Hydroxy In The Component Patents (Class 510/502)
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Patent number: 6165971Abstract: The present invention relates to the use of amides of polymerized fatty acids as thickeners.Moreover, the invention relates to aqueous compositions comprising these amides as thickeners.Type: GrantFiled: May 12, 1999Date of Patent: December 26, 2000Assignee: BASF AktiengesellschaftInventors: Knut Oppenlander, Michael Zirnstein, Kristin Tiefensee, Gunter Oetter
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Patent number: 6156721Abstract: The present invention relates to the use of anionic gemini tensides of the formula (I) ##STR1## in which R.sup.1 and R.sup.3 are, mutually independently, a hydrocarbon radical with 1 to 22 carbon atoms, R.sup.2 is a spacer containing 0 to 100 alkoxy groups, and X and Y, mutually independently, are functional groups and the degree of substitution Z=1 to 10, in washing, cleaning and body care agents in which the proportion of said tensides amounts to at least 0.1%.Type: GrantFiled: October 23, 1998Date of Patent: December 5, 2000Assignee: RWE-DEA Aktiengesellschaft fuer Mineraloel und ChemieInventors: Klaus Kwetkat, Michael Brock, Herbert Koch
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Patent number: 6153571Abstract: A viscous firearm gel cleaner that includes an organic cleaning agent such as terpene, terpene derivatives, terpenoids, terpenoid derivatives, turpentine and/or turpentine derivatives. The organic solvent includes substantially no petroleum distillates. The cleaner includes non-ionic and ionic surfactants to enhance the usability and effectiveness of the cleaner. The cleaner can also include an amine cleaning agent, a scent agent, a rust and/or corrosion inhibitor, a thickener, and/or a biocide. The cleaner removes grease, oil, carbon, plastic wad fouling and metal residues that can foul firearms. The cleaner is a water soluble, non-flammable, biodegradable cleaner. The cleaner is especially useful for cleaning outdoor sporting equipment such as firearms.Type: GrantFiled: January 29, 1999Date of Patent: November 28, 2000Assignee: Sports Care Products, Inc.Inventors: David Stanley Komocki, Robert Joseph Harmacek
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Patent number: 6147124Abstract: A free-flowing pearlescer concentrate is presented which is composed of: (a) 5 to 50% by weight of a pearlescing component which is (1) a compound of formula R.sup.3 --(OC.sub.n H.sub.2n).sub.x --OR.sup.4 where R.sup.3 is a fatty acyl group having 14 to 22 carbon atoms, R.sup.4 is hydrogen or linear fatty acyl group having 14 to 22 carbon atoms, n is 2 or 3, and x is 1; (2) a compound of formula R.sub.5 --CO--NH--X, where R.sup.5 is an alkyl group having 8 to 22 carbon atoms and X is selected from the group --CH.sub.2 --CH.sub.2 --OH, --CH.sub.2 --CH.sub.2 --CH.sub.2 --OH, and --C(CH.sub.3).sub.2 --OH; and a linear saturated fatty acid having 12 to 14 carbon atoms; (b) 5 to 55% by weight of a fatty acid-N-alkyl polyhydroxyalkylamide nonionic emulsifier of the formula ##STR1## as the sole emulsifier, where R.sup.1 --CO is an aliphatic acyl group having 6 to 22 carbon atoms, R.sup.2 is an alkyl or hydroxyalkyl group having 1 to 4 carbon atoms, and R.sup.Type: GrantFiled: April 16, 1998Date of Patent: November 14, 2000Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Achim Ansmann, Rolf Kawa, Helga Gondek
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Patent number: 6143706Abstract: A surface treatment composition containing a complexing agent as a metal deposition preventive in a liquid medium, in which the complexing agent is an ethylenediaminephenol derivative of the following general formula (1) or its salt: ##STR1## wherein X.sub.1 and X.sub.2 are hydroxyl groups; Y.sub.1 to Y.sub.8 are respectively independently a hydrogen atom, a hydroxyl group, a halogen atom, a carboxyl group, a phosphonic acid group, a sulfonic acid group, a carbonyl group, a nitro group, a nitroso group, an amino group, an imino group, a nitrilo group, a nitrile group, a thiocyanate group, a hydroxyamino group, a hydroxyimino group, or an alkyl or alkoxy group which may have a substituent, provided that at least one of Y.sub.1 to Y.sub.8 is not a hydrogen atom; Z.sub.1 to Z.sub.4 are respectively independently a hydrogen atom, a carboxyl group or a sulfonic acid group; and R.sub.1 to R.sub.4 are respectively independently a hydrogen atom or an alkyl group which may have a substituent.Type: GrantFiled: January 26, 1998Date of Patent: November 7, 2000Assignee: Mitsubishi Chemical CorporationInventor: Hitoshi Morinaga
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Patent number: 6126757Abstract: A method of preventing asphalt and tar from sticking to paving equipment comprises diluting a concentrate with about four to about 50 parts water to one part concentrate and spraying, rolling or brushing the diluted concentrate on the equipment, coating the dilution on equipment prior to its coming into contact with tar or asphalt. The concentrate comprises a fatty acid amide or mixture of fatty acid amides, a fatty acid neutralized with an excess of an alkyl- or alkanol- or mixed-type amine or ammonia, and an optional solvent or solvents. The chief advantages of the instant invention are that the dilutions are viscous, and so prevent the diluted material from running off of the equipment prior to contact with tar or asphalt, and that the diluted material leaves a lubricious film on the surface even after all the water in the diluted film has evaporated.Type: GrantFiled: March 16, 1998Date of Patent: October 3, 2000Assignee: Chemtek, Inc.Inventor: Michael Gates Kinnaird
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Patent number: 6087314Abstract: The present invention relates to detergent compositions having a pH of at least 8.0 in a 0.5% by weight aqueous solution containing a mixture of AS and LAS surfactants and cationic surfactants of the formula: R.sup.1 R.sup.2 R.sup.3 R.sup.4 N+X.sup.- in which R.sup.1 is a hydroxyalkyl group having no greater than 6 carbon atoms; each of R.sup.2 and R.sup.3 is independently selected from C.sub.1 -C.sub.4 alkyl or alkenyl; R.sup.4 is one or mixtures of more than one of C.sub.5-11 alkyl or alkenyl; and X.sup.- is a counterion which does not substantially exchange with a hydroxide ion at 20.degree. C. in a 0.5% by weight solution of the detergent composition.Type: GrantFiled: April 19, 1999Date of Patent: July 11, 2000Assignee: The Procter & Gamble CompanyInventors: Stephen Wayne Heinzman, Robin Gibson Hall, Peter Gerard Gray
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Patent number: 6057274Abstract: A liquid cleaning composition containing: (a) at least one surfactant, other than a nonionic sugar surfactant; (b) an antibacterial agent; (c) a nonionic sugar surfactant; and (d) a glyceride component.Type: GrantFiled: July 20, 1998Date of Patent: May 2, 2000Assignee: Henkel CorporationInventor: Patricia E. Bator
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Patent number: 6057283Abstract: Fatty acid derivatives based on epoxidized unsaturated fatty acid esters or triglycerides and reacted with amines such as hydroxy- and/or amino-substituted hydrophilic amines or amino acids and/or with alkanols or with water on the epoxy group and/or the carboxylic ester groups are described. These fatty amides are suitable as surfactants in detergents and cleaners.Type: GrantFiled: July 6, 1999Date of Patent: May 2, 2000Assignee: BASF AktiengesellschaftInventors: Alfred Oftring, Martin aus dem Kahmen, Christian Ott, Gunter Oetter, Richard Baur
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Patent number: 6034043Abstract: The present invention relates to liquid skin cleansing compositions comprising (1) mild surfactant systems; (2) 0.1 to 10% by wt. of a polyvalent cation or cations selected from the group consisting of zinc, copper, tin, aluminum cobalt, nickel, chromium, titanium and/or manganese and mixture thereof; and (3) 1% to 99% water wherein said cation or cations provide antibacterial activity. In a second embodiment of the invention, the cation or cations potentiates antibacterial effect in compositions already containing an antibacterial agent. In a third embodiment, the invention relates to a method of enhancing antibacterial effect using these polyvalent cation or cations.Type: GrantFiled: April 20, 1999Date of Patent: March 7, 2000Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Mitsuko Fujiwara, Carol Vincent, Kavssery Ananthapadmanabhan
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Patent number: 6030931Abstract: A foaming cleansing product is provided as a cleansing composition packaged in a non-aerosol mechanical dispenser. The dispenser includes a container for holding a liquid composition, a dispensing head with a housing enclosing a pump mechanism and a screen material in the flow path to convert liquid composition into a foam, and a diptube for delivering liquid from the container to the dispensing head. The cleansing composition is free of water insoluble emollients and includes an anionic surfactant and an amphoteric surfactant of structure: ##STR1## wherein R is a fatty alkyl of 6 to 22 carbons; R.sup.1 is selected from the group consisting of H, C.sub.2 H.sub.4 COOH and C.sub.2 H.sub.4 COONa; and R.sup.2 is selected from the group consisting of COONa, CH.sub.2 CHOHCH.sub.2 SO.sub.3 Na, C.sub.2 H.sub.4 COONa, CH.sub.2 COOCH.sub.2 COOH and CH.sub.2 COOCH.sub.2 COONa.Type: GrantFiled: February 3, 1998Date of Patent: February 29, 2000Assignee: Chesebrough-Pond's USA Co., Division of Conopco, Inc.Inventors: Paul Vinski, Alexander Paul Znaiden, Craig Stephen Slavtcheff
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Patent number: 6004914Abstract: Amphoteric derivatives of aliphatic polyamines, such as diethylenetriamine or triethylenetetramine reacted with long chain fatty acids, esters or triglycerides from various natural or synthetic sources are effective in the softening/texture modification of substrates such as paper, textiles, human skin surfaces and hair tresses, as well as in applications for metal working and lubrication. The polyamines are first reacted with fatty acids, esters or triglycerides derived from various animal, vegetable or synthetic sources ranging in molecular distribution from butyric through erucic acids (e.g. milkfat, soy bean oil, rapeseed oil) to form polyamines or imidazolines; they are then further reacted with unsaturated or halogenated carboxylic acids, carboxylated epoxy compounds or acid anhydrides (e.g. acrylic acid, itaconic acid, chloroacetic acid, maleic anhydrides octadecenyl anhydride) to form the various amphoteric structures.Type: GrantFiled: August 20, 1998Date of Patent: December 21, 1999Assignee: Mona Industries, Inc.Inventors: James e. Perella, Joseph A. Komor, Richard D. Katstra
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Patent number: 5985809Abstract: A personal cleansing composition comprising: (a) from about 1% to about 30% by weight of a dispersed oil phase comprising at least one nonocclusive liquid polyol fatty acid polyester containing at least four fatty acid ester groups wherein the polyol moiety is selected from sugars and sugar alcohols containing from about 4 to about 8 hydroxyl groups, and wherein each carboxylic acid moiety has from about 8 to about 22 carbon atoms and wherein the liquid polyol fatty acid polyester has a complete melting point of less than about 30.degree. C.; and (b) from about 5% to about 30% by weight of water-soluble surfactant selected from anionic, nonionic, zwitterionic and amphoteric surfactants and mixtures thereof. The products provide excellent in-use and efficacy benefits including excellent skin feel during and after use, good lather volume and stability characteristics, skin conditioning, mildness, stability, cleansing, good water-feel and appearance.Type: GrantFiled: November 26, 1997Date of Patent: November 16, 1999Assignee: The Procter & Gamble CompanyInventors: Gayle Marie Frankenbach, Nicola Jacqueline Phipps, Wendy Victoria J. Richardson
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Patent number: 5968890Abstract: An aqueous liquid detergent composition comprises a mixture of synthetic anionic and amphoteric surfactants in a weight ratio within the range 4:1 to 0.1:1 and a polyethylene glycol having a molecular weight of not more than 100,00. The later component boosts the lather of the composition during use. It may also enhance the mildness of the formulation.Type: GrantFiled: March 14, 1997Date of Patent: October 19, 1999Assignee: Lever Brothers CompanyInventors: John George Chambers, Izuma Kutsuwa, David Serridge
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Patent number: 5965516Abstract: The present invention concerns aqueous surfactant composition comprising poly hydroxy fatty acid amides of formula (A), ##STR1## wherein R.sup.2 is C.sub.11 -C.sub.19 alkyl, alkenyl or mixtures thereof, Z is a polyhydroxyhydrocarbyl moiety having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain; and in a part of the total amide surfactant (a) R.sup.1 is a methyl group and in the remainder of the total amide surfactant (b) R.sup.1 is an alkyl group with from 3 to 8 carbon atoms; said composition further comprising (c) from 0% to 15% by weight of an organic solvent; wherein the ratio of N-methyl poly hydroxy fatty acid amide (a) to N-alkyl (C.sub.3 -C.sub.8) polyhydroxy fatty acid amide (b), is from 25:1 to 1:1.Type: GrantFiled: February 27, 1998Date of Patent: October 12, 1999Assignee: The Procter & Gamble CompanyInventors: Jean-Pol Boutique, Patrick Firmin A. Delplancke
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Patent number: 5958868Abstract: The invention concerns aqueous surfactant concentrates having a solids content of between 35 and 65 wt % and containing (a1) alkyl oligoglycosides and/or alkenyl oligoglycosides; and/or (a2) fatty acid N-alkylpolyhydroxy alkylamides; and (b) betaine, in weight ratios of (a):(b) of between 10:90 and 90:10; wherein the pH of these concentrates is between 3.5 and 6.5.Type: GrantFiled: October 24, 1997Date of Patent: September 28, 1999Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Rafael Pi Subirana, Nuria Bonastre Gilabert, Ester Prat Queralt, Joaquim Bigorra Llosas
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Patent number: 5942479Abstract: A personal cleansing composition comprising: (a) from about 1% to about 30% by weight of a dispersed oil phase comprising a first oil component having an oil/surfactant solution interfacial tension (IFT) of greater than about 1.0 dynes/cm and a second oil component having an oil/surfactant solution interfacial tension (IFT) in the range of from about 0.1 to about 1.0 dynes/cm; and (b) from about 5% to about 30% by weight of water-soluble surfactant selected from anionic, nonionic, zwitterionic and amphoteric surfactants and mixtures thereof; and (c) water; and wherein the ratio of first to second dispersed oil component is in the range from about 20:1 to about 1:20. The cleansing products demonstrate excellent in-use efficacy benefits including excellent skin feel during and after use, good lather volume, stability and appearance characteristics, good skin conditioning, mildness, stability, cleansing, good water feel and appearance.Type: GrantFiled: November 26, 1997Date of Patent: August 24, 1999Assignee: The Proctor & Gamble CompanyInventors: Gayle Marie Frankenbach, Nicola Jacqueline Phipps, Wendy Victoria J. Richardson
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Patent number: 5942485Abstract: Concentrated heavy duty liquid laundry detergent compositions containing an anionic surfactant component, polyhydroxy fatty acid amide surfactant and a water-soluble salt of toluene sulfonic acid, and containing no more than about 50% water. The concentration of all surfactants in the detergent compositions is greater than about 10% by weight of the composition. The anionic surfactant component comprises between about 50% and 100% alkyl polyethoxylate sulfates. The compositions are substantially clear and isotropic when prepared and remain stable after extended periods of time and under extreme conditions. Toluene sulfonate salts, although known hydrotropes, provides improved phase stability to the compositions unlike other standard hydrotropes and solvents.Type: GrantFiled: February 5, 1996Date of Patent: August 24, 1999Assignee: The Procter & Gamble CompanyInventor: Kenneth M. Kemen
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Patent number: 5939372Abstract: Detergent mixtures containing fatty alcohol sulfates, fatty alcohol ether sulfates, alkyl and/or alkenyl oligoglycosides and/or fatty acid N-alkyl polyhydroxyalkyl amides are eminently suitable in solid form for the production of toilet blocks.Type: GrantFiled: May 28, 1996Date of Patent: August 17, 1999Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Karl Schmid, Andreas Syldath, Ditmar Kischkel, Volker Bauer, Wolfgang Schmidt, Anke Grosser
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Patent number: 5932535Abstract: Light-colored, low-viscosity surfactant concentrates, are made by mixing: mixing: (a) a sugar surfactant selected from the group consisting of an alkyl and/or alkenyl oligoglycoside, a fatty acid-N-alkyl polyhydroxyalkylamide and a combination thereof and, (b) a betaine in a ratio by weight of (a) to (b) of from about 90:10 to about 10:90, with the proviso that components (a) and (b)are present in the gel phase.Type: GrantFiled: December 17, 1996Date of Patent: August 3, 1999Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Michael Neuss, Karl Heinz Schmid, Andrea Borntraeger
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Patent number: 5922662Abstract: A high foaming, light duty, liquid detergent with desirable cleansing properties and mildness to the human skin comprising: a water soluble nonionic surfactant at least one water soluble, foaming, anionic surfactant, a zwitterionic surfactant, an alkyl succinamate and the balance being water.Type: GrantFiled: August 1, 1997Date of Patent: July 13, 1999Assignee: Colgate Palmolive CompanyInventor: Barbara Thomas
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Patent number: 5919749Abstract: A detergent composition, which exerts sufficient detergency and foaming power even in the presence of oily stains comprising an amide ether carboxylate component (a) and an amide ether component (b), wherein the weight ratio of the content of the component (a) to the content of the component (b) is from 0.1 to 100; the molar ratio of the total divalent metal salt ions (X) in the whole composition and to total anionic surfactants (Y) including the component (a) is from 0.025 to 10; and the composition contains substantially no glycerol or glycerol ether component (z) or the content of said component (z) is not more than 10% by weight based on the sum of the contents of the components (a), (b) and (z) as defined in the specification.Type: GrantFiled: November 28, 1995Date of Patent: July 6, 1999Assignee: Kao CorporationInventors: Yuichi Sakamoto, Taeko Hayase, Kazutoshi Ide, Masaki Tosaka, Noriyuki Morii, Tomoko Shibata
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Patent number: 5919743Abstract: The present invention deals with a process for conditioning hair and skin using a novel guerbet based quat compounds. These materials are useful in personal care applications, where mildness, skin feel and conditioning on hair are desired.Type: GrantFiled: December 28, 1998Date of Patent: July 6, 1999Assignee: Petroferm Inc.Inventor: Anthony J. O'Lenick, Jr.
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Patent number: 5914310Abstract: According to the invention, an improved class of amphoteric surfactant having improved surfactant properties characterized as mild and environmentally safe has been provided comprising compounds of the formula: ##STR1## The amphoteric surfactant of the subject invention have at least two hydrophobic moieties and at least two hydrophilic groups per molecule and are useful as emulsifiers, detergents, dispersants and solubilizing agents.Type: GrantFiled: July 30, 1997Date of Patent: June 22, 1999Assignee: Rhodia Inc.Inventors: Ji Li, Manilal Dahanayake, Robert Lee Reierson, David James Tracy
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Patent number: 5891836Abstract: Disclosed are light-duty liquid or gel dishwashing detergent compositions that are especially useful for the manual washing of heavily soiled dishware. Such compositions are in the form of oil-in-water or bicontinuous microemulsions. They essentially contain an alkyl ether sulfate-based anionic surfactant, a polyhydroxy fatty acid amide-based nonionic surfactant component, a suds booster which is preferably an amine oxide, an aqueous liquid carrier, a liquid hydrocarbon such as isoparaffin and an glycol ether microemulsion-forming solvent.Type: GrantFiled: May 14, 1998Date of Patent: April 6, 1999Assignee: The Procter & Gamble CompanyInventor: Mark Leslie Kacher
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Patent number: 5888955Abstract: Liquid dishwashing detergent compositions comprising a co-surfactant selected from amine oxides, betaines, branched alkyl carboxylates and non bridged polyhydroxy fatty acid amides. The dishwashing composition further comprises a bridged polyhydroxy fatty acid amide for improved sudsing performance.Type: GrantFiled: February 4, 1997Date of Patent: March 30, 1999Assignee: The Procter & Gamble CompanyInventors: Peter Robert Foley, Joanna Margaret Clarke, Yi-Chang Fu, Phillip Kyle Vinson
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Patent number: 5888949Abstract: A cleaning additive containing (a) from about 8 to about 16% by weight of a nonionic sugar surfactant selected from the group consisting of alkyl glucose esters, aldobionamides, gluconamides, glyceramides, glyceroglycolipids, polyhydroxy fatty acid amides, an alkyl polyglycoside of formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6, and mixtures thereof; (b) from about 3 to about 7% by weight of a C.sub.8 -C.sub.16 quaternary ammonium salt; and (c) remainder water, all weights being based on the weight of the additive.Type: GrantFiled: January 8, 1997Date of Patent: March 30, 1999Assignee: Henkel CorporationInventors: Howard Cole, Brian Francois
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Patent number: 5888958Abstract: A process for forming solid cast detergent products comprising the steps of: (a) forming an aqueous detergent slurry comprising from about 60 to about 90 parts by weight of solid detergent ingredients, per 100 parts of total detergent slurry weight, said solid detergent ingredients comprising: (i) from about 5 to about 50 parts by weight of a surfactant; (ii) from about 0.1 to about 10 parts by weight of a salt-form builder component; (iii) from about 30 to about 75 parts by weight of a hydrated alkaline component; (b) adding from about 0.5 to about 10 parts by weight of a sugar surfactant selected from the group consisting of an alkyl polyglycoside, a glucamide, and mixtures thereof, to form a uniform dispersion; and (c) casting said uniform dispersion to form a solid cast detergent product.Type: GrantFiled: February 24, 1998Date of Patent: March 30, 1999Assignee: Henkel CorporationInventors: Allen D. Urfer, Virginia L. Lazarowitz
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Patent number: 5888960Abstract: A surfactant composition comprising a combination of: (1) a surfactant mixture containing: (a) from about 4 to about 35 wt % actives of a linear alkyl sulfonate; and (b) from about 1 to about 20 wt % actives of an alkyl polyglycoside having the general formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6, and (2) a foam additive containing a blend of: (c) from about 0.5 to about 4 wt % actives of an amide having the general formula (II): ##STR1## wherein R.sub.3 is an alkyl group containing from about 8 to about 18 carbon atoms and each R.sub.4 is the same or different and is selected from the group consisting of hydrogen, C.sub.13 alkyl, C.sub.1-3 alkanol, and --(C.sub.2 H.sub.Type: GrantFiled: July 16, 1996Date of Patent: March 30, 1999Assignee: Henkel CorporationInventors: Virginia Lazarowitz, Mary Frances Frazer
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Patent number: 5885955Abstract: An amide represented by the following formula (1): ##STR1## wherein R.sup.1 and R.sup.2 are C1-C24 alkyl, etc.; B is C2-C10 alkylene, etc.; A.sup.1 and A.sup.2 are C1-C6 alkylene, etc.; Y.sup.1 and Y.sup.2 are ##STR2## wherein R.sup.3, R.sup.4, and R.sup.5 are C1-C4 alkyl, etc., and X.sup.1 is halogen; or a salt of the amide and detergent compositions containing the amide or salt are mild to the skin or hair, provide a pleasant sensation to the skin or hair, and have excellent latherability and emulsion stability. These compounds are useful as components of various detergents and cosmetic compositions, emulsifiers, and conditioners.Type: GrantFiled: November 12, 1997Date of Patent: March 23, 1999Assignee: Kao CorporationInventors: Mitsuru Uno, Tetsuya Miyajima, Tomohito Kitsuki, Katsumi Kita
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Patent number: 5883070Abstract: A process for making a stabilized aqueous zeolite suspension involving: (a) providing an aqueous zeolite suspension; (b) providing at least one nonionic sugar surfactant; (c) providing at least one electrolyte; and (d) adding the sugar surfactant and electrolyte to the aqueous zeolite suspension to form a stabilized aqueous zeolite suspension.Type: GrantFiled: October 8, 1997Date of Patent: March 16, 1999Assignee: Henkel CorporationInventors: Allen D. Urfer, Virginia Lazarowitz
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Patent number: 5863886Abstract: A surfactant composition comprising compounds of the general formula: ##STR1## wherein R(CO).sub.n -- and R.sub.1 (CO).sub.n can be the same or different and comprise a C.sub.1 to C.sub.30 alkyl, or alkyl aryl and R.sub.2 is a C.sub.1 to C.sub.10 alkylene, arylene and the hydroxy-substituted derivatives thereof, a polyether (--O(R.sub.4 O).sub.x --) wherein R.sub.4 is a C.sub.2 to C.sub.4 alkyl and x is a whole number of from 1 to about 100; --S--, --SO.sub.2 --, --O--, --S--S--, --O--R.sub.5 --O-- or --S--R.sub.5 --S wherein R.sub.5 is a C.sub.1 to C.sub.10 alkyl, aryl or alkyl aryl, --N(R.sub.6)-- or --(NR.sub.6) R.sub.7 (NR.sub.6)-- wherein R.sub.6 is a C.sub.2 to C.sub.6 alkyl and R.sub.7 is a C.sub.2 to C.sub.6 alkyl or aryl with the further stipulation that R.sub.6 and R.sub.7 may form a heterocyclic ring, X is O or NZ wherein Z is a C.sub.1 to C.sub.10 alkyl, aryl, alkylaryl or hydrogen, and Y and Y.sub.1 represents an alcohol-containing group having at least two and preferably more hydroxyl groups.Type: GrantFiled: September 3, 1997Date of Patent: January 26, 1999Assignee: Rhodia Inc.Inventors: David James Tracy, Ruoxin Li, Jiang Yang
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Patent number: 5858957Abstract: A process for the manufacture of detergent compositions from a surfactant paste which is substantially in the solid phase at temperatures of 25.degree. C. and below comprises the steps of: (i) mixing the surfactant paste at a temperature above its softening point, the surfactant paste comprising at least 50% by weight of nonionic surfactant; (ii) forming the molten surfactant paste into drops on a cooling surface; (iii) forming solid pastilles by cooling the drops of molten surfactant paste; and (iv) removing solidified pastilles from the cooling surface.Type: GrantFiled: September 23, 1997Date of Patent: January 12, 1999Assignee: The Procter & Gamble CompanyInventors: Scott John Donoghue, David John Smith
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Detergent compositions with optimized surfactant systems to provide dye transfer inhibition benefits
Patent number: 5804543Abstract: Disclosed are detergent compositions and methods which are suitable for washing colored fabrics in aqueous washing solution with little or no transfer of dye between fabrics. The compositions utilized comprise certain nil-LAS detersive surfactants, detergent builder and certain selected polymeric dye transfer inhibiting agents. The detersive surfactants used must comprise alkyl ether sulfates and certain types of nonionic surfactants (polyhydroxy fatty acid amides and/or alcohol ethoxylates). The polymeric dye transfer inhibiting agents are polyamine N-oxides such as poly(4-vinylpyridine-N-oxide), i.e., PVNO and/or copolymers of N-vinylpyrrolidone and N-vinylimidazole, i.e., PVPVI.Type: GrantFiled: July 19, 1996Date of Patent: September 8, 1998Assignee: The Procter & Gamble CompanyInventors: William C. Wertz, Rajan K. Panandiker -
Patent number: 5801270Abstract: The present invention relates to an amine derivative represented by the following general formula (1): ##STR1## wherein R.sup.2 and R.sup.3 mean individually an alkyl or alkenyl group which may have --OH and has 1-24 carbon atoms, A denotes an alkylene or alkenylene group which may have at least one --OH, --COOH or --SO.sub.3 H and has 1-6 carbon atoms, Y.sup.1 is --COOH, --SO.sub.3 H or --OSO.sub.3 H, Y.sup.2 means --OH, --OSO.sub.3 H or --OCO--A--COOH, n stands for a number of 0 or 1, and p is an integer of 1-8, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.Type: GrantFiled: June 13, 1996Date of Patent: September 1, 1998Assignee: Kao CorporationInventors: Mitsuru Uno, Tomohito Kitsuki, Katsumi Kita, Yoshiaki Fujikura, Akiko Okutsu
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Patent number: 5789372Abstract: Surfactant mixtures having improved surface-active properties containinga) fatty acid-N-alkyl polyhydroxyalkylamides corresponding to formula (I): ##STR1## in which R.sup.1 CO is an aliphatic acyl radical containing 6 to 10 carbon atoms, R.sup.2 is hydrogen, an alkyl or hydroxyalkyl radical containing 1 to 4 carbon atoms and ?Z! is a linear or branched polyhydroxyalkyl radical containing 3 to 12 carbon atoms and 3 to 10 hydroxyl groups, andb) fatty acid-N-alkyl polyhydroxyalkylamides corresponding to formula (II): ##STR2## in which R.sup.3 CO is an aliphatic acyl radical containing 12 to 22 carbon atoms, R.sup.4 is hydrogen, an alkyl or hydroxyalkyl radical containing 1 to 4 carbon atoms and ?Z! is a linear or branched polyhydroxyalkyl radical containing 3 to 12 carbon atoms and 3 to 10 hydroxyl groups,the ratio by weight between components a) and b) being from 80:20 to 20:80.Type: GrantFiled: September 15, 1997Date of Patent: August 4, 1998Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Bernd Fabry
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Patent number: 5783535Abstract: The present invention relates to a detergent composition which comprises (A) an amidoether derivative mixture (A) comprising an amidoether carboxylic acid or a salt thereof, an amidoether, and a glycerin derivative; and (B) a conditioning component, wherein the total amount of the amidoether carboxylic acid or a salt thereof and the amidoether is 50 wt % or more; the weight ratio of the amidoether carboxylic acid or a salt thereof to the amidoether is from 99:1 to 10:90; and the amount of the glycerin derivative is 5 wt % or less.Type: GrantFiled: June 17, 1997Date of Patent: July 21, 1998Assignee: Kao CorporationInventors: Kazuo Isobe, Toshikazu Azuma, Hideyo Nishikawa, Takashi Imamura
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Patent number: 5780411Abstract: A high foaming, nonionic surfactant based, light duty, liquid detergent with desirable cleansing properties and mildness to the human skin comprising: a water soluble nonionic surfactant as the major active ingredient, in an amount in excess of 40% by weight of the total surfactant content; a water soluble, foaming, anionic sulfate, a water soluble, foaming zwitterionic betaine surfactant, a pearlescing agent and the balance being water.Type: GrantFiled: June 9, 1997Date of Patent: July 14, 1998Assignee: Colgate-Palmolive CompanyInventor: Rita Erilli
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Patent number: 5776882Abstract: The present invention relates to isotropic liquids in which hydrophobically modified polar polymers having much higher ratios of hydrophile:hydrophobe than previously possible can be incorporated into the compositions. The compositions comprise greater than 17% to 85% surfactant and rate of hydrophile to hydrophobe on the polymers is greater than 7:1, preferably greater than 20:1, preferably 25:1 and up and most preferably no upper limit.Type: GrantFiled: January 14, 1997Date of Patent: July 7, 1998Assignee: Lever Brothers Compay, Division of Conopco, Inc.Inventor: Tirucherai Varahan Vasudevan
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Patent number: 5756446Abstract: A surfactant composition containing: (a) a nonionic sugar surfactant selected from the group consisting of alkyl glucose esters, aldobionamides, gluconamides, glyceramides, glyceroglycolipids, polyhydroxy fatty acid amides, alkyl polyglycosides having the general formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6, and mixtures thereof; and(b) an additive consisting of a copolymer of acrylamide and dimethyl diallyl ammonium chloride.Type: GrantFiled: May 7, 1996Date of Patent: May 26, 1998Assignee: Henkel CorporationInventors: Patricia E. Bator, Arturo Valdes
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Patent number: 5750733Abstract: The present invention relates to novel hydroxy-containing alkyl glycamide surfactants and detergent composition comprising said surfactants. Since they surprisingly provide low foam, these surfactants can be used as cleansing surfactants in applications where low foaming is desirable.Type: GrantFiled: August 6, 1996Date of Patent: May 12, 1998Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Robert Vermeer, Bijan Harichian
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Patent number: 5750748Abstract: A process for the preparation of a surfactant composition comprising N-methyl polyhydroxy fatty acid amide and N-alkyl (C3-C8) polyhydroxy fatty acid amide comprises mixing N-methyl polyhydroxy fatty acid amine and N-alkyl (C3-C8) polyhydroxy fatty acid amine to form a mixture. The mixture is reacted with a fatty acid ester reactant in the presence of a base catalyst and, optionally, in the presence of a reaction solvent. Unreacted N-alkoxyamino polyol is acylated with an acid anhydride at a temperature in the range of from 50.degree. C. to 85.degree. C. The weight ratio of N-methyl polyhydroxy fatty acid amide to N-alkyl (C3-C8) polyhydroxy fatty acid amide in the surfactant composition is from 25:1 to 1:1.Type: GrantFiled: April 19, 1996Date of Patent: May 12, 1998Assignee: The Procter & Gamble CompanyInventors: Jean-Pol Boutique, Patrick Firmin A. Delplancke
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Patent number: 5747440Abstract: Modified polyamines comprise polyalkyleneoxy or carboxylate-like or carboxylate-derived substituents or mixtures thereof, said polyamines are useful in laundry detergent compositions, presoak compositions or conditioning compositions for the control of dye fabric color loss or fading or for the prevention of graying or yellowing of white fabric. The present invention also relates to a method for preventing the fading of colored fabric or the build up yellow or gray color on white fabric.Type: GrantFiled: January 30, 1996Date of Patent: May 5, 1998Assignee: Procter & Gamble CompanyInventors: Patti Jean Kellett, Eugene Paul Gosselink, Christopher Mark Perkins
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Patent number: 5736503Abstract: Detergent compositions with high sudsing properties comprise an anionic surfactant of the alkyl sulfate, alkyl ethoxy sulfate, 2-sulfonated fatty acid methyl esters, alkyl benzene sulfonates, secondary alkyl or alkenyl sulfates, alkyl ethoxy carboxylates, sulfated or polyhydroxy fatty acid amides class, and a specially selected soap such as sodium 2-butyl-1-octanoate. The compositions provide spontaneous emulsification of grease even at neutral pH, especially in the presence of calcium ions. Sudsing may optionally be boosted by incorporating magnesium ions into the compositions. Laundry and dishwashing compositions are provided. Compositions containing a polyhydroxy fatty acid amide, sulfated polyhydroxy fatty acid amide, or alkyl ethoxy carboxylate are especially useful.Type: GrantFiled: January 3, 1997Date of Patent: April 7, 1998Assignee: The Procter & Gamble CompanyInventor: Phillip Kyle Vinson
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Patent number: 5728661Abstract: The subject of the invention is the compounds of formula: ##STR1## in which R denotes a saturated or unsaturated, linear or branched alkyl group containing from 5 to 21 carbon atoms.The invention also relates to a process for the preparation of the abovementioned compounds, characterized in that it consists ina) forming an N-acylglucosamine from glucosamine hydrochloride and C.sub.6 -C.sub.22 acid chloride, andb) reacting the compound from stage a) with glycerol in the presence of an acid catalyst.It also relates to detergent or cosmetic compositions including the abovementioned compounds.Type: GrantFiled: October 21, 1996Date of Patent: March 17, 1998Assignees: Elf Atochem, S.A., Ceca S.A.Inventors: Serge Petit, Daniel Bernard, Henri-Jean Caupin
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Patent number: 5723435Abstract: The present invention relates to fabric care compositions to reduce the fading of fabrics from sunlight, comprising:(A) from about 1% to about 25% by weight of the composition of a non-fabric staining, light stable antioxidant compound, preferably containing at least one C.sub.8 -C.sub.22 hydrocarbon fatty organic moiety;(B) from 3% to about 50% by weight of the composition of a fabric softening compound;(C) from about 25% to about 95% by weight of the composition of a carrier material; and(D) optionally, from about 0% to about 20% by weight of the composition of a non-fabric staining, light stable sunscreen compound, preferably containing at least one C.sub.8 -C.sub.22 hydrocarbon fatty organic moiety;wherein the antioxidant compound is a solid material having a melting point of less than about 80.degree. C. or is a liquid at a temperature of less than about 40.degree. C.Type: GrantFiled: February 5, 1996Date of Patent: March 3, 1998Assignee: The Procter & Gamble CompanyInventors: John Cort Severns, Mark Robert Sivik, Ellen Schmidt Baker, Frederick Anthony Hartman
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Patent number: 5716922Abstract: Gelled detergent compositions comprise a polyhydroxy fatty acid amine surfactant and an alkyl alkoxylated sulfate surfactant. Gels form spontaneously without the need for extraneous gelling agents. Thus, a mixture of coconutalkyl N-methyl glucamide and an AEmS surfactant gels in water to provide a composition which is useful for cleaning hard surfaces, especially tableware. Grease-cutting gels which contain magnesium and/or calcium ions are also provided.Type: GrantFiled: November 20, 1996Date of Patent: February 10, 1998Assignee: The Procter & Gamble CompanyInventors: John Downing Curry, Alan Edward Sherry, Dale Alan Gregory, Edgar Manual Marin Carrillo
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Patent number: 5714448Abstract: The invention provides an aqueous, hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising:(a) an effective amount of at least one organic solvent with a vapor pressure of at least 0.001 mm Hg at 25.degree. C., and mixtures of such solvents;(b) an effective amount of at least one semi-polar nonionic surfactant, said surfactant having the structure: ##STR1## wherein R.sup.1 is C.sub.5-20 alkyl, R.sup.2 and R.sup.3 are both C.sub.1-4 alkyl, ##STR2## or --(CH.sub.2).sub.p --OH, although R.sup.2 and R.sup.3 do not have to be equal, and n is 1-5, and p is 1-6;(c) an effective amount of a buffering system which comprises a nitrogenous buffer which will result in a pH of greater than 6.5; and(d) the remainder as substantially all water.Type: GrantFiled: December 16, 1996Date of Patent: February 3, 1998Assignee: The Clorox CompanyInventors: Clement K. Choy, Aram Garabedian, Jr., Jennifer C. Julian, Gary L. Robinson
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Patent number: 5714446Abstract: Disclosed are hair conditioning shampoo compositions comprising(a) from about 5% to about 50%, by weight, of an anionic surfactant component;(b) from about 0.1% to about 10%, by weight, of a dispersed, insoluble, nonionic silicone hair conditioning agent, said silicone hair conditioning agent comprising a non-volatile, insoluble, nonionic silicone fluid component;(c) from about 0.2% to about 10%, by weight, of a soluble cationic, amino or quaternary ammonium conditioning surfactant having a cationic nitrogen atom and at least one N-radical containing one or more hydrophilic moieties that are within 4 carbon atoms (inclusive) of a cationic nitrogen, said hydrophilic moieties being selected from the group consisting of alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, and alkylester moieties, and combinations thereof; and(d) an aqueous carrier.Type: GrantFiled: February 8, 1995Date of Patent: February 3, 1998Assignee: The Procter & Gamble CompanyInventors: Lisa Jo Bartz, James David Landgrebe, Robert Lee Wells
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Patent number: 5712232Abstract: An aqueous liquid cleansing composition, packaged in a foamer container, said composition comprising:(A) from 5 to 50% by weight of an anionic carboxylate surfactant; and(B) from 0.1 to 5% by weight of a salt.The aqueous liquid cleansing composition of the present invention shows an extremely low viscosity increase at a low temperature and can be easily pushed out from the foamer container even at a low temperature thus giving uniform foam. It is particularly suitable for a skin cleanser.Type: GrantFiled: September 14, 1995Date of Patent: January 27, 1998Assignee: Kao CorporationInventors: Masaaki Moriyama, Hisateru Tanabe, Hideyuki Hanazawa, Yasushi Kajihara