Abstract: A water treatment system is disclosed. The water treatment system comprises a filtration module comprising one or more ultrafiltration membrane configured to remove one or more non-PFAS contaminant from a PFAS contaminated water stream to provide a partially purified water stream containing soluble PFAS contaminants. The water treatment system also comprises a sorption module comprising one or more sorption units comprising a sorbent material, the sorption module being in fluid communication with the filtration module and downstream therefrom and configured to remove substantially all PFAS contaminants from the partially purified water stream to provide purified water that is substantially free from PFAS contamination.

Abstract: A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

Abstract: Methods of stabilizing virgin ion exchange resin material are provided. The methods include cleansing the virgin ion exchange resin material with a preparation comprising a non-ionic detergent. The methods include cleansing the virgin ion exchange resin material with a preparation comprising an alcohol solvent. The methods include rinsing virgin ion exchange resin material with deoxygenated water. the methods include introducing the cleansed/rinsed virgin ion exchange resin material into a gas impermeable vessel and hermetically sealing the vessel. The methods include introducing an oxygen scavenging material into the gas impermeable vessel, and hermetically sealing the vessel. A method of facilitating water treatment in a site in need thereof by providing a cleansed virgin ion exchange resin material in deoxygenated water is also disclosed.

Abstract: The present disclosure provides a system for efficiently preparing taurine, including: a solution storage unit configured to store a solution containing alkali metal taurinate, the solution being prepared by an ethylene oxide process; an ion exchange unit including at least one ion exchange resin column each configured to be activated by a first activation manner or a second activation manner independently, the first activation manner using sulfurous acid for activation to obtain alkali metal bisulfate and taurine, and the second activation manner using sulfuric acid for activation to obtain alkali metal sulfate and taurine; and a dispensing unit connected to the solution storage unit and the ion exchange unit respectively, and configured to adjust an amount of a solution conveyed from the solution storage unit to each of the at least one ion exchange resin column in the ion exchange unit.

Abstract: Some embodiments of the invention include inventive catalysts (e.g., catalysts of Formula (I)). Other embodiments include compositions comprising the inventive catalysts. Some embodiments include methods of using the inventive catalysts (e.g., in hydrofluorination of an organic compound). Further embodiments include methods for making the inventive catalysts. Additional embodiments of the invention are also discussed herein.

Abstract: A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

Abstract: The present disclosure relates to a process for reducing the amount of carbon disulphide (CS2) in a hydrocarbon feed containing C5-C8 fractions. The hydrocarbon feed is treated with an amine functionalized anion exchange resin (basic anion exchange resin) to obtain a mixture comprising a liquid fraction containing treated hydrocarbon and a solid mass containing an adduct of CS2 and the amine functionalized anion exchange resin. The so obtained liquid fraction containing the treated hydrocarbon is separated from the solid mass to obtain the hydrocarbon having CS2 content less than 2 ppm. The amine functionalized anion exchange resin can be regenerated from the solid mass.

Abstract: Provided is a method of cleaning a collection of resin beads, wherein the method comprises bringing the collection of resin beads into contact with an aqueous solution, wherein the aqueous solution comprises one or more dissolved amine compounds, wherein the collection of resin beads comprises polymer that comprises attached carboxylic acid groups or sulfonic acid groups or a mixture thereof.

Abstract: Novel water softening products and methods of treating hard water are provided. The products comprise a salt and a metal chelating agent. The products are useful for regenerating ion exchange material in a water softening system and providing softened water containing both sodium and potassium ions, while having dramatically increased efficiencies over prior art products.

Abstract: Provided is a method of regenerating an acrylic resin (B2), comprising (A) providing a collection of particles of acrylic resin (B2) that has calculated Hansch parameter of ?1.0 to 2.5, wherein one or more humic acid, one or more fulvic acid, or a mixture thereof, is adsorbed onto said acrylic resin (B2), and (B) bringing said collection of particles of acrylic resin (B2) into contact with an aqueous solution (RA) having pH of 4 or lower, to form a mixture B2RA, (C) then separating acrylic resin (B3) from said mixture B2RA.

Abstract: Provided is a method of regenerating an acrylic resin (B2), comprising (A) providing a collection of particles of acrylic resin (B2) that has calculated Hansch parameter of ?1.0 to 2.5, wherein one or more humic acid, one or more fulvic acid, or a mixture thereof, is adsorbed onto said acrylic resin (B2), and (B) bringing said collection of particles of acrylic resin (B2) into contact with an aqueous solution (RB) having pH of 10 or higher, to form a mixture B2RB, (C) then separating acrylic resin (B4) from said mixture B2RB.

Abstract: A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

Abstract: A catalyst prepared by polymerizing 0-98 weight % butylstyrene; 0-80 weight % vinyl toluene; 1.5-25 weight % divinyl benzene having 1-98 weight % of ethyl vinyl benzene; and 0-80 weight % styrene. Copolymer beads are made, sulfonated, and used as a catalyst.

Abstract: Provided is a method for resourceful utilization of desorption liquid generated in the resin ion exchange process. This method effectively separates highly-concentrated organics and salts from the desorption liquid and puts these two components into comprehensive utilization.

Abstract: Polymers, particularly those used in pressure-sensitive adhesives, are prepared from a mixture of structural isomers of a secondary alkyl (meth)acrylate monomer. The mixture is made by dehydrating a biobased C2-C22 alcohol with a first acid catalyst using a continuous process to form a mixture of olefins, and reacting (meth)acrylic acid with at least some of the mixture of olefins in the presence of a second acid catalyst. The adhesives are characterized by exhibiting an overall balance of adhesive and cohesive characteristics, and containing biobased material.

Abstract: The present invention relates to a water softening device including: a resin chamber which has an ion exchange resin and softens hard water passing through the ion exchange resin; and electrodes which are arranged by placing the resin chamber therebetween and apply voltages to the resin chamber so as to soften the hard water, and which regenerates the ion exchange resin, wherein the ion exchange resin is a slightly acidic cation exchange resin and/or a weakly alkaline anion exchange resin. The present invention provides the water softening device capable of easily regenerating the ion exchange resin and repeating the softening-regenerating without using chemicals or the like while maintaining the performance of softening water, thereby enabling a continuous use thereof.

Abstract: An ion-exchange membrane is provided, and the fibers of the ion-exchange membrane are obtained by electrospinning. The electrospinning solution contains 100 parts by weight of polyvinyl alcohol (PVA), 10-100 parts by weight of a modifier, 10-100 parts by weight of an ion exchanger, and 100-2,500 parts by weight of water. The modifier has a reactive group that can react with the hydroxyl groups of the PVA. The ion exchanger has a polar functional group that can form hydrogen bonds with the hydroxyl groups of the PVA, and has an anion group that can provide ion-exchange ability.

Abstract: Processes, systems, and methods for selectively regenerating an ion exchange resin generally comprises washing the ion exchange resin with an elution agent that encourages only selected contaminants, and especially selected radioactive isotopes, to disengage or decouple from the resin and enter solution in the elution agent, which thereafter is identified as the elution agent solution. The elution agent solution is then passed through a column of isotope-specific media (ISM). When the selected radioactive isotopes within the elution agent solution come into contact with the constituent media isotopes of the ISM, the selected radioactive isotopes are retained on the reactive surface areas of the ISM or within the interstitial spaces of the porous structures of the constituent media isotopes of the ISM. In some embodiments, the constituent media isotopes of the ISM are embedded, impregnated, or coated with the specific radioactive isotope that the particular ISM are adapted to separate.

Abstract: A plurality of laterals operably associated with a treatment unit for treating water and/or wastewater. The plurality of laterals can form many systems including a sludge removal system and a fluid scour system. The treatment unit can take many forms including but not limited to a filter and a sludge collection basin. Preferably, each of the plurality of laterals has a hollow passageway for permitting at least one of a fluid and a material to flow through each of the plurality of laterals. Each of the plurality of laterals includes means for permitting cleaning of a corresponding lateral to remove one or more obstructions obstructing the flow of one of a fluid and a material through at least a portion of the hollow passageway without damaging or altering the corresponding lateral. Preferably, the means for cleaning is configured to seal an opening in the corresponding lateral.

Abstract: Described herein is a process for producing phenol in which (a) benzene and hydrogen are contacted with a hydroalkylation catalyst under hydroalkylation conditions to produce cyclohexylbenzene; (b) the cyclohexylbenzene is contacted with an oxidation catalyst under oxidation conditions to produce cyclohexylbenzene hydroperoxide; (c) the cyclohexylbenzene hydroperoxide is contacted with a cleavage catalyst under cleavage conditions to produce a cleavage effluent comprising phenol and cyclohexanone; (d) the cyclohexanone is contacted with a dehydrogenation catalyst under dehydrogenation conditions to produce a dehydrogenation effluent having at least a portion of the cyclohexanone and a first contaminant; and (e) the first contaminant is contacted with an acidic material under contaminant treatment conditions to convert at least a portion of the first contaminant into a converted first contaminant. Phenol compositions made from the above-described process are also described herein.

Abstract: A method of processing ion exchange resin radioactive waste, wherein the radioactive waste contains a plurality of fractions of radioactive waste based on density, which may include cation resin waste and anion resin waste, wherein at least one of the plurality of fractions comprises a total concentration of at least one radionuclide, including performing at least one of the following operations (i), (ii) or (iii): (i) separating the at least one of the plurality of fractions from the radioactive waste utilizing a moving freeboard; (ii) separating the radioactive waste into cation resin waste and anion resin waste; or (iii) removing at least a portion of the total concentration of the at least one radionuclide from: the radioactive waste; the at least one of the plurality of fractions separated by the moving freeboard; or at least one of the radioactive waste, the cation resin waste or the anion resin waste.

Abstract: Described herein are compositions having (a) at least 99 wt % phenol; and (b) 0.1 wppm to 1000 wppm of at least one of the following components: bicyclohexane, cyclohexylbenzene, methylcyclopentylbenzene, hydroxycyclohexanone, cyclohexenone, cyclohexanol, cyclohexanone, cyclohexanedione, benzoic acid, hexanal, and methycyclopentanone, wherein the wt % and wppm are based upon the total weight of the composition.

Abstract: A water treatment system includes a weak acid cation resin where a portion of the feed water is exposed to the resin and then blended with untreated feed water to produce a stream of water with reduced mineral scaling and potential. Feed water is split into a first fluid stream, fed to a bypass conduit and a second fluid stream that is conveyed through a weak acid cation treatment bed. After passing through the bed, the treated fluid is combined with the bypass fluid stream to produce a blended feed water at the outlet. The ratio of the bypass fluid stream and treated fluid stream is a function of pH and L.S.I. A controller and associated sensors may control the relative flow rates between the bypass fluid stream and the treated stream to maintain a predetermined water parameter such pH, L.S.I., etc. within a predetermined range.

Abstract: The present invention relates to a method for removal of metal ions from an aqueous solution, which comprises contacting the aqueous solution with a phosphazene-formaldehyde resin as well as an ion exchange resin comprising a phosphazene-formaldehyde resin.

Abstract: Methods for producing or regenerating an iodinated anion exchange resin are presented. The methods include treating an iodide loaded anionic resin with an aqueous solution comprising an in situ formed I2 to produce the iodinated resin. The iodinated resins show reduced and stable levels of iodine elution compared to resins produced by conventional methods. Methods and systems for purifying water are also presented.

Abstract: Methods for producing or regenerating an iodinated resin are presented. The methods include converting iodide residues on a surface of and in pores of an iodide loaded anion exchange resin to iodine and iodine intermediates using a source of active halogen to form an iodinated resin having iodine and iodine intermediate residues on the surface of and in the pores of the iodinated resin. The iodinated resins show reduced and stable levels of iodine elution compared to conventional iodinated anion exchange resins and may utilizes less iodine raw materials during the manufacturing process. The iodinated resin can also act as an end-of life indicator in a water purification system that incorporates the iodinated resin to reduce microbial, including bacterial and viral, contamination in drinking water sources. Methods and systems for purifying water are also presented.

Abstract: A process for the reactivation of an acidic ion exchange resin is described. The invention relates to the treatment of an at least partially deactivated resin which has been deactivated by contact with an impure ethylenically unsaturated acid or ester containing target impurities. The reactivation includes the step of contacting the at least partially deactivated resin with an alcohol to thereby increase the activity thereof. The invention extends to reactivating a resin deactivated by contact with an impure ethylenically unsaturated acid, ester or nitrile containing target impurities by contacting the at least partially deactivated resin with an alcohol and a carboxylic acid to thereby increase the activity thereof. A reactivated resin and a process for preparing and purifying an ethylenically unsaturated acid or ester of the following formula: R1—C(?(CH2)m)—COOR2 are also described.

Abstract: A process for the reactivation of an acidic ion exchange resin is described. The invention relates to the treatment of an at least partially deactivated resin which has been deactivated by contact with an impure ethylenically unsaturated acid or ester containing target impurities. The reactivation includes the step of contacting the at least partially deactivated resin with an alcohol to thereby increase the activity thereof. The invention extends to reactivating a resin deactivated by contact with an impure ethylenically unsaturated acid, ester or nitrile containing target impurities by contacting the at least partially deactivated resin with an alcohol and a carboxylic acid to thereby increase the activity thereof. A reactivated resin and a process for preparing and purifying an ethylenically unsaturated acid or ester of the following formula: —R1—C(?(CH2)m)—COOR2 are also described.

Abstract: The present invention relates to block copolymer electrolyte composite membranes with improved ionic conductivity. The block copolymer electrolyte composite membrane in accordance with an aspect of the present invention can comprise a plate-like inorganic filler as surface-modified with a sulfonic group; and a block copolymer comprising at least one selected from the group consisting of a sulfonic group, a carbonic acid group, and a phosphoric acid group.

Abstract: The present invention relates to a method for removal of metal ions from an aqueous solution, which comprises contacting the aqueous solution with a phosphazene-formaldehyde resin as well as an ion exchange resin comprising a phosphazene-formaldehyde resin.

Abstract: The present embodiment relates to a method for recovering a boron adsorbent, including: preparing water having an electric resistivity of 0.01 M?·cm or more and kept at a temperature within a temperature range; and contacting the water with the boron adsorbent to release boron adsorbed at the boron adsorbent.

Abstract: Methods for producing or regenerating an iodinated anion exchange resin are presented. The methods include treating an iodide loaded anionic resin with an aqueous solution comprising an in situ formed I2 to produce the iodinated resin. The iodinated resins show reduced and stable levels of iodine elution compared to resins produced by conventional methods. Methods and systems for purifying water are also presented.

Abstract: Polymeric anion exchanger are used as host materials in which sub-micron sized hydrated Zr(IV) oxides (HZrO) particles are irreversibly dispersed within the ion exchange medium, such as beads or fibers. The HZrO can be impregnated into the pore structure of resin by mixing the parent anion exchange resin with zirconium solution prepared by pre-calcined zirconium oxide dissolved in concentrated mixture of alcohol and acid, and then followed by precipitation of HZrO particles within the resin by using alkaline solution. Since the anion exchangers have positively charged such as quaternary ammonium functional groups, anionic ligands such as arsenate, fluoride can transport in and out of the gel phase without subjected to the Donnan exclusion effect. Consequently, anion exchanger-supported HZrO submicron particles exhibit significantly greater capacity to remove arsenic and fluoride in comparison with parent anon exchange resins.

Abstract: Processes and apparatuses for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil are provided herein. An exemplary process for washing a spent ion exchange bed employed in purification of biomass-derived pyrolysis oil includes the step of providing a ion-depleted pyrolysis oil stream having an original oxygen content. The ion-depleted pyrolysis oil stream is partially hydrotreated to reduce the oxygen content thereof, thereby producing a partially hydrotreated pyrolysis oil stream having a residual oxygen content that is less than the original oxygen content. At least a portion of the partially hydrotreated pyrolysis oil stream is passed through the spent ion exchange bed. Water is passed through the spent ion exchange bed after passing at least the portion of the partially hydrotreated pyrolysis oil stream therethrough.

Abstract: The invention relates to a process for producing non-agglomerating mixed bed ion exchangers or mixed bed components.

Abstract: This invention relates to an improved process for producing weakly acidic cation exchange resins, in particular the purification of weakly acidic cation exchange resins derived from crosslinked poly(acrylonitrile) and also the use of steam for reducing the leaching of weakly acidic cation exchangers and finally a process for increasing the performance of water treatment systems, preferably of tap water treatment systems, using the weakly acidic cation exchangers produced according to the invention.

Abstract: The invention relates to a method for regenerating acidic cation exchangers, which are used as catalysts in the reaction of phenols with aldehydes or ketones to give bisphenols, in particular to give bisphenol A, with acids, with the proviso that, in the method according to the invention, these cation exchangers experience very little mechanical damage due to swelling processes during the regeneration process.

Abstract: The present invention relates to a process for separating a charged species from an aqueous system, wherein the process comprises the following steps: (a) a first aqueous system comprising the charged species is contacted at a first temperature with an ampholytic polymeric 5 system comprising cationic and anionic domains, wherein the charged species is bonded to the ampholytic polymeric system; and (b) the ampholytic polymeric system is contacted with a second aqueous system at a second temperature, wherein the charged species is released to the second aqueous system, wherein the second temperature is higher than the first temperature and wherein the second temperature is higher than the first temperature and wherein the second 10 temperature is less than 60° C.

Abstract: The present disclosure is directed towards systems and methods for the treatment of wastewater. A system in accordance with one particular embodiment may include a vacuum filter band system configured to receive a saturated ion exchange resin tank and to apply a water rinse to the resin to generate a resin slurry. The vacuum filter band system may further include a vacuum filter band configured to receive the resin slurry. The vacuum filter band system may also be configured to generate a mixed metal solution. The system may further include a metal specific purification system including a plurality of purification units configured to receive a continuous flow of the mixed metal solution, each of the purification units configured to target a particular metal from the mixed metal solution. Numerous other embodiments are also within the scope of the present disclosure.

Abstract: The present embodiment relates to a method for recovering a boron adsorbent, including: preparing water having an electric resistivity of 0.01 M?·cm or more and kept at a temperature within a temperature range; and contacting the water with the boron adsorbent to release boron adsorbed at the boron adsorbent.

Abstract: The present invention provides a novel and practical method for treating a perchlorate ion-containing liquid. The perchlorate ion-containing liquid is brought into contact with a weak base anion exchange resin, so that perchlorate ions are adsorbed to the weak base anion exchange resin, and then an acid is brought into contact with the resin, so as to remove the perchlorate ions from the weak base anion exchange resin to which the perchlorate ions are adsorbed. This makes it possible to repeatedly use the weak base anion exchange resin.

Abstract: A process for the reactivation of an acidic ion exchange resin is described. The invention relates to the treatment of an at least partially deactivated resin which has been deactivated by contact with an impure ethylenically unsaturated acid or ester containing target impurities. The reactivation includes the step of contacting the at least partially deactivated resin with an alcohol to thereby increase the activity thereof. The invention extends to reactivating a resin deactivated by contact with an impure ethylenically unsaturated acid, ester or nitrile containing target impurities by contacting the at least partially deactivated resin with an alcohol and a carboxylic acid to thereby increase the activity thereof. A reactivated resin and a process for preparing and purifying an ethylenically unsaturated acid or ester of the following formula:— R1—C(?(CH2)—COOR2 are also described.

Abstract: The membrane electrode assembly (MEA) of a PEM fuel cell can be recycled by contacting the MEA with a lower alkyl alcohol solvent which separates the membrane from the anode and cathode layers of the assembly. The resulting solution containing both the polymer membrane and supported noble metal catalysts can be heated under mild conditions to disperse the polymer membrane as particles and the supported noble metal catalysts and polymer membrane particles separated by known filtration means.

Abstract: A diamine absorbent that contains heat stable salts is regenerated using an ion exchange process wherein the cation exchange resin is regenerated using sulfurous acid reflux.

Abstract: Absorption of ethylene oxide is one of the methods commonly used to reduce air emissions from sterilization operations. Unlike prior art abators, the present method provides a means to regenerate the absorption medium within the abator and thus avoid the need to remove spent medium and load new medium every time the medium substantially consumed by the absorption process. Regeneration of the absorption medium is achieved through aqueous wash and air dry under ambient conditions and the regeneration cycle can be timed or automated as a function of medium consumption and regeneration of the liquid medium is achieved through electrochemical oxidation of the ethylene oxide reaction products.

Abstract: A method is provided for reducing natural organic fouling levels in contaminated ion exchange resins by contacting the resins with an oxidizing agent solution.

Abstract: A method and solution for eluting one of antimony(V) and a mixture of antimony(III) and antimony(V) from an ion exchange resin, comprises contacting the resin with an eluting solution comprising thiourea having a concentration of at least 0.002 M and hydrochloric acid having a concentration of at least 3 M. The method can be used for electrolytes in an industrial electrorefining process, by the further steps of contacting the electrolyte with an ion exchange resin to adsorb the antimony from the electrolyte and separating the resin from the electrolyte, before contacting the resin with the eluting solution comprising thiourea and hydrochloric acid. The method and solution address the difficulties of removing antimony(V), and allow for increased reuse of the resins.

Abstract: A process for the regeneration of loaded ion-exchange resin comprising (a) providing loaded resin for regeneration; (b) providing first stage and third stage regenerant suitable for regenerating loaded resin; (c) providing a plurality of regeneration vessels; (d) filling a regeneration vessel with a desired amount of the loaded resin before filling another regeneration vessel; (e) once a regeneration vessel has been filled, contacting the loaded resin within the vessel with first stage regenerant in a plug flow to provide a first stage regenerated resin; (f) contacting the first stage regenerated resin with third stage regenerant in a plug flow to provide regenerated resin and (g) removing and collecting third stage regenerant from a vessel containing regenerated resin and adding the collected regenerant to the first stage regenerant.

Abstract: A diamine absorbent that contains heat stable salts is regenerated using an ion exchange process wherein the cation exchange resin is regenerated using sulfurous acid reflux.

Abstract: This invention presents an ion exchange media including a plurality of cation exchange zones and anion exchange zones in flow paths that are contained in a substantially nonporous resin transport framework. During electrodeionization and other potential applications the ion exchange media of the invention prevents unfavorable water splitting at resin-membrane interfaces and encourages water splitting at resin-resin interfaces where the water splitting may be constructively used to regenerate the resin.