Ingredient Contains A Sulfur Atom Patents (Class 521/120)
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Patent number: 11319399Abstract: A device for preparing a liquid polymer blend is proposed having a storage container for the liquid polymer blend; a degassing device, which is arranged downstream of the storage container, for the liquid polymer; a gassing device, which is arranged downstream of the degassing device, for adding an additive gas to the liquid polymer blend; a homogenization unit, which is arranged downstream of the gassing device, for the polymer blend to which the additive gas was added; and an output line, which is connected to the homogenization unit, for the homogenized polymer blend.Type: GrantFiled: October 26, 2016Date of Patent: May 3, 2022Assignee: WEBASTO SEInventors: Martin Sacher, Markus Rauch, Jan Woköck, Alexander Isbach, Karl-Heinz Bartl, Martin Seebass
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Patent number: 10570245Abstract: This invention discloses the use of sulfite salts as catalysts to make polyurethane polymers. In particular, this invention discloses the use of metal salts such as alkali metal salts as well as alkyl ammonium salts such as tetralkyl ammonium salts as catalysts to make polyurethane polymers. The sulfite salts are useful to make a wide variety of polyurethane polymers and polyurethane foam polymer products such as flexible polyurethane foam polymers, rigid foam polyurethane polymers, semi-rigid polyurethane polymer, microcellular polyurethane polymer, and spray foam polyurethane polymer as well as any polymeric material that requires the assistance of catalysts to promote the formation of urethane and urea bonds such as those found in polyurethane emusions for paints, coatings, protective coatings, lacquer, etc as well as other polyurethane or polyurethane containing materials such as thermoplastic polymers, thermoplastic polyurethane polymers, elastomers, adhesives, sealants, etc.Type: GrantFiled: April 13, 2016Date of Patent: February 25, 2020Assignee: Evonik Operations GmbHInventor: Juan Jesus Burdeniuc
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Patent number: 10472459Abstract: This invention discloses the use of sulfite salts as catalysts to make polyurethane polymers. In particular, this invention discloses the use of metal salts such as alkali metal salts as well as alkyl ammonium salts such as tetralkyl ammonium salts as catalysts to make polyurethane polymers. The sulfite salts are useful to make a wide variety of polyurethane polymers and polyurethane foam polymer products such as flexible polyurethane foam polymers, rigid foam polyurethane polymers, semi-rigid polyurethane polymer, microcellular polyurethane polymer, and spray foam polyurethane polymer as well as any polymeric material that requires the assistance of catalysts to promote the formation of urethane and urea bonds such as those found in polyurethane emusions for paints, coatings, protective coatings, lacquer, etc as well as other polyurethane or polyurethane containing materials such as thermoplastic polymers, thermoplastic polyurethane polymers, elastomers, adhesives, sealants, etc.Type: GrantFiled: October 13, 2015Date of Patent: November 12, 2019Assignee: Evonik Degussa GmbHInventor: Juan Jesus Burdeniuc
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Patent number: 10004646Abstract: Disclosed are methods for using open-celled polymeric foam wound dressings made from high internal phase emulsions (HIPEs). The wound dressings have a high capillary pressure and may reduce or obviate the need for treatments like negative pressure wound treatment (NPWT). Also disclosed are structures for HIPE foam wound dressings. The HIPE foam wound dressings typically include at least two layers of HIPE foam with different, but homogeneous, average cell sizes. The average cell sizes form a cell size gradient, with cell size typically decreasing from the front or face layer of foam toward the back layer of foam. The back layer of foam may be a collapsed layer, while the front layer or layers may be expanded. Compared with HIPE foams for other absorbent applications, the wound dressing foams may be higher in hydratable salts and higher in initial moisture levels.Type: GrantFiled: August 19, 2014Date of Patent: June 26, 2018Assignee: Dristi, LLCInventor: Ranjit Chatterjee
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Publication number: 20150051305Abstract: The present disclosure relates to a bone cement composed of a hydrophilic component and a hydrophobic component, wherein biodegradable material is deposited in pores of the bone cement via the hydrophilic component.Type: ApplicationFiled: October 30, 2014Publication date: February 19, 2015Inventors: Christoph Sattig, Elvira Dingeldein
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Publication number: 20130295371Abstract: Combinations of gelatinous elastomer containing one or more phase change materials, known as “phase change gel”, and polyurethane foam may be made by introducing at least partially cured phase change gel particles comprising plasticized triblock copolymer resin and/or diblock copolymer resin and one or more phase change materials, into a mixture of polyurethane foam-forming components including a polyol and an isocyanate. The phase change gel can be crosslinked to form a cured gelatinous gel, which is then reduced in size before introduction. After the foam-forming components polymerize to make polyurethane foam, the phase change gel particles are discrete visible particles dispersed throughout the foam. The polyurethane reaction is exothermic and can generate sufficient temperature to at least partially melt the styrene-portion of the triblock copolymer resin thereby extending the crosslinking.Type: ApplicationFiled: July 1, 2013Publication date: November 7, 2013Inventors: Bruce W. Peterson, Mark L. Crawford
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Patent number: 8476329Abstract: A bioresin composition is used to form a rigid polyurethane article that includes a first and a second biopolyol and is substantially free of aprotic solvents that chemically decompose in the presence of water. The first biopolyol includes a natural oil component. The second biopolyol includes the reaction product of a natural carbohydrate and an alkylene oxide. The rigid polyurethane foam article includes the reaction product of the bioresin composition and an isocyanate which are reacted in the presence of a chemical blowing agent.Type: GrantFiled: June 9, 2010Date of Patent: July 2, 2013Assignee: BASF SEInventors: Christopher M. Tanguay, Patrick J. Watters, John P. Erickson, Eric W. Banks
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Patent number: 8138235Abstract: A polyurethane foam is obtained by reacting, foaming, and curing raw material that includes a polyol, a polyisocyanate, a blowing agent, a catalyst, and an inorganic compound hydrate. The raw material includes, as the polyol, a polymeric polyol obtained by graft polymerization of a vinyl monomer onto a polyether polyol and a polyether polyol obtained by addition polymerization of an alkylene oxide to a polyhydric alcohol and having a mass average molecular weight of 400 to 1,000. The blending quantity of the inorganic compound hydrate is 10 to 80 parts by mass per 100 parts by mass of the polyol. Preferably, the raw material further includes, as the polyol, a polyether polyol obtained by addition polymerization of an alkylene oxide to a polyhydric alcohol and has a molecular weight of 2,000 to 4,000.Type: GrantFiled: April 4, 2008Date of Patent: March 20, 2012Assignee: INOAC CorporationInventors: Tadashi Yano, Satoshi Iwase
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Patent number: 8076385Abstract: A flame retardant aqueous liquid composition containing water, guanidine sulfamate, a citric acid compound including a metal salt of citric acid, and a water soluble polymer. A flame retardant polyurethane foam is produced by a process including the steps of providing a mixture of the above flame retardant aqueous liquid composition with a polyol and an isocyanate, and reacting the mixture in the presence of a catalyst.Type: GrantFiled: December 15, 2009Date of Patent: December 13, 2011Assignee: Nankyo Efnica Co., Ltd.Inventor: Chiaki Ohama
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Publication number: 20110190408Abstract: A process for producing a polyurethane product comprises steps of (a) supplying at least one polyisocyanate (b) supplying at least one polyol composition comprising at least about 5 weight percent based on total weight of polyols of at least one natural oil based polyol (b1) having a hydroxyl number of at most about 300 and a viscosity below about 10000 mPa·os; and (c) exposing the polyisocyanate and the polyol composition to reaction conditions such that urethane bonds are formed, wherein reaction conditions include the presence of at least one bismuth catalyst. Use of bismuth catalysts is particularly applicable to preparation of open celled, flexible polyurethane foams using polyols made from renewable resources, optionally with other polyols. The invention includes foams made by the process, including viscoelastic foams, preferably having a velvet feel.Type: ApplicationFiled: August 26, 2008Publication date: August 4, 2011Applicant: Dow Global Technologies Inc.Inventors: Francois M. Casati, Jean-Marie Sonney, Herve Wuilay
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Publication number: 20100286296Abstract: The present invention relates to an anti-termite styrofoam heat insulation material which is safe for use with humans and animals and method for making the same. The material contains the insecticide Thiamethoxam.Type: ApplicationFiled: October 14, 2008Publication date: November 11, 2010Applicant: SYNGENTA CROP PROTECTION, INC.Inventors: Shuichi Tamai, Minoru Yonehara, Takatoshi Karino
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Publication number: 20100159232Abstract: A composition for a rigid polyurethane foam with reduced cell sizes contains a polyol, water, a catalyst, a blowing agent; and an ionic liquid. The rigid polyurethane foam is produced by adding an ionic liquid as an eco-friendly additive to a polyol composition so as to improve insulation efficiency thereof.Type: ApplicationFiled: December 24, 2009Publication date: June 24, 2010Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Kwang Hee KIM, Myung Dong CHO, Sang Ho PARK, Sung Woo HWANG
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Patent number: 7737192Abstract: A flexible polyurethane foam is produced by blending a polyurethane raw material containing a polyol, a polyisocyanate, a blowing agent, and a catalyst with an inorganic compound hydrate having a specific gravity of 1.5 to 4.0 and reacting the above polyurethane raw material to effect foaming and curing. The inorganic compound hydrate is preferably an iron sulfate hydrate, a calcium sulfate hydrate, or a magnesium sulfate hydrate. The above inorganic compound hydrate preferably has decomposition temperature of from 100 to 170° C. Then, an increase in exothermic temperature owing to the above foaming and curing is diminished by evaporation of water formed through decomposition of the above inorganic compound hydrate.Type: GrantFiled: July 28, 2005Date of Patent: June 15, 2010Assignee: INOAC CorporationInventor: Tadashi Yano
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Publication number: 20090099273Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to open-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a surfactant component which comprises a non-silicone surfactant and is substantially absent of a silicone surfactant, and a tertiary amine catalyst.Type: ApplicationFiled: September 30, 2008Publication date: April 16, 2009Inventors: David J. Williams, Michael Van Der Puy
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Patent number: 6906110Abstract: In a process for producing polyurethanes by reacting at least one polyisocyanate with at least one compound containing at least two hydrogen atoms which are reactive toward isocyanate groups, the compound having at least two active hydrogen atoms which is used is at least one polyether alcohol prepared by addition of alkylene oxides onto H-functional initiator substances by means of multimetal cyanide catalysis and the reaction is carried out in the presence of at least one metal salt.Type: GrantFiled: November 4, 2000Date of Patent: June 14, 2005Assignee: BASF AktiengesellschaftInventors: Reinhard Lorenz, Stephan Bauer, Dieter Junge, Eva Baum, Kathrin Harre, Jörg Erbes, Thomas Ostrowski, Georg Heinrich Grosch
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Patent number: 6894082Abstract: This invention relates to latent foamable compositions for use in or as adhesives, sealants and/or coatings. The compositions include a curable component or a thermoplastic component, together with a latent foaming agent. In curable versions of the inventive compositions, a cure initiator or catalyst may also be included.Type: GrantFiled: September 16, 2002Date of Patent: May 17, 2005Assignee: Henkel CorporationInventors: Karen R. Brantl, Philp T. Klemarczyk
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Patent number: 6660780Abstract: A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase.Type: GrantFiled: November 27, 2002Date of Patent: December 9, 2003Assignee: The United States of America as represented by the Secretary of the NavyInventors: Michael A. Markowitz, Paul E. Schoen, Bruce P. Gaber, Banahalli R. Ratna, Paul R. Kust, David C. Turner, Douglas S. Clark, Jonathan S. Dordick
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Patent number: 6610756Abstract: An inorganic/organic composite foam that has a foam structure obtained from a combination of a phosphoric acid compound and/or a sulfuric acid compound with a blowing agent therefor, has reduced brittleness due to a cured material of an urethane prepolymer having NCO groups, and contains a powdery boric acid compound, and a process for producing the same. The foam is not only reduced in brittleness but also improved in foam strength after combustion due to the incorporation of the powdery boric acid compound while retaining inherent foam properties and inherent low quantities of heat of combustion and smoking in combustion. It is used in exterior wall panels, heat insulating materials, sound insulating materials, fireproof covering materials, lightweight aggregates, filling materials for cavities, and the like, which are required to have fire-proofing performance.Type: GrantFiled: December 30, 1999Date of Patent: August 26, 2003Assignee: Sanyo Checmical Industries, Ltd.Inventors: Tomokazu Shimizu, Tadaaki Yamazaki, Shinzo Kaida, Tsuyoshi Tomosada
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Patent number: 6583191Abstract: A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase.Type: GrantFiled: September 19, 2001Date of Patent: June 24, 2003Inventors: Michael A. Markowitz, Paul E. Schoen, Bruce P. Gaber, Banahalli R. Ratna, Paul R. Kust, David C. Turner, Douglas S. Clark, Jonathan S. Dordick
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Publication number: 20020065334Abstract: A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase.Type: ApplicationFiled: September 19, 2001Publication date: May 30, 2002Inventors: Michael A. Markowitz, Paul E. Schoen, Bruce P. Gaber, Banahalli R. Ratna, Paul R. Kust, David C. Turner, Douglas S. Clark, Jonathan S. Dordick
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Publication number: 20010041752Abstract: The object is to obtain a foam, an interior material, and a molded article destined for an interior automotive or other vehicular material which can inhibit the formation of crystals in the fogging test.Type: ApplicationFiled: November 10, 1998Publication date: November 15, 2001Inventors: AKIHIRO KATAOKA, SHUNJI OKUBO, TOSHIHARU NAKAE, FUSAYOSHI AKIMARU
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Patent number: 6310110Abstract: A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase.Type: GrantFiled: July 30, 1999Date of Patent: October 30, 2001Inventors: Michael A. Markowitz, Paul E. Schoen, Bruce P. Gaber, Banahalli R. Ratna, Paul R. Kust, David C. Turner, Douglas S. Clark, Jonathan S. Dordick
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Patent number: 6211259Abstract: The present invention includes new compositions for making polyurethane and polyurethane foam compositions. These compositions comprise the reaction product of an isocyanate A-Side and a B-Side comprising: (i) a polyol having a molecular weight of about 1000 g/mol or more, and having an average functionality of 2.0 or greater; (ii) a polyol having a Tg of about −80° C. or less, and having a molecular weight of about 1000 g/mol or more, and having an average functionality of 2.0 or greater; and(iii) a polyhydric alcohol having a molecular weight of about 90 g/mol or more, and having an average functionality of 3.0 or more. In the case of polyurethane foam compositions, the system also comprises water. The invention also includes processes for making the polyurethane and polyurethane foam compositions, as well as methods of adhering the same to cosmetic layers comprising thermoplastic, acrylic, and gel coat materials. The invention also includes articles made from these reinforced cosmetic layers.Type: GrantFiled: February 1, 1999Date of Patent: April 3, 2001Assignee: Aristech Acrylics LLCInventors: Keith A. Borden, Robert E. Anderson, Jr., Kathleen M. Yusko, Randall S. Reynolds
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Patent number: 6169124Abstract: In a process for producing self-releasing, compact or cellular moldings which comprise polyisocyanate polyaddition products and may contain reinforcing material by reacting a) organic and/or modified organic polyisocyanates with b) at least one compound containing at least two reactive hydrogen atoms and having a molecular weight of from 62 to 10,000 and, if desired, c) chain extenders and/or crosslinkers in the presence of d) internal mold release agents and in the presence of or absence of e) catalysts, f) blowing agents, g) reinforcing materials and h) auxiliaries in an open or closed mold, the internal mold release agents (d) used are diesters and/or monoesters of alkylsuccinic acids and/or diesters and/or monoesters of alkenylsuccinic acids.Type: GrantFiled: May 14, 1999Date of Patent: January 2, 2001Assignee: BASF AktiengesellschaftInventors: Peter Horn, Dietrich Scherzer, Karl H{umlaut over (a)}berle, Ulrich Treuling, Georg Partusch, G{umlaut over (u)}nter T{umlaut over (a)}nny, Axel Kistenmacher
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Patent number: 6136870Abstract: Modified or filled rebond polyurethane foam structures having desired plushness and compression without adversely affected tensile strength at a given density as compared to unfilled rebond polyurethane foams are formed from an admixture of shredded or chopped polyurethane foam particles and a finely divided inorganic mineral filler, such as barium sulfate or calcium carbonate or mixtures of these and like mineral fillers, that is further mixed with a substantially non-foam forming liquid prepolymer binder that is free of surfactants in foam-stabilizing amounts. A portion of the polyurethane foam particles, from about 10 to about 60 parts by weight based upon 100 parts by weight, is replaced with filler. For each 100 parts by weight of the combined foam particles and filler, about 10 to about 30 parts by weight of prepolymer is added. After the wetted admixture is compressed to the required density, the prepolymer binder is cured with heat and/or steam.Type: GrantFiled: February 2, 1999Date of Patent: October 24, 2000Assignee: Foamex L.P.Inventors: Rocco P. Triolo, Richard A. Rossow, David J. Kelly
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Patent number: 5880165Abstract: Modified or filled rebond polyurethane foam structures having desired plushness and compression without adversely affected tensile strength at a given density as compared to unfilled rebond polyurethane foams are formed from an admixture of shredded or chopped polyurethane foam particles and a finely divided inorganic mineral filler, such as barium sulfate or calcium carbonate or mixtures of these and like mineral fillers, that is further mixed with a substantially non-foam forming liquid prepolymer binder. A portion of the polyurethane foam particles, from about 10 to about 60 parts by weight based upon 100 parts by weight, is replaced with filler. For each 100 parts by weight of the combined foam particles and filler, about 10 to about 30 parts by weight of prepolymer is added. After the wetted admixture is compressed to the required density, the prepolymer binder is cured with heat and/or steam.Type: GrantFiled: May 1, 1997Date of Patent: March 9, 1999Assignee: Foamex L.P.Inventors: Rocco P. Triolo, Richard A. Rossow, David J. Kelly
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Patent number: 5719200Abstract: The flame-resistant polyurea foam of the invention contains calcium sulfate dihydrate as filler and ammonium polyphosphate as flame retardant. Its bulk density is from 25 to 250 kg/m.sup.3 and the number of open cells is above 80% of all its cells. The polyurea has been formed from a reaction of prepolymers of diphenylmethane 4,4'-diisocyanate with water.The polyurea foam of the invention can be used as a block foam or on-site foam for sound and/or heat insulation.Type: GrantFiled: July 1, 1996Date of Patent: February 17, 1998Assignee: Hoechst AktiengesellschaftInventors: Horst Staendeke, Reinhold Lagoda
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Patent number: 5710190Abstract: The invention provides a biodegradable thermoplastic composition made of soy protein, a plasticizing agent, a foaming agent, and water, that can be molded into biodegradable articles that have a foamed structure and are water-resistant with a high level of physical strength and/or thermal insulating properties.Type: GrantFiled: June 7, 1995Date of Patent: January 20, 1998Assignee: Iowa State University Research Foundation, Inc.Inventors: Jay-lin Jane, Su She Zhang
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Patent number: 5605721Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH .ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.Type: GrantFiled: June 7, 1995Date of Patent: February 25, 1997Inventor: Joseph W. Di Geronimo
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Patent number: 5561170Abstract: A process for the preparation of expandable thermoplastic polymers by post-impregnation with a blowing agent in aqueous suspension in the presence of a mixture of magnesium pyrophosphate and a sulfonate group-containing extender as suspension stabilizer, in a reactor comprisesa) preparing the magnesium pyrophosphate in the same reactor at below 50.degree. C. by adding a solid magnesium salt in an amount corresponding to an at least 3% stoichiometric excess, based on pyrophosphate, to an aqueous solution of the pyrophosphate,b) heating the suspension medium to from 70.degree. to 140.degree. C. andc) adding the blowing agent in this temperature range.Type: GrantFiled: April 20, 1995Date of Patent: October 1, 1996Assignee: BASF AktiengesellschaftInventors: Michael Witt, Klaus Hahn, Maria Lorenz
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Patent number: 5514722Abstract: The present invention is directed to an underlayment composition for an artificial playing surface comprised of a butadiene rubber, such as polybutadiene or styrene-butadiene that is commercially available as recycled polycord tires that have been granulized. An inorganic-base moisture-retaining agent such as vermiculite or perlite is also included in the composition in addition to a binder comprised of a mixture of isocyanate polyurethane and an inorganic acid. The present invention also provides a method of making the present composition. The method comprises the steps of mixing thoroughly granulized particles of butadiene rubber in a mixing container, mixing an inorganic-based moisture-retaining component with the butadiene rubber, mixing an acid having a pH.ltoreq.3 with the butadiene rubber and the inorganic-based moisture-retaining component, and mixing an isocyanate polyurethane with the butadiene rubber, the inorganic-based moisture-retaining component and the acid.Type: GrantFiled: August 12, 1994Date of Patent: May 7, 1996Assignee: Presidential Sports Systems, Inc.Inventor: Joseph W. Di Geronimo
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Patent number: 5403655Abstract: Toughened thermosetting resins are disclosed comprising a thermosetting resin having a Tg of at least 150.degree. C., preferably 180.degree. C., and having dispersed substantially uniformly therethrough microspheres of a thermoplastic resin having a Tg of at least 150.degree. C., preferably 180.degree. C. It is preferred to use thermoplastic resins with functional groups on the surface thereof capable of bonding to an available group on the thermosetting resin. High performance structural composites made from such toughened resins are disclosed as well as the process of making such composites.Type: GrantFiled: October 5, 1994Date of Patent: April 4, 1995Assignee: Southwest Research InstituteInventors: Marvin L. Deviney, Joel J. Kampa
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Patent number: 5401785Abstract: Foamed polyurethanes substantially free from non-uniform density distribution are obtained by dispersing an inert gas with mechanical stirring into a foamed polyurethane-forming composition containing substantially no blowing agent and comprising (1) an organic polyisocyanate component, (2) a polyol component comprising a high molecular weight polyol (A1) and a low molecular weight polyol (A2), (3) a dehydrating agent (B) and optionally organic microballoons, and curing the resulting composition containing therein the inert gas substantially homogeneously distributed. Foamed polyurethanes thus obtained are lightweight and of reduced warpage after processing and are suitable for model materials.Type: GrantFiled: December 27, 1993Date of Patent: March 28, 1995Assignee: Sanyo Chemical Industries, Ltd.Inventors: Yasushi Kumagai, Sukeo Ban, Yuichi Sasatani
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Patent number: 5373028Abstract: In a method of preparing a poly-urethane and/or -urea foam from a formulation including (a) a polyisocyanate, (b) an isocyanate-reactive component, and (c) a visible emissions producing component, wherein (a), (b) and (e) are reacted under reaction conditions sufficient to form a poly-urethane and/or -urea foam and the foam is then cooled, whereby visible emissions are emitted during cooling, an improvement comprising including in the formulation a visible emissions reducing agent, such that the amount of the visible emissions is reduced as compared with the amount emitted by a foam prepared from a formulation which does not contain the visible emissions reducing agent but which is otherwise substantially similar. Foams prepared therefrom exhibit reduction in visible emissions during the cure period, which is particularly evident when the foams are mechanically cooled. They also exhibit generally good physical properties.Type: GrantFiled: October 15, 1993Date of Patent: December 13, 1994Assignee: The Dow Chemical CompanyInventors: Carl D. McAfee, Richard G. Skorpenske, Don H. Ridgway, Stephen K. Lewis, Eugene P. Wiltz, Jr.
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Patent number: 5317033Abstract: The present invention concerns a process for producing a synthetic resin foam composed of cells having substantially two sizes, one of the sizes being at most 0.3 mm and the other size as being 0.4 to 1 mm, comprising the steps of:forming a mixture of one or more of a water-absorbent high molecular compound, a cell-controlling agent, a synthetic resin, and water; melting the mixture with heating; incorporating a volatile type foaming agent into the mixture under pressure; and extruding the mixture into a lower pressure space to form a foam.Type: GrantFiled: January 14, 1993Date of Patent: May 31, 1994Inventors: Shigeru Motani, Tadayuki Saito, Takahiro Hayashi
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Patent number: 5312845Abstract: In an active hydrogen-containing B-side composition for reaction with a polyisocyanate-containing A-side composition to make a polyurethane or polyurethaneurea elastomer by reaction injection molding, the improvement which comprises a mold release composition consisting essentially of (1) the reaction product of a mixture of a carboxylic acid, a tertiary amine, and a reactive epoxide and (2) a carboxy functional siloxane.Type: GrantFiled: December 16, 1992Date of Patent: May 17, 1994Assignee: Air Products and Chemicals, Inc.Inventor: John E. Dewhurst
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Patent number: 5256703Abstract: Particles of abrasives such as Garnet, Staurolite or Wollastonite bound to polymer are used as propellant particles to remove undesired materials from surfaces such as floors, walls, ceilings, machinery etc. For example, soil, paint, oil, grease etc. can be thereby removed.Type: GrantFiled: September 12, 1991Date of Patent: October 26, 1993Assignee: Sponge Jet Inc.Inventors: Paul F. Hermann, William R. Lynn
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Patent number: 5234964Abstract: Microcellular polyurethane elastomers having nonpeelable skin surfaces having densities ranging from 0.1-1.1 gm/cm.sup.3 can be made from conventionally employed reactants using carbon dioxide gas as the sole source of blowing agent resulting from the H.sub.2 O/-NCO reaction when carried out in an admixture with nonhydratable particulate inorganic salts.Type: GrantFiled: January 28, 1992Date of Patent: August 10, 1993Assignee: Imperial Chemical Industries PLCInventors: Nai W. Lin, Roland G. Jaber, Brian Fogg
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Patent number: 5173559Abstract: The present invention relates to reactive systems comprising(a) a storable mixture of (i) a polyisocyanate component comprising at least one organic polyisocyanate, and (ii) an epoxide component stabilized by heating in the presence of an alkylating agent, wherein said heating is optionally carried out in the further presence of part of the polyisocyanate component (i),(b) an isocyanate-reactive component containing at least two isocyanate-reactive groups in a quantity such that 0.1 to 0.9 isocyanate-reactive groups are present for every isocyanate group in component (a), wherein at least 10% by weight of component (b) comprises compounds having a molecular weight greater than about 2000,(c) optionally, tertiary amines in a quantity such that the total storable mixture contains at least 0.005 mole of tertiary amine nitrogen atoms for each 100 g of the total amount of the storable mixture, and, optionally,(d) other auxiliaries and additives.Type: GrantFiled: October 20, 1989Date of Patent: December 22, 1992Assignee: Bayer AktiengesellschaftInventors: Hanns-Peter Muller, Otto Ganster, Bruno Luckas
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Patent number: 5118722Abstract: A method of producing elastic foam having a base of polyurethane, in particular for use in the field of automobiles for sound damping. Allows production of foam parts directly in a desired shape in as few operations as possible. The foam is formed from a mixture of at least one polyurethane precondensate, at least on melamine precondensate and further additives for the foaming.Type: GrantFiled: November 27, 1989Date of Patent: June 2, 1992Assignee: Illbruck GmbHInventors: Klaus Wollmann, Alexander Ach, Werner Frank
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Patent number: 5112876Abstract: The present invention relates to a polyether polyol which is prepared by(i) reacting 3.0 to 4.0 molecular equivalents of ethylene oxide with one molecular equivalent of 2,3- or 3,4-tolylenediamine, or a mixture thereof in the absense of catalyst, and thereafter,(ii) reacting 2.8 to 4.8 molecular equivalents of propylene oxide with one molecular equivalent of the reaction product in the presence of an alkali metal hydroxide in an amount of not more than 0.8% by weight based on the 2,3- or 3,4-tolylenediamine, or the mixture thereof.The present invention also relates to a rigid polyurethane foam which is prepared by reacting a polyol mixture containing not less than 50 wt % of the above-mentioned polyether polyol with an isocyanate. The rigid polyurethane foam is obtained with reduced fron requirements.Type: GrantFiled: October 25, 1989Date of Patent: May 12, 1992Assignee: Takeda Chemical Industries, Ltd.Inventors: Yoshihiko Tairaka, Katsumi Inaoka
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Patent number: 5106684Abstract: Foam sheets of high heat distortion resistance contain a) from 80 to 99% by weight of a styrene polymer and b) from 1 to 20% by weight of poly-1,4-phenylene sulfide, and, if desired, conventional additives and are produced by extrusion using a low-boiling blowing agent.Type: GrantFiled: February 15, 1991Date of Patent: April 21, 1992Assignee: BASF AktiengesellschaftInventors: Reinhold Weber, Gerhard Alicke, Manfred Weilbacher, Uwe Guhr, Klaus Hahn
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Patent number: 5096623Abstract: A flame retardant composition and process which is particular useful for rebounded foam products. The composition of the present invention includes a solid component of magnesium sulfate, boric acid, decabromodiphenylethylene oxide (DECA) and antimony trioxide and a liquid component of halogenated phosphorous. The present invention is based upon the discovery of the synergism between boric acid and DECA. The process, according to the present invention, includes the steps of forming a dispersion of the solid portion of the flame retardant composition along with a small amount of water based adhesive to a mass of foam chips. The treated chips are then dried to permit handling and storage. The dried foam chips subsequently are mixed with a conventional urethane prepolymer binder and the liquid halogenated phosphorous flame retardant compound. After mixing the foam mass is transferred to molds and steamed to allow the binder to cure.Type: GrantFiled: August 12, 1991Date of Patent: March 17, 1992Assignee: Triad-Fabco, Inc.Inventors: Robert W. Ward, Rogelio Tornero, Freeman J. Henderson
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Patent number: 5057546Abstract: A semi-flexible or flexible phenolic foam composition having a substantially open cellular structure. It comprises the reaction product of a mixture of a phenol-aldehyde resin, a surfactant, a blowing agent; optionally a wetting agent and a catalyst. Also within the scope of the present invention is a method for producing a semi-flexible or flexible phenolic foam composition having a substantially opened cellular structure. This method comprises mixing a phenol-aldehyde resin with a surfactant, a blowing agent and optionally a cell opening and wetting agent; curing the mixture by reacting it with an acid catalyst; compressing the cured or semi-cured product below its original thickness and releasing the pressure, thereby obtaining the desired semi-flexible or flexible phenolic foam composition. The semi-flexible or flexible foam thus obtained possesses excellent insulation and flame retardant properties.Type: GrantFiled: July 14, 1989Date of Patent: October 15, 1991Inventor: Krishan Sudan
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Patent number: 5023280Abstract: The present invention relates to a process for the production of polyurethane foams by the reaction of 1) polyisocyanates with 2) polyesters, polycarbonates, polylactones, or polyamides having a molecular weight range of about 400 to about 10,000 and containing at least two isocyanate reactive hydrogen atoms, or mixtures thereof, in the presence of 3) water and/or organic blowing agents, 4) catalysts and 5) flame-retardants, and optionally in the presence of 6) compounds with molecular weights of from 32 to 399 containing at least two isocyanate reactive hydrogen atoms and 7) surface-active additives and other auxiliary agents known in the art. The flame-retardants consist of graphite which has been modified with inorganic expandable materials, either alone or in combination with an inorganic co-flame-retardant.Type: GrantFiled: April 7, 1989Date of Patent: June 11, 1991Assignee: Bayer AktiengesellschaftInventors: Peter Haas, Hans Hettel
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Patent number: 5019599Abstract: A deodorizing urethane foam comprising a urethane foam substrate and a deodorizing component. The deodorizing component is composed of (A) a Diels-Alder reaction-type addition reaction product between an alpha,beta-unsaturated dicarboxylic anhydride and an olefin or a derivative of the reaction product and optionally (B) a copper compound. This urethane foam is produced by foaming a mixture of materials for the urethane foam substrate and the Diels-Alder reaction-type addition reaction product between an alpha,beta-unsaturated dicarboxylic anhydride and an olefin or its derivative of the reaction product and optionally the copper compound.Type: GrantFiled: March 22, 1989Date of Patent: May 28, 1991Assignee: Nippon Zeon Co., Ltd.Inventors: Yoshiaki Miki, Tsunehisa Ueda
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Patent number: 4977194Abstract: The present invention relates to a process for the preparation of polyurethane foams comprising reacting polyisocyanates with dispersions of (i) polymer-containing relatively high molecular weight hydroxyl compounds that are prepared by reaction of mono- or polyisocyanates with NH-containing compounds selected from the group consisting of polyamines containing primary and/or secondary amino groups, hydrazines, hydrazides, and alkanolamines in (ii) a compound containing 1 to about 8 primary and/or secondary hydroxyl groups and having a molecular weight of about 400 to about 16,000, in the presence of water and/or organic blowing agents; catalysts; and flameproofing agents comprising an expandable graphite modified by inorganic expandable materials, alone or in combination with inorganic co-flameproofing agents.Type: GrantFiled: August 11, 1989Date of Patent: December 11, 1990Assignee: Bayer AktiengesellschaftInventors: Peter Haas, Hans Hettel
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Patent number: 4972002Abstract: This invention concerns a process for producing cellular plastics by the polyisocyanate polyaddition process by reaction of(a) organic and/or modified organic polyisocyanates with(b) at least one high molecular compound with at least two reactive hydrogens and optionally(c) low molecular chain extenders and/or crosslinking agentsin the presence of(d) blowing agents(e) catalysts(f) additives and/or processing aids where low boiling fluorinated or perfluorinated hydrocarbons with 3 to 8 carbons that are insoluble or almost insoluble in (a) to (c), sulfur hexafluoride or mixtures thereof are used as blowing agent (d) which is emulsified in reaction components (a), (b), mixtures of (b) and (c) or (a) and (b) as well as stable blowing agent emulsion of the aforementioned blowing agents (d) reaction components (a), (b) or (b) and (c).Type: GrantFiled: July 3, 1989Date of Patent: November 20, 1990Assignee: BASF AktiengesellschaftInventor: Otto Volkert
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Patent number: 4968724Abstract: Novel polyurethane resin foam compositions are provided which are only water-blown and require no halocarbon blowing agents, yet suffer no degradation in physical properties. The formulations include a hydrated salt containing at least two hydrated salts that release water at a temperature above 80.degree. C. By using at least an acidic salt and a basic salt, the pH of the salt system may be balanced. A preferred hydrated salt system is a combination of borax (sodium tetraborate decahydrate) and alum (aluminum potassium sulfate dodecahydrate).Type: GrantFiled: May 31, 1990Date of Patent: November 6, 1990Assignee: Arco Chemical Technology, Inc.Inventor: Rocco L. Mascioli
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Fire retardant for isocyanate-based foams comprising ammonium sulfate and a cyanuric acid derivative
Patent number: 4908161Abstract: Ammonium sulfate powder is employed, alone, or in conjunction with a weakly basic powder to neuturalize the acidity of the sulfate, as a flame retardant for isocyanate-based foams and, in particular, rigid and flexible polyurethane foams.Type: GrantFiled: June 23, 1988Date of Patent: March 13, 1990Assignee: Harry FischerInventor: Kaneyoshi Ashida