Abstract: The various aspects presented herein relate to the perfumery industry. More particularly, the various aspects presented herein relate to malodor counteracting compositions and/or ingredients, methods for counteracting malodors, as well as to the perfumed articles or perfuming compositions comprising as an active ingredient, at least one compound selected from the group consisting of: a compound of Formula (I), a compound of Formula (II), a compound of Formula (III), a compound of Formula (IV), and mixtures thereof.
Type:
Grant
Filed:
November 21, 2018
Date of Patent:
December 31, 2024
Assignee:
Firmenich SA
Inventors:
Huey-Ling Kao, Stefan Alexander Ruider, Steven Williams, Julien Coulomb
Abstract: The present disclosure relates to the field of perfumery and more precisely it concerns a deodorant or an antiperspirant composition comprising a ?-thio carbonyl profragrance. The use of the composition to reduce body odour and a dispensing container comprising the composition are also objects of the disclosure.
Abstract: Disclosed is a use of a compound of formula (I), a composition of matter comprising a compound of formula (I) and a consumer product comprising a compound of formula (I).
Abstract: The present invention relates to the use as perfuming ingredient of a compound of formula in the form of any one of its stereoisomers or a mixture thereof, and wherein one dotted line represents a carbon-carbon single bond and the other a carbon-carbon double bond; and R represents a hydrogen atom or a C1-4 alkyl or alkenyl group; as well as to the perfuming composition and the consumer products containing said compound.
Type:
Grant
Filed:
June 20, 2017
Date of Patent:
December 31, 2019
Assignee:
Firmenich SA
Inventors:
Peter Fankhauser, Robert Moretti, Florian De Nanteuil
Abstract: The invention relates to organic compounds having the ability to reduce or suppress the onset of skin irritation induced by extraneous cause selected from the group of 2-heptylcyclopentanone, 2-ethoxynaphthalene; 2-methoxynaphthalene; 1-methoxy-4-(prop-1-enyl)benzene; 1-(cyclopropylmethyl)-4-methoxybenzene; wherein X, Y, and R1 to R11 have the same meaning as given in the description. Furthermore the invention refers to compositions for topical application to the skin comprising them. It further relates to a method of reducing or suppressing the formation of skin irritation.
Abstract: The present invention concerns compound of formula in the form of any one of its stereoisomers or a mixture thereof, and wherein the exocyclic dotted line represents a carbon-carbon single or double bond, and one endocyclic dotted to line represents a carbon-carbon single bond and the other endocyclic dotted line represents a carbon-carbon double bond; and R, R1 and R2 represent, independently from each other, a hydrogen atom or a C1-3 alkyl group; and their use in perfumery to impart odor notes of the green, floral type.
Type:
Grant
Filed:
September 13, 2016
Date of Patent:
October 16, 2018
Assignee:
Firmenich SA
Inventors:
Robert Moretti, Anthony Alexander Birkbeck
Abstract: The present invention is a fragrance composition comprising methyl dihydrojasmonate and a compound (I), the fragrance composition containing 94.5 to 99% by mass of the methyl dihydrojasmonate and 1 to 5% by mass of the compound (I), the methyl dihydrojasmonate. In addition, the present invention is a method for producing the fragrance composition, the method comprising subjecting a composition that contains methyl dihydrojasmonate and the compound (I) sequentially to a concentration distillation step and a thin film distillation step, the composition containing 90 to 99.5% by mass of the methyl dihydrojasmonate and 0.1 to 1.5% by mass of the compound (I), the methyl dihydrojasmonate having a cis isomer content of less than 20 mol %.
Abstract: The present invention relates to compounds of formula wherein one R group is a hydrogen atom and the other is a hydrogen atom or a C1-3 alkyl group; and each carbon-carbon double bond of said compound, independently from each other, can be in a configuration Z or E or a mixture thereof; which are useful perfuming ingredients.
Abstract: The present invention relates to the field of perfumery. More particularly, it concerns co-polymeric latex particles derived from 2-oxo-2-(3- or 4-vinylphenyl)acetates capable of liberating an active molecule such as, for example, an aldehyde or ketone upon exposure to light. The present invention concerns also the use of said latex in perfumery as well as the perfuming compositions or perfumed articles comprising the invention's latex.
Type:
Grant
Filed:
September 28, 2012
Date of Patent:
April 19, 2016
Assignee:
Firmenich SA
Inventors:
Andreas Herrmann, Damien Berthier, Nicolas Paret, Myléne Therrien
Abstract: Compounds of formula (I) wherein R is hydrogen and the bond between C-2 and C-3 together with the dotted line represents a double bond, or R is —CH2— and together with C-2 and C-3 represents a cyclopropane ring and the bond between C-2 and C-3 together with the dotted line represents a single bond, having floral rosy odor notes, their use as fragrance and perfumed products comprising them.
Abstract: The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities' options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.
Type:
Application
Filed:
January 22, 2015
Publication date:
May 21, 2015
Inventors:
Johan SMETS, Hugo Robert Germain DENUTTE, An PINTENS, Koen VAN AKEN, Freek Annie Camiel VRIELYNCK
Abstract: A fragrance mixture, preferably perfume oil, is described, comprising the constituents (a) (cyclopent-2-enyl ethyl acetate) and additionally (b) one or a plurality of fragrances, preferably with a floral odor note, from the group consisting of alcohols and aldehydes with a molecular weight of 210 g/mol or less and/or (c) one or a plurality of fragrances from the group consisting of ketones, ethers and esters with a molecular weight in the range from 190 g/mol through 250 g/mol.
Abstract: The present invention relates to novel compounds and their use as fragrance materials.
Type:
Application
Filed:
August 22, 2014
Publication date:
February 26, 2015
Inventors:
Benjamin Amorelli, Edward Mark Arruda, Robert P. Belko, Tingwei Cai, Adam P. Closson, Nicole L. Giffin, Gary J. Mertz, Michael G. Monteleone
Abstract: An aldehyde of formula (I) in the form of any one of its stereoisomers or a mixture thereof, wherein each dotted line, independently from each other, represents a single or double bond; n is 0 or 1; R1 is a hydrogen atom or a methyl group; R2 is a hydrogen atom or a methyl or ethyl group; and R3, which can be present in any of positions 2 to 6 of the cyclic moiety, is a hydrogen atom or a methyl or ethyl group, or a CH2 group bridging positions 3 and 6. Also, the use of the aldehyde as perfuming ingredient to impart odor notes of the aldehyde, lily of the valley type.
Abstract: Compounds of formula (I) wherein R is hydrogen and the bond between C-2 and C-3 together with the dotted line represents a double bond, or R is —CH2— and together with C-2 and C-3 represents a cyclopropane ring and the bond between C-2 and C-3 together with the dotted line represents a single bond, having floral rosy odor notes, their use as fragrance and perfumed products comprising them.
Abstract: The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities' options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.
Type:
Application
Filed:
September 12, 2014
Publication date:
December 25, 2014
Inventors:
Hugo Robert Germain DENUTTE, Johan SMETS, An PINTENS, Koen VAN AKEN, Freek Annie Camiel VRIELYNCK
Abstract: The present invention relates to a composition of matter comprising at least 95% w/w of at least one compound of formula (I), wherein R group is a C1—6 alkyl group optionally comprising an ether functional group; and wherein each carbon-carbon double bond of said compound, independently from each other, can be in a configuration Z or E; which is a useful perfuming ingredient.
Abstract: A process of forming methoxymelonal comprising the steps of treating a solution of citronellene to ozonolysis, and hydrogenating the product formed to provide methoxymelonal.
Abstract: The present invention relates to some perfuming ingredients which are esters of formula (I) wherein R1 and R2 represent each a hydrogen atom or a methyl or ethyl group; and R3 represents a C5-C8 group of formula satured or unsatured linear, branched or cyclic group.
Abstract: The present invention primarily concerns certain 4-alkyl pyridines of the following formula (I), wherein R is C8-C12 alkyl, odiferous substance mixtures and aromatic substance mixtures containing these 4-alkyl pyridines, the respective uses thereof as an odiferous or aromatic substance (mixture) and corresponding perfumed products.
Abstract: Perfume compositions effective against urine malodor and having a low odor, comprise between 20% and 50% of perfume ingredients comprising at least 15% by-weight of N-ethyl-N-(3-methylphenyl) propanamide.
Type:
Grant
Filed:
April 12, 2013
Date of Patent:
September 2, 2014
Assignee:
Givaudan Nederland Services B.V.
Inventors:
Keith Douglas Perring, Michael Gordon Evans, Alan Forbes Provan, David Jonathan Bradshaw, John Martin Behan
Abstract: Perfume ingredients have been investigated and classified for their effectiveness in detaching biofilms from surfaces. Based on this classification, perfume compositions that are effective in assisting biofilm detachment can be formulated, whilst also allowing a degree of freedom in formulation that permits consideration of the hedonic properties of the composition. The compositions can be used in a wide range of perfumed consumer products, such as personal, domestic and industrial products, e.g. hard surface cleaning products, dental care products, and deodorant products.
Type:
Application
Filed:
January 21, 2014
Publication date:
August 21, 2014
Applicant:
Givaudan Nederland Services B.V.
Inventors:
David Jonathan Bradshaw, Alan Forbes Provan, Christopher James Ioannou, John Martin Behan, Keith Douglas Perring
Abstract: Compounds of formula (I) wherein R is methyl or ethyl, having floral, green odor notes, their use as fragrance and perfumed products comprising them.
Abstract: The present invention relates to the preparation of trimethylcyclododecatriene in a continuous or batchwise process by trimerizing isoprene in the presence of a catalyst system and of a solvent. It is possible to isolate the resulting crude trimethylcyclododecatriene by means of distillation. The dimethylcyclooctadiene formed as a by-product may likewise be isolated from the crude product.
Abstract: The present invention relates to compounds of Formula (I), wherein one R group is a hydrogen atom and the other is a hydrogen atom or a C1-3 alkyl group; and each carbon-carbon double bond of said compound, independently from each other, can be in a configuration Z or E or a mixture thereof; which are useful perfuming ingredients.
Abstract: The invention concerns the use of 6-cyclopentylidenehexane derivatives—6, cyclopentylidenehexan-1-ol and 6-cyclopentylidenehexanal—as sensory agents giving off a fragrance and/or a flavor of interest for a use in perfumery, in cosmetic, in parapharmacy, in detergent industry and in the food industry.
Abstract: The use of certain compounds for masking or decreasing the or one or a plurality of unpleasant olfactory impressions of one or a plurality of substances with an unpleasant odor and/or for enhancing the or one or a plurality of pleasant olfactory impressions of one or a plurality of substances with a pleasant odor and new fragrance mixtures and perfumed products containing such compounds.
Abstract: A rose-like fragrance composition including methyl epijasmonate, provided that a natural jasmine fragrance containing methyl epijasmonate is excluded. The rose-like fragrance composition can also include 2-isopropyl-4-methyl thiazole.
Type:
Application
Filed:
March 13, 2013
Publication date:
September 26, 2013
Applicants:
TAKASAGO INTERNATIONAL CORPORATION, SHISEIDO COMPANY, LTD.
Abstract: A fragrance mixture, preferably perfume oil, is described, comprising the constituents (a) (cyclopent-2-enyl ethyl acetate) and additionally (b) one or a plurality of fragrances, preferably with a floral odor note, from the group consisting of alcohols and aldehydes with a molecular weight of 210 g/mol or less and/or (c) one or a plurality of fragrances from the group consisting of ketones, ethers and esters with a molecular weight in the range from 190 g/mol through 250 g/mol.
Abstract: A novel odorant of formula (I) wherein each of R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are independently selected from H, CH3, and C2H5; X is selected from —CH2OH, —CH2OCOCH3 and —CHO and —CHO, n is selected from 0 and 1. The dotted line represents double bond or single bond.
Abstract: The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.
Type:
Grant
Filed:
September 14, 2012
Date of Patent:
April 30, 2013
Assignee:
The Procter & Gamble Company
Inventors:
Johan Smets, Hugo Robert Germain Denutte, An Pintens, David Thomas Stanton, Koen Van Aken, Inge Helena Hubert Laureyn, Bram Denolf, Freek Annie Camiel Vrielynck
Abstract: The present invention pertains to a method of counteracting a malodor by introducing a malodor counteracting effective amount of a novel 3.2.1-bicyclo-octene or -octane compound represented by formula: wherein R is selected from the group consisting of hydrogen, acetate, carbonate monomethyl ester, and allyloxy; and wherein the broken line represents a single or double bond.
Type:
Grant
Filed:
October 8, 2010
Date of Patent:
April 9, 2013
Assignee:
International Flavors & Fragrances Inc.
Inventors:
Benjamin Amorelli, Johan Gerwin Lodewijk Pluyter, Adam P. Closson
Abstract: A compound of formula (I) wherein R1 and R2 are independently selected from hydrogen, methyl, ethyl, propyl and isopropyl; or R1 and R2 together form a saturated or monounsaturated 5- or 6-membered hydrocarbon ring, as represented by the arcuate dotted line; R3 is selected from methyl and ethyl; R4 is selected from methyl, ethyl, propyl, isopropyl, cyclopropyl, butyl, isobutyl, cyclobutyl and cyclopentyl; R5 is selected from hydrogen and methyl, and the dotted line between positions 3? and 4? represents an optional double bond. The compounds have a musk odour and are useful in fine and functional fragrances.
Abstract: The present invention is directed to a novel compound, 3-methyl-cyclohexadec-6-enone, and a method of improving, enhancing or modifying a fragrance formulation through the addition of an olfactory acceptable amount of 3-methyl-cyclohexadec-6-enone.
Type:
Application
Filed:
August 22, 2011
Publication date:
February 28, 2013
Inventors:
Anubhav P.S. Narula, Edward Mark Arruda, Benjamin Amorelli, Franc T. Schiet
Abstract: Disclosed is a cooling sensation agent composition or sensory stimulation agent composition which contains at least one of diester compounds of dicarboxylic acid represented by the formula (1) wherein A represents CH2 or CH?CH, n represents an integer of 0 to 4 when A is CH2, or 1 when A is CH?CH, B is an alcohol residue having 10 to 18 carbon atoms and containing a para-menthane skeleton, which may have a substituent, and C is an alcohol residue having 6 to 18 carbon atoms, which may have a substituent as well as a flavor or fragrance composition, a beverage, a food product, a perfume or cosmetic product, a toiletry product, daily utensil products or groceries, a fiber, a fiber product, clothes, clothing or a medicine, wherein the cooling sensation agent composition or the sensory stimulation agent composition is compounded.
Type:
Grant
Filed:
October 6, 2010
Date of Patent:
February 19, 2013
Assignee:
Takasago International Corporation
Inventors:
Yasuhiro Komatsuki, Tomoko Yamamoto, Takashi Aida, Kenya Ishida
Abstract: The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.
Type:
Application
Filed:
September 14, 2012
Publication date:
January 10, 2013
Inventors:
Johan SMETS, Hugo Robert Germain Denutte, An Pintens, David Thomas Stanton, Koen Van Aken, Inge Helena Hubert Laureyn, Bram Denolf, Freek Annie Camiel Vrielynck
Abstract: The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities' options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.
Type:
Application
Filed:
May 24, 2012
Publication date:
December 27, 2012
Inventors:
Hugo Robert Germain Denutte, Johan Smets, An Pintens, Jeanne Alfons Van Aken, Freek Annie Camiel Vrielynck
Abstract: The invention relates to novel aldehydes and nitriles from isophorone with general formula (I) having a specific fragrance (Formula I) (I), as well as to the use of said compounds in perfumery.
Abstract: The present invention relates to some perfuming ingredients which are esters of formula (I) wherein R1 and R2 represent each a hydrogen atom or a methyl or ethyl group; and R3 represents a C5-C8 group of formula satured or unsatured linear, branched or cyclic group.
Abstract: (Problem) The object of the invention relates to a development of a new musk-feeling fragrance material which is a highly scenting musk-feeling fragrance, and is to provide a fragrance composition which, when added to fragrances or cosmetics, can improve the fixative property and express a high performance and excellent musky aromatic quality. (Means for resolution) A fragrance composition is prepared using, as the active ingredient, a mixture of (R)-form of optically active muscone with (S)-form of optically active muscone with the mixing ratio thereof within the range of from 90:10 to 95:5 (weight ratio) in terms of weight ratio, or a mixture of (R)-form of optically active muscone with (S)-form of optically active muscone with the mixing ratio thereof within the range of from 75:25 to 80:20 (weight ratio) in terms of weight ratio.
Abstract: A compound of formula (I) wherein R1 and R2 are independently selected from hydrogen, methyl, ethyl, propyl and isopropyl; or R1 and R2 together form a saturated or monounsaturated 5- or 6-membered hydrocarbon ring, as represented by the arcuate dotted line; R3 is selected from methyl and ethyl; R4 is selected from methyl, ethyl, propyl, isopropyl, cyclopropyl, butyl, isobutyl, cyclobutyl and cyclopentyl; R5 is selected from hydrogen and methyl, and the dotted line between positions 3? and 4? represents an optional double bond. The compounds have a musk odour and are useful in fine and functional fragrances.
Abstract: The present invention relates to a process for preparing at least one compound with Z?1 cycles and 7 to 16 carbon atoms with at least one aldehyde group, at least comprising the stages: (a1) oxidation of a composition (A), at least comprising a cyclic olefin with Z cycles and 7 to 16 carbon atoms and at least two C—C double bonds, by means of dinitrogen monoxide to give a composition (A1), (a2) separating off the at least one cyclic olefin with Z cycles and 7 to 16 carbon atoms with at least two C—C double bonds from the composition (A1) from stage (a1) in order to obtain a composition (A2), (b1) separating off the at least one cyclic compound with Z cycles and 7 to 16 carbon atoms with a keto group from the composition (A2) from step (a2), in order to obtain a composition (B1), comprising at least 50% by weight of the at least one compound with Z?1 cycles and 7 to 16 carbon atoms with at least one aldehyde group and at least two C—C double bonds, where Z may be 1, 2, 3 or 4.
Type:
Grant
Filed:
January 27, 2010
Date of Patent:
July 3, 2012
Assignee:
BASF SE
Inventors:
Joaquim Henrique Teles, Beatrice Röβler-Feigel, Alexander Hauk, Christian Müller, Michael Schelper, Tanja Kirchner, Susanne Szeschkus
Abstract: The invention proposes a fragrance dispenser, comprising a first and a second carrier, each carrier comprising one or more fragrance substances, wherein the fragrance substances comprise one or more fragrance substances a) with a vapor pressure of at least 0.1 mmHg at 25° C. (“HVA”) and one or more fragrance substances b) with a vapor pressure of less than 0.1 mmHg at 25° C. (“LVA”), and wherein the fragrance substances are distributed to the first and second carrier such that at least 80 wt.-% of all HVA fragrance substances are carried by the first carrier.
Type:
Grant
Filed:
February 28, 2007
Date of Patent:
June 5, 2012
Assignee:
Symrise AG
Inventors:
Matthias Lammert, Alma Ortiz Vela, Angelica Leal Mendieta, Maria De la Luz Hernandez Sanchez, Ruben Israel Chavez Rico, Carlos Eloy Embarcadero Dominguez
Abstract: The present invention is directed to novel 4-alkyl cyclohexanepropanal compounds and a method of improving, enhancing or modifying a fragrance formulation through the addition of an olfactory acceptable amount of the novel compounds.
Type:
Grant
Filed:
November 16, 2009
Date of Patent:
May 29, 2012
Assignee:
International Flavors & Fragrances Inc.
Inventors:
Anthony T. Levorse, Jr., Robert P. Belko, Benjamin Amorelli, Michael G. Monteleone
Abstract: The present invention is directed to novel fragrance compounds and their unexpected advantageous use in improving, enhancing or modifying a fragrance formulation through the addition of an olfactory acceptable amount of the compounds, wherein the compounds are represented by the following formula: wherein R1, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen and C1-C5 alkyl.
Type:
Grant
Filed:
December 16, 2010
Date of Patent:
May 22, 2012
Assignee:
International Flavors & Fragrances Inc.
Inventors:
Anubhav P. S. Narula, Richard M. Boden, James A. Lasome
Abstract: The invention relates to a malodor counteractancy or counteracting (MOC) method that resorts to the use of specific malodor counteracting (MOC) mixtures of MOC ingredients. More particularly, the invention relates to new MOC compositions capable of neutralizing or masking in an efficient manner sweat malodor and which can be used in perfumes, deodorants, antiperspirants and other body care products.
Type:
Application
Filed:
June 17, 2010
Publication date:
March 1, 2012
Inventors:
Myriam Troccaz, Sabine Beccucci, Monica Bandera, Manuel Bourgaux, Catherine Selig, Magali Lateulere, Anthony Clark
Abstract: The present disclosure refers to sila-substituted carbinols of formula (I) wherein R1, R2 and R3 are independently selected from C1-C4 alkyl or C3-C4 cycloalkyl; R4 is methyl or ethyl; and R5 is methyl or ethyl. The disclosure further refers to their preparation and to perfume compositions and fragrance applications comprising them.
Type:
Application
Filed:
April 19, 2010
Publication date:
February 16, 2012
Inventors:
Philip Kraft, Astrid Sunderkötter, Reinhold Tacke
Abstract: The object of the invention relates to a development of a new musk-feeling fragrance material which is a highly scenting musk-feeling fragrance, and is to provide a fragrance composition which, when added to fragrances or cosmetics, can improve the fixative property and express a high performance and excellent musky aromatic quality. A fragrance composition is prepared using, as the active ingredient, a mixture of (R)-form of optically active muscone with (S)-form of optically active muscone with the mixing ratio thereof within the range of from 90:10 to 95:5 (weight ratio) in terms of weight ratio, or a mixture of (R)-form of optically active muscone with (S)-form of optically active muscone with the mixing ratio thereof within the range of from 75:25 to 80:20 (weight ratio) in terms of weight ratio.
Abstract: The present invention relates to certain derivatives of 2-ethyl-4-(2?,2?-dimethyl-3?-alkyl-3?-cyclopenten-1?-yl)-4-penten-1-ol. These compounds possess very interesting perfuming ingredients due to their unusual combination of sandalwood and floral notes. The present invention also concerns the use of such compounds in the perfumery industry as well as the compositions or articles containing such compounds.
Type:
Application
Filed:
March 19, 2010
Publication date:
December 22, 2011
Inventors:
Hervé Pamingle, Christian Chapuis, Peter Fankhauser, Piero Fantini
Abstract: The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities' options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.
Type:
Application
Filed:
June 22, 2011
Publication date:
December 22, 2011
Inventors:
Johan Smets, Hugo Robert Germain Denutte, An Pintens, Koen Van Aken, Freek Annie Camiel Vrielynck