kubozono, Tomonari Suekuni, Yosuke Kono, Yukiko Iwasa, Hideyuki Kaneda, Yukihiro Dannoue, Hiroaki Hara, Yasushi Hirata
  • Patent number: 8883704
    Abstract: The invention relates to co-granules containing a) at least one bleach activator, b) at least one metal-containing bleach catalyst, and c) at least 5 wt. % of at least one organic acid. The co-granules are easy to produce, have a high stability in storage and are advantageously suitable for producing cleaning products and detergents and especially products for cleaning crockery in a machine.
    Type: Grant
    Filed: April 1, 2010
    Date of Patent: November 11, 2014
    Assignee: Clariant International Ltd.
    Inventors: Georg Borchers, Gerd Reinhardt, Andreas Schottstedt
  • Patent number: 8883703
    Abstract: The present invention relates to encapsulated phthalocyanine particles, to a process for the preparation thereof, compositions comprising such particles and washing agent formulations. The encapsulated phthalocyanine particles comprise a) at least one water-soluble phthalocyanine compound, and b) gelatine having a bloom strength of 2 to 80 as encapsulating material.
    Type: Grant
    Filed: April 25, 2013
    Date of Patent: November 11, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Patrick Christopher Stenger, Gregory Scot Miracle, Andrew Phillip Moon, Michael McDonnell, Stefan Bruhns, Gunther Schlingloff, Ulrich Menge, Frank Bachmann, Andreas Lindenmaier
  • Patent number: 8822402
    Abstract: The present application relates to encapsulated, solid, water soluble benefit agents and products comprising such encapsulates, as well as processes for making and using such encapsulates and products comprising such encapsulates. In one aspect, the present application relates to a melamine formaldehyde and/or urea formaldehyde encapsulation process that offers as solution to the dissolution of solid, water soluble benefit agents during the process's emulsification step.
    Type: Grant
    Filed: December 16, 2013
    Date of Patent: September 2, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Johan Smets, Susana Fernandez Prieto, Sandra Jacqueline Guinebretiere
  • Patent number: 8809251
    Abstract: The present invention relates to compositions having granules of phthalocyanine compounds, to a process for the preparation thereof, and to the use thereof in washing agent and additive formulations. The composition has: a) At least one water-soluble phthalocyanine compound; b) At least one cross-linked polyvinylpyrrolidone component; c) At least one hydrophilic binding agent; and, optionally, d) Further additives suitable for the preparation of solid agglomerates; and may be liquid, solid, paste-like or gel-like.
    Type: Grant
    Filed: April 3, 2013
    Date of Patent: August 19, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Patrick Christopher Stenger, Andrew Philip Moon, Gregory Scot Miracle, Ullrich Menge, Gunther Schlingloff, Frank Bachmann, Andreas Lindenmaier
  • Patent number: 8633148
    Abstract: The present application relates to encapsulated, solid, water soluble benefit agents and products comprising such encapsulates, as well as processes for making and using such encapsulates and products comprising such encapsulates. In one aspect, the present application relates to a melamine formaldehyde and/or urea formaldehyde encapsulation process that offers as solution to the dissolution of solid, water soluble benefit agents during the process's emulsification step.
    Type: Grant
    Filed: April 5, 2011
    Date of Patent: January 21, 2014
    Assignee: The procter & Gamble Company
    Inventors: Johan Smets, Susana Fernandez Prieto, Sandra Jacqueline Guinebretiere
  • Patent number: 8486881
    Abstract: The invention relates to co-granules containing a granule core and a sheath or coating layer surrounding the granule core. Said co-granules are characterized in that the granule core contains a) at least one bleach activator, a2) between 0 and 20 wt. % of the total quantity of at least one bleach catalyst contained in the co-granule, and c) at least one binding agent, and the sheath or coating layer contains d) between 80 and 100 wt. % of the total quantity of the at least one bleach catalyst contained in the co-granule, and e) at least one coating agent. The co-granules are advantageously suitable for producing cleaning products and detergents and especially products for washing crockery in a machine.
    Type: Grant
    Filed: April 1, 2010
    Date of Patent: July 16, 2013
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Georg Borchers, Gerd Reinhardt, Andreas Schottstedt
  • Patent number: 8431519
    Abstract: A process for preparation of co-granules including one or more bleach activators and one or more bleach agent compounds is described. The bleach component is mixed and coated with a binder selected from the group of fatty acids, fatty acid polyol esters, polyglycols and fatty alcohol oxalkylates. One or more bleach activators is added to this mixture followed by granulation or agglomeration in a mixer, resulting in a bleach co-granule composition including the bleach activator and peroxide components.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: April 30, 2013
    Assignee: OCI Chemical Corp.
    Inventors: Robert Scarella, Georg Borchers
  • Publication number: 20120302487
    Abstract: A composite includes: one or more core units comprising a bleach activating agent; and an alkali soluble polymer coating on the surface of said one or more core units.
    Type: Application
    Filed: October 28, 2010
    Publication date: November 29, 2012
    Applicant: REVOLYMER LIMITED
    Inventors: Stephen Armstrong, Terence Cosgrove, John Jeffrey Gerrard, Melaine Jane Hughes, David Alan Pears
  • Patent number: 8080511
    Abstract: The present invention relates to formulations comprising water-soluble granulates of phthalocyanine compounds, to a process for the preparation thereof, and to the use thereof in washing agent and washing agent additive formulations.
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: December 20, 2011
    Assignee: BASF SE
    Inventors: Pierre Dreyer, Elke Haiss, Laure Iltis, Petr Kvita, Ullrich Menge
  • Publication number: 20110009304
    Abstract: Compositions that contain a co-particle, a bleach catalyst, and optionally, a detergent adjunct material are disclosed. The disclosed co-particles contain a binder, a hydrogen peroxide source, such as sodium percarbonate or the like, and a bleach activator such as TAED. Methods of making and using these compositions are also disclosed.
    Type: Application
    Filed: July 8, 2010
    Publication date: January 13, 2011
    Inventors: Nigel Patrick Somerville-Roberts, Alan Thomas Brooker, David James Parmley, Victor Stuart Reid, Colin Ure, Kim Keltie, Carly Pickering
  • Publication number: 20100267602
    Abstract: The present invention provides an oxidation catalyst for bleaching containing a component (a) which is an anion caused from a chelating agent having less than or equal to coordination position 5 and/or the chelating agent, and a component (b) which is a copper and/or manganese compound; and a binder compound (c); a hydrogen peroxide-based compound (d) which dissolves in water and generates hydrogen peroxide, the bleaching composition containing a granulated product or a molded product in which at least the component (b) and the component (c) are granulated or molded together. According to the invention, an oxidation catalyst that promotes the oxidation effect of hydrogen peroxide-based compounds with a trace amount of the composition, and has excellent effects of suppressing the decomposition of hydrogen peroxide-based compounds and suppressing coloration of the catalyst itself, and a bleaching composition containing the oxidation catalyst can be utilized.
    Type: Application
    Filed: December 18, 2008
    Publication date: October 21, 2010
    Applicant: LION CORPORATION
    Inventors: Takayasu Kubozono, Tomonari Suekuni, Yosuke Kono, Yukiko Iwasa, Hideyuki Kaneda, Yukihiro Dannoue, Hiroaki Hara, Yasushi Hirata
  • Patent number: 7708905
    Abstract: A method for preparing an ester bleach activator compound is disclosed. The method includes (A) preparing fatty acid monoester; (B) making chloroformate by reacting the fatty acid monoester with at least one selected from the group consisting of phosgene, diphosgene and triphosgene in the presence of base; and (C) reacting the chloroformate with hydroxybenzene, its derivatives, or its salts in solvent. According to the method, the ester bleach activator compound can be made in a simple and economic way.
    Type: Grant
    Filed: May 25, 2004
    Date of Patent: May 4, 2010
    Assignee: LG Household & Health Care Ltd.
    Inventors: Chang-Woo Lee, Wan-Goo Cho, Jin-Young Hyun, Kyung-Hee Oh
  • Patent number: 7709437
    Abstract: A process for preparation of co-granules including one or more bleach activators and one or more bleach agent compounds is described. The bleach component is mixed and coated with a binder selected from the group of fatty acids, fatty acid polyol esters, polyglycols and fatty alcohol oxalkylates. One or more bleach activators is added to this mixture followed by granulation or agglomeration in a mixer, resulting in a bleach co-granule composition including the bleach activator and peroxide components.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: May 4, 2010
    Assignee: OCI Chemical Corp.
    Inventors: Robert Scarella, Georg Borchers
  • Patent number: 7678753
    Abstract: A liquid detergent composition containing (a) hydrogen peroxide or a compound for forming hydrogen peroxide in water, (b) a compound selected from boric acid, borax, a boric acid salt in an amount of from 0.05 to 1% by mass as a boron atom, (c) a compound having one or more sites, the site having one hydroxyl group at each of both sides of adjacent carbon atoms, in an amount of from 3 to 35% by mass, (d) a surfactant in an amount of from 4 to 45% by mass, and (e) water, wherein the molar ratio of the component (c)/the component (b) is from 1.5 to 2.7, and wherein the detergent composition has a pH at 20° C. of from 4.6 to 7.0.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: March 16, 2010
    Assignee: Kao Corporation
    Inventors: Masataka Maki, Hitoshi Ishizuka, Nobuyoshi Yamaguchi, Yuuichirou Tase
  • Publication number: 20100062963
    Abstract: Disclosed is the detergent composition containing (a) an inorganic peroxide; (b) a specific phenylester-type bleaching activator; and (1d) a polyglyceryl alkyl ether having an alkyl group of 4 to 20 carbon atoms in an amount of more than 5% by mass to 35% by mass, or the detergent composition containing (a) an inorganic peroxide; (b) a specific phenylester-type bleaching activator; (2d) a polyglyceryl alkyl ether having an alkyl group of 4 to 20 carbon atoms; and, (e) a fatty acid or a salt thereof.
    Type: Application
    Filed: December 27, 2007
    Publication date: March 11, 2010
    Applicant: Kao Corporation
    Inventors: Takanori Kotera, Nobuyoshi Yamaguchi
  • Publication number: 20100005596
    Abstract: A detergent granule comprising at least one composite material, wherein said at least one composite material comprises: a C10-C13 sodium linear alkylaryl sulfonate and/or an alpha-sulfonated fatty acid ester such as methyl ester sulfonate; an alkaline agent, from about 0.05% to about 1.2%, by weight of said granular detergent admix, of an brightener; and from about 10% to about 35%, by weight of said granular detergent admix, of a bleaching system comprising: a source of peroxide; and a bleach activator.
    Type: Application
    Filed: July 10, 2009
    Publication date: January 14, 2010
    Inventors: Annette Kay Bryan, Julie Ann Cassedy, Eva Schnelderman, Linda Carol McWilliams, Les Charles Zorb, Manasvini Egan, Jodi Elizabeth Koehler, Donna Jean Maag, Paul R. Mort, III
  • Patent number: 7534757
    Abstract: The present invention provides a bleaching composition comprising a [3.3.1] bicycle compound of formula (I) carrying at least one C8-C22-alkyl chain, together with a peroxygen source.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: May 19, 2009
    Assignee: Conopco Inc.
    Inventors: Ronald Hage, Joachim Lienke, Patricia Veerman-Petersen
  • Patent number: 7524804
    Abstract: A bleach composition containing (a) a peroxide generating hydrogen peroxide by being dissolved in water, (b) a water-insoluble or poorly water-soluble textile powder selected from powder cellulose, silk powder, wool powder, nylon powder, and polyurethane powder, and (c) (c-1) a bleaching activating catalyst and/or (c-2) a bleaching activator. A bleaching detergent composition containing (a) a peroxide generating hydrogen peroxide by being dissolved in water, (b) a water-insoluble or poorly water-soluble textile powder selected from powder cellulose, silk powder, wool powder, nylon powder, and polyurethane powder, and (c) (c-1) a bleaching activating catalyst or (c-1) a bleaching activating catalyst and (c-2) a bleaching activator, and (d) a surfactant.
    Type: Grant
    Filed: May 7, 2003
    Date of Patent: April 28, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Hideyuki Kaneda, Yoshitaka Miyamae, Satoru Nagata
  • Patent number: 7517847
    Abstract: Bleaching product in the form of a coated substrate comprising a water-soluble film and a coating comprising a bleaching agent.
    Type: Grant
    Filed: May 11, 2006
    Date of Patent: April 14, 2009
    Assignee: The Procter & Gamble Company
    Inventors: Vincenzo Catalfamo, Frank William Denome, Dennis Allen Beckholt, Yousef Georges Aouad, James Michael Archbold
  • Patent number: 7501389
    Abstract: The present invention provides a bleaching composition comprising a [3.3.1] bicycle compound of formula (I) carrying at least one C8-C22-alkyl chain, the bleaching composition being substantially devoid of a peroxygen source.
    Type: Grant
    Filed: October 18, 2004
    Date of Patent: March 10, 2009
    Assignee: Conopco Inc.
    Inventors: Ronald Hage, Joachim Lienke, Patricia Veerman-Petersen
  • Patent number: 7435714
    Abstract: The invention relates to liquid detergent and cleaning agent compositions of high storage stability. They comprise a liquid medium with a water content of up to 15 wt. % and particulate coating bleaching agents suspended therein. The bleaching agent has a dissolving time of at least 5 minutes and a coating of at least two layers: The innermost layer comprises one or more hydrate-forming inorganic salts as the main component(s), and an outer layer, which makes up 0.2 to 5 wt. % of the coated bleaching agent, comprises alkali metal silicate(s) with a modulus of SiO2 to M2O (M=alkali metal) of greater than 2.5 as the main component(s). Preferred compositions comprise sodium percarbonate with an innermost layer of substantially sodium sulfate and an outermost layer of substantially 0.5 to 1.5 wt. % sodium silicate (modulus 3.2 to 4.2) as the bleaching agent.
    Type: Grant
    Filed: December 11, 2003
    Date of Patent: October 14, 2008
    Assignee: Evonik Degussa GmbH
    Inventors: Ulrike Kottke, Silke Stoschek, Klaus Zimmermann, Ralph Overdick, Michael Fender, Harald Jakob
  • Patent number: 7323437
    Abstract: The invention provides a process for producing a bleaching activator composition, which includes removing a solvent and/or water from a mixture of a bleaching activator and a surfactant dispersed in a non-aqueous solvent, a bleaching activator composition produced by the process and a bleaching activator granule obtained by further granulating the bleaching activator composition.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: January 29, 2008
    Assignee: Kao Corporation
    Inventors: Shigeaki Fujinami, Hiroshi Noro, Masakazu Furukawa, Hiroyuki Yamashita
  • Patent number: 7125832
    Abstract: Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.
    Type: Grant
    Filed: May 14, 2003
    Date of Patent: October 24, 2006
    Assignee: Procter & Gambel Company
    Inventors: Daryle Hadley Busch, Simon Robert Collinson, Timothy Jay Hubin, Christopher Mark Perkins, Regine Labeque, Barbara Kay Williams, James Pyott Johnston, David Johnathan Kitko, James Charles Theophile Roger Burckett-St. Laurent
  • Patent number: 6995125
    Abstract: Compositions in a water-soluble pouch containing at least two compartments, each compartment containing a different component of the composition, where a first compartment contains a first component which contains a liquid matrix and a source of peracid.
    Type: Grant
    Filed: November 29, 2000
    Date of Patent: February 7, 2006
    Assignee: The Procter & Gamble Company
    Inventors: Bruno Matthieu Dasque, Nicola Ethel Davidson, Francesco de Buzzaccarini, James Charles Theophile Roger Burckett-St Laurent, Valerio Del Duca, Frank William DeNome
  • Patent number: 6930054
    Abstract: Disclosed herein are slurry compositions for use in CMP(chemical mechanical polishing) process of metal wiring in manufacturing semiconductor devices, comprising a peroxide, an inorganic acid, a propylenediaminetetraacetate(PDTA)-metal complex, a carboxylic acid, a metal oxide powder, and de-ionized water, wherein the PDTA-metal complex plays a major role in improving overall polishing performance and reproducibility thereof by preventing abraded tungsten oxide from readhesion onto the polished surface, as well as in improving the dispersion stability of the slurry composition.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: August 16, 2005
    Assignees: Cheil Industries, Inc., Samsung Electronics Co., Ltd.
    Inventors: Jae Seok Lee, Won Joong Do, Hyun Soo Roh, Kil Sung Lee, Jong Won Lee, Bo Un Yoon, Sang Rok Hah, Joon Sang Park, Chang Ki Hong
  • Patent number: 6914041
    Abstract: The present invention relates to laundry detergent compositions which provide enhanced hydrophilic soil cleaning benefits comprising a zwitterionic polyamine, a surfactant system comprising a mid-chain branched surfactant, and carrier and other adjunct ingredients.
    Type: Grant
    Filed: October 6, 2003
    Date of Patent: July 5, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Nathan Price, Eugene Paul Gosselink
  • Patent number: 6906024
    Abstract: The present invention relates to fabric care compositions comprising one or more amino acid sequence(s) comprising a Cellulose Binding Domain for providing fabric care. In a further embodiment, the present invention relates to fabric care compositions wherein the amino acid sequence comprising one or more cellulose binding domains is linked to a softening protein.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: June 14, 2005
    Assignee: Procter & Gamble Company
    Inventors: AndréCesar Baeck, Johan Smets, Stanton Lane Boyer
  • Patent number: 6903059
    Abstract: The present invention relates to detergent compositions comprising a polyamine with defined end capping units and a mid-chain branched surfactant and also optionally containing a bleach agent, aluminosilicate, silicate, and/or detersive enzyme.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: June 7, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Nathan Price, Eugene Paul Gosselink, Randall Scott Deinhammer
  • Patent number: 6846791
    Abstract: The present invention relates to hydrophobically modified polyamines and laundry detergent compositions comprising such polyamines and a surfactant system. In addition to traditional cleaning benefits, such compositions provide enhanced greasy soil removal capabilities.
    Type: Grant
    Filed: November 7, 2000
    Date of Patent: January 25, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey Scott Dupont, Eugene Paul Gosselink, Kenneth Nathan Price, Robert Henry Rohrbaugh
  • Publication number: 20040266641
    Abstract: The present invention relates to support-fixed bleaching catalyst(s)suitable or the catalysis of peroxide compounds, characterized in that the support-fixed bleaching catalyst(s) is/are covalently bonded to a support by means of at least one organic ligand of the bleaching catalyst. The bleaching catalyst(s) form(s) a complex with at least on transition metal. The invention further relates to support-fixed bleaching catalysts for the catalysis of peroxide compounds, where at least one ligand, covalently bonded to a support, is a transition-metal-free ligand, which chelates with transition metal, derived from another source, preferably from the bleaching composition and/or added water and thus forms the complex with a transition metal.
    Type: Application
    Filed: June 21, 2004
    Publication date: December 30, 2004
    Inventors: Pavel Gentschev, Steve Doring, Jacques Breyer, Antonio Machin
  • Publication number: 20040248755
    Abstract: The present invention relates to methods for producing bleach-activator-containing granules from a water-containing bleach activator preparation form by granulation and simultaneous drying in a fluidized-bed and subsequent consolidation of the primary granules by treatment with an aqueous polymer and/or phosphonate solution, in a fluidized bed.
    Type: Application
    Filed: June 4, 2004
    Publication date: December 9, 2004
    Inventors: Georg Assmann, Olaf Joachim Blochwitz, Horst-Dieter Speckmann, Jorg Poethkow, Birgit Middelhauve, Gerhard Blasey
  • Publication number: 20040248754
    Abstract: The present invention relates to methods for coating bleach activator-containing granules by treatment with an acidic aqueous consolidating solution, comprising polymeric polycarboxylate and/or alkali metal phosphonate as coating and consolidation active ingredient, with simultaneous drying in a fluidized-bed apparatus.
    Type: Application
    Filed: June 4, 2004
    Publication date: December 9, 2004
    Inventors: Georg Assmann, Olaf Joachim Blochwitz, Horst-Dieter Speckmann, Jorg Poethkow, Birgit Middelhauve, Gerhard Blasey
  • Patent number: 6812198
    Abstract: The present invention relates to hydrophobically modified polyamines and laundry detergent compositions which comprise said polyamines, said compositions comprising: A) from about 0.01%, preferably from about 0.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: November 2, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey Scott Dupont, Eugene Paul Gosselink, Kenneth Nathan Price, Robert Henry Rohrbaugh
  • Patent number: 6797196
    Abstract: A bleaching formulation comprising (a) a peroxy bleaching agent selected from hydrogen peroxide and a peroxide or an organic peracid capable of generating hydrogen peroxide in an aqueous solution, (b) an anionic bleaching catalyst containing a metal, and (c) a cationic compound, and a bleaching method comprising using the bleaching formulation wherein pretreatment with component (c) precedes treatment with components (a) and (b), or components (a), (b), and (c) are used simultaneously.
    Type: Grant
    Filed: January 2, 2002
    Date of Patent: September 28, 2004
    Assignee: Kao Corporation
    Inventor: Hiroshi Danjo
  • Publication number: 20040142842
    Abstract: Water soluble granules or particles of saldimine-type manganese complexes that are suitable as catalysts in reactions with peroxy compounds are described. The granules are used especially in washing agents. They are distinguished by retarded disssolution of and improved action of the manganese complexes.
    Type: Application
    Filed: March 11, 2004
    Publication date: July 22, 2004
    Inventors: Menno Hazenkamp, Bryan David Grey, Kishor Kumar Mistry, Frank Bachmann, Josef Dannacher, Kenneth Charles Symes, Petr Kvita, Susanne Maier
  • Publication number: 20040142843
    Abstract: Use of metal complex compounds of formula (1): [LnMemXp]zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —OR13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N+R14R15R16 wherein
    Type: Application
    Filed: October 28, 2003
    Publication date: July 22, 2004
    Inventors: Gunther Schlingloff, Torsten Wieprecht, Frank Bachmann, Josef Dannacher, Marie-Josee Dubs, Menno Hazenkamp, Grit Hansler(-Richter), Brigitte Schmidt, Albert Schneider, Peter Weingartner
  • Patent number: 6764613
    Abstract: Substantially solid compositions are provided having therein a compound with the structure of Formula I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) —CR2R3C≡N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is a value in the range of 0 to 10, and wherein Y is monovalen
    Type: Grant
    Filed: May 3, 2001
    Date of Patent: July 20, 2004
    Assignee: Mid-America Commercialization Corporation
    Inventors: Ulrich Annen, James E. Deline, Kevin A. Klotter, Michael Müller, Klaus Mundinger, Sarah A. Perkins, Martin J. Phillippi, Martin Scholtissek, Michael Schönherr, William L. Smith, Alfred G. Zielske
  • Publication number: 20040138081
    Abstract: The invention concerns a heat stabilizer of organic peroxides characterized in that it contains at least a nitroxyl radical in its molecule. The invention also concerns a storage-stable and heat-stable organic peroxide composition, the method for preparing the same and uses thereof for modifying polymers.
    Type: Application
    Filed: November 17, 2003
    Publication date: July 15, 2004
    Inventors: Sandra Grimaldi, Olivier Guerret, Jean-Luc Couturier, Fabien Debaud
  • Patent number: 6746996
    Abstract: Transition metal complexes used as bleach catalysts of the formula (1) M(L)nXm  (1) where M is a metal atom from the group Mn, Fe, Co, Ni, Mo, W, L is a ligand of the formula R1R2C═N—O(H)z R1 is C1-C22-alkyl, C2-C22-alkenyl or C5-C24-aryl, R2 is H, C1-C22-alkyl, C2-C22-alkenyl, C5-C24-aryl or where z=0 or 1, X is a neutral or anion ligand from the group consisting of pyridines, imidazolines, methylimidazoles, picolines, lutidines, chloride, bromide, nitrate, perchlorate, citrate, hexafluorophosphate or anions of organic acids having C1-C22 carbon atoms, n is a number from 2 to 4 and m is a number from 0 to 4.
    Type: Grant
    Filed: January 17, 2002
    Date of Patent: June 8, 2004
    Assignee: Clariant GmbH
    Inventors: Gerd Reinhardt, Michael Seebach, Nicole Reichardt, Laszlo I. Simandi, Tatiana M. Simandi, Gabor Besenyei
  • Patent number: 6740126
    Abstract: A method for the application of durable press to textiles via the pre-treatment bleaching of a non-finished textile component followed by the application of a durable press finish is provided. The method comprises the steps of treating a non-finished textile component in an aqueous bleaching solution of hydrogen peroxide and a hydrophobic activator or hydrophobic peracid for a time sufficient to bleach the textile component followed by application of the durable press finish preferably via immersion in an aqueous solution of formaldehyde, a cross lining catalyst and a silicone elastomer forming material or a solution of alkylene urea and a crosslinking catalyst. Preferred bleach activators include the alkanoyloxybenzene sulfonates and in particular noanoyloxybenzene sulfonate. The method allows significant savings in both energy and time due to the lower bleaching temperatures possible via the present method as opposed to conventional peroxide processing.
    Type: Grant
    Filed: February 15, 2001
    Date of Patent: May 25, 2004
    Assignee: Strike Investments, LLC
    Inventors: Jiping Wang, Robert William Johnston
  • Publication number: 20040097391
    Abstract: A new chromotropic compound, compositions containing such a compound and methods of using such compound, such as in a test method for identifying the presence of free radicals, are disclosed.
    Type: Application
    Filed: March 11, 2003
    Publication date: May 20, 2004
    Applicant: The Procter & Gamble Company
    Inventors: Giuseppina Chiaradonna, Francesca Cicogna, Giovanni Ingrosso, Emanuela Franchi, Calogero Pinzino, Valerio Del Duca, Stefano Scialla
  • Patent number: 6727218
    Abstract: The present invention relates to a cleaning composition comprising an immiscible liquid system having at least one liquid-liquid interface with an interfacial tension greater than 5 mN/m. The less polar solvent in the system has a carbon chain length of at least 4, or is a silicone with more than 3 SiO units. The composition furthermore comprises from 0.001-20% by weight of a benefit agent such as a fluorescer, a dye transfer inhibitor, a fabric softening agent or an anti redeposition agent. The compositions provide for an improved delivery and efficacy of the benefit agents in e.g. a fabric cleaning process.
    Type: Grant
    Filed: October 10, 2002
    Date of Patent: April 27, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Vijaya Milind Bargaje, Kavitha Dhandapani, Glyn Roberts
  • Publication number: 20040067863
    Abstract: The invention set out to improve the oxidizing and bleaching effect of inorganic peroxygen compounds in dishwashing, more particularly machine dishwashing, in terms of their storage stability. This was essentially achieved by using particulate compounds corresponding to formula R1R2R3N+CH2CN X−, in which R1, R2, and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, in addition to which the groups R2 and R3 may even be part of a heterocycle including the N atom and optionally other hetero atoms, and X is a charge-equalizing anion. Dishwashing detergents, more particularly machine dishwashing detergents, contain about 1% by weight to 10% by weight of this bleach-boosting agent.
    Type: Application
    Filed: June 5, 2003
    Publication date: April 8, 2004
    Inventors: Horst-Dieter Speckmann, Bernd Larson, Joerg Poethkow, Peter Schmiedel, Lars Zuechner, Manfred Schreiber, Georg Borchers, Oliver Mogck, Frank Weinelt
  • Publication number: 20040058847
    Abstract: The present invention relates to liquid washing, cleaning, disinfecting bleaching compositions comprising amphiphilic copolymers which include structural units derived from
    Type: Application
    Filed: September 19, 2003
    Publication date: March 25, 2004
    Applicant: Clariant GmbH
    Inventors: Roman Morschhauser, Matthias Loffler, Christoph Kayser, Johannes Himmrich, Aranka Tardi, Sebastiano Lo Vasco, Carsten Muller