The Agent Contains Material Which Is Different From The Primary Components Of Both Liquid Phases Of The Emulsion Colloid System (i.e., More Than Only Diluting) Patents (Class 516/139)
  • Patent number: 9375660
    Abstract: This invention relates to a method and device to be used in connection with thickening and clarifying apparatuses for shear-thinning of solids containing material such as slurry. According to the invention the flow area of the shear-thinned material (11) is restricted by arranging a restriction element (12) in the conduit (4,15) for discharging back the shear-thinned material (11).
    Type: Grant
    Filed: April 27, 2007
    Date of Patent: June 28, 2016
    Assignee: Outotec Oyj
    Inventor: Richard Triglavcanin
  • Publication number: 20140303265
    Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.
    Type: Application
    Filed: June 23, 2014
    Publication date: October 9, 2014
    Inventors: Paul Rey, David M. Sunderlik, Steven P. Ceplecha
  • Patent number: 8440727
    Abstract: A method and system for recovering fluid (e.g. liquid) hydrocarbons from both naturally-occurring and man-made mixtures of hydrocarbons and mineral substrates by the exploiting of buoyant beads.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: May 14, 2013
    Inventor: Thomas Gradek
  • Publication number: 20120317875
    Abstract: Systems and methods for processing glycerol into one or more products are provided. In at least one specific embodiment, the method can include decreasing a pH of a mixture comprising glycerol and fatty acids to produce an emulsion comprising a glycerol-rich portion and a fatty acids-rich portion. At least a portion of the glycerol-rich portion can be reacted with an acid comprising phosphorus at conditions sufficient to produce a reacted product comprising glycerophosphoric acid, glycerol, and a portion of the acid.
    Type: Application
    Filed: August 20, 2012
    Publication date: December 20, 2012
    Applicant: Envirosource, Inc.
    Inventors: Spencer S. Awbrey, John Deloach, Tony Alexander, Don Darbonne, Marilyn Darbonne
  • Publication number: 20110124747
    Abstract: The present invention relates to methods for the separation of oil and water, in particular through the action of a polymeric material on oil/water emulsions (including oil-in-water and water-in-oil emulsions).
    Type: Application
    Filed: August 24, 2010
    Publication date: May 26, 2011
    Inventors: Galip Akay, John Vickers
  • Patent number: 7884137
    Abstract: Hydroxyl polyester compounds or compositions which are useful as oilfield demulsifiers are prepared through esterifying carboxylic compounds and epoxide compounds under controlled molar ratios. The hydroxyl polyesters are useful as biodegradable demulsifiers on oil productions.
    Type: Grant
    Filed: February 22, 2008
    Date of Patent: February 8, 2011
    Assignee: M-I L.L.C.
    Inventor: Wei Wang
  • Publication number: 20090215629
    Abstract: Fatty esters of oligoesters of a dicarboxylic acid and a polyol retaining at least one free hydroxyl group, particularly of the formula (I): R1—[OR2O—C(O)—R3—(O)C—]m—R4 (I), where R1 is H, a monocarboxylic acid group, or R6O—[C(O)—R3—(O)C]—; R2s are residues of polyols having at least one substituent free hydroxyl; R3s are hydrocarbylene; R4 is —OH, —OM where M is a salt forming metal, amine or ammonium, —OR6, or —OR2O—R7; R5 is C7 to C21 hydrocarbyl; R6 is C8 to C22 hydrocarbyl; R7 is H, or —C(O)R5; and m is 1 to 20; provided that at least one of R1 and R4 is or includes a C8 to C22 group, are surfactants. A range of surfactant properties can be obtained by varying the molecules within these ranges. Especially where R2 is derived from a higher polyol e.g. sorbitol, R3 is C2 to C6, and the fatty terminal group is C8 to C14, the products can be highly water soluble and effective oil in water emulsifiers.
    Type: Application
    Filed: October 18, 2005
    Publication date: August 27, 2009
    Inventors: Hanamanthsa S. Bevinakatti, Alan G. Waite
  • Publication number: 20090192234
    Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a polyorganosiloxane demulsifier into an emulsion comprising an oil phase and an aqueous phase. The invention also relates to compositions containing polyorganosiloxane demulsifier and the water and oil phases of an emulsion.
    Type: Application
    Filed: January 25, 2008
    Publication date: July 30, 2009
    Inventors: Anubhav Saxena, Monjit Phukan, Senthilkumar U., Ian Procter, Sigfredo Gonzalez, Kalman Koczo, Sabine Azouani, Vikram Kumar
  • Publication number: 20090166028
    Abstract: A method of demulsifying a water-in-oil emulsion is provided. The method includes treating a volume of fluids comprising oil and water by adding a salt of a polynuclear, aromatic sulfonic acid to the fluids so as to cause the oil and water to be at least partially demulsified. The method may further include separating water and oil in a separator. A method of producing hydrocarbons from a subsurface reservoir is also provided. The hydrocarbons include a water-in-oil emulsion. The method includes producing the hydrocarbons through a wellbore, and subjecting the water-in-oil emulsion to a salt of a polynuclear, aromatic sulfonic acid additive so as to cause the oil and water to be at least partially demulsified.
    Type: Application
    Filed: June 14, 2007
    Publication date: July 2, 2009
    Inventors: Ramesh Varadaraj, Cornelius Brons
  • Patent number: 7491427
    Abstract: [PROBLEMS] To provide a polyimidesiloxane solution composition that is excellent in defoaming ability and that can maintain the wettability of an outer lead bonded portion on a wiring board at a high level, even when it is applied on the surface of the wiring board and then cured, to form an insulating cured film. [MEANS FOR SOLVING PROBLEMS] A polyimidesiloxane solution composition which comprises an organic solvent, polyimidesiloxane soluble in the organic solvent, a curable components such as an epoxy compound and a polyvalent isocyanate compound, and a silicone defoamer, wherein the silicone defoaming agent comprises dimethylpolysiloxane, a polysiloxane compound having a hydrophilic group in a side chain or a terminal moiety, and a micro-powder silica.
    Type: Grant
    Filed: February 21, 2005
    Date of Patent: February 17, 2009
    Assignee: UBE Industries, Ltd.
    Inventors: Koji Hayashi, Yoshiki Tanaka, Katsutoshi Hirashima, Seiichirou Takabayashi
  • Patent number: 7482162
    Abstract: We disclose methods for measuring vitamin D metabolite in plasma or serum samples. The methods comprise a step of adding to the plasma or serum samples a non-competitive displacement agent comprising 8-anilino-1-naphthalenesulfonic acid ammonium salt, 3-(acetonylbenzyl)-4-hydroxycoumarin and a water miscible solvent. The non-competitive displacement agent separates vitamin D metabolite from binding proteins in the sample, such that the displaced vitamin D metabolite is available for capture and detection in subsequent binding assays. Thus, our invention finds use in methods of separating and detecting vitamin D metabolites otherwise tightly bound to plasma or serum binding proteins.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: January 27, 2009
    Assignee: Immunodiagnostic Systems Ltd.
    Inventors: David Laurie, Alexander Kirkley Barnes, Michael James Gardner
  • Publication number: 20080207780
    Abstract: Hydroxyl polyester compounds or compositions which are useful as oilfield demulsifiers are prepared through esterifying carboxylic compounds and epoxide compounds under controlled molar ratios. The hydroxyl polyesters are useful as biodegradable demulsifiers on oil productions.
    Type: Application
    Filed: February 22, 2008
    Publication date: August 28, 2008
    Inventor: Wei Wang
  • Publication number: 20080076839
    Abstract: A composition comprising one or more siloxane cross-linked demulsifiers wherein said siloxane cross-linked demulsifiers are prepared by reacting one or more alkylphenol-formaldehyde resin alkoxylates, one or more polyalkylene glycols, or a mixture thereof, with up to about 1.0 molar equivalents of one or more silicon-based cross-linkers of formula R1R2R3R4Si wherein R1, R2, R3, R5, R6 and R7 are independently selected from H, Cl, C1-C4 alkyl and C1-C4 alkoxy; R4. is selected from H, Cl, C1-C4 alkyl, C1-C4 alkoxy and a group of formula L1SiR5R6R7; L1 is absent or is selected from —O—, arylene and C1-C12 alkylene, optionally interrupted by one or more —O— or —N(R8)—; and R8 is H or C1-C4 alkyl and a method of using the demulsifier composition to resolve water-in-oil emulsions.
    Type: Application
    Filed: September 20, 2007
    Publication date: March 27, 2008
    Inventor: Austen K. Flatt
  • Patent number: 7026363
    Abstract: The present invention relates to the use of alkoxylated polyglycerols preparable by polycondensation of glycerol and subsequent alkoxylation for demulsifying water-oil emulsions, in particular in the production of crude oil from crude oil/water emulsions. The invention provides for the use of alkoxylated polyglycerols with a molecular weight of from 250 to 100,000 units which comprise 2 to 100 glycerol units whose free OH groups are alkoxylated with C2–C4-alkylene oxide groups or a mixture of such alkylene oxide groups so that the alkoxylated polyglycerol has a degree of alkoxylation of from 1 to 100 alkylene oxide units per free OH group. The alkoxylated polyglycerols of the present invention are employed for demulsifying oil/water emulsions in amounts of from 0.0001 to 5% by weight, based on the oil content of the emulsion to be demulsified.
    Type: Grant
    Filed: February 9, 2002
    Date of Patent: April 11, 2006
    Assignee: Clariant GmbH
    Inventors: Dirk Leinweber, Franz Xaver Scherl, Elisabeth Wasmund, Heidi Grundner
  • Patent number: 6841089
    Abstract: A method for reducing the toxicity of onium compounds, such as ammonium compounds and phosphonium compounds, by the use of certain additives is described. Suitable additives include, but are not necessarily limited to, carboxylic acids (e.g. naphthenic acids), sulfonic acids, organophosphonic acids, phenolic compounds, ether sulfates, phosphoric acid esters, sulfonated fatty acids, sulfated fatty acids, oligocarboxylic acids, and mixtures thereof, and alkali metal salts of these compounds and amine salts of these compounds.
    Type: Grant
    Filed: January 14, 2004
    Date of Patent: January 11, 2005
    Assignee: Baker Hughes Incorporated
    Inventors: Gordon T. Rivers, Hartley H. Downs
  • Publication number: 20040266892
    Abstract: A process for preparing particles of a substance comprising contacting a first formulation including a first substance with a first solvent stream and a second solvent stream, thereby causing formation of particles of the first substance, wherein both the first and second solvent streams are in a non-supercritical state, and subjecting the resultant mixture to a separation process which causes separation of the first substance from the first and second solvent streams.
    Type: Application
    Filed: May 7, 2004
    Publication date: December 30, 2004
    Inventors: Mazin Nicola, Neale Gray
  • Patent number: 6207722
    Abstract: The present invention relates to a foam control composition and to its use in foaming systems. More particularly, this invention relates to a foam control composition comprising a polysiloxane and a resin-filler made from MQ resins having at least one polyoxyalkylene group. The compositions of this invention exhibit excellent defoam effects and antifoam persistency.
    Type: Grant
    Filed: December 31, 1998
    Date of Patent: March 27, 2001
    Assignees: Dow Corning Corporation, Dow Corning S.A.
    Inventors: Donnie Ray Juen, Bianxiao Zhong, Mercedes Diaz, Tessa Johnson