Sulfonate Surfactant With Sulfate Monoester Surfactant Patents (Class 510/429)
  • Patent number: 9695385
    Abstract: Surfactant compositions comprising an alkoxylate, a sulfate, or ether sulfate of a C10-C12 monounsaturated alcohol are disclosed. The alkoxylate, sulfate, or ether sulfate may derive from undecylenic acid or undecylenic alcohol. Compared with their saturated analogs, the monounsaturated alkoxylates, sulfates, and ether sulfates are less irritating, making them valuable for personal care, laundry, cleaners, and other household applications. Microscopy studies show that the alkoxylates, sulfates, and ether sulfates have favorable phase behavior over a wide range of actives levels, expanding opportunities for products with greater compaction. When combined with cationic surfactants, the alkoxylates, sulfates, and ether sulfates exhibit synergy, and they have improved solubility compared with their saturated analogs. The surfactants find value for the personal care, laundry and cleaning, emulsion polymerization, agricultural products, oilfield applications, and specialty foams industries.
    Type: Grant
    Filed: March 5, 2014
    Date of Patent: July 4, 2017
    Assignee: STEPAN COMPANY
    Inventors: David R Allen, Randal J Bernhardt, Aaron Brown, Gregory P Dado, Xue Min Dong, Wilma Gorman, Ronald Masters, Patti Skelton
  • Patent number: 9624455
    Abstract: The present invention relates to an Automatic Dishwashing (ADW) detergent composition comprising at least one cationic polysaccharide of molecular weight of less than 1,000,000 g/mol. The invention also relates to a method for eliminating, limiting or preventing the spotting and/or filming phenomena during the washing comprising the use of a detergent composition according to claim 1.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: April 18, 2017
    Assignee: Rhodia Operations
    Inventors: Dominique Labarre, Marie-Pierre Labeau, Florence Lambert, Céline Orizet, Gilda Lizarraga, Véronique Geoffroy
  • Patent number: 8383569
    Abstract: A single phase alkaline composition comprising by weight about 10 to about 25 percent of nonionic surfactant blend comprising a ratio of between about 1:1 to about 1:2 of alcohol ethoxylate:fatty alcohol alkoxylate, about 3-10% of at least one water soluble solvent, about 1-10% of a chelant, 2-12% of an alkalinity source, 0.5-2% of an anionic surfactant blend comprised of at least about 40-70% of a sulfosuccinate, the balance being water. Compositions of the invention are useful for removing hydrophobic soils or oils whether they are located on a hard surface or on a linen. A method of cleaning a hard surface is also disclosed comprising the steps of diluting the composition of the invention with water to about 1 to about 3 weight percent, applying the diluted composition to the surface, and wiping the surface, wherein the surface is substantially free of oil or residue and the surface is substantially free of corrosion.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: February 26, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Andrea Schwerter, Katja Teusch, Matthias Menzel
  • Patent number: 8304377
    Abstract: Provided are new anionic surfactants and methods of their preparation and use. The surfactants are compounds of the formula I: wherein R, R1, R2, R3, R4, R5, and R6 are as defined herein.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: November 6, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Wanglin Yu, Cynthia Rand, Edward D. Daugs, Yang Cheng, Irina V. Graf, Andre B. Argenton, Kari S. Phillipson
  • Patent number: 8168580
    Abstract: The present invention relates to a method for producing an aqueous ?-SF salt solution that maintains fluidity and has superior production adaptability. The method includes dissolving a solid component (a) in the form of an ?-sulfo fatty acid alkyl ester salt and a component (b) in the form of an inorganic sodium salt and/or inorganic potassium salt in water, wherein component (a) is dissolved in water at a temperature of 50° C. or higher while maintaining the following condition (i) or (ii): (i): the concentration of component (a) is 35% by weight or less when the total concentration of sodium and potassium ions derived from component (b) is less than 0.55 mol/kg, or (ii) the concentration of component (a) is 55% by weight or less when the total concentration of sodium and potassium ions derived from component (b) is 0.55 mol/kg to less than 1.8 mol/kg.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: May 1, 2012
    Assignee: Lion Corporation
    Inventors: Hiroyuki Masui, Kensuke Itakura, Hiroshi Gotou
  • Patent number: 7923426
    Abstract: A detergent composition comprising: a non-sulphated anionic surfactant, alkyl sulphate surfactant(s) of formula R2—O—SO3?M+, with R2 being a linear or branched, substituted or unsubstituted, optionally alkoxylated, C6-C18 alkyl and with M+ being a proton or a cation which provides charge neutrality, and wherein the alkyl sulphate surfactant(s) of formula R2—O—SO3?M+, comprises from 85% to 100% by weight of alkyl sulphate surfactant(s) of formula R1—O—SO3?M+, with R1 being a linear or branched, substituted or unsubstituted, optionally alkoxylated, C6-C14 alkyl and with M+ being a proton or a cation which provides charge neutrality, wherein the composition comprises from 0 to 20% of zeolite, and wherein the composition does not comprise from 40% to 43% by weight of sodium chloride.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: April 12, 2011
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Nathan Price, Hiroshi Oh, Qing Chen, Ming Tang, Suxuan Gong, Lucia Mendez-Mata
  • Patent number: 7910538
    Abstract: A detergent composition comprising at most 15% by weight of phosphate builder(s) and aluminosilicate builder(s), and comprising at least one short chain anionic surfactant selected from alkyl sulfate surfactant(s) and alkyl sulfonate surfactants.
    Type: Grant
    Filed: June 4, 2009
    Date of Patent: March 22, 2011
    Assignee: The Procter & Gamble Company
    Inventors: Ming Tang, Qing Chen, Sen Liu, Kenneth Nathan Price
  • Publication number: 20100323946
    Abstract: This invention encompasses a light duty liquid detergent composition that includes a C14-C15 alcohol and alcohol ethoxylate sulfate surfactant blend as an efficient and effective foaming agent. The surfactant-based product may be a hand dishwashing liquid, a liquid skin cleanser or any type of cleaning or cleansing product based on surfactants. Specifically, the invention relates to a light duty liquid detergent composition with desirable cleansing properties and foaming capability including an anionic sulfonate surfactant, an amine oxide, a C14-C15 alcohol, and a C14-C15 alcohol ethoxylate sulfate.
    Type: Application
    Filed: May 19, 2009
    Publication date: December 23, 2010
    Applicant: COLGATE-PALMOLIVE COMPANY
    Inventors: Thomas Connors, Gary Jakubicki, Gregory Szewczyk, Petra Archibald, Philip Anthony Gorlin
  • Patent number: 7781390
    Abstract: There is provided a new branched primary alcohol composition and the sulfates thereof exhibiting good cold water detergency and biodegradability. The branched primary alcohol composition has an average number of branches per chain of at least 0.7, having at least 8 carbon atoms and containing both methyl and ethyl branches. The primary alcohol composition may also contain less than 0.5 atom % of quaternary carbon atoms, and a significant number ethyl branches, terminal isopropyl branches, and branching at the C3 position relative to the hydroxyl carbon. The process for its manufacture is by skeletally isomerizing an olefin feed having at least 7 carbon atoms followed by conversion to an alcohol, as by way of hydroformylation, and ultimately, sulfation to obtain a detergent surfactant. Useful catalysts include the zeolites having at least one channel with a crystallographic free diameter along the x and/or y planes of the [001] view ranging from greater than 4.
    Type: Grant
    Filed: May 15, 2007
    Date of Patent: August 24, 2010
    Assignee: Shell Oil Company
    Inventors: David M. Singleton, Louis Kravetz, Brendan Dermot Murray
  • Patent number: 7427586
    Abstract: A degreasing agent includes a mixture of trisodium phosphate, sodium silicate, sodium carbonate, sodium dodecyl benzene sulphonate, sodium hydrosulphite and octyl-phenol-polyoxyethylene ether. The degreasing agent may maintain degreasing effect for longer period of time. In addition, the metal product cleaned by the degreasing agent has a low cleaning inferior rate.
    Type: Grant
    Filed: November 1, 2007
    Date of Patent: September 23, 2008
    Assignees: Shenzhen Futaihong Precision Industry Co., Ltd., Sutech Trading Limited
    Inventors: Xian-Liang Liu, Rui-Feng Zhang, Jian-Bin Zhao
  • Patent number: 6908894
    Abstract: A surfactant composition comprising: alkylarylsulfonate surfactant system comprising at least two isomers of the alkylarylsulfonate surfactant of the formula: wherein: L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; a and b are numbers selected such that said composition is electroneutral; R? is selected from H and C1 to C3 alkyl; R? is selected from H and C1 to C3 alkyl; R?? is selected from H and C1 to C3 alkyl; any of R? and R? is nonterminally attached to L and at least one of R? and R? is C1 to C3 alkyl; and A is aryl; and wherein: said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R?, R? and A to L; in at least about 60% of said composition, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms thereof; and wherein further said alkylarylsulfonate surfactant system has
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: June 21, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Kevin Lee Kott, Jeffrey John Scheibel, Thomas Anthony Cripe, Daniel Stedman Connor, Phillip Kyle Vinson
  • Patent number: 6846785
    Abstract: A liquid soap having vitamin-containing microcapsules including a base having an anionic surfactant and a chelating agent, a cross-linked acrylic polymer suspending agent, and multiple vitamin-containing microcapsules uniformly suspended in the liquid soap. The liquid soap is formulated at an elevated temperature which is maintained throughout the formulation process.
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: January 25, 2005
    Assignee: The Dial Corporation
    Inventor: Jayesh A. Patel
  • Patent number: 6824623
    Abstract: A terpene-free cleaning composition containing: (a) an oil-soluble anionic surfactant; (b) a water-soluble anionic surfactant; (c) a primary solvent consisting of a C1-4 alkyl ester; (d) a short-chain cosurfactant; and (e) water.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: November 30, 2004
    Assignee: Cognis Corporation
    Inventors: Stephen F. Gross, Martin J. Barabash, J. Frederick Hessel
  • Patent number: 6815405
    Abstract: A cleaning composition with desirable cleansing properties to the human skin comprising at least one surfactant, a preservative system and water.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: November 9, 2004
    Assignee: Colgate-Palmolive Company
    Inventors: Julien Drapier, Francoise Siquet-Descans, Maria Galvez
  • Patent number: 6593285
    Abstract: A surfactant composition comprising: alkylarylsulfonate surfactant system comprising at least two isomers of the alkylarylsulfonate surfactant of the formula:  wherein: L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; a and b are numbers selected such that said alkylarylsulfonate surfactant is electroneutral; R′, R″ and R′″ are independently selected from H and C1 to C3 alkyl; both of R′ and R″ are nonterminally attached to L and at least one of R′ and R″ is C1 to C3 alkyl; and A is aryl;  wherein: said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R′, R″ and A to L; in at least about 40% of said composition, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms of L; and  wherein fu
    Type: Grant
    Filed: January 7, 2000
    Date of Patent: July 15, 2003
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey John Scheibel, Thomas Anthony Cripe, Kevin Lee Kott, Daniel Stedman Connor, Phillip Kyle Vinson
  • Publication number: 20030100464
    Abstract: A hand dishwashing composition comprising i) from about 0.01% to about 99.
    Type: Application
    Filed: July 19, 2001
    Publication date: May 29, 2003
    Inventors: Kevin Lee Kott, Jeffrey John Scheibel, Thomas Anthony Cripe, Daniel Stedman Connor, Phillip Kyle Vinson, William Michael Scheper, Chandria Kasturi
  • Publication number: 20030027737
    Abstract: The present invention relates to a process of cleaning a hard surface with a liquid acidic composition comprising a surfactant system, wherein said surfactant system comprises: a sulphated or sulphonated anionic surfactant; a neutralizing co-surfactant; and a sulfobetaine and/or an alkoxylated nonionic surfactant.
    Type: Application
    Filed: August 26, 2002
    Publication date: February 6, 2003
    Applicant: The Procter & Gamble Company
    Inventor: Marc Francois Theophile Evers
  • Patent number: 6468956
    Abstract: Compositions containing a &agr;-sulfofatty acid ester and a hydrotrope. The &agr;-sulfofatty acid ester and the hydrotrope reduce the pH drift in the composition and solubilize the &agr;-sulfofatty acid ester in solution. Methods are also disclosed for making such compositions.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: October 22, 2002
    Assignee: Huish Detergents, Inc.
    Inventors: Paul Danton Huish, Laurie A. Jensen, Pule B. Libe
  • Publication number: 20020082182
    Abstract: Surfactant mixtures, improved detergent and cleaning products containing particular types of alkybenzene sulfonate surfactants.
    Type: Application
    Filed: May 16, 2001
    Publication date: June 27, 2002
    Applicant: The Procter & Gamble Company
    Inventors: Kevin Lee Kott, Jeffrey John Scheibel, Roland George Severson, Thomas Anthony Cripe, James Charles Theophile Roger Burckett-St. Laurent, Thomas Walter Federle
  • Publication number: 20020061828
    Abstract: This invention relates to an anionic alkoxylate surfactant of formula (I), where R is a di- or tri-unsaturated C4-22 straight or branched hydrocarbon chain, at least two double bonds of said unsaturated chain being conjugated and exhibiting opposite geometric isomerism; m is 0 or 1; Y is O or NR′; each R′ is independently selected from hydrogen, C1-6 alkyl and phenyl; n is 1 to 50; and OX is an anionic group selected from the group consisting of acids or salts of sulfate, phosphate, sulphosuccinate, succinate, carbomethyl, maleate, carboxyethyl, alkenylsuccinate, phthalate, sulphoethyl, 3-sulpho-2-hydroxypropyl, sulphopropyl, oxalate and citrate.
    Type: Application
    Filed: August 9, 2001
    Publication date: May 23, 2002
    Inventors: Elizabeth Ann Salter, Patrick William Houlihan, Michael Anthony Bajraszewski, Rodney Walter Parr, Keith Moody
  • Publication number: 20020042354
    Abstract: Detergents and cleaners comprising an active ingredient combination of a soil-release polymer and alkanesulfonate and/or &agr;-olefinsulfonate.
    Type: Application
    Filed: October 2, 2001
    Publication date: April 11, 2002
    Inventors: Frank-Peter Lang, Gerd Reinhardt
  • Patent number: 6306805
    Abstract: The present invention relates to surfactant compositions comprising a mixture of at least one cationic surfactant, at least one anionic surfactant, preferably a sulfonated methyl ester and/or a sulfonated fatty acid, and at least one “bridging surfactant” selected from semi-polar nonionic, ethoxylated alkanolamide, and amphoteric/zwitterionic surfactants, and mixtures thereof. More specifically, the invention relates to stable, synergistic mixtures of cationic, anionic, and bridging surfactants that are useful primarily as shampoos and/or body washes. The instant invention further provides both a method for preparing the inventive surfactant compositions, i.e., shampoos, and a method of treating hair with the shampoo compositions. When applied to hair or skin, the surfactant shampoo compositions of the instant invention generally provide for cleaning, conditioning, bodifying, and/or moisturization of the hair or skin.
    Type: Grant
    Filed: September 15, 2000
    Date of Patent: October 23, 2001
    Assignee: Stepan Company
    Inventors: Daniela T. Bratescu, Randy Bernhardt, Cathie Sporer, Sandy Lyons, Jeff Nelson, Rita Bezdicek
  • Patent number: 6268330
    Abstract: A light duty liquid detergent with desirable cleansing properties to the human skin comprising a C8-18 ethoxylated alkyl ether sulfate anionic surfactant, a sulfonate anionic surfactant, a hydroxy aliphatic acid and water.
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: July 31, 2001
    Assignee: Colgate-Palmolive Company
    Inventors: Isabelle Leonard, Jean Massaux, Christine Toussaint, Claude Blanvalet
  • Patent number: 6180583
    Abstract: Short-chain surfactants such as octyl sulfate are used to provide a solvent-like cleaning function in detergent compositions. Preferred bleach-containing hard surface cleaners comprising the short-chain surfactants and long-chain surfactants, are especially useful for bathroom and kitchen clean-up operations. Compositions with long-plus-short chain surfactants including alkyl sulfates, olefin sulfonates, amine oxides and the like, are disclosed.
    Type: Grant
    Filed: October 2, 1996
    Date of Patent: January 30, 2001
    Assignee: The Procter & Gamble Company
    Inventors: William Ajalon Cilley, Donald Ray Brown
  • Patent number: 6172021
    Abstract: The present invention relates to detergent compositions containing alkaolamine, preferably triethanolamines, divalent ions, chelants, and amphoteric surfactants. More particularly, the invention is directed to detergent compositions for hand dishwashing which has improved grease removal performance and benefits in sudsing. The detergent compositions of this invention can be in any form, including granular, gel or liquid. Highly preferred embodiments are in liquid form.
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: January 9, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Kofi Ofosu-Asante, Robert N. Owens
  • Patent number: 6162775
    Abstract: An anhydrous foaming cleansing composition for topical application to the man skin, comprising an anionic surfactant, glycerine, polyethylene glycol, and a water insoluble benefit agent.
    Type: Grant
    Filed: August 12, 1999
    Date of Patent: December 19, 2000
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventor: Suree Methmanus-Spaltro
  • Patent number: 6117831
    Abstract: The subject invention relates to a novel class of compounds, known as alkali metal salts of hydroxyalkyl sulfonates of aminoalkyl alkanol amines and/or aminoalkyl alkanol ethers, the methods of making such compounds, the alkali-stable solutions containing such compounds, and the use of said solutions as strong detergent compositions. Those alkali-stable solutions are temperature-stable, exhibit superior wetting characteristics, and can be made into low or high foam formulations useful for hard surface cleaning, oven and grill cleaning, metal cleaning, bottle washing, steam cleaning and wax stripping formulations.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: September 12, 2000
    Assignee: Lonza Inc.
    Inventors: Michael Yao-Chi Chiang, Daniel Wayne Lemke, Joseph William Scheblein
  • Patent number: 6090772
    Abstract: A disinfectant hand wash includes Triclosan and a reduced amount of surfactants in order to reduce skin irritation while maintaining improved activity against Gram negative and Gram positive organisms, including Serratia marcescens. The hand wash includes an effective amount of Triclosan, preferably 0.2-3.0% and a non-aqueous solvent. Hexylene glycol, or a mixture of hexylene glycol and isopropanol as the non-aqueous solvent provide improved efficacy in killing skin-born microbes. The hand wash further includes less than about 10% surfactant, preferably less than 5%. The hand wash further includes a chelating agent, a thickener, a buffering agent, and water.
    Type: Grant
    Filed: July 23, 1999
    Date of Patent: July 18, 2000
    Assignee: Steris Inc
    Inventors: Nancy E. Kaiser, Denise K. Pretzer
  • Patent number: 5945394
    Abstract: Disclosed are detergent compositions comprising:(a) an .alpha.-sulfonated alkyl ester of a fatty acid having an average of about 12-14 carbon atoms;(b) an anionic surfactant; and(c) a nonionic surfactant, and methods for preparing such compositions.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: August 31, 1999
    Assignee: Stepan Company
    Inventors: Branko Sajic, Irma Ryklin, Arshad Malik
  • Patent number: 5929023
    Abstract: The present invention relates to a cleaning composition containing at least one first surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, partially esterified ethoxylated glycerol surfactants, and alkyl polyglucoside surfactants and mixtures thereof and a second surfactant selected from the group consisting of sulfonamide, hydroxy sulfobetaine, betaines, amine oxides, glucoamides, N-C.sub.1-3 alkyl C.sub.8 -C.sub.16 alkyl glucoamide, and C.sub.5 -C.sub.12 N-alkyl aldoamide and mixtures thereof and water.
    Type: Grant
    Filed: May 8, 1997
    Date of Patent: July 27, 1999
    Assignee: Colgate Palmolive Company
    Inventors: Patrick Durbut, Guy Broze
  • Patent number: 5922662
    Abstract: A high foaming, light duty, liquid detergent with desirable cleansing properties and mildness to the human skin comprising: a water soluble nonionic surfactant at least one water soluble, foaming, anionic surfactant, a zwitterionic surfactant, an alkyl succinamate and the balance being water.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: July 13, 1999
    Assignee: Colgate Palmolive Company
    Inventor: Barbara Thomas
  • Patent number: 5922670
    Abstract: Dimer alcohol bis-sulfates, trimer alcohol tris-sulfates and ether sulfates thereof are prepared by reacting dimer alcohols, trimer alcohols, or alkylene oxide adducts thereof with a sulfating agent, and then neutralizing the reaction product with an aqueous base material.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: July 13, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Georg Knuebel, Alfred Westfechtel, Gerhard Hermanns, Rainer Hoffmann, Hans-Christian Raths
  • Patent number: 5912222
    Abstract: A liquid duty liquid microemulsion composition comprises a mixture of a magnesium salt of a sulfonate surfactant, an alkyl ether polyethenoxy sulfate, a biodegradable surfactant, a cosurfactant, a perfume or water insoluble hydrocarbon and water.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: June 15, 1999
    Assignee: Colgate Palmolive Company
    Inventors: Barbara Thomas, Ammanuel Mehreteab, Gilbert Gomes, Frank Bala, Jr., Jiashi Tarng
  • Patent number: 5900398
    Abstract: A process for making a surfactant product involving the steps of: (1) providing a solid water-free sugar surfactant; (2) providing a co-reactant selected from the group consisting of alpha-olefins, internal olefins, linear alkylbenzene, branched alkylbenzene, fatty alcohol, alkoxylated fatty alcohol, secondary alkanes, N-methylglucamide, tall oil, napthalene, xylene, cumene, toluene, dodecylbenzene and mixtures thereof; (3) dispersing or dissolving the solid water-free sugar surfactant in the co-reactant to form a feed mixture; and (4) sulfating/sulfonating the feed mixture to form a surfactant product.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: May 4, 1999
    Assignee: Henkel Corporation
    Inventors: Richard A. Winstanley, Harald P. Wulff
  • Patent number: 5895765
    Abstract: Disclosed is an improved method for the detection of an analyte in a fluid test sample using a strip of a negatively charged matrix material having a zone containing mobile, labeled binding partner for the analyte and a separate zone for capturing the labeled binding partner as it is carried through this zone by the fluid test sample. The improvement involves combining the fluid test sample with a polyalkoxylated amine surfactant to control non-specific binding of the labeled binding partner to the negatively charged matrix material.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: April 20, 1999
    Assignee: Bayer Corporation
    Inventors: Gary W. Rheinheimer, Meitak Teresa Yip
  • Patent number: 5888957
    Abstract: All purpose cleaning or microemulsion compositions more environmentally friendly, which is especially effective in the removal of a mixture of oil and kaolin soil, contains an analephotropic negatively charged complex, a hydrocarbon ingredient, a cosurfactant, and water.
    Type: Grant
    Filed: May 9, 1997
    Date of Patent: March 30, 1999
    Assignee: Colgate Palmolive Company
    Inventors: Patrick Durbut, Guy Broze
  • Patent number: 5856293
    Abstract: A light duty liquid detergent with desirable cleansing properties and mildness to the human skin comprising: two different sulfonate surfactant, an alkali metal or ammonium salt of a C.sub.8-18 ethoxylated alkyl ether sulfate anionic surfactant, a betaine surfactant, an alkyl polyglucoside surfactant, an ethoxylated C.sub.12 -C.sub.14 monoalkanol amide and water.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: January 5, 1999
    Assignee: Colgate Palmolive Company
    Inventors: Joan E. Gambogi, Philip A. Gorlin, Robert D'Ambrogio, Gary Jakubicki, Leonard Zyzyck
  • Patent number: 5854196
    Abstract: The present invention relates to detergent compositions comprising an anionic surfactant system. The anionic surfactant system comprises alkyl alkoxylated sulphate having specific ratios of mono-, di- and trialkoxylated sulphate. The anionic surfactant system provides improved oily and greasy soil removal over a wide temperature range.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: December 29, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Barry Thomas Ingram, Christian Leo Marie Vermote
  • Patent number: 5851976
    Abstract: An improvement is described in all purpose liquid cleaning compositions and microemulsion compositions which are especially effective in the removal of oily and greasy soil and containing an anionic surfactant, an amine oxide surfactant, an ethoxylated nonionic surfactant, a cosurfactant, a hydrocarbon ingredient, and water.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: December 22, 1998
    Assignee: Colgate Palmolive Company
    Inventor: Baudouin Mertens
  • Patent number: 5851974
    Abstract: A light duty liquid detergent with desirable cleansing properties and mildness to the human skin comprising: two different sulfonate surfactants, an alkali metal or ammonium salt of a C.sub.8-18 ethoxylated alkyl ether sulfate anionic surfactant, an alkyl polyglucoside surfactant, an alkanol amide or amine oxide and an antibacterial system comprising trichlorohydroxydiphenyl ether, a C.sub.1 -C.sub.3 alkanol and an alkali metal halide, and water.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: December 22, 1998
    Assignee: Colgate Palmolive Company
    Inventor: Sukhvinder Sandhu
  • Patent number: 5773395
    Abstract: An improvement is described in the microemulsion compositions which is especially effective in the removal of oily and greasy soil contains an anionic detergent, a saturated fatty acid, an unsaturated fatty acid, a solubilizing agent, a perfume having a pine like odor, an alkali metal hydroxide and water.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: June 30, 1998
    Assignee: Colgate-Palmolive Co.
    Inventors: Maria Jose Charlez, Abraham Cazes
  • Patent number: 5750482
    Abstract: A non-streaking glass cleaning composition comprising, on a weight basis, from about 0.1 to about 1% ethylene glycol monohexyl ether, from about 0.01 to about 0.5% of a surfactant selected from the group consisting of anionic surfactants, nonionic surfactants, amphoteric surfactants, zwitterionic surfactants and mixtures thereof, from about 0.1 to about 7% of an organic cosolvent comprising a mixture of (i) a low boiling point organic cosolvent having a boiling point of less than about 115.degree. C. and (ii) a high boiling point organic cosolvent having a boiling point of from 120.degree. to about 230.degree. C., from 0 to about 2% of a builder, and water, said composition having a pH of from about 3.5 to about 11.5, to provide a non-streaking glass cleaning formulation.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: May 12, 1998
    Assignee: S. C. Johnson & Son, Inc.
    Inventor: Gerald Cummings
  • Patent number: 5747435
    Abstract: Composition useful as 2-in-1 cleansing products are disclosed that are extremely mild to skin and hair, which use neutralized, essentially chargeless, ionic complexes of fatty amines and fatty acids to deliver various levels of conditioning; neutralized, essentially chargeless, ionic complexes of a detersive surfactant comprising a water soluble cationic surfactant and/or polymer complexed with one or more anionic surfactants; or an amphoteric surfactant complexed with one or more anionic surfactants; or a water soluble cationic surfactant and/or polymer complexed with one or more amphoteric surfactants; or a water soluble cationic surfactant and/or polymer complexed with one or more anionic surfactants and an amphoteric surfactant; detersive surfactant-soluble but water-insoluble silicones or derivatives thereof; and water. These products exhibit true 2-in- conditioning properties, and are lower in cost than current 2 in 1 products. Clear or opacified products can be formulated.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: May 5, 1998
    Assignee: Colgate-Palmolive Company
    Inventor: Amrit M. Patel
  • Patent number: 5741769
    Abstract: A liquid duty liquid microemulsion composition comprises a mixture of a secondary alkane sulfonate surfactant, an alkyl ether polyethenoxy sulfate surfactant, an anionic biodegradable surfactant, a cosurfactant, a perfume or water insoluble hydrocarbon and water.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: April 21, 1998
    Assignee: Colgate Palmolive Company
    Inventor: Rita Erilli
  • Patent number: 5736496
    Abstract: All purpose cleaning or microemulsion compositions more environmentally friendly, which is especially effective in the removal of a mixture of oil and kaolin soil, contains an analephotropic negatively charged complex, a hydrocarbon ingredient, a Lewis base, neutral polymer, a cosurfactant, and water.
    Type: Grant
    Filed: July 9, 1996
    Date of Patent: April 7, 1998
    Assignee: Colgate-Palmolive Co.
    Inventors: Patrick Durbut, Anne-Marie Misselyn, Guy Broze
  • Patent number: 5723434
    Abstract: Isotropic liquid detergent composition comprises specific soil antiredeposition polymers containing a hydrophilic backbone and monomer with hydrophobic side chains. When the molar ratio of the number hydrophilic groups to number of hydrophobic groups on said polymers is below certain critical levels, it has been unexpectedly found that the stability (i.e., clarity) of the composition remarkably increases. The solubility of the polymer is further dependent on the type and amount (minimum required) of hydrotrope; surfactant type and levels; and minimum electrolyte levels.
    Type: Grant
    Filed: January 25, 1996
    Date of Patent: March 3, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Nancy Ann Falk, Barbara Bory, Tamara Padron, Tirucherai Varahan Vasudevan, Diane Wolf, Jeanie Lum
  • Patent number: 5719117
    Abstract: Isotropic liquid detergent composition comprises specific soil antiredeposition polymers containing a hydrophilic backbone and hydrophobic side chain; and aliphatic hydrocarbon oils. When the molar ratio of hydrophilic groups of the backbone to number of hydrophobic groups attached to the backbone is below certain critical levels; and aliphatic hydrocarbon oil of defined molecular weight (MW) range are incorporated in the formulation; it has been unexpectedly found that the stability (i.e., clarity) of the composition remarkably increases in such oil containing compositions.
    Type: Grant
    Filed: January 25, 1996
    Date of Patent: February 17, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Nancy Ann Falk, Barbara Bory, Leslie Jo Morgan, Tamara Padron, Tirucherai Varahan Vasudevan, Diane Wolf
  • Patent number: 5707957
    Abstract: This invention relates to a liquid crystal composition comprising a water insoluble organic compound, an ethoxylated nonionic surfactant, an alkyl polyglucoside surfactant, an ethoxylated alkyl ether sulfate surfactant, a cosurfactant and water.
    Type: Grant
    Filed: March 6, 1996
    Date of Patent: January 13, 1998
    Assignee: Colgate-Palmolive Co.
    Inventors: Georges Yianakopoulos, Genevieve Blandiaux, Myriam Mondin
  • Patent number: 5703028
    Abstract: This invention relates to a liquid crystal composition comprising a water insoluble organic compound, a sulfonate surfactant, an abrasive, an ethoxylated alkyl ether sulfate surfactant, a cosurfactant and water.
    Type: Grant
    Filed: June 14, 1996
    Date of Patent: December 30, 1997
    Assignee: Colgate-Palmolive Co
    Inventors: Rita Erilli, Chantal Gallant, Regis Lysy
  • Patent number: 5700331
    Abstract: This invention relates to a cleaning composition comprising a water insoluble organic compound, an alkyl glucoside surfactant, an abrasive, a sulfonate surfactant, an ethoxylated alkyl ether sulfate surfactant, a polymeric thickener, a cosurfactant and water.
    Type: Grant
    Filed: June 14, 1996
    Date of Patent: December 23, 1997
    Assignee: Colgate-Palmolive Co.
    Inventors: Barbara Thomas, Karen Wisniewski