Carbonyl Bonded Directly To The Ring Patents (Class 512/24)
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Patent number: 10889780Abstract: Disclosed are fragrance compositions comprising ethyl cyclohexanoate.Type: GrantFiled: May 14, 2018Date of Patent: January 12, 2021Assignee: Givaudan SAInventors: Dominique Lelievre, Alain Alchenberger, Heinz Koch
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Patent number: 10252975Abstract: The present disclosure provides compounds that are derivatives of 2,2,6-trimethylcyclohexanecarboxylate. The disclosed compounds have useful flavor and fragrance characteristics. The present disclosure also provides flavor and fragrance compositions.Type: GrantFiled: July 21, 2014Date of Patent: April 9, 2019Assignee: TAKASAGO INTERNATIONAL CORPORATIONInventors: Thalia S. Dickerson, Maureen Blandino, Michael E. Lankin
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Patent number: 8911716Abstract: The present invention concerns a compound of formula (I), in the form of any one of its stereoisomers or a mixture thereof, and wherein the dotted line represents a carbon-carbon single or double bond; as well as its use as perfuming ingredient.Type: GrantFiled: February 20, 2012Date of Patent: December 16, 2014Assignee: Firmenich SAInventor: George Lem
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Patent number: 8907134Abstract: The present invention relates to 1-(5-ethyl-5-methyl-1-cyclohexen-1-yl)-4-penten-1-one and its use as perfuming ingredient.Type: GrantFiled: January 23, 2012Date of Patent: December 9, 2014Assignee: Firmenich SAInventor: Anthony A. Birkbeck
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Patent number: 8877704Abstract: Disclosed are certain compounds according to the general formula (I) and their use as flavoring and fragrancing compounds, as well as fragranced and flavored compositions comprising the compounds of formula (I), and methods for providing a flavor or fragrance to compositions and articles utilizing the compounds of formula (I).Type: GrantFiled: October 11, 2013Date of Patent: November 4, 2014Assignee: Givaudan SAInventors: Jean-Pierre Bachmann, Felix Flachsmann
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Patent number: 8691746Abstract: The present invention relates to a process for the production of formyl cyclohexene derivatives which are suitable as odorants as such or as intermediates for the preparation of further odorants. In particular the present invention relates to a domino-methylenation-Diels-Alder reaction of ?,?-unsaturated aldehydes using formaldehyde in the presence of 1,3-butadienes.Type: GrantFiled: October 8, 2012Date of Patent: April 8, 2014Assignee: Givaudan SAInventors: Andreas Goeke, Yue Zou
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Publication number: 20130310293Abstract: The present invention relates to 1-(5-ethyl-5-methyl-1-cyclohexen-1-yl)-4-penten-1-one and its use as perfuming ingredient.Type: ApplicationFiled: January 23, 2012Publication date: November 21, 2013Applicant: FIRMENICH SAInventor: Anthony A. Birkbeck
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Patent number: 8383574Abstract: The present invention relates to a perfume composition as a raw material of fruity perfumes which has a conventionally unknown peculiar fresh, woody, floral, grassy-leafy nuance and is capable of harmonizing with various perfumes to provide perfume preparations having a more sophisticated odor or scent. The perfume composition of the present invention includes a compound represented by the general formula (I): wherein R1 and R2 are each independently a hydrocarbon group having 1 to 4 carbon atoms; and R3 is a hydrocarbon group having 2 to 4 carbon atoms.Type: GrantFiled: March 2, 2009Date of Patent: February 26, 2013Assignee: Kao CorporationInventors: Shinji Kotachi, Shinya Nagasawa, Satoshi Ohno
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Publication number: 20130035278Abstract: The present invention relates to a process for the production of formyl cyclohexene derivatives which are suitable as odorants as such or as intermediates for the preparation of further odorants.Type: ApplicationFiled: October 8, 2012Publication date: February 7, 2013Applicant: GIVAUDAN SAInventor: Givaudan SA
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Solubilization of cyclohexane-based carboxamide derivatives for use as sensates in consumer products
Patent number: 8277824Abstract: Disclosed are methods of solubilizing various coolants, in particular cyclohexane-based carboxamide derivatives to facilitate formulating these coolants into a wide variety of consumer products, including those for oral cavity, throat, skin and hair care applications. Suitable solvents are those that provide at least 5% concentrated solutions of these coolants. Particularly preferred solvents are those used in the perfume and flavor industries and are GRAS materials that do not contribute formulation difficulties or negative aesthetics.Type: GrantFiled: August 14, 2009Date of Patent: October 2, 2012Assignee: The Procter & Gamble CompanyInventor: John Christian Haught -
Patent number: 8222199Abstract: The present invention concerns the use as perfuming ingredient of a lower alkyl ester of 4,6,6-trimethyl-1,3-cyclohexadiene-1-carboxylate or 4,6,6-trimethyl-3-cyclohexene-1-carboxylate. These compounds are able to impart odor notes of the spicy/saffron type.Type: GrantFiled: February 22, 2007Date of Patent: July 17, 2012Assignee: Firmenich SAInventors: Charles Fehr, Pierre-Alain Blanc
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Patent number: 8022030Abstract: The present invention relates to the field of perfumery. More particularly, it concerns co-polymers, derived from a maleic anhydride derivative and a ethylenic derivative, comprising at least one ?-oxy or ?-thio carbonyl moiety capable of liberating an active molecule such as, for example, an ?,?-unsaturated ketone, aldehyde or carboxylic ester. The present invention concerns also the use of polymers or co-polymers in perfumery as well as the perfuming compositions or perfumed articles comprising the invention's compounds.Type: GrantFiled: October 5, 2007Date of Patent: September 20, 2011Assignee: Firmenich SAInventors: Damien Berthier, Andreas Herrmann
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Publication number: 20110071070Abstract: The present invention relates to a perfume composition as a raw material of fruity perfumes which has a conventionally unknown peculiar fresh, woody, floral, grassy-leafy nuance and is capable of harmonizing with various perfumes to provide perfume preparations having a more sophisticated odor or scent. The perfume composition of the present invention includes a compound represented by the general formula (I): wherein R1 and R2 are each independently a hydrocarbon group having 1 to 4 carbon atoms; and R3 is a hydrocarbon group having 2 to 4 carbon atoms.Type: ApplicationFiled: March 2, 2009Publication date: March 24, 2011Applicant: KAO CORPORATIONInventors: Shinji Kotachi, Shinya Nagasawa, Satoshi Ohno
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Patent number: 7812195Abstract: The present invention relates to substituted cyclohexenyl butenones of the formula wherein R1, R2, R3, R4 and R5 are independently selected from hydrogen, methyl or ethyl; and the total sum of carbon atoms is 11 to 15; as well as to a method for their production and to fragrance compositions and fragrance applications comprising them.Type: GrantFiled: December 11, 2007Date of Patent: October 12, 2010Assignee: Givaudan SAInventors: Thierry Granier, Andreas Hart, Jerzy A. Bajgrowicz
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Publication number: 20100173821Abstract: The present invention relates to 1-(2-isobutylcyclohex-1-enyl)but-2-en-1-one and 1-(2-isobutylcyclohex-2-enyl)but-2-en-1-one and their use as fragrance ingredient.Type: ApplicationFiled: June 3, 2008Publication date: July 8, 2010Applicant: GIVAUDAN SAInventors: Thierry Granier, Andreas Hanhart, Jerzy Bajgrowicz
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Patent number: 7741267Abstract: The present invention relates to a perfuming ingredient of a compound of formula in the form of any one of its isomers or of a mixture thereof, and having a boiling point above 250° C., as measured at a pressure of 1013 mbar and its use in a method to confer, enhance, improve or modify the odor properties of a perfuming composition or perfumed article. The perfuming compositions and perfumed articles having the desirable odor characters are also part of this invention.Type: GrantFiled: December 26, 2006Date of Patent: June 22, 2010Assignee: Firmenich S.A.Inventor: Jean-Marc Gaudin
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Publication number: 20100137178Abstract: The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.Type: ApplicationFiled: December 1, 2009Publication date: June 3, 2010Inventors: Johan Smets, Hugo Robert Germain Denutte, An Pintens, David Thomas Stanton, Koen Van Aken, Inge Helena Hubert Laureyn, Bram Denolf, Freek Annie Camiel Vrielynck
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Publication number: 20100028288Abstract: The invention relates to a malodor counteractancy or counteracting (MOC) method that resorts to the use of specific malodor counteracting (MOC) mixtures of fragrance ingredients. More particularly, the invention relates to new MOC compositions capable of neutralizing or masking in an efficient manner malodors of a large variety of such as body or animal malodors, kitchen malodors, toilet and bathroom malodors, and tobacco malodor. The novel MOC compositions of the invention contain at least one nitrile material in combination with another fragrance material and can be used in any finished consumer products such as air fresheners, kitchen or toilet/bathroom cleaning or freshening products, textile treatment products and products for application on the human skin or hair, or on animal fur, litter containers or cages.Type: ApplicationFiled: August 24, 2007Publication date: February 4, 2010Applicant: FIRMENICH SAInventors: Lyse Tranzeat, Nicholas O'Leary, Wessel-Jan Kos
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Publication number: 20100016197Abstract: The present invention relates to substituted cyclohexenyl butenones of the formula wherein R1, R2, R3, R4 and R5 are independently selected from hydrogen, methyl or ethyl; and the total sum of carbon atoms is 11 to 15; as well as to a method for their production and to fragrance compositions and fragrance applications comprising them.Type: ApplicationFiled: December 11, 2007Publication date: January 21, 2010Inventors: Thierry Granier, Andreas Hart, Jerzy A. Bajgrowicz
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Publication number: 20090326079Abstract: The present invention a method of improving, enhancing or modifying a fragrance formulation through the addition of an olfactory acceptable amount of the following compound: wherein R represents a straight, branched, or cyclic C1 to C5 hydrocarbon moiety containing saturated and/or unsaturated bonds, or a C3 to C5 glycolether, and wherein the methyl substituent is located in the ortho, meta, or para position on the cyclohexane ring.Type: ApplicationFiled: September 8, 2009Publication date: December 31, 2009Inventors: Anthony T. Levorse, JR., Richard A. Weiss
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Publication number: 20090325855Abstract: A fragrance composition for control of kitchen malodor, kitchen cleaning and deodorizing products comprising them, and methods for the reduction of malodor utilizing them, the fragrance composition comprising a decyl aldehyde; an allyl amyl glycolate; cis-3-hexenyl acetate; a rose oxide; a terpinolene; and 2,4-dimethyl-3-cyclohexene-1-carbaldehyde.Type: ApplicationFiled: September 3, 2009Publication date: December 31, 2009Applicant: COLGATE-PALMOLIVE COMPANYInventors: Joan E. Gambogi, Mary C. Brauchli, Gary J. Marr, Robert C. Vermeer
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Publication number: 20090326144Abstract: Disclosed are a method for preparing a fragrant powder composition for a tire, a rubber composition for a tire, which includes the prepared fragrant powder composition for a tire, a rubber containing the prepared fragrant powder composition for a tire, and a tire including the rubber which contains the prepared fragrant powder composition for a tire.Type: ApplicationFiled: June 11, 2009Publication date: December 31, 2009Applicant: KUMHO TIRE CO., INC.Inventors: SUN NY CHO, JE HWAN PARK
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Publication number: 20090325836Abstract: This invention relates to substituted cyclooctenes of the formula I, wherein X and R are defined in the specification.Type: ApplicationFiled: September 1, 2009Publication date: December 31, 2009Applicant: Givaudan SAInventors: Thierry Granier, Jerzy A. Bajgrowicz, Andreas Hanhart
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Publication number: 20090263344Abstract: Perfume compositions effective against urine malodour and having a low odour, comprise between 20% and 50% of perfume ingredients comprising at least 15% by-weight of N-ethyl-N-(3-methylphenyl) propanamide.Type: ApplicationFiled: August 3, 2007Publication date: October 22, 2009Applicant: Givaudan Nederland Services B.V.Inventors: Michael Gordon Evans, Keith Douglas Perring, Alan Forbes Provan, David Jonathan Bradshaw, John Martin Behan
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Patent number: 7572938Abstract: The present invention refers to compounds of formula I as precursors for a ketone of formula II, an aldehyde or ketone of formula III, and an aldehyde or ketone of formula IV, These compounds are useful in perfumery, especially in the fine and functional perfumery.Type: GrantFiled: May 29, 2002Date of Patent: August 11, 2009Assignee: Givaudan SAInventors: Samuel Derrer, Markus Gautschi
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Patent number: 7569732Abstract: A process of preparation of cis-2-acetyl-1,2,3,4,5,6,7,8-octahydro-1,2,8,8-tetramethylnaphthalene (“?-Georgywood”) from cis-1-[1,2-dimethyl-4(4-methyl-pent-3-enyl)-cyclohex-3-enyl]-ethanone (“?-Georgywood”), comprising the reaction of ?-Georgywood with more than one molar equivalent of a Lewis acid. The method allows the preparation of isomeric mixtures that contain a much higher proportion of the olfactorily-desirable ?-Georgywood than was previously possible.Type: GrantFiled: February 16, 2006Date of Patent: August 4, 2009Assignee: Givaudan SAInventor: Fridtjof Schröder
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Publication number: 20090181878Abstract: The present invention relates to the field of perfumery. More particularly, it concerns compounds comprising at least one ?-oxy or ?-thio carbonyl moiety capable of liberating a perfuming molecule such as, for example, an ?,?-unsaturated ketone, aldehyde or carboxylic ester. The present invention concerns also the use of the compounds in perfumery as well as the perfuming compositions or perfumed articles comprising the invention's compounds.Type: ApplicationFiled: February 25, 2009Publication date: July 16, 2009Inventors: Charles Fehr, Arnaud Struillou, Jose Galindo
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Publication number: 20090054299Abstract: Unsaturated ketones of general formula (I) where the groups R1, R2, R3, R4 and R5 independently=H or 1-6 C alkyl groups, which can be saturated or unsaturated, straight-chained, branched or cyclic are characerised by an interesting and original odour characteristic with good emanation and are suitable for use as perfumes, for example in cosmetic preparations, technical products or alcoholic perfumery.Type: ApplicationFiled: November 3, 2008Publication date: February 26, 2009Applicant: KAO CORPORATIONInventors: Thomas MARKERT, Volker Porrmann, Frank Rittler
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Patent number: 7494968Abstract: The present invention relates to the use as perfuming ingredient of a compound of formula wherein R represents a hydrogen atom or a methyl or ethyl group, and R1 represents (i) a (Me)(R2)C?C(R3) group, R2 representing a hydrogen atom or a methyl group and R3 representing a methyl or ethyl group, or (ii) a phenyl group optionally substituted by one or two methyl groups; as well as to the compositions or articles associated with these compounds.Type: GrantFiled: September 27, 2006Date of Patent: February 24, 2009Assignee: Firmenich SAInventors: Jean-Marc Gaudin, Pascal Millet
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Publication number: 20080221003Abstract: Consumer products having fragrance that can develop distinguishable odor patterns which are separately detectable. Scent dynamics allow the consumer with one and the same product to experience different scent experiences during a single application. The limited range and monotony of odor associated with the conventional perfumed consumer products is thereby completely broken.Type: ApplicationFiled: March 7, 2008Publication date: September 11, 2008Applicant: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENInventors: Georg MEINE, Thomas FELDBRUGGE, Alfred-Michael LUSSE
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Publication number: 20080114189Abstract: A process of preparation of cis-2-acetyl-1,2,3,4,5,6,7,8-octahydro-1,2,8,8-tetramethylnaphthalene (“?-Georgywood”) from cis-1-[1,2-dimethyl-4(4-methyl-pent-3-enyl)-cyclohex-3-enyl]-ethanone (“?-Georgywood”), comprising the reaction of ?-Georgywood with more than one molar equivalent of a Lewis acid. The method allows the preparation of isomeric mixtures that contain a much higher proportion of the olfactorily-desirable ?-Georgywood than was previously possible.Type: ApplicationFiled: February 16, 2006Publication date: May 15, 2008Applicant: GIVAUDAN SAInventor: Fridtjof Schroder
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Patent number: 7312187Abstract: Described are polyalkylbicylic chemical derivatives for use a fragrance ingredients having the generic structure: wherein m=0 or 1; wherein X is methyl or hydrogen; wherein R1, R2, R3 and R4 each represents methyl or ethyl with the proviso that when X is methyl, each of R1, R2, R3 and R4 is methyl and when X is hydrogen, one of R1, R2, R3 and R4 is ethyl; and wherein R6 represents hydrogen or methyl. Methods for using and making these compounds are also disclosed.Type: GrantFiled: September 26, 2003Date of Patent: December 25, 2007Assignee: International Flavors & Fragrances Inc.Inventors: Anubhav P. S. Narula, Edward Mark Arruda
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Patent number: 7018978Abstract: The present invention relates to novel heterocyclic pro-fragrances, preferably oxazolidines, tertahydro-1,3-oxazines, thiazolidines, or tetrahydro-1,3-thiazines, more preferably oxazolidines, or tertahydro-1,3-oxazines, most preferably oxazolidines, which are capable of sustained release of fragrance raw material ketones and aldehydes and to fragrance delivery systems which comprise said pro-fragrances.Type: GrantFiled: April 16, 2003Date of Patent: March 28, 2006Assignee: Procter & Gamble CompanyInventors: Gregory Scot Miracle, Kenneth Nathan Price
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Patent number: 6960350Abstract: An antifungal fragrance composition containing as its active ingredients: (a) at least one type of fragrance component selected from the group consisting of an aliphatic or aromatic aldehyde having 5 to 16 carbon atoms and an aliphatic or aromatic alcohol having 5 to 16 carbon atoms, and (b) at least one type of compound different from component (a) and selected from the group consisting of an aliphatic or aromatic aldehyde, an aliphatic or aromatic alcohol, acetal and ester that produces synergistic antifungal effects in the presence of said fragrance component (a). The present antifungal fragrance composition demonstrates antifungal activity by adding a small amount of oils and fragrant chemical products that have a minimal effect on the scent of the fragrance composition.Type: GrantFiled: December 12, 2001Date of Patent: November 1, 2005Assignee: Takasago International CorporationInventors: Minoru Hanada, Hisao Iwai, Jun Fujigasaki
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Patent number: 6861402Abstract: The present invention relates to fragrance delivery systems which comprise: A) from about 0.01% by weight of a pro-fragrance component which comprises pro-fragrances or pro-accords selected from at least two of the following: i) aldehyde and ketone releasing pro-fragrances, preferably an oxazolidine pro-fragrance; ii) ?-amino pro-fragrances; and iii) orthoester pro-accords; and B) the balance carries and others adjunct ingredients.Type: GrantFiled: May 31, 2000Date of Patent: March 1, 2005Assignee: The Procter & Gamble CompanyInventors: Gregory Scot Miracle, Lon Montgomery Gray
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Publication number: 20040171516Abstract: The present invention refers to compounds of formula I 1Type: ApplicationFiled: November 26, 2003Publication date: September 2, 2004Inventors: Samuel Derrer, Markus Gautschi
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Patent number: 6770618Abstract: Trans-2,2,6-trimethylcyclohexyl methyl ketone, including (1S,6R)-2,2,6-trimethylcyclohexyl methyl ketone represented by the formula (1a): and (1R,6S)-2,2,6-trimethylcyclohexyl methyl ketone represented by the formula (1b): are useful components in a perfume composition. A process for producing the same is also described. A unique eucalyptus, mint-like and white floral perfume material is provided using the ketone compounds disclosed in the present invention. The process of the present invention produces the optically active ketone compounds having optical purity up to at least 98.0 % e.e.Type: GrantFiled: June 7, 2001Date of Patent: August 3, 2004Assignee: Takasago International Corp.Inventors: Hideo Ujihara, Shinya Watanabe, Takeshi Yamamoto, Toshimitsu Hagiwara
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Publication number: 20040072721Abstract: The present invention relates to the perfumery industry. It concerns more particularly an alcohol, ester, ether or ketone derivative having a spiro-type skeleton, the latter being substituted by short alkyl groups. The invention also relates to the use of the invention compounds as perfuming ingredients, able to impart a woody and/or aromatic, as well as to the perfumed articles or perfuming compositions comprising as active ingredient a compound of formula (I).Type: ApplicationFiled: October 8, 2003Publication date: April 15, 2004Inventors: Christian Vial, Robert Moretti, Alain Charpilloz, Peter Fankhauser, Piero Fantini
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Publication number: 20030207790Abstract: A geometrical isomer composition excellent in odor and in chemical resistance, which is applicable to a base material containing a strongly alkaline chemical or a strongly acidic chemical, which can suppress the deterioration with time and the color change of the base material in the case that the material is exposed to light, and which also have highly tasteful and unique fruity floral fragrance. A geometrical isomer composition containing 93 to 99% by weight of optically active trans-1-(2,2,6-trimethylcyclohexyl)-2-buten-1-one represented by Formula-1 or a mixture thereof and 7 to 1% by weight of optically active cis-1-(2,2,6-trimethylcyclohexyl)-2-buten-1-one represented by Formula-2 or a mixture thereof is, respectively, used.Type: ApplicationFiled: March 19, 2003Publication date: November 6, 2003Applicant: Takasago International CorporationInventors: Takeshi Yamamoto, Shinya Watanabe, Hideo Ujihara, Toshimitsu Hagiwara
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Publication number: 20030158080Abstract: An excellent fragrance compound having high palatability.Type: ApplicationFiled: December 4, 2002Publication date: August 21, 2003Applicant: Takasago International CorporationInventors: Hiroyuki Matsuda, Kenji Maruyama
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Patent number: 6551987Abstract: The present invention relates to fragrance delivery systems which comprise: a) one or more pro-fragrances having formula (I) wherein G1 and G2 are methyl, or a cyclic hydrocarbyl unit derived from the isomers of ionone and/or damascone; R and R1 are each independently C1-C22 substituted or unsubstituted, branched or unbranched alkyl, C2-C22 substituted or unsubstituted, branched or unbranched alkenyl, C2-C20 substituted or unsubstituted, branched or unbranched hydroxyalkyl, C7-C20 substituted or unsubstituted alkylenearyl, C3-C20 substituted or unsubstituted cycloalkyl, alkyleneoxy, C6-C20 aryl, C5-C20 heteroaryl comprising one or more heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, and mixtures thereof; two of the units Y1, Y2, R or R1 can be taken together to form one or more aromatic or non-aromatic, heterocyclic or non-heterocyclic, single rings, fused rings, bicyclo rings, spiroannulated rings, or mixtures thereof, said rings comprising from 3 to 20 carbon atoms and one or morType: GrantFiled: October 22, 2001Date of Patent: April 22, 2003Assignee: The Procter & Gamble CompanyInventors: Gregory Scott Miracle, Lon Montgomery Gray
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Publication number: 20020173444Abstract: The present invention is directed to the use of an olfactory acceptable amount comprising tetrahydro-4-methylene-2-(4-methoxyphenyl)-2H-pyran, 5,6-dihydro-4-methyl-2-(4-methoxyphenyl)-2H-pyran, 3,6-dihydro-4-methyl-2-(4-methoxyphenyl)-2H-pyran and mixtures of these materials which are useful in creating fragrances, and scents in items such as perfumes, colognes and personal care products.Type: ApplicationFiled: March 12, 2001Publication date: November 21, 2002Inventors: Mark A. Sprecker, Charles E.J. Beck
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Patent number: 6468949Abstract: The present invention is directed to cyclopropyl-2,6,6-trimethylcyclohex-3-enyl ketone and is use in creating perfumes and scents in such items as perfumes, colognes, toilet water and personal care products.Type: GrantFiled: December 10, 2001Date of Patent: October 22, 2002Assignee: International Flavors & Fragrances Inc.Inventors: Richard M. Boden, William L. Schreiber
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Patent number: 6177400Abstract: The compounds according to the general formula in which formula the dotted lines indicate a single or a double bond, n and m are 0 or 1, R1 is hydrogen or an acyl group —C(O)R3, R3 being a linear or branched alkyl or alkylene group from C1 to C8, the oxygen atom being bound to the adjacent &agr;-carbon atom by a double bond in the case where n is 0 and by a single bond in the case where n is 1, R2 is hydrogen or a linear or branched alkyl, alkenyl or alkoxy group from C1 to C8, or R2 is an alkenoxy group which is linked to the group R1 to form a 1,3-dioxolane cycle having 5 to 7 ring members, are useful perfuming ingredients. The most preferred compounds according to the invention are those which have a damascone- or damascenone-like structure, with the methyl substituent being in 4-position of the ring instead of the 2-position, as is the case in damascones and damascenones.Type: GrantFiled: May 7, 1999Date of Patent: January 23, 2001Assignee: Firmenich SAInventors: Hubert Mimoun, Wolfgang Klaus Giersch
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Patent number: 6025323Abstract: The compounds of formula ##STR1## in which R stands for a methyl or ethyl group, are used as perfume ingredients for the preparation of perfuming compositions and perfumed articles, to which they confer aromatic and thujonic notes. The compounds can be used in the form of a mixture of enantiomers or in an enantiomerically pure state. The invention also comprises original processes for the preparation of these compounds.Type: GrantFiled: May 13, 1998Date of Patent: February 15, 2000Assignee: Firmenich SAInventors: Charles Fehr, Christian Margot
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Patent number: 5707961Abstract: The invention is concerned with novel odorants, including the compounds of the formula ##STR1## wherein R.sup.1 .dbd.R.sup.4 .dbd.CH.sub.3 and R.sup.2 .dbd.R.sup.3 .dbd.H orR.sup.1 .dbd.R.sup.2 .dbd.R.sup.3 .dbd.H and R.sup.4 .dbd.CH.sub.3, orR.sup.1 +R.sup.2 .dbd.--CH.sub.2 CH.sub.2 -- and R.sup.3 .dbd.H and R.sup.4 .dbd.CH.sub.3, orR.sup.1 .dbd.R.sup.4 .dbd.CH.sub.3 and R.sup.2 +R.sup.3 .dbd.--CH.sub.2 -- orR.sup.1 .dbd.CH.sub.3 and R.sup.2 .dbd.R.sup.3 .dbd.H and R.sup.4 .dbd.CH.sub.2 CH.sub.3 orR.sup.1 .dbd.R.sup.2 .dbd.R.sup.4 .dbd.CH.sub.3 and R.sup.3 .dbd.H and R.sup.5 .dbd.H (preferred) or CH.sub.3.Type: GrantFiled: April 25, 1996Date of Patent: January 13, 1998Assignee: Givaudan-Roure (International) SAInventors: Jerzy A. Bajgrowicz, Alain Bringhen, Georg Frater, Urs Muller
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Patent number: 5614486Abstract: The compounds of formula ##STR1## wherein the Z group can be located in positions ortho-, meta- or para-relative to the carboxylic group, symbol R.sup.1 stands for a saturated or unsaturated, linear or branched C.sub.1 to C.sub.4 alkyl radical anda. the dotted lines represent a cyclohexanic moiety and Z represents a ##STR2## group, R.sup.2 being a saturated or unsaturated, linear or branched C.sub.1 to C.sub.4 alkyl radical; orb. the dotted lines represent a cyclohexanic or benzenic moiety and Z represents a group of formula ##STR3## in which R.sup.2 is a saturated or unsaturated, linear or branched C.sub.1 to C.sub.4 alkyl radical, are useful as perfuming ingredients for the preparation of perfuming compositions and a variety of perfumed consumer articles. They impart to the latter odor notes of the fruity and floral type.Type: GrantFiled: May 23, 1995Date of Patent: March 25, 1997Assignee: Firmenich SAInventors: Wolfgang K. Giersch, Peter Fankhauser
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Patent number: 5525589Abstract: The present invention is concerned with novel odorant compositions which are characterized by a content of cyclic compounds of the formula ##STR1## From this group of compounds the compounds I' with the meanings b), d), f) and g) are novel compounds.Type: GrantFiled: February 18, 1994Date of Patent: June 11, 1996Assignee: Givaudan-Roure CorporationInventors: Franz Etzweiler, Daniel Helmlinger
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Patent number: 5288702Abstract: Ethyl (1R,6S)-2,2,6-trimethylcyclohexanecarboxylate represented by formula (1) ##STR1## is disclosed. Also, an aroma chemical composition containing the same and a process of the production of the same are disclosed.Type: GrantFiled: March 26, 1992Date of Patent: February 22, 1994Assignee: Takasago International CorporationInventors: Miharu Ogura, Hiroyuki Matsuda, Takeshi Yamamoto, Akemi Shimada
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Patent number: 5240907Abstract: Described are substituted cyclopentyl oxabicyclooctanes, cyclopentyl vinyl pyrans, cyclopentylformylcyclohexenes and cyclopentylhydroxymethyl cyclohexenes having the generic structures: ##STR1## wherein R.sub.1, R.sub.2, R', R", R.sub.1 ', R.sub.2 ', R.sub.1 " and R.sub.2 " represent hydrogen or methyl with the provisos that:(i) R.sub.1 and R.sub.2 are not both methyl;(ii) R' and R" are not both methyl;(iii) when R.sub.1 ' is methyl, R.sub.2 ' is hydrogen; and(iv) when R.sub.2 " is methyl, then R.sub.1 " is hydrogen,processes for preparing same and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles, e.g., solid or liquid, anionic, cationic, nonionic or zwitterionic detergents, cosmetic preparations, fabric softener compositions, fabric softener articles, hair preparations and perfumed polymers.Type: GrantFiled: October 23, 1992Date of Patent: August 31, 1993Assignee: International Flavors & Fragrances Inc.Inventors: Anubhav P. S. Narula, John J. De Virgilio, Franc T. Schiet, Charles E. J. Beck, Charles J. Vinals, Marie R. Hanna