Ingredient Contains A Boron Atom Patents (Class 521/103)
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Patent number: 11952455Abstract: The present invention provides a foam having a surface which solates or gelates after absorption of water and appropriately absorbs the water. The foam is prepared by a foam reaction of a mixture comprising at least one polyol, a compound having at least one isocyanate group, and a hydrophilic polymer.Type: GrantFiled: December 28, 2017Date of Patent: April 9, 2024Assignee: ALCARE CO., LTD.Inventors: Takabumi Kubo, Tomoya Tanaka, Ryota Watanabe
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Patent number: 11799166Abstract: The present invention provides a process for modifying a Li-ion battery having a region of electrochemical activity and an enclosure therefor, said process comprising forming at least one chamber within said enclosure separate from said region of electrochemical activity, positioning combustion abatement agent within said chamber, whereby said combustion abatement agent is not in contact with said region of electrochemical activity, said chamber being pressure or heat sensitive, whereby when said region of electrochemical activity overheats, said chamber is breached, allowing said combustion abatement agent to contact said region of electrochemical activity to abate combustion of said region of electrochemical activity, wherein exemplary of combustion abatement agent is the composition comprising liquid fluoropolyether and exemplary of the of the chamber exhibiting pressure or heat sensitivity is to include a low melting, non-flammable polymer such as polyvinyl alcohol in the material of construction of the cType: GrantFiled: September 26, 2019Date of Patent: October 24, 2023Assignee: THE CHEMOURS COMPANY FC, LLCInventors: Dennis J. Kountz, Alan D. English, Paul Douglas Brothers, James R. Hoover, Donna Lynn Visioli
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Patent number: 11198773Abstract: The presently disclosed subject matter is directed to a method of making a foam, specifically, the development of isocyanate-free foams using at least one unsaturated polyester. The at least one unsaturated polyester is a reaction product of at least one unsaturated cyclic anhydride, dicyclopentadiene, and at least one polyol. The disclosed formulation further comprises at least one reactive diluent and at least one initiator. The disclosed formulations are cured by a free radical mechanism.Type: GrantFiled: November 19, 2018Date of Patent: December 14, 2021Assignee: Cryovac, LLCInventors: Drew V. Speer, Christopher Scott, Amber C. Rumple, Njamkou N. Noucti
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Patent number: 11009176Abstract: A thermal insulation structure for a substrate for use subsea, and a method of providing a thermal insulating structure. The structure comprises: an inner layer and an outer layer. The inner layer is the reaction product of a first part and a second part, wherein the weight ratio of the first part to the second part is from about 15:1 to 1:1. The first part comprises any of alkenyldialkyl terminated polydialkylsiloxane, alkenyldialkyl terminated polydialkylalkenylmethylsiloxane or mixtures thereof, which will individually or collectively have a viscosity of from 250 to 10000 mPa·s at 25° C., and a hydrosilylation catalyst. The second part comprises a mixture of organohydrogensiloxane having two Si—H bonds per molecule and organohydrogensiloxane having at least three Si—H bonds per molecule. The outer layer is the reaction product of a first part and a second part, wherein the weight ratio of the first part to the second part is from about 15:1 to 1:1.Type: GrantFiled: June 19, 2018Date of Patent: May 18, 2021Assignees: Advanced Insulation Limited, Dow Silicones CorporationInventors: Simon Harry Shepherd, Laura Louise Jordan, Brian Swanton, Patrick Beyer, Roman Vanecek
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Patent number: 10844189Abstract: A functional material has, as a first component, a thermoset plastic material, as a second component, a binding material for binding the thermoset plastic material, and, as a third component, at least one additive, which is configured to improve a burning behavior, wherein the burning behavior corresponds at least to a fire reaction class C as given by DIN EN 113501-1 [German/European norm 113501-1]. A method is intended for producing such a functional material and an element is produced from such a functional material.Type: GrantFiled: November 4, 2016Date of Patent: November 24, 2020Assignee: Puren GmbHInventor: Hans Bommer
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Patent number: 10611066Abstract: Embodiments of the present invention are based, at least in part, on the discovery of methods for encapsulating fragile insulation materials within polyisocyanurate foam to thereby provide a construction board having an advantageous balance of insulating properties and mechanical durability.Type: GrantFiled: March 31, 2015Date of Patent: April 7, 2020Assignee: Firestone Building Products Co., LLCInventors: John B. Letts, Michael J. Hubbard
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Patent number: 9890420Abstract: An article such as a biosensor having a nonfouling surface thereon is described. The article comprises: (a) a substrate having a surface portion; (b) a linking layer on the surface portion; (c) a polymer layer comprising brush molecules formed on the linking layer; and (d) optionally but preferably, a first member of a specific binding pair (e.g., a protein, peptide, antibody, nucleic acid, etc.) coupled to the brush molecules. The polymer layer is preferably formed by the process of surface-initiated polymerization (SIP) of monomeric units thereon. Preferably, each of the monomeric units comprises a monomer (for example, a vinyl monomer) core group having at least one protein-resistant head group coupled thereto, to thereby form the brush molecule on the surface portion. Methods of using the articles are also described.Type: GrantFiled: July 25, 2016Date of Patent: February 13, 2018Assignee: Duke UniversityInventor: Ashutosh Chilkoti
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Patent number: 9850429Abstract: The invention relates to a firestop material consisting of a polymer foam, notably a polyurethane foam, containing flame-retardant means. This firestop material is characterized in that the flame-retardant means consist of means designed to form a charred layer on the foam surface, under the effect of a rise in the temperature of the material resulting from a fire, and are supplemented by at least one inorganic type flame retardant. The invention furthermore relates to a chemical composition intended, after expansion and drying, to form such a firestop material, and to a use of such a firestop material.Type: GrantFiled: July 22, 2005Date of Patent: December 26, 2017Assignee: COMPART SASInventors: Fouad Laoutid, Jean Sauttreau, Laurent Bergogne
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Patent number: 9815952Abstract: A solid material can be prepared from a liquid precursor in solvent free conditions.Type: GrantFiled: March 14, 2014Date of Patent: November 14, 2017Assignee: Melior Innovations, Inc.Inventor: Walter Sherwood
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Patent number: 9777199Abstract: To provide an amine catalyst for curing a polyisocyanate which can satisfy both initial moldability before a thermal compression step and high reactivity at the time of thermal compression molding, and an adhesive composition containing it. A catalyst comprising an amine compound (1) represented by the formula (1) and an amine compound (2) represented by the formula (2) is used as an amine catalyst for curing a polyisocyanate compound. wherein each of R1 and R2 which are independent of each other, is a C1-4 hydrocarbon group, and R3 is a C1-4 hydrocarbon group having a hydroxy group or an amino group; wherein each of R4 and R5 which are independent of each other, is a C1-4 hydrocarbon group, R6 is a C1-4 hydrocarbon group or a C1-4 hydrocarbon group having a hydroxy group or an amino group, R7 is a C1-4 hydrocarbon group having a hydroxy group or an amino group, and m is an integer of from 2 to 6.Type: GrantFiled: July 26, 2013Date of Patent: October 3, 2017Assignee: TOSOH CORPORATIONInventors: Yasumichi Miyagawa, Hiroyuki Kiso
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Patent number: 9493823Abstract: An article such as a biosensor having a nonfouling surface thereon is described. The article comprises: (a) a substrate having a surface portion; (b) a linking layer on the surface portion; (c) a polymer layer comprising brush molecules formed on the linking layer; and (d) optionally but preferably, a first member of a specific binding pair (e.g., a protein, peptide, antibody, nucleic acid, etc.) coupled to the brush molecules. The polymer layer is preferably formed by the process of surface-initiated polymerization (SIP) of monomeric units thereon. Preferably, each of the monomeric units comprises a monomer (for example, a vinyl monomer) core group having at least one protein-resistant head group coupled thereto, to thereby form the brush molecule on the surface portion. Methods of using the articles are also described.Type: GrantFiled: January 3, 2013Date of Patent: November 15, 2016Assignee: Duke UniversityInventor: Ashutosh Chilkoti
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Patent number: 9422391Abstract: The present invention relates to a two-part composition suitable for use in the preparation of a foamed material wherein the first part comprises a source of metal ions and water and the second part comprises an isocyanate, wherein the ratio of NCO isocyanate to water to metal ions is 1 mol:3.5 to 5.5 mol:95 to 650 mmol. Also forming part of the invention is a foamed isocyanate material, a method of preparing the material and controlling foam formation and uses of the composition and material.Type: GrantFiled: October 10, 2012Date of Patent: August 23, 2016Assignee: MINOVA INTERNATIONAL LIMITEDInventors: Robert Penczek, Jan Franek, Krzysztof Chabrzyk, Stanislaw Makarski, Mariusz Rasek, Olga Krizanovic
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Patent number: 9074315Abstract: The present disclosure relates to a composition comprising cross linking agents, polymers, proteins and alkaline reducing agents to obtain wrinkle free woolen garment. The present disclosure further relates to a method of obtaining said composition along with a process of obtaining the wrinkle free woolen garment. The disclosure also relates to the treated garment.Type: GrantFiled: December 14, 2009Date of Patent: July 7, 2015Assignee: Aditya Birla Nuvo LimitedInventor: Debashis Bhadra
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Publication number: 20140364523Abstract: This invention relates to viscoelastic silicone rubber compositions that are the products of the reaction of: (a) a silanol-terminated polyorganosiloxane base; (b) a boron-containing crosslinking agent; and (c) a siloxane bond-forming crosslinking agent. In a viscoelastic silicone rubber composition of the invention some of the crosslinks, the siloxane crosslinks, are permanent and others of the crosslinks, the boron-containing crosslinks, are temporary. Because a fraction of its crosslinks can come apart and then reform, a viscoelastic silicone rubber composition of the invention can relax stress in response to strain and thus adapt to new shapes. The composition has sufficient permanent crosslinks, however, to establish a permanent equilibrium shape to which the composition will eventually return when not subject to any imposed stress.Type: ApplicationFiled: July 21, 2014Publication date: December 11, 2014Applicant: UNIVERSITY OF VIRGINIA PATENT FOUNDATIONInventor: Louis A. Bloomfield
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Publication number: 20140066532Abstract: Polyurethane/polyisocyanurate foams having a NFPA 101 Class A rating (ASTM E-84) are produced from a foam-forming reaction mixture that includes: an organic polyisocyanate, an isocyanate-reactive composition that includes at least one polyether polyol or polyester polyol with a nominal hydroxyl functionality of at least 2.0, a blowing agent composition and at least one halogen-free flame retardant. The blowing agent composition includes: (1) up to 5% by weight, based on total weight of the foam-forming composition, of one or more hydrocarbons having an LEL less than 2% by volume in air; and/or (2) a hydrocarbon having an LEL greater than 2% by volume in air; and (3) up to 1% by weight, based on total weight of foam-forming composition, of water.Type: ApplicationFiled: September 6, 2012Publication date: March 6, 2014Applicant: Bayer MaterialScience LLCInventors: George G. Combs, Susan C. Pigott
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Publication number: 20130295371Abstract: Combinations of gelatinous elastomer containing one or more phase change materials, known as “phase change gel”, and polyurethane foam may be made by introducing at least partially cured phase change gel particles comprising plasticized triblock copolymer resin and/or diblock copolymer resin and one or more phase change materials, into a mixture of polyurethane foam-forming components including a polyol and an isocyanate. The phase change gel can be crosslinked to form a cured gelatinous gel, which is then reduced in size before introduction. After the foam-forming components polymerize to make polyurethane foam, the phase change gel particles are discrete visible particles dispersed throughout the foam. The polyurethane reaction is exothermic and can generate sufficient temperature to at least partially melt the styrene-portion of the triblock copolymer resin thereby extending the crosslinking.Type: ApplicationFiled: July 1, 2013Publication date: November 7, 2013Inventors: Bruce W. Peterson, Mark L. Crawford
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Patent number: 8569062Abstract: The present invention relates to a cryogel which contains a polyol selected from polyvinyl alcohol or galactomannan and a co-polymer of Formula I: The cryogel is formed by mixing the monomers of the co-polymer of Formula I at a temperature of less about 5 degrees C. with the polyol and a free radical initiator in an aqueous solution and polymerizing the solution to form the cryogel. The cryogel is used for culturing cells and can be decomposed by contact with a monosaccharide.Type: GrantFiled: August 8, 2011Date of Patent: October 29, 2013Assignee: Indian Institute of Technology KanpurInventor: Ashok Kumar
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Publication number: 20130197113Abstract: The present invention generally relates to polyurethane foam composition. In one embodiment, the present invention relates to polyurethane foam compositions that have increased and/or improved fire-retardant properties due to the inclusion of one or more liquid and/or solid fire-retardants. In another embodiment, the present invention relates to polyurethane foam compositions that have increased and/or improved fire-retardant properties due to the inclusion of one or more intumescent materials (e.g., expandable graphite (EG)). In still another embodiment, the present invention relates to polyurethane foam compositions that have increased and/or improved fire-retardant properties due to the inclusion of expandable graphite.Type: ApplicationFiled: March 13, 2013Publication date: August 1, 2013Inventor: Preferred Solutions, Inc.
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Publication number: 20120264838Abstract: Methods of forming an insulating material comprising combining a polysilazane, a cross-linking compound, and a gas-generating compound to form a reaction mixture, and curing the reaction mixture to form a modified polysilazane. The gas-generating compound may be water, an alcohol, an amine, or combinations thereof The cross-linking compound may be an isocyanate, an epoxy resin, or combinations thereof The insulating material may include a matrix comprising one of a reaction product of a polysilazane and an isocyanate and a reaction product of a polysilazane and an epoxy resin. The matrix also comprises a plurality of interconnected pores produced from one of reaction of the polysilazane and the isocyanate and from reaction of the polysilazane and the epoxy resin. A precursor formulation that comprises a polysilazane, a cross-linking compound, and a gas-generating compound is also disclosed.Type: ApplicationFiled: April 14, 2011Publication date: October 18, 2012Applicant: ALLIANT TECHSYSTEMS INC.Inventors: Robert S. Larson, Michael E. Fuller
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Patent number: 8124665Abstract: This invention relates to fire-resistant, flexible, molded, medium density polyurethane foams. These foams typically have a density of from 10 to 30 pcf. The foams are the reaction product of a) at least one polyester polyol, b) at least one highly branched polyether polyol, c) at least one chain extender, d) a polymethylene poly(phenyl isocyanate), an isocyanate group containing prepolymer based on a polymethylene poly(phenyl isocyanate), or mixtures thereof, e) a solid flame retardant and f) water. This invention also relates to a process for preparing these polyurethane foams in open molds.Type: GrantFiled: August 29, 2008Date of Patent: February 28, 2012Assignee: Bayer MaterialScience LLCInventors: James W. Rosthauser, Theodore S. Frick, Michael T. Wellman
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Publication number: 20120022176Abstract: The present invention generally relates to polyurethane foam composition. In one embodiment, the present invention relates to polyurethane foam compositions that have increased and/or improved fire-retardant properties due to the inclusion of one or more liquid and/or solid fire-retardants. In another embodiment, the present invention relates to polyurethane foam compositions that have increased and/or improved fire-retardant properties due to the inclusion of one or more intumescent materials (e.g., expandable graphite (EG)). In still another embodiment, the present invention relates to polyurethane foam compositions that have increased and/or improved fire-retardant properties due to the inclusion of expandable graphite.Type: ApplicationFiled: September 14, 2009Publication date: January 26, 2012Applicant: PREFERRED SOLUTIONS, INC.Inventors: John A. Stahl, Jonathon S. Stahl
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Patent number: 8097658Abstract: Fire-resistant, medium density molded polyurethane foams which may be removed from a mold in substantially shorter times than previously possible are produced by the process of the present invention. These reduced de-mold times are achieved by including a solid flame retardant composition in the polyurethane foam forming composition. This solid flame retardant composition includes a melamine coated ammonium polyphosphate and zinc borate.Type: GrantFiled: November 18, 2009Date of Patent: January 17, 2012Assignee: Bayer MaterialScience LLCInventor: James W. Rosthauser
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Publication number: 20110206835Abstract: A remedial railroad tie repair treatment capable of extending the useful life of a railroad tie. The remedial repair treatment comprises a mixture of a borate solution and a chemical tie plugging compound combined that, when applied to a wooden area of interest, will delay the decay thereof and facilitate penetration of the borate through the wood fibers. The remedial repair treatment may alternatively comprise sequential application of the borate solution and the plugging compound to the wooden area of interest.Type: ApplicationFiled: February 3, 2011Publication date: August 25, 2011Inventors: Doug Delmonico, Fabian Weber
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Patent number: 7674837Abstract: Gelled biopolymer based foams are disclosed. The gelled foams comprise a cross-linked biopolymer, preferably alginate; optionally, a foaming agent such as hydroxy propyl methyl cellulose; and a plasticizer, preferably glycerin sorbitol, or a mixture thereof, that forms the predominant portion of the gelled foam. The foams are soft and pliable and have high absorbency. They are used as wound dressing materials, controlled release delivery systems, cell culture, barrier media for preventing tissue adherence, and bioabsorbable implants. They also have various personal care applications, especially in oral hygiene, and can be used in food applications.Type: GrantFiled: September 2, 2004Date of Patent: March 9, 2010Assignee: FMC Biopolymer ASInventors: Olav Gaserod, Peder Oscar Andersen, Rolf Myrvold
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Publication number: 20070197672Abstract: Foamable one-part polyurethane compositions contain a high functionality quasi-prepolymer and a hydrated salt. The foamable compositions are capable of expanding to 1000% or more of their original volume to form a low density, stable foam. The compositions are particularly useful as foam-in-place thermal or sound insulation materials, especially in vehicle applications.Type: ApplicationFiled: February 13, 2007Publication date: August 23, 2007Inventors: Huzeir Lekovic, Ali El-Khatib
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Patent number: 6967223Abstract: A fiber-free molding composition containing: (a) a binder selected from the group consisting of an epoxide, a polyisocyanate, a furane-resin-free phenolic resin, and mixtures thereof; and (b) a filler mixture containing: (i) an inorganic high-temperature-resistant filler; and (ii) a heat-activatable swelling agent.Type: GrantFiled: February 17, 1999Date of Patent: November 22, 2005Assignee: Cognis Deutschland GmbH & Co. KGInventors: Robert Graf, Maria-Elisabeth Kaiser, Klaus Lehr, Wolfgang Six
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Patent number: 6783701Abstract: An electrically conductive foam component free from blooming and having a stable electrically conductive property. The electrically conductive foam component is produced by foaming an electrically conductive composition which comprises a base polymer and a borate compound represented by the following general formula (1): wherein R1 and R2, which may be the same or different, each represent a hydrogen atom, an alkyl group or an aryl group; M is an alkaline metal or an alkaline earth metal; and n is a positive number.Type: GrantFiled: December 4, 2002Date of Patent: August 31, 2004Assignee: Tokai Rubber Industries, Ltd.Inventors: Hitoshi Yoshikawa, Satoshi Suzuki, Kunio Ito, Akitoshi Nozawa
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Patent number: 6610756Abstract: An inorganic/organic composite foam that has a foam structure obtained from a combination of a phosphoric acid compound and/or a sulfuric acid compound with a blowing agent therefor, has reduced brittleness due to a cured material of an urethane prepolymer having NCO groups, and contains a powdery boric acid compound, and a process for producing the same. The foam is not only reduced in brittleness but also improved in foam strength after combustion due to the incorporation of the powdery boric acid compound while retaining inherent foam properties and inherent low quantities of heat of combustion and smoking in combustion. It is used in exterior wall panels, heat insulating materials, sound insulating materials, fireproof covering materials, lightweight aggregates, filling materials for cavities, and the like, which are required to have fire-proofing performance.Type: GrantFiled: December 30, 1999Date of Patent: August 26, 2003Assignee: Sanyo Checmical Industries, Ltd.Inventors: Tomokazu Shimizu, Tadaaki Yamazaki, Shinzo Kaida, Tsuyoshi Tomosada
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Patent number: 6294589Abstract: A polyurethane composition for fabricating antimicrobial based products such as polyurethane foam carpet backing materials and carpets having a polyurethane foam carpet backing material. The polyurethane composition includes a plurality of particles comprising an antimicrobial agent which are at least partially encapsulated by a plasticizer material before being dispersed within a polyurethane.Type: GrantFiled: May 12, 2000Date of Patent: September 25, 2001Assignee: Shaw Industries, Inc.Inventor: Von L. Moody
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Patent number: 6169124Abstract: In a process for producing self-releasing, compact or cellular moldings which comprise polyisocyanate polyaddition products and may contain reinforcing material by reacting a) organic and/or modified organic polyisocyanates with b) at least one compound containing at least two reactive hydrogen atoms and having a molecular weight of from 62 to 10,000 and, if desired, c) chain extenders and/or crosslinkers in the presence of d) internal mold release agents and in the presence of or absence of e) catalysts, f) blowing agents, g) reinforcing materials and h) auxiliaries in an open or closed mold, the internal mold release agents (d) used are diesters and/or monoesters of alkylsuccinic acids and/or diesters and/or monoesters of alkenylsuccinic acids.Type: GrantFiled: May 14, 1999Date of Patent: January 2, 2001Assignee: BASF AktiengesellschaftInventors: Peter Horn, Dietrich Scherzer, Karl H{umlaut over (a)}berle, Ulrich Treuling, Georg Partusch, G{umlaut over (u)}nter T{umlaut over (a)}nny, Axel Kistenmacher
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Patent number: 6140380Abstract: A silicate-based blowing agent and method for producing foamed polymers provides a blowing agent containing at least one metal silicate, boric acid or a salt thereof, a peroxy compound, a reaction initiator and, optionally, a desiccant. The blowing agent is prepared by mixing the ingredients at least one time and allowing the mixture to rest without mixing until a dry dilatent gel is formed. The blowing agent is useful for the production of foamed polymers, especially for the production of foamed rubber.Type: GrantFiled: March 26, 1999Date of Patent: October 31, 2000Inventors: Jeffrey L. Mauk, Kenneth G. Mauk
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Patent number: 6010565Abstract: This invention relates to a foamed material for fireproofing and/or insulating purposes, consisting of 30 to 90 parts by weight of a solution that contains 20 to 70 wt-% Al (H.sub.2 PO.sub.4).sub.3 and 30 to 80 wt-% water, 5 to 55 parts by weight of a mixture that contains 10 to 70 wt-% MgO, 0 to 70 wt-% mica, 0 to 70 wt-% aluminium hydroxide and 1 to 20 wt-% MnO.sub.2, as well as 1 to 30 parts by weight of a foaming agent that contains 3 to 33 wt-% H.sub.2 O.sub.2 and 67 to 97 wt-% water. In accordance with the invention, the term "insulating purposes" refers to the use of the inventive foamed material for heat and sound insulation.Type: GrantFiled: March 2, 1999Date of Patent: January 4, 2000Assignee: Metallgesellschaft AktiengesellschaftInventors: Wolfgang Bastian, Horst Kempf, Jorg Lind, Thomas Schmidt-Hansberg
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Patent number: 5973015Abstract: A flexible aerogel and process of fabrication. An aerogel solution is mixed with fibers in a mold and allowed to gel. The gel is then processed by supercritical extraction, or by air drying, to produce a flexible aerogel formed to the shape of the mold. The flexible aerogel has excellent thermal and acoustic properties, and can be utilized in numerous applications, such as for energy absorption, insulation (temperature and acoustic), to meet the contours of aircraft shapes, and where space is limited since an inch of aerogel is a 4-5 times better insulator than an inch of fiberglass. The flexible aerogel may be of an inorganic (silica) type or an organic (carbon) type, but containing fibers, such as glass or carbon fibers.Type: GrantFiled: February 2, 1998Date of Patent: October 26, 1999Assignee: The Regents of the University of CaliforniaInventors: Paul R. Coronado, John F. Poco
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Patent number: 5726214Abstract: Fluoropolymer having unstable end groups is used to form foamed fluoropolymer structures without added blowing agent.Type: GrantFiled: December 26, 1996Date of Patent: March 10, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Marlin Dwight Buckmaster, Stuart Karl Randa
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Patent number: 5639800Abstract: In the production of a flame resistant, halogen-free polyurethane/polyurea from a polyisocyanate and polyol, wherein to the mixture of polyisocyanate and polyol there is added an amine adduct of an acidic metal salt of the formulaA.sub.1-3 B.sub.0-12 P.sub.3-9 N.sub.4-12 M.sub.0-9 xH.sub.2 O(I),in whichA denotes at least one hydroxide or oxide of a metal selected from the group consisting of aluminum, magnesium, calcium and zinc,B denotes o-boric acid,P denotes an acid containing phosphorus,N denotes at least one of an amine or ammonia,M denotes an alkali metal hydroxide andx denotes an integer from 0 to 90.The products are especially flame resistant foams.Type: GrantFiled: March 28, 1996Date of Patent: June 17, 1997Assignee: Bayer AktiengesellschaftInventors: Wulf von Bonin, Hanns-Peter Muller, Gert Jabs
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Patent number: 5556891Abstract: The invention relates to prepolymers containing isocyanate groups which can be prepared by reactinga) organic isocyanates withb) polyetherols containing at least 2 hydroxyl groups per molecule and having molecular weights of greater than 400 and/or polyesterols containing at least 2 hydroxyl groups per molecule and having molecular weights of greater than 400,c) isocyanate-reactive compounds which are at least difunctional and have molecular weights of from 18 to 399, and, if desired,d) Lewis and/or Bronsted acidic compounds ande) conventional auxiliaries and additives, such as antioxidants, light stabilizers or fillers,wherein at least one aromatic aminopolyether alcohol of the formula ##STR1## where R is aryl, alkylaryl containing one or more C.sub.1 - to C.sub.4 -alkyl groups, haloaryl, nitroaryl or cyanoaryl,R' and R" are identical or different and are, independently of one another, hydrogen, alkyl, aryl, aralkyl, alkoxyalkyl, alkoxyaryl or aroxyaryl,x and y are independent of one another andx+y.gtoreq.Type: GrantFiled: November 1, 1995Date of Patent: September 17, 1996Assignee: BASF Schwarzheide GmbHInventors: Holger Seifert, Juergen Winkler, Regina Pretzsch, Robert O'Meara
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Patent number: 5539007Abstract: A method for catalyzing the blowing reaction and making polyurethane foams employing a catalyst composition consisting essentially of a hydroxy-functional imidazole of the following formula I ##STR1## where R.sup.1 is a C.sub.1 -C.sub.10 alkyl; R.sup.2 is hydrogen, methyl or ethyl and R.sup.3 is hydrogen or a C.sub.1 -C.sub.20 organic group optionally having an ether functionality, provided that when R.sup.1 is methyl, R.sup.2 and R.sup.3 are not both hydrogen or a hydrogen and a methyl, in combination with a boron compound of the formulaR.sub.n B(OH).sub.3-nwhere n=0 or 1, and R=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl, or C.sub.6 -C.sub.10 aryl.Type: GrantFiled: June 7, 1995Date of Patent: July 23, 1996Assignee: Air Products and Chemicals, Inc.Inventors: Mark L. Listemann, Lisa A. Mercando, Ann C. L. Savoca
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Patent number: 5391583Abstract: Flame-retardant poly (polyisocyanate-organic phosphorus) products are produced by mixing and reacting an organic phosphorus containing compound and a polyisocyanate compound in the presence of a polyisocyante catalyst. No other blowing agent is necessary.The flame-retardant polyurethane foam products may be used for thermal and sound-insulation, for cushioning, for molding useful objects and as a cavity filler.Type: GrantFiled: October 28, 1993Date of Patent: February 21, 1995Inventor: David H. Blount
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Patent number: 5373028Abstract: In a method of preparing a poly-urethane and/or -urea foam from a formulation including (a) a polyisocyanate, (b) an isocyanate-reactive component, and (c) a visible emissions producing component, wherein (a), (b) and (e) are reacted under reaction conditions sufficient to form a poly-urethane and/or -urea foam and the foam is then cooled, whereby visible emissions are emitted during cooling, an improvement comprising including in the formulation a visible emissions reducing agent, such that the amount of the visible emissions is reduced as compared with the amount emitted by a foam prepared from a formulation which does not contain the visible emissions reducing agent but which is otherwise substantially similar. Foams prepared therefrom exhibit reduction in visible emissions during the cure period, which is particularly evident when the foams are mechanically cooled. They also exhibit generally good physical properties.Type: GrantFiled: October 15, 1993Date of Patent: December 13, 1994Assignee: The Dow Chemical CompanyInventors: Carl D. McAfee, Richard G. Skorpenske, Don H. Ridgway, Stephen K. Lewis, Eugene P. Wiltz, Jr.
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Patent number: 5356942Abstract: An amine-boron composition for catalyzing the urethane reaction, particularly in preparing a polyurethane foam, consisting essentially of the addition product of a tertiary amine and a boron compound of the formulaR.sub.n B(OH).sub.3-nwheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.Preferred catalysts are prepared by mixing triethylenediamine or 3-quinuclidinol with boric acid.Type: GrantFiled: June 10, 1992Date of Patent: October 18, 1994Assignee: Air Products and Chemicals, Inc.Inventors: Ann C. L. Savoca, Michael Louie, Mark L. Listemann
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Patent number: 5268393Abstract: Flame-retardant polyurethane foam products are produced by mixing and reacting an organic phosphorus containing compound which will react with a polyisocyanate compound and produce a gaseous compound and a polyisocyanate compound in the presence of a polyurethane catalyst. No other blowing agent is necessary.The flame-retardant polyurethane foam products may be used for thermal and sound-insulation, for cushioning, for molding useful objects and as a cavity filler.Type: GrantFiled: July 17, 1992Date of Patent: December 7, 1993Inventor: David H. Blount
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Patent number: 5177046Abstract: An amine-boron composition for catalyzing the urethane reaction, particularly in preparing a polyurethane foam, consisting essentially of the addition product of a tertiary amine and a boron compound of the formula R.sub.n B(OH).sub.3-n wheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.Preferred catalysts are prepared by mixing triethylenediamine with boric acid.Type: GrantFiled: November 18, 1991Date of Patent: January 5, 1993Assignee: Air Products and Chemicals, Inc.Inventors: Ann C. L. Savoca, Michael Louie
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Patent number: 5173515Abstract: New particularly effective fire retardent elements based on foams and expandable graphite are characterized in that they additionally contain one or more components from the group consisting of phosphate-containing polyols, borates and amine salts.Type: GrantFiled: May 10, 1990Date of Patent: December 22, 1992Assignee: Bayer AktiengesellschaftInventors: Wulf von Bonin, Dietmar Schapel
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Patent number: 5166223Abstract: An amine-boron composition for catalyzing the urethane reaction, particularly in preparing a polyurethane foam, consisting essentially of the addition product of a tertiary amine and a boron compound of the formulaR.sub.n B(OH).sub.3-nwheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.Preferred catalysts are prepared by mixing triethylenediamine or 3-quinuclidonol with boric acid.Type: GrantFiled: February 20, 1992Date of Patent: November 24, 1992Assignee: Air Products and Chemicals, Inc.Inventors: Ann C. L. Savoca, Michael Louie, Mark L. Listemann
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Patent number: 5162379Abstract: An amine-boron composition for catalyzing the urethane reaction, particularly in preparing a polyurethane foam, consisting essentially of the addition product of a tertiary amine and a boron compound of the formula R.sub.n B(OH).sub.3-n wheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.Preferred catalysts are prepard by mixing triethylenediamine with boric acid.Type: GrantFiled: January 31, 1992Date of Patent: November 10, 1992Assignee: Air Products and Chemicals, Inc.Inventors: Ann C. L. Savoca, Michael Louie
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Patent number: 5118721Abstract: A process for preparing a dispersion of a filler e.g., melamine, urea or borax in a dispersion or graft polymer polyol is provided. The process comprises (1) dispersing the filler in a suitable basestock (e.g., a polyether polyol) and (2) thereafter using this as the basestock for preparing the dispersion or graft polymer polyol.The polymer which is prepared in dispersed form in the second step may be for example (1) the reaction product of a polyamine, hydrazine or hydrazide and an isocyanate (PHD polymer) or (2) the reaction product of an olamine and an isocyanate (PIPA polymer). Alternatively styrene and acrylonitrile can be graft polymerised in the basestock in step (2). The new dispersion or graft polymer polyols containing dispersed filler are useful in the manufacture of fire resistant polyurethane foam for e.g., furniture applications.Type: GrantFiled: August 23, 1989Date of Patent: June 2, 1992Assignee: Polyol International, B.V.Inventors: Jose Godoy, Jitka Jenc, Werner A. Lidy
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Patent number: 5110834Abstract: Chlorofluorocarbon-free urethane-containing, soft-elastic moldings having a cellular core, a compacted peripheral zone and an essentially pore-free smooth surface are produced by reactinga) an organic and/or modified organic polyisocyanate withb) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and, if desired,c) a low-molecular-weight chain extender and/or crosslinking agent,in the presence ofd) a blowing agent,e) a catalyst,f) a crystalline, microporous molecular sieve having a cavity diameter of less than 1.3 nm and comprising metal oxides or metal phosphates, and, if desired, further additives andg) assistants,in a closed mold with compaction, expediently by RIM.Type: GrantFiled: October 3, 1991Date of Patent: May 5, 1992Assignee: BASF AktiengesellschaftInventors: Peter Horn, Wolfgang Hoelderich, Rudolf Taddey, Dieter Tintelnot
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Patent number: 5096623Abstract: A flame retardant composition and process which is particular useful for rebounded foam products. The composition of the present invention includes a solid component of magnesium sulfate, boric acid, decabromodiphenylethylene oxide (DECA) and antimony trioxide and a liquid component of halogenated phosphorous. The present invention is based upon the discovery of the synergism between boric acid and DECA. The process, according to the present invention, includes the steps of forming a dispersion of the solid portion of the flame retardant composition along with a small amount of water based adhesive to a mass of foam chips. The treated chips are then dried to permit handling and storage. The dried foam chips subsequently are mixed with a conventional urethane prepolymer binder and the liquid halogenated phosphorous flame retardant compound. After mixing the foam mass is transferred to molds and steamed to allow the binder to cure.Type: GrantFiled: August 12, 1991Date of Patent: March 17, 1992Assignee: Triad-Fabco, Inc.Inventors: Robert W. Ward, Rogelio Tornero, Freeman J. Henderson
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Patent number: 5086081Abstract: An amine-boron composition for catalyzing the urethane reaction, particularly in preparing a polyurethane foam, consisting essentially of the addition product of a tertiary amine and a boron compound of the formula R.sub.n B(OH).sub.3-n wheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.Preferred catalysts are prepared by mixing triethylenediamine with boric acid.Type: GrantFiled: September 20, 1991Date of Patent: February 4, 1992Assignee: Air Products and Chemicals, Inc.Inventors: Ann C. L. Savoca, Michael Louie
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Patent number: 5075413Abstract: A fire resistant resin for use as a binder in reinforced plastics and a resultant reinforced plastic includes the reaction product of (a) at least one resorcinol component selected from the group consisting of resorcinol and resorcinol formaldehyde novolak resin, and (b) a phenolic resole resin. The reaction may be achieved in the presence of an alkaline catalyst.A method of making a fire resistant resin binder for reinforced plastics and the method of making such reinforced plastics including, (a) at least one resorcinol component selected from the group consisting of resorcinol and resorcinol formaldehyde novolak resin, and (b) a phenolic resole resin. The reaction may be achieved in the presence of an alkaline catalyst.Type: GrantFiled: September 4, 1990Date of Patent: December 24, 1991Assignee: Indspec Chemical CorporationInventor: Theodore H. Dailey, Jr.