Liquid, Paste, Foam, Or Gel (e.g., Slurry, Aerosol Composition Or Package, Etc.) Patents (Class 510/370)
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Patent number: 6294514Abstract: Mono-long chain amine oxide surfactants can be prepared containing active levels of greater than about 30%, by weight of amine, and with low nitrite and nitrosamine levels and low levels of residual hydrogen peroxide when oxidized under controlled temperature conditions in the presence of bicarbonate material present at levels less than about 2.5%, by weight of amine, and without the presence of phase-modifying solvents.Type: GrantFiled: November 24, 1998Date of Patent: September 25, 2001Assignee: The Procter & Gamble CompanyInventor: Stanley James Welling
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Patent number: 6277153Abstract: A chemical cleaning system for a multi-tank or a single-tank laundry washing machine, having at least two separate components for aqueousdissolution or dilution to respective use concentrations, a first component comprising a proteolytic enzyme, and a second component comprising an imidoperoxycarboxylic acid, particularly phthaloylaminoperoxycaprbic acid (PAP), wherein the first component is introduced into a prewash zone or step, and the second component is introduced into a main wash zone or step. When using this system, it was found that effective cleaning could be obtained even at relatively low main wash temperatures of 45-55° C. As a result, much less energy was needed and a considerable reduction of textile damage was observed as compared with cleaning systems of the prior art.Type: GrantFiled: July 13, 2000Date of Patent: August 21, 2001Assignee: Diversey Lever, Inc.Inventors: Eddy Petrus Van Kouwen, Frederik Jan Schepers, Rudolf Comelis Verheul, Wilhelm Ewald Smit
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Publication number: 20010003737Abstract: A fabric bleaching composition comprising a peroxy compound and a specified manganese compound is disclosed, as well as a process for bleaching and/or cleaning a fabric by contacting it with said fabric bleaching composition.Type: ApplicationFiled: October 13, 1998Publication date: June 14, 2001Inventors: DIETER REINEHR, GEORGES METZGER
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Patent number: 6221827Abstract: The invention relates to new bleaching and disinfecting compositions containing—based on the composition (a) 1 to 8% by weight of alkali metal hypochlorites, (b) 0.1 to 2% by weight of alkali metal hydroxides, (c) 0.1 to 2% by weight of betaines, (d) 0.1 to 1% by weight of hydrotropes and (e) 0.05 to 1% by weight of sequestrants, with the proviso that the quantities add up to 100% by weight with water and optionally other auxiliaries and additives. The clear compositions are viscoelastic and show inter alia high stability in storage in addition to excellent washing and bleaching performance.Type: GrantFiled: December 17, 1999Date of Patent: April 24, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Mercedes Mendoza Cruz, Elisabet de Jorge
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Publication number: 20010000251Abstract: A system for forming and releasing an aqueous peracid solution is disclosed. The system includes a container and a peracid forming composition provided within the container. The container is permeable to the passage of water and aqueous peracid solution. The peracid forming composition includes a peracid precursor and a peroxygen source. Preferably, the peracid forming composition includes a chemical heater capable of releasing heat upon hydration. When placed in water, water enters the container and interacts with the peracid forming composition provided within the container. The water combines with the peracid precursor and peroxygen source to provide an aqueous peracid composition. The presence of a chemical heater within the container provides for the generation of heat within the container which enhances the rate of peracid formation. The peracid solution leaves the container and forms an effective sanitizing amount of sanitizer.Type: ApplicationFiled: December 13, 2000Publication date: April 12, 2001Applicant: Ecolab, Inc.Inventors: G. Jason Wei, David D. McSherry
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Patent number: 6207201Abstract: A first embodiment of the present invention is directed to an aqueous disinfectant solution comprising an alkali metal or alkaline earth metal hypochlorite, an amount of base sufficient to raise the pH of the solution to at least 12, and water. A second embodiment of the present invention is directed to a method for sterilizing medical and dental instruments and hard surfaces which comprises contacting the medical or dental instruments or hard surfaces with an aqueous disinfecting solution comprising an alkali metal or alkaline earth metal hypochlorite, an amount of a base sufficient to raise the pH of the solution to at least 12, and water, for a time sufficient to disinfect the medical or dental instruments or hard surface.Type: GrantFiled: May 23, 1997Date of Patent: March 27, 2001Assignee: Amuchina International, Inc.Inventor: Giuseppe Piacenza
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Patent number: 6204236Abstract: New enzyme granulates are described which contain an organic disulfide compound (R—S—S—R), particularly they contain the free amino acid cystine, optionally mixed with the amino acid cysteine. The new enzyme granulates are for us in detergent and cleanser compositions, particularly in dishwasher compositions, and they have properties. For example, insofar as protecting objects made of silver against tarnishing, for example, dishes, cutlery, and other objects to be cleaned.Type: GrantFiled: March 31, 1999Date of Patent: March 20, 2001Assignee: Genencor International, Inc.Inventors: Hubert A. Herrmann, Rolf Spannagl, Günther Richter
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Patent number: 6143707Abstract: Automatic dishwashing detergent compositions comprising blooming perfume composition containing blooming perfume ingredients selected from the group consisting of: ingredients having a boiling point of less than about 260.degree. C. and a ClogP of at least about 3, and wherein said perfume composition comprises at least 5 different blooming perfume ingredients, bleaching agent, builder and optionally, bleach catalysts. Preferred automatic dishwashing compositions further comprise amylase and/or protease enzymes.Type: GrantFiled: February 18, 1998Date of Patent: November 7, 2000Assignee: The Procter & Gamble CompanyInventors: Toan Trinh, Dennis Ray Bacon, Alex Haejoon Chung, Patricia Ann Blondin
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Patent number: 6133219Abstract: A reductive bleaching composition containing: (a) from 80 to 90% by weight of a glucose component; (b) from 1 to 5% by weight of a nonionic surfactant; and (c) from 5 to 20% by weight of a buffer salt selected from the group consisting of an inorganic buffer salt, an organic buffer salt, and mixtures thereof, all weights being based on the total weight of the composition.Type: GrantFiled: November 4, 1998Date of Patent: October 17, 2000Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Terese Copete Vidal, Emili Brau Balague
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Patent number: 6127330Abstract: A process for bleaching and/or providing limescale removal at a surface, by applying to that surface an aqueous composition having a pH of 2 or less and comprises a mixture of (a) an aqueous composition comprising hydrogen peroxide or an organic peracid having a pH of greater than 2 but less than 7 and (b) an acidic composition wherein components (a) and (b) are mixed not more than two hours before being applied to the surface requiring bleaching and/or limescale removal. The organic acid of component (a) has the formula XC (O)OOH where X is hydrogen or CH.sub.3 (CH.sub.2).sub.n and n is 0 to 8. The acid composition (b) comprises hydrochloric, sulphamic, tartaric, phosphoric, oxalic, citric, salicylic or ascorbic acids.Type: GrantFiled: March 17, 1998Date of Patent: October 3, 2000Assignee: Reckitt & Colman Products LimitedInventor: Heather Elizabeth Bonett
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Patent number: 6121225Abstract: A stabilized aqueous enzyme composition comprising water, from about 0.1% to about 75% by weight of a detergent surfactant selected from the group consisting of anionic surfactants or anionic surfactants and one or more non-anionic detergent actives, from about 0.001% to about 10% by weight proteolytic enzyme, and an effective amount of an enzyme stabilizer having the formula:X--O--(C.sub.n H.sub.2n O).sub.a --H [I]wherein "X" is an organic radical having from 14 to 22 carbon atoms, "a" is an integer from 10 to 26, and "n" is an integer from 2 to 4, and provided that "X" has a hydrophobicity similar to a linear alkyl group having from 14 to 22 carbon atoms.Type: GrantFiled: December 21, 1998Date of Patent: September 19, 2000Assignee: CONDEA Vista CompanyInventors: Larry N. Britton, Geoffrey L. Russell, Allen M. Nielsen
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Patent number: 6113654Abstract: A cleaning composition for carpets, rugs, and the like is provided. The dispensable cleaner includes: a) an effective amount of an organic solvent having a Hansen solubility parameter of less than about 10; b) an effective amount of an emulsifying or dispersing agent; c) an effective amount of a source of hydrogen peroxide; and d) the balance being water. Emulsifying or dispersing agents that are surfactants having an HLB of less than about 10 are particularly suited for removing oily soil from absorbent or adsorbent surfaces. Optional components include sequestering agents, fragrances, builders and soil retardants.Type: GrantFiled: September 12, 1996Date of Patent: September 5, 2000Inventor: David Peterson
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Patent number: 6096098Abstract: The present invention discloses asymmetrical bleach activators for use in both solid and liquid additive, bleaching and detergent compositions. The asymmetrical bleach activators display the unique ability to form both hydrophilic and hydrophobic bleaching agents in aqueous liquors such as bleaching solutions. Thus, fabrics, hard surfaces or dishes having hydrophobic stains such as dingy and or hydrophilic stains such as beverages can be effectively cleaned or bleached using the bleach activators of the present invention.Type: GrantFiled: April 15, 1999Date of Patent: August 1, 2000Assignee: The Procter & Gamble CompanyInventors: Gregory Scot Miracle, Robert Richard Dykstra, Kevin Lee Kott, Stefano Scialla
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Patent number: 6046150Abstract: The invention provides liquid cleaning or bleaching compositions containing compounds having the structure of Formula I ##STR1## wherein A is a saturated ring formed by five atoms in addition to the N.sub.1 atom, the five saturated ring atoms being four carbon atoms and a heteroatom, the substituent R.sub.1 bound to the N.sub.1 atom of the Formula I structure including either (a) a C.sub.1-24 alkyl or alkoxylated alkyl where the alkoxy is C.sub.2-4, (b) a C.sub.4-24 cycloalkyl, (c) a C.sub.7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C.sub.2-4, or (e) --CR.sub.2 R.sub.3 CN where R.sub.2 and R.sub.3 are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, the R.sub.2 and R.sub.3 substituents are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.Type: GrantFiled: April 30, 1999Date of Patent: April 4, 2000Assignee: The Clorox CompanyInventors: Clement K. Choy, James E. Deline, Lafayette D. Foland, Aram Garabedian, Jr., Kevin A. Klotter, Michael J. Petrin, Martin J. Phillippi, William L. Smith
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Patent number: 6042744Abstract: The invention provides a bleaching composition of pH 8-14 which comprises an oxygen transfer agent and hypochlorite or a source thereof and a method for bleaching a stained substrate which comprises the step of treating the substrate with a bleaching composition of pH 8-14 which bleaching composition comprises an oxygen transfer agent and hypochlorite or a source thereof. Particularly preferred oxygen transfer agents are imine quaternary ammonium salts such as N-methyl-3,4-dihydroisoquinolinium salts. Where these salts are used, suitable counter-ions include halides, sulphate, methosulphate, sulphonate, p-toluene sulphonate and phosphate. Oxygen transfer agents which comprise a quaternary nitrogen atom are preferred. In the alternative, the oxygen transfer agent can be a sulphonimine.Type: GrantFiled: April 13, 1998Date of Patent: March 28, 2000Assignee: Lever Brothers Company, division of Conopco, Inc.Inventors: Jayne Elisabeth Nation, Katherine Mary Thompson, David William Thornthwaite
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Patent number: 6036789Abstract: Dilute aqueous compositions for removing soap scum consisting essentially of sodium carbonate, hypochlorite bleach, alkali metal hydroxide and a surfactant system consisting either of sodium 2-ethylhexyl sulfate and myristyldimethylamine oxide or of sodium 2-ethylhexyl sulfate alone.Type: GrantFiled: February 2, 1999Date of Patent: March 14, 2000Assignee: Reckitt & Colman Inc.Inventor: A. Thomas Weibel
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Patent number: 6037318Abstract: An improved process for the manufacture of alkaline bleaching compositions, especially liquid and/or gel compositions of high solubility and low abrasiveness, useful to the consumer, especially as products for hard surface cleaning, bleaching or disinfectancy. The products are made by a three-stage process and comprise particular chlorine and bromine bleach sources and particular aminofunctional materials such as low-impurity sulfamate.Type: GrantFiled: November 13, 1998Date of Patent: March 14, 2000Assignee: The Procter & Gamble CompanyInventors: Henry Cheng Na, Michael Charles Frazee, James Charles Theophile Roger Burckett St. Laurent, Kyle David Jones, Marco Petri
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Patent number: 6022840Abstract: Dilute aqueous compositions for removing soap scum consisting essentially of sodium carbonate, hypochlorite bleach, alkali metal hydroxide and a surfactant system consisting of sodium 2-ethylhexyl sulfate and a C.sub.8 -C.sub.10 -alkyldimethylamine oxide.Type: GrantFiled: February 2, 1999Date of Patent: February 8, 2000Assignee: Reckitt & Colman Inc.Inventor: A. Thomas Weibel
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Patent number: 6015782Abstract: Process for manufacturing bleaching compositions comprising halogen bleach, a source of bromine and an organic or inorganic derived --NH.sub.2 compound whereby improved bleaching performance is obtained and compositions obtainable by said process.Type: GrantFiled: June 5, 1998Date of Patent: January 18, 2000Assignee: The Procter & Gamble CompanyInventors: Marco Petri, Henry Cheng Na
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Patent number: 5998344Abstract: Disclosed for cleaning hard surfaces is a detergent gel containing:(a) a detergent composition without thickeners having(i) a first surfactant, wherein the first surfactant is a non-ionic glycolipid, and(ii) a second surfactant, wherein the second surfactant is a charged surfactant, wherein the ratio of the first surfactant and the second surfactant is 1:10-10:1;(b) water, wherein the detergent composition is mixed with a sufficient amount of water to induce a phase change from a liquid phase to a gel phase; and(c) one or more enzymes.Type: GrantFiled: January 8, 1998Date of Patent: December 7, 1999Assignee: Novo Nordisk A/SInventors: Poul N.o slashed.rgaard Christensen, Bo Kalum, Otto Andresen
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Patent number: 5985811Abstract: A cleaning solution and cleaning method are provided which: (1) make treatment at room temperature possible, and do not require heating, (2) use little chemicals and water, (3) do not require specialized apparatuses, and moreover, (4) do not require the use of specialized chemicals. The cleaning solution of the present invention comprises pure water containing 20 ppb-100 ppb of oxygen and 2 ppb or more of nitrogen. Furthermore, the cleaning solution may comprise electrolytically ionized water containing OH.sup.- and containing 20 ppb-100 ppb of oxygen. In the cleaning method of the present invention, the cleaning of a material to be cleaned is conducted in a cleaning solution comprising pure water containing 20 ppb-100 ppb of oxygen and 2 ppb-15 ppm of nitrogen, while applying ultrasound having a frequency of 30 kHz or more.Type: GrantFiled: January 8, 1997Date of Patent: November 16, 1999Assignees: Tadhiro Ohmi, Pre-Tech Co., Ltd., Kabushiki Kaisha Ultraclean Technology Research InstituteInventors: Toda Masayuki, Tadahiro Ohmi, Yasuyuki Harada
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Patent number: 5981455Abstract: A composition comprising short chain alkoxylated alcohols as nonionic surfactants. The short chain alkoxylated alcohols provide superior cleaning compared to their homologues with longer chains as well as other benefits including, low foaming and skin mildness, and the ability to formulate concentrated compositions.Type: GrantFiled: February 9, 1996Date of Patent: November 9, 1999Assignee: The Procter & Gamble CompanyInventors: Michel Jean Carrie, William Ajalon Cilley, Peter Rosalia Joannes Geboes, Massimo Morini, Louise Gail Scott, Eddy Vos, Ricky Ah-Man Woo
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Patent number: 5981457Abstract: The present invention relates to a concentrated liquid gel warewash detergent composition which contains about 5% to about 30% by weight of an alkali polyphosphate, about 8% to about 50% by weight of a source of alkalinity, about 0% to about 5% by weight of a surface active agent, about 0.1% to about 2% by weight of a hydrophilic crosslinkled polycarboxylate thickening agent, about 0.1% to about 2% by weight of a hydrogen bonding agent for the polycarboxylate, and about 0 to about 15% of a polyacrylate, the balance being water. The composition may also contain about 0% to about 3% by weight of a chlorine bleach. The composition is predissolved and can be accurately metered into warewash machines to clean and destain tablewares and dishwares.Type: GrantFiled: January 31, 1997Date of Patent: November 9, 1999Assignee: Kay Chemical CompanyInventor: Fahim U. Ahmed
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Patent number: 5968202Abstract: A method of cleaning textile fabrics comprising the steps of (i) dispensing a detergent foam from an aerosol container, (ii) dissolving the foam in water to form an aqueous solution; and either subsequently or simultaneously, (iii) agitating the textile fabrics in the aqueous solution.Type: GrantFiled: January 13, 1998Date of Patent: October 19, 1999Assignee: The Procter & Gamble CompanyInventors: Jan Hendrik Maria Verbiest, Jean Wevers
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Patent number: 5945391Abstract: A vehicle and method for storing ozone is disclosed. A vehicle made of a water miscible, organic compound of a glycol-containing chemical compound, a tertiary alcohol or a mixture thereof that is capable of receiving and containing ozone is disclosed. The method involves producing ozone gas, introducing the ozone-containing gas into a mixing vessel that contains the aforementioned organic compound, agitating the organic compound in the presence of the ozone-containing gas, wherein the ozone-containing gas is at atmospheric pressure or at a pressure of up to about 150 psig., and releasing the pressure if pressures in excess of atmospheric are used.Type: GrantFiled: October 20, 1997Date of Patent: August 31, 1999Assignee: Quantum Technologies, Inc.Inventors: Robert E. Yant, Marilyn M. Hurst, David B. Galluch
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Patent number: 5942480Abstract: Disclosed herein is a synergistic cleaning and disinfecting composition for use in decontaminating biofilm-coated surfaces like fresh water lines providing water supply to dental instruments, these lines being susceptible to contamination by microorganisms and being susceptible to the formation of biofilm coatings on their inner walls, the composition comprising an effective amount of a detergent, an effective amount of a denaturing agent attacking the extracellular matrix formed between microorganisms and between microorganisms and the inner walls of these water lines and an effective amount of a bactericide for destroying the microorganisms.Type: GrantFiled: June 27, 1997Date of Patent: August 24, 1999Assignee: Universite de MontrealInventors: Andre Prevost, Jean Barbeau, Ludger Cote, Robert Charland, Esther Faucher
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Patent number: 5916865Abstract: Liquid bleaching agent suspension comprising essentiallya) a mixture of a C.sub.8 -C.sub.18 -fatty alcohol, oxyethylated with 1 to 5 units of ethylene oxide, and a C.sub.8 -C.sub.18 -fatty alcohol, oxyethylated with 6 to 25 units of ethylene oxide,b) a cyclic anhydride,c) an aqueous solution of hydrogen peroxide andd) water.Type: GrantFiled: August 29, 1997Date of Patent: June 29, 1999Assignee: Clariant GmbHInventors: Gerd Reinhardt, Vera Friderichs, Nicole Horneff
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Patent number: 5914069Abstract: Liquid aqueous bleaching compositions are disclosed which comprise hypochlorite and a specific complexing agent or mixtures thereof selected from the group consisting of polycarboxylic acid derivatives of pyridine or the salts thereof. The compositions have a pH from 11-14 and preferably further comprise a calcium/magnesium precipitation system. The complexing agent counteracts the adverse affect which certain metal ions have on fabric strength and fabric color when hypochlorite bleaches are used in the presence of said ions.Type: GrantFiled: January 17, 1997Date of Patent: June 22, 1999Assignee: The Procter & Gamble CompanyInventors: Francesco Agostini, Giuseppe Caire
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Patent number: 5905065Abstract: The present invention relates to compositions comprising from 0.01% to 10% by weight of the total composition of salicylic acid or derivatives thereof according to the following formula: ##STR1## wherein X is carbon, Y is one of the following groups --CHO, --OH, --(CH2)n--COOH, wherein n is an integer of from 0 to 20 and from 0.01% to 20% by weight of a compound selected from the group consisting of amine oxide surfactants according to the formula R1R2R3NO, wherein each of R1, R2 and R3 is independently a saturated substituted or unsubstituted, linear or branched alkyl group of from 1 to 30 carbon atoms, soil suspending polycarboxylate polymers, soil suspending polyamine polymers, hydroxy-pyridine N-oxides and derivatives thereof, chelating agents, and mixtures thereof. Said compositions are particularly suitable for the cleaning of carpets, resulting in improved particulate stains and/or greasy/oily stains removal performance.Type: GrantFiled: June 27, 1996Date of Patent: May 18, 1999Assignee: The Procter & Gamble CompanyInventors: Stefano Scialla, Floriana Raso
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Patent number: 5866524Abstract: The invention relates to a foam composition for cleaning textiles comprising detergent active components, including a surfactant system. The surfactant system consists of anionic surfactant and, optionally, nonionic surfactant, at a level of at least 18% by weight. Preferably both anionic and nonionic surfactants are present in the surfactant system of the foam. The invention also relates to a method of cleaning textiles using foamed compositions, and also to a packaged product for delivering the foamed compositions.Type: GrantFiled: September 27, 1996Date of Patent: February 2, 1999Assignee: Procter & Gamble CompanyInventor: Jean Wevers
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Patent number: 5851974Abstract: A light duty liquid detergent with desirable cleansing properties and mildness to the human skin comprising: two different sulfonate surfactants, an alkali metal or ammonium salt of a C.sub.8-18 ethoxylated alkyl ether sulfate anionic surfactant, an alkyl polyglucoside surfactant, an alkanol amide or amine oxide and an antibacterial system comprising trichlorohydroxydiphenyl ether, a C.sub.1 -C.sub.3 alkanol and an alkali metal halide, and water.Type: GrantFiled: October 28, 1997Date of Patent: December 22, 1998Assignee: Colgate Palmolive CompanyInventor: Sukhvinder Sandhu
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Patent number: 5849678Abstract: Basic cleaning compositions using toxicologically-acceptable ingredients for cleaning fruits and vegetables are provided. Liquid formulations comprising detergent surfactant, such as oleate, alcohol ethoxylates, etc., and neutralized phosphoric acid are sprayed onto apples, lettuce and the like to remove soil and unwanted deposits, especially wax. Articles for applying the compositions to produce by spraying are disclosed. Use of the compositions for disinfectancy/sanitization of produce and cleaning/disinfectancy/sanitization of non-food inantimate surfaces are disclosed.Type: GrantFiled: April 7, 1997Date of Patent: December 15, 1998Assignee: The Procter & Gamble CompanyInventors: Bruce Prentiss Murch, Brian Joseph Roselle, Kyle David Jones, Keith Homer Baker, Thomas Edward Ward, Toan Trinh
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Patent number: 5846921Abstract: Cleaning solutions for application to semiconductor substrates comprise hydrofluoric acid, hydrogen peroxide, isopropyl alcohol, and water. Methods of cleaning semiconductor substrates comprise contacting the semiconductor substrates having contaminants contained thereon with cleaning solutions comprising hydrofluoric acid, hydrogen peroxide, isopropyl alcohol, and water; contacting the semiconductor substrates with first baths of water to remove the cleaning solutions contained on the semiconductor substrates; contacting the semiconductor substrates with second baths containing water to remove the contaminants contained on the semiconductor substrates; and rotating the semiconductor substrates to remove water remaining thereon to clean the semiconductor substrates.Type: GrantFiled: February 27, 1997Date of Patent: December 8, 1998Assignee: Samsung Electronics Co., Ltd.Inventors: June-ing Gil, Seok-ho Yi, Sang-mun Chon, Ho-kyoon Chung
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Patent number: 5814596Abstract: The present invention provides a structured paste which is substantially free of LAS and which is suitable for processing into a high bulk density, high active granular detergent. Surfactant pastes of the present invention have a viscosity of at least 10 Pa.s (measured at 70.degree. C. and 25 sec.sup.-1) and comprise: from 30% to 90% by weight of anionic surfactant; from 0% to 50% by weight of nonionic surfactant; from 0.5% to 20% by weight of either a polymeric cationic material or a polar amino acid; and from 1% to 40% by weight of water.Type: GrantFiled: February 24, 1997Date of Patent: September 29, 1998Assignee: The Procter & Gamble CompanyInventors: Yousef Georges Aquad, Brian Joseph Pangrle, Johan Gerwijn L. Pluyter
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Patent number: 5801138Abstract: A liquid concentrate peroxide composition contains a combination of sequestrants which together are capable of universal sequestration of transition metal ions which would otherwise cause decomposition of the peroxide. The combination preferably includes a sequestrant capable of sequestering cobalt and a sequestrant capable of sequestering metal ions other than cobalt. A particularly preferred combination includes a poly(methylene phosphonic acid) and nitrogen-donor type sequestrants such as dipyridylamine or triazacyclononane.Type: GrantFiled: April 21, 1997Date of Patent: September 1, 1998Assignee: Warwick International Group LimitedInventors: Vincent Brian Croud, Stephen James Tompsett, Susan Jane Scarborough
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Patent number: 5770555Abstract: A process for preparing stable aqueous cleaning concentrate compositions containing high concentrations of alkali and polymers useful as scale-inhibiting cleaning additives is disclosed. Water-soluble polymer additives useful for preparing the stable cleaning concentrates are polymers of acrylic acid, and optionally maleic acid, and selected allyloxy monomers. The storage-stable cleaning concentrates are especially useful in providing cleaning formulations for automatic washing systems, such as bottle washing and clean-in-place operations.Type: GrantFiled: November 13, 1996Date of Patent: June 23, 1998Assignee: Rohm and Haas CompanyInventor: Barry Weinstein
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Patent number: 5767055Abstract: An apparatus for surface cleaning is provided in which a first liquid, which includes an oxidizing agent, and a second liquid, which includes a builder or a chelating agent, are initially maintained separately. The apparatus is constructed to facilitate delivery of these two liquids such that they are combined to form an admixture during delivery to a surface to be treated. Either or both of the first and second liquids include a pH-adjusting agent, which is present in an amount such that when the liquids are so delivered, the resulting admixture is maintained at a pH sufficient for cleaning efficacy and stability of the oxidizing agent. The present invention also provides a composition produced by a process of maintaining the two above-mentioned liquids separately and forming an admixture thereof during delivery to a surface to be treated.Type: GrantFiled: February 23, 1996Date of Patent: June 16, 1998Assignee: The Clorox CompanyInventors: Clement K. Choy, Michael H. Robbins
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Patent number: 5749923Abstract: A method for chlorine-free bleaching of denim textile material composed of warp yarn which is dyed with at least one of (a) indigo dye and at least one sulfur dye, and (b) at least one derivative of indigo dye and at least one sulfur dye, and weft yarn which is undyed and substantially white and which continues to be substantially white after bleaching to provide a denim textile material having a stylish gray cast.Type: GrantFiled: May 24, 1996Date of Patent: May 12, 1998Assignee: Degussa AktiengellschaftInventors: Vinzenz Olip, Norbert Steiner
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Patent number: 5731275Abstract: Disclosed herein is a synergistic cleaning and disinfecting composition for use in decontaminating biofilm-coated surfaces like fresh water lines providing water supply to dental instruments, these lines being susceptible to contamination by microorganisms and being susceptible to the formation of biofilm coatings on their inner walls, the composition comprising an effective amount of a detergent, an effective amount of a denaturing agent attacking the extracellular matrix formed between microorganisms and between microorganisms and the inner walls of these water lines and an effective amount of a bactericide for destroying the microorganisms.Type: GrantFiled: December 30, 1994Date of Patent: March 24, 1998Assignee: Universite de MontrealInventors: Andre Prevost, Jean Barbeau, Ludger Cote, Robert Charland, Esther Faucher
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Patent number: 5705467Abstract: Aqueous cleaning compositions and methods of use are disclosed with a thickening agent including an alkyl ether sulfate surfactant forming about 0.1 to about 10% by wt. of the composition, about 0.1-5.0% by wt. of a cothickening surfactant comprising an alkali metal fatty acid sulfate and/or an alkoxylated alkylphenol sulfate salt, a solvent selected from the class consisting of terpene derivatives including a functional group and tertiary alcohols forming about 0.01 to about 10% by wt. of the composition and an electrolyte component in an amount effective for enhancing thickening effects of the alkyl ether sulfate surfactant and solvent. The electrolyte component preferably includes an alkali metal hypochlorite, more preferably at least one additional multivalent electrolyte, and most preferably sodium carbonate. With the electrolyte component including a hypochlorite, additional electrolytes and the solvent are selected to be bleach stable, the solvent also preferably being a fragrance for the composition.Type: GrantFiled: November 3, 1995Date of Patent: January 6, 1998Inventor: Clement K. Choy
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Patent number: 5705468Abstract: A vehicle and method for storing ozone is disclosed. A vehicle made of a water miscible, organic compound of a glycol-containing chemical compound, a tertiary alcohol or a mixture thereof that is capable of receiving and containing ozone is disclosed. The method involves producing ozone gas, introducing the ozone-containing gas into a mixing vessel that contains the aforementioned organic compound, agitating the organic compound in the presence of the ozone-containing gas, wherein the ozone-containing gas is at atmospheric pressure or at a pressure of up to about 150 psig., and releasing the pressure if pressures in excess of atmospheric are used.Type: GrantFiled: November 18, 1996Date of Patent: January 6, 1998Assignee: Quantum Technologies, Inc.Inventors: Robert E. Yant, Marilyn M. Hurst, David B. Galluch
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Patent number: 5681805Abstract: A stable liquid peracid precursor composition for delivering a bleaching and cleaning material is provided in which the liquid peracid precursor composition combines a dispersion medium which comprises a stabilizing effective amount of a liquid matrix and an emulsifier, and a dispersed phase that comprises a peracid precursor. The bleaching and cleaning material comprises either a hydrophobic or hydrotropic generated mono- or diperoxyacid, or mixtures thereof.Type: GrantFiled: May 25, 1995Date of Patent: October 28, 1997Assignee: The Clorox CompanyInventors: David R. Scheuing, James D. McManus, Gregory Van Buskirk
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Patent number: 5624891Abstract: A thickened composition comprises:(a) an active cleaning component, present in a cleaning effective amount; and(b) a thickening system comprising an alkali metal salt of an N-alkyl-N-acyl amino acid and a mixture of myristyl/cetyl dimethyl amine oxides. In a preferred embodiment, the cleaning composition comprises an alkali metal hypochlorite and a strong base comprising an alkali metal hydroxide and an alkali metal silicate. The thickened compositions are useful as hard surface cleaners and particularly useful as drain opening compositions.Type: GrantFiled: January 29, 1996Date of Patent: April 29, 1997Assignee: Reckitt & Colman Inc.Inventors: Dennis T. Smialowicz, Ernest J. Sachs, Edward M. Cooney, III
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Patent number: 5605578Abstract: A concentrated cleaning composition for cleaning outdoor vinyl surfaces. The concentrated cleaning solution includes an aqueous chlorinated bleach solution, a surfactant, a phosphate and a silicate. The concentrated cleaning solution is diluted with water to form a diluted composition which is applied to the surfaces to be cleaned to effect loosening of soil. Thereafter, the loosened soil is removed by the mechanical action of a water spray.Type: GrantFiled: February 3, 1995Date of Patent: February 25, 1997Assignee: Armor All Products CorporationInventors: Charles Hawes, Mark Thompson
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Patent number: 5602091Abstract: The present invention relates to a self-foaming, self-leveling aqueous liquid composition packagable in a non-pressurized deformable dispenser of flexible barrier material adapted to contain, maintain and dispense a proportioned amount of the cleansing composition under positive pressure. The composition comprises: a major amount of water; a surfactant; and a dual purpose pressure agent comprising at least one aliphatic hydrocarbon fluid in amounts sufficient to provide the liquid composition, which when contained in a dispenser exerts a positive vapor pressure at least at about 1.6.degree. C. The composition is dispensed as a liquid under normal operating conditions, which liquid foams instantaneously and spontaneously on spreading.Type: GrantFiled: June 7, 1995Date of Patent: February 11, 1997Assignee: Dowbrands L.P.Inventors: James A. Monson, Dawn T. Anderson, James L. Kurtz, Joseph I. Kravitz
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Patent number: 5597793Abstract: The invention is a foam stabilizing composition which is used in conjunction with alkaline detergent products to produce a foam which is capable of clinging to vertical surfaces for extended time periods without breakdown or drying and which ultimately rinses freely with water. The foam stabilizing composition generally comprises a vinyl polymer emulsion. The invention also comprises a method of cleaning hard surfaces using the combination of the alkaline detergent product and the disclosed foam stabilizing composition.Type: GrantFiled: November 15, 1994Date of Patent: January 28, 1997Assignee: Ecolab Inc.Inventors: Michael Besse, Timothy Gutzmann, Roger Keppers, Richard Ruhr
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Patent number: 5589267Abstract: A polyvinyl ether and paraffin wax blend is described which is useful as a coating for encapsulates which are stable in an alkaline environment and which exhibit a volume % compressibility of 20.degree. or less at 30.degree. C. The polyvinyl ether material has a formula [C.sub.x H.sub.2x O].sub.y.Type: GrantFiled: July 17, 1995Date of Patent: December 31, 1996Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Francois Delwel, David J. Lang
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Patent number: 5567247Abstract: A concentrated cleaning composition for cleaning outdoor painted/stained surfaces. The concentrated cleaning solution includes an aqueous chlorinated bleach solution, a surfactant, a phosphate and a silicate. The concentrated cleaning solution is diluted with water to form a diluted composition which is applied to the surfaces to be cleaned to effect loosening of soil. Thereafter, the loosened soil is removed by the mechanical action of a water spray.Type: GrantFiled: August 11, 1995Date of Patent: October 22, 1996Assignee: Armor All Products CorporationInventors: Charles Hawes, Mark Thompson
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Patent number: 5567444Abstract: A cleaning and sanitizing method for soiled solid surfaces, especially clean-in-place process facilities, is described which involves contacting the surfaces first with an aqueous ozone cleaning composition having a pH greater than 7, wherein the ozone is generated by electrical discharge, then quenching the excess ozone and simultaneously sanitizing the surfaces by contact with an aqueous composition containing hydrogen peroxide, a C.sub.1 -C.sub.10 peroxyaliphatic carboxylic acid or a mixture thereof.Type: GrantFiled: September 22, 1995Date of Patent: October 22, 1996Assignee: Ecolab Inc.Inventors: Robert D. Hei, Guange-jong J. Wei, Bruce R. Cords, Keith D. Lokkesmoe
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Patent number: 5559090Abstract: Aqueous acidic bleaching compositions are described which comprise hydrogen peroxide and a specific class of surfactants which stabilize hydrogen peroxide.Type: GrantFiled: September 22, 1994Date of Patent: September 24, 1996Assignee: The Procter & Gamble CompanyInventors: Stefano Scialla, Sergio Cardola