Ingredient Is A Nitrogen Containing Compound Patents (Class 521/128)
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Patent number: 11548997Abstract: The invention is related to a method for reducing the emission of acetaldehyde and/or propionaldehyde from a polyurethane or polyurea foam, by using a reaction mixture comprising at least one isocyanate reactive component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamine and a polyester polyamine; an isocyanate component; and cyanoacetamide.Type: GrantFiled: February 6, 2017Date of Patent: January 10, 2023Assignee: Huntsman International LLCInventors: Ingrid Welvaet, Geert Lodewijk Dries, Joris Karel Peter Bosman
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Patent number: 11547977Abstract: The current disclosure provides reinforced aerogel compositions that are durable and easy to handle, have favorable performance in aqueous environments, have favorable insulation properties, and have favorable, reaction to fire, combustion and flame-resistance properties. Also provided are methods of preparing or manufacturing such reinforced aerogel compositions. In certain embodiments, the composition has a silica-based aerogel framework, reinforced with an open-cell macroporous framework, and includes one or more fire-class additives, where the silica-based aerogel framework comprises at least one hydrophobic-bound silicon and the composition or each of its components has desired properties.Type: GrantFiled: May 29, 2019Date of Patent: January 10, 2023Assignee: Aspen Aerogels, Inc.Inventors: David J. Mihalcik, Kathryn Elizabeth deKrafft, Nicholas Anthony Zafiropoulos, Owen Richard Evans, George L. Gould, Wibke Lölsberg
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Patent number: 11434344Abstract: A (super)hydrophobic isocyanate based organic aerogel/xerogel/cryogel having a water contact angle of at least 90° comprising: a cross-linked porous network structure made of polyurethane and/or polyisocyanurate and/or polyurea, and hydrophobic compounds having before the gelling step at least one isocyanate-reactive group and no isocyanate groups Characterized in that said hydrophobic compounds are covalently bonded within the porous network of the aerogel/xerogel/cryogel and wherein said bondings are created during the gelling step of the formation of the isocyanate based organic aerogel/xerogel/cryogel cross-linked porous network structure.Type: GrantFiled: October 12, 2016Date of Patent: September 6, 2022Assignee: HUNTSMAN INTERNATIONAL LLCInventors: Thomas Julien Joncheray, Jan Vandenbroeck, Gilles Jean Geumez
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Patent number: 11203708Abstract: The present application provides a gas-generating aqueous fluid containing a gas-generating compound like an azo compound, and an organic amine like a primary, secondary or tertiary amine, a hydrazine, a hydrazide, or a semicarbazide. The aqueous fluid may also a viscosifier, and a foaming surfactant. The present application also provides a method of using the gas-generating composition to modulate density of a wellbore fluid for use in downhole applications. The method optionally includes adding an oxidizer to the wellbore fluid.Type: GrantFiled: November 4, 2020Date of Patent: December 21, 2021Assignee: Saudi Arabian Oil CompanyInventor: B. Raghava Reddy
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Patent number: 11059932Abstract: To provide a catalyst composition to obtain a flexible polyurethane foam from which substantially no amine compound is discharged and which has sufficient resistance to compressive strain, and a method for producing a flexible polyurethane foam using the catalyst composition. A polyurethane foam is produced by using a catalyst composition for producing a polyurethane foam, which comprises an amine compound represented by the following formula (1) and at least one glycol selected from the group consisting of ethylene glycol and polyethylene glycol, provided that when the compound of the formula (1) has enantiomers, diastereomers or geometric isomers, both a mixture thereof and isolated isomers are included: wherein R1, R2, R3 and R4 are each independently a hydrogen atom, a C1-4 alkyl group, a hydroxy group, a hydroxymethyl group or a C1-4 alkoxy group, and m is an integer of 1 or 2.Type: GrantFiled: November 29, 2016Date of Patent: July 13, 2021Assignee: TOSOH CORPORATIONInventors: Yusuke Sesoko, Hiroyuki Kiso
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Patent number: 10851196Abstract: Disclosed are polyurethane-foam forming compositions, rigid polyurethane foams and methods for their production, as well as to composite articles comprising such foams sandwiched between facer substrates, including use of such composite elements for floor insulating elements for refrigerated tractor trailers. The rigid polyurethane foams are produced from an isocyanate-reactive composition comprising: (1) a polyol blend; (2) a hydrochlorofluoroolefin; and (3) a tertiary amine catalyst composition.Type: GrantFiled: April 29, 2019Date of Patent: December 1, 2020Assignee: Covestro LLCInventors: Shawn G. Rider, Brandon W. Parks, Carson C. Miller
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Patent number: 10829799Abstract: The present invention relates to the production of activated biological molecules for use in profiling biological molecule interactions. The activated biological molecule may be a ubiquitin (Ub) and ubiquitin-like conjugation enzyme as well as other proteins with internal reactive cysteine residues.Type: GrantFiled: September 30, 2015Date of Patent: November 10, 2020Assignee: UNIVERSITY COURT OF THE UNIVERSITY OF DUNDEEInventors: Satpal Virdee, Mathew Stanley, Kuan-Chuan Pao
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Patent number: 10808070Abstract: The present invention relates to a polyisocyanurate foam obtainable by reacting a mixture in the presence of a catalyst and optionally an initiator, comprising or consisting of: A) a polyisocyanate component comprising at least one aliphatic polyisocyanate; B) a component reactive to isocyanate comprising at least one polyol and/or an alcohol and also optionally an amine; C) at least one blowing agent; D) at least one foam stabilizer and E) optionally at least one additive, characterized in that the mixture, upon accompanying use of an isocyanate-reactive component (polyol, alcohol, amine), has an index of at least 200. The invention further relates to a process for producing such a foam and use thereof as an insulating material, as a construction element, as facade insulation, as reactor insulation, as battery insulation, as superheated steam insulation, as insulation for a still, or as weather-resistant insulating material.Type: GrantFiled: July 12, 2017Date of Patent: October 20, 2020Assignee: Covestro Deutschland AGInventors: Lutz Böhnke, Dirk Achten
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Patent number: 10759896Abstract: Provided is a method for producing a light rigid urethane foam superior in moldability (cell interconnection, spraying thickness, adhesiveness, etc.), heat-insulating efficiency, and others by a spraying method, using water as foaming agent. A method for producing an open-cell polyurethane foam, comprising obtaining the open-cell polyurethane foam by mixing and reacting a polyol composition containing a polyol compound, water as a foaming agent, a foam stabilizer, a catalyst, and a flame retardant with a polyisocyanate compound by a spraying method, the polyol compound containing polyols (A), (B), and (C) at a polyol (A) content of 10 to 40 wt parts, a polyol (B) content of 10 to 70 wt parts, and a polyol (C) content of 10 to 70 wt parts.Type: GrantFiled: November 18, 2016Date of Patent: September 1, 2020Assignee: Covestro Deutschland AGInventors: Hideki Wada, Takayasu Tanabe, Kenichi Sakata
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Patent number: 10649350Abstract: The present invention provides an electrophotographic member having excellent deformation recovery even when stored or used under a high temperature and high humidity environment, which is useful in forming a high-quality electrophotographic image; a process cartridge; and an electrophotographic apparatus. The electrophotographic member of the present invention includes a conductive mandrel and an electro-conductive layer; the electro-conductive layer including a resin synthesized from an ion conducting agent and a compound being able to react with the ion conducting agent; the ion conducting agent including a specific anion and a cation having at least three hydroxyl groups; the compound being able to react with the hydroxyl group.Type: GrantFiled: May 18, 2015Date of Patent: May 12, 2020Assignee: CANON KABUSHIKI KAISHAInventors: Sosuke Yamaguchi, Masaki Yamada, Kazuhiro Yamauchi, Satoru Nishioka, Taichi Shintou
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Patent number: 10626290Abstract: A liquid coating composition is disclosed that is prepared from a reaction mixture comprising an amine component comprising (a) an amine component comprising a polyamine complexed with CO2 and (b) a crosslinker, wherein the amine component is liquid at ambient conditions.Type: GrantFiled: December 16, 2013Date of Patent: April 21, 2020Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan P. Breon, Robert E. Jennings
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Patent number: 10538614Abstract: The purpose of the present invention is to provide a composition for forming a semi-rigid polyurethane foam that has low hardness and a resilient feel, has excellent moldability and curability even when made lightweight (made thin), and is suitable for use as an automobile interior material. The present invention is a composition for forming a semi-rigid polyurethane foam that comprises: a polyol mixture (P) that contains a specific polyol (the composition) (A), a water-containing foaming agent (C), and a catalyst (D); and a polyisocyanate component (B). The content of foaming agent (C) is 1.5-2.5 wt % based on the total weight of (A).Type: GrantFiled: December 16, 2014Date of Patent: January 21, 2020Assignee: SANYO CHEMICAL INDUSTRIES, LTD.Inventor: Shunsuke Kinoshita
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Patent number: 10450403Abstract: A composition for polyurethane foaming, a polyurethane foam and a use thereof. The composition contains two different polyols with a polyethylene oxide ether structure and a polypropylene oxide ether structure, and a specific type of catalyst, flame retardant and water are added thereto; at the same time, the composition contains a small amount of a surfactant and other small molecular alcohols. The traits of the product are that it is pale yellow and transparent, and the product is not layered during long-term storage. The above-mentioned composition and polyphenylpolymethylene polyisocyanate (PAPI) produce a low-density polyurethane foam by means of a foaming machine.Type: GrantFiled: January 29, 2015Date of Patent: October 22, 2019Assignee: Wanhua Chemical (Ningbo) Rongwei Polyurethane Co., Ltd.Inventors: Junfeng Wang, Xialin Zhu, Jing Chen
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Patent number: 10400081Abstract: The present invention relates to a method of synthesis and the use of foamed, cross-linked polyurethane polymers, as a three-dimensional support called a “scaffold” for cell cultures in vitro and for in vivo implantation for the regeneration of connective tissues such as adipose tissue, osteochondral tissue and bone tissue. In particular, the invention relates to a method of preparing polymers or foamed polyurethane co polymers, having improved hydrophilia, which involves the use of two types of catalyst, one for the cross-linking reaction and one for the foaming reaction and the use of at least one polar aprotic high-boiling solvent.Type: GrantFiled: April 15, 2015Date of Patent: September 3, 2019Assignee: TENSIVE S.R.L.Inventors: Irini Gerges, Federico Martello, Margherita Tamplenizza, Alessandro Tocchio
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Patent number: 10385177Abstract: The invention is directed to methods of preparing compositions used to manufacture polyurethane foams. The invention provides methods for making compositions used to make polyurethane foams that include amine catalysts, but formulated such that catalytic potency is not diminished over time before the forming of a foam.Type: GrantFiled: August 3, 2005Date of Patent: August 20, 2019Assignee: Foam Supplies, Inc.Inventors: David G. Keske, David L. Modray, Mark S. Schulte, Timothy T. Kalinowski
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Patent number: 10196493Abstract: The present invention relates to a process for the production of polyurethanes where (a) polyisocyanate, (b) polymeric compounds having groups reactive toward isocyanates, (c) catalysts, (d) a CH-acidic compound of the general formula R1—CH2—R2, where R1 and R2 independently of one another are an electron-withdrawing moiety of the general formula —C(O)—R3 or —CN, where the moiety R3 is selected from the group consisting of —NH2, —NH—R4—NR5R6, OR7 or R8, where R4, R5, R6, R7, and R8 are independently selected from the group consisting of aliphatic, araliphatic or aromatic hydrocarbons, which may have substitution, and optionally (e) blowing agent, (f) chain extender and/or crosslinking agent, and (g) auxiliaries and/or additives are mixed to give a reaction mixture, and the reaction mixture is allowed to complete a reaction to give the polyurethane. The present invention further relates to polyurethanes produced by this process and to the use of these polyurethanes in the interior of means of transport.Type: GrantFiled: November 27, 2014Date of Patent: February 5, 2019Assignee: BASF SEInventors: Iran Otero Martinez, Georg Partusch, Christian Hagen
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Patent number: 10047207Abstract: Disclosed is a net-shaped polyimide sponge. The polyimide sponge has a stack structure of nets. Also disclosed is a method for producing a polyimide sponge. The method enables the production of a polyimide sponge in a simple manner compared to conventional methods based on wet or dry phase inversion techniques using porogens.Type: GrantFiled: October 8, 2015Date of Patent: August 14, 2018Assignee: INDUSTRY-ACADEMIC COOPERATION FOUNDATION, YONSEI UNIVERSITYInventors: Haksoo Han, Jinuk Kwon, Jinyoung Kim
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Patent number: 9951172Abstract: Using general purpose raw materials, a polyurethane foam having higher water stopping properties than conventional ones is provided. The polyurethane foam is a polyurethane foam obtained by foaming and curing a composition containing a polyol component, an isocyanate component, a foam stabilizer, a cross-linking agent, and a catalyst.Type: GrantFiled: January 8, 2015Date of Patent: April 24, 2018Assignee: BRIDGESTONE CORPORATIONInventor: Shinya Kanzaki
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Patent number: 9815932Abstract: The present invention provides trimerization catalyst compositions having an ?,?-unsaturated carboxylate salt and methods to produce a polyisocyanurate/polyurethane foam using such trimerization catalyst compositions.Type: GrantFiled: October 22, 2013Date of Patent: November 14, 2017Assignee: Evonik Degussa GmbHInventors: Juan Jesus Burdeniuc, Torsten Panitzsch, John Elton Dewhurst
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Patent number: 9777104Abstract: The present invention relates to predominantly (>50 vol %) open-cell (to DIN ISO 4590-5 86), cold-deformable, rigid polyurethane foams which possess high acoustic absorption and a uniform cell structure and which are suitable for producing automotive interior trim, more particularly roof linings and pillar trim.Type: GrantFiled: March 25, 2013Date of Patent: October 3, 2017Assignee: Covestro Deutschland AGInventors: Lutz Boehnke, Joern Beaujean, Rolf Albach, Jun Li, Ling Shi
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Patent number: 9718936Abstract: The present invention relates to a process for producing a rigid polyurethane-polyisocyanurate foam C, comprising the step of reacting (i) an isocyanate-terminated prepolymer B with (ii) an activator component A comprising at least one trimerization catalyst A1 and at least one blowing agent A3 in a reaction mixture to form a foam, characterized in that—there is used an isocyanate-terminated prepolymer B obtained from a reaction of an isocyanate B1 having a mean isocyanate functionality of from ?2.3 to ?2.9 with a polyol component B2, and—the activator component A comprises water as the blowing agent A3 in an amount of from ?5 wt. % to ?50 wt. %,—the isocyanate index in the reaction mixture is in a range of from ?400 to ?500, and—the isocyanate content of the prepolymer B is in a range of from ?21 wt. % to ?30 wt. %, based on the total mass of the prepolymer B, and—wherein in the reaction of the prepolymer B and the activator component A a conversion contribution to polyisocyanurate of ?75% is achieved.Type: GrantFiled: February 5, 2013Date of Patent: August 1, 2017Assignee: Covestro Deutschland AGInventors: Stephan Schleiermacher, Patrick Klasen, Reinhard Albers, Stephan Moers, Dirk Steinmeister, Dieter Seidel, Torsten Heinemann, Hans-Detlef Arntz
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Patent number: 9701804Abstract: The present invention relates to a method for producing flexible polyurethane foams, wherein an isocyanate component (component B) which comprises fatty acid derivatives comprising hydroxyl groups is used as starting substance. The flexible polyurethane foams according to the invention have a bulk density according to DIN EN ISO 3386-1-98 in the range of ?10 kg/m3 to ?150 kg/m3, preferably ?20 kg/m3 to ?70 kg/m3, and in general their compressive strength according to DIN EN ISO 3386-1-98 is in the range of ?0.5 kPa to ?20 kPa (at 40% deformation and 4th cycle). The invention also provides an NCO-terminated prepolymer comprising urethane groups obtainable by reaction of one or more polyisocyanates (B1) with one or more fatty acid derivatives comprising hydroxyl groups (B2).Type: GrantFiled: November 18, 2011Date of Patent: July 11, 2017Assignee: Covestro Deutschland AGInventors: Norbert Hahn, Sven Meyer-Ahrens, Gundolf Jacobs, Bernd Dohmen
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Patent number: 9505895Abstract: The present invention relates to the use of nitrogenous compounds of formula (I) or of corresponding quaternized, or protonated compounds, for producing polyurethanes, to compositions containing these compounds and also to polyurethane systems obtained using the compounds.Type: GrantFiled: January 7, 2014Date of Patent: November 29, 2016Assignee: EVONIK DEGUSSA GMBHInventors: Sarah Schmitz, Martin Glos, Roland Hubel, Annegret Terheiden
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Patent number: 9469715Abstract: The invention relates to a method for producing non-alternating formaldehyde/CO2 copolymers, said method comprising the step of reacting formaldehyde or a compound that releases formaldehyde with carbon dioxide in the presence of a catalyst system. Said method is characterized in that the catalyst system comprises a Lewis acid component and a basic component, the Lewis acid component being at least temporarily coordinatively unsaturated under reaction conditions and the basic component having a pKb value of >=0.Type: GrantFiled: December 17, 2013Date of Patent: October 18, 2016Assignee: Covestro Deutschland AGInventors: Thomas Ernst Müller, Christoph Gürtler, Henning Vogt, Mario Krautschick, Walter Leitner
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Patent number: 9382396Abstract: Cavity blocks contain a rigid polyurethane foam having a density in the range of 30-70 g/L in at least one chamber, the rigid polyurethane foam being obtained by reacting at least one polyisocyanate a) with at least one compound having at least two isocyanate-reactive hydrogen atoms b) in the presence of at least one catalyst d) and using at least one blowing agent c), comprising at least one blowing agent ci), which only develops its blowing effect at the time of the reaction of a) with b), and at least one blowing agent cii), which has a boiling point which is below the temperature at which said components a) and b) are mixed, wherein the pressure buildup during the foaming reaction of the polyurethane remains below 20 kPa, and the invention also relates to the corresponding process for producing the cavity blocks.Type: GrantFiled: August 27, 2012Date of Patent: July 5, 2016Assignee: BASF SEInventor: Peter Wintermann
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Patent number: 9334369Abstract: The present invention provides a polyimide precursor composition comprising a polyimide precursor and a thermal base generator having the structure of formula (1): wherein R1, R2, R3, R4, R5 and Y? are as defined in the specification. The present invention also provides a polyimide prepared from the aforementioned precursor composition, and a preparation method thereof.Type: GrantFiled: December 21, 2012Date of Patent: May 10, 2016Assignee: Eternal Chemical Co., Ltd.Inventors: Pi-Chen Cheng, Meng-Yen Chou, Chuan Zong Lee, Chung-Jen Wu
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Patent number: 9181377Abstract: Biodegradable graft copolymers derived from a carbohydrate and at least one ?,?-unsaturated carboxylic acid derivative having superabsorbent properties are disclosed in addition to the substantially adiabatic polymerization process by which the graft copolymers are made. The methods disclosed can be carried out in a variety of currently available continuous commercial reactors. Polymerizations carried out with starch have surprisingly produced substantially quantitative yields of graft copolymer free of residual monomer produced as a moist copolymer. Product work-up typically involves an optional neutralization and drying.Type: GrantFiled: July 8, 2013Date of Patent: November 10, 2015Assignee: Tryeco, LLCInventor: William J. Chambers
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Patent number: 9133377Abstract: A heat-activable powder adhesive composition for use in bonding a component to a surface such as glass is disclosed. The composition of the disclosed invention includes at least two polymers, at least one solid di- or poly-isocyanate in powder form, and a catalyst. Each of the two polymers has a melting point above 40° C. The two polymers are selected from the group consisting of di-functional polymers and multi-functional polymers. The preferred method of preparing the composition of the disclosed invention includes first forming three parts, including a first melted part comprising the polymers, a second melted part comprising the polymers and a catalyst, and a third part comprising the isocyanate. Once cooled, each of the first and second parts forms solid blocks which are fragmented and sieved. The three dry parts are then brought together to form the adhesive powder of the disclosed invention. The adhesive powder can be pre-applied to the attachment surface of a component to be bonded.Type: GrantFiled: May 20, 2010Date of Patent: September 15, 2015Assignee: A. Raymond Et CieInventors: Michel Brémont, Michel Awkal
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Patent number: 9023905Abstract: The present invention relates to a cleaning implement based on melamine formaldehyde foams comprising, abrasive particles and to a method of cleaning a hard surface with said cleaning implement.Type: GrantFiled: February 24, 2012Date of Patent: May 5, 2015Assignee: The procter & Gamble CompanyInventors: David John Pung, Denis Alfred Gonzales, Tobias Heinz Steinke, Peter Nessel
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Publication number: 20150094387Abstract: The present disclosure relates to an amine catalyst composition for producing polyurethane foam. The amine catalyst composition includes an amine catalyst and a diluent containing a thickening agent and water. The use of such a diluent, in place of conventional glycols, reduces raw material and processing costs as well as environmental concerns during the production of polyurethane foam.Type: ApplicationFiled: August 10, 2012Publication date: April 2, 2015Applicant: Huntsman Petrochemical LLCInventors: Eugene P. Wiltz, JR., Donald Ridgway, Jennifer Chavez, Frank Rodriguez, Robert A. Grigsby, JR., Gwynne Whitcombe
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Patent number: 8974903Abstract: Porous cross-linked polyimide-urea networks are provided. The networks comprise a subunit comprising two anhydride end-capped polyamic acid oligomers in direct connection via a urea linkage. The oligomers (a) each comprise a repeating unit of a dianhydride and a diamine and a terminal anhydride group and (b) are formulated with 2 to 15 of the repeating units. The subunit was formed by reaction of the diamine and a diisocyanate to form a diamine-urea linkage-diamine group, followed by reaction of the diamine-urea linkage-diamine group with the dianhydride and the diamine to form the subunit. The subunit has been cross-linked via a cross-linking agent, comprising three or more amine groups, at a balanced stoichiometry of the amine groups to the terminal anhydride groups. The subunit has been chemically imidized to yield the porous cross-linked polyimide-urea network. Also provided are wet gels, aerogels, and thin films comprising the networks, and methods of making the networks.Type: GrantFiled: March 14, 2013Date of Patent: March 10, 2015Assignees: Ohio Aerospace Institute, The United States of America, represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Mary Ann B. Meador, Baochau N. Nguyen
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Patent number: 8975306Abstract: A viscoelastic foam system is provided having an amine-based polyoxypropylene extended polyol to impart strength, recoverability and endurance to the foam, and an appropriately selected non-amine-based polyol to provide flexibility to the foam. The combination of amine-based propylene oxide extended polyol and non-amine-based polyol provides a viscoelastic semi-rigid foam with excellent impact and recovery properties, recovering to substantially 100% of its initial volume and shape following an impact, yet with sufficient rigidity and stiffness so that it is effective at absorbing multiple impacts. A method of making the above viscoelastic foam is also provided.Type: GrantFiled: October 19, 2004Date of Patent: March 10, 2015Assignee: Intellectual Property Holdings, LLCInventor: Charles M. Milliren
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Publication number: 20150065592Abstract: A formulation for preparing a low density, full water blown polyurethane rigid foam includes an isocyanate component; an isocyanate-reactive component comprising from 30-50 wt % of a first polyether polyol having a functionality greater than 5 and an OH value from 350-550 mgKOH/g; from 5 to 25 wt % of a diol having an OH value from 100-300 mgKOH/g; and from 15 to 35 weight percent of a second polyether polyol having a functionality from 3 to 5; further including from 1.5 to 5 wt % of a catalyst selected from dimethylbenzylamine and/or 1,2-dimethyl-imidazole; from greater than 0 to 1 wt % of a trimerization catalyst selected from a glycine salt and/or tris(dimethyl aminomethyl) phenol; greater than 4.1 wt % water as a blowing agent; and any additional constituents selected such that the formulation, excluding the isocyanate component, totals 100 wt % and, the formulation absent the isocyanate component, has a dynamic viscosity from 540 to 864 mPa*s at 20° C.Type: ApplicationFiled: March 3, 2013Publication date: March 5, 2015Applicant: Dow Global Technologies LLCInventor: Cecilia Girotti
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Publication number: 20140364525Abstract: Melamine-polyol dispersions comprising ethoxylated alcohols of specific structures are disclosed. Such dispersions maintain their stability under stationary conditions for at least 24 hours and are useful in the manufacturing of polyurethane foams. The resulted polyurethane foams display more evenly-distributed flame retardant properties.Type: ApplicationFiled: January 6, 2012Publication date: December 11, 2014Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Jackson Su, Jacky Cao, Tadao Yasue, Mark Cao
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Patent number: 8906975Abstract: A conventional flexible polyurethane foam, made using methylene diphenyl diisocyanate (MDI), having a bulk foam density in the range of 2.5 pounds per cubic foot or lower and having a foam hardness or IFD in the range of 10 to 90 lb/50 in2. The present invention is also directed to the method for the making thereof.Type: GrantFiled: February 5, 2010Date of Patent: December 9, 2014Assignee: Hickory Springs Manufacturing CompanyInventors: Dimitrios V. Dounis, Dwayne Lewis Beard, Camden Eugene McLaughlin, Kimberly R. Fair
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Patent number: 8901187Abstract: A high resilience flexible polyurethane foam, made using methylene diphenyl diisocyanate (MDI), having a bulk foam density in the range of 2.5 pounds per cubic foot or lower and having a foam hardness or IFD in the range of 10 to 40 lb/50 in2. The present invention is also directed to the method for the making thereof.Type: GrantFiled: December 17, 2009Date of Patent: December 2, 2014Assignee: Hickory Springs Manufacturing CompanyInventors: Dimitrios V. Dounis, Dwayne Lewis Beard, Camden Eugene McLaughlin, Kimberly R. Fair
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Patent number: 8875402Abstract: A low volatile organic emission method for making a door using a liquid hardenable flowable material. The liquid hardenable flowable material expands upon contact with a blowing agent forming a foam, wherein the liquid material is formed from plant materials, and a door formed from the method. The method forms a door with sound deadening qualities, increased impact resistance, and resistance to burning and capable of sustaining at least hurricane force winds without deforming.Type: GrantFiled: June 5, 2014Date of Patent: November 4, 2014Assignee: Glasscraft Door CompanyInventor: John B. Plummer
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Publication number: 20140323605Abstract: The invention relates to stable emulsions for the production of foams based on isocyanate, at least comprising three polyols A1a, A1b and A1c as well as at least one physical blowing agent T, wherein A1a is a polyether polyol obtained by addition of epoxides to starter compounds selected from carbohydrates and di- or higher-functional alcohols, A1b is a polyether polyol started on an aromatic amine, and A1c is a polyester polyol obtained by esterification of a polycarboxylic acid component and a polyalcohol component, wherein the total amount of aromatic dicarboxylic acid derivatives used in the esterification, calculated on the basis of the free aromatic dicarboxylic acids and based on the total mass of polyalcohol component and polycarboxylic acid component, is less than or equal to 48.5% by mass.Type: ApplicationFiled: August 22, 2012Publication date: October 30, 2014Applicant: Bayer Intellectual Property GmbHInventors: Reinhard Albers, Torsten Heinemann, Stephanie Vogel, Hartmut Nefzger, Frank Otto
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Publication number: 20140319502Abstract: An object of the present invention is to provide a coating composition capable of being easily formed by coating or the like, and a porous membrane and a light scattering layer which are excellent in heat resistance, surface smoothness and flexibility and have a high refractive index, a high light scattering property, and a high light transmittance, and further an organic electroluminescent element having the light scattering layer. It has been found that voids are formed inside a cured product obtained by curing a composition containing a polysilane, a metal oxide, and a solvent. The cured product having the voids formed therein has a light scattering property and therefore is applicable as a light scattering membrane.Type: ApplicationFiled: July 10, 2014Publication date: October 30, 2014Applicant: MITSUBISHI CHEMICAL CORPORATIONInventor: Tomokazu UMEMOTO
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Publication number: 20140319410Abstract: In one aspect, compositions are described herein. In some embodiments, a composition comprises a latent heat storage material having a solid-to-gel transition between about ?50° C. and about 100° C. at 1 atm. In some embodiments, a composition comprises a foam and a latent heat storage material dispersed in the foam, the latent heat storage material having a solid-to-gel transition between about ?50° C. and about 100° C. at 1 atm.Type: ApplicationFiled: December 28, 2012Publication date: October 30, 2014Inventors: Reyad I. Sawafta, Najih Naser
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Publication number: 20140272358Abstract: Porous cross-linked polyimide-urea networks are provided. The networks comprise a subunit comprising two anhydride end-capped polyamic acid oligomers in direct connection via a urea linkage. The oligomers (a) each comprise a repeating unit of a dianhydride and a diamine and a terminal anhydride group and (b) are formulated with 2 to 15 of the repeating units. The subunit was formed by reaction of the diamine and a diisocyanate to form a diamine-urea linkage-diamine group, followed by reaction of the diamine-urea linkage-diamine group with the dianhydride and the diamine to form the subunit. The subunit has been cross-linked via a cross-linking agent, comprising three or more amine groups, at a balanced stoichiometry of the amine groups to the terminal anhydride groups. The subunit has been chemically imidized to yield the porous cross-linked polyimide-urea network. Also provided are wet gels, aerogels, and thin films comprising the networks, and methods of making the networks.Type: ApplicationFiled: March 14, 2013Publication date: September 18, 2014Applicant: OHIO AEROSPACE INSTITUTEInventors: Mary Ann B. Meador, Baochau N. Nguyen
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Publication number: 20140243441Abstract: A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.Type: ApplicationFiled: March 12, 2014Publication date: August 28, 2014Applicant: NATIONAL RESEARCH COUNCIL OF CANADAInventors: Naiying DU, Michael D. GUIVER, Gilles P. ROBERTSON
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Publication number: 20140235739Abstract: In one embodiment, a method for producing a template includes applying a resin to a first template having a first concavo-convex pattern, hardening the resin, releasing the hardened resin from the first template to produce a second template having a second concavo-convex pattern corresponding to the first concavo-convex pattern, and enlarging the second template.Type: ApplicationFiled: August 29, 2013Publication date: August 21, 2014Applicant: KABUSHIKI KAISHA TOSHIBAInventor: Seiji MORITA
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Patent number: 8779018Abstract: In the present invention, a catalyst composition comprising the following amine compounds of (A) and (B) and/or (C) is used and further, a raw material-blended composition further containing a polyol component and water is used. (A) A quaternary ammonium salt represented by the following general formula (1): wherein each of R1 to R3 represents a hydrocarbon group having 1 to 12 carbon atoms, R4 represents an alkyl group or an aromatic hydrocarbon group having 1 to 18 carbon atoms, and X represents an organic acid group having an acid dissociation constant (pKa) of 4.8 or less; (B) A hydrophobic amine compound; (C) A heterocyclic tertiary amine compound.Type: GrantFiled: October 17, 2011Date of Patent: July 15, 2014Assignee: Tosoh CorporationInventors: Katsumi Tokumoto, Yutaka Tamano
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Publication number: 20140186246Abstract: Methods are provided for synthesizing novel types of self-assembled siloxanes, such as polysiloxanes, with a sufficiently high density of amine functional groups to be useful for CO2 capture and release processes. Additionally, it has been unexpectedly found that some self-assembled polysiloxanes can be used for high temperature adsorption of CO2.Type: ApplicationFiled: November 25, 2013Publication date: July 3, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: David C. Calabro, Quanchang Li, Dennis G. Peiffer, Mobae Afeworki, Stephen M. Cundy, Charanjit S. Paur, Peter I. Ravikovitch
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Patent number: 8716359Abstract: A scorch inhibitor composition for polyurethane foams is composed of (a) one or more derivatized phenolic compounds in an amount of about 60-80% by weight; (b) one or more aromatic amines in the form of a liquid in an amount of about 15-35% by weight; (c) an alkyl-substituted hydroquinone in an amount of about 4-8% by weight, and (d) phenothiazine at 0 to about 1.0% by weight.Type: GrantFiled: March 18, 2010Date of Patent: May 6, 2014Assignee: Vanderbilt Chemicals, LLCInventor: John M. Demassa
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Publication number: 20140100297Abstract: A bone cement is shown that includes a monomer, and a non-reactive substance that is fully miscible with the monomer. A resulting cured bone cement exhibits desirable properties such as modification in a stiffness of the material. Modified properties such a stiffness can be tailored to match bone properties and reduce an occurrence of fractures adjacent to a region repaired with bone cement. One example includes adjacent vertebral body fractures in vertebroplasty procedures.Type: ApplicationFiled: December 10, 2013Publication date: April 10, 2014Applicant: DePuy Synthes Products, LLCInventors: Elliott Gruskin, Andreas Boger, Andrea Montali, Kurtis Wheeler
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Publication number: 20140066532Abstract: Polyurethane/polyisocyanurate foams having a NFPA 101 Class A rating (ASTM E-84) are produced from a foam-forming reaction mixture that includes: an organic polyisocyanate, an isocyanate-reactive composition that includes at least one polyether polyol or polyester polyol with a nominal hydroxyl functionality of at least 2.0, a blowing agent composition and at least one halogen-free flame retardant. The blowing agent composition includes: (1) up to 5% by weight, based on total weight of the foam-forming composition, of one or more hydrocarbons having an LEL less than 2% by volume in air; and/or (2) a hydrocarbon having an LEL greater than 2% by volume in air; and (3) up to 1% by weight, based on total weight of foam-forming composition, of water.Type: ApplicationFiled: September 6, 2012Publication date: March 6, 2014Applicant: Bayer MaterialScience LLCInventors: George G. Combs, Susan C. Pigott
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Publication number: 20140058005Abstract: The present invention relates to a process for producing a thermoformable rigid polyurethane-polyamide foam having a closed-cell content of less than 70%, which comprises mixing (a) an organic polyisocyanate with (b) one or more polymeric compounds having two or more isocyanate-reactive hydrogen atoms, (c) optionally crosslinking and/or chain-extending agents, (d) one or more carboxylic acids having a functionality of 2 or more, (e) a catalyst comprising a Lewis base component, and (f) optionally auxiliaries and additives to form a reaction mixture and reacting this reaction mixture to form the rigid polyurethane-polyamide foam. The present invention further relates to a thermoformable rigid polyurethane-polyamide foam obtained by such a process and also to the use of such a thermoformable rigid polyurethane-polyamide foam for interior lining or engine compartment lining of motor vehicles.Type: ApplicationFiled: August 19, 2013Publication date: February 27, 2014Applicant: BASF SEInventors: Frank Prissok, Julio Albuerne, Christian Renner
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Patent number: 8642669Abstract: The invention relates to a foamable mixture which contains at least one alkoxysilane-terminated prepolymer and which can be produced of a) at least one alkoxysilane that was functionalized with isocyanate groups and that can be produced of at least one hydroxyfunctional and/or aminofunctional alkoxysilane and at least one diisocyanate or polyisocyanate, and b) at least one compound that contains at least one OH group, and at least one blowing agent, characterized in that the foamable mixture has a dynamic viscosity of 100 to 25,000 mPas, preferably 500 to 10,000 mPas, at 23° C. The invention further relates to a method for producing said foamable mixture. The foamable mixtures according to the invention are suitable for sealing, insulating and mounting joints, roof surfaces, windows and doors or for filling hollow spaces.Type: GrantFiled: January 20, 2011Date of Patent: February 4, 2014Assignee: Henkel AG & Co., KGaAInventors: Wilfried Huebner, Milan Sebestian, Christiane Kunze, Lars Zander, Johann Klein