Sulfonic Acid Or Sulfate Monoester Substituent In The Component, Or Salt Thereof Patents (Class 510/495)
  • Patent number: 11946020
    Abstract: The need for a spray application of detersive compositions comprising perfume and low levels of surfactant, which provides more even coverage of the surface to be treated, while limiting nose and throat irritation is met by limiting the spray droplet size, such that the spray droplets have a particle size distribution such that the Dv10 is greater than about 40 microns.
    Type: Grant
    Filed: September 12, 2022
    Date of Patent: April 2, 2024
    Assignee: The Procter & Gamble Company
    Inventors: Deepak Ahirwal, Paulus Antonius Augustinus Hoefte, Cindy Jean, Cedric Joseph Volont
  • Patent number: 11939554
    Abstract: The need for a light duty maintenance cleaning spray for hard surfaces, which result in less over-spray during application, especially when using spray applicators which provide large coverage angles, and provides more uniform coverage, especially on inclined surfaces, is met when the spray composition is formulated with low surfactant levels and thickener, and is applied as spray droplets having the desired particle size.
    Type: Grant
    Filed: August 2, 2022
    Date of Patent: March 26, 2024
    Assignee: The Procter & Gamble Company
    Inventors: Deepak Ahirwal, Christophe Matthias Guillaumin, Paulus Antonius Augustinus Hoefte, James Robert Tinlin
  • Patent number: 11844864
    Abstract: A method for preparing granules. A slurry containing solid API powder particles dispersed in a liquid is prepared. The slurry is fed to a granulator and mixed with a dry base powder within the granulator in order to produce a slurry/base powder mixture. The slurry/base powder mixture produced within the granulator is dried in order to obtain granules containing the solid API particles and the base powder.
    Type: Grant
    Filed: August 30, 2018
    Date of Patent: December 19, 2023
    Assignee: Novartis AG
    Inventors: Markus Krumme, Hans De Waard, Klaus-Peter Moll, Adrian Schmidt, Julien Taillemite
  • Patent number: 11833237
    Abstract: The present invention is directed to a method of making a personal care composition comprising the following steps: combine a particulate scalp active with an anionic polymer to form a mixture (a); combine the mixture (a) with a cationic polymer having a charge density of 3 to 10 meq/gram to form a mixture (b); combine mixture (b) into a personal care composition base.
    Type: Grant
    Filed: March 9, 2021
    Date of Patent: December 5, 2023
    Assignee: The Procter & Gamble Company
    Inventor: Geoffrey Marc Wise
  • Patent number: 11505766
    Abstract: Stable and clear liquid laundry detergent compositions having a DADMAC Acrylic Acid co-polymer, a surfactant system including alcohol ethoxysulfate anionic surfactant (AES) and at least one of a linear alkyl benzene sulfonic acid anionic surfactant (LAS) and a non-ionic surfactant (NI), and an aqueous carrier. In one embodiment, the aqueous composition includes water in an amount of 30% to 80% by weight, a surfactant system in an amount of 8% to 35% by weight, and DADMAC Acrylic Acid co-polymer. The surfactant system may include: (1) at least about 40 wt % alcohol ethoxylsulfate (AES), and (2) a linear alkylbenzene sulfonate (LAS) and/or a non-ionic surfactant. The liquid compositions have a turbidity less than 50 NTUs.
    Type: Grant
    Filed: December 15, 2020
    Date of Patent: November 22, 2022
    Inventor: Daniel Thomas Piorkowski
  • Patent number: 11434453
    Abstract: The need for a light duty maintenance cleaning spray for hard surfaces, which result in less over-spray during application, especially when using spray applicators which provide large coverage angles, and provides more uniform coverage, especially on inclined surfaces, is met when the spray composition is formulated with low surfactant levels and thickener, and is applied as spray droplets having the desired particle size.
    Type: Grant
    Filed: May 16, 2019
    Date of Patent: September 6, 2022
    Assignee: The Procter & Gamble Company
    Inventors: Deepak Ahirwal, Christophe Matthias Guillaumin, Paulus Antonius Augustinus Hoefte, James Robert Tinlin
  • Patent number: 11142729
    Abstract: Detergents useful for cold-water cleaning and mid-chain headgroup and alkylene-bridged surfactants useful therein are disclosed. The mid-chain headgroup surfactant has a C14-C30 alkyl chain and a polar group bonded to a central zone carbon of the alkyl chain. The alkylene-bridged surfactant has a C12-C18 alkyl chain, a polar group, and a C1-C2 alkylene group bonded to the polar group and a central zone carbon of the C12-C18 alkyl chain. Preferred surfactants in these classes are alcohol sulfates, alcohol ethoxylates, ether sulfates, sulfonates, arylsulfonates, alcohol phosphates, amine oxides, quaterniums, betaines, and sulfobetaines. Surprisingly, detergents formulated with the surfactants provide outstanding cold-water performance in removing greasy stains such as bacon grease, butter, cooked beef fat, or beef tallow from soiled articles.
    Type: Grant
    Filed: August 9, 2019
    Date of Patent: October 12, 2021
    Assignee: STEPAN COMPANY
    Inventors: Brian Holland, Randal J. Bernhardt, Branko Sajic, Rick Tabor
  • Patent number: 9994497
    Abstract: The present invention relates generally to methods for producing renewable detergent compounds. More specifically, the invention relates to methods for producing detergent intermediates, including bio-linear alkylbenzene (LAB), bio-alcohols, and long chain bio-paraffins, from natural oils.
    Type: Grant
    Filed: February 24, 2015
    Date of Patent: June 12, 2018
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey John Scheibel, Scott Leroy Cron, Stephen Anthony DeRose, Ryan Michael West, Phillip Kyle Vinson, Thomas Earl Williams, Kevin Lee Garber, Praveen Kumar Depa
  • Patent number: 9969661
    Abstract: Disclosed are a method of preparing conjugated diene and a device therefor. More particularly, disclosed a method of preparing conjugated diene, wherein generated gas including butadiene is cooled and then water discharged at a lower part is not directly treated as waste water and subjected to byproduct removal and steam-extraction to utilize converted steam, and an installation issue of an existing biological waste water disposal equipment due to an excessive amount of byproducts can be resolved, and a device therefor are disclosed.
    Type: Grant
    Filed: October 20, 2015
    Date of Patent: May 15, 2018
    Assignee: LG CHEM, LTD.
    Inventors: Sang Jin Han, Jun Han Kang, Dong Hyun Ko, Hyun Seok Nam, Joo Hyuck Lee, Jun Kyu Han, Myung Ji Suh, Kyong Yong Cha, Dae Heung Choi, Ye Seul Hwang
  • Patent number: 9751905
    Abstract: A surfactant and a surfactant formulation comprising at least one ionic surfactant of the general formula R1—O-(D)n-(B)m-(A)l-XY?M+ where R1 is a linear or branched, saturated or unsaturated, aliphatic and/or aromatic hydrocarbon radical having 8 to 30 carbon atoms, A is ethyleneoxy, B is propyleneoxy, and D is butyleneoxy, l is from 0 to 99, m is from 0 to 99 and n is from 1 to 99, X is an alkyl or alkylene group having 0 to 10 carbon atoms, M+ is a cation, and Y? is selected from the group of sulfate groups, sulfonate groups, carboxylate groups and phosphate groups.
    Type: Grant
    Filed: November 15, 2013
    Date of Patent: September 5, 2017
    Assignee: BASF SE
    Inventors: Christian Bittner, Günter Oetter, Jack Tinsley, Christian Spindler, Gabriela Alvarez-Juergenson, Sophie Vogel
  • Patent number: 9598359
    Abstract: Sulfonate compositions are disclosed. The compositions include alkanesulfonates, alkenesulfonates, sultones, and hydroxy-substituted alkanesulfonates. The sulfonates comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a sulfonating or sulfitating agent. In one aspect, the sulfonate composition is a sulfo-estolide made by reacting a metathesis-derived C10-C17 monounsaturated acid or octadecene-1,18-dioic acid with a sulfonating agent, optionally in the presence of a saturated fatty acid. The sulfonates are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), paint additives, antimicrobial compositions, agricultural uses, and oil field applications.
    Type: Grant
    Filed: October 25, 2011
    Date of Patent: March 21, 2017
    Assignee: Stepan Company
    Inventors: Dave R. Allen, Randal J. Bernhardt, Aaron Brown, Gary Luebke, Renee Luka, Andrew D. Malec, Ronald A. Masters, Patti Skelton, Brian Sook, Jeremy Aaron Weitgenant, Patrick Shane Wolfe
  • Patent number: 9011610
    Abstract: The present invention is a solid rinse aid composition and methods of making and using the same. Applicants have surprisingly found that the crystal modifier sodium xylene sulfonate (short chain alkyl benzene or alkyl naphthalene sulfonates) at higher percentage can act as a solidification agent. The solid rinse aid composition generally includes an short chain alkyl benzene or alkyl naphthalene sulfonates solidification agent and an effective amount of a surfactant which can include a sheeting agent component, defoamer component and/or association disruption agent. The solid rinse aid composition may be phosphate-free, aminocarboxylate-free, and GRAS if desired.
    Type: Grant
    Filed: June 22, 2012
    Date of Patent: April 21, 2015
    Assignee: Ecolab USA Inc.
    Inventors: Janel Marie Kieffer, Victor Fuk-Pong Man, Melissa Hunter
  • Patent number: 8987179
    Abstract: The invention relates to compositions containing a) 45 to 65 wt. % of one or more secondary paraffin sulfonates with 8 to 22 carbon atoms, b) 1 to 10 wt. % of one or more alcohol alkoxylates which are produced from the reaction of alcohols R—OH, wherein R is an alkyl group with 4 to 8 carbon atoms, with alkoxylating agents selected from ethylene oxide, propylene oxide, or mixtures thereof and which contain on average 1 to 10 mol of structural units derived from the alkoxylating agents per 1 mol of structural units derived from the alcohols, and c) 25 to 52 wt. % water, in relation to the total weight of the composition in each case. The compositions can be used in an advantageous manner for producing washing and cleaning agents.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: March 24, 2015
    Assignee: Weylchem Switzerland AG
    Inventors: Johannes Himmrich, Wolfgang Walther
  • Publication number: 20150072916
    Abstract: The production of linear alkylbenzene from a natural oil is provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. The paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product.
    Type: Application
    Filed: June 6, 2014
    Publication date: March 12, 2015
    Applicant: UOP LLC
    Inventors: Stanley J. Frey, Daniel L. Ellig, Andrea G. Bozzano, Geoffrey W. Fichtl, Debarshi Majumder
  • Patent number: 8940104
    Abstract: A cleaning composition for removing temporary wafer bonding material is provided. The cleaning composition comprises an alkylarylsulfonic acid and an aliphatic alcohol dispersed or dissolved in a hydrocarbon solvent system. Methods of separating bonded substrates and cleaning debonded substrates using the cleaning composition are also provided. The invention is particularly useful for temporary bonding materials and adhesives. The methods generally comprise contacting the bonding material with the cleaning solution for time periods sufficient to dissolve the desired amount of bonding material for separation and/or cleaning of the substrates.
    Type: Grant
    Filed: August 2, 2011
    Date of Patent: January 27, 2015
    Assignee: Brewer Science Inc.
    Inventors: Xing-Fu Zhong, John Moore
  • Patent number: 8940679
    Abstract: The present invention relates to compositions for deodorizing and cleaning, in particular solid compositions in the form of effervescent tablets which can be reconstituted in water to obtain solutions for cleaning and deodorizing. The compositions comprise one or more Bacillus subtilis strain(s), one or more surfactant(s), one or more fragrance(s), one or more descaling agent(s), and one or more effervescent agent(s). The invention further relates to a kit comprising such tablets, as well as methods for obtaining cleaning and deodorizing tablets and solutions and their use for cleaning and deodorizing.
    Type: Grant
    Filed: January 25, 2013
    Date of Patent: January 27, 2015
    Assignee: Pollets S.A.
    Inventor: Abdelhamid Jabrane
  • Patent number: 8921299
    Abstract: This disclosure relates to detergent compositions containing tiron, a ligand capable of binding iron, an iron-displacing species, and iron. Methods for altering the color in a tiron-containing detergent composition are also disclosed.
    Type: Grant
    Filed: July 25, 2012
    Date of Patent: December 30, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Gregory Scot Miracle, Patrick Christopher Stenger, Jean-Pol Boutique
  • Publication number: 20140364355
    Abstract: A linear alkyl benzene product and production of linear alkylbenzene from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. The paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product.
    Type: Application
    Filed: June 6, 2014
    Publication date: December 11, 2014
    Inventors: Stanley J. Frey, Daniel L. Ellig, Andrea G. Bozzano, Geoffrey W. Fichtl, Debarshi Majumder
  • Patent number: 8901065
    Abstract: The present invention is to a process for preparing a spray-dried detergent powder comprising: (a) forming an aqueous detergent slurry in a mixer; (b) transferring the aqueous detergent slurry from the mixer to a pipe leading through a first pump and then through a second pump to a spray nozzle; (c) contacting a liquid detergent ingredient having a viscosity of less than 2 Pa·s to the aqueous detergent slurry in the pipe after the first pump and before the second pump to form a mixture; (d) spraying the mixture through the spray nozzle into a spray-drying tower; and (e) spray-drying the mixture to form a spray-dried powder, wherein a nitrogen-rich gas is introduced between the first and second pumps.
    Type: Grant
    Filed: February 20, 2013
    Date of Patent: December 2, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Hossam Hassan Tantawy, Larry Savio Cardozo, Andre-Brian Greenaway Patton
  • Publication number: 20140349915
    Abstract: An industrial cleaning composition comprises (a) from 5 to 50% by volume of an anionic surfactant having a log10P value in the range 5 to 7, (b) from 5 to 50% by volume of a first non-ionic surfactant having a log10P value in the range 0.1 to 3 and having the general formula, R?-(A0)n-OH wherein R? is C9 to C20 alkyl, each AO unit is either —OCH2CH2— or —OCH2CH(CH3)—; the molar ratio [—OCH2CH(CH3)—]/[—OCH2CH2—] is in the range up to 8 and n is greater than 6 and (c) from 5 to 50% by weight of a second non-ionic surfactant having a log10P value in the range 0.1 to 3 having the general formula, R?—(OCH2CH2)n—OH wherein R? is C9 to C20 alkyl, and n is less than 6, each of said volume percentages being with respect to the total volume of (a), (b) and (c). Corresponding cleaners derived therefrom by water dilution are also disclosed.
    Type: Application
    Filed: August 6, 2014
    Publication date: November 27, 2014
    Inventors: Wakhloo JAWAHAR, Alan KEASEY, Caroline KELLY
  • Publication number: 20140290694
    Abstract: Cleaning compositions for cleaning debris from a hard surface are described herein, the cleaning compositions include from about 0.001% to about 1% by weight of the composition of a thickener and from about 0.1% to about 50% by weight of the composition of an alkyl sulfate detergent surfactant that contains about 8 carbon atoms on the average, with substantially all of the alkyl groups having within two carbon atoms of the 8 average carbon atoms. They are high sudsing, have excellent soap scum removal and hard water deposit removal properties and are easy to rinse. A sprayer, methods of use and kits are also disclosed.
    Type: Application
    Filed: March 21, 2014
    Publication date: October 2, 2014
    Applicant: The Procter & Gamble Company
    Inventors: Hirotaka UCHIYAMA, Joseph Michael GAINES, Mimi Gizaw DANIEL, Roberto Manuel MATOS
  • Patent number: 8845817
    Abstract: Provided herein is an aqueous, non-toxic, non-flammable, non-explosive, biodegradable, hypoallergenic cleaning composition. Also provided are pre-loaded wipes containing the cleaning solution, kits, and methods of cleaning surfaces using the same.
    Type: Grant
    Filed: June 5, 2013
    Date of Patent: September 30, 2014
    Assignee: Green Way Laboratories
    Inventors: Thomas Bakehorn, Guy Roland Adams
  • Publication number: 20140200173
    Abstract: A solution having improved stain removing properties on hard surfaces, carpets and fabrics, that is easier to handle (stored or transported at lower temperatures and less corrosive) and that is environmentally friendly. The stain removing solution includes the following components: a surfactant selected from the group consisting of alcohol ethoxylates, alkyl sulfates, alkyl ether sulfates, alpha olefin sulfonates, alkyl phosphates, alkyl amidopropyl betaines, alkyl betaines, amphoacetates, amphoproprionates, amphosulfonates, amine oxides, alkanolamides, sulfosuccinates, and sultaines, a hydrotrope, and a solvent. The surfactant is preferably an alcohol ethoxylate. The hydrotrope is preferably lauramine oxide. The solvent is preferably a dibasic ester or a glycol ether. The solution may further comprise a diluent, a mild acid, and/or a preservative. A mild acid can be added to lower the pH of the solution.
    Type: Application
    Filed: January 16, 2013
    Publication date: July 17, 2014
    Applicant: Jelmar, LLC
    Inventor: Rosemary Gaudreault
  • Publication number: 20140148375
    Abstract: The present invention relates to detergent compositions containing a surfactant system comprising “sustainable” or bio-derived surfactant hydrophobes or “sustainable” or bio-derived surfactants.
    Type: Application
    Filed: January 29, 2014
    Publication date: May 29, 2014
    Applicant: The Procter & Gamble Company
    Inventors: Stephanie Ann URBIN, Jeffrey John SCHEIBEL, Phillip Kyle VINSON, Praveen Kumar DEPA, Randall Thomas REILMAN, Melinda Phyllis STEFFEY
  • Patent number: 8729001
    Abstract: The invention relates to compositions containing a) 45 to 65 wt. % of one or more secondary paraffin sulfonates with 8 to 22 carbon atoms, b) 1 to 10 wt. % of one or more alcohol alkoxylates which are produced from the reaction of alcohols R—OH, wherein R is an alkyl group with 9 to 11 carbon atoms, with alkoxylating agents selected from ethylene oxide, propylene oxide, or mixtures thereof and which contain on average 1 to 4 mol of structural units derived from the alkoxylating agents per 1 mol of structural units derived from the alcohols, and c) 25 to 52 wt. % water, in relation to the total weight of the composition in each case. The compositions can be used in an advantageous manner for producing washing and cleaning agents.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: May 20, 2014
    Assignee: Clariant International, Ltd
    Inventors: Johannes Himmrich, Wolfgang Walther
  • Patent number: 8722610
    Abstract: An auto-emulsifying cleaning composition capable of emulsifying upon contact with water, the composition in one typical embodiment comprising, based on the total weight of the composition, (a) from about 1% to about 99% by weight a blend of dibasic esters; (b) from about 1% to about 40% by weight of a blend of surfactants consisting of an organic anion neutralized with an organic cation, where either or both of the anion and the cation have surfactant properties, and the complex of which is soluble in the dibasic ester solvent blend. The blend of surfactants is typically a cationic surfactant and an anionic surfactant, which may or may not be used in conjunction with non-ionic surfactants. The dibasic esters are be derived from a blend of adipic, glutaric, and succinic diacids, and, in one particular embodiment, the blend comprises dialkyl adipate, dialkyl methylglutarate and dialkyl ethylsuccinate, wherein the alkyl groups individually comprise a C1-C12 hydrocarbon group.
    Type: Grant
    Filed: October 19, 2010
    Date of Patent: May 13, 2014
    Assignee: Rhodia Operations
    Inventors: Amit Sehgal, Cecile Lara, Ashwin Rao, Charles Aymes
  • Publication number: 20140100153
    Abstract: The invention relates to methods and compositions that may be used in a pre-soak system which maintains whitening and eliminates concerns of chlorine stability. The compositions and methods may be used for laundry, toilet bowl cleaners, ware wash cleaners, floor cleaners and the like. The system and compositions are particularly suited for laundry in a pre-soak system that includes the use of a “strainer” or basket for accomplishing the pre-soak step. Heavier soils fall to the bottom of the receptacle while greasy soils float to the top.
    Type: Application
    Filed: February 27, 2013
    Publication date: April 10, 2014
    Applicant: ECOLAB USA INC.
    Inventors: Melissa Martinez-Crowley, Amie Blanks, Rachel Moore
  • Patent number: 8669216
    Abstract: The present invention relates to concentrated hard surface treatment compositions which are primarily intended to be dispersed in a larger volume or quantity of water prior to use by a consumer, in order to produce a ready to use type composition.
    Type: Grant
    Filed: September 8, 2009
    Date of Patent: March 11, 2014
    Assignee: Reckitt Benckiser LLC
    Inventor: Yun-Peng Zhu
  • Patent number: 8658581
    Abstract: A cosmetic preparation is disclosed, comprising (a) at least one surfactant selected from the group consisting of non-alkoxylated anionic surfactants, zwitterionic surfactants and amphoteric surfactants, (b) a microemulsion, and (c) at least one cationic polymer.
    Type: Grant
    Filed: June 14, 2008
    Date of Patent: February 25, 2014
    Assignee: Cognis IP Management GmbH
    Inventors: Matthias Hloucha, Hans-Martin Haake, Esther Küsters, Jasmin Menzer, Wolf Eisfeld, Werner Seipel, Hermann Hensen, Esther Ricarda Reinhardt
  • Patent number: 8648026
    Abstract: A composition for dissolving and/or inhibiting deposition of scale on a surface of a system comprises an acidic component, a wetting agent, and a corrosion inhibitor. The composition may further comprise water. The acidic component comprises an alkanesulfonic acid, e.g. methanesulfonic acid (MSA). The wetting agent comprises a surfactant. The corrosion inhibitor comprises an amphoteric surfactant. The alkanesulfonic acid is present in an amount of at least about 50 weight percent (wt %), the surfactant is present in an amount of from about 0.1 to about 30 wt %, and the amphoteric surfactant is present in an amount of from about 0.025 to about 20 wt %, each based on 100 wt % of the alkanesulfonic acid, the surfactant, and the amphoteric surfactant combined. A method of dissolving and/or inhibiting deposition of scale on the surface of the system comprises the step of contacting the surface of the system with the composition.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: February 11, 2014
    Assignee: BASF SE
    Inventors: Joseph P Borst, Keith Hirsch, Stephen F Gross
  • Publication number: 20130326830
    Abstract: Provided herein is an aqueous, non-toxic, non-flammable, non-explosive, biodegradable, hypoallergenic cleaning composition. Also provided are pre-loaded wipes containing the cleaning solution, kits, and methods of cleaning surfaces using the same.
    Type: Application
    Filed: June 5, 2013
    Publication date: December 12, 2013
    Inventors: Thomas BAKEHORN, Guy Roland ADAMS
  • Publication number: 20130331308
    Abstract: Self-adhesive detergent compositions are described including a pH-sensitive color-changing system. The color-changing system is useful with certain acidic compositions and certain alkaline compositions. The compositions have a given color upon application to a hard surface, e.g., a toilet bowl. In one embodiment, when the self-adhesive composition is exposed to a water-based rinse, such as on flushing a toilet, the color-changing system provides the released cleaning portion of the composition, and thereby the water, with a color different from the color of the composition to indicate cleaning is occurring. In another embodiment, following exposure to a plurality of rinses, the color-changing system changes the color of the composition when the composition is near depletion to provide an “end-of-use” cue.
    Type: Application
    Filed: June 8, 2012
    Publication date: December 12, 2013
    Inventors: Wayne M. REES, Thomas A. STRASH
  • Publication number: 20130296219
    Abstract: The invention relates to compositions containing a) 45 to 65 wt. % of one or more secondary paraffin sulfonates with 8 to 22 carbon atoms, b) 1 to 10 wt. % of one or more alcohol alkoxylates which are produced from the reaction of alcohols R—OH, wherein R is an alkyl group with 9 to 11 carbon atoms, with alkoxylating agents selected from ethylene oxide, propylene oxide, or mixtures thereof and which contain on average 1 to 4 mol of structural units derived from the alkoxylating agents per 1 mol of structural units derived from the alcohols, and c) 25 to 52 wt. % water, in relation to the total weight of the composition in each case. The compositions can be used in an advantageous manner for producing washing and cleaning agents.
    Type: Application
    Filed: December 15, 2011
    Publication date: November 7, 2013
    Applicant: CLARIANT INTERNATIONAL LTD.
    Inventors: Johannes Himmrich, Wolfgang Walther
  • Patent number: 8536112
    Abstract: Liquid cleaning compositions are described that comprise sulfo-estolide (SE) salts, particular sodium, lithium or ammonium salts of sulfo-estolides, and alkyl ester sulfonates. The liquid cleaning compositions are clear, stable and substantially free of precipitates due to the use of sodium, lithium or ammonium salts of sulfo-estolide rather than a potassium sulfo-estolide salt in the composition. The liquid cleaning compositions also have a total combined amount of saturated C16 and C18 fatty acids of less than about 5% by weight to prevent the formation of precipitates in the composition.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: September 17, 2013
    Assignee: Stepan Company
    Inventors: Randal J. Bernhardt, Jeremy Aaron Weitgenant, Gregory P. Dado, Dennis S. Murphy
  • Publication number: 20130225473
    Abstract: Sulfonate compositions are disclosed. The compositions include alkanesulfonates, alkenesulfonates, sultones, and hydroxy-substituted alkanesulfonates. The sulfonates comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a sulfonating or sulfitating agent. In one aspect, the sulfonate composition is a sulfo-estolide made by reacting a metathesis-derived C10-C17 monounsaturated acid or octadecene-1,18-dioic acid with a sulfonating agent, optionally in the presence of a saturated fatty acid. The sulfonates are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), paint additives, antimicrobial compositions, agricultural uses, and oil field applications.
    Type: Application
    Filed: October 25, 2011
    Publication date: August 29, 2013
    Applicant: Stepan Company
    Inventors: Dave R Allen, Randal J Bernhardt, Aaron Brown, Gary Luebke, Renee Luka, Andrew D. Malec, Ronald A. Masters, Patti Skelton, Brian Sook, Jeremy Aaron Weitgenant, Patrick Shane Wolfe
  • Publication number: 20130225469
    Abstract: Aqueous hard surface cleaner compositions derived from metathesized natural oil feedstocks are disclosed. In one aspect, the compositions comprise at least one anionic surfactant derived from a metathesis-derived C10-C17 monounsaturated acid, 5 octadecene-1,18-dioic acid, or their ester derivatives. In another aspect, aqueous hard surface cleaners comprising at least one nonionic or amphoteric surfactant derived from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. The aqueous cleaners noted above rival or outperform commercial baselines in a Gardner straight-line washability test. Industrial degreasers comprising a C10 or C12 amide solvent and derived from a metathesis-derived C10-C17 monounsaturated acid are superior to commercial standards.
    Type: Application
    Filed: October 25, 2011
    Publication date: August 29, 2013
    Applicant: Stepan Company
    Inventors: Dave R Allen, Randal J Bernhardt, Aaron Brown, Ronald A. Masters, Patrick Shane Wolfe, Lena Titievsky
  • Patent number: 8461090
    Abstract: The present invention relates to a dissolvable article in the form of a porous dissolvable solid structure, comprising from about 23% to about 75% surfactant; wherein the surfactant has an average ethoxylate/alkyl ratio of from about 0.001 to about 0.45; from about 10% to about 50% water soluble polymer; and from about 1% to about 15% plasticizer; and wherein the article has a density of from about 0.05 g/cm3 to about 0.25 g/cm3.
    Type: Grant
    Filed: December 8, 2009
    Date of Patent: June 11, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Robert Wayne Glenn, Jr., James Merle Heinrich, Kathleen Mary Kaufman, John Robert Rusche, David Johnathan Kitko
  • Patent number: 8461091
    Abstract: The present invention relates to a dissolvable article in the form of a porous dissolvable solid structure, comprising from about 10% to about 50% water soluble polymer; from about 1% to about 25% plasticizer; from about 23% to about 75% surfactant; wherein the surfactants comprise one or more surfactants from Group I, wherein Group I includes anionic surfactants, and one or more surfactants from Group II, wherein Group II includes a surfactant selected from the group consisting of amphoteric, zwitterionic and combinations thereof; wherein the ratio of Group I to Group II surfactants is from about 5:95 to about 30:70; and wherein the dissolvable article has a density of from about 0.05 g/cm3 to about 0.40 g/cm3.
    Type: Grant
    Filed: December 8, 2009
    Date of Patent: June 11, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Robert Wayne Glenn, Jr., James Merle Heinrich, Kathleen Mary Kaufman, Darren Paul Trokhan, Thomas Edward Dufresne, Julie Masters Lubbers, Renee Danielle Bolden, Lee Arnold Schechtman
  • Publication number: 20130109611
    Abstract: An aqueous composition comprising: (a) an acyl isethionate of formula (I): wherein R1 is an alkyl or alkenyl group having from (7) to (21) carbon atoms and M+0 is a cation; and (b) a further surfactant selected from nonionic surfactants, cationic surfactants and anionic surfactants other than those of formula (I); wherein component (a) and component (b) together comprise more than (12) wt % of the composition.
    Type: Application
    Filed: March 25, 2011
    Publication date: May 2, 2013
    Applicant: INNOSPEC LIMITED
    Inventors: Stephen Moss O'Connor, Phillip Lorraine Cotrell
  • Publication number: 20130109610
    Abstract: An aqueous composition comprising: (a) an acyl isethionate of formula (I): wherein R1 is an alkyl or alkenyl group having from (7) to (21) carbon atoms and M+ a cation; and (b) an amphoteric, betaine or sultaine surfactant; wherein the weight ratio of component (a) to component (b) is more than 3:1.
    Type: Application
    Filed: March 25, 2011
    Publication date: May 2, 2013
    Applicant: INNOSPEC LIMITED
    Inventors: Stephen Moss O'Connor, Phillip Lorraine Cotrell
  • Patent number: 8426349
    Abstract: A chlorinated alkaline cleaning agent and methods for removing food soils with no resultant increase in foam generation. Particularly advantageous is that the addition of methanesulfonic acid in removing food soils with no resultant increase in foam generation.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: April 23, 2013
    Assignee: DeLaval Holding AB
    Inventor: Alan Monken
  • Publication number: 20130090280
    Abstract: The present invention relates, in part, to compositions including at least one hydrofluoro-olefin or hydrochlorofluoro-olefin solvent. Such compositions may optionally contain one or more alcohols or other co-solvent or agent and may be used to provide one or more cleaning applications.
    Type: Application
    Filed: August 23, 2012
    Publication date: April 11, 2013
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: RAJAT S. BASU, KANE D. COOK, RYAN HULSE, DIANA MERCIER, GARY M. KNOPECK, TODD WHITCOMB, MARTIN R. PAONESSA
  • Publication number: 20130072414
    Abstract: The present invention relates to detergent compositions containing a surfactant system comprising “sustainable” or bio-derived surfactant hydrophobes or “sustainable” or bio-derived surfactants. Specifically, the invention relates to detergent compositions containing a surfactant system that has a “Surfactant Hydrophobe Sustainability Index” (SHSI) greater than or equal to 0.70 or a “Surfactant Sustainability Index” (SSI) greater than or equal to 0.70.
    Type: Application
    Filed: September 20, 2012
    Publication date: March 21, 2013
    Applicant: The Procter & Gamble Company
    Inventor: The Procter & Gamble Company
  • Publication number: 20130072415
    Abstract: The present invention relates to detergent compositions containing a blend of selected isoprenoid-based surfactants and methods of making and using the same.
    Type: Application
    Filed: September 20, 2012
    Publication date: March 21, 2013
    Applicant: The Procter & Gamble Company
    Inventor: The Procter & Gamble Company
  • Publication number: 20130072413
    Abstract: The present invention relates to detergent compositions containing a surfactant system comprising a highly branched surfactant as the primary surfactant. Specifically, the invention relates to detergent compositions containing a surfactant system comprising greater than about 25% of a highly branched surfactant.
    Type: Application
    Filed: September 20, 2012
    Publication date: March 21, 2013
    Applicant: The Procter & Gamble Company
    Inventor: The Procter & Gamble Company
  • Patent number: 8389458
    Abstract: An ADW composition comprising a builder and a water-soluble copolymer which comprises: (a) from about 30 to 60 mol % of the copolymer having a structural unit originating from a monoethylenic unsaturated dicarboxylic acid (or dicarboxylate) monomer having 4 to 6 carbon atoms or its anhydride at; (b) from about 30 to 60 mol % of the copolymer having a structural unit originating from a monoethylenic unsaturated monocarboxylic acid (or monocarboxylate) monomer having 3 to 8 carbon atoms; and (c) from about 5 to 15 mol % of the polymer having a structural unit originating from a monoethylenic unsaturated monomer having a sulfonic (or sulfonate) group; wherein the water-soluble copolymer has a weight average molecular weight of from about 1,000 to about 50,000 wherein the copolymer is polymerized with hydrogen peroxide.
    Type: Grant
    Filed: March 27, 2009
    Date of Patent: March 5, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Takahiro Tsumori, Masato Nakano
  • Patent number: 8383569
    Abstract: A single phase alkaline composition comprising by weight about 10 to about 25 percent of nonionic surfactant blend comprising a ratio of between about 1:1 to about 1:2 of alcohol ethoxylate:fatty alcohol alkoxylate, about 3-10% of at least one water soluble solvent, about 1-10% of a chelant, 2-12% of an alkalinity source, 0.5-2% of an anionic surfactant blend comprised of at least about 40-70% of a sulfosuccinate, the balance being water. Compositions of the invention are useful for removing hydrophobic soils or oils whether they are located on a hard surface or on a linen. A method of cleaning a hard surface is also disclosed comprising the steps of diluting the composition of the invention with water to about 1 to about 3 weight percent, applying the diluted composition to the surface, and wiping the surface, wherein the surface is substantially free of oil or residue and the surface is substantially free of corrosion.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: February 26, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Andrea Schwerter, Katja Teusch, Matthias Menzel
  • Patent number: 8338358
    Abstract: Compositions comprising sulfo-estolides and alkyl ester sulfonates are described. Detergent formulations, such as laundry detergents, softeners, and other materials, containing any of these materials are disclosed, as well as personal care formulations, hard surface cleaner formulations, and automatic dishwasher detergent formulations. Laundry methods employing these formulations are also disclosed. These formulations are useful as laundry detergents and can be biodegradable, heavy duty liquids, 2× or 3× and up to 6× concentrates, low foaming, and/or effective in a high efficiency washing machine.
    Type: Grant
    Filed: January 26, 2012
    Date of Patent: December 25, 2012
    Assignee: Stepan Company
    Inventors: Randal J. Bernhardt, Lourdes R. Alonso, Gregory P. Dado, Eddie I. Filipovic, Christopher A. Gariepy, Ronald A. Masters, Dennis S. Murphy, Jacqueline Maas Pytel, Branko Sajic, Irene Shapiro, Jeremy Aaron Weitgenant
  • Patent number: 8324143
    Abstract: Provided is a cleaning agent for electronic materials, which enables very efficient advanced cleaning such that yield in the production of the electronic materials is improved and cleaning in a short period of time becomes possible, the cleaning agent having excellent cleaning power for fine-grained particles and organic matter and being able to reduce metallic contamination on the substrate. The cleaning agent for electronic materials comprises sulfamic acid (A), an anionic surfactant having at least one sulfonic acid group or a salt thereof in the molecule (B), a chelating agent (C), and water, wherein the pH at 25 C is preferably not more than 3.0 and the (B) is preferably a polymeric anionic surfactant (B1) having a weight average molecular weight of 1,000 to 2,000,000.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: December 4, 2012
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Kazumitsu Suzuki, Shohei Sato, Ayayo Sugiyama
  • Patent number: 8278260
    Abstract: Eco-friendly, or “green”, cleaning wipes are disclosed. The wipes may include a substrate and a green concentrated aqueous cleaning composition impregnated therein. The wipes are dry to the touch before they are activated by water and applied to inanimate surfaces for cleaning. Because of the green concentrated cleaning composition and water-activation just before application, the disclosed wipes may clean larger surface areas and have longer shelf lives and lower weights for easy transportation, packaging and handling than conventional wet wipes that are pre-loaded with a diluted cleaning composition.
    Type: Grant
    Filed: August 21, 2009
    Date of Patent: October 2, 2012
    Assignee: S.C. Johnson & Son, Inc.
    Inventor: Marie-Esther Saint Victor