Liquid Composition Patents (Class 510/527)
  • Patent number: 5877145
    Abstract: Biodegradable fabric softener compounds that contain ester linkages a substantial level of polyunsaturation in the hydrophobic chains. The compounds can be used to form fabric softening compositions that are aqueous dispersions of the compounds or clear compositions. These compositions have a desirable low viscosity and recover, after freezing and thawing to have a stable low viscosity.
    Type: Grant
    Filed: January 26, 1998
    Date of Patent: March 2, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Errol Hoffman Wahl, Helen Bernardo Tordil, Toan Trinh, Eugene Robert Carr, Robert Otis Keys, Laura Marie Meyer, Hugo Jean Marie Demeyere, Dean Larry DuVal, Mitsuyo Okamoto
  • Patent number: 5861370
    Abstract: Biodegradable fabric softener premix compositions are described containing (1) biodegradable softener actives that contain substantial unsaturation and (2) perfume. The premixes can be added at ambient temperatures to water containing acid, to provide a pH of from about 1.5 to about 5, to form finished compositions. The water can also contain calcium and/or magnesium salt to modify the viscosity.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: January 19, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Toan Trinh, George Joseph Harvey, Helen Bernardo Tordil, Hugo Jean Marie Demeyere, Marc Johan Declercq, Errol Hoffman Wahl
  • Patent number: 5858960
    Abstract: A fabric softening composition comprising a compound of formula I ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are independently selected from C.sub.1 -C.sub.4 alkyl groups or C.sub.2 -C.sub.4 alkenyl groups, a is from 1 to 4, x.sup.- is a compatible anion and R.sup.4 and R.sup.5 are independently selected from C.sub.12 -C.sub.22 alkyl or alkenyl groups, the sum of the chain lengths or R.sup.4 and R.sup.5 preferably being at least 30.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: January 12, 1999
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: James Patrick Conroy, Stephen Graham Hales, Abid Nadim Khan-Lodhi
  • Patent number: 5854201
    Abstract: The invention relates to textile softener concentrates based on pentaerythritol and/or dipentaerythritol fatty acid partial esters. The dispersibility of such softener concentrates in cold water can be significantly improved by addition of a special emulsifier combination of quaternary ammonium compounds and nonionic compounds. The quaternary ammonium compounds are quaternized alkoxylated alkylamines and/or esterquats. Ethoxylated and/or propoxylated fatty acids or fatty acid esters and end-capped fatty alcohol polyglycol ethers are suitable nonionic emulsifiers.
    Type: Grant
    Filed: July 10, 1997
    Date of Patent: December 29, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ansgar Behler, Guenther Uphues, Bernd Wahle, Peter Waltenberger, Almud Folge
  • Patent number: 5851982
    Abstract: To provide a liquid softener composition which is satisfactory in respects of softening effect, storage stability and water absorption properties, is excellent in biodegradability and is gentle with the environment. A liquid softener composition comprising 3 to 40% by weight of a quaternary ammonium salt (7-I) and water ##STR1## wherein R.sup.1 represents C.sub.20 -C.sub.44 alkyl or alkenyl group; R.sup.2, R.sup.3, and R.sup.4 are the same of different from each other and are C.sub.1 -C.sub.5 alkyl or hydroxyalkyl group; Y represents C.sub.2 -C.sub.4 alkylene group; m is a number of 0 to 20; n is an integer of 1 to 6; and X.sup.- represents an anion group.
    Type: Grant
    Filed: March 27, 1996
    Date of Patent: December 22, 1998
    Assignee: Kao Corporation
    Inventors: Yuushi Sakata, Junichi Inokoshi, Osamu Tachizawa, Tohru Katoh, Uichiro Nishimoto, Yasuki Ohtawa, Akira Sakaguchi, Kohshiroh Sotoya, deceased, Noriko Yamaguchi
  • Patent number: 5830845
    Abstract: Biodegradable fabric softener compounds that contain ester linkages a substantial level of polyunsaturation in the hydrophobic chains. The compounds can be used to form fabric softening compositions that are aqueous dispersions of the compounds. These compositions have a desirable low viscosity and recover, after freezing and thawing to have a stable low viscosity.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: November 3, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Toan Trinh, George Joseph Harvey, Helen Bernardo Tordil, Errol Hoffman Wahl
  • Patent number: 5773409
    Abstract: A fabric softening composition is described which has a substantially water-insoluble fabric softening compound and a solubilizing agent which is a non-ionic surfactant and may include a non-surfactant cosolubilizer. The composition is up to at least 70 wt. % soluble when diluted in water to a concentration of 5 wt. % of the mixture of the fabric softening compound and the solubilizing agent. The fabric softening compound comprises a head group and two alkyl or alkenyl chains each having an average chain link equal to a greater than C.sub.14 or a single alkyl or alkenyl chain with an average chain link equal to a greater than C.sub.20.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: June 30, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Ziya Haq, Abid Nadim Khan-Lodhi, Philip John Sams
  • Patent number: 5773405
    Abstract: The present invention relates to a surface cleaner composition comprising:1) from 0.1 to 70% of tensoactive, or mixtures thereof;2) from 0 to 95% builder/softener;3) from 0 to 99.9% solvent;4) from 0 to 50% hydrotrope; and5) from 1 to 5000 ppm of a poly(oxyalkylene)-substituted colorant which is liquid in its undiluted state having the structure ABXYZ, where AB is a reactive dye moiety whereinA is an organic chromophore;B is and electrophilic reactive group covalently bonded to A directly or through a linking group;X is a nucleophilic linking group covalently bonding B and Y, selected from the group consisting of NR, O, S, and 4-oxyanilino (--HN--Ph--O--); where R is selected from the group consisting of H, alkyl, aryl, and YZ;Y is a poly(oxyalkylene)-containing moiety; andZ is a terminal group for Y.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: June 30, 1998
    Assignee: Milliken Research Corporation
    Inventor: John D. Bruhnke
  • Patent number: 5770552
    Abstract: The present invention relates to a laundry detergent composition, e.g, granular or liquid, comprising:a) from 5 to 70% of tensoactive, or mixtures thereof,b) from 2 to 95% builders;c) from 0 to 25% additives; andd) from 1 to 5000 ppm of a poly(oxyalkylene)-substituted colorant which is liquid in its undiluted state having the structure ABXYZ, where AB is a reactive dye moiety whereinA is an organic chromophore;B is an electrophilic reactive group covalently bonded to A directly or through a linking group;X is a nucleophilic linking group covalently bonding B and Y, selected from the group consisting of NR, O, S, and 4-oxyanilino (--HN--Ph--O--); where R is selected from the group consisting of H, alkyl, aryl, and YZ;Y is a poly(oxyalkylene)-containing moiety; andZ is a terminal group for Y.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: June 23, 1998
    Assignee: Milliken Research Corporation
    Inventor: John D. Bruhnke
  • Patent number: 5770557
    Abstract: A fabric softener composition comprising:a) from 3 to 50% by weight of fabric softener, or mixtures thereof;b) a liquid carrier including water, the pH of the composition being less than 7, andc) from 1 ppm to 5000 ppm of a poly(oxyalkylene)-substituted colorant which is a liquid in its undiluted state having the structure ABXYZ, where B is a reactive dye moiety whereinA is an organic chromophore;B is an electrophilic reactive group covalently bonded to A directly or through a linking group;X is a nucleophilic linking group covalently bonding B and Y, selected from the group conisting of NR, O, S, and 4-oxyanilino (--HN--Ph--O--); where R is selected from the group consisting of H, alkyl, aryl, and YZ;Y is a poly(oxyalkylene)-containing moiety; andZ is a terminal group for Y.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: June 23, 1998
    Assignee: Milliken Research Corporation
    Inventor: John D. Bruhnke
  • Patent number: 5759990
    Abstract: Biodegradable fabric softener compounds that contain ester linkages a substantial level of polyunsaturation in the hydrophobic chains. The compounds can be used to form fabric softening compositions that are aqueous dispersions of the compounds or clear compositions. These compositions have a desirable low viscosity and recover, after freezing and thawing to have a stable low viscosity.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: June 2, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Errol Hoffman Wahl, Helen Bernardo Tordil, Toan Trinh, Eugene Robert Carr, Robert Otis Keys, Laura Marie Meyer
  • Patent number: 5750492
    Abstract: Cationic surfactant compound comprising, in the form of a quaternary ammonium salt, a product of condensation between, on the one hand a fraction of saturated or unsaturated fatty acids, or of derivatives of said acids chosen from the group comprising esters, anhydrides and acid chlorides, and on the other hand at least one tertiary amine, characterized in that, in combination:the alkyl chains of the tertiary amine together contain from 4 to 12 carbon atomsthe alkyl chains of the tertiary amine together contain from 1 to 4 functions each chosen from the group comprising hydroxyl and amine functionsthe fatty acids fraction/tertiary amine mole ratio is between 1.85 and 1.40the fatty acids each possess a hydrocarbon chain in which the number of carbon atoms is between 5 and 23.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: May 12, 1998
    Assignee: Stepan Europe
    Inventors: Jean-Pierre Contet, Stephane Courdavault Duprat, Yvan Storet, Jean-Francois Vindret
  • Patent number: 5721205
    Abstract: Fabric softening compositions comprising fabric softening active(s), cellulase and an antioxidant effective amount of free radical scavenging antioxidant material and/or chelant.
    Type: Grant
    Filed: March 12, 1997
    Date of Patent: February 24, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Mary Vijayarani Barnabas, Kimberley Suzanne Severin, Scott William Waite
  • Patent number: 5703035
    Abstract: The disclosed invention relates to aqueous fabric softeners containingA) 22-30% by weight of at least one compound of the general formula (1) ##STR1## B) 0-7% by weight of one or more amides of the general formula (2)?R.sup.11 --C(O)NH--(CH.sub.2).sub.3 --N(CH.sub.3).sub.2 R.sup.12 !.sup.+ A.sup.- (2)C) 0.5-6% by weight of one or more compounds of the general formula (3) ##STR2## and electrolyte salts, perfume oils, short-chain alcohol and water.
    Type: Grant
    Filed: October 16, 1996
    Date of Patent: December 30, 1997
    Assignee: Witco Surfactants GmbH
    Inventors: Horst Birkhan, Michael Fender, Bernhard Irrgang, Christiane Loffert, Simone Schussler
  • Patent number: 5696070
    Abstract: A liquid softener composition comprising a quaternary ammonium salt represented by the general formula (1) and a method for its preparation: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 are an alkyl group or hydroxyalkyl group of 1 to 4 carbon atoms, R.sup.4 and R.sup.5 are an unsubstituted or hydroxyl group-substituted linear or branched alkyl group or alkenyl group of 8 to 36 carbon atoms, A is a linear or branched alkylene group of 2 or 3 carbon atoms, X is an anion group, n is an integer in the range of 1 to 6, and m is a numeral in the range of 0 to 20.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: December 9, 1997
    Assignee: Kao Corporation
    Inventors: Osamu Tachizawa, Akira Sakaguchi, Tohru Katoh, Kohshiro Sotoya, deceased, Noriko Yamaguchi, Junichi Inokoshi, Muneo Aoyagi
  • Patent number: 5663138
    Abstract: Novel fabric conditioning compounds derived from glycerol and betaine are described. Fabric conditioning compositions containing the compounds, which provide effective fabric softening and antistatic benefits are also described.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: September 2, 1997
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Leonora Marie Ilardi, Stephen Alan Madison
  • Patent number: 5652205
    Abstract: Laundry and cleaning compositions comprising a nonionic or anionic ester of an allylic alcohol perfume having the formula: ##STR1## especially geranyl and neryl esters.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: July 29, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Frederick Anthony Hartman, Mark Robert Sivik, John Cort Severns, Scott William Waite, Cynthia Lee Eddy
  • Patent number: 5645751
    Abstract: A ready-to-use fabric composition and a fabric finish concentrate composition are disclosed as well as a method of providing a stiffness to a fabric. The compositions comprise water, a water soluble polymer that casts a clear, continuous film from aqueous solution and a film-compatible silicone ironing aid/lubricant that in combination dries on clothes or textiles as a colorless and transparent, flexible film. Optionally, a preservative and, in some instances other ingredients such as fragrances and dyes may be added for aesthetic purposes.
    Type: Grant
    Filed: January 26, 1995
    Date of Patent: July 8, 1997
    Assignee: Amway Corporation
    Inventor: Kalliopi S. Haley
  • Patent number: 5616553
    Abstract: The present invention relates to aqueous fabric conditioning compositions containing a quaternary ammonium compound and/or amine precursor thereof of the formulae (I) or (II) herein, and a cellulase, said compositions having a neat pH at 20.degree. C., of from about 2.0 to about 4.5.
    Type: Grant
    Filed: August 12, 1993
    Date of Patent: April 1, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Frederick A. Hartman, Bruno A. J. Hubesch, Johan G. L. Pluyter, Manuel G. Venegas
  • Patent number: 5580481
    Abstract: To provide an aqueous fabric softener composition, which is excellent in softening performance, elasticity and storage stability, and a quaternary ammonium salt which is useful as a softening base of this composition and nondetrimental to the natural environment because of its excellent biodegradability, and a process for the preparation of this salt.The aqueous fabric softener composition of the present invention comprises from 8 to 40% by weight of a quaternary ammonium salt represented by the following formula (I), a quaternary ammonium salt represented by the following formula (II) or a mixture thereof, and water: ##STR1## wherein R.sup.1 and R.sup.2 represent each a C.sub.1-4 alkyl group, etc.; R.sup.3 and R.sup.4 represent each a C.sub.7-35 alkyl group, etc.; and X.sup.- represents an anion group; and ##STR2## wherein R.sup.5 and R.sup.6 represent each a C.sub.1-4 group, etc.; R.sup.7 and R.sup.8 represent each a C.sub.1-5 alkylene group, etc.; R.sup.9 and R.sup.10 represent each a C.sub.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: December 3, 1996
    Assignee: Kao Corporation
    Inventors: Yushi Sakata, Junichi Inokoshi, Tohru Katoh, Osamu Tachizawa, Uichiro Nishimoto, Yasuki Ohtawa, Masaaki Yamamura
  • Patent number: 5567340
    Abstract: Nitrogen-free anionic fabric softeners are provided by sulfated fatty acid partial glycerides corresponding fo formula (I): ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently of one another represent at least one aliphatic, linear or branched acyl radical containing 6 to 22 carbon atoms, at least one sulfate group and optionally a hydroxyl group, and m, n and p=0 or a number from 1 to 10.
    Type: Grant
    Filed: June 16, 1995
    Date of Patent: October 22, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ansgar Behler, Uwe Ploog, Guenther Uphues, Bernd Wahle, Peter Waltenberger, Yvonne Jansen
  • Patent number: 5545340
    Abstract: The present invention relates to softening compounds; stable, homogeneous, preferably concentrated, aqueous liquid and solid textile treatment compositions; and intermediate compositions and/or processes for making said compositions. The compositions of the present invention contain diester quaternary ammonium compounds wherein the fatty acyl groups have an Iodine Value of from greater than about 5 to less than about 100, a cis/trans isomer weight ratio of greater than about 30/70 when the Iodine Value is less than about 25, the level of unsaturation being less than about 65% by weight, wherein said compounds are capable of forming concentrated aqueous compositions with concentrations greater than about 13% by weight at an Iodine Value of greater than about 10 without viscosity modifiers other than normal polar organic solvents present in the raw material of the compound or added electrolyte.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: August 13, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Errol H. Wahl, Dennis R. Bacon, Ellen S. Baker, Jean-Francois Bodet, Michael E. Burns, Hugo J. M. Demeyere, Charles A. Hensley, Robert Mermelstein, John C. Severns, John H. Shaw, Jr., Michael P. Siklosi, Alice M. Vogel, Jeffrey W. Watson
  • Patent number: 5545350
    Abstract: Compositions are disclosed containing fabric softener compound having two hydrophobic groups attached to the remainder of the compound through ester linkages (DEQA), said compositions being concentrated and containing viscosity/dispersibility modifiers which are single long chain cationic surfactants, highly ethoxylated nonionic surfactants and/or mixtures thereof. Premixes of the DEQA and viscosity modifiers to lower the viscosity of the molten DEQA are disclosed. Processes for making aqueous liquid compositions from solid particulate compositions containing the DEQA are also disclosed.
    Type: Grant
    Filed: November 3, 1994
    Date of Patent: August 13, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Ellen S. Baker, Jean-Francois Bodet, Hugo J. M. Demeyere, Frederick A. Hartman, Bruno A. Hubesch, Robert Mermelstein, Lucille F. Taylor, Errol H. Wahl
  • Patent number: 5543067
    Abstract: Substantially waterless self-emulsifiable biodegradable chemical softening compositions are provided comprising a mixture of an ester-functional quaternary ammonium compound and a polyhydroxy compound. Preferred biodegradable ester-functional quaternary ammonium compounds include diesterdialkyl dimethyl ammonium salts such as diester ditallow dimethyl ammonium chloride, diester di(touch hydrogenated)tallow dimethyl ammonium chloride and diester di(hydrogenated)tallow dimethyl ammonium chloride. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, polyglycerols having a weight average molecular weight from about 150 to about 800 and polyoxyethylene glycols and polyoxypropylene glycols having a weight average molecular weight from about 200 to about 4000.
    Type: Grant
    Filed: November 2, 1994
    Date of Patent: August 6, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Dean V. Phan, Paul D. Trokhan, Robert G. Laughlin, Toan Trinh
  • Patent number: 5543066
    Abstract: A fabric softening composition containing as essential constituent a biodegradable quaternary ammonium compound, characterized in that the composition comprises at least one or more compounds of the formula: ##STR1## wherein X is an anion, A is an (m+n) valent radical remaining after the removal of (m+n) hydroxy groups from an aliphatic polyol having phydroxy groups and an atomic ratio of carbon to oxygen in the range of 1.0 to 3.0 and up to 2 groups per hydroxy group selected from ethylene oxide and propylene oxide, m is 0 or an integer from 1 to p-n, n is an integer from 1 to p-m, and p is an integer of at least 2, B is an alkylene or alkylidene group containing 1 to 4 carbon atoms, R.sup.1, R.sup.2, R.sup.3 and R.sup.
    Type: Grant
    Filed: July 29, 1994
    Date of Patent: August 6, 1996
    Inventors: Hans J. Weissen, Norbert Porta