Abstract: Rigid foams are made by reacting a polyisocyanate with an isocyanate-reactive composition which includes at least one isocyanate-reactive compound, preferably, an amine-initiated polyol and more preferably, an amine-initiated polyether polyol and a second, different polyol in the presence of a blowing agent composition which includes water and a catalyst composition which includes two different blowing catalysts, preferably, pentamethyldiethylenetriamine and bis(2-dimethylamino-ethyl)ether.

Abstract: The present invention relates to an improvement in flexible, semi-flexible and rigid foams formed by the catalytic reaction of an aromatic polyisocyanate, a polyol and a blowing agent and a process for preparing such polyisocyanate. The improvement resides in using an effective amount of a bismuth carboxylate or bismuth sulfonate having less than 34% free acid as the catalyst.

Abstract: A process for preparing a polyurethane foam is provided which comprises reacting a polyisocyanate and an active hydrogen-containing component, including water and an organic polyol, in the presence of a catalytically effective amount of a delayed action amine catalyst system, and optionally an organotin catalyst. The delayed action catalyst is composed of the reaction product of (a) one or more carboxylic acids having hydroxy and/or halo functionality; (b) one or more tertiary amine ureas; and, optionally, (c) a reactant selected from the group consisting of specific reactive tertiary amine(s), specific tertiary amine carbamate(s) and mixture thereof.

Abstract: The present invention relates to a mixture that contains (i) at least one isocyanate and (ii) at least one organic and/or inorganic acid anhydride.

Abstract: Polyurethane article black colorants which comprise a novel blue polymeric anthraquinone colorant, rather than the previous standard polymeric triphenylmethane blue-type colorants are provided. Such a novel blend of colorants to produce black colorations within the target polyurethane foams exhibits very low color degradation within polyurthane foams, primarily due to the stability and resiliency of the novel anthraquinone-based polymeric colorant in the presence of high isocyanate levels, as well as large amounts of reactive tertiary amines (from catalyst residue, for example). A black colorant comprising such a novel blue polymeric colorant, as well as polyurethane foams comprising such a novel black coloring agent and methods of producing such foams are all contemplated within this invention.

Abstract: A process for preparing a polyurethane foam, comprising reacting a polyol having a number-average molecular weight of not less than 1000 and less than 2500 with a polyisocyante compound in the presence of a catalyst and a blowing agent in a mold, to give a molded article having a density of 0.4 to 0.8 g/cm3, and heating the resulting molded article to a temperature of 60° to 100° C. The polyurethane foam is used as a cushioning material such as shoe soles of sports shoes.

Abstract: A method for producing a rigid polyurethane foam, which comprises reacting a polyol with a polyisocyanate in the presence of an amine catalyst and a blowing agent, wherein as the amine catalyst, at least one amine compound having at least one type of substituent selected from the group consisting of a hydroxyl group, a primary amino group and a secondary amino group in its molecule, or N-(2-dimethylaminoethyl)-N′-methylpiperazine, is used, and as the blowing agent, 1,1,1,3,3-pentafluoropropane (HFC-245fa) and/or 1,1,1,3,3-pentafluorobutane (HFC-365mfc) is used.

Abstract: A catalyst for producing a polyurethane, comprising a dialkylaminoalkyl alcohol represented by the formula (I): R1R2N—X—OH  (I) wherein each of R1 and R2 is independently an alkyl group having 1 to 4 carbon atoms; and X is a branched alkylene group having 4 to 8 carbon atoms; a process for producing a polyurethane, comprising reacting a polyol component with an isocyanate component in the presence of the above-mentioned catalyst for producing a polyurethane; and a process for producing a polyurethane foam, comprising reacting a polyol component with an isocyanate component in the presence of the above-mentioned catalyst for producing a polyurethane, and a compound having a primary amino group and a tertiary amino group in its molecule, and a blowing agent.

Abstract: The present invention relates to a method for preparing a polyurethane foam, which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, and a tertiary amino alkyl amide catalyst composition. The catalyst composition is represented by the formula I: wherein R1, R2, R3, R4, R5, R6, A, and n are as defined herein.

Abstract: The present invention relates to a method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, a gelling catalyst, and a tertiary amino alkyl amide catalyst composition. The catalyst composition is represented by the formula I: wherein R1, R2, R3, R4, R5, R6, A, and n are as defined herein.

Abstract: Activators with reduced volatility that are liquid at room temperature are obtained as the reaction product of (A) a secondary amine or primary alcohol having at least one tertiary amine group, (B) a polyisocyanate of the diphenylmethane series having a functionality of from 2.5 to 4.0 and an OH-functional reactive component capable of addition to isocyanate. These activators are useful for the production of polyurethane foams having improved emission behavior.

Abstract: The present invention relates to a method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, and a tertiary amine amide catalyst composition represented by formula (I): wherein A, R1-R6, and n are defined herein.

Abstract: The invention concerns a method for making a polyurethane foam by reacting at least a polyester polyol with at least a polyisocyanate in the presence of a foaming agent and a catalytic agent, such a polyester polyol having been previously obtained by reacting a reactive acid A comprising at least an aliphatic or aromatic polyacid with functionality not less than 2 with at least a polyol P2 with functionality equal to 2 and at least an aliphatic or aromatic polyacid with functionality not less than 2 with at least a polyol P2 with functionality equal to 2 and at least a polyol P3 with functionality not less than 3, being thereafter called AP2P3, wherein the catalytic agent at least partly consists of at least one amine polyester polyol AP2P3, wherein at least part of polyol P3 consists of at least a polyoxyalkylene polyalkanolamine having at least a tertiary amine function, the alkanol radicals of said polyalkanolamine being C1-C6, the alkylene oxide units being C2-C4 and the statistical mean of the number N o

Abstract: The present invention relates to a method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of water as a blowing agent, a cell stabilizer, a gelling catalyst, a blowing catalyst, and a tertiary amino alkyl amide catalyst composition. The catalyst composition is represented by the formula I: wherein R1, R2, R3, R4, R5, R6, A, and n are as defined herein.

Abstract: A solid and/or cellular polyurethane elastomers which are produced using polyester polyols are disclosed. The elastomers which exhibit improved stability to hydrolysis are characterized in that their preparation is carried out in the presence of at least one esters of monobasic carboxylic acid or polybasic carboxylic acids, the (first) dissociation constant (pK) of which is 0.5 to 4.

Abstract: Polyurethane resins are produced by reacting a polyol with a polyisocyanate in the presence of an amine catalyst of one of the formulae:

Abstract: A scorch inhibitor composition for use an additive in the manufacture of polyurethane foams is based on a derivatized phenol, 4-tertbutyl catechol, and optionally, phenothiazine. The derivatized phenol is a di-tert-butyl phenol, preferably a 2,6 tert-butyl phenol substituted at least at the 4-position with an aliphatic, aromatic or aliphatic-aromatic moiety, of C2 or greater. Preferably, the phenol is a liquid, and is chosen from among 2,6 di-tert-butyl-4-isobutyl phenol; 2,6 di-tert-butyl-4-nonyl phenol; and benzenepropanoic acid, 3,5-bis (1,1-dimethyl-ethyl)-4-hydroxy-.C7-C9 branched alkyl esters. The phenol may optionally possess combinations of heteroatoms, such as O, N, P or S, and may be dimerized.

Abstract: Highly resilient polyurethane foams are prepared by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms reactive with isocyanate groups, by a process in which a mixture containing, based in each case on the weight of the mixture, b1) from 5 to 75% by weight of at least one polymer polyol and b2) from 25 to 95% by weight of a mixture containing, based in each case on the weight of the mixture b2), b2i) from 70 to 98% by weight of at least one polyether alcohol having a molecular weight of from 3 500 to 6 500 g/mol, a functionality of less than or equal to 3 and an ethylene oxide content of from 8 to 20% by weight, based on the weight of the polyether alcohol, and b2ii) from 2 to 30% by weight of at least one polyether alcohol having a molecular weight of from greater than 4 000 to 7 000 g/mol, a functionality of from 4 to 8 and an ethylene oxide content of from 5 to 15% by weight, based on the weight of the polyether alcohol, is used as compounds b) having two hydrogen atom

Abstract: A process for preparing a polyurethane foam, especially according to the one-shot foaming process the quasi-prepolymer process and the prepolymer process, by reactions between a polyisocyanate and an active hydrogen-containing component including water and an organic polyol wherein said reactions are conducted in the presence of a reaction product formed by reaction between a tertiary amnine and an aryloxy substituted carboxylic acid.

Abstract: A polyurethane foam or elastomer comprises an organic polyisocyanate component, an active hydrogen-containing component reactive with the polyisocyanate component, wherein the viscosity of this component is less than about 500 cP at room temperature, a catalyst component, a surfactant, and a flame retarding composition. The components may be low VOC. A preferred flame retarding composition comprises an antimony-based compound, a halogenated, active hydrogen-containing component reactive with the polyisocyanate component, and a halogenated flame-retarding agent. Such polyurethanes are useful as gaskets, seals, padding, in automotive applications, and the like.

Abstract: Polyurethane article black colorants which comprise a novel blue polymeric anthraquinone colorant, rather than the previous standard polymeric triphenylmethane blue-type colorants are provided. Such a novel blend of colorants to produce black colorations within the target polyurethane foams exhibits very low color degradation within polyurethane foams, primarily due to the stability and resiliency of the novel anthraquinone-based polymeric colorant in the presence of high isocyanate levels, as well as large amounts of reactive tertiary amines (from catalyst residue, for example). A black colorant comprising such a novel blue polymeric colorant, as well as polyurethane foams comprising such a novel black coloring agent and methods of producing such foams are all contemplated within this invention.

Abstract: The present invention relates to a catalyst system for the production of polyurethane comprising catalysts for polyurethane formation and sterically hindered carbodiimides, which system is capable of lessening the “fogging” problem in the production of polyurethane materials, without impairing in particular the aging properties of the polyurethane materials thus produced.

Abstract: A process for the synthesis of polyurethanes is disclosed wherein the process comprises reacting polyurethane-forming reactants in the presence of an effective amount of a catalyst comprising at least one alkylamino oxainide of the structure: wherein: R1 and R2 are independently selected alkyl groups or can be taken together to form a five or six-membered heterocyclic ring; R3 and R4 are independently selected from the group consisting of hydrogen and alkyl; n is 2 or 3; x is 0 or 1; Y is selected from the group consisting of O and NR9,  wherein: R9 is selected from the group consisting of hydrogen and alkyl; and X is selected from the group consisting of OR10 and G,  wherein: R10 is selected from the group consisting of hydrogen and alkyl; and G is

Abstract: A catalyst composition for the production of a polyurethane resin, which comprises an amine compound of the following formula (1): wherein each of R1 and R2 which are independent of each other, is a C1-4 alkyl group, such alkyl groups bonded to each other directly or via a nitrogen atom or an oxygen atom to form a ring structure, a dimethylaminopropyl group or a diethylaminopropyl group, and R3 is a C2-16 straight chain or branched chain alkylene group, and an amine compound of the following formula (2): wherein each of R4 and R5 which are independent of each other, is a C1-4 alkyl group, such alkyl groups bonded to each other directly or via a nitrogen atom or an oxygen atom to form a ring structure, a dimethylaminopropyl group or a diethylaminopropyl group, R6 is a C2-16 straight chain or branched chain alkylene group, R7 is a C2-3 straight chain or branched chain alkylene group, and n is an integer of from 0 to 2.

Abstract: The invention provides polyurethane elastomers (PU elastomers), a process for their production using special catalyst mixtures and their use in particular for the manufacture of shoe soles.

Abstract: A method for making an energy-absorbing foam having a density that is less than about 7 pcf that exhibits excellent strength properties and that is particularly suitable for automobile bumper applications. The invention is also directed to the energy-absorbing foam made with the method.

Abstract: Low-density hydrophilic flexible polyurethane foams are prepared by reacting organic and/or modified organic polyisocyanates (a) with a polyetherol mixture (b) and, if required, further compounds (c) having hydrogen atoms reactive toward isocyanates, in the presence of water and/or other blowing agents (d), catalysts (e) and, if required, further assistants and additives (f), by a process in which the polyetherol mixture (b) consists of b1) at least one difunctional or polyfunctional polyetherol based on propylene oxide and/or butylene oxide and ethylene oxide, having an ethylene oxide content of more than 40% by weight, based on the total amount of alkylene oxide used, an OH number of from 20 to 120 mg KOH/g and a proportion of primary OH groups of more than 20% and b2) at least one difunctional or polyfunctional polyetherol based on propylene oxide and/or butylene oxide and, if required, ethylene oxide, the ethylene oxide content being not more than 40% by weight, and having an OH number of more than 25 m

Abstract: In a process for producing flexible polyurethane foams by the reaction known per se of polyisocyanates with compounds containing at least two hydrogen atoms which react with isocyanate, the reaction is carried out in the presence of cyclic or heterocyclic compounds containing at least one reactive hydrogen atom.

Abstract: To provide a type of phenol foam characterized by the fact that the phenol foam is formed by using a hydrocarbon as the foaming agent. The phenol foam has excellent heat-insulating performance, high compressive strength and other mechanical strengths, improved brittleness and is friendly to the environment of the earth.

Abstract: The invention relates to a process for preparing polyurethane foams (PUR foams) which uses reactive amines of the formula where n is 1 to 4, R1 and R2 are —(CH2—CH2—O)xH, —(CH2—CH(CH3)—O)xH, or —((CH2—CH(CH2—CH3)—O)xH, and x is 0, 1, 2, 3 or 4, with the proviso that, at least one of the indices in the molecule is greater than 0, in combination with metal salts.

Abstract: There is disclosed an elastic member constituted of polyurethane foam obtained by agitationally mixing with water, a urethane prepolymer synthesized from a polyol and a polyisocyanate, characterized by simultaneously employing as polyols, a (A) polymer polyol synthesized from a polyether polyol as a basis, comprising at least 70% by weight of oxypropylene moiety; and a (B) hydrophilic polyether polyol comprising at least 50% by weight of oxyethylene moiety, or simultaneously employing as polyols, the component (A), the component (B) and a (C) polyether polyol comprising at least 70% by weight of oxypropylene moiety. The above elastic member is simultaneously imparted with excellent characteristics such as low hardness, fine cells, low residual compressive strain, high strength and the like. The polyurethane foam which constitutes the elastic member can be produced by free foaming.

Abstract: Provided are catalyst systems which produce flexible polyurethane polyester foams that are color stable, are lower in odor, and uses less catalysts than current most commonly practiced technology. The use of lower amounts of catalysts with low vapor pressure reduces worker exposure to alkaline corrosive materials, reduces pollution through less pounds of volatile organic chemicals (VOC's) and is less expensive.

Abstract: New, useful and surprisingly effective antiscorch compositions for utilization within polyurethane foam production methods which utilize very popular tertiary amine catalysts are provided. Such compositions require the presence of nominal yet effective amounts of organic cyclic ester materials. The ring systems of such materials appear to open during exposure to heat (during the curing process) and release carboxylic acids into the curing formulation. The tertiary amines become quenched by the carboxylic acids and thus do not exhibit heat destabilization. The resultant foams exhibit extremely low, if no, areas of excessive heating (i.e., scorch) and thus are substantially uniformly colored throughout. The processes and resultant foams are also contemplated within this invention.

Abstract: Novel acid-blocked amine catalysts and their use in the preparation of polyurethanes. The acid-blocked amine catalysts have the general structure shown below: wherein A is the residue of an organic acid anhydride; R1 is H or C1 to C6 alkyl; R2 is H or C1 to C6 alkyl; n is an integer of 0 to 10; and B is a compound containing a protonated amine and one or more primary amine, secondary amine, or tertiary amine groups.

Abstract: A thermosetting plastic foam solid formed from the reaction product of: (a) either polyisocyanate or isocyanate-based foam; (b) a polyol-based foam; (c) a catalyst which is capable of promoting the thermosetting reaction between the polyisocyanate or isocyanate-based foam and the polyol-based foam; and (d) a blowing agent which comprises a high purity cyclopentane product, wherein the high purity cyclopentane product is about 95% or greater pure cyclopentane, and, optionally, (e) water and/or (f) liquid flame retardant.

Abstract: Carbamate solutions are obtainable by reacting at least one alkanolamine with carbon dioxide in, as solvent, at least one organic compound having a molecular weight of from 60 to 600 and containing at least one hydroxyl group, wherein the carbamate contains at least 0.

Abstract: A process including preparing a polyurethane in the presence of a catalyst which is a bicyclic amidine of the formula: wherein A is selected from the group consisting of —CR1R2—CR3R4—CR5R6—, —CR1R2—CR3R4—CR5R6—CR7R8—, and —CR1R2—CR3R4—CR5R6—CR7R8—CR9R10—, wherein the substituents in A are in each case numbered starting from the nitrogen atom, and B is selected from the group consisting of —CR11R12—CR13R14—, —CR11R12—CR15R16—CR13R14—, and —CR11R12—CR15R16—CR17R18—CR13R14—, and R1 to R18 are, in each case independent of one another, hydrogen, C1-C4-alkyl, aryl, or C1-C4-alkyl that is substituted with hydroxyl, amino, C1-C4-alkylamino or mercapto, with the proviso that at least one of the substituents R1 to R18 is (1) hydroxyl, (2) amino, (3) C1-C4-alkylamino, (4) mercapto, (5) C1-C4-alkyl substituted with hydroxyl, (6) C1-C4-alkyl sub

Abstract: Provided herein are catalyst systems useful for providing polyurethane foam products which exhibit low fogging characteristics while possessing favorable overall physical properties when used as interior components of automobiles and other motorized vehicles.

Abstract: Open-cell rigid foams containing urethane and/or isocyanurate and/or urea groups are produced with a long-chain polyether polyol having low double bond content.

Abstract: Process for the preparation of open celled rigid polyurethane or urethane-modified polyisocyanurate foams by reaction of a polyfunctional isocyanate-reactive composition with a polyisocyanate composition comprising a prepolymer of NCO-value 21-30% based on a high molecular weight oxyethylene-containing polyol.

Abstract: An improved process to enhance polyurethane foam performance is described. Polyurethane foam is prepared by reactions between a polyisocyanate and an active hydrogen-containing component wherein said reactions are conducted in the presence of catalysts composed of (a) at least one specific tertiary amine carbamate (formed by the reaction of reactive tertiary amine and polyisocyanate) and, optionally, (b) salts formed by the reaction between the specific tertiary amine carbamate(s) and hydroxy- and/or halo-carboxylic acids. The specific tertiary amine carbamates in the subject invention are dimethylaminoethoxyethyl carbamate, bis(dimethylaminopropyl)amino-2-propyl carbamate, dimethylaminoethyl carbamate, and mixtures thereof.

Abstract: A co-initiated polyether polyol is produced by suspending a solid polyhydroxyl compound in an amine-initiated polyol, heating the suspension and alkoxylating the heated suspension. These co-initiated polyether polyols are particularly useful for the production of polyurethanes.

Abstract: Polyurethane foams formed under vacuum (below atmospheric pressure) conditions using a specific mixture of polyisocyanate and with a major portion of methylene diisocyanate (MDI) and a specific mixture of polyether and graft polyols exhibit superb static shock cushioning characteristics (energy absorption) as illustrated by drop curves of deceleration versus static load. The foam-forming ingredients are mixed together and foamed under controlled pressures in the range 0.5 to 0.90 bar (absolute), preferably 0.5 to 0.8 bar (absolute). A major portion of the MDI is 4, 4′ methylene diisocyanate.

Abstract: A process for producing a polyurethane foam comprising reacting a polyol component with an isocyanate component in the presence of a catalyst comprising a compound represented by the formula (I): wherein p is an integer of 4 to 8, and a compound having a primary amino group and a tertiary amino group in its molecule, a blowing agent and a surfactant. The polyurethane foam obtained by the process of the present invention can be suitably used for heat insulating materials for construction materials, electric refrigerators, refrigerated warehouses, baths and the like, interior materials for automobiles, and the like.

Abstract: The invention relates to the combined use of metal salts of ricinoleic acid with reactive amines in the preparation of polyurethane foams (PUR foams) and of their solutions in aqueous or organic solvents in the preparation of polyurethane foams in combination with reactive amines.

Abstract: A process for preparing a polyurethane foam, especially according to the one-shot foaming process, the quasi-prepolymer process and the prepolymer process by reactions between a polyisocyanate and an active hydrogen-containing component including water and an organic polyol wherein said reactions are conducted in the presence of a reaction product formed by reaction between a tertiary amine and a carboxylic acid having halo functionality and optional hydroxyl functionality.

Abstract: New, useful and surprisingly effective polymeric triphenylmethane colorant-containing compositions which exhibit very low color degradation within polyurethane foams. Generally during polyurethane foam production, certain amine-based hydroxyl-group containing catalysts deleteriously attack the nitrogen linking groups within triphenylmethane polymeric colorants. Such compositions require the presence of nominal yet effective amounts of organic cyclic ester materials. The ring systems of such materials appear to open during exposure to heat (during the foaming procedure) and release carboxylic acids into the foaming formulation. The tertiary amines become quenched by the carboxylic acids and thus do not exhibit degradation of the TPM-based chromophore. The resultant foams exhibit substantially uniform color throughout. The processes and resultant foams are also contemplated within this invention.

Abstract: An improved process to enhance polyurethane foam performance is described. Polyurethane foam is prepared by reactions between a polyisocyanate and a polyfunctional isocyanate-reactive component wherein said reactions are conducted in the presence of catalysts composed of (a) a specific reactive tertiary amine compound selected from the group consisting of bis(dimethylaminopropyl)amino-2-propanol, bis(dimethylaminopropyl)amine, dimethylaminopropyldipropanolamine, bis(dimethylamino)-2-propanol, N,N,N′-trimethyl-N′-hydroxyethyl-bis(aminoethyl)ether and mixtures thereof; and (b) at least one carboxylic acid salt of the specific reactive tertiary amine compound selected from the group consisting of hydroxy-carboxylic acid salts and halo-carboxylic acid salts.

Abstract: The use of 3-[3-(dimethylamino)propyl]-propionamide (Formula I) and 3,3′-{[3-(dimethylamino)propyl]imino}bis-propanamide (Formula II) as catalysts in the production of polyurethanes. The use of 3-{[3-(dimethylamino)propyl]amino}-propionamide (Formula I) and 3,3′-{[3-(dimethylamino)propyl]imino}bis-propanamide (Formula II) as catalysts in the production of polyurethanes.

Abstract: The present invention relates to a process for preparing polyisocyanate polyaddition products by reacting (a) polyisocyanates with (b) relatively high molecular weight compounds containing at least two isocyanate-reactive hydrogen atoms and (c) chain-extending agents, in the presence of (d) N-(aminoalkyl)pyrrolidine catalysts corresponding to formula (I) in which R is a C2-12 alkylene group (optionally containing O or N atoms but not isocyanate-reactive groups) and R′ is hydrogen or a C1-4 alkyl group, (e) optionally, other known catalysts, and (f) other known additives.