Plural Zones Each Having A Fischer-tropsch Reaction Patents (Class 518/706)
  • Patent number: 11946001
    Abstract: A process and/or system for producing fuel using renewable hydrogen having a reduced carbon intensity. The renewable hydrogen is produced in a hydrogen production process comprising methane reforming, wherein at least a portion of the feedstock for the hydrogen production process comprises upgraded biogas sourced from a plurality of biogas plants. Each of the upgraded biogases is produced in a process that includes collecting biogas comprising methane and carbon dioxide, capturing at least 50% of the carbon dioxide originally present in the collected biogas and producing the upgraded biogas. Storage of the captured carbon dioxide reducing a carbon intensity of the fuel, without having to provide carbon capture and storage of carbon dioxide from hydrogen production.
    Type: Grant
    Filed: July 13, 2023
    Date of Patent: April 2, 2024
    Assignee: Iogen Corporation
    Inventor: Patrick J. Foody
  • Patent number: 11752478
    Abstract: A catalyst carrier for insertion in a reactor tube of a tubular reactor, said catalyst carrier comprising: a container for holding catalyst in use, said container having a bottom surface closing the container, and a top surface; a carrier outer wall extending from the bottom surface to the top surface; a seal extending from the container by a distance which extends beyond the carrier outer wall; said carrier outer wall having apertures located below the seal.
    Type: Grant
    Filed: August 4, 2021
    Date of Patent: September 12, 2023
    Assignee: Johnson Matthey Davy Technologies Linited
    Inventor: Julian Gray
  • Patent number: 11697107
    Abstract: The present invention describes a mixture comprising carbonaceous raw material of low value as a fuel and a nanocatalyst. The catalytic mixture comprises from 1% to 50% by weight of a nanocatalyst; and from 99% to 50% by weight of carbonaceous raw material selected from petroleum coke, coal, heavy residual fraction of oil, or a mixture thereof. The nanocatalyst comprises a carbon nanomaterial of between 99.99% and 80% by weight in contents and at least one alkali metal of between 0.01% and 20% by weight in contents, based on the total weight of the nanocatalyst, and the specific surface area of the nanocatalyst ranges between 400 and 1300 m2/g. Furthermore, the present invention also describes a process for gasifying the catalytic mixture which comprises the steps of placing the mixture in a gasifier; heating the mixture in the presence of an oxidizing agent selected from air, pure oxygen, carbon dioxide, water vapor, or a mixture thereof at a temperature ranging between 200 and 1,300° C.
    Type: Grant
    Filed: August 2, 2019
    Date of Patent: July 11, 2023
    Assignee: PETROLEO BRASILEIRO S.A.—PETROBRAS
    Inventors: Wladmir Ferraz De Souza, Vivian Passos De Souza, Maira Andrade Rodrigues, Amanda De Almeida Dumani Dos Santos
  • Patent number: 11697628
    Abstract: A method for the preparation of methanol by conversion of a mixture of fresh methanol synthesis gas and unconverted methanol synthesis separated from produced methanol in a low pressure separator and recycled and admixed to the fresh synthesis gas upstream the suction side of a make-up gas compressor.
    Type: Grant
    Filed: November 30, 2020
    Date of Patent: July 11, 2023
    Assignee: Topsoe A/S
    Inventor: Søren Grønborg Eskesen
  • Patent number: 11578413
    Abstract: Disclosed is a Sabatier reactor apparatus including a carbon sorbent bed having an inlet for introducing a reactant stream to the carbon sorbent bed and an outlet for exiting a treated reactant stream from the carbon sorbent bed; and a Sabatier reactor having an inlet for introducing the treated reactant stream to the Sabatier reactor and an outlet for removing a product stream from the Sabatier reactor. Also disclosed is a method of preparing a reactant stream for a Sabatier reactor.
    Type: Grant
    Filed: January 13, 2020
    Date of Patent: February 14, 2023
    Assignee: HAMILTON SUNDSTRAND CORPORATION
    Inventor: Ping Yu
  • Patent number: 11027972
    Abstract: A synthesis process comprising steam reforming a gaseous hydrocarbon feedstock; exothermically reacting the resulting synthesis gas; removing heat from said exothermal reaction by producing steam; using said steam as heat input to the steam reforming, wherein the steam reforming comprises: a) forming a mixture containing steam and hydrocarbons by at least the step of adding a first stream of water to the hydrocarbon feedstock; b) heating said mixture by indirect heat exchange with synthesis gas; c) reforming said mixture after said heating step b).
    Type: Grant
    Filed: January 31, 2018
    Date of Patent: June 8, 2021
    Assignee: CASALE SA
    Inventors: Pietro Moreo, Fabio Sassi
  • Patent number: 10898874
    Abstract: A reactor for conducting exothermic equilibrium reactions, especially for the performance of methanol synthesis by heterogeneously catalysed conversion of synthesis gas, is proposed, which enables readjustment and hence optimization of the reaction conditions along the longitudinal coordinate of the reactor. For this purpose, in accordance with the invention, the reactor is divided into a multitude of series-connected reaction cells, each of which comprises a preheating zone, a cooled reaction zone, one or more cooling zones and a deposition zone for condensable reaction products. In this way, the reaction conditions are adjustable to the respective, local composition of the reaction mixture and variable over the reactor length.
    Type: Grant
    Filed: April 26, 2018
    Date of Patent: January 26, 2021
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Frank Castillo-Welter, Stephane Haag, Robert Frind, Timm Schuhmann, Andreas Ochs, Marc Wagner, Solene Valentin
  • Patent number: 10625236
    Abstract: Various embodiments may include a reactor comprising: a reaction chamber having a lower region defining a sorbent collection zone; a first feed device supplying reactants to the reaction chamber; a second feed device supplying a liquid sorbent to the reaction chamber; a discharge device connected to the sorbent collection zone for removing sorbent from the sorbent collection zone; and a cooling device for cooling the sorbent in the reaction chamber.
    Type: Grant
    Filed: March 16, 2017
    Date of Patent: April 21, 2020
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Jakob Albert, Manfred Baldauf, Jenny Reichert, Katharina Stark, Alexander Tremel, Peter Wasserscheid
  • Patent number: 10550055
    Abstract: In a novel process for methanol production from low quality synthesis gas, in which relatively smaller adiabatic reactors can be operated more efficiently, some of the inherent disadvantages of adiabatic reactors for methanol production are avoided. This is done by controlling the outlet temperature in the pre-converter by rapid adjustment of the recycle gas, i.e. by manipulating the gas hourly space velocity in the pre-converter.
    Type: Grant
    Filed: July 15, 2016
    Date of Patent: February 4, 2020
    Assignee: Haldor Topsoe A/S
    Inventor: Hassan Modarresi
  • Patent number: 10478793
    Abstract: Various embodiments may include a reactor for carrying out equilibrium-limited reactions comprising: a reaction chamber for receiving a catalyst; a sorption chamber for receiving a sorption agent; a feedstock feeding device; a sorption agent feeding device; and a gas-permeable element separating the reaction chamber from the sorption chamber, wherein the gas-permeable element repels particles of the sorption agent.
    Type: Grant
    Filed: February 28, 2017
    Date of Patent: November 19, 2019
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Jakob Albert, Manfred Baldauf, Jenny Reichert, Katharina Stark, Alexander Tremel, Peter Wasserscheid
  • Patent number: 10227534
    Abstract: Disclosed herein are reactors comprising: a) a first mixing zone, b) a first reaction zone, c) a first cooling zone, d) a first H2O separation zone, e) a second mixing zone, f) a second reaction zone, g) a second cooling zone, and h) a second H2O separation zone, wherein the first mixing zone is in fluid communication with the first reaction zone, wherein the first reaction zone is in fluid communication with the first cooling zone, wherein the first cooling zone is in fluid communication with the first H2O separation zone, wherein the first H2O separation zone is in fluid communication with the second mixing zone, wherein the second mixing zone is in fluid communication with the second reaction zone, wherein the second reaction zone is in fluid communication with the second cooling zone, and wherein the second cooling zone is in fluid communication with the second H2O separation zone.
    Type: Grant
    Filed: November 12, 2015
    Date of Patent: March 12, 2019
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Talal Khaled Al-Shammari, Khalid Karim
  • Patent number: 10176985
    Abstract: The method includes the steps of: storing slurry containing optical matter particles into a slurry tank; stirring the slurry inside the slurry tank by causing a bubble producing unit arranged below a liquid surface of the slurry to produce bubbles; and spraying the slurry onto a coating target including a light emitting element from a nozzle arranged above the coating target.
    Type: Grant
    Filed: December 26, 2017
    Date of Patent: January 8, 2019
    Assignees: NICHIA CORPORATION, MTEK-SMART CORPORATION
    Inventors: Takayuki Igarashi, Masafumi Matsunaga
  • Patent number: 10076773
    Abstract: The method for cleaning a reactor of the present invention comprises passing a solvent through a wax-fraction hydrocracking apparatus which is charged with a catalyst and to which supply of a wax fraction is stopped, wherein the solvent comprising at least one oil selected from a group consisting of hydrocarbon and vegetable oils, and having a sulfur content of less than 5 ppm and being in a liquid state at 15° C.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: September 18, 2018
    Assignees: JAPAN OIL, GAS AND METALS NATIONAL CORPORATION, INPEX CORPORATION, JX NIPPON OIL & ENERGY CORPORATION, JAPAN PETROLEUM EXPLORATION CO., LTD., COSMO OIL CO., LTD., NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD.
    Inventors: Shinya Takahashi, Kazuhiko Tasaka, Yuichi Tanaka, Marie Iwama
  • Patent number: 10065911
    Abstract: The present invention provides an improved process for removing heat from an exothermic reaction. In particular, the present invention provides a process wherein heat can be removed from multiple reaction trains using a common coolant system.
    Type: Grant
    Filed: November 20, 2017
    Date of Patent: September 4, 2018
    Assignee: Velocys Technologies Ltd.
    Inventors: Ivan Phillip Greager, Steven Claude LeViness, Roger Allen Harris, Andre Peter Steynberg, Jasmeer Jaichland Ramlal, Dennis Parker, John Dolan
  • Patent number: 10029966
    Abstract: The present invention relates to a method for preparing dimethyl ether from methanol which is carried out in a reaction device arranged with a plurality of catalyst bed layers connected in series, and comprises: dividing the reactant stream that contains methanol into n substreams, and feeding these different substreams into the reaction device through top feed ports or side feed ports between the catalyst bed layers of the reaction device for methanol-to-dimethyl ether reaction; wherein, the temperature T1 of the substream fed into the first catalyst bed layer is controlled within the following range: 290?50K1?T1?150K12?271K1+397.5; where, 1>K1?0.5, and T1 is in unit of ° C.
    Type: Grant
    Filed: September 16, 2016
    Date of Patent: July 24, 2018
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC
    Inventors: Shuai Hu, Xin Jin
  • Patent number: 9387456
    Abstract: Reactor for Fischer-Tropsch reaction which is carried out in a three-phase system essentially consisting of a reacting gaseous phase, a reacted liquid phase and a solid catalytic phase, wherein the solid catalytic phase consists of packed or structured bodies of catalytic material encaged within at least one honeycomb monolithic structure with a high thermal conductivity.
    Type: Grant
    Filed: May 10, 2010
    Date of Patent: July 12, 2016
    Assignee: ENI S.p.A.
    Inventors: Massimo Iovane, Roberto Zennaro, Pio Forzatti, Gianpiero Groppi, Luca Lietti, Enrico Tronconi, Carlo Giorgio Visconti, Stefano Rossini, Elsa Mignone
  • Patent number: 9296672
    Abstract: A method for producing methanol from inert-rich syngas includes installing a catalytic pre-reactor is upstream of the single or mufti-stage synthesis loop, a first part of the syngas being converted to methanol in the catalytic pre-reactor. Furthermore, an inert gas separation stage, for example a pressure swing adsorption system or a membrane system, is connected downstream of the synthesis loop, whereby a hydrogen-enriched syngas stream can be returned to the synthesis loop. In the processing of methane-rich syngas, the inert gas separation stage may also comprise an autothermal reformer in which methane is converted to carbon oxides and hydrogen, which are also returned into the synthesis loop.
    Type: Grant
    Filed: March 22, 2012
    Date of Patent: March 29, 2016
    Assignee: AIR LIQUIDE GLOBAL E&C SOLUTIONS GERMANY GMBH
    Inventors: Philipp Marius Hackel, Rainer Morgenroth, Andreas Bormann, Veronika Gronemann
  • Patent number: 9233352
    Abstract: A tubular reactor is described, for catalytic reactions involving thermal exchanges, in particular for etherification reactions between branched olefins and linear alcohol, for dimerization reactions of branched olefins or cracking reactions, essentially consisting of a vertical tube-bundle exchanger whose tubes contain catalyst, having inlet and outlet nozzles for each passage side of the reagents, catalyst and thermal exchange liquid, characterized in that it has one or more metallic supports situated outside the lower tube plate in the lower part of the reactor for sustaining the catalyst so that the same catalyst is contained not only in the tubes of the tube-bundle but also in said lower part outside the lower tube plate and also in the upper part outside the upper tube plate.
    Type: Grant
    Filed: August 7, 2008
    Date of Patent: January 12, 2016
    Assignee: SAIPEM S.p.A.
    Inventors: Marco Di Girolamo, Maura Brianti, Massimo Conte
  • Patent number: 9193925
    Abstract: Techniques, systems, apparatus and material are disclosed for regeneration or recycling of carbon substances into renewable fuel and materials. In one aspect, a method of recycling carbon to produce a renewable fuel can include harvesting carbon donors, such as carbon dioxide (CO2), emitted from an agricultural process. Hydrogen donors, such as from biomass waste, can be dissociated under an anaerobic reaction to produce hydrogen. The harvested carbon dioxide can be reacted with the waste-produced hydrogen under pressure and temperature to generate a renewable fuel, such as methanol fuel.
    Type: Grant
    Filed: August 13, 2012
    Date of Patent: November 24, 2015
    Assignee: McAlister Technologies, LLC
    Inventor: Roy Edward McAlister
  • Patent number: 9174185
    Abstract: Techniques, methods and systems for preparation liquid fuels from hydrocarbon and carbon dioxide are disclosed. The present invention can transform hydrocarbon and carbon dioxide generated from organic feed stocks or other industrial emissions into renewable engineered liquid fuels and store them in a cost-efficient way. The method of the present invention includes: supplying hydrocarbon and carbon dioxide to a heated area of a reaction chamber in controlled volumes; forming carbon monoxide by the energy provided by the heated area; transporting carbon monoxide and hydrogen to a reactor in controlled volumes; supplying additional hydrogen to the reactor; regulating the pressure in the reactor by adjusting the controlled volumes in order to achieve a predetermined object; forming the liquid fuel in the reactor according to the predetermined object; and, storing the liquid fuel in a storage device.
    Type: Grant
    Filed: December 3, 2013
    Date of Patent: November 3, 2015
    Assignee: McAlister Technologies, LLC
    Inventor: Roy Edward McAlister
  • Patent number: 9040595
    Abstract: A process for the synthesis of methanol, comprising the steps of reforming a hydrocarbon source obtaining a make-up gas feed (101), feeding said make up gas to a synthesis loop (L), converting said make up gas to methanol (108) in a substantially isothermal catalytic environment, wherein said catalytic environment comprises a plurality of isothermal catalytic beds (11, 12, 21) preferably arranged in series, and at least a portion of make-up gas (101) is mixed with recycle gas (112) from the loop (L), obtaining a gaseous mixture of fresh gas and recycle gas, and at least a portion of said gaseous mixture is directed between two consecutive catalytic beds acting as a quench gas. A related plant is also disclosed.
    Type: Grant
    Filed: August 4, 2011
    Date of Patent: May 26, 2015
    Assignee: Casale SA
    Inventor: Fabio Laurenzi
  • Patent number: 9029429
    Abstract: The present invention is directed to a process for the production of hydrocarbon product from two different hydrocarbonaceous feedstocks comprising the steps of preparing a feed syngas having a hydrogen/carbon monoxide [H2/CO] molar feed ratio suitable for Fischer-Tropsch synthesis, wherein the feed syngas is prepared by combining a first syngas having a H2/CO molar ratio below the molar feed ratio and a second syngas having a H2/CO molar ratio above the molar feed ratio; the first syngas is prepared from a liquid hydrocarbon comprising feedstock as the sole source of carbon in a first syngas manufacturing process comprising a non-catalytic partial oxidation step; the second syngas is prepared from a methane comprising feedstock as the sole source of carbon in a second syngas manufacturing process comprising a heat exchange reforming step and an auto-thermal reforming step; and the first and second syngas manufacturing processes are operated in parallel.
    Type: Grant
    Filed: December 10, 2012
    Date of Patent: May 12, 2015
    Assignee: Shell Oil Company
    Inventors: Maarten Bracht, Martin Philipp Rohde
  • Patent number: 9006297
    Abstract: A method and an apparatus is disclosed that uses a gas lift tubing arrangement to produce synthetic hydrocarbon related products. Using the Fischer Tropsch process as an example, the tubing is packed with a suitable catalyst and then hydrogen and carbon monoxide are injected into the top of the tubing in a fashion similar to a gas lift process. As the gases travel past the catalyst, synthetic hydrocarbons are formed and heat is rejected. The synthetic hydrocarbons and water flow out of the bottom of the tubing and travel up the annulus to the surface. In some embodiments, this process is carried out in a producing well or a in producing riser. In a producing well or a producing riser, the production from the well which flows up the annulus cools the synthetic hydrocarbon derived products. In additional and alternate embodiments, this process can be used in non-flowing wells.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: April 14, 2015
    Inventor: Robert P. Herrmann
  • Patent number: 9005554
    Abstract: A method and an apparatus is disclosed that uses a gas lift tubing arrangement to produce synthetic hydrocarbon related products. Using the Fischer Tropsch process as an example, the tubing is packed with a suitable catalyst and then hydrogen and carbon monoxide are injected into the top of the tubing in a fashion similar to a gas lift process. As the gases travel past the catalyst, synthetic hydrocarbons are formed and heat is rejected. The synthetic hydrocarbons and water flow out of the bottom of the tubing and travel up the annulus to the surface. In some embodiments, this process is carried out in a producing well or a in producing riser. In a producing well or a producing riser, the production from the well which flows up the annulus cools the synthetic hydrocarbon derived products. In additional and alternate embodiments, this process can be used in non-flowing wells.
    Type: Grant
    Filed: January 12, 2015
    Date of Patent: April 14, 2015
    Inventor: Robert P. Herrmann
  • Patent number: 9005538
    Abstract: The invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5%-40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) of between 3.0 to 4.5 mm-1, and the remaining catalyst particles have an average S/V of between 4.5 to 8.0 mm-1, and wherein the difference between the average S/V of the particles at the upstream end and the remaining fixed bed volume is at least 0.5 mm-1. Additionally the fixed bed volume at the upstream end shows a full-bed apparent catalytic activity per volume unit lower than the full-bed apparent catalytic activity per volume unit in the remaining fixed bed volume and/or the weight of catalytically active metal per weight unit at the upstream end is more than 70% lower than in the remaining fixed bed volume.
    Type: Grant
    Filed: June 27, 2012
    Date of Patent: April 14, 2015
    Assignee: Shell Oil Company
    Inventors: Robert Martijn Van Hardeveld, Thomas Joris Remans, Erwin Roderick Stobbe
  • Publication number: 20150080482
    Abstract: The invention relates to a process for increasing the carbon monoxide content of a feed gas mixture comprising carbon dioxide, hydrogen and carbon monoxide via a catalytic reversed water gas shift reaction, comprising the steps of (1) heating the feed gas mixture having an initial feed temperature of at most 350° C. in a first zone to a temperature within a reaction temperature range in the presence of a first catalyst; and (2) contacting the heated feed gas in a second zone within the reaction temperature range with a second catalyst. This process shows relatively high conversion of carbon dioxide, and virtually no methane or coke is being formed, allowing stable operation.
    Type: Application
    Filed: November 18, 2014
    Publication date: March 19, 2015
    Inventors: Aggadin Kh. Mamedov, Mubarak Bashir
  • Patent number: 8980194
    Abstract: The present invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5% to 40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) in the range of between 3.0 to 4.5 mm?1, and the catalyst particles in the remaining fixed bed volume have an average outer surface to volume ratio (S/V) in the range of between 4.5 to 8.0 mm?1, and wherein the difference between the average S/V of the particles at the upstream end and the average S/V of the particles in the remaining fixed bed volume is at least 0.5 mm?1.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: March 17, 2015
    Assignee: Shell Oil Company
    Inventors: Alouisius Nicolaas Renée Bos, Peter John Van Den Brink, Thomas Joris Remans, Erwin Roderick Stobbe, Dominik Johannes Michael Unruh, Ronald Vladimir Wisman
  • Patent number: 8946308
    Abstract: The invention relates to a process for increasing the carbon monoxide content of a feed gas mixture comprising carbon dioxide, hydrogen and carbon monoxide via a catalytic reversed water gas shift reaction, comprising the steps of (1) heating the feed gas mixture having an initial feed temperature of at most 350° C. in a first zone to a temperature within a reaction temperature range in the presence of a first catalyst; and (2) contacting the heated feed gas in a second zone within the reaction temperature range with a second catalyst. This process shows relatively high conversion of carbon dioxide, and virtually no methane or coke is being formed, allowing stable operation.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: February 3, 2015
    Assignee: Saudi Basic Industries Corporation
    Inventors: Aggadin Kh. Mamedov, Mubarak Bashir
  • Patent number: 8927611
    Abstract: The invention discloses an improved multistage fischer tropsch process scheme for the production of hydrocarbon fuels comprising feeding gaseous phase syngas and liquid stream hydrocarbons in a counter current manner such as herein described into the reaction vessel at a number of stages containing reaction catalysts; wherein fresh syngas enters into the stage where the product liquid stream leaves and the fresh liquid stream enters into the stage where the unreacted syngas leaves; wherein further the temperature of each stage can be controlled independently. More particularly the invention relates to improving the heat release in different reactors, product selectivity and reactor productivity of FT reactors.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: January 6, 2015
    Assignee: Bharat Petroleum Corporation Limited
    Inventors: Ravi Kumar Voolapalli, Pranab Kumar Rakshit, Venkateswarlu Choudary Nettem, Mohammad Amir Siddiqui
  • Patent number: 8921433
    Abstract: Process for the conversion of carbon oxide(s) and hydrogen containing feedstocks into alcohols in the presence of a particulate catalyst.
    Type: Grant
    Filed: June 29, 2006
    Date of Patent: December 30, 2014
    Assignee: BP Chemicals Limited
    Inventors: Peter Simpson Bell, Leslie William Bolton, Benjamin Patrick Gracey, Michael Keith Lee
  • Patent number: 8906970
    Abstract: In a process for converting synthesis gas to higher hydrocarbons in a tubular reactor, reactants are introduced through an inlet of the reactor. The reactants are passed downwardly through at least one tube to an upper surface of a catalyst carrier where they pass into a passage defined by an inner perforated wall of a catalyst container before passing radially through the catalyst bed towards the perforated outer wall. Reaction occurs as the synthesis gas contacts the catalyst. Unreacted reactant and product is passed out of the container through a perforated outer wall thereof and then upwardly between a skirt and an outer wall of the container, followed by being directed over the end of the skirt and downwardly between the skirt and the reactor tube where heat transfer takes place. These steps are repeated for any subsequent catalyst carrier, then product is removed from an outlet of the reactor.
    Type: Grant
    Filed: February 6, 2012
    Date of Patent: December 9, 2014
    Assignee: Davy Process Technology Limited
    Inventor: Timothy Douglas Gamlin
  • Patent number: 8884089
    Abstract: The present invention provides a process for producing olefins, comprising: a. cracking an ethane-comprising feed in a cracking zone under cracking conditions to obtain at least olefins and hydrogen; b. converting an oxygenate feedstock in an oxygenate-to-olefin zone to obtain at least olefins; wherein at least part of the oxygenate feedstock is obtained by providing hydrogen obtained in step a) and a feed containing carbon monoxide and/or carbon dioxide to an oxygenate synthesis zone and synthesizing oxygenates. In another aspect the invention provides an integrated system for producing olefins.
    Type: Grant
    Filed: November 9, 2010
    Date of Patent: November 11, 2014
    Assignee: Shell Oil Company
    Inventors: Leslie Andrew Chewter, Jeroen Van Westrenen
  • Patent number: 8859631
    Abstract: A process is described for the conversion of synthesis gas into hydrocarbons including the steps of; (i) passing a synthesis gas comprising hydrogen and carbon monoxide over a cobalt catalyst at elevated temperature and pressure to produce a first reaction product mixture comprising hydrocarbons, steam, carbon monoxide and hydrogen, (ii) condensing and separating water from the first reaction product mixture to produce a de-watered first reaction product mixture, (iii) passing the de-watered first reaction product mixture over a supported ruthenium catalyst at elevated temperature and pressure to produce a second reaction product mixture containing hydrocarbons, and (iv) recovering the hydrocarbons from the second reaction product mixture.
    Type: Grant
    Filed: December 16, 2010
    Date of Patent: October 14, 2014
    Assignee: Johnson Matthey PLC
    Inventor: Mark McKenna
  • Patent number: 8852539
    Abstract: A second stage Fischer-Tropsch reaction system to enhance a conversion ratio of a synthetic gas, includes, at least one first reactor that uses a Fe catalyst, receives a first synthetic gas extracted from a coal, biomass or natural gas, and reacts the first synthetic gas with the Fe catalyst to obtain a synthetic fuel, and a second reactor that uses a Fe.Co or Co catalyst, receives a second synthetic gas discharged from the first reactors after reaction, and reacts the second synthetic gas with the Fe.Co or Co catalyst to obtain a synthetic fuel.
    Type: Grant
    Filed: July 7, 2011
    Date of Patent: October 7, 2014
    Assignee: Korea Institute of Energy Research
    Inventors: Ho Tae Lee, Heon Jung, Jung Il Yang, Hak Joo Kim, Dong Hyun Chun, Jung Hoon Yang, Ji Chan Park, Byung Kwon Kim
  • Patent number: 8795597
    Abstract: A method and apparatus for converting natural gas from a source, such as a wellhead, pipeline, or a storage facility, into hydrocarbon liquid stable at room temperature, comprising a skid or trailer mounted portable gas to liquids reactor. The reactor includes a preprocessor which desulfurizes and dehydrates the natural gas, a first stage reactor which transforms the preprocessed natural gas into synthesis gas, and a liquid production unit using a Fischer-Tropsch or similar polymerization process. The hydrocarbon liquid may be stored in a portable tank for later transportation or further processed on site.
    Type: Grant
    Filed: November 4, 2013
    Date of Patent: August 5, 2014
    Assignee: Greenway Innovative Energy, Inc.
    Inventor: F. Conrad Greer
  • Patent number: 8773118
    Abstract: A magnetometer which includes an elongate reactor in which a sample can be secured in a sample support zone and which is located within a magnetic field space of a magnetic field generator and one or more signal pickup coils. Movement generating means is provided for generating relative movement in a generally linear direction between the reactor and at least one of the magnetic field and pickup coil, preferably by moving the reactor in its length. The magnetometer is characterised in that the reactor is a metal tube having a length which permits its ends to remain external of the signal pickup device during the relative movement.
    Type: Grant
    Filed: July 10, 2009
    Date of Patent: July 8, 2014
    Assignee: University of Cape Town
    Inventors: Michael Christian Maximilian Claeys, Eric Wilhelmus Josephus Van Steen, Jacobus Lucas Visagie, Jan van de Loosdrecht
  • Publication number: 20140187653
    Abstract: In a process for converting synthesis gas to higher hydrocarbons in a tubular reactor, reactants are introduced through an inlet of the reactor. The reactants are passed downwardly through at least one tube to an upper surface of a catalyst carrier where they pass into a passage defined by an inner perforated wall of a catalyst container before passing radially through the catalyst bed towards the perforated outer wall. Reaction occurs as the synthesis gas contacts the catalyst. Unreacted reactant and product is passed out of the container through a perforated outer wall thereof and then upwardly between a skirt and an outer wall of the container, followed by being directed over the end of the skirt and downwardly between the skirt and the reactor tube where heat transfer takes place. These steps are repeated for any subsequent catalyst carrier, then product is removed from an outlet of the reactor.
    Type: Application
    Filed: February 6, 2012
    Publication date: July 3, 2014
    Applicant: DAVY PROCESS TECHNOLOGY LIMITED
    Inventor: Timothy Douglas Gamlin
  • Patent number: 8759406
    Abstract: The invention is directed to a process for the production of hydrocarbon products from a methane comprising feedstock comprising of the steps of: preparing a feed syngas comprising hydrogen and carbon monoxide having a hydrogen/carbon monoxide molar feed ratio in a syngas manufacturing process and using the feed syngas in a Fischer-Tropsch process using one or more fixed bed catalyst beds as present in one or more syngas conversion reactors thereby obtaining the hydrocarbon product and an residual tail gas. The manufacturing process comprises of two parallel operated syngas manufacturing processes starting from the same gaseous methane comprising feedstock.
    Type: Grant
    Filed: April 20, 2010
    Date of Patent: June 24, 2014
    Assignee: Shell Oil Company
    Inventors: Maarten Bracht, Martin John Fernie
  • Patent number: 8759407
    Abstract: Process for producing synthetic natural gas (SNG) which is provided in an energy-efficient way at the inlet pressure into a downstream pipeline system. For this purpose, a synthesis gas containing carbon oxides and hydrogen is converted into a product gas rich in methane by multi-stage catalytic methanation in a main reaction zone and a post-reaction zone, wherein the adjustment of the target pressure is effected by compression before the main reaction zone and/or before or in the post-reaction zone.
    Type: Grant
    Filed: June 15, 2011
    Date of Patent: June 24, 2014
    Assignee: Lurgi GmbH
    Inventor: Stefan Walter
  • Publication number: 20140107235
    Abstract: In a process for converting synthesis gas to methanol, gas is introduced through an inlet of a tubular reactor. Reactants pass downwardly through at least one reactor tube to an upper surface of a catalyst carrier and into a passage defined by an inner perforated wall of a carrier container before passing radially through the catalyst bed towards a perforated outer container wall. Reaction occurs as synthesis gas contacts the catalyst. Unreacted reactant and product pass out of the container through the outer container wall and then upwardly between the inner surface of a container skirt and an outer annular container wall, and then over the end of the skirt and downwardly between the outer surface of the skirt and the inner surface of the reactor tube where heat transfer takes place. The steps are repeated at any subsequent catalyst carrier and then product is removed from the reactor outlet.
    Type: Application
    Filed: February 14, 2012
    Publication date: April 17, 2014
    Applicant: DAVY PROCESS TECHNOLOGY LIMITED
    Inventor: Timothy Douglas Gamlin
  • Patent number: 8637717
    Abstract: A municipal solid waste material is converted to a refuse derived fuel then to syngas which is processed to produce a liquid feedstream via Fischer-Tropsch Synthesis. The Fischer-Tropsch liquid feedstream is combined with a triglyceride feedstream then hydroprocessed to produce a distillate fuel end product.
    Type: Grant
    Filed: September 3, 2010
    Date of Patent: January 28, 2014
    Assignee: Rational Energies, LLC
    Inventors: Ian S. Mackay, Juan F. Pearcy Salinas
  • Patent number: 8629190
    Abstract: For producing methanol from a synthesis gas containing hydrogen and carbon oxides the synthesis gas is passed through a first, preferably water-cooled reactor in which a part of the carbon oxides is catalytically converted to methanol, and the resulting mixture containing synthesis gas and methanol vapor is supplied to a second, preferably gas-cooled reactor in which a further part of the carbon oxides is converted to methanol. The mixture withdrawn from the first reactor is guided through a gas/gas heat exchanger in which the mixture is cooled to a temperature below its dew point. Subsequently, methanol is separated from the gas stream in a methanol separator and withdrawn, while the remaining gas stream is supplied to the second reactor.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: January 14, 2014
    Assignee: Lurgi GmbH
    Inventor: Hans Kopetsch
  • Patent number: 8629191
    Abstract: For producing methanol from a synthesis gas containing hydrogen and carbon oxides the synthesis gas is passed through a first, water-cooled reactor in which a part of the carbon oxides is catalytically converted to methanol. The resulting mixture containing synthesis gas and methanol vapor is supplied to a second, gas-cooled reactor in which a further part of the carbon oxides is converted to methanol. Subsequently, methanol is separated from the synthesis gas, and synthesis gas is recirculated to the first reactor. The cooling gas flows through the second reactor cocurrent to the mixture withdrawn from the first reactor.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: January 14, 2014
    Assignee: Lurgi GmbH
    Inventors: Hans Kopetsch, Philipp Marius Hackel, Veronika Gronemann, Rainer Morgenroth
  • Publication number: 20130303638
    Abstract: The invention relates to a method for making a methane-rich gas from synthesis gas. This necessitates a method in which a synthesis gas (4) containing CO and H2 is mixed with a gas stream (8) that is diverted from the methane-rich product gas and returned thereto, and is then passed through a catalyst bed (1) consisting of a methanation catalyst, wherein methanation takes place in the catalyst bed (1) and the gas stream is heated by released reaction heat. According to the invention, the catalyst bed (1) is divided into several methanation stages (2.1 to 2.4) through which the gas flows one after the other, and the synthesis gas (4) is split correspondingly into partial streams (4.1 to 4.4), each of which is fed to the catalyst bed (1) of an assigned methanation stage (2.1 to 2.4). The gas (6.1 to 6.3) that exits a methanation stage, and that has been heated up by methanation reactions in this stage is mixed with the partial stream of synthesis gas (4.2 to 4.
    Type: Application
    Filed: October 5, 2011
    Publication date: November 14, 2013
    Inventors: Holger Thielert, Johannes Menzel
  • Patent number: 8557192
    Abstract: Improved design of a catalytic method and reactor for the production of methanol at equilibrium conditions, whereby methanol, as it is formed, is separated from the gaseous phase into the liquid phase within the reactor without reducing the catalytic activity of the methanol catalyst. This is achieved by adjusting the boiling point or temperature of a liquid cooling agent being in indirect contact with the catalyst particles and by providing a specific ratio of catalyst bed volume to cooling surface area. Thereby, condensation of methanol as it is formed in the gaseous phase takes place for the most at the cooling surface arranged evenly distributed within the reactor and if at all within a very limited region of the catalyst bed.
    Type: Grant
    Filed: June 15, 2012
    Date of Patent: October 15, 2013
    Assignee: Haldor Topsoe A/S
    Inventor: Max Thorhauge
  • Patent number: 8506910
    Abstract: A process and system for producing high octane fuel from carbon dioxide and water is disclosed. The feedstock for the production line is industrial carbon dioxide and water, which may be of lower quality. The end product can be high octane gasoline, high cetane diesel or other liquid hydrocarbon mixtures suitable for driving conventional combustion engines or hydrocarbons suitable for further industrial processing or commercial use. Products, such as dimethyl ether or methanol may also be withdrawn from the production line. The process is nearly emission free and reprocesses all hydrocarbons not suitable for liquid fuel to form high octane products. The heat generated by exothermic reactions in the process is fully utilized as is the heat produced in the reprocessing of hydrocarbons not suitable for liquid fuel.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: August 13, 2013
    Assignee: CRI EHF
    Inventors: Shwetank Singh, Omar Freyr Sigurbjornsson, Kim-Chinh Tran
  • Publication number: 20130203872
    Abstract: A process for the synthesis of methanol, comprising the steps of reforming a hydrocarbon source obtaining a make-up gas feed (101), feeding said make up gas to a synthesis loop (L), converting said make up gas to methanol (108) in a substantially isothermal catalytic environment, wherein said catalytic environment comprises a plurality of isothermal catalytic beds (11, 12, 21) preferably arranged in series, and at least a portion of make-up gas (101) is mixed with recycle gas (112) from the loop (L), obtaining a gaseous mixture of fresh gas and recycle gas, and at least a portion of said gaseous mixture is directed between two consecutive catalytic beds acting as a quench gas. A related plant is also disclosed.
    Type: Application
    Filed: August 4, 2011
    Publication date: August 8, 2013
    Inventor: Fabio Laurenzi
  • Patent number: 8497308
    Abstract: A process for carrying out at least two unit operations in series, the process comprising the step of: (a) directing a feed stream into an integrated assembly which comprises a first microchannel unit operation upon at least one chemical of the feed stream to generate a distributed output stream that exits the first microchannel unit operation in a first set of discrete microchannels isolating flow through the discrete microchannels; and (b) directing the distributed output stream of the first microchannel unit operation into a second microchannel unit operation as a distributed input stream, to continue isolating flow between the first set of discrete microchannels, and conducting at least one operation upon at least one chemical of the input stream to generate a product stream that exits the second microchannel unit operation, where the first microchannel unit operation and the second unit operation share a housing.
    Type: Grant
    Filed: September 5, 2007
    Date of Patent: July 30, 2013
    Assignee: Velocys, Inc.
    Inventors: Anna Lee Y. Tonkovich, Robert D. Litt, Timothy M. Werner, Bin Yang
  • Patent number: 8497310
    Abstract: The present invention relates to a process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle (i.e. between regenerations or between start-up with freshly loaded catalyst and the first regeneration) by catalytic conversion of synthesis gas in a multiple reactor arrangement comprising at least two parallel operating reactors containing a catalyst capable of converting synthesis gas to hydrocarbons, and each reactor having a different relative reaction rate, wherein synthesis gas is distributed to each reactor at a feed rate proportional to the relative reaction rate in the respective reactor.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: July 30, 2013
    Assignee: Shell Oil Company
    Inventors: Arend Hoek, Hans Michiel Huisman
  • Patent number: 8471076
    Abstract: In the production of methanol from a synthesis gas containing hydrogen and carbon oxides, the synthesis gas is passed through a first, preferably water-cooled reactor, in which a part of the carbon oxides is catalytically converted to methanol. The obtained mixture containing synthesis gas and methanol vapor is supplied to a second, preferably gas-cooled reactor, in which a further part of the carbon oxides is converted to methanol. Subsequently, methanol is separated from the synthesis gas, and the synthesis gas is recirculated to the first reactor. To achieve a maximum methanol yield even with an aged catalyst, a partial stream of the synthesis gas is guided past the first reactor and introduced directly into the second reactor.
    Type: Grant
    Filed: August 18, 2008
    Date of Patent: June 25, 2013
    Assignee: Lurgi GmbH
    Inventors: Dierk Müller, Andreas Bormann