The Compound Contains Silicon Patents (Class 516/144)
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Patent number: 8809404Abstract: The present invention is related to the preparation and use of moderately cross-linked (chin-extended), reverse (or “inverted”) surfactants, wherein the reverse surfactants comprise a polyether backbone with oligomeric or polymeric silicon-containing substitutions along the backbone. The present invention further describes crosslinked versions of the inverted surfactants, reaction products of alkenyl (allyl, vinyl, methallyl) functional copolymers (polyethers), silicone hydrides and cross-linking agents, which may be optionally reacted with water to react the remaining alkoxy groups. The crosslinking agent contains either SiH or Si-alkoxy groups or both. The compounds of the present invention exhibit only moderate cross-linking in order to be soluble or dispersible in appropriate solvents.Type: GrantFiled: January 30, 2013Date of Patent: August 19, 2014Assignee: Momentive Performance Materials Inc.Inventors: Kalman Koczo, Benjamin Falk, Mark Leatherman, Antonio Palumbo
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Patent number: 8796433Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.Type: GrantFiled: September 5, 2012Date of Patent: August 5, 2014Assignees: Kroff Chemical Company, Dow Agrosciences LLCInventors: Paul Rey, David M. Sunderlik, Steven P. Ceplecha
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Publication number: 20130299390Abstract: The present invention provides for a demulsifying composition comprising the reaction product of an oxirane or oxetane compound (I) comprising at least two oxirane or oxetane groups; a compound (II) comprising silicon and one or more amino groups; and optionally a polyamine (III); and a secondary amine (IV).Type: ApplicationFiled: July 12, 2013Publication date: November 14, 2013Inventors: Kalman Koczo, Benjamin Falk, Antonio Palumbo, Monjit Phukan
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Patent number: 8507565Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a polyorganosiloxane demulsifier into an emulsion comprising an oil phase and an aqueous phase. The invention also relates to compositions containing polyorganosiloxane demulsifier and the water and oil phases of an emulsion.Type: GrantFiled: June 14, 2011Date of Patent: August 13, 2013Assignee: Momentive Performance Material Inc.Inventors: Anubhav Saxena, Monjit Phukan, Senthilkumar U., Ian Procter, Sigfredo Gonzalez, Kalman Koczo, Sabine Azouani, Vikram Kumar
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Publication number: 20130197108Abstract: The present invention is related to the preparation and use of moderately cross-linked (chin-extended), reverse (or “inverted”) surfactants, wherein the reverse surfactants comprise a polyether backbone with oligomeric or polymeric silicon-containing substitutions along the backbone. The present invention further describes crosslinked versions of the inverted surfactants, reaction products of alkenyl (allyl, vinyl, methallyl) functional copolymers (polyethers), silicone hydrides and cross-linking agents, which may be optionally reacted with water to react the remaining alkoxy groups. The crosslinking agent contains either SiH or Si-alkoxy groups or both. The compounds of the present invention exhibit only moderate cross-linking in order to be soluble or dispersible in appropriate solvents.Type: ApplicationFiled: January 30, 2013Publication date: August 1, 2013Applicant: Momentive Performance Materials Inc.Inventor: Momentive Performance Materials Inc.
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Patent number: 8268975Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.Type: GrantFiled: April 3, 2009Date of Patent: September 18, 2012Assignees: DOW Agrosciences LLC, Kroff Chemical CompanyInventors: Paul Rey, Steve P. Ceplecha, David M. Sunderlik
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Patent number: 8198337Abstract: The present invention provides for a demulsifying composition comprising a blend of a) an emulsion; and b) a demulsifying-effective amount of a non-crosslinked silicon polyether. The present invention also provides for a method for separating emulsions using the demulsifying composition discussed.Type: GrantFiled: January 27, 2010Date of Patent: June 12, 2012Assignee: Momentive Performance Materials Inc.Inventors: Benjamin Falk, Kalman Koczo, Monjit Phukan, Antonio Palumbo, Anubhav Saxena
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Patent number: 8129435Abstract: The present invention relates to a perfluoropolyether-modified polysiloxane represented by general formula (1): wherein Rf is a linear or branched perfluoroalkyl group having 1 to 10 carbon atoms; X is a fluorine atom or a trifluoromethyl group; Q is a divalent organic group having 1 to 12 carbon atoms; R1, R2, and R3 are, independently of each other, an alkyl group having 1 to 10 carbon atoms or an aryl group; a, b, c, and d are, independently of each other, an integer of from 0 to 200, provided that a total of a, b, c and d is 1 or larger; e is an integer of 0 or 1; and z is an integer of from 5 to 100; a method for preparing the same; and a defoaming agent comprising the same.Type: GrantFiled: June 17, 2010Date of Patent: March 6, 2012Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hiromasa Yamaguchi, Noriyuki Koike, Kazuyuki Takewaki
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Publication number: 20120024759Abstract: The present invention provides for a demulsifying composition comprising a blend of a) an emulsion; and b) a demulsifying-effective amount of a silicon containing co-polymer. The present invention also provides for a method for separating emulsions using the demulsifying composition discussed.Type: ApplicationFiled: August 2, 2010Publication date: February 2, 2012Applicant: Momentive Performance Materials Inc.Inventors: Kalman KOCZO, Benjamin FALK, Antonio PALUMBO
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Publication number: 20110245354Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a polyorganosiloxane demulsifier into an emulsion comprising an oil phase and an aqueous phase. The invention also relates to compositions containing polyorganosiloxane demulsifier and the water and oil phases of an emulsion.Type: ApplicationFiled: June 14, 2011Publication date: October 6, 2011Applicant: Momentive Performance Materials Inc.Inventors: Anubhav Saxena, Monjit Phukan, Senthilkumar U, Ian Procter, Sigfredo Gonzalez, Kalman Koczo, Sabine Azouani, Vikram Kumar
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Patent number: 8030363Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a polyorganosiloxane demulsifier into an emulsion comprising an oil phase and an aqueous phase. The invention also relates to compositions containing polyorganosiloxane demulsifier and the water and oil phases of an emulsion.Type: GrantFiled: January 25, 2008Date of Patent: October 4, 2011Assignee: Momentive Performance Materials Inc.Inventors: Anubhav Saxena, Monjit Phukan, Umapathy Senthilkumar, Ian Procter, Sigfredo Gonzalez, Kalman Koczo, Sabine Azouani, Vikram Kumar
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Publication number: 20110184075Abstract: The present invention provides for a demulsifying composition comprising a blend of a) an emulsion; and b) a demulsifying-effective amount of a non-crosslinked silicon polyether. The present invention also provides for a method for separating emulsions using the demulsifying composition discussed.Type: ApplicationFiled: January 27, 2010Publication date: July 28, 2011Applicant: Momentive Performance Materials Inc.Inventors: Benjamin Falk, Kalman Koczo, Monjit Phukan, Antonio Palumbo, Anubhav Saxena
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Patent number: 7981979Abstract: A composition comprising one or more siloxane cross-linked demulsifiers wherein said siloxane cross-linked demulsifiers are prepared by reacting one or more alkylphenol-formaldehyde resin alkoxylates, one or more polyalkylene glycols, or a mixture thereof, with up to about 1.0 molar equivalents of one or more silicon-based cross-linkers of formula R1R2R3R4Si wherein R1, R2, R3, R5, R6 and R7 are independently selected from H, Cl, C1-C4 alkyl and C1-C4 alkoxy; R4. is selected from H, Cl, C1-C4 alkyl, C1-C4 alkoxy and a group of formula L1SiR5R6R7; L1 is absent or is selected from —O—, arylene and C1-C12 alkylene, optionally interrupted by one or more —O— or —N(R8)—; and R8 is H or C1-C4 alkyl and a method of using the demulsifier composition to resolve water-in-oil emulsions.Type: GrantFiled: September 20, 2007Date of Patent: July 19, 2011Assignee: Nalco CompanyInventor: Austen K. Flatt
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Patent number: 7745501Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a silicone demulsifier into an emulsion comprising an oil phase and an aqueous phase, the silicone demulsifier having a molecular structure comprising a polysiloxane backbone of at least two siloxane units covalently bound to (i) one or more alkylene oxide groups comprising one or more alkylene oxide units independently having one to five carbon atoms, and (ii) one or more oxirane-containing and/or oxetane-containing groups, wherein said oxirane or oxetane is optionally ring-opened by reaction with a chemical or group capable of ring-opening an oxirane or oxetane ring, respectively, and wherein a solid filler is substantially excluded from the silicone demulsifier and emulsion. The invention also relates to compositions containing the above-described demulsifier and the water and oil phases of an emulsion.Type: GrantFiled: June 22, 2006Date of Patent: June 29, 2010Assignee: Momentive Performance Materials Inc.Inventors: Kalman Koczo, Sabine Isabelle Azouani, Benjamin Falk
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Patent number: 7652072Abstract: Compositions comprising an asymmetric disiloxane surfactant composition comprising a silicone composition comprising a silicone having the formula: MM? where M or M? comprises an alkylpolyalkyleneoxide bearing substituent selected from the group consisting of: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 and R12SiR5R6(R13(C2H4O)a(C3H6O)b(C4H8O)cR14) that exhibit resistance to hydrolysis over a wide pH range.Type: GrantFiled: June 30, 2006Date of Patent: January 26, 2010Assignee: Momentive Performance Materials Inc.Inventors: Mark D. Leatherman, George A. Policello, Suresh K. Rajaraman
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Patent number: 7491427Abstract: [PROBLEMS] To provide a polyimidesiloxane solution composition that is excellent in defoaming ability and that can maintain the wettability of an outer lead bonded portion on a wiring board at a high level, even when it is applied on the surface of the wiring board and then cured, to form an insulating cured film. [MEANS FOR SOLVING PROBLEMS] A polyimidesiloxane solution composition which comprises an organic solvent, polyimidesiloxane soluble in the organic solvent, a curable components such as an epoxy compound and a polyvalent isocyanate compound, and a silicone defoamer, wherein the silicone defoaming agent comprises dimethylpolysiloxane, a polysiloxane compound having a hydrophilic group in a side chain or a terminal moiety, and a micro-powder silica.Type: GrantFiled: February 21, 2005Date of Patent: February 17, 2009Assignee: UBE Industries, Ltd.Inventors: Koji Hayashi, Yoshiki Tanaka, Katsutoshi Hirashima, Seiichirou Takabayashi
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Publication number: 20080076840Abstract: A composition comprising one or more siloxane cross-linked demulsifiers wherein said siloxane cross-linked demulsifiers are prepared by reacting one or more alkylphenol-formaldehyde resin alkoxylates, one or more polyalkylene glycols, or a mixture thereof, with up to about 1.0 molar equivalents of one or more cross-linkers of formula R1R2R3R4Si wherein R1, R2, R3 and R4 are independently selected from H, Cl, C1-C4 alkyl and C1-C4 alkoxy and a method of using the demulsifier composition to resolve water-in-oil emulsions.Type: ApplicationFiled: September 22, 2006Publication date: March 27, 2008Inventor: Austen K. Flatt
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Publication number: 20070299143Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a silicone demulsifier into an emulsion comprising an oil phase and an aqueous phase, the silicone demulsifier having a molecular structure comprising a polysiloxane backbone of at least two siloxane units covalently bound to (i) one or more alkylene oxide groups comprising one or more alkylene oxide units independently having one to five carbon atoms, and (ii) one or more oxirane-containing and/or oxetane-containing groups, wherein said oxirane or oxetane is optionally ring-opened by reaction with a chemical or group capable of ring-opening an oxirane or oxetane ring, respectively, and wherein a solid filler is substantially excluded from the silicone demulsifier and emulsion. The invention also relates to compositions containing the above-described demulsifier and the water and oil phases of an emulsion.Type: ApplicationFiled: June 22, 2006Publication date: December 27, 2007Inventors: Kalman Koczo, Sabine Isabelle Azouani, Benjamin Falk
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Publication number: 20040101859Abstract: Antifoam agents improve detection of polynucleotide amplification reactions and improve manipulation of fluids in microfluidic devices.Type: ApplicationFiled: November 25, 2002Publication date: May 27, 2004Applicant: CepheidInventors: Byung Sook Moon, Jose Johnny Valdez
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Patent number: 6727388Abstract: The present invention is a demulsifying and corrosion-inhibiting compound formed from the salt of an amphiphilic amine and an amphiphilic acid. In a preferred embodiment of the invention, the demulsifier may be a salt of an alkyl amine and an alkyl aryl sulfonic acid. Even more preferably, the demulsifier may be a salt of a methyl, di-cocoyl amine and an alkyl aryl sulfonic acid. According to another embodiment of the invention, an organic system may be demulsified by mixing the salt of an alkyl amine and an alkyl sulfonic acid with the system to be demulsified.Type: GrantFiled: February 4, 2003Date of Patent: April 27, 2004Assignee: Pilot Chemical Holdings, Inc.Inventor: Robert Golden
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Publication number: 20030130534Abstract: The present invention is a demulsifying and corrosion-inhibiting compound formed from the salt of an amphiphilic amine and an amphiphilic acid. In a preferred embodiment of the invention, the demulsifier may be a salt of an alkyl amine and an alkyl aryl sulfonic acid. Even more preferably, the demulsifier may be a salt of a methyl, di-cocoyl amine and an alkyl aryl sulfonic acid. According to another embodiment of the invention, an organic system may be demulsified by mixing the salt of an alkyl amine and an alkyl sulfonic acid with the system to be demulsified.Type: ApplicationFiled: February 4, 2003Publication date: July 10, 2003Applicant: Pilot Chemical Holdings, Inc.Inventor: Robert Golden
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Patent number: 6187107Abstract: The water-repellent mixture comprises i) a halogenated dispersant chosen from the group constituted by a totally halogenated molecule and a partially halogenated molecule with at least one atom of hydrogen and ii) a copolymeric silicone having a hydrophilic function, for drying solids by the movement of water, the copolymeric silicone preferably being a polyalkylineoxide modified polydimethylsiloxane of formula: with 0≦m≦100, 4≦n≦50 and R being a radical chosen from the group of radicals constituted by a hydrogen atom, an alcohol group, an amine group and a polyalkyl group containing 1 to 5 carbon atoms.Type: GrantFiled: June 24, 1998Date of Patent: February 13, 2001Assignee: Promosol S.A.Inventors: Patrick Duchi, Joseph Micozzi