Sulfur Containing Anionically Substituted Surfactant Patents (Class 510/426)
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Patent number: 12054693Abstract: The invention meets the needs above by providing a surfactant system, mixture or blend that can be used as a part of a soaking composition. The surfactant system is capable of forming emulsions with, and thus removing, oily and greasy stains. In a preferred embodiment the surfactant compositions of the invention can remove non-trans fat and fatty acid stains. The invention involves foaming soaking compositions that have some or part of the anionic surfactant present in the same replaced with an extended chain anionic surfactant.Type: GrantFiled: April 25, 2023Date of Patent: August 6, 2024Assignee: ECOLAB USA INC.Inventors: Victor Fuk-Pong Man, Yvonne Marie Killeen, Derrick Richard Anderson
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Patent number: 11674111Abstract: The invention meets the needs above by providing a surfactant system, mixture or blend that can be used as a part of a soaking composition. The surfactant system is capable of forming emulsions with, and thus removing, oily and greasy stains. In a preferred embodiment the surfactant compositions of the invention can remove non-trans fat and fatty acid stains. The invention involves foaming soaking compositions that have some or part of the anionic surfactant present in the same replaced with an extended chain anionic surfactant.Type: GrantFiled: October 19, 2021Date of Patent: June 13, 2023Assignee: ECOLAB USA INC.Inventors: Victor Fuk-Pong Man, Yvonne Marie Killeen, Derrick Richard Anderson
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Patent number: 10407609Abstract: A lost-circulation material including a mixture of an aqueous colloidal dispersion and fatty acid. The aqueous colloidal dispersion includes silica nanoparticles and has a pH of at least 8. Combining the colloidal dispersion and the fatty acid initiates gelation of the lost-circulation material when the pH of the lost-circulation material is less than 8 and a temperature of the lost-circulation material is in a range of 5° C. to 300° C. Sealing an opening in a portion of a wellbore or a portion of a subterranean formation in which the wellbore is formed may include providing the aqueous colloidal dispersion and the fatty acid to the wellbore, mixing the colloidal dispersion and the fatty acid to yield the lost-circulation material, initiating gelation of the lost-circulation material, and solidifying the lost-circulation material in the wellbore to yield a set gel.Type: GrantFiled: May 2, 2017Date of Patent: September 10, 2019Assignee: Saudi Arabian Oil CompanyInventors: Rajendra Arunkumar Kalgaonkar, Vikrant Bhavanishankar Wagle, Abdullah Saleh Hussain Al-Yami, Ayman Mohammed Almohsin
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Patent number: 10370624Abstract: Described herein, are dishwashing paste compositions comprising: an abrasive; a pH modifying agent in an amount effective to provide a pH greater than 7; a structuring agent; and a source of polyvalent cations. Methods of making and using these compositions are also described.Type: GrantFiled: June 14, 2016Date of Patent: August 6, 2019Assignee: Colgate-Palmolive CompanyInventors: Santiago Salas, Joshua Gerardo Henderson Villalpando, Ammanuel Mehreteab, Lidia Venegas, Margarita Zapata, Arianis Riofrio, Mario Alejandro Herrera Lazo De La Vega
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Patent number: 10315988Abstract: Methods of making an alpha-olefin sulfonic dimer acid (AOS dimer acid) are disclosed. In one method, an alpha-olefin is sulfonated, preferably with sulfur trioxide, to produce a mixture comprising an alpha-olefin sulfonic acid (AOS acid) and sulfur dioxide. This mixture is then heated while purging sulfur dioxide and hydrogen sulfide from the reactor to produce an AOS dimer acid composition. In another method, the AOS acid mixture is treated to remove sulfur dioxide and is then heated to produce an AOS dimer acid composition. With either method, the resulting AOS dimer acid composition has at least a 30% decrease in the level of elemental sulfur when compared with that of an AOS dimer acid composition prepared by a similar process in the absence of any active removal of sulfur dioxide or hydrogen sulfide. AOS dimer acid compositions and salts of the AOS dimer acids, which are useful surfactants for oilfield and other applications, are also disclosed.Type: GrantFiled: July 28, 2016Date of Patent: June 11, 2019Assignee: STEPAN COMPANYInventors: Gregory P. Dado, Aaron Sanders, Xue Min Dong, E. Carolina Rojas
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Patent number: 9738856Abstract: The disclosure relates to a silica-based structurant and methods of making such a structurant. According to one embodiment, the structurant may include 55 wt % to 90 wt % of a silica having a [Na2O]/[SiO2] molar ratio of from 0.02 to 0.14 and at least 15 wt % of an adjunct salt. The structurant may have a hydrated particle size distribution such that no more than 30 wt % of the structurant has a hydrated particle size greater than 45 micrometers according to the Structurant Residue Test. The structurant may also have a tapped bulk density of from 200 g/L to 300 g/L. Methods of making the structurant include combining starting materials with a non-stoichiometric amount of acid, then drying the reaction mixture without first washing any silica-based particles to produce a silica-based structurant with adjunct salt.Type: GrantFiled: March 5, 2015Date of Patent: August 22, 2017Assignee: PABEN PROYECTOS ESTRATEGICOS, S.A. DE C.V.Inventor: Enrique Hernandez
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Patent number: 9610619Abstract: A method and system for cleaning a secure instrument, such as a banknote, including a substrate, visual data and a security feature, including exposing the secure instrument to a supercritical fluid at a temperature and a pressure and for a duration sufficient to clean the substrate and not compromise the security feature and the visual data, wherein to clean the substrate includes to remove one or more substances from the substrate into the supercritical fluid. The substances removed from the substrate may include contaminants, dirt, sebum and pathogens.Type: GrantFiled: February 20, 2015Date of Patent: April 4, 2017Assignee: Spectra Systems CorporationInventor: Nabil M. Lawandy
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Patent number: 9550964Abstract: This disclosure relates to detergent compositions containing pyridinol-N-oxide compounds and being substantially free of bleach. Methods for treating a stained fabric using such detergent compositions are also disclosed.Type: GrantFiled: August 20, 2014Date of Patent: January 24, 2017Assignee: The Procter & Gamble CompanyInventors: Gregory Scot Miracle, Bruce Prentiss Murch, Patrick Christopher Stenger, Charles Allen Pettigrew, Jr., Justin Angelo Caserta, Casey Patrick Kelly
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Patent number: 9034813Abstract: The invention meets the needs above by providing a surfactant system, mixture or blend that can be used as a part of a soaking composition. The surfactant system is capable of forming emulsions with, and thus removing, oily and greasy stains. In a preferred embodiment the surfactant compositions of the invention can remove non-trans fat and fatty acid stains. The invention involves foaming soaking compositions that have some or part of the anionic surfactant present in the same replaced with an extended chain anionic surfactant.Type: GrantFiled: June 27, 2014Date of Patent: May 19, 2015Assignee: ECOLAB USA INC.Inventors: Victor Fuk-Pong Man, Yvonne Marie Killeen, Derrick Richard Anderson
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Publication number: 20150119313Abstract: A liquid solution for polishing has been discovered which is particularly effective on smooth, solid surfaces. The solution may be embodied as a concentrate that is dissolved in water, which consist of, by volume at room temperature, 9.375 percent wax enhancer, 0.782 percent polydimethlsiloxanne solution, 15.625 percent methanol-propylene glycol, 0.132 percent anionic surfactant, and 70.31 percent water. Various ranges of concentrations for the composition components have been discovered, and the concentration ranges featuring various advantages and disadvantages are disclosed herein. The composition may be applied to various surfaces to be polished in a number of ways as disclosed herein.Type: ApplicationFiled: October 31, 2014Publication date: April 30, 2015Inventor: Michael Connelly
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Patent number: 9018150Abstract: Disclosed is a cleansing composition containing from about 6% to about 20% of at least one nonionic surfactant; from about 3% to about 10% of at least one amphoteric surfactant; from about 2% to about 8% of at least one anionic surfactant; and from about 0.1% to about 5% of at least one cationic conditioning surfactant, cationic conditioning amine, or a mixture thereof; wherein the amount of nonionic surfactant present in the final composition is greater than the amount of the amphoteric surfactant, and the ratio of the nonionic surfactant (a) to anionic surfactant (c) is at least about 1.9 as much as the anionic surfactant, based on the weight percent of each surfactant in the final composition.Type: GrantFiled: December 9, 2013Date of Patent: April 28, 2015Assignee: L'OrealInventor: Kirolos Rizk
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Patent number: 9018145Abstract: A new general purpose foaming agent having application as drilling fluid foaming agents or as any foaming agent needed an a wide variety of applications is disclosed, where the agent includes at least one anionic surfactant, at least one cationic surfactant, and mixtures thereof and one or more zwitterionic compounds. A method for using the foaming agent in capillary coiled tubing application is also disclosed. The foaming agents can also include additive to augment the properties of the foaming agent for a given application.Type: GrantFiled: December 23, 2003Date of Patent: April 28, 2015Assignee: Lubrizol Oilfield Solutions, Inc.Inventors: Larry W. Gatlin, Garth Shewchuk, Colby P. Rodriguez
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Patent number: 9006162Abstract: The present invention is directed to a cleansing composition containing: (a) from about 6% to about 20% of at least one nonionic surfactant; (b) from about to about 10% of at least one amphoteric surfactant; (c) from about 2% to about 8% of at least one anionic surfactant; and (d) from about 0.01% to about 5% of at least one cationic conditioning polymer; wherein the amount of nonionic surfactant (a) present in the final composition is greater than the amount of the amphoteric surfactant (b), and the ratio of nonionic surfactant (a) to anionic surfactant (c) is at least 1.9, based on the weight percent of each surfactant in the final composition.Type: GrantFiled: December 9, 2013Date of Patent: April 14, 2015Assignee: L'OrealInventor: Kirolos Rizk
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Patent number: 8999910Abstract: An industrial cleaning composition comprises (a) from 5 to 50% by volume of an anionic surfactant having a log10P value in the range 5 to 7, (b) from 5 to 50% by volume of a first non-ionic surfactant having a log10P value in the range 0.1 to 3 and having the general formula, R?-(A0)n-OH wherein R? is C9 to C20 alkyl, each AO unit is either —OCH2CH2— or—OCH2CH(CH3)—; the molar ratio [—OCH2CH(CH3)—]/[—OCH2CH2—] is in the range up to 8 and n is greater than 6 and (c) from 5 to 50% by weight of a second non-ionic surfactant having a log10P value in the range 0.1 to 3 having the general formula, R?—(OCH2CH2)n—OH wherein R? is C9 to C20 alkyl, and n is less than 6, each of said volume percentages being with respect to the total volume of (a), (b) and (c). Corresponding cleaners derived therefrom by water dilution are also disclosed.Type: GrantFiled: August 6, 2014Date of Patent: April 7, 2015Assignee: OTI Greentech Group AGInventors: Jawahar Wakhloo, Alan Keasey, Caroline Kelly
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Patent number: 8993502Abstract: A composition for treating a hard surface. The composition has: (a) at least one adhesion promoter; (b) at least one surfactant selected from the group consisting of: anionic, non-ionic, cationic, amphoteric, zwitterionic, and combinations thereof; (c) mineral oil; (d) a blend of linear primary alcohols, wherein each alcohol of said blend includes a carbon chain containing 9 to 17 carbons or an ethoxylated blend thereof; (e) water; (f) optionally, at least one solvent; and wherein the composition is self-adhering upon application to a surface to be treated, and wherein the composition provides a wet film to said surface when water passes over said composition and surface.Type: GrantFiled: January 20, 2012Date of Patent: March 31, 2015Assignee: S. C. Johnson & Son, Inc.Inventors: Michael E. Klinkhammer, Russell B. Wortley, Thomas A. Strash
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Patent number: 8987183Abstract: The present invention relates to the use of (oxidized) thioethers of polyalkylene oxides in washing and cleaning compositions, especially in dishwashing compositions, and to washing and cleaning compositions, especially dishwashing compositions, which comprise (oxidized) thioethers of alcohol alkoxylates. These (oxidized) thioethers are especially suitable as surfactants with rinse aid function (rinse aid surfactants). “Oxidized” relates to the sulfur atom in the thioether, which may be present in oxidized form as sulfoxide (SO) or sulfonyl (SO2). The invention also relates to particular oxidized thioethers of polyalkylene oxides.Type: GrantFiled: January 13, 2012Date of Patent: March 24, 2015Assignee: BASF SEInventors: Sophie Maitro-Vogel, Jürgen Tropsch, Wolfgang Spiegler, Roman Benedikt Raether
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Patent number: 8987179Abstract: The invention relates to compositions containing a) 45 to 65 wt. % of one or more secondary paraffin sulfonates with 8 to 22 carbon atoms, b) 1 to 10 wt. % of one or more alcohol alkoxylates which are produced from the reaction of alcohols R—OH, wherein R is an alkyl group with 4 to 8 carbon atoms, with alkoxylating agents selected from ethylene oxide, propylene oxide, or mixtures thereof and which contain on average 1 to 10 mol of structural units derived from the alkoxylating agents per 1 mol of structural units derived from the alcohols, and c) 25 to 52 wt. % water, in relation to the total weight of the composition in each case. The compositions can be used in an advantageous manner for producing washing and cleaning agents.Type: GrantFiled: December 15, 2011Date of Patent: March 24, 2015Assignee: Weylchem Switzerland AGInventors: Johannes Himmrich, Wolfgang Walther
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Patent number: 8980813Abstract: A composition for treating a hard surface. The composition has: (a) at least one adhesion promoter; (b) at least one surfactant selected from the group consisting of: anionic, non-ionic, cationic, amphoteric, zwitterionic, and combinations thereof; (c) mineral oil; (d) water; (e) optionally, at least one solvent; and wherein the composition is self-adhering upon application to a surface to be treated, and wherein the composition provides a wet film to said surface when water passes over said composition and surface.Type: GrantFiled: January 20, 2012Date of Patent: March 17, 2015Assignee: S. C. Johnson & Son, Inc.Inventors: Michael E. Klinkhammer, Thomas A. Strash, John R. Wietfeldt, Russell B. Wortley
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Publication number: 20150072914Abstract: In a process of making a liquid cleaning composition, adding a gel breaker upstream of an anionic surfactant addition in the recirculatory loop of a recirculatory batch processor mitigates the viscous hexagonal phase whilst providing maximum flexibility in formulating various ingredients in the composition.Type: ApplicationFiled: August 18, 2014Publication date: March 12, 2015Inventors: Chong GU, Vincenzo GUIDA, Geoffrey Marc WISE, Wei DAI, Bernie George DURHAM, Boon HO NG, Fang HU
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Patent number: 8968482Abstract: The need for a method for hand washing dishes by direct application of an easily pourable liquid detergent composition, that delivers great grease cleaning with an excellent sudsing profile, is met by a liquid hand dishwashing detergent composition comprising small amounts of a branched alkoxylated nonionic surfactant.Type: GrantFiled: August 16, 2011Date of Patent: March 3, 2015Assignee: The Procter & Gamble CompanyInventors: Karl Ghislain Braeckman, Ikram El Idrissi, Ashmita Randhawa, Gang Si
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Publication number: 20150057214Abstract: A method for preparing a microemulsion is disclosed which employs a method based upon identification of the phase behavior of a plurality of components comprising the microemulsion. Further disclosed is a microemulsion composition comprising a first component, coupling agent, and surfactant.Type: ApplicationFiled: January 9, 2013Publication date: February 26, 2015Applicant: INVISTA North America S.a.r.l.Inventor: RICHARD P. BEATTY
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Patent number: 8961700Abstract: Disclosed are aqueous, concentrated dilutable liquid cleaning compositions comprising one or more anionic surfactants, one or more non-ionic surfactants, and an electrolyte, preferably in combination with one or more amphoteric surfactants, having a total active matter higher than 45 wt % based on the sum of the surfactants above that exhibit a controllable viscosity profile that is satisfactory to the consumer while being easy to dilute, providing fast enough a diluted, a medium diluted or a highly diluted cleaning composition.Type: GrantFiled: May 22, 2013Date of Patent: February 24, 2015Assignee: KAO Corporation S.A.Inventors: Elisabet Moragas Arjant, Blanca Nogues Lopez
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Patent number: 8940104Abstract: A cleaning composition for removing temporary wafer bonding material is provided. The cleaning composition comprises an alkylarylsulfonic acid and an aliphatic alcohol dispersed or dissolved in a hydrocarbon solvent system. Methods of separating bonded substrates and cleaning debonded substrates using the cleaning composition are also provided. The invention is particularly useful for temporary bonding materials and adhesives. The methods generally comprise contacting the bonding material with the cleaning solution for time periods sufficient to dissolve the desired amount of bonding material for separation and/or cleaning of the substrates.Type: GrantFiled: August 2, 2011Date of Patent: January 27, 2015Assignee: Brewer Science Inc.Inventors: Xing-Fu Zhong, John Moore
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Patent number: 8940673Abstract: The present invention provides a skin cleansing composition comprising the following components (A), (B), and (C): (A) (a1) an alkenylsulfonic acid having 12 to 22 carbon atoms or its salt, (a2) an alkylsulfonic acid having 12 to 22 carbon atoms or its salt, or a mixture of them, (B) an alkyl ether carboxylic acid represented by the following formula (1) or its salt: R1—O—(CH2CH2O)n—CH2—COOX??(1) wherein R1 represents an alkyl group having 4 to 22 carbon atoms, n denotes a number from 0 to 20, X represents a hydrogen atom, an alkali metal, an alkali earth metal, ammonium, or organic ammonium, and n denotes a number of 0.5 or more and less than 4 on average; and (C) water.Type: GrantFiled: December 26, 2012Date of Patent: January 27, 2015Assignee: Kao CorporationInventors: Mayuko Hirahara, Koji Endo, Kenji Kaneda, Masahiro Miyaki
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Patent number: 8933009Abstract: The present invention relates to the field of membrane separation processes and clean in place compositions for cleaning such membranes. The cleaning compositions can remove proteins, fats, and other food, beverage, and brewery based soils and offer an environmentally friendly alternative surfactant system to NPE. According to the invention, surfactants and polymers useful for this process are unpredictable and specific surfactants, polymers, and combinations of the same are disclosed for use alone, as part of a cleaning composition. Methods of use of the same are also included.Type: GrantFiled: March 12, 2013Date of Patent: January 13, 2015Assignee: Ecolab USA Inc.Inventors: Paul Schacht, Jeffrey Weilage, Eric Schmidt, Joseph P. Curran, Ralf Krack, Victor Fuk-Pong Man, Charles Allen Hodge
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Patent number: 8927479Abstract: An aqueous aerosol bathroom cleaner includes a surfactant, a water-soluble or dispersible organic solvent, a chelating agent and a propellant that comprises n-butane. Comparative data demonstrate that the presence of n-butane in the composition enhances the rate of bathroom soap scum removal relative to aerosol compositions that do not contain n-butane in the propellant. The amount of surfactant present is sufficient so that the composition develops a stable foam upon being dispensed onto a soiled bathroom hard surface. The foam collapses after 10 to 60 seconds to deliver the cleaning components onto the surface.Type: GrantFiled: August 30, 2012Date of Patent: January 6, 2015Assignee: The Clorox CompanyInventor: Kristina Perlas
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Patent number: 8921297Abstract: The need for a liquid hand dishwashing detergent composition, having excellent low temperature stability and delivering good cleaning and long-lasting suds, is met by incorporating a branched, alkoxylated nonionic surfactant, in combination with ethoxylated anionic surfactants having little or no branching, into the composition. Surprisingly, such a combination also provides an excellent sudsing profile during direct application dishwashing methods.Type: GrantFiled: August 16, 2011Date of Patent: December 30, 2014Assignee: The Procter & Gamble CompanyInventors: Karl Ghislain Braeckman, Roel Krols, Jean-Luc Philippe Bettiol
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Patent number: 8921302Abstract: Provided is an aqueous hair cleansing composition, including the following components (A) to (D) and water, in which the aqueous hair cleansing composition has a pH of from 2 to 5 when diluted 20-fold: (A) an anionic surfactant; (B) a cationized hydroxypropyl cellulose having a main chain derived from an anhydroglucose, and having a degree of substitution with cationized ethyleneoxy groups of from 0.01 to 2.9 and a degree of substitution with propyleneoxy groups of from 0.1 to 4.0; (C) an organic solvent selected from (C1) and (C2): (Cl) an aromatic alcohol; and (C2) a polypropylene glycol having a molecular weight of from 200 to 1,000; and (D) a hydroxy monocarboxylic acid or a dicarboxylic acid.Type: GrantFiled: May 1, 2012Date of Patent: December 30, 2014Assignee: Kao CorporationInventors: Hiroki Mizushima, Azusa Kasuga, Eiji Terada
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Patent number: 8901059Abstract: A hand dishwashing detergent composition comprising a chelant and branched surfactants to provide superior grease cleaning and shine.Type: GrantFiled: June 21, 2010Date of Patent: December 2, 2014Assignee: The Procter & Gamble CompanyInventors: Marc Francois Theophile Evers, Tania Patricia Maddox
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Patent number: 8901062Abstract: An oil-in-water emulsion comprising droplets of a molten hydrogenated castor oil, the droplets having a mean diameter of between 0.1 ?m and 4 ?m; and an anionic surfactant; and wherein the mean diameter is measured when the emulsion is at a temperature of between 85° C. and 95° C.Type: GrantFiled: August 13, 2013Date of Patent: December 2, 2014Assignee: The Procter & Gamble CompanyInventors: Niels De Meirleir, Walter August Maria Broeckx, Linda Pellens
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Patent number: 8895492Abstract: This application relates to a dilutable aqueous liquid cleaning composition, typically a dishwashing liquid, which comprises a plurality of surfactants, the surfactants including surfactant active components comprising from greater than 30% to up to 55% by weight, based on the weight of the composition, wherein the composition has a viscosity of 100 to 500 mPas as measured at 25° C., and the composition is dilutable with water to form a non-gelling diluted composition having up to six times the volume of the undiluted composition and a viscosity within the range of 100 to 1600 mPas as measured at 25° C. at any dilution up to the six times dilution.Type: GrantFiled: December 13, 2010Date of Patent: November 25, 2014Assignee: Colgate-Palmolive CompanyInventors: Jiashi Tarng, Joan Gambogi
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Patent number: 8883710Abstract: The present invention includes compositions comprising an active material having groups capable of covalent attachment to a substrate in the presence of an acid or a base, a photocatalyst capable of generating an acid or a base upon exposure to light, and a vehicle. Also included herein is a method for treating a substrate with these compositions. The method includes the steps of applying at least one active material having functional groups to the substrate, applying a photocatalyst to the substrate, and exposing the photocatalyst and the at least one active material to light for forming covalent attachments between the functional groups and constituent groups on the substrate. The compositions and methods described herein are useful in consumer care and personal care product applications.Type: GrantFiled: April 27, 2010Date of Patent: November 11, 2014Assignee: The Procter & Gamble CompanyInventors: Alan David Willey, Ellen Schmidt Baker, William Richard Mueller, Ioannis Constantine Constantinides
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Patent number: 8883700Abstract: The present invention relates to a method of manually cleaning dishware using a liquid hand dishwashing detergent composition comprising an anionic surfactant and a cationic polymer having a MW below or equal to 2,100,000; and a charge density above or equal to 0.45 meq/g, wherein such composition will have a coacervation index upon dilution of at least 2.5%; to provide skin care.Type: GrantFiled: March 2, 2012Date of Patent: November 11, 2014Assignee: The Procter & Gamble CompanyInventors: Eva Maria Perez-Prat Vineusa, Nathan Ray Whitely, Anna Asmanidou, Qing Chen, Robby Renilde François Keuleers, An Van Laere
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Patent number: 8877702Abstract: The present invention relates to the detergent composition, containing (a) a nonionic surfactant represented by the formula (1); and (b) a sulfuric acid ester salt represented by the formula (2): R—O-(EO)m—(PO)n-(EO)m?—H??(1) wherein, R represents a hydrocarbon group having 6 to 24 carbon atoms; EO represents an ethyleneoxy group; PO represents a propyleneoxy group; m=0.1 to 25; m?=0 to 24.9; m+m?=0.5 to 25; and n=0.1 to 10; with the proviso that (EO)m, (PO)n, and (EO)m? are arranged in a block addition mode in this order; R1—O—(PO)x-(EO)y—SO3M??(2) wherein, R1 represents a hydrocarbon group having 6 to 24 carbon atoms; x=0.1 to 10; y=0 to 30; (PO)x and (EO)y are arranged in any order in any addition mode, being a block addition or a random addition, M is a counter ion.Type: GrantFiled: July 14, 2010Date of Patent: November 4, 2014Assignee: Kao CorporationInventors: Masato Nomura, Katsuhisa Inoue, Hisato Fukuda
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Patent number: 8871704Abstract: An industrial cleaning composition is provided that includes: (a) from 5 to 50% by volume of an anionic surfactant having a log10P value in the range 5 to 7; (b) from 5 to 50% by volume of a first non-ionic surfactant having a log10P value in the range 0.1 to 3 and having the general formula, R?—(A0)n—OH, wherein R? is C9 to C20 alkyl, each AO unit is either —OCH2CH2— or —OCH2CH(CH3)—, the molar ratio [—OCH2CH(CH3)—]/[—OCH2CH2—] is in the range up to 8 and n is greater than 6; and (c) from 5 to 50% by volume of a second non-ionic surfactant having a log10P value in the range 0.1 to 3 having the general formula, R?—(OCH2CH2)n—OH wherein R? is C9 to C20 alkyl, and n is less than 6, each of said volume percentages being with respect to the total volume of (a), (b) and (c). Corresponding cleaners derived therefrom by water dilution are also disclosed.Type: GrantFiled: April 26, 2013Date of Patent: October 28, 2014Assignee: OTI Greentech Group AGInventors: Jawahar Wakhloo, Alan Keasey, Caroline Kelly
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Patent number: 8871700Abstract: The present invention relates to cleaning and disinfecting liquid detergent compositions and, in one embodiment, liquid hand dishwashing compositions, comprising a metal salt, preferably a divalent metal salt, preferably Zn2+-salt and linear alkyl nucleophilic surfactant, preferably a linear alkyl chain amine oxide. The present invention further relates to methods of disinfecting dishware and/or dishwashing implements and/or skin using such a liquid detergent compositions.Type: GrantFiled: May 24, 2013Date of Patent: October 28, 2014Assignee: The Procter & Gamble CompanyInventors: Jamila Tajmamet, Jean-Luc Philippe Bettiol, Robby Renilde Francois Keuleers
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Patent number: 8865636Abstract: An environmental safety paint stripping composition comprising dichloroethylene, aromatic alcohols and ethers, surfactants, corrosion inhibitors, thickeners, wax solvents and water. This paint stripping composition is particularly useful in stripping paint and other polymeric coatings from metal substrates such as aluminum and it alloys.Type: GrantFiled: January 18, 2013Date of Patent: October 21, 2014Assignee: The United States of America as represented by the Secretary of the NavyInventors: Young Han, Dane Hanson
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Patent number: 8853141Abstract: Sulfomethylsuccinates of the formula: wherein R is an alkyl, alkenyl, alkynyl, alkoxylated alkyl, cycloalkyl, cycloalkenyl, cycloalkynyl, branched alkyl, branched alkenyl, branched alkynyl, branched alkoxylated alkyl, aromatic, substituted alkyl aromatic, substituted alkenyl aromatic or substituted alkoxylated aromatic group; M is a cation, hydrogen, amine or ammonium salt or combinations thereof, and each M may be the same as or different from the other; and n is from 1 to about 6. Processes for synthesizing the sulfomethylsuccinates are also provided. The sulfomethylsuccinates can be used as surfactants, emulsifiers, skin feel agents, film formers, rheological modifiers, solvents, release agents, lubrication agents, conditioners, and dispersants, etc.Type: GrantFiled: November 3, 2010Date of Patent: October 7, 2014Assignee: Stepan CompanyInventors: Aaron Michael Brown, Xue Min Dong
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Patent number: 8845817Abstract: Provided herein is an aqueous, non-toxic, non-flammable, non-explosive, biodegradable, hypoallergenic cleaning composition. Also provided are pre-loaded wipes containing the cleaning solution, kits, and methods of cleaning surfaces using the same.Type: GrantFiled: June 5, 2013Date of Patent: September 30, 2014Assignee: Green Way LaboratoriesInventors: Thomas Bakehorn, Guy Roland Adams
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Patent number: 8801864Abstract: An aqueous composition is disclosed, comprising at least one strain of Class 1 Bacillus bacterial spores, selected from Bacillus Cirulans, Bacillus Megaterium, Bacillus Licheniformis, Bacillus Pumilus, Bacillus Sphaericus, Bacillus Subtilis sub species 10144 and Bacillus Subtilis sub species 8646, a terpene and one or more surfactants. The terpene is preferably d-limonene. A method for cleaning surfaces is also disclosed, which method comprises deploying an aqueous composition comprising at least one strain of Class 1 Bacillus bacterial spores, selected from Bacillus Cirulans, Bacillus Megaterium, Bacillus Lichenforms, Bacillus Pumilus, Bacillus Sphaericus, Bacillus Subtilis sub species 10144 and Bacillus Subtilis sub species 8646, a terpene and one or more surfactants to a surface.Type: GrantFiled: September 30, 2011Date of Patent: August 12, 2014Assignee: Cleveland Biotech LimitedInventor: Anthony Brooke
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Patent number: 8802613Abstract: The present invention is directed to a stabilized hydrogen peroxide solution containing stabilizers that maintain relatively high hydrogen peroxide stability in both concentrated form and when formulated into a cleaning solution that has a pH above 6 and contains components that normally would have a destabilizing effect on the hydrogen peroxide. The stabilizers include a first cyclic amino methane diphosphonic acid compound stabilizer in combination with a second phosphonic acid based stabilizer (different from the cyclic amino methane diphosphonic acid compound), wherein the weight ratio of the first stabilizer to the second stabilizer is at least about 2:1.Type: GrantFiled: December 13, 2007Date of Patent: August 12, 2014Assignee: Akzo Nobel N.V.Inventors: David J. Bonislawski, David C. Lovetro
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Patent number: 8802607Abstract: A composition comprising a) a surfactant comprising an anionic surfactant; b) at least 8 weight % of the composition of a C12-18 fatty alcohol, and c) water. A cleansing method includes applying the composition to skin or hair and washing, and optionally rinsing with water.Type: GrantFiled: December 9, 2010Date of Patent: August 12, 2014Assignee: Colgate-Palmolive CompanyInventors: Aixing Fan, Jeffrey Mastrull, Edward Simpson
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Patent number: 8785363Abstract: The invention discloses synergistic combinations of surfactants blends and cleaning composition. In certain embodiments a surfactant system is disclosed which includes extended anionic surfactants, linker surfactants, and a multiply charged cation component. This system forms emulsions with, and can remove greasy and oily stains, even those comprised of non-trans fats. In another embodiment anionic surfactants are combined with a solvent, and amine oxide to remove sunscreen stains. The compositions may be used alone, as a pre-spotter or other pre-treatment or as a part of a soft surface or hard surface cleaning composition.Type: GrantFiled: October 23, 2013Date of Patent: July 22, 2014Assignee: Ecolab USA Inc.Inventors: Victor Fuk-Pong Man, Michael Charles DeNoma, Yvonne Marie Killeen, Steven E. Lentsch
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Patent number: 8778861Abstract: An aqueous and liquid cleansing composition comprises a fatty acid soap, a salt of a lauryl ether sulfate surfactant that is present in an amount that is at least 50% of the weight of the fatty acid soap, a betaine surfactant that is present in an amount that is at least 23% of the weight of the fatty acid soap, and at least 0.05% by weight of the composition of triclocarban. The lauryl ether sulfate and betaine surfactant in the specified amount in relation to the fatty acid soap amount keep the triclocarban from precipitating out of the composition.Type: GrantFiled: May 27, 2011Date of Patent: July 15, 2014Assignee: Colgate-Palmolive CompanyInventors: Manying Shi, David Chang
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Patent number: 8778862Abstract: Concentrated liquid cleaning fluid compositions for hard surface cleaning which are particularly suited for storage and dispensing from water-dissolvable plastic pouches. In use the pouches are placed in water whereupon the plastic pouch dissolves allowing the concentrated composition to become diluted in the water to provide a cleaner. The concentrated cleaning composition has good stability and does not affect the plastic or rate of dissolution of the pouch, and allows use of a variety of colorants and fragrances with a base product formulation. The formulation includes a linear alkyl benzene sulfonic acid (LABSA), a nonionic ethoxylated alcohol surfactant, and an alkanol amine or alkyl amine capable of reacting with the LABSA so that the sulfonic group is added to the amine.Type: GrantFiled: May 22, 2012Date of Patent: July 15, 2014Assignee: S.C. Johnson & Son, Inc.Inventors: Pablo M. Hernandez, Sergio Reyes Salgado, Rahul Saxena
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Publication number: 20140194337Abstract: A method for preparing a microemulsion is disclosed which employs a method based upon identification of the phase behavior of a plurality of components comprising the microemulsion. Further disclosed is a microemulsion composition comprising a first component, coupling agent, and surfactant.Type: ApplicationFiled: January 9, 2013Publication date: July 10, 2014Applicant: INVISTA North America S.a.r.l.Inventor: RICHARD P. BEATTY
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Patent number: 8765655Abstract: This invention encompasses compositions of surfactant-based products containing anionic and nonionic sufactants, one or more sequestering agents, a glycol solvent for the preparation of liquid cleaning compositions. The surfactant-based product may be any type of cleaning product based on surfactants, which include a sequestering agent. Specifically, the invention relates to a cleaning composition with desirable cleansing properties possessing increased grease cutting.Type: GrantFiled: December 18, 2007Date of Patent: July 1, 2014Assignee: Colgate-Palmolive CompanyInventors: Georges Yianakopoulos, Patricia Pagnoul
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Patent number: 8765651Abstract: Method of cleansing hair comprising: (a) applying a composition to the hair; (b) dissolving and lathering the composition using a water-based solvent; (c) rinsing the hair with a water-based solvent; wherein during the rinsing a total of about 100 gram to about 300 gram of water-based solvent per gram of hair (dry weight) is employed; wherein the composition comprises from about 3 wt % to about 35 wt % of a mixture of at least two compounds of Formula I.Type: GrantFiled: July 14, 2011Date of Patent: July 1, 2014Assignee: The Procter & Gamble CompanyInventors: Howard David Hutton, III, Jeffrey John Scheibel, David Johnathan Kitko, Jun Xu, Charles Winston Saunders, Kenneth Nathan Price, Stephanie Ann Urbin, Phillip Richard Green
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Patent number: 8759276Abstract: The invention involves foam stabilization compositions that rely upon an electrostatic charge interaction. According to the invention, the positively charged class of polymers such as polyethyleneimine (PEI) polymers are used to provide a long range electrostatic interaction with detersive anionic or amphoteric surfactants present in the same. The interaction must be of sufficient character so that the components do not precipitate out, instead causing longer lasting and increased foam production. The system provides an environmentally friendly alternative for traditional foaming enhancers such as cocamide DEA.Type: GrantFiled: March 8, 2013Date of Patent: June 24, 2014Assignee: Ecolab USA Inc.Inventors: Victor Fuk-Pong Man, Yvonne Marie Killeen
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Patent number: 8759271Abstract: A liquid detergent composition having a modified polyethyleneimine polymer and a surfactant to provide improved shine on hard surfaces.Type: GrantFiled: May 11, 2012Date of Patent: June 24, 2014Assignee: The Procter & Gamble CompanyInventors: Stefano Scialla, Frank Hulskotter, Gloria DiCapua, Patrick Firmin August Delplancke, Marc François Theophile Evers, Rainer (Anton) Dobrawa, Sophia Ebert