Ternary Composition Patents (Class 510/410)
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Patent number: 6635686Abstract: This invention provides azeotrope-like compositions of 1,1,1,2-tetrafluoroethane, 1,1,1,3,3-pentafluoropropane-245fa and 2-methylbutane that are environmentally desirable for use as refrigerants, aerosol propellants, metered dose inhalers, blowing agents for polymer foam, heat transfer media, and gaseous dielectrics.Type: GrantFiled: June 10, 2002Date of Patent: October 21, 2003Assignee: Honeywell International Inc.Inventors: Mary C. Bogdan, Hang T. Pham, David J. Williams, Gary M. Knopeck, Rajiv R. Singh
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Patent number: 6635187Abstract: A process is disclosed for producing compositions including (a) a compound selected from the group consisting of CHF2CF3, CHF2CHF2, CH2FCF3, CH3CF3, CH3CHF2, CH2FCF2CHF2 and CHF2CF2CF2CHF2 and (b) at least one saturated halogenated hydrocarbon and/or ether having the formula: CnH2n+2-a-bClaFbOc wherein n is an integer from 1 to 4, a is an integer from 0 to 2n+1, b is an integer from 1 to 2n+2-a, and c is 0 or 1, provided that when c is 1 then n is an integer from 2 to 4, and provided that component (b) does not include the selected component (a) compound, wherein the molar ratio of component (b) to component (a) is between about 1:99 and a molar ratio of HF to component (a) in an azeotrope or azeotrope-like composition of component (a) with HF.Type: GrantFiled: November 15, 2000Date of Patent: October 21, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Barry A. Mahler, V. N. Mallikarjuna Rao, Allen Capron Sievert
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Patent number: 6541435Abstract: Engine cleaner compositions are reported comprising a single phase solution comprising a polar solvent having a Hildebrand solubility parameter of about 10 cal½ cm−3/2 or greater; a non-polar solvent, immiscible with the polar solvent, having a Hildebrand solubility parameter of about 10 cal½ cm−3/2 or less; and a fugitive cosolvent having a higher evaporation rate than the polar solvent and the non-polar solvent. The engine cleaner compositions are suitable for cleaning internal combustion engines.Type: GrantFiled: December 7, 2000Date of Patent: April 1, 2003Assignee: 3M Innovative Properties CompanyInventor: Kenneth G. Gatzke
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Patent number: 6531441Abstract: Refrigerant compositions include mixtures of difluoromethane and isobutane, butane, propylene or cyclopropane; pentafluoroethane and propylene or cyclopropane; 1,1,2,2-tetrafluoroethane and propane; 1,1,1,2-tetrafluoroethane and cyclopropane; 1,1,1-trifluoroethane and DME or propylene; 1,1-difluoroethane and propane, isobutane, butane or cyclopropane; fluoroethane and propane or cyclopropane; 1,1,1,2,2,3,3-heptafluoropropane and butane, cyclopropane, DME, isobutane or propane; or 1,1,1,2,3,3,3-heptafluoropropane and butane, cyclopropane, isobutane or propane.Type: GrantFiled: August 27, 1999Date of Patent: March 11, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Donald Bernard Bivens, Brooks Shawn Lunger
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Patent number: 6511610Abstract: Composition consisting essentially of 55 to 94% R-125, 2.5 to 35% of R-134a and 3.5 to 25% by weight of DME, and its use as a refrigerant in a heat transfer system designed for R-22 and comprising, as lubricant, a mineral oil or an alkylbenzene oil.Type: GrantFiled: August 29, 2001Date of Patent: January 28, 2003Assignee: AtofinaInventors: Laurent Caron, GĂ©rard Guilpain
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Patent number: 6503417Abstract: Disclosed are ternary azeotropic, azeotrope-like, and zeotropic compositions of ammonia, pentafluoroethane and difluoromethane. These compositions are useful as refrigerants, and particularly as high capacity and efficiency alternatives to binary mixtures of difluoromethane and pentafluoroethane.Type: GrantFiled: April 12, 1999Date of Patent: January 7, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Donald Bernard Bivens, Akimichi Yokozeki
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Patent number: 6426327Abstract: The invention provides azeotrope-like compositions consisting essentially of RfOCH3, where Rf is a branched or straight chain perfluoroalkyl group having 4 carbon atoms, and one or more organic solvent(s) selected from the group consisting of: straight chain, branched chain and cyclic alkanes containing 6 to 8 carbon atoms; cyclic and acyclic ethers containing 4 to 6 carbon atoms; ketones having 3 carbon atoms; chlorinated alkanes containing 1, 3 or 4 carbon atoms; chlorinated alkenes containing 2 carbon atoms, alcohols containing 1 to 4 carbon atoms, partially fluorinated alcohols containing 2 to 3 carbon atoms, 1-bromopropane, acetonitrile, HCFC 225ca (1,1,-dichloro-2,2,3,3,3 pentafluoropropane and HCFC-225cb (1,3-dichloro-1,1,2,2,3-pentafluoropropane).Type: GrantFiled: February 14, 2001Date of Patent: July 30, 2002Assignee: 3M Innovative Properties CompanyInventors: Richard M. Flynn, Dean S. Milbrath, John G. Owens, Daniel R. Vitcak, Hideto Yanome
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Patent number: 6403550Abstract: Azeotropic and azeotrope-like compositions of 142/365 mfc, 142/methanol, and 142/365 mfc/methanol are provided, as are methods for using the same for cleaning, drying, foam blowing and the like.Type: GrantFiled: March 10, 2000Date of Patent: June 11, 2002Assignee: ATOFINA Chemicals, Inc.Inventors: Michael S. Bolmer, Pascal Michaud
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Patent number: 6399562Abstract: Azeotropic or near azeotropic solvent compositions, based on 1-difluoromethoxy-1,1,2,2-tetrafluoroethyl difluoromethyl ether, essentially consisting of (% by weight): I) 1-difluoromethoxy 15-99 1,1,2,2-tetrafluoroethyl difluromethyl ether (HCF2OCF2CF2OCF2H); isopentane 85-1 II) 1-difluromethoxy 25-99 1,1,2,2-tetrafluroethyl difluoromethyl ether (HCF2OCF2CF2OCF2H); methyl-acetate 75-1 III) 1-difluoromethoxy 35-99 1,1,2,2-tetrafluoroethyl difluoromethyl ether (HCF2OCF2CF2OCF2H); 1-bromo-propane 65-1.Type: GrantFiled: February 9, 2001Date of Patent: June 4, 2002Assignee: Ausimont S.p.A.Inventors: Giampiero Basile, Mario Visca, Ezio Musso
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Patent number: 6395699Abstract: A solvent composition comprising (a) dichloropentafluoropropane, (b) trans-1,2-dichloroethylene and (c) methanol, wherein the proportions of (a), (b) and (c) in the total amount of (a), (b) and (c) are from 57 to 75 wt %, from 20 to 35 wt % and from 5 to 8 wt %, respectively.Type: GrantFiled: August 13, 1996Date of Patent: May 28, 2002Assignee: Asahi Glass Company Ltd.Inventors: Kenroh Kitamura, Michino Ikehata, Masaaki Tsuzaki
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Publication number: 20020007841Abstract: The disclosed invention relates to compositions having an alkylene carbonate and a primary hydroxyl functional capping agent for treating materials fouled with isocyanate. The invention also relates to decontamination of materials fouled with isocyanate, and to methods for decontamination of solvent fouled with isocyanate.Type: ApplicationFiled: January 18, 2001Publication date: January 24, 2002Inventor: James A. Yavorsky
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Patent number: 6288017Abstract: The invention provides azeotrope-like compositions consisting essentially of RfOCH3, where Rf is a branched or straight chain perfluoroalkyl group having 4 carbon atoms, and one or more organic solvent(s) selected from the group consisting of: straight chain, branched chain and cyclic alkanes containing 6 to 8 carbon atoms; cyclic and acyclic ethers containing 4 to 6 carbon atoms; ketones having 3 carbon atoms; chlorinated alkanes containing 1, 3 or 4 carbon atoms; chlorinated alkenes containing 2 carbon atoms, alcohols containing 1 to 4 carbon atoms, partially fluorinated alcohols containing 2 to 3 carbon atoms, 1-bromopropane, acetonitrile, HCFC 225ca (1,1,-dichloro-2,2,3,3,3 pentafluoropropane and HCFC-225cb (1,3-dichloro-1,1,2,2,3-pentafluoropropane).Type: GrantFiled: October 28, 1999Date of Patent: September 11, 2001Assignee: 3M Innovative Properties CompanyInventors: Richard M. Flynn, Dean S. Milbrath, John G. Owens, Daniel R. Vitcak, Hideto Yanome
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Patent number: 6281184Abstract: Compns. based on azeotropic or quasi-azeotropic mixts. of trichloroethylene and 1,1,1,2,3,4,4,5,5,5-decafluoropentane are useful for replacing CFC or HCFC in cleaning and degreasing of surfaces (e.g., defluxing of printed circuits) and drying of surfaces. The ability of these compns. to dry surfaces is improved by addn. of RCONR(CH2)nNHCOR surfactants (R=C14-22 alkyl, n=1-5).Type: GrantFiled: April 21, 2000Date of Patent: August 28, 2001Assignee: AtofinaInventors: Pascal Michaud, Jean-Jacques Martin
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Patent number: 6277807Abstract: The invention provides azeotropc-like compositions consisting essentially of RfOCH3, where Rf is a branched or straight chain perfluoroalkyl group having 4 carbon atoms, and one or more organic solvent(s) selected from the group consisting of: straight chain, branched chain and cyclic alkanes containing 6 to 8 carbon atoms; cyclic and acyclic ethers containing 4 to 6 carbon atoms; ketones having 3 carbon atoms; chlorinated alkanes containing 1, 3 or 4 carbon atoms; chlorinated alkenes containing 2 carbon atoms, alcohols containing 1 to 4 carbon atoms, partially fluorinated alcohols containing 2 to 3 carbon atoms, 1-bromopropane, acetonitrile, HCFC 225ca (1,1,-dichloro-2,2,3,3,3 pentafluoropropane and HCFC-225cb (1,3-dichloro-1,1,2,2,3-pentafluoropropane).Type: GrantFiled: February 14, 2001Date of Patent: August 21, 2001Assignee: 3M Innovative Properties CompanyInventors: Richard M. Flynn, Dean S. Milbrath, John G. Owens, Daniel R. Vitcak, Hideto Yanome
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Patent number: 6270689Abstract: Compositions suitable for use as refrigerants comprise blends of trifluoroiodomethane, 1,1,1,2-tetrafluoroethane and 1,1-difluoroethane. Preferred compositions are non-flammable and at least near azeotropic.Type: GrantFiled: March 26, 1998Date of Patent: August 7, 2001Assignee: Ikon CorporationInventor: Jonathan S. Nimitz
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Patent number: 6235700Abstract: The invention provides azeotrope-like compositions consisting essentially of RfOC2H5, where Rf is a branched or straight chain perfluoroalkyl group having 4 carbon atoms, and an organic solvent selected from the group consisting of: straight chain, branched chain and cyclic alkanes having 6 to 8 carbon atoms; esters having 4 carbon atoms; ketones having 4 carbon atoms; disiloxanes having 6 carbon atoms; cyclic and acyclic ethers having 4 to 6 carbon atoms; chlorinated alkanes having 3 to 4 carbon atoms and chlorinated alkenes having 2 carbon atoms. The compositions are useful for cleaning, as solvents or carriers for coating and as heat transfer materials.Type: GrantFiled: October 28, 1999Date of Patent: May 22, 2001Assignee: 3M Innovative Properties CompanyInventors: Richard M. Flynn, Dean S. Milbrath, John G. Owens, Daniel R. Vitcak, Hideto Yanome
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Patent number: 6221273Abstract: Azeotropic or near azeotropic compositions based on hexafluoropropane (R 236) as substitutes of CClF2-CClF2 (R 114) which essentially consist of R 236 and bis(difluoromethyl)-ether or n-butane, or mixtures thereof, for heat pumps, air-conditioners, etc.Type: GrantFiled: July 9, 1998Date of Patent: April 24, 2001Assignee: Ausimont S.p.A.Inventors: Giampiero Basile, Ezio Musso
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Patent number: 6187107Abstract: The water-repellent mixture comprises i) a halogenated dispersant chosen from the group constituted by a totally halogenated molecule and a partially halogenated molecule with at least one atom of hydrogen and ii) a copolymeric silicone having a hydrophilic function, for drying solids by the movement of water, the copolymeric silicone preferably being a polyalkylineoxide modified polydimethylsiloxane of formula: with 0≦m≦100, 4≦n≦50 and R being a radical chosen from the group of radicals constituted by a hydrogen atom, an alcohol group, an amine group and a polyalkyl group containing 1 to 5 carbon atoms.Type: GrantFiled: June 24, 1998Date of Patent: February 13, 2001Assignee: Promosol S.A.Inventors: Patrick Duchi, Joseph Micozzi
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Patent number: 6107267Abstract: A process is disclosed for recovering HF from a product mixture including HF and CF.sub.3 CF.sub.2 CHF.sub.2. The process involves (1) distilling the product mixture to remove all products which have a lower boiling point than the lowest boiling azeotrope containing HF and CF.sub.3 CF.sub.2 CHF.sub.2 ; and (2) distilling the azeotrope to recover HF as an azeotropic composition containing HF and CF.sub.3 CF.sub.2 CHF.sub.2. Also disclosed are compositions of hydrogen fluoride in combination with an effective amount of CF.sub.3 CF.sub.2 CHF.sub.2 to form an azeotrope or azeotrope-like composition with hydrogen fluoride, (e.g., compositions containing from about 57.1 to 67.2 mole percent CF.sub.3 CF.sub.2 CHF.sub.2).A process for producing certain compositions comprising(a) CF.sub.3 CF.sub.2 CHF.sub.2 and (b) at least one saturated halogenated hydrocarbon and/or ether having the formula:C.sub.n H.sub.2n+2-a-b Cl.sub.a F.sub.b O.sub.Type: GrantFiled: August 20, 1998Date of Patent: August 22, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: V. N. Mallikarjuna Rao, Allen Capron Sievert, Munirpallam A. Subramanian
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Patent number: 6048832Abstract: The invention relates to novel azeotrope-like compositions of 1-bromopropane, 4-methoxy-1,1,1,2,2,3,3,4,4-nonafluorobutane (HFE-7100) and at least one organic solvent selected from the group consisting of methanol, ethanol, 2-propanol, 2-methyl-2-propanol, tetrahydrofuran, nitromethane, and methylene chloride and more particularly to azeotrope-like compositions based on these compounds which are useful as solvents in refrigeration flushing, oxygen system cleaning and vapor degreasing applications.Type: GrantFiled: June 25, 1998Date of Patent: April 11, 2000Assignee: AlliedSignal Inc.Inventors: Alagappan Thenappan, Leonard Michael Stachura, Martin Richard Paonessa, Kane David Cook, Ian R. Shankland
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Patent number: 6048833Abstract: This invention provides a solvent composition comprising 1-bromopropane and a decafluoropentane for use as a cleaning and degreasing solvent. Preferably the decafluoropentane consists essentially of 1,1,1,2,3,4,4,5,5,5-decafluoropentane. The solvent composition optionally includes stabilizers and co-solvents such alcohols, ketones, ethers, acetals, nitroalkanes, epoxides and amines. Specific compositions of 1-bromopropane, 1,1,1,2,3,4,4,5,5,5-decafluoropentane and optional stabilizers provide azeotrope compositions that are particularly well suited as cleaning and degreasing solvents.Type: GrantFiled: July 9, 1998Date of Patent: April 11, 2000Assignee: Great Lakes Chemical CorporationInventor: Richard J. DeGroot
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Patent number: 6036727Abstract: This invention relates to dry-cleaning systems which include anhydrous dry-cleaning compositions which contain polysulfonic acid, and a bag for the cleaning and containment of soiled fabric articles. In a first embodiment, the dry-cleaning compositions includes organic solvents, polysulfonic acid, and not more than about 10 wt % water. In a second embodiment, the dry-cleaning compositions includes organic solvents and polysulfonic acid, and not more than 1 about wt % water. The invention also relates to methods of using the dry-cleaning system and dry-cleaning composition.Type: GrantFiled: September 29, 1997Date of Patent: March 14, 2000Assignee: Creative Products Resource, Inc.Inventor: James A. Smith
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Patent number: 6022842Abstract: The invention provides azeotrope-like compositions consisting essentially of R.sub.f OCH.sub.3, where R.sub.Type: GrantFiled: February 11, 1998Date of Patent: February 8, 2000Assignee: 3M Innovative Properties CompanyInventors: John G. Owens, Hideto Yanome
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Patent number: 6010997Abstract: The invention relates to novel compositions of 1-bromopropane, nitromethane or acetonitrile and at least one alcohol selected from the group consisting of ethanol, 2-propanol and 2-methyl-2-propanol and more particularly to azeotrope-like compositions based on these compounds which are useful as solvents in refrigeration flushing, oxygen system cleaning and vapor degreasing applications.Type: GrantFiled: June 25, 1998Date of Patent: January 4, 2000Assignee: Alliedsignal Inc.Inventors: Alagappan Thenappan, Leonard Michael Stachura, Martin Richard Paonessa, Kane David Cook
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Patent number: 6008179Abstract: The invention provides azeotrope-like compositions consisting essentially of R.sub.f OCH.sub.3, where R.sub.f is a branched or straight chain perfluoroalkyl group having 4 carbon atoms, and one or more organic solvent(s) selected from the group consisting of: straight chain, branched chain and cyclic alkanes containing 6 to 8 carbon atoms; cyclic and acyclic ethers containing 4 to 6 carbon atoms; ketones having 3 carbon atoms; chlorinated alkanes containing 1, 3 or 4 carbon atoms; chlorinated alkenes containing 2 carbon atoms, alcohols containing 1 to 4 carbon atoms, partially fluorinated alcohols containing 2 to 3 carbon atoms, 1-bromopropane, acetonitrile, HCFC 225ca (1,1,-dichloro-2,2,3,3,3-pentafluoropropane and HCFC- 225cb (1,3-dichloro-1,1,2,2,3-pentafluoropropane).Type: GrantFiled: September 21, 1998Date of Patent: December 28, 1999Assignee: 3M Innovative Properties CompanyInventors: Richard M. Flynn, Dean S. Milbrath, John G. Owens, Daniel R. Vitcak, Hideto Yanome
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Patent number: 5977054Abstract: Disclosed are mildly acidic liquid compositions for use in cleaning hard surfaces. The compositions contain from about 1% to about 60% of an amine oxide detergent surfactant, an aqueous carrier liquid, and an acidifying agent having a pK.sub.a of less than about 6.0. The compositions contain enough of the acidifying agent to protonate at least about 10% of the amine oxide species within the compositions and to provide a composition pH of between about 3 and 7. These no-rinse liquid hard surface cleaning compositions have excellent cleaning properties, they do not leave a visible residue when they dry, and they cause minimal or no staining of vinyl surfaces. Also disclosed are a method for cleaning vinyl surfaces using the liquid compositions, and non-liquid compositions from which the mildly acidic liquid compositions can easily be obtained by adding an aqueous liquid.Type: GrantFiled: October 15, 1996Date of Patent: November 2, 1999Assignee: The Procter & Gamble CompanyInventor: Thomas James Wierenga
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Patent number: 5968882Abstract: Disclosed herein is a nonflammable mixed solvent composition comprising a completely fluorinated organic compound and a partially fluorinated organic compound as essential components, wherein the completely fluorinated organic compound is contained in an amount of at least 5% by weight.Type: GrantFiled: September 15, 1995Date of Patent: October 19, 1999Assignee: Canon Kabushiki KaishaInventors: Hirohide Matsuhisa, Tomomasa Nakamura
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Patent number: 5965511Abstract: In order to replace compositions based on CFC or on HCFC in applications for cleaning or drying solid surfaces (in particular defluxing), the invention proposes azeotropic or virtually azeotropic compositions based on 1,1,1,2,3,4,4,5,5,5-decafluoropentane, methylene chloride and optionally methanol.Type: GrantFiled: January 30, 1998Date of Patent: October 12, 1999Assignee: Elf Atochem S. A.Inventors: Pascal Michaud, Jean-Jacques Martin
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Patent number: 5962401Abstract: A detergent builder is composed of a maleic acid copolymer having a weight-average molecular weight in a range of from 5,000 to 100,000, wherein a molar ratio of a maleic acid (salt) monomer to total monomers used in a process is in a range of from 0.1 to 0.9. The detergent builder is obtained by a copolymerization reaction of the monomers using a hydrogen peroxide and a persulfate as a polymerization initiator. As such detergent builder has high calcium ion stability constant and desirable property against iron particle deposition, it is suitably used as a detergent composition. The detergent builder may be prepared by granulation with agitation of powders containing the maleic acid copolymer as water-soluble polycarboxylic acid (salt) using a surface active agent.Type: GrantFiled: July 16, 1996Date of Patent: October 5, 1999Assignee: Nippon Shokubai Co., Ltd.Inventors: Shigeru Yamaguchi, Yoshihiro Maeda
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Patent number: 5853492Abstract: A wet chemical process is provided for treating an emitter formed on a substrate of a field emission display, the process comprises applying a solution including hydrogen to the emitter. In one embodiment of the invention, the steps of applying a solution comprises applying a solution of hydrofluoric acid to the emitter.Type: GrantFiled: February 28, 1996Date of Patent: December 29, 1998Assignee: Micron Display Technology, Inc.Inventors: David A. Cathey, Terry Gilton
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Patent number: 5851436Abstract: Compositions of nonafluoromethoxybutane and cyclopentane, nonafluoromethoxybutane and cyclohexane; nonafluoromethoxybutane, cyclopentane and acetone, nonafluoromethoxybutane, cyclohexane and acetone, nonafluoromethoxybutane, trans-1,2-dichloroethylene and cyclopentane; and nonafluoromethoxybutane, trans-1,2-dichloroethylene, cyclopentane and methanol are described. These compositions are useful as cleaning agents, displacement drying agents, refrigerants, heat transfer media, expansion agents for polyolefins and polyurethanes, aerosol propellants, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, and buffing abrasive agents.Type: GrantFiled: May 19, 1997Date of Patent: December 22, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Abid Nazarali Merchant, Barbara Haviland Minor, Shoeb Akberali Moiyadi
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Patent number: 5839311Abstract: In one aspect, this invention provides a lubricating and colling composition for the forming of metals comprising a hydrofluoroether. In another aspect, the present invention provides a method of forming metals comprising applying to the metal and the workpiece a composition comprising a hydrofluoroether.Type: GrantFiled: September 17, 1996Date of Patent: November 24, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventors: Mark W. Grenfell, Dean S. Milbrath, Daniel D. Krueger, Richard M. Flynn, Frederick E. Behr
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Patent number: 5827446Abstract: Compositions of nonafluoromethoxybutane and at least one component selected from the group consisting of methanol, ethanol, isopropanol, n-heptane, trans-1,2-dichloroethylene, cis-1,2-dichloroethylene and acetone, and 1,1,1,2,3,4,4,5,5,5-decafluoropentane are described. These compositions are useful as cleaning agents, displacement drying agents, refrigerants, heat transfer media, expansion agents for polyolefins and polyurethanes, aerosol propellants, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, and buffing abrasive agents.Type: GrantFiled: January 15, 1997Date of Patent: October 27, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Abid Nazarali Merchant, Barbara Haviland Minor
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Patent number: 5817615Abstract: The invention provides an aqueous, hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising:(a) an effective amount of at least one organic solvent with a vapor pressure of at least 0.001 mm Hg at 25.degree. C., and mixtures of such solvents;(b) an effective amount of at least one semi-polar nonionic surfactant, said surfactant having the structure: ##STR1## wherein R.sup.1 is C.sub.5-20 alkyl, R.sup.2 and R.sup.3 are both C.sub.1-4 alkyl, or --(CH.sub.2).sub.p --OH, although R.sup.2 and R.sup.3 do not have to be equal, and p is 1-6;(c) an effective amount of a buffering system which comprises a nitrogenous buffer which will result in a pH of greater than 6.5; and(d) the remainder as substantially all water.Type: GrantFiled: June 3, 1996Date of Patent: October 6, 1998Assignee: The Clorox CompanyInventors: Aram Garabedian, Jr., Scott C. Mills, William P. Sibert, Clement K. Choy
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Patent number: 5800730Abstract: Near-Azeotropic blends of:pentafluoroethane and 1,1,1-trifluoroethane with one or more of chlorodifluoromethane, 1,2,2,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,2,3,3-heptafluoropropane, and perfluorocyclopropane;chlorodifluoromethane and pentafluoroethane with one or more of ethane, butane, isobutane, dimethyl ether, propylene, and difluoromethane;chlorodifluoromethane with 1,1,1-trifluoroethane and 1,2,2,2-tetrafluoroethane, propane and pentafluoroethane, or 1,1,1-trifluoroethane and octafluoropropane;and pentafluoroethane with fluoroethane and 1,2,2,2-tetrafluoroethane, along with their use as refrigerants.Type: GrantFiled: January 13, 1997Date of Patent: September 1, 1998Assignee: E. I. du Pont de Nemours and CompnayInventors: Donald Bernard Bivens, Mark Brandon Shiflett, Akimichi Yokozeki
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Patent number: 5762817Abstract: Azeotropic or azeotrope-like compositions of effective amounts of 1,1,1,2,3,4,4,5,5,5-decafluoropentane, 1,1-dichloroethane and an alcohol such as methanol, ethanol, or isopropanol, to form an azeotropic or azeotrope-like composition are disclosed that are useful as cleaning agents, refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes and as power cycle working fluids.Type: GrantFiled: February 24, 1997Date of Patent: June 9, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Abid Nazarali Merchant, Barbara Haviland Minor
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Patent number: 5747437Abstract: To replace compositions based on CFC or CFHC in applications for cleaning solid surfaces (in particular defluxing), the invention proposes azeotropic or quasi-azeotropic compositions based on 1,1,1,2,2,4,4-heptafluorobutane and a C.sub.1 -C.sub.3 alcohol.Type: GrantFiled: October 30, 1996Date of Patent: May 5, 1998Assignee: Elf Atochem S.A.Inventor: Pascal Michaud
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Patent number: 5747435Abstract: Composition useful as 2-in-1 cleansing products are disclosed that are extremely mild to skin and hair, which use neutralized, essentially chargeless, ionic complexes of fatty amines and fatty acids to deliver various levels of conditioning; neutralized, essentially chargeless, ionic complexes of a detersive surfactant comprising a water soluble cationic surfactant and/or polymer complexed with one or more anionic surfactants; or an amphoteric surfactant complexed with one or more anionic surfactants; or a water soluble cationic surfactant and/or polymer complexed with one or more amphoteric surfactants; or a water soluble cationic surfactant and/or polymer complexed with one or more anionic surfactants and an amphoteric surfactant; detersive surfactant-soluble but water-insoluble silicones or derivatives thereof; and water. These products exhibit true 2-in- conditioning properties, and are lower in cost than current 2 in 1 products. Clear or opacified products can be formulated.Type: GrantFiled: July 17, 1996Date of Patent: May 5, 1998Assignee: Colgate-Palmolive CompanyInventor: Amrit M. Patel
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Patent number: 5744052Abstract: Refrigerant compositions are disclosed which are non-flammable when vapor charged and which perform as well as compositions of 50 weight percent difluoromethane and 50 weight percent pentafluoroethane.Type: GrantFiled: April 17, 1996Date of Patent: April 28, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Donald Bernard Bivens
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Patent number: 5741766Abstract: Oil-in-water (O/W) cleansing emulsions having the appearance of a milk, comprising a self-emulsifiable composition based on fatty alcohols as emulsifying agent and an acrylic copolymer as gelling agent, useful for cleansing the skin of the face and/or of the body. These emulsions may be used in particular as a make-up removing milk.Type: GrantFiled: June 14, 1995Date of Patent: April 21, 1998Assignee: L'OrealInventors: Catherine Marion, Nathalie Louvet-Plaisant, Liliane Lukassen
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Patent number: 5736062Abstract: Azeotrope-like mixtures, utilizable as refrigerating fluids in substitution of R-12 or R-502, constituted by hydrogen-(chloro)fluorocarbons, optionally in admixture with propane, cyclopropane or dimethylether.Type: GrantFiled: February 12, 1996Date of Patent: April 7, 1998Assignee: Ausimont S.p.A.Inventors: Giampiero Basile, Ezio Musso
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Patent number: 5728315Abstract: Azeotrope-like compositions of trifluoromethane, carbon dioxide, ethane, and hexafluoroethane are provided. The compositions of the invention are environmentally desirable for use as refrigerants, aerosol propellants, blowing agents for polymer foam, heat transfer media, and gaseous dielectrics.Type: GrantFiled: May 1, 1996Date of Patent: March 17, 1998Assignee: AlliedSignal Inc.Inventors: Rajiv Ratna Singh, Ian Robert Shankland, Roy Phillip Robinson, Hang Thanh Pham, Raymond Hilton Percival Thomas, Peter Brian Logsdon
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Patent number: 5723057Abstract: To replace the azeotropic mixture of chlorodifluoromethane and chloropentafluoroethane (R-502) in low-temperature refrigeration, the invention proposes to use a pseudo-azeotropic mixture containing 45 to 50% by weight of chlorodifluoromethane, 44 to 48% by weight of 1,1,1-trifluoroethane, and 6 to 8% by weight of pentafluoroethane. The thermodynamic properties of this mixture are very similar to those of mixture R-502.Type: GrantFiled: September 23, 1996Date of Patent: March 3, 1998Assignee: Elf Atochem S.A.Inventor: Sylvie Macaudiere
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Patent number: 5656646Abstract: Mixtures of(I)polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and(II)(1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising(a) from 10 to 70% by weight of monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acids or the salts thereof and(b) from 30 to 90% by weight of monoethylenically unsaturated C.sub.3 -C.sub.10 -monocarboxylic acids and/or the salts thereof,(2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of(A) monoethylenically unsaturated C.sub.3 -C.sub.10 -carboxylic acids or the anhydrides and/or the salts thereof in the presence of(B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or(3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groupscontain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.Type: GrantFiled: May 22, 1995Date of Patent: August 12, 1997Assignee: BASF AktiengesellschaftInventors: Johannes Perner, Paul Diessel, Helmut Guembel, Walter Denzinger, Heinrich Hartmann, Matthias Kroner
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Patent number: 5648325Abstract: An azeotropic composition consisting of 89.2 wt % of 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorohexane and 10.8 wt % of methanol and an azeotropic composition consisting of 91.1 wt % of 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorohexane and 8.9 wt % of ethanol.The present invention provides alternative azeotropic solvent compositions which have excellent properties of conventional 1,1,2-trichloro-l,2,2-trifluoroethane and do not deplete the stratospheric ozone layer.Type: GrantFiled: June 9, 1995Date of Patent: July 15, 1997Assignee: AG Technology Co., Ltd.Inventors: Kenroh Kitamura, Michino Ikehata, Masaaki Tsuzaki, Kazuya Oharu
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Patent number: 5643492Abstract: Ternary mixtures of pentafluoroethane, difluoromethane and tetrafluoroethane are useful as refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes, and as power cycle working fluids.Type: GrantFiled: February 22, 1995Date of Patent: July 1, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Mark Brandon Shiflett
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Patent number: 5635099Abstract: Near-Azeotropic blends of:pentafluoroethane and 1,1,1-trifluoroethane with one or more of chlorodifluoromethane, 1,2,2,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,2,3,3-heptafluoropropane, and perfluorocyclopropane;chlorodifluoromethane and pentafluoroethane with one or more of ethane, butane, isobutane, dimethyl ether, propylene, and difluoromethane;chlorodifluoromethane with 1,1,1-trifluoroethane and 1,2,2,2-tetrafluoroethane, propane and pentafluoroethane, or 1,1,1-trifluoroethane and octafluoropropane;and pentafluoroethane with fluoroethane and 1,2,2,2-tetrafluoroethane, along with their use as refrigerants.Type: GrantFiled: June 7, 1995Date of Patent: June 3, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Donald B. Bivens, Mark B. Shiflett, Akimichi Yokozeki
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Patent number: 5635098Abstract: This invention relates to compositions that include at least one hydrocarbon and at least one fluorinated species. Such compositions may be used as refrigerants, cleaning agents, expansion agents for foams such as polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, displacement drying agents, among others.Type: GrantFiled: May 8, 1995Date of Patent: June 3, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Brooks S. Lunger, Glenn S. Shealy
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Patent number: 5624596Abstract: This invention relates to compositions that include at least one hydrocarbon and at least one fluorinated species. Such compositions may be used as refrigerants, cleaning agents, expansion agents for foams such as polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, displacement drying agents, among others.Type: GrantFiled: May 8, 1995Date of Patent: April 29, 1997Assignee: E. I. Dupont de Nemours and CompanyInventors: Brooks S. Lunger, Glenn S. Shealy
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Patent number: 5616276Abstract: Near-Azeotropic blends of:pentafluoroethane and 1,1,1-trifluoroethane with one or more of chlorodifluoromethane, 1,2,2,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,2,3,3-heptafluoropropane, and perfluorocyclopropane;chlorodifluoromethane and pentafluoroethane with one or more of ethane, butane, isobutane, dimethyl ether, propylene, and difluoromethane;chlorodifluoromethane with 1,1,1-trifluoroethane and 1,2,2,2-tetrafluoroethane, propane and pentafluoroethane, or 1,1,1-trifluoroethane and octafluoropropane;and pentafluoroethane with fluoroethane and 1,2,2,2-tetrafluoroethane, along with their use as refrigerants.Type: GrantFiled: June 7, 1995Date of Patent: April 1, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Donald B. Bivens, Mark B. Shiflett, Akimichi Yokozeki