Abstract: A porous ion exchanger which has a porous structure having ion exchange resin particles bound by a binder polymer, and which has a water permeability of at least 30 kg.multidot.cm.sup.-1 .multidot.hr.sup.-1 under a pressure of 0.35 kg/cm.sup.2.

Abstract: Novel organic ion-exchange polymers and membranes formed from these polymers provide improved performance in electrolytic cells. The membranes exhibit an expanded micro-structure as the result of the removal of organic groups previously reacted with the ion-exchange groups of the polymer. The polymers are also useful in finely divided form as catalysts or deposited on a catalyst support. When formed into sheets, the polymers are useful as membranes in the separation of miscible liquids and in the separation of gases.

Abstract: A method for minimizing wastewater discharge generated in an ion exchange regeneration system having a cation exchange bed and an anion exchange bed, which method is characterized in that all of the segments of regenerant and displacement rinse are recirculated in a common loop, and shifted forward by one position, whereby the first segment is discarded in the subsequent cycle, and the last segment in the subsequent cycle is provide by fresh rinse, while chemicals are added as necessary, and in final rinse cycle, rinse flows through the cation exchange bed and the anion exchange bed in series, and recirculates in a loop, thereby eliminating over 90% of waste.

Abstract: A composition for regenerating spent weak cation exchange resin and a method of utilization including salts of .alpha.-hydroxy carboxylic acids or o-hydroxy benzoic acids. The following steps are employed in cyclically regenerating polycarboxylic acid cation exchange resins: (a) utilizing a charged or alkali metal salt of polycarboxylate acid cation resin to soften water; (b) regenerating the spent resin in one step with an active regenerant of the .alpha.-hydroxy carboxylic acids or o-hydroxy benzoic acids to produce spent regenerant; (c) precipitating the polyvalent hard ions in the spent regenerant with sodium or potassium carbonate to reform the active regenerant; (d) separating the precipitate; and (e) concentrating the dilute active regenerate solution to its approximate initial concentration and recovering of water for process rinses.

Abstract: The present invention provides methods for producing top anti-reflective coating compositions having a very low level of metal ions, utilizing specially treated ion exchange resins. A method is also provided for producing semiconductor devices using such top anti-reflective coating compositions.

Abstract: Proposed is a method for the preparation of an efficient ion exchanger useful for separation and recovery of cesium ions from an aqueous solution such as strongly acidic waste solutions containing radioactive species of cesium. The method comprises the steps of (a) adsorption of hexacyanoferrate (II) ions on to porous particles of an anion exchange resin, (b) conversion of the hexacyanoferrate (II) ions into water-insoluble copper salt thereof in situ in the resin pores, (c) an oxidation treatment of the resin particles and (d) a reduction treatment in the presence of potassium ions followed by contacting of the resin particles with an aqueous solution containing copper ions. A method for the regeneration of the ion exchanger after adsorption of cesium ions is also proposed.

Abstract: The present invention provides methods for producing top anti-reflective coating compositions having a very low level of metal ions, utilizing specially treated ion exchange resins. A method is also provided for producing semiconductor devices using such top anti-reflective coating compositions.

Abstract: Improved compositions for the treatment and regeneration of ion exchange resin beds typically used in water softening systems are provided, which possess enhanced iron sequestering capabilities. The compositions include citric acid and a salt of citric acid, together with an iron sequestration-enhancing amount of an agent including a quantity of a source of gluconic acid or salt of gluconic acid. Preferred agents include gluconic acid, the alkali metal gluconates, glucono lactone and mixtures thereof. The compositions are advantageously formulated as dry products, which can be mixed with a preponderant amount of sodium chloride to yield regenerating media.

Abstract: The invention relates to repeatedly regeneratable ion exchanger resins with a thin covering of alkyl-SH groups.

Abstract: Aqueous solutions of an amine N-oxide such as N-methyl morpholine N-oxide used in the manufacture of regenerated cellulose can be purified by passage through a strongly basic anion-exchange resin. The resin is regenerated by treatment with (1) an aqueous solution of a strong inorganic acid such as hydrochloric or sulphuric acid and (2) an aqueous solution of sodium hydroxide.

Abstract: A method is provided for regenerating deactivated sulfonated aromatic organic ion-exchange resin beds, such as a polystyrene ion-exchange resin bed, having chemically combined amino organo mercaptan groups with anhydrous phenol at an elevated temperature.

Abstract: In a method for separating and regenerating a mixed bed of exhausted anion and cation resins and for removing metallic foulants from the mixed bed, substantially all of the cation and anion resins in the bed are separated by their respective buoyancies and metallic foulants are displaced from the resins using an amine salt solution having a density between the densities of the anion and cation resins. A composition formed during this method comprises the anion resin, the metallic foulants, the cation resin, and the amine salt solution.

Abstract: An electrolytic process and apparatus are disclosed for regenerating separate bed ion exchange resins used to demineralize aqueous solutions, preferably softened water, without the use of additional chemicals. The cation exchanger is regenerated by applying a DC electric voltage between an anode and a cathode across the cation exchanger whereby hydrogen ions produced at the anode displace cations previously absorbed on the cation exchanger during the previous demineralization cycle. The displaced cations move towards the cathode under the influence of the electric voltage and there form a caustic solution with hydroxyl ions produced by the cathode. The cathodically generated caustic solution is then used to chemically regenerate the anion exchanger in a traditional manner. Two embodiments of the invention are disclosed, one of which is an intermittent system of demineralization and regeneration and the other is a continuously operating system.

Abstract: The present invention includes a process for rejuvenating a spent aqueous alkanolamine solution comprising use of alkyl-substituted ammonium-containing organic base treatment to remove inorganic ions.

Abstract: Water is purified to reduce pollution to less than 0.3%, by mixing re-generated and non re-generated anion and cation resins, followed by appropriate final mixing of both when re-generated, for further use.

Abstract: High pressure boiler condensate returns are polished and softened with a macroreticular cation exchange resin, and the resin is regenerated with a readily ionizable organic acid salt of a relatively low volatility amine corrosion inhibitor.

Abstract: A method of mixed-bed filtration and demineralization for removing suspended impurities from the primary cooling water in a power plant by means of a demineralizer having a mixed bed formed of a particulate cation and anion exchange resin that have such a surface layer structure that granules are seen to bind with one another under microscopic examination, being able to be operated in a safe and yet economical manner by virtue of established conditions for operating processes, such as regeneration of the demineralizer by backwashing and by passage of chemicals and also, replacement of the demineralizer.

Abstract: A method of regenerating an ion exchanger which is used to treat a solution introduced to the ion exchanger in a downward charging direction. The ion exchanger comprises a non-constrained bed of ion exchange material in the form of ion exchange granules and has a concentration profile through the ion exchange material after the solution has been introduced to the ion exchanger in the charging direction. The method in one embodiment comprises passing a regenerating solution upwardly through the non-constrained bed of ion exchange material in an intermittent pulsed flow comprising a pulse or up flow of regenerating solution, a subsequent non-flow pause time, followed by a down flow pulse in a direction opposite to the up flow.

Abstract: A method of regenerating an ion exchanger which is used to treat a solution introduced to the ion exchanger in a downward changing direction. The ion exchanger contains a non-constrained bed of ion exchange material in the form of ion exchange granules and has a concentration profile through the ion exchange material after solution has been introduced to the ion exchanger in the charging direction. The method of regenerating comprises passing a regenerating solution upwardly through the non-constrained bed of ion exchange material in an intermittent flow manner comprising an alternating up flow of regenerating solution followed by a down flow of liquid in a direction opposite to the up flow. The duration and velocity of the up flow of regenerating solution is sufficient to lift and generate a perceptible mixing of ion exchange materials in approximately the bottom portion of the ion exchange bed, with the down flow being sufficient to seat the bed very rapidly and terminate mixing.

Abstract: A water treatment apparatus and method for softening "problem water". The apparatus includes a pair of treatment tank assemblies, each tank including serially connected filter and ion exchange beds. When a tank assembly requires regeneration, the tank assembly is taken off line and is regenerated using a regenerating apparatus that communicates a mixture of citric acid and brine solution to the ion exchange bed, followed by brine solution alone to form a barrier. A mixture of sodium carbonate and brine solution is then communicated to the ion exchange bed followed by a backwashing step which conveys treated water through both the ion exchange bed and the filter media in a counter flow direction. The regeneration apparatus includes a brine venturi and a chemical draw venturi connected in a parallel flow relationship and solenoid control valves for selectively communicating either a citric acid reservoir or a sodium carbonate reservoir to the chemical draw venturi.

Abstract: Hydrogen chloride is stripped from spent basic ion exchange resin by treatment with a solution of a tertiary amine in an amide solvent. The eluent solution is treated with anhydrous ammonia to precipitate ammonium chloride. The solution of tertiary amine in amide solvent is separated from the precipitate and may be used to regenerate spent resin.

Abstract: The present invention provides a process for removing heat stable salts which accumulate in alkanolamine gas purification process units. Surprisingly, it has been found that weakly acidic cationic exchange resins are dramatically more effective for removing heat stable salts from alkanolamine solutions than strongly acidic cationic exchange resins.Specifically, it has been found in accordance with the invention that ion exchange resins are useful for purifying used aqueous alkanolamine solutions, in the following order of preference: Weak Acid IX>Weak Base IX>Strong Acid IX>Strong Base IX.

Abstract: The present invention provides a process for treating ion exchange resin which includes the steps of firstly introducing a liquor for treating the resin in substantially vertical upflow into a treatment zone in order to produce a fluidised bed comprising the resin and insoluble particulate matter interspersed with each other, and secondly separating the resin from the particulate matter through entrainment of the latter by the liquor being withdrawn from the fluidised bed in a substantially horizontal flow direction. An apparatus for performing the process outlined above is also disclosed.

Abstract: A process is disclosed for the removal of heat stable salts from ethanolamine gas purification process units using ion-exchange resins and for regenerating said ion-exchange resins in-situ.

Abstract: A water softening device is provided with a waste storage tank for receiving waste liquid, such as hard water used to draw out brine from a brine storage tank, as well as the used brine itself during a regeneration cycle. The tank outlet communicates with a sprinkler system, and when the sprinkler system is on, an injector valve sucks waste liquid from the waste tank to mix it in with the sprinkler system water and thereby further dilute the liquid. A method of processing the waste water accordingly includes collecting this waste liquid and preferably mixing it in with the sprinkler fluid. The brine waste and brine supply tanks in one embodiment are preferably formed as one unit with two separate compartments. The inlet pipe to the brine waste compartment has an overflow safety valve which senses, through a float mechanism, when the tank is substantially full. The valve has a normally closed port connected to a leach line or the like.

Abstract: This invention relates to a catalyst modified with mercapto amines, its preparation and its use for the preparation of bisphenols.

Abstract: A method for regenerating the exhausted anion and cation exchange resin in a mixed bed demineralizer which utilizes an interface tank to increase the volume of interface resin that is physically isolated to increase separation efficiencies. An anticipatory interface detection sample flow of cation resin is directed from an intermediate section of the separation vessel through a sample line into the interface tank simultaneously with the transfer of cation resin from the bottom of the separation vessel into a cation regeneration vessel. Upon detection of an interface by the entry of anion resin, or inert material if present, into the sample line, the transfer of cation resin into the cation regeneration tank is terminated. The remaining cation resin from the separation vessel is transferred into the interface tank until an interface is detected by the entry of anion resin, or inert material if present, into the cation transfer line.

Abstract: A method is provided for regenerating a mass of active resin contained in a water softening device connected in the water filling circuit of a washing machine. The water softener device has an internal volume which is equal to the sum of the volume of the mass of resin plus a free volume, and is selectively supplied with both fresh water and brine through respective valves controlled by a program control device. The water softening device is supplied with a volume of brine during a first period of time, and is subsequently supplied with a complementary volume of water during a second period of time. The sum of the volume of brine, which is selected according to the hardness of the supply water, and the complementary volume of water is equal to the free volume of the water softening device.

Abstract: An improved process for regenerating the ion exchange resin in a water softening system. The process substantially reduces the amount of water and salt required for regeneration of the resin. The process includes the steps of venting the resin tank to the atmosphere and draining eventually all of the water from around the resin. Next, a brine solution is added to the resin tank. This is allowed to remain in contact with the resin until the resin is regenerated, preferably aided by energizing a vibrator positioned on the exterior of the tank. Next, the brine solution is drained from the resin tank which is then filled with water to rinse the brine from the resin. After rinsing, the resin is ready for use.

Abstract: A cation exchange polyimide resin having resistance to organic solvents which contains polyamidocarboxylic acid units providing sites of ion exchange and represented by the formula (I): ##STR1## wherein R.sup.1 is a tetravalent organic group, and R.sup.2 is a bivalent organic group, which is capable of trapping cations from organic solvents.

Abstract: A method for rejuvenating a membrane or diaphragm from an electrochemical cell which comprises the steps of treating the membrane or disphragm with an inorganic acid at an elevated temperature so as to dissolve metallic particles and then optionally treating the membrane or diaphragm with a basic solution. Metals dissolved in the acid solution can be recovered by conventional methods.

Abstract: A method for removing organic foulants such as organic sulfonates from an anion exchange resin comprises treating the anion exchange resin at an elevated temperature with a defouling solution containing at least 6% ammonium sulfate (wt/wt sulfate). The method is useful for removing organic foulants from the anion exchange resin used for polishing condensate water in power plants.

Abstract: The invention concerns an ion exchange process and system, particularly for the regeneration step following a softening or desalination of aqueous solutions. The regenerant solution is fed in an upward stream through the ion exchanger in a direction opposite to the charging direction, as a sequence of intermittent pulse intervals consisting of pulse flow followed by a period of no flow. During the pulse flow, there is limited hydrodynamic lifting of the ion exchange resin beds in layers, followed by subsequent sedimentation during the pause period, without mixing of the layers.

Abstract: A process for reducing decomposition products released during use or storage from a strong base, Type II anion exchange resin in the hydroxide form by reacting either the chloride form or the sulfate form of the resin with a bisulfite salt before conversion of the resin to the hydroxide form, and the resin prepared from the process.

Abstract: Disclosed is a method of regenerating a cationic exchange resin that has been exposed to chlorate ion. The resin is treated with an acidic regenerating solution that contains sulfite ion in an amount at least stoichiometric with the amount of chlorate remaining on the resin. The resin can either be rinsed with water first and then contacted with an acidic regenerating solution containing sulfite, or the resin can be washed with acidic water containing sulfite ion and then treated with an acidic regenerating solution.

Abstract: In a method for separating and regenerating a mixed bed of exhausted anion and cation resins, substantially all of the cation and anion resins in the bed are separated by their respective buoyancies using an amine salt solution having a density between the densities of the anion and cation resins. A composition formed during this method comprises the anion resin, the cation resin, and the amine salt solution.

Abstract: An improved method is provided for regenerating cation exchange resin loaded with metal ion impurities from wet process phosphoric acid. A regenerant solution is used composed of a mixture of ammonium sulfate and sulfuric acid in predetermined proportions which are maintained during recycle of the regenerant. This solution is preferably formed from anhydrous ammonia and sulfuric acid. Calcium and magnesium sulfates are selectively crystallized from the regenerant solution in the form of readily filterable crystals.

Abstract: Spent aqueous alkanolamine solution containing free alkanolamine, alkali metal salts of anions which form heat stable salts with such alkanolamine and heat stable alkanolamine salts is reactivated by contacting the solution with an acidic cation ion exchange resin to remove alkali metal cations and alkanolamine cations resulting from (1) protonation of free alkanolamine with hydrogen on the resin and (2) the alkanolamine salts, followed by eluting the resin with aqueous ammonia to preferentially displace alkanolamine from the resin and thereafter eluting the resin with a dilute mineral acid to displace the ammonia, metal cations and any remaining alkanolamine. The displaced alkanolamine is recovered for reuse. The aqueous ammonia may also be recovered for reuse.

Abstract: A process for regenerating anion exchange resins loaded with organic contaminants is described. The anion exchange capacity of loaded resins can be increased by treatment with an aqueous mixture of a strong mineral acid and an organic solvent for naphthenic acid.

Abstract: A process for removing cations of a first alkaline earth metal species from an aqueous solution with an ion exchanger material that is a cation exchanger or contains one and subsequently regenerating the loaded or exhausted ion exchanger material. A cation exchanger that has been loaded in advance with cations of a second alkaline earth metal species is used to remove the cations of the first alkaline earth metal species. The cation exchanger that is loaded or exhausted with the first species to be removed is regenerated by bringing the loaded or exhausted cation exchanger into contact with an aqueous suspension of a slightly soluble carbonate and/or hydroxide of the second alkaline earth metal species, either alone or in a mixture with an anion exchanger, and introducing a CO.sub.2 -containing gas into the suspension.

Abstract: A process for removing heavy metal cations and/or alkali metal cations from aqueous solutions with an ion exchanger material that comprises a cation exchanger loaded with alkaline earth metal ions, and subsequently regenerating the loaded or exhausted ion exchanger material. The loaded or spent cation exchanger either alone or in a mixture with an anion exchanger is regenerated by bringing it into contact with an aqueous suspension of a slightly soluble carbonate and/or hydroxide of an alkaline earth metal ion and/or a completely or partially calcined, natural carbonate and introducing a CO.sub.2 -containing gas into the suspension.

Abstract: A method for separating and transferring an ion-exchange resin having the lower specific gravity from an ion-exchange resin having the higher specific gravity in an ion-exchange resin separating tank that is indispensable to a pure or ultrapure water producing plant and which is packed with a mixed bed of ion-exchange resins having different specific gravities is disclosed.

Abstract: A process for the removal of cationic impurities from inorganic solutions and especially wet process phosphoric acid solutions wherein the solutions are passed through an ammonium ion or hydrogen ion charged cation exchange resin to remove various metal cations and thereafter the ion exchange resin is regenerated using an excess volume of ammonium sulfate solution which is subsequently treated to precipitate and filter out the cationic impurities so that the ammonium sulfate solution may be recycled for further ion exchange regeneration.

Abstract: Mercury is removed from a gas stream using anion exchange resins.

Abstract: The invention is concerned with the improved compositions for the treatment and regeneration of ion exchange resin beds typically used in water softening systems for domestic or industrial applications. The compositions of the invention include those designed for addition to sodium chloride to yield a final regenerating medium for exchange resins, along with finished compositions including a preponderant proportion of sodium chloride. In pertinent part, the compositions of the invention include respective quantitites of citric acid and a salt of citric acid such as sodium or potassium citrate. In particularly preferred form, the compositions include a minor amount of an anti-caking agent selected from the group consisting of alkyl substituted napthalene sulfonates. The compositions in accordance with the invention are characterized by relatively low pH levels and the ability to minimize the oxidation of ferrous iron to the insoluble ferric form.

Abstract: Described are processes for improving and maintaining the performance of particulate and othe types of water-treatment solids, especially particulate ion exchange resins, filter media, and adsorbents which have become fouled with organic contaminants, micro-organisms, and wasteproducts thereof.

Abstract: A water softening apparatus and method for reducing odor in, and improving the taste of, problem water, including a pair of treatment tanks and a control valve assembly for determining which tank is on-line, and which tank is off-line, and for controlling the regeneration of the off-line tank. An exhausted tank is taken off-line and partially regenerated by communicating a regeneration solution from a reservoir to the tank and passing the solution through a resin compartment after which the solution is discharged to drain. After a predetermined quantity of regeneration solution is passed through the tank, the resin compartment is slowly rinsed using treated water from the on-line tank. Prior to fully rinsing the off-line tank, the fluid flow is terminated leaving a diluted regeneration solution in the off-line tank thereby keeping the off-line tank in a "high solids" condition.

Abstract: A method and apparatus for selecting the quantity of salt to be used during each regeneration of a water softener system. The quantity of salt used during each regeneration is approximately equal to the quantity of salt needed to regenerate the resin bed to a preselected design capacity, which is less than the maximum capacity of the resin bed. The design exchange capacity is approximately equal to the exchange capacity of the resin bed at a particular salt dosage, wherein the exchange capacity of the bed at the particular salt dosage divided by the particular salt dosage is generally equal to or greater than 2850. The system is regenerated when at the end of any preselected time period, the percentage of the design capacity of the resin bed used since the last regeneration cycle exceeds a predetermined percentage.In determining the salt dosage used during each regeneration cycle, the exchange capacity of the resin bed is determined for various salt dosages.

Abstract: A process is provided for removing cyanide from a dilute cyanide solution. The solution is passed through a weak base anion exchange resin to absorb cyanide complexes. The resin is eluted with a weakly basic Ca(OH).sub.2 solution, to produce a cyanide-rich eluate. Elution is accomplished by recycling the eluting fluid past a bed of solid Ca(OH).sub.2, to maintain the eluting fluid in Ca(OH).sub.2 saturation. Recycling in this manner produces an eluate with relatively high cyanide concentration using economical reagents. The eluate is subjected to an acidification/volatilization process including acidification, preferably with H.sub.2 SO.sub.4, heating by introduction of steam and removal of volatilized HCN by an air sparge. The HCN-rich off-gas and slats produced therefrom may be recycled in the process. The cyanide-depleted waste streams may be disposed of in, for example, tailings ponds.

Abstract: The present invention involves a process for removing water from mixtures of alcohols and water by contacting such a mixture with an ion exchange resin of either the cation or anion type. Prior to use for alcohol dehydration, the ion exchange resin itself is dehydrated if necessary or desired by contacting it with methanol, propanol, isopropanol, acetone or other like low molecular weight hydrophilic solvents. After use for alcohol dehydration, the ion exchange resin is regenerated by contacting it with these regenerating agents.