At Least One Polymer Is Derived From A Polycarboxylic Acid Or Derivative And A Polyol Or Wherein The Polymer-forming System Containing The Same Type Of Reactants Patents (Class 521/138)
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Patent number: 11034813Abstract: A variety of foams and foam components are provided, including foam components for articles of footwear and athletic equipment. The articles include a composition having a foam structure, wherein the composition includes a thermoplastic copolyester elastomer comprising: (a) a plurality of first segments, each first segment derived from a dihydroxy-terminated polydiol; (b) a plurality of second segments, each second segment derived from a diol; and (c) a plurality of third segments, each third segment derived from an aromatic dicarboxylic acid. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including at least one of the foam components. In some aspects, the foams and foam components can be made by extrusion or injection molding to foam the polymeric composition, or extrusion or injection molding to foam the polymeric composition followed by compression molding of the foam.Type: GrantFiled: March 12, 2019Date of Patent: June 15, 2021Assignee: NIKE, Inc.Inventor: Hossein A. Baghdadi
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Patent number: 10865339Abstract: A coated particulate composition includes a vitreous polyphosphate glass particulate and a coating on at least a portion of the surface of the particulate, the coating comprising a water-insoluble polymer or a water-insoluble particulate, wherein the coating weight is about 0.01 wt % to 90 wt % of the mass of the coated particulate. The particulates provide long-term scale inhibition downhole in subterranean reservoirs where temperatures exceed 70° C.Type: GrantFiled: May 12, 2017Date of Patent: December 15, 2020Assignee: CHAMPIONX USA INC.Inventors: Daniel R. Dreyer, Pious V. Kurian
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Patent number: 10563011Abstract: A dual curable composition is provided, comprising a compound represented by formula (I): (acrylate)a-(A)-(silane)b??(I) in which a and b are identical or different and are each represented by an integer greater than or equal to 1; and wherein the dual curable composition is radiation curable and/or moisture curable. The moiety A comprises at least one of an aliphatic hydrocarbon, a cycloaliphatic hydrocarbon, an aryl moiety, an ether, an ester, an amide, a urethane, a urea, a hydroxyl group-containing organic moiety, an acrylic oligomer, an epoxy oligomer, a urethane oligomer, a polyester oligomer, or mixtures thereof, and the dual curable composition has a molecular weight greater than or equal to 300.Type: GrantFiled: March 14, 2014Date of Patent: February 18, 2020Inventor: Benedict S. Curatolo
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Patent number: 10377872Abstract: The present invention provides a foamable resin composition excellent in terms of the dispersibility and moldability. The foamable resin composition containing: from 30 to 80 wt % of a polyolefin; from 3 to 40 wt % of a polylactic acid; from 1 to 20 wt % of a modified polyolefin containing a carbonyl group in a molecule; from 10 to 40 wt % of a layered silicate; and from 0.01 to 0.5 wt % of a filler, the polyolefin containing at least one of polypropylene and polyethylene, the filler having a density different from the density of the layered silicate by at least 0.20 g/cm3.Type: GrantFiled: March 3, 2016Date of Patent: August 13, 2019Assignee: Bando Chemical Industries, Ltd.Inventors: Tomohito Ichiki, Saki Jindai
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Patent number: 9815964Abstract: The present invention relates to a polyester resin for extrusion blow molded containers comprising a branched copolymer and fumed silica to improve the aged drop performance said branched copolyester is made from the reaction of purified terephthalic acid or its dimethyl ester, ethylene glycol, bifunctional diacid other than terephthalic acid, diol other than ethylene glycol, and multifunctional compound having a least 3 carboxyl groups, hydroxyl groups and/or ester forming groups thereof, said fumed silica has a particle size of 0.1 to 5 microns and is present at about 100 ppm to about 2,500 ppm based on the weight of said copolyester.Type: GrantFiled: October 28, 2014Date of Patent: November 14, 2017Assignee: Auriga Polymers, Inc.Inventors: K. Prasanna U. Perera, Geoffrey R. Scantlebury
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Patent number: 9796842Abstract: Polystyrene blends and methods of making polystyrene blends including combining a styrene monomer and an epoxy-functional comonomer to form a combined mixture, subjecting the combined mixture to polymerization to obtain a polystyrene copolymer and combining the polystyrene copolymer with a biodegradable polymer to obtain a polystyrene blend.Type: GrantFiled: April 16, 2015Date of Patent: October 24, 2017Assignee: FINA TECHNOLOGY, INC.Inventors: Wei Wang, David W. Knoeppel, Fengkui Li, Jose M. Sosa
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Patent number: 9441105Abstract: There are disclosed a biodegradable resin composition including a starch (a1), a biodegradable resin (a2) other than a polylactic acid-based polymer and a non-crystalline polylactic acid-based polymer (b), a mass ratio of the starch (a1) to the biodegradable resin (a2) other than a polylactic acid-based polymer (a1/a2) being from 20/80 to 50/50, and a mass ratio of a sum of the components other than the polymer (b) to the polymer (b) (sum of components other than polymer (b)/polymer (b)) being from 95/5 to 50/50, and a biodegradable film using the biodegradable resin composition.Type: GrantFiled: November 5, 2012Date of Patent: September 13, 2016Assignee: SHOWA DENKO K.K.Inventors: Yasushi Ichikawa, Hideharu Kimura, Yuuki Tetsuka
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Patent number: 9416240Abstract: A low-wear microporous friction material with a high stability coefficient and a manufacturing method thereof are provided. The formula of the friction material includes GM-15 resin 15-50 wt %, rubber 0-10 wt %, shaping aid 0.5-5 wt %, sintering aid 0.5-5 wt %, foaming aid 0.5-5 wt %, kaolin powder 0.5-20 wt %, barite powder 5-40 wt %, carbon fiber 2-20 wt %, KEVLAR 1-5 wt %, zinc oxide 1-10 wt %, and iron oxide red 0-2 wt %. By adjusting the hydrophilicity of the friction material and controlling the surface tension of the material, the friction coefficient of the material is kept from lowering under wet conditions and is rendered stable in dry and wet conditions. More specifically, the friction coefficient of the friction material stays above 0.25 under wet conditions, and the stability coefficient of the friction coefficient can reach 85% or above on an MM 1000 tester.Type: GrantFiled: October 11, 2012Date of Patent: August 16, 2016Assignee: SHANGHAI REINPHEN COMPOSITE MATERIALS CO., LTDInventor: Ding Quan Zhang
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Publication number: 20150147929Abstract: Compositions of biobased polymer blends of polymers of polybutylene succinate (PBS) or polybutylene-adipate-terephthalate (PBAT) and a polyhydroxyalkanoate copolymer are described. In certain embodiments, the copolymer is a multiphase copolymer blend having one phase a glass transition temperature of about ?5° C. to about ?50° C. Methods of making the compositions of the invention are also described. The invention also includes articles, films and laminates comprising the compositions.Type: ApplicationFiled: June 5, 2013Publication date: May 28, 2015Inventors: Rajendra K. Krishnaswamy, Johan van Walsem, Oliver P. Peoples, Yossef Shabtai, Allen R. Padwa
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Publication number: 20150140315Abstract: A resin foam having excellent dustproofness not only at ordinary temperatures but also particularly at high temperatures as well as having excellent flexibility. The resin foam has a thickness recovery ratio at high temperatures as defined below of not less than 25%, an average cell diameter of 10 to 200 ?m, and a maximum cell diameter of not more than 300 ?m, wherein the thickness recovery ratio at high temperatures is defined as follows: a resin foam in a sheet form is compressed, in an atmosphere of 80° C., for 22 hours in a thickness direction so as to have a thickness of 20% of the initial thickness; then, the compression state is released in an atmosphere of 23° C.; and a ratio of a thickness 24 hours after the release of the compression state to the initial thickness is defined as the thickness recovery ratio at high temperatures.Type: ApplicationFiled: May 21, 2013Publication date: May 21, 2015Applicant: NITTO DENKO CORPORATIONInventors: Kazumichi Kato, Makoto Saitou, Kiyoaki Kodama
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Publication number: 20150119481Abstract: There are provided a resin composition for foaming including a biodegradable resin and a foamed article made thereof. The resin composition for foaming according to the present invention includes an ethylene-vinyl acetate resin, a biodegradable polyester resin containing a monomer of a double bond compound, a cross-linking agent, a co-crosslinking agent, a filler, and a foaming agent. In the resin composition, the double bond in the biodegradable polyester resin can be chemically cross-linked to the ethylene-vinyl acetate resin by a cross-linking agent, so that a compatibility with the ethylene-vinyl acetate resin can be improved, processability (mold releasability) during a mixing and melting process can be improved, and a foaming property and a mechanical property of a foamed article can be remarkably improved.Type: ApplicationFiled: May 13, 2013Publication date: April 30, 2015Applicant: SAMSUNG FINE CHEMCIALS CO., LTD.Inventors: Jong Pil Chun, Hee Soo Kim, Soo Youn Choi, Ye Jin Kim, Ki Chull Yun, Min Kyoung Kim
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Patent number: 9000061Abstract: The present invention relates to poured-in place polyurethane foams and polyol premixes comprising 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd) and one or more additional co-blowing agents.Type: GrantFiled: July 26, 2011Date of Patent: April 7, 2015Assignee: Honeywell International Inc.Inventors: Yiu Keung Ling, David J Williams
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Publication number: 20150065591Abstract: The present disclosure provides a modified starch composition. The modified starch composition includes starch with a terminal siloxane having 100 parts by weight, water having 30-70 parts by weight, and a polyol having 5-35 parts by weight. The present disclosure also provides a starch composite foam material and method for preparing the same.Type: ApplicationFiled: July 11, 2014Publication date: March 5, 2015Inventors: Sheng-Ju LIAO, Chih-Jen CHANG, Yen-Po LIU, Shihn-Juh LIOU, Yao-Chu CHUNG, Chien-Ming CHEN
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Patent number: 8961879Abstract: The invention relates to curable compositions which are prepared from polyol components containing one or more polyols and isocyanate components containing one or more isocyanates, which compositions contain at least one indicator having at least one quinonoid group, which indicator signifies the degree of curing by a change of color. The invention also relates to a method for indicating the progress of curing in such curable compositions.Type: GrantFiled: March 19, 2009Date of Patent: February 24, 2015Assignee: Mankiewicz Gebr. & Co. GmbH & Co. KGInventors: Guenther John, Stefanie Ehmke (nee Behrens Brammertz)
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Publication number: 20150051308Abstract: Provided are a polymethylpentene conjugate fiber, which is capable of imparting to a lightweight polymethylpentene fiber an ability to develop a vivid and deep color, and a porous polymethylpentene fiber, which has a lightweight, a high pore diameter uniformity and a high porosity retention ratio against an external force, said polymethylpentene conjugate fiber and said porous polymethylpentene fiber being appropriately usable as a fiber structure for woven knitted goods, non-woven fabrics, yarns, cotton waddings, etc. The polymethylpentene conjugate fiber is characterized by having an island-in-sea structure wherein the sea component comprises a polymethylpentene-based resin and the island component comprises a thermoplastic resin. The porous polymethylpentene fiber, which comprises a polymethylpentene-based resin, is characterized in that the coefficient of variation (CV) of pore diameter at the fiber cross section is 1-50%.Type: ApplicationFiled: March 7, 2013Publication date: February 19, 2015Applicant: TORAY INDUSTRIES, INC.Inventors: Hidekazu Kano, Shogo Hamanaka, Yoshitaka Aranishi
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Publication number: 20150037559Abstract: Pressure-sensitive adhesive having high bond strengths to polar substrates as well as to non-polar substrates, comprising: a) 30-65 wt %, based on the total weight of the adhesive, of at least one poly(meth)acrylate; b) 5-20 wt %, based on the total weight of the adhesive, of at least one synthetic rubber; c) at least one tackifier compatible with the poly(meth)acrylate(s); and d) at least one hydrocarbon resin compatible with the synthetic rubber(s), and adhesive tape comprising at least one layer of the pressure-sensitive adhesive.Type: ApplicationFiled: July 29, 2014Publication date: February 5, 2015Inventors: Thilo DOLLASE, Anika PETERSEN, Thorsten KRAWINKEL, Axel BURMEISTER, Michael MAYER
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Publication number: 20150025163Abstract: The present invention is directed to a polyalkylene carbonate resin composition for producing a decorating material and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom. More particularly, the invention is directed to polyalkylene carbonate resin composition for producing a decorating material in which including a polymer additive to impart heat resistance and shape stability to the decorating material, a crosslinker and a chain extender to improve the processability at the processing temperature, and a flame retardant agent to impart a flame retardant effect, and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom. The environment-friendly polyalkylene carbonate resin decorating material produced using the inventive composition has excellent thermal stability, processability, and dimensional stability.Type: ApplicationFiled: May 28, 2014Publication date: January 22, 2015Applicant: SK INNOVATION CO., LTD.Inventors: Younghyo Park, Inhun Son, Kangmin Jung, Jaekoo Kim, Kwangjin Chung, Myungahn Ok
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Patent number: 8937135Abstract: The present invention relates to biodegradable polymer mixtures comprising i) 40% to 95% by weight, based on the total weight of components i to ii, of at least one polyester based on aliphatic or aliphatic and aromatic dicarboxylic acids and aliphatic dihydroxy compounds; ii) 5% to 60% by weight, based on the total weight of said components i to ii, of polyalkylene carbonate, particularly polypropylene carbonate; iii) 0% to 60% by weight, based on the total weight of said components i to iii, of at least one biodegradable homo- or copolyester selected from the group consisting of polylactic acid, polycaprolactone and polyhydroxyalkanoate, and/or of an inorganic or organic filler; iv) 0% to 10% by weight, based on the total weight of said components i to ii, of an epoxy-containing copolymer based on styrene, acrylic ester and/or methacrylic ester, and v) 0% to 15% by weight of an additive selected from the group consisting of lubricant, antiblocking agent, antistat, UV absorber, UV stabilizer, thermal stabilType: GrantFiled: September 21, 2009Date of Patent: January 20, 2015Assignee: BASF SEInventors: Tobias Heinz Steinke, Hans-Helmut Görtz, Jürgen Ahlers, Freddy Gruber, Gabriel Skupin
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Publication number: 20140357748Abstract: An object of the present invention is to provide a polycarbonate resin composition comprising a polycarbonate resin containing, as a raw material, isosorbide that is easy to produce and excellent in such as mechanical properties, etc., and a molded body, particularly a foam-molded body, composed of the resin composition. The present invention provides a foam-molded body of a resin composition containing a polycarbonate resin having at least a structural unit derived from a dihydroxy compound represented by the following formula (1): wherein the strain-hardening factor of uniaxial extensional viscosity of said resin composition is from 0.1 to 5.Type: ApplicationFiled: August 20, 2014Publication date: December 4, 2014Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Katsushi YAMAOKA, Toru Takashima
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Publication number: 20140350135Abstract: Embodiments relate to an additive for a biopolymer article, where the additive includes at least one impact modifier between 50-75 weight % of the total weight of the additive; and at least one aliphatic-aromatic polyester polymer between 10-25 weight % of the total weight of the additive and compounded in a carrier resin, where the carrier resin is between 10-25 weight % of the total weight of the additive.Type: ApplicationFiled: May 19, 2014Publication date: November 27, 2014Applicant: Clear Lam Packaging, Inc.Inventors: Paul Georgelos, JEANNE SKAGGS, PAT MONTEFUSCO, BOHDAN WYSLOTSKY
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Patent number: 8877223Abstract: The present application discloses biodegradable polymers, to porous and other materials comprising such polymers, and to various medical uses of such materials, including use as a scaffold for supporting cell adhesion or the in-growth for regeneration of tissue. The polymer is of the formula A-O—(CHR1CHR2O)n—B wherein A is a poly(lactide-co-glycolide) residue, the molar ratio of (i) lactide units [—CH(CH3)—COO—] and (ii) glycolide units [—CH2—COO—] in the poly(lactide-co-glycolide) residue being in the range of 80:20 to 10:90, B is either a poly(lactide-co-glycolide) residue or hydrogen, C1-6-alkyl or hydroxy protecting groups, one of R1 and R2 is hydrogen or methyl, and the other is hydrogen, n is 10-1000, the molar ratio of (iii) polyalkylene glycol units [—(CHR1CHR2O)—] to the combined amount of (i) lactide units and (ii) glycolide units in the poly(lactide-co-glycolide) residue(s) is at the most 14:86, and the molecular weight of the copolymer is at least 20,000 g/mol.Type: GrantFiled: March 7, 2007Date of Patent: November 4, 2014Assignee: Coloplast A/SInventors: Jakob Vange, Khadija Schwach-Abdellaoui, Hanne Everland, Peter Sylvest Nielsen, Brian Nielsen, Lene Karin Jespersen, Lene Feldskov Nielsen
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Publication number: 20140316022Abstract: Disclosed are an optical film and a preparation method thereof. The optical film comprises a base layer, a plurality of polymer particles disposed in the base layer, and voids formed in the base layer and enclosing the respective polymer particles, wherein the polymer particles comprise a crosslinked polymer. The optical film has uniform voids, enhanced processing and dimensional stabilities, as well as improved optical properties such as whiteness, hiding power, reflectance and the like. Thus, the optical film can be useful for a reflector sheet for a BLU of an LCD device, and the like.Type: ApplicationFiled: August 31, 2012Publication date: October 23, 2014Applicant: SKC CO., LTD.Inventors: Kweon Hyung Han, Seong Do Kim, Heon Jung Shin, Hyung Suk Pak
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Publication number: 20140265053Abstract: Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive that is a cross-linkable polycarbonate resin containing a photoactive group derived from a dihydroxybenzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: SABIC Innovative Plastics IP B.V.Inventors: Jean-Francois Morizur, Paul Dean Sybert
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Publication number: 20140255636Abstract: Disclosed are blended polymeric membranes that include at least a first polymer and a second polymer that is UV treated, wherein the first and second polymers are each selected from the group consisting of a polymer of intrinsic microporosity (PIM), a polyetherimide (PEI) polymer, a polyimide (PI) polymer, and a polyetherimide-siloxane (PEI-Si) polymer.Type: ApplicationFiled: February 28, 2014Publication date: September 11, 2014Applicant: SAUDI BASIC INDUSTRIES CORPORATIONInventors: Ihab Nizar Odeh, Lei Shao
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Patent number: 8822584Abstract: Compositions comprising linear polyhydroxyalkanoates and biodegradable aromatic/aliphatic polyesters are disclosed, as well as methods for using same, and articles made therefrom.Type: GrantFiled: May 6, 2009Date of Patent: September 2, 2014Assignee: Metabolix, Inc.Inventor: Robert S. Whitehouse
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Publication number: 20140235740Abstract: A significant disadvantage of the use of polylactic acid (PLA), lack of good heat stability, has been overcome by the use of talc, optionally in combination with an acrylic impact modifier. The compound achieves a threshold of 100° C. in heat deflection temperature.Type: ApplicationFiled: August 23, 2012Publication date: August 21, 2014Applicant: POLYONE CORPORATOINInventor: Jing Liu
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Publication number: 20140170406Abstract: A resin foam has a thickness recovery rate (23° C., one minute, 50% compression) of 70% or more and a strain recovery rate (80° C., 24 hours, 50% compression) of 80% or more. The thickness recovery rate is determined by compressing the resin foam, holding the resin foam in the compressed state, decompressing the resin foam, measuring a thickness of the resin foam one second after the decompression, and calculating a percentage of the measured thickness with respect to the initial thickness as the thickness recovery rate. The strain recovery rate is determined by compressing the resin foam, holding the resin foam in the compressed state, returning the resin foam to 23° C. while maintaining the compressed state, decompressing the resin foam, and determining a percentage of a recovered distance with respect to a compressed distance as the strain recovery rate.Type: ApplicationFiled: July 24, 2012Publication date: June 19, 2014Applicant: NITTO DENKO CORPORATIONInventors: Hironori Yasuda, Mitsuhiro Kanada, Yoshinori Kouno, Mie Ota, Yuko Kandori
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Publication number: 20140155507Abstract: Provided is a resin foam that is satisfactorily flexible and highly resistant to heat, exhibits superior strain recoverability at high temperatures, and has a high instantaneous recovery rate. This resin foam is formed from a resin composition containing an acrylic polymer, an active-energy-ray-curable compound having two (meth)acryloyl groups per molecule, an active-energy-ray-curable compound having three or more (meth)acryloyl groups per molecule, and a thermal crosslinking agent. The active-energy-ray-curable compound having two (meth)acryloyl groups per molecule and the active-energy-ray-curable compound having three or more (meth)acryloyl groups per molecule are preferably contained in a total content of from 20 to 150 parts by weight per 100 parts by weight of the acrylic polymer.Type: ApplicationFiled: July 24, 2012Publication date: June 5, 2014Applicant: NITTO DENKO CORPORATIONInventors: Mitsuhiro Kanada, Mie OTA, Yoshinori Kouno, Hironori Yasuda, Yuko Kandori
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Patent number: 8735459Abstract: Provided are a composition for preparing expandable polypropylene carbonate and an expandable polypropylene carbonate prepared therefrom, and more particularly, to a composition for preparing expandable polypropylene carbonate capable of using supercritical carbon dioxide as a foaming agent and producing a foam having excellent moldability by using an appropriate foaming method. By using the composition according to the present invention, highly magnificated expandable polypropylene carbonate capable of having excellent thermal stability and dimensional stability can be prepared.Type: GrantFiled: October 10, 2011Date of Patent: May 27, 2014Assignee: SK Innovations Co., Ltd.Inventors: Minho Jeon, Younghyo Park, Kwangjin Chung, Myungahn Ok
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Patent number: 8691883Abstract: An aerogel-foam composite includes an open cell foam and an aerogel matrix polymer disposed in the open cell foam. The aerogel-foam composite has compression strength of about 15 megaPascals (MPa) or more. The open cell foam may be a polyurethane foam including a carbonate group (—OC(O)O—).Type: GrantFiled: June 21, 2011Date of Patent: April 8, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Myung-Dong Cho, Sang-Ho Park, Kwang-Hee Kim, Sung-Woo Hwang
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Patent number: 8664286Abstract: To provide a vibration damping composition: excellent in vibration damping property and thermal drying property in a wide temperature range; and sufficiently suppressing sagging of a vibration damping coating film on the vertical surface; and therefore useful for vibration damping materials of various structures. A vibration damping composition comprising an emulsion for vibration damping materials, a foaming agent, and an inorganic pigment, wherein the emulsion for vibration damping materials comprises a particle having a core part formed from an acrylic copolymer (A) and a shell part formed from an acrylic copolymer (B), and at least one of the acrylic copolymers (A) and (B) is prepared by copolymerizing a monomer component comprising methacrylic acid.Type: GrantFiled: September 19, 2006Date of Patent: March 4, 2014Assignees: Nippon Shokubai Co., Ltd., Nihon Tokushu Toryo Co., Ltd.Inventors: Yoshihiko Yasui, Hiroshi Suzuki, Dai Nagaishi
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Patent number: 8575296Abstract: A polyester article is made to appear lustrously metallic or pearlescent by the addition of polymethylpentene and non-metallic, non-pearlescent colorant; and optionally other functional additives. The colorant can be one or more pigments, one or more dyes, or combination thereof. A stretch blow molded plastic article, such as a bottle, using the polymethylpentene in the polyester can simulate the appearance of a metallic surface or a pearlescent luster even though non-metallic and non-pearlescent colorants are used.Type: GrantFiled: September 29, 2009Date of Patent: November 5, 2013Assignee: PolyOne CorporationInventors: Gary Vernon, David Rosendale
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Publication number: 20130281560Abstract: This invention relates to a polymer composition comprising at least two polyesters having improved mechanical properties, in particular a good balance between ultimate tensile strength, elastic modulus and elongation on failure. This composition is particularly suitable for the production of manufactured articles such as for example films, moulded objects, thermoformed objects or expanded articles.Type: ApplicationFiled: December 22, 2011Publication date: October 24, 2013Applicant: Novamont S.p.A.Inventors: Catia Bastioli, Luigi Capuzzi, Tiziana Milizia, Roberto Vallero
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Patent number: 8557885Abstract: The present invention relates to an extruded thermoplastic resin foam, particularly relates to a board extruded thermoplastic resin which has low heat conductivity, an excellent heat insulating property over a long period of time, high flame retardancy, and excellent mechanical strength. The extruded thermoplastic resin foam having an apparent density of 20 to 50 kg/m3, a closed cells ratio of 85% or more and a thickness of 10 to 150 mm, and containing a non-halogen organic physical blowing agent, wherein the thermoplastic resin composing the extruded foam contains a mixture of 100 parts by weight of a polystyrene resin (A) and 5 to 150 parts by weight of a polyester resin (B), and an endothermic calorific value of the polyester resin (B) less than 5 J/g (including 0) for fusion of the polyester resin on a DSC curve obtained by heat flux differential scanning calorimetry based on JIS K7122 (1987).Type: GrantFiled: April 6, 2011Date of Patent: October 15, 2013Assignee: JSP CorporationInventors: Akira Okuda, Tatsuyuki Ishikawa, Naochika Kogure, Kazunobu Sato
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Publication number: 20130197116Abstract: Disclosed herein are ultra high strength compositions, such as comprising, in parts by weight: from about 20% to about 30% plastic; from about 55% to about 65% calcium carbonate; and from about 10% to about 20% fiber. Further disclosed is an ultra high strength composition, comprising, in parts by weight: from about 31% to about 39% plastic; from about 40% to about 50% calcium carbonate and from about 15% to about 25% fiber to which a foaming agent is added.Type: ApplicationFiled: January 31, 2012Publication date: August 1, 2013Inventor: Jack Elijah Williams, III
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Patent number: 8497316Abstract: It concerns a crosslinkable and foaming polyester-polyurethane resin moulding composition, comprising: an A component, comprising: A1) at least one poly-functional isocyanate compound, and A2) at least one free radical polymerization initiator a B component, comprising by weight: B1) 100 parts of at least one polyol resin comprising: —B11) 50 to 80 parts of at least one ethylenically unsaturated polyester polyol—B 12) 20 to 50 parts of at least one ethylenically unsaturated monomer, with, B11), being the reaction product of: a) an acid component comprising: a1) at least one ethylenically unsaturated diacid, and a2) at least one saturated diacid with a1/a2 molar ratio so varying to have an unsaturation content in B11) from 0.25/1 to 5/1, and, b) a diol component in excess with respect to component a) B2) from 0.01 to 1.Type: GrantFiled: September 29, 2008Date of Patent: July 30, 2013Assignee: CCP Composites UK LtdInventors: Paul Darby, Phil Dean
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Publication number: 20130190413Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, an infrared attenuating agent, and a polystyrene/polyethylene oxide copolymer are provided. In exemplary embodiments, the blowing agent contains an HFC. The maleic anhydride-styrene copolymer grafted with polyethylene oxide increases the cell size of the polymer foam and offsets or even negates the decreased cell size caused by an HFC blowing agent and/or infrared attenuating agents. In addition, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid. A method of forming an extruded foam product is also provided.Type: ApplicationFiled: January 7, 2013Publication date: July 25, 2013Applicant: OWENS CORNING INTELLECTUAL CAPITAL, LLCInventor: OWENS CORNING INTELLECTUAL CAPITAL, LLC
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Publication number: 20130150468Abstract: The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.Type: ApplicationFiled: January 6, 2011Publication date: June 13, 2013Applicant: BASF SEInventors: Andreas Füssi, Bangaru Sampath, Maximilian Hofmann, Ingo Bellin, Sameer Nalawade, Klaus Hahn, Andreas Künkel, Robert Loos
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Publication number: 20130123379Abstract: Provided herein are graft copolymers of polyfarnesenes with condensation polymers; and methods of making and using the graft copolymers disclosed herein. The graft copolymers are obtained from the reaction of a polycondensation polymer with a modified polyfarnesene obtained from reaction of a polyfarnesene with a modifier in the presence of a grafting initiator. In certain embodiments, the condensation polymers include polyesters, polycarbonates, polyamides, polyethers, phenol-formaldehyde resins, urea-formaldehyde resins, melamine-formaldehyde resins and combinations thereof. In some embodiments, the polyfarnesenes include farnesene homopolymers derived from a farnesene, and farnesene interpolymers derived from a farnesene and at least a vinyl monomer. In certain embodiments, the farnesene is prepared from a sugar by using a microorganism.Type: ApplicationFiled: July 29, 2011Publication date: May 16, 2013Applicant: AMYRIS, INC.Inventor: Derek James Mcphee
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Publication number: 20130089686Abstract: The invention relates to a plastic material comprising a composition Z comprising the components A, B, C and D, the component A being a polyester, the component B being a polyamide, the component C being a transition metal catalyst, the component D being an organic compound selected from the group consisting of paraffins, vegetable oils, polyalkylene glycols, esters of polyols, alkoxylates, and mixtures of these substances.Type: ApplicationFiled: June 16, 2011Publication date: April 11, 2013Applicant: CLARIANT MASTERBATCHES (ITALIA) SPAInventor: Flavio Fava
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Publication number: 20130059141Abstract: The present invention relates to foam layers based on a biodegradable polyester mixture PM, comprising: i) from 5 to 49% by weight, based on the total weight of components i to ii, of at least one polypropylene carbonate; ii) from 51 to 95% by weight, based on the total weight of components i to ii, of polylactic acid; iii) from 0 to 25% by weight, based on the total weight of components i to v, of a polyester composed of an (x1) aliphatic and/or (x2) aromatic dicarboxylic acid and of an (y) aliphatic diol; iv) from 0 to 5% by weight, based on the total weight of components i to v, of a copolymer which comprises epoxy groups and which is based on styrene, acrylate, and/or methacrylate; and v) from 0 to 15% by weight, based on the total weight of components i to v, of additives.Type: ApplicationFiled: September 4, 2012Publication date: March 7, 2013Applicant: BASF SEInventors: Andreas Füßl, Jan Kurt Walter Sandler, Sameer Nalawade, Tobias Heinz Steinke, Volker Warzelhan, Andreas Künkel, Klaus Hahn, Jerome Lohmann, Anna Katharina Brym
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Publication number: 20130040122Abstract: Organic infrared attenuation agents have been developed to improve the thermal insulation properties of polymeric foams such as polystyrene low density foams. The organic infrared attenuation agents can include polyols such as sorbitol, maltitol, and poly(ethylene glycol), polysaccharides such as starch or cellulose, and infrared attenuation polyesters such as polybutylene terephthalate. The organic attenuation agents include aromatic compounds or carbon oxygen bonds that are effective in absorbing infrared radiation at the desired wavelengths.Type: ApplicationFiled: June 25, 2012Publication date: February 14, 2013Applicant: OWENS CORNING INTELLECTUAL CAPITAL LLCInventors: Nikoi Annan, Yadollah Delaviz, Xiangmin Han, Roland Loh
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Publication number: 20130011657Abstract: There is provided a polyester elastomer which is excellent in compression set characteristics and has a micro cell structure. The polyester elastomer foam is formed by allowing a polyester elastomer composition containing a polyester elastomer having a melting point of 180 to 240° C. and an epoxy-modified polymer to expand. The epoxy-modified polymer is an epoxy-modified polymer having a weight average molecular weight of 5,000 to 100,000 and an epoxy equivalent of 100 to 3000 g/eq.Type: ApplicationFiled: July 3, 2012Publication date: January 10, 2013Applicant: NITTO DENKO CORPORATIONInventors: Kazumichi KATO, Makoto SAITOU, Kiyoaki KODAMA, Itsuhiro HATANAKA
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Patent number: 8314160Abstract: A thermoplastic resin foam which has both high reflectance and superior shape-retention properties, suitable for use in backlights and illumination boxes for illumination signboards, lighting fixtures, displays and the like. The thermoplastic resin foam is manufactured by a manufacturing method including a procedure for holding a resin sheet composed of thermoplastic resin (A) and thermoplastic resin (B), which has a functional group having an affinity with thermoplastic resin (A), within a pressurized inert gas atmosphere to enable the resin sheet to contain inert gas, and a procedure for foaming by heating the resin sheet containing inert gas at a temperature higher than the softening temperature of thermoplastic resin, under normal pressure.Type: GrantFiled: December 13, 2005Date of Patent: November 20, 2012Assignee: The Furukawa Electric Co., Ltd.Inventors: Kohji Masuda, Masayasu Ito, Kojiro Inamori, Naoki Yoshida, Michiaki Kawakami, Hiroyuki Yamazaki, Hidehumi Miyagi, Yong Hoon Kim
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Patent number: 8288447Abstract: Expandable, thermally curable compositions containing at least one epoxy resin, at least one polyester, at least one blowing agent, and at least one curing agent are useful as adhesives and structural reinforcement materials. When foamed and adhered to a metal substrate surface, such polyester-modified foamable compositions can exhibit improved adhesion to the substrate surface after exposure to a corrosive environment, as compared to compositions that do not contain polyester. Furthermore, these compositions can exhibit improved flow properties in the uncured state at temperatures between 50 and 100° C. They are granulatable, with the granules produced thereby having non-tacky surfaces at room temperature and being capable of being readily processed into molded objects by injection molding processes.Type: GrantFiled: December 8, 2008Date of Patent: October 16, 2012Assignee: Henkel AG & Co. KGaAInventors: Xaver Muenz, Bernd Mayer, Christian Scheffner, Rajat K. Agarwal, Michael S. Puckett, Gregory A. Ferguson, Olaf Lammerschop
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Publication number: 20120225230Abstract: Biodegradable aliphatic/aromatic copolyester comprising: A) an acid component comprising repeating units of: 1) 53 to 54 mol % of an aromatic carboxylic acid; 2) 47 to 36 mol % of an aliphatic acid at least 50% of which is azelaic acid; B) a diol component selected from the group consisting of C3, C4 and C6 diols said AAPE being disintegrated according to the Standard ISO 20200 in 90 days.Type: ApplicationFiled: May 7, 2012Publication date: September 6, 2012Applicant: Novamont S.p.A.Inventors: Catia Bastioli, Tiziana Milizia, Giovanni Floridi, Andrea Scaffidi Lallaro, Giandomenico Cella, Maurizio Tosin
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Publication number: 20120219740Abstract: Biodegradable aliphatic/aromatic copolyester comprising 50 to 60 mol % of an aromatic dicarboxylic acid and 40 to 50 mol % of an aliphatic acid, at least 90% of which is a long-chain dicarboxylic acid (LCDA) of natural origin selected from azelaic acid, sebacic acid, brassylic acid or mixtures thereof; and a diol component.Type: ApplicationFiled: May 8, 2012Publication date: August 30, 2012Applicant: Novamont S.p.A.Inventors: Catia Bastioli, Tiziana Milizia, Giovanni Floridi, Andrea Scaffidi Lallaro, Giandomenico Cella, Maurizio Tosin
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Publication number: 20120201806Abstract: Disclosed are compositions-of-matter composed of a continuous elastomeric matrix and a liquid; the matrix entrapping the liquid therein in the form of closed-cell droplets dispersed throughout the matrix. The disclosed compositions-of-matter are characterized by a low tensile/compressive modulus and are capable of retaining the liquid for exceedingly long periods of time. Further disclosed are processes for forming the compositions-of-matter and uses thereof.Type: ApplicationFiled: February 9, 2012Publication date: August 9, 2012Applicant: Technion Research & Development Foundation Ltd.Inventors: Michael S. Silverstein, Inna Gurevitch
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Patent number: 8217092Abstract: A multicomponent polyurethane/vinyl ester hybrid foam system for forming a gradient foam with soft and rigid foam regions, with a polyol component (A), a polyisocyanate component (B), and a component (C), which contains a catalyst for the polymerization of the vinyl monomer, with the polyol component (A) containing, as vinyl monomer, a mixture of vinyl esters of at least one polymerizable hydroxyvinyl ester and at least one branched, at least trifunctional, polymerizable vinyl ester, and the polyisocyanate component (B) containing a thermally activatable free radical-forming agent as catalyst for the polymerization of the vinyl monomers, with the proviso that the proportion by weight of the vinyl ester mixture is greater than the proportion by weight of the at least one polyol as well as the proportion by weight of the at least one polyisocyanate.Type: GrantFiled: November 28, 2007Date of Patent: July 10, 2012Assignee: Hilti AktiengesellschaftInventor: Arne Reinheimer
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Patent number: 8217093Abstract: A two-component polyurethane/vinyl ester hybrid foam system is formed of a polyol component (A), which contains at least one polyol, a catalyst for the reaction of the polyol with the polyisocyanate, at least one polymerizable vinyl monomer and water or a blowing agent on the basis of a compressed or liquefied gas as foam-forming agent, and a polyisocyanate component (B), which contains at least one polyisocyanate and a catalyst for the polymerization of the vinyl monomer, and is designed for use as a flame retardant material and material for filling openings, cable and pipe bushings in walls, floors and/or of buildings for the purpose of fire protection.Type: GrantFiled: November 28, 2007Date of Patent: July 10, 2012Assignee: Hilti AktiengesellschaftInventor: Arne Reinheimer