At Least One Polymer Is Derived From An Ethylenically Unsaturated Aromatic Reactant Or Wherein The Polymer-forming System Contains The Same Type Of Reactant Patents (Class 521/139)
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Patent number: 7977397Abstract: The present invention relates to compositions comprising blends of alkenyl aromatic polymers such as styrenic polymers (i.e. PS and HIPS) and bio-based or biodegradable polymers (i.e. PLA, PGA, PHA, PBS, PCL) compatibilized with styrene-based copolymers (i.e. styrene-ethylene-butylene-styrene (SEBS) block copolymers, maleated SEBS, styrene-maleic anhydride (SMA) copolymer, styrene-methyl methacrylate (SMMA) copolymer) or a mixture of two or more styrene-based copolymers such as SEBS and SMA. These novel compositions can be extruded and thermoformed to produce very low density food service and consumer foam articles such as plates, hinged lid containers, trays, bowls, and egg cartons with good mechanical properties.Type: GrantFiled: March 14, 2008Date of Patent: July 12, 2011Assignee: Pactiv CorporationInventors: Yunwa Wilson Cheung, David V. Dobreski, Richard Turner, Mark Wheeler, Y. Paul Handa
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Publication number: 20110159362Abstract: In regards with the porous film provided on the surface of the electrode used for the secondary battery or so, the present invention provides the porous film which can contribute to reduce the adhered material to the roll during the roll winding of the electrode. The secondary battery electrode formed by adhering; the porous film comprising the inorganic filler and the binder, and styrene and the polymer having the glass transition temperature of 15° C. or less as said binder, the porous film slurry comprising the inorganic filler, the polymer having the glass transition temperature of 15° C. or less and the solvent, and the electrode composite layer comprising the binder and the electrode active material, to the current collector, and said porous film is provided on the surface of the electrode composite layer.Type: ApplicationFiled: August 27, 2009Publication date: June 30, 2011Inventors: Yasuhiro Wakizaki, Mayumi Fukumine
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Patent number: 7960443Abstract: The present invention relates to an extruded styrenic resin foam and a method for producing the same, wherein a base resin composing the extruded styrenic resin foam is a styrenic resin mixture of a styrene-(meth)acrylic ester copolymer, or a combination of a styrene-(meth)acrylic ester copolymer and polymethyl methacrylate, and a styrenic resin except the styrene-(meth)acrylic ester copolymer, and the styrenic resin mixture contains a (meth)acrylic ester component at a ratio of 4 to 45% by weight with reference to the styrenic resin mixture. The present invention provides an extruded styrenic resin foam having an apparent density of 20 to 60 kg/m3, a thickness of 10 to 150 mm, and a low thermal conductivity, and keeping excellent heat insulation performance over a long period of time and flame retardancy, even when the styrenic resin extruded foam is foamed using a blowing agent having an ozone depleting potential of 0 (zero) and a low global warming potential.Type: GrantFiled: April 15, 2008Date of Patent: June 14, 2011Assignee: JSP CorporationInventors: Shunsuke Sekiya, Atsushi Taira, Noritoshi Nishiyama, Naochika Kogure
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Patent number: 7947754Abstract: The present invention provides a foam comprising (a) a polylactic acid resin, (b) at least one thermoplastic resin selected from a polyolefin resin and a polystyrene resin, and (c) a block copolymer of a vinyl aromatic compound and a conjugated diene, wherein a ratio of (a) to (b) by weight (a/b) is 80/20 to 20/80, and the foam comprises 0.5 to 20 parts by weight of (c) with respect to 100 parts by weight of (a) and (b) in total.Type: GrantFiled: January 18, 2007Date of Patent: May 24, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Tohru Okuda, Shoichiro Harada, Yoshihito Fukasawa
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Publication number: 20110118371Abstract: The invention relates to thermoplastic molding compositions comprising A) from 55 to 98% by weight of at least one vinylaromatic copolymer impact-modified with a particulate graft rubber, B) from 1 to 44% by weight of a flame retardant comprising B1) an expandable graphite, B2) a phosphorus-comprising flame-retardant compound, and B3) a fluorine-comprising polymer, C) from 1 to 20% by weight of a non-particulate rubber comprising polar groups, and D) from 0 to 40% by weight of further additives, where the percentages by weight are in each case based on the total weight of components A) to D) and give a total of 100% by weight, and also to processes for the preparation of these molding compositions, to the use of these molding compositions for the production of moldings, of fibers, of foams, or of foils, and also to the resultant moldings, fibers, foams, and foils.Type: ApplicationFiled: July 3, 2009Publication date: May 19, 2011Applicant: BASF SEInventors: Maarten Staal, Piyada Charoensirisomboon, Norbert Güntherberg, Hartmut Heinen, Günter Kehr, Michel Pepers
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Patent number: 7939572Abstract: An aqueous dispersion of polymeric particles, the particles including: from 5% to 80% by weight, based on the weight of the polymeric particles, of a first polymer including at least one copolymerized ethylenically unsaturated monomer; and, substantially encapsulating the first polymer, from 20% to 95% by weight, based on the weight of the polymeric particles, of a second polymer including at least one copolymerized ethylenically unsaturated monomer, the second polymer having a Tg of from ?40° C. to 30° C., wherein at least 90 weight % of the second polymer is formed by polymerization at a temperature of from 5° C. to 65° C. is provided. The invention also relates to a process for forming the aqueous dispersion of polymeric particles and an aqueous coating composition including the aqueous dispersion of polymer particles, a method for providing a coated substrate, and the coated substrate so provided.Type: GrantFiled: August 23, 2005Date of Patent: May 10, 2011Assignee: Rohm and Haas CompanyInventors: James Keith Bardman, Robert Mitchell Blankenship, John Michael Friel
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Publication number: 20110098372Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.9% by weight of at least one thermoplastic polyamide B) from 0.1 to 50% by weight of a copolymer obtainable via (i) preparation of at least one reaction mixture (a) via free-radical copolymerization of one or more monoethylenically unsaturated monomeric compound(s) (monomer(s) B1) with one or more compound(s) selected from the group of itaconic acid, mesaconic acid, fumaric acid, maleic acid, aconitic acid, glutaconic acid, and salts, esters, and anhydrides thereof (monomer(s) B2), and (ii) if appropriate, reaction of at least one of the copolymers obtained in step (i) with one or more crosslinking agent(s) (b), and C) from 0 to 60% by weight of further additives, where the total of the percentages by weight of components A) to C) is 100%.Type: ApplicationFiled: June 9, 2009Publication date: April 28, 2011Applicant: BASF SEInventors: Francesca Aulenta, Cecile Gibon, Arnold Schneller, Martin Weber
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Patent number: 7930782Abstract: A tear and fatigue resistant gels, gel composites, and gel articles including collapsible articles having two or more communicating internal volumes like cavities when depressed by external pressure or force is capable of collapsing unto itself in a controllable and directionally preselected manner by venting static air within said internal through openings in said gel article, said gel of said article having rigidity of from about 20 gram Bloom to about 1,800 gram Bloom suitable for cushioning, cushioning composites, cushioning gel liners, cushioning composite gel liners, and other uses of selected shape gels, gel composites, and articles.Type: GrantFiled: June 5, 2007Date of Patent: April 26, 2011Assignee: Applied Elastomerics, Inc.Inventor: John Y. Chen
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Publication number: 20110082225Abstract: A blend of thermoplastic polyester elastomer, hydrogenated styrenic block copolymer, and high styrene content styrenic block copolymer is disclosed which has good processability and more effective abrasion resistance than the blend using polystyrene in place of the high styrene content styrenic block copolymer.Type: ApplicationFiled: June 16, 2009Publication date: April 7, 2011Applicant: POLYONE CORPORATIONInventors: Guoqiang Qian, Krishna Venkataswamy
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Patent number: 7919539Abstract: A masterbatch composition comprising an aromatic polyester resin, a polyolefin and a polyfunctional compound selected from the dianhydrides of tetracarboxylic aromatic and/or aliphatic acids and the polyepoxidic compounds, wherein the polyester resin and the polyfunctional compounds are omogeneously dispersed as solids in a matrix formed by the polyolefin, as domains of average particle size less than 800?. The masterbatch is prepared by milling polyester resins and polyolefin granules to obtain powders having average particle size of less than 200?, and the powders are therafter homogeneously mixed.Type: GrantFiled: May 27, 2008Date of Patent: April 5, 2011Assignee: Point Plastic S.R.L.Inventor: Alessandro Tabacchiera
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Patent number: 7919538Abstract: Polymer foam containing styrene-acrylonitrile and containing one or more infrared attenuating agents achieves surprisingly high dimensional integrity at elevated temperatures.Type: GrantFiled: October 15, 2007Date of Patent: April 5, 2011Assignee: Dow Global Technologies LLCInventors: Chau V. Vo, Lawrence S. Hood
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Publication number: 20110071448Abstract: A liquid impermeable material comprising a layer of vapour permeable viscoelastic polymer gel, applications of said material, a composite material comprising said material and a method of producing said material.Type: ApplicationFiled: June 24, 2005Publication date: March 24, 2011Inventor: Ezio Margiotta
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Publication number: 20110047819Abstract: A system of two different styrenic thermoplastic elastomers is disclosed. One styrenic thermoplastic elastomer is vinyl-isoprene styrene-isoprene-styrene which is known for its shock-damping properties. The other styrenic thermoplastic elastomer is oil absorbing and known for softness on the Shore A hardness scale. The system includes plasticizer oil. The system can be molded into articles that can provide dissipation of impact energy, for shock absorbing elastomeric uses, such as seals, closures, shoe insoles, and other goods.Type: ApplicationFiled: August 27, 2008Publication date: March 3, 2011Applicant: POLYONE CORPORATIONInventor: Marcel Pelletier
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Publication number: 20110039965Abstract: There is a resin composition containing a propylene polymer (A), an ethylene-?-olefin copolymer (B), and organic polymer beads (C), wherein the proportion of the amount of the propylene polymer (A) and the proportion of the amount of the ethylene-?-olefin copolymer (B) relative to the sum total of the amounts of the propylene polymer (A) and the ethylene-?-olefin copolymer (B) are 40 to 95% by mass and 5 to 60% by mass, respectively, the amount of the organic polymer beads (C) for 100 parts by weight in total of the propylene polymer (A) and the ethylene-?-olefin copolymer (B) is 0.1 to 20 parts by weight, and the density of the ethylene-?-olefin copolymer (B) is 0.85 to 0.89 g/cm3.Type: ApplicationFiled: October 30, 2008Publication date: February 17, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Hiroyoshi Nakajima, Takashi Fuujimoto
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Patent number: 7879922Abstract: Expanded products, more specifically, rigid or semi-flexible foams of low density from 1.5 to 12 lbs/ft3 or more, with closed cells can be manufactured. The products have a PVC backbone with branches with methacrylate crosslinked with isocyanate through a reaction activated by ultraviolet or microwave radiation. The use of polyfunctional monomers that are sensitive to irradiation yields a higher cross-link density, which improves the physical and mechanical properties such as hardness, resistance to abrasion, ductility, and resistance to friction. The selection of monomers and oligomers allows the manufacturer to determine of the final properties of the foam. The process yields foams with extreme hardness and better shear factors making the foam an ideal product for aerospace and windmill use. These physical properties emerge during the post-curing process, preferably by use of compounds based on methacrylates in dispersion with PVC and isocyanates.Type: GrantFiled: November 20, 2007Date of Patent: February 1, 2011Assignee: PolyuMAC Inc.Inventor: Juan Miguel Vazquez
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Publication number: 20110020575Abstract: Composition comprising at least one copolymer A composed of at least one alkylated styrene, of acrylonitrile, and, if appropriate, of at least one further monomer, at least one block copolymer B which has at least one block forming a hard phase and composed of at least one vinylaromatic monomer and has at least one block forming a soft phase and composed of at least one vinylaromatic monomer and of at least one diene, and at least one further copolymer C, and, if appropriate, one polymer D, where the copolymer C is at least one triblock copolymer composed of a first block composed of at least one vinylaromatic monomer, of a second block composed of at least one diene, and of a third block composed of at least one methyl methacrylate monomer, or comprising at least 50% by weight of methyl methacrylate, and the polymer D is at least one styrene polymer selected from glass-clear and impact-resistant polystyrene.Type: ApplicationFiled: March 4, 2009Publication date: January 27, 2011Applicant: BASF SEInventors: Konrad Knoll, Koch Jürgen, Piyada Charoensirisomboon
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Patent number: 7872056Abstract: The present invention relates to compositions comprising blends of alkenyl aromatic polymers such as styrenic polymers (i.e. PS and HIPS) and bio-based or biodegradable polymers (i.e. PLA, PGA, PHA, PBS, PCL) compatibilized with styrene-based copolymers (i.e. styrene-ethylene-butylene-styrene (SEBS) block copolymers, maleated SEBS, styrene-maleic anhydride (SMA) copolymer, styrene-methyl methacrylate (SMMA) copolymer) or a mixture of two or more styrene-based copolymers such as SEBS and SMA. These novel compositions can be extruded and thermoformed to produce very low density food service and consumer foam articles such as plates, hinged lid containers, trays, bowls, and egg cartons with good mechanical properties.Type: GrantFiled: February 2, 2009Date of Patent: January 18, 2011Assignee: Pactiv CorporationInventors: Yunwa Wilson Cheung, David V. Dobreski, Richard Turner, Mark Wheeler, Y. Paul Handa
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Publication number: 20110008609Abstract: A resin foam has a porosity (X) of not less than 80%, having a cell (L) with a cell diameter of not less than 1 ?m and not more than 1000 ?m, and a cell (S) with a cell diameter of not less than 0.01 ?m and less than 1 ?m. The resin foam is excellent in thermal insulation performance and environmental performance, further, to provide a non Freon thermal insulation foam material maintaining the excellent thermal insulation performance for a long period of time and not generating condensation easily.Type: ApplicationFiled: March 6, 2009Publication date: January 13, 2011Applicant: TORAY INDUSTRIES, INC.Inventors: Hirokado Nakamura, Kazuhiro Shino, Masahiro Kimura
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Patent number: 7868053Abstract: Expandable pelletized styrene polymer materials with at least bi- or multimodal molecular weight distribution, to a process for their preparation, and to use for producing moldable-foam moldings.Type: GrantFiled: December 10, 2004Date of Patent: January 11, 2011Assignee: BASF SEInventors: Klaus Hahn, Gerd Ehrmann, Joachim Ruch, Markus Allmendinger, Bernhard Schmied, Jan Holoch, Franz-Josef Dietzen
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Publication number: 20100317757Abstract: Certain brominated polymers compounds are effective FR additives for combustible organic polymers. These FR additives include: i) a copolymer having styrene and 2,3-dibromopropylmaleimide repeating units; ii) a brominated polyester having aliphatically bound bromine; iii) an allyl ether of a ring-brominated novolac resin; iv) a 3-bromo-2-hydroxypropyl ether of a novolac resin; v) a 2,3-dibromopropyl ether of a cresol novolac resin; and vi) a brominated ROMP polymer or copolymer.Type: ApplicationFiled: January 30, 2009Publication date: December 16, 2010Inventors: Bruce A. King, Anteneh Worku, William G. Stobby
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Patent number: 7838567Abstract: Foams composed of water-absorbing basic polymers, obtainable by (I) foaming a crosslinkable aqueous mixture including (a) at least one basic polymer whose basic groups have optionally been neutralized, (b) at least one crosslinker, (c) at least one surfactant, (d) optionally at least one solubilizer, (e) optionally thickeners, foam stabilizers, fillers, fibers and/or cell nucleators, and (f) optionally particulate water-absorbing acidic polymers, by dissolving a gas which is inert toward free radicals in the crosslinkable aqueous mixture under a pressure from 2 to 400 bar and subsequently decompressing the crosslinkable aqueous mixture to atmospheric or by dispersing fine bubbles of a gas which is inert toward free radicals, and (II) crosslinking the foamed mixture to form a hydrogel foam and if applicable adjusting the water content of the polymer foam to 1-60% by weight.Type: GrantFiled: January 30, 2003Date of Patent: November 23, 2010Assignee: Basf AktiengesellschaftInventors: Samantha Champ, Hans-Joachim Hähnle, Martin Beck, Rüdiger Funk
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Publication number: 20100292355Abstract: Prepare an alkenyl-aromatic foam having good surface quality, high thermal insulating properties and low density using an extrusion method by expanding a foamable polymer composition of an alkenyl-aromatic polymer composition containing less than 20 weight-percent covalently bonded halogens and having a polydispersity of less than 2.5 and a water solubility greater than 0.09 moles per kilogram and 2.2 moles per kilogram or less at 130 degrees Celsius and 101 kilopascals pressure and 0.8-2 moles per kilogram of a blowing agent containing 0.4 moles per kilogram or more of a chlorine-free fluorinated blowing agents and water at a concentration of at least 0.22 moles per kilogram; wherein moles per kilogram are relative to kilograms of alkenyl-aromatic polymer. The resulting foam has a density of 64 kilograms per cubic meter or less and a thermal conductivity of 32 milliwatts per meter-Kelvin or less after 180 days.Type: ApplicationFiled: April 18, 2008Publication date: November 18, 2010Inventors: Mark A. Barger, Charles A. Berglund, Clive P. Bosnyak, Stephanie A. Donati, John Gordon-Duffy, Warren H. Griffin, Ing-Feng Hu, Jean-Francois Koenig, Simon Lee, Creston D. Shmidt, Roy E. Smith, Chau V. Vo
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Publication number: 20100263906Abstract: A flexible thermoplastic composition comprises a poly(arylene ether), a first block copolymer, a second block copolymer and a flame retardant wherein the second block copolymer comprises a controlled distribution copolymer block. The flexible thermoplastic composition is useful in the manufacture of coated wires.Type: ApplicationFiled: July 2, 2010Publication date: October 21, 2010Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Kazunari Kosaka, Xiucuo Li, Weiguang Yao
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Patent number: 7812062Abstract: Olefin polymer-based, durable, open-cell foam compositions, structures and articles derived from same; methods for preparation of such foams; and use of the dry durable foams in various applications are disclosed. Further described is use of the foams and structures and articles made of same in absorption, filtration, insulation, cushioning and backing applications, and in particular for odor removal, hygiene and medical applications due to, among other properties, good absorption capabilities, softness and/or flexibility of the foams and their recyclable nature.Type: GrantFiled: May 25, 2007Date of Patent: October 12, 2010Assignee: Dow Global Technologies, Inc.Inventors: Gary M. Strandburg, Mark W. VanSumeren, Shaofu Wu, Luther E. Stockton
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Publication number: 20100256248Abstract: According to the present invention there are provided improved rubber modified monovinylidene aromatic polymers having the specified relatively high molecular weight and the necessary rubber levels and particles. These improved resins are specially adapted and suited for use in stretch blow molding processes. They provide improved combinations of container neck strength and toughness, wall strength and stiffness and packaging efficiency. The present invention provides the makers of stretch blow molded containers with options for improved packaging cost and efficiency.Type: ApplicationFiled: October 23, 2008Publication date: October 7, 2010Inventors: Rodolfo Salmang, Enrique Torres, Julien Damen, Amaia Montoya-Goni
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Patent number: 7767723Abstract: According to the present invention, there is provided expandable beads of a styrene-modified linear low-density polyethylene-based resin comprising a volatile blowing agent and a base resin, the base resin containing more than 50 to 1000 parts by weight of a polystyrene-based resin component relative to 100 parts by weight of a non-crosslinked linear low-density polyethylene-based resin component, wherein the base resin contains less than 2 wt % of a gel component comprising a graft polymer of the polystyrene-based resin component and the low-density polyethylene-based resin component.Type: GrantFiled: March 22, 2004Date of Patent: August 3, 2010Assignee: Sekisui Plastics Co., Ltd.Inventors: Hideyasu Matsumura, Yasutaka Tsutsui
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Patent number: 7767724Abstract: According to the present invention, there is provided expandable beads of a styrene-modified linear low-density polyethylene-based resin comprising a volatile blowing agent and a base resin, the base resin containing more than 300 parts by weight and less than 1000 parts by weight of a polystyrene-based resin component relative to 100 parts by weight of a non-crosslinked linear low-density polyethylene-based resin component, wherein the base resin contains 2 to 40 wt % of a gel component comprising a graft copolymer of the polystyrene-based resin component and the low-density polyethylene-based resin component.Type: GrantFiled: March 22, 2004Date of Patent: August 3, 2010Assignee: Sekisui Plastics Co., Ltd.Inventors: Hideyasu Matsumura, Yasutaka Tsutsui
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Publication number: 20100159172Abstract: A permeable film or container for use in extending the storage life of a foodstuff or produce is provided. The film or container is formed from a plastics component, a porous component having a particle size smaller than the thickness of the film, and an acid component selected from at least one carboxylic acid compound in free or salt form. The permeable film is adapted for controlling the environment surrounding the foodstuff to reduce its respiration rate or senescence by controlling the transfer of gases, particularly oxygen and carbon dioxide, and build up of moisture. In one preferred embodiment the present invention provides a permeable film for use in the storage of a foodstuff, formed from a polymer component, a clay activated base component, and sorbic acid in free or salt form.Type: ApplicationFiled: August 11, 2006Publication date: June 24, 2010Inventors: Lynden William Trickey, Jeffery Earnest Peck
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Publication number: 20100113628Abstract: A foamed composition adapted to seal to a substrate is provided. The foamed composition includes a radiation curable rubber, a photoinitiator, a blowing agent, a styrene-ethylene/butylene block copolymer, a light mineral oil, rheology modifier, a tackifier, and one of a radiation curable monomer and radiation curable oligomer, and wherein the composition is foamed upon application to the substrate.Type: ApplicationFiled: August 10, 2007Publication date: May 6, 2010Inventors: Eli Kendra, Dennis Booth, Paul Snowwhite
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Publication number: 20100099784Abstract: A thermoplastic elastomer foaming material is provided. The thermoplastic elastomer foaming material includes a hydrogenated styrenic/conjugated diene copolymer in a range from 5 to 35 weight percent; at least one of an acetate copolymer and an acrylate copolymer in a range from 3 to 30 weight percent; an amorphous polyolefin in a range from 20 to 60 weight percent; and a plasticizer in a range from 10 to 40 weight percent.Type: ApplicationFiled: December 21, 2009Publication date: April 22, 2010Applicant: TSRC CORPORATIONInventors: Jan-Rong SU, Cheng-Te LEE, Ching-En TSAI
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Patent number: 7683101Abstract: A pre-expanded beads of olefin-modified polystyrene-based resin comprising a pie-expanded beads of a polystyrene-based resin modified with a polyolefin-based resin, wherein a styrene-based monomer forming a polystyrene-based resin in the beads is used in the range of 100 to 1,000 parts by weight relative to 100 parts by weight of a polyolefin-based resin, a bulk density of each bead is 0.012 to 0.20 g/cm3, and an absorbance ratio at 698 cm?1 and 2850 cm?1 (D698/D2850) obtained from an infrared absorption spectrum of each bead surface measured by ATR method infrared spectroscopy is in the range of 0.1 to 2.5.Type: GrantFiled: July 23, 2004Date of Patent: March 23, 2010Assignee: Sekisui Plastics Co., Ltd.Inventors: Naokuni Inada, Hideyasu Matsumura, Yasutaka Tsutsui, Ikuo Morioka
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Publication number: 20100048752Abstract: A polymer composition that includes a first polyolefin polymer and an interpenetrating network polymer. The interpenetrating network polymer includes a second polyolefin polymer present in an amount of from 10 percent by weight to 80 percent by weight, based on total weight of the interpenetrating network polymer, and a vinyl aromatic polymer present in an amount of from 20 percent by weight to 90 percent by weight, based on total weight of the interpenetrating network polymer. As initially provided in the polymer composition, the interpenetrating network polymer is substantially free of crosslinking. The polymer composition itself is at least partially crosslinked. An expandable polymer composition is provided that includes the polymer composition and an expansion agent, which can be expanded to form an expanded polymer composition that can have a density of from 16 to 400 Kg/m3.Type: ApplicationFiled: August 19, 2009Publication date: February 25, 2010Applicants: NOVA CHEMICALS INC., CELLECT LLCInventors: Eric Vignola, Shelly Martel, Edwin Niemann, Robert F. Hurley, Scott C. Smith
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Patent number: 7661164Abstract: A tear and fatigue resistant gel article comprising two or more communicating internal volumes like cavities when depressed by external pressure or force is capable of collapsing unto itself in a controllable and directionally preselected manner by venting static air within said internal through openings in said gel article, said gel article is made from gel compositions having rigidity of from about 20 gram Bloom to about 1,800 gram Bloom suitable for cushioning and other uses.Type: GrantFiled: April 12, 2007Date of Patent: February 16, 2010Assignee: Applied Elastomerics, Inc.Inventor: John Y. Chen
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Publication number: 20100036009Abstract: A process for producing a microporous polymeric object to improve the degree of freedom for its various properties, compared to conventional processes, includes: mixing a block copolymer made of three or more kinds of segments with a polymer, wherein one or more of the segments are made of monomer units having a first functional group forming ionic and/or hydrogen bond, the segments constitute a co-continuous structure having mutually-independent and continuous regions due to a phase separation based on incompatibility between the segments, and the polymer has, at other than polymer chain terminals, a second functional group forming such bond with the first functional group, thereby allowing the segments to associate with the polymer at many points; forming a co-continuous structure including a region composed of the polymer and the segments due to the phase separation; and removing the polymer from the region by weakening the bond between the functional groups.Type: ApplicationFiled: January 7, 2008Publication date: February 11, 2010Applicant: NITTO DENKO CORPORATIONInventors: Takahisa Konishi, Takuji Shintani, Yushu Matsushita, Atsushi Takano, Takeshi Asari
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Patent number: 7655705Abstract: The present invention relates to an open-cell foam, and to a process for producing this open-cell foam by melting a thermoplastic, or a mixture comprising a thermo-plastic, giving a melt, mixing the melt with at least one blowing agent under pressure, and foaming the melt comprising the blowing agent via extrusion into the free atmosphere, the temperature of the melt during the foaming process being greater than the melt temperature at which a closed-cell foam is formed, and/or adding a pulverulent solid, and/or adding a foreign polymer. The present invention further relates to the use of the foam of the invention for sound deadening or for producing materials by sound deadening.Type: GrantFiled: February 24, 2004Date of Patent: February 2, 2010Assignee: BASF AktiengesellschaftInventors: Dietrich Scherzer, Hanns-Jörg Krautschneider, Franz-Josef Dietzen
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Publication number: 20100022674Abstract: Expandable polystyrenic resin particles having superior resistance to cracking of a molded foam product, having superior retention of blowing agent and maintaining expandability over a long period of time, a production process thereof, and a molded foam product are provided.Type: ApplicationFiled: October 25, 2007Publication date: January 28, 2010Applicant: SEKISUI PLASTICS CO., LTD.Inventors: Ikuo Morioka, Yasutaka Tsutsui, Hideyasu Matsumura
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Publication number: 20100006199Abstract: This invention provides a rubber composition highly balancing flexibility at a low temperature and a low rolling resistance, which is formed by compounding a low-molecular weight conjugated diene-based polymer (B) having at least one functional group, an aromatic vinyl compound content of less than 5% by mass and a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 2,000 but less than 150,000 and a filler (C) into a high-molecular weight rubber component (A) having a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 150,000.Type: ApplicationFiled: September 4, 2007Publication date: January 14, 2010Applicant: BRIDGESTONE CORPORATIONInventors: Fuminori Ohta, Koji Masaki, Keisuke Kidono
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Publication number: 20090313764Abstract: The present invention relates to springs made from compositions comprising rubber, foam formulated therewith and resulting bedding products such as foam mattress or toppers as well as other cushioning elements in a bedding or a seating product.Type: ApplicationFiled: June 22, 2007Publication date: December 24, 2009Applicant: Latexco NVInventor: Erik Deporte
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Publication number: 20090263604Abstract: To provide a novel cross copolymer and resin composition which are improved in heat resistance and compatibility over conventional ethylene/aromatic vinyl compound copolymers and which have low crystallinity, are excellent in softness, transparency and compatibility and show mechanical properties similar to soft vinyl chloride resins, as compared with conventional cross copolymers.Type: ApplicationFiled: May 29, 2007Publication date: October 22, 2009Applicant: Denki Kagaku Kogyo Kabushiki KaishaInventors: Toru Arai, Masaru Hasegawa, Ayumu Tsukamoto, Akira Miyama, Shigeru Suzuki
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Publication number: 20090234035Abstract: The present invention relates to compositions comprising blends of alkenyl aromatic polymers such as styrenic polymers (i.e. PS and HIPS) and bio-based or biodegradable polymers (i.e. PLA, PGA, PHA, PBS, PCL) compatibilized with styrene-based copolymers (i.e. styrene-ethylene-butylene-styrene (SEBS) block copolymers, maleated SEBS, styrene-maleic anhydride (SMA) copolymer, styrene-methyl methacrylate (SMMA) copolymer) or a mixture of two or more styrene-based copolymers such as SEBS and SMA. These novel compositions can be extruded and thermoformed to produce very low density food service and consumer foam articles such as plates, hinged lid containers, trays, bowls, and egg cartons with good mechanical properties.Type: ApplicationFiled: March 14, 2008Publication date: September 17, 2009Inventors: Yunwa Wilson Cheung, David V. Dobreski, Richard Turner, Mark Wheeler
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Patent number: 7579384Abstract: An expanded molded article having a void percentage of 5 to 50%, the molded article comprising 50 to 800 parts by weight of styrene-based resin relative to 100 parts by weight of non-crosslinked linear low-density polyethylene-based resin which can be obtained by using a metallocene catalyst, wherein the molded article is obtained by impregnating styrene-modified linear low-density polyethylene-based resin beads with a volatile blowing agent to provide expandable beads, pre-expanding the expandable beads and then subjecting the obtained pre-expanded beads to expansion molding, the styrene-modified linear low-density polyethylene-based resin beads each have the styrene-based resin dispersed in the form of particles, and a diameter of particle is 0.8 ?m or smaller in a surface region within at least 5 ?m from the bead surface and in a center region within a 5 ?m radius from the bead center.Type: GrantFiled: September 20, 2005Date of Patent: August 25, 2009Assignee: Sekisui Plastics Co., Ltd.Inventors: Hideyasu Matsumura, Tatsuya Matsugashita
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Publication number: 20090197983Abstract: An extruded polymeric foam comprising a styrenic polymer and an olefinic polymer, the olefinic polymer in an amount less than the amount of the styrenic polymer. The styrenic polymer and the olefinic polymer are present as a blend, preferably free of an interpolymer or compatiblizer. The foam has a density below about 36 kg/m3 (as measured by ASTM D1622-03), a vertical compressive strength greater than about 100 kPa (as measured by ASTM D1621-04) and a compressive strength ratio greater than about 0.35.Type: ApplicationFiled: December 15, 2008Publication date: August 6, 2009Inventors: Chau Van Vo, David J. Frankowski, Stephane Costeux
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Publication number: 20090152754Abstract: A thermoplastic elastomer composition for foam injection molding is provided that includes component (A), component (B), component (C), and component (D) below, relative to 100 parts by weight of component (A), component (B) having a content of 5 to 150 parts by weight, component (C) having a content of 5 to 300 parts by weight, and component (D) having a content of 5 to 150 parts by weight. (A): A hydrogenated product of a block copolymer comprising a block composed of an aromatic vinyl compound-based monomer unit and a block composed of a conjugated diene compound-based monomer unit, the hydrogenated product having a weight-average molecular weight of not more than 200,000, (B): a propylene resin, (C): a mineral oil, and (D): an ethylene-propylene copolymer rubber having a Mooney viscosity (ML1+4, 100° C.) of 20 to 200, an ethylene-based monomer unit having a content of 40 to 80 wt % (relative to 100 wt % of the copolymer rubber).Type: ApplicationFiled: December 4, 2008Publication date: June 18, 2009Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Kazuyoshi FUSE, Yuya YAMAMOTO
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Publication number: 20090100704Abstract: The present invention provides a resin composition capable of providing foams (non-crosslinked and crosslinked foams) which have low specific gravity and low compression set (CS) and are excellent in tensile strength properties, tear strength properties and vibration-damping properties at room temperature to high temperatures, and a foam of the resin composition. The resin composition for foams of the present invention comprises 5 to 95 parts by weight of an ethylene/?-olefin copolymer (A) and 5 to 95 parts by weight of a hydrogenated copolymer (B) obtained by hydrogenating a copolymer comprising a conjugated diene and a vinyl aromatic compound, and is characterized in that the hydrogenated copolymer (B) does not have a glass transition point of not higher than ?10° C. when measured at a frequency of 1 Hz in accordance with JIS-K7198.Type: ApplicationFiled: May 17, 2006Publication date: April 23, 2009Applicant: Mitsui Chemicals, Inc.Inventors: Takayuki Kajihara, Eiji Shiba, Masayoshi Yamaguchi, Kiminori Noda
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Publication number: 20090069455Abstract: The present invention relates to an extruded styrenic resin foam and a method for producing the same, wherein a base resin composing the extruded styrenic resin foam is a styrenic resin mixture of a styrene-(meth)acrylic ester copolymer, or a combination of a styrene-(meth)acrylic ester copolymer and polymethyl methacrylate, and a styrenic resin except the styrene-(meth)acrylic ester copolymer, and the styrenic resin mixture contains a (meth)acrylic ester component at a ratio of 4 to 45% by weight with reference to the styrenic resin mixture. The present invention provides an extruded styrenic resin foam having an apparent density of 20 to 60 kg/m3, a thickness of 10 to 150 mm, and a low thermal conductivity, and keeping excellent heat insulation performance over a long period of time and flame retardancy, even when the styrenic resin extruded foam is foamed using a blowing agent having an ozone depleting potential of 0 (zero) and a low global warming potential.Type: ApplicationFiled: April 15, 2008Publication date: March 12, 2009Applicant: JSP CORPORATIONInventors: Shunsuke Sekiya, Atsushi Taira, Noritoshi Nishiyama, Naochika Kogure
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Publication number: 20090030099Abstract: An object of the present invention is to provide a foam having reduced hardness and density, and an improved resistance to compression set, as well as a foam composition for producing such a foam. This object is achieved by a foam composition described below. The foam composition of the present invention comprises a thermoplastic elastomer which has a side chain containing imino group and/or a nitrogen-containing heterocycle, and a carbonyl-containing group; and a blowing agent.Type: ApplicationFiled: February 21, 2006Publication date: January 29, 2009Applicant: The Yokohama Rubber Co., Ltd.Inventors: Keisuke Chino, Tomoyuki Sakai
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Publication number: 20090023826Abstract: The present invention provides a crosslinked polyolefin resin foam which is excellent in heat resistance, and also can be secondarily processed into a complicated shape. The crosslinked polyolefin resin foam includes a polyolefin resin composition containing 20 to 50% by weight of a polypropylene-based resin (A) which shows at least one endothermic peak measured by differential scanning calorimeter at a temperature of 160° C. or higher, 20 to 50% by weight of a polypropylene-based resin (B) which shows an endothermic peak measured by differential scanning calorimeter at a temperature of lower than 160° C., and 20 to 40% by weight of a polyethylene-based resin (c), and can be obtained by forming the polyolefin resin composition into an optional form and foaming and crosslinking the resin.Type: ApplicationFiled: May 11, 2006Publication date: January 22, 2009Applicant: TORAY INDUSTRIES, INC.Inventors: Keisuke Nishimura, Masahiko Oyama, Yoshiyuki Oka, Fusayoshi Akimaru
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Publication number: 20090012194Abstract: The present invention provides a foam comprising (a) a polylactic acid resin, (b) at least one thermoplastic resin selected from a polyolefin resin and a polystyrene resin, and (c) a block copolymer of a vinyl aromatic compound and a conjugated diene, wherein a ratio of (a) to (b) by weight (a/b) is 80/20 to 20/80, and the foam comprises 0.5 to 20 parts by weight of (c) with respect to 100 parts by weight of (a) and (b) in total.Type: ApplicationFiled: January 18, 2007Publication date: January 8, 2009Applicant: Asahi Kasei Chemicals CorporationInventors: Tohru Okuda, Shoichiro Harada, Yoshihito Fukasawa
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Publication number: 20080287559Abstract: A thermally stable brominated butadiene copolymer, such as brominated styrene/butadiene block copolymer, brominated random styrene/butadiene copolymer or brominated styrene/butadiene graft copolymer, preparation of the brominated butadiene copolymers, use of the brominated butadiene copolymers as a flame retardant additive and polymeric compositions, both foamed and non-foamed, that incorporate a flame-retarding amount of brominated butadiene copolymer.Type: ApplicationFiled: October 23, 2006Publication date: November 20, 2008Inventors: Bruce A. King, William G. Stobby, Daniel J. Murray, Anteneh Z. Worku, Inken Beulich, Sheila M. Tinetti, Stephen F. Hahn, Ray E. Drumright
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Publication number: 20080281012Abstract: The present invention provides an additive for thermoplastic polymer foams which provide for enlarged cell size or with decreased density with minimal impact on the thermal mechanical properties of the thermoplastic foam. The additive is an essentially block copolymer blowing agent compatibilizer. Including the additive in a thermoplastic foaming composition comprised of a thermoplastic polymer resin and a physical blowing agent provides for the production of foam having enlarged cell size or with decreased density and minimal impact on the thermal mechanical properties of the thermoplastic foam. The block copolymer compatibilizer has at least a first block having at least one functionality compatible with the thermoplastic resin and at least one second block having a functionality compatible with the blowing agent.Type: ApplicationFiled: January 18, 2007Publication date: November 13, 2008Applicant: Arkema Inc.Inventor: Brett L. Van Horn