Polymer Characterized By Defined Size Or Shape Other Than Bead Or Pearl Patents (Class 521/29)
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Patent number: 11883563Abstract: A resin composition for a medical device to be subjected to gas low-temperature sterilization includes a resin and an ion exchanger.Type: GrantFiled: April 23, 2020Date of Patent: January 30, 2024Assignee: OLYMPUS CORPORATIONInventors: Koji Kobayashi, Takayuki Kondo, Rieko Niino, Masaya Iwamoto
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Patent number: 11820038Abstract: A handheld punch tool includes a housing, a die holder coupled to the housing, a die supported by the die holder, the die and the die holder defining a feed slot therebetween for receiving a workpiece to be cut, and a punch configured to reciprocate within the die holder, with a main body defining a first longitudinal axis extending centrally through the main body and a punch element extending from the main body along a second longitudinal axis parallel to the first longitudinal axis. The punch element is configured to cut a first distance into the workpiece per stroke of the punch when the feed slot faces a first side of the punch and to cut a second distance into the workpiece per stroke when the feed slot faces a second side of the punch opposite the first side. The first distance is greater than the second distance.Type: GrantFiled: October 13, 2021Date of Patent: November 21, 2023Assignee: MILWAUKEE ELECTRIC TOOL CORPORATIONInventors: Jacob C. Strachan, Benjamin J. Boldt, Gerald A. Zucca
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Patent number: 11746020Abstract: Sulfur-crosslinked olefins, particularly sulfur-crosslinked heavy hydrocarbon products having one or more sulfur-crosslinked olefin moieties, may undergo pyrolysis to form sulfur-doped porous carbon having high BET surface area values. Pyrolysis to form the sulfur-doped porous carbon may be particularly efficacious in the presence of a hydroxide base. BET surface areas up to 2000 m2/g or even higher may be obtained. Such sulfur-doped porous carbon may be prepared by combining a heavy hydrocarbon product with sulfur, heating to a first temperature state to form a liquefied reaction mixture containing a sulfur-crosslinked heavy hydrocarbon, homogeneously mixing a hydroxide base with the liquefied reaction mixture, and pyrolyzing the sulfur-crosslinked heavy hydrocarbon to form sulfur-doped porous carbon.Type: GrantFiled: January 24, 2020Date of Patent: September 5, 2023Assignee: EXXONMOBIL TECHNOLOGY AND ENGINEERING COMPANYInventors: Yi Du, Bradley D. Wooler, Stuart E. Smith, Brenda A. Raich, Clarence Chase, Lesheng Wang
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Patent number: 11000781Abstract: Provided is a process for purifying an aqueous solution, wherein the aqueous solution comprises one or more sugars and additionally comprises furfural, hydroxymethylfurfural, or a mixture thereof; wherein the process comprises passing the aqueous solution through a collection of resin particles; and wherein the resin particles comprise covalently bound acid functional groups.Type: GrantFiled: November 1, 2016Date of Patent: May 11, 2021Assignee: DDP SPECIALTY ELECTRONIC MATERIALS US 8, LLCInventors: Collin H. Martin, Stephen Pease
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Patent number: 10379090Abstract: An ion exchange chromatographic packing material is described that includes a copolymer grafted to support resin particles. The copolymer includes an ion exchange group, an ionic crosslinking group configured to ionically bind to the ion exchange group, and an adjustable ionization state group having at least a first net charge at the first pH and a second net charge at the second pH. An overall first net charge of the chromatographic packing material at the first pH is opposite in polarity to the overall second net charge of the chromatographic packing material. This allows impurities to be removed from the chromatographic packing material at the second pH.Type: GrantFiled: June 17, 2016Date of Patent: August 13, 2019Assignee: Dionex CorporationInventor: Christopher A. Pohl
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Patent number: 10191372Abstract: A polymer comprising recurring units derived from vinylanthraquinone, recurring units derived from acid labile group-substituted hydroxystyrene, and recurring units derived from hydroxystyrene is provided. The polymer is used as a base resin to formulate a positive resist composition having a high resolution and minimal LER.Type: GrantFiled: May 4, 2017Date of Patent: January 29, 2019Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Jun Hatakeyama, Daisuke Domon
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Patent number: 9376540Abstract: Polymeric porous particles have a continuous solid phase and at least two sets of discrete pores that are isolated from each other within the continuous phase and that have different average sizes. One set of discrete pores has a larger average size than another set of discrete pores by at least 50%. At least one set of discrete pores is free of detectably different marker materials. There porous particles can be prepared using evaporative limited coalescence techniques with especially chosen discrete pore stabilizing hydrocolloids to protect the pores during formation and to provide the different average sizes.Type: GrantFiled: January 25, 2013Date of Patent: June 28, 2016Assignee: EASTMAN KODAK COMPANYInventors: David Charles Boris, Teresa Joy Hosmer, Mridula Nair
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Publication number: 20150083667Abstract: Provided are filtration media and matrixes comprising a pulverized powder of ion exchange resin and a polymeric binder. The resin can be pulverized to an average particle size in the range of 50 to 250 microns and can comprise a cation exchange resin, an anion exchange resin, a chelating resin, a biologically-related ion exchange resin, or combinations thereof. The media can further comprise activated carbon. The binder can be ultra high molecular weight polyethylene. The filtration media can be used to make matrixes and systems. Methods of making and using the same are also provided.Type: ApplicationFiled: March 7, 2013Publication date: March 26, 2015Inventor: Mark R. Stouffer
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Patent number: 8846773Abstract: This invention relates to a method for manufacturing a cation exchange resin, wherein the method includes the steps of: copolymerizing a monovinyl aromatic monomer and a cross-linkable aromatic monomer to obtain a cross-linked copolymer; specifying a content of a leachable compound represented by formula (I) to be 400 ?g or less relative to 1 g of the cross-linked copolymer, wherein Z represents a hydrogen atom or an alkyl group, and l represents a natural number; and then sulfonating the cross-linked copolymer to form a sulfonylated cross-linked copolymer.Type: GrantFiled: May 8, 2012Date of Patent: September 30, 2014Assignee: Kurita Water Industries Ltd.Inventors: Takeo Fukui, Tetsuo Mizuniwa, Kazuhiko Tokunaga, Masako Yasutomi
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Patent number: 8816026Abstract: Monomer solution and liquid solution immiscible with the monomers in the monomer solution are cocurrently jetted upwardly in a pulsating manner in a reaction vessel. Monomer droplets are allowed to rise up in a controlled and smooth manner under the dynamic forces exerted by differential flow rate and differential pressure between the monomer and liquid solutions and the differential densities between the monomer and liquid solutions without causing coalescence, agglomeration and breakup of the monomer droplets and to stabilize by partial polymerization of the droplets at 50-60° C. The monomer droplets flow out horizontally into a polymerization reactor and get polymerized in the polymerization reactor under agitation at 80-85° C. The polymer beads are dried at 80-100° C. and sieved.Type: GrantFiled: February 4, 2013Date of Patent: August 26, 2014Assignee: Thermax LimitedInventors: Apte Ashutosh, Naik Shirish
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Patent number: 8765825Abstract: The invention relates to a method for manufacturing an anion exchange resin, wherein the method includes the step of contacting a water soluble polymer containing an anionic dissociative group with a resin to produce an anion exchange resin. In the method, an amount of contact of the water soluble polymer is 0.01 to 10 mmol/L, in terms of an amount of the anionic dissociative group, relative to 1 liter of the anion exchange resin, and a wafer surface flatness (Rms) of the anion exchange resin is 4 ? or less, determined by a silicon wafer test.Type: GrantFiled: May 8, 2012Date of Patent: July 1, 2014Assignee: Kurita Water Industries Ltd.Inventors: Takeo Fukui, Tetsuo Mizuniwa, Kazuhiko Tokunaga, Masako Yasutomi
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Publication number: 20140096596Abstract: The invention provides novel porous materials that are useful in chromatographic processes, e.g., solid phase extraction, and that provide a number of advantages. Such advantages include superior wetting characteristics, selective capture of analytes of interest, and non-retention of interfering analytes. The invention advantageously provides novel porous materials having a large percentage of larger pores (i.e. wide pores). The invention advantageously provides novel porous materials that overcome the problems of SPE of biological samples.Type: ApplicationFiled: May 18, 2012Publication date: April 10, 2014Applicant: WATERS TECHNOLOGIES CORPORATIONInventors: Darryl W. Brousmiche, Kevin D. Wyndham
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Patent number: 8617764Abstract: Provided are an ion conductive resin fiber, an ion conductive hybrid membrane, a membrane electrode assembly and a fuel cell. The ion conductive resin fiber comprises an inner layer including an ion conductive resin; and an outer layer including an ion conductive resin having larger EW than the ion conductive resin of the inner layer, and surrounding the inner layer. The ion conductive resin fiber and the ion conductive hybrid membrane are excellent in ion conductivity, polar solvent stability and dimensional stability under low humidity conditions. The fuel cell manufactured using the same has advantages of stable operation and management of a system at ease, removal or reduction of components related to water management, and even in case of low relative humidity, operation at high temperature of 80° C. or higher.Type: GrantFiled: May 28, 2009Date of Patent: December 31, 2013Assignee: LG Chem, Ltd.Inventors: Go-Young Moon, Won-Ho Lee, Sang-Hyun Lee, Young-Il Choi, Hyuk Kim
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Patent number: 8476324Abstract: A method for manufacturing an anion exchange resin, in which remaining of impurities and generation of decomposition products are suppressed and leachables are reduced, the method including the following steps (1-a) to (1-e) of: (1-a) obtaining a cross-linked copolymer by copolymerizing a monovinyl aromatic monomer and a cross-linkable aromatic monomer; (1-b) specifying the content of a specific leachable compound to be 400 ?g or less relative to 1 g of the cross-linked copolymer; (1-c) haloalkylating the cross-linked copolymer so as to introduce 80 percent by mole or less of haloalkyl group relative to the monovinyl aromatic monomer; (1-d) removing a specific leachable compound from the haloalkylated cross-linked copolymer; and (1-e) subjecting the haloalkylated cross-linked copolymer to a reaction with an amine compound.Type: GrantFiled: April 15, 2008Date of Patent: July 2, 2013Assignees: Kurita Water Industries Ltd., Mitsubishi Chemical CorporationInventors: Takeo Fukui, Tetsuo Mizuniwa, Kazuhiko Tokunaga, Masako Yasutomi
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Publication number: 20130081643Abstract: The invention relates to composite materials comprising particles of at least two different additive materials and a polymer binding said additive particles together the composite material. The invention also relates to incorporating at least two different additive materials into a filter material, using the composite material.Type: ApplicationFiled: March 31, 2011Publication date: April 4, 2013Applicant: BRITISH AMERICAN TOBACCO (INVESTMENTS) LIMITEDInventors: Peter Branton, Michele Mola
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Publication number: 20130053458Abstract: The present invention relates to a method for the production of improved shell functionalized ion exchange resins from core/shell copolymer having a highly crosslinked core.Type: ApplicationFiled: August 21, 2012Publication date: February 28, 2013Inventor: William I. Harris
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Patent number: 8349523Abstract: To provide an electrolyte membrane having excellent dimensional stability even upon absorption of water, a high proton conductance and high power generation performance; and a process for producing the electrolyte membrane with a high productivity. An electrolyte membrane for polymer electrolyte fuel cells, which is made mainly of an ion exchange resin and reinforced with a nonwoven fabric made of fiber of a fluororesin wherein at least some of intersecting points of the fiber are fixed, and which has, as the outermost layer on one side or each side, a layer not reinforced, made of an ion exchange resin which may be the same as or different from the above ion exchange resin, wherein the fluororesin is an ethylene/tetrafluoroethylene copolymer having a melting point of at most 240° C., and the above fixing is fixing by fusion of the fiber.Type: GrantFiled: March 20, 2009Date of Patent: January 8, 2013Assignee: Asahi Glass Company, LimitedInventors: Seigo Kotera, Hiroyuki Watabe, Shigeru Aida
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Patent number: 8309265Abstract: The present invention provides an electrolyte membrane for a fuel cell that has a minute projection cluster on one side or both sides of a polymer electrolyte membrane. Further, the present invention provides a production method of an electrolyte membrane for a fuel cell, wherein a mold comprising convex portions having a fixed planar pattern is pressed on one side or both sides of a polymer electrolyte membrane, then while concave portions of the polymer electrolyte membrane formed in the concave portions are being stretched, the mold is removed from the polymer electrolyte membrane for forming a minute projection cluster.Type: GrantFiled: August 31, 2004Date of Patent: November 13, 2012Assignee: Hitachi, Ltd.Inventors: Akihiro Miyauchi, Kenichi Souma, Shuichi Suzuki, Yoshiyuki Takamori, Masahiko Ogino, Takashi Ando, Hidetoshi Honbo
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Patent number: 8217094Abstract: A monolith separation medium comprising a skeletal phase and continuous pores forming a three-dimensional network structure, which has a functional group enabling the introduction of a new functional group on the surface of the skeletal phase. The skeletal phase has an average diameter of a submicron to micrometer size and is in a co-continuous structure of the non-particle-aggregation type. It is composed of an addition polymer of 1,3-bis(N,N?-diglycidylaminomethyl)cyclohexane as an epoxy compound with a bifunctional or higher amine compound, is rich in organic matters and is free from any aromatic-origin carbon atom. Thus, it is an organic polymer monolith separation medium of the non-particle-aggregation type.Type: GrantFiled: October 17, 2007Date of Patent: July 10, 2012Assignee: Shimadzu CorporationInventors: Ken Hosoya, Mari Sakamoto, Shigeyoshi Horiike
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Publication number: 20120024791Abstract: The present invention further is directed to the improved process for making by free radical polymerization a monodisperse, macroporous polymeric media with covalently bonded polymer chains. The media can be applied for chromatographic purification, resulting in polymer supports having improved protein binding capacity and resin selectivity, as well as methods relating to making and using the same.Type: ApplicationFiled: July 26, 2011Publication date: February 2, 2012Inventors: Martin J. Deetz, John J. Maikner
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Patent number: 8053483Abstract: A gas adsorbent which has sufficient gas adsorptivity for noxious gas components in a cigarette when brought into contact with a gas stream having a high flow rate as that when it passes through a cigarette filter, and which releases a small amount of bad odor components such as amine impurities and free noxious components which adversely affect health such as aromatic compounds derived from the gas adsorbent itself, the gas adsorbent satisfying conditions (I), (II), (IV) and (V) or conditions (I), (III), (IV) and (V), as described in the specification.Type: GrantFiled: August 10, 2006Date of Patent: November 8, 2011Assignee: Mitsubishi Chemical CorporationInventor: Hirohisa Kubota
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Publication number: 20110124492Abstract: The present invention provides a multifunctional nanocomposite with at least two components, at least one component of which is a nanoparticle that includes a polymer.Type: ApplicationFiled: September 17, 2010Publication date: May 26, 2011Inventors: Nikolai Loukine, Anjan Das, Danielle Norton, Darren Anderson
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Patent number: 7947748Abstract: A method for preparing monodisperse crosslinked bead polymers by introducing droplets having a harmonic mean size from 50 to 1500 microns and comprising at least one monomer, at least one crosslinker and a free-radical polymerization initiator into an aqueous medium through orifices to produce an aqueous suspension of droplets having a volume fraction of droplets from 35 to 64%; wherein the droplets are not encapsulated; causing the aqueous suspension of droplets to flow in a downward direction in a pipe in which the temperature is maintained at least 20° C. below the temperature at which the polymerization initiator has a half-life of 1 hour; and polymerizing the droplets in a reactor.Type: GrantFiled: December 29, 2008Date of Patent: May 24, 2011Assignee: Rohm and Haas CompanyInventors: John David Finch, Biwang Jiang, Aaron Sarafinas, Andrew M. Savo
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Patent number: 7893118Abstract: Solid and liquid compositions containing particles of highly fluorinated ion-exchange polymer having sulfonate functional groups with an ion exchange ratio of less than about 33. The compositions contain at least about 25% by weight of polymer particles having a particle size of about 2 nm to about 30 nm.Type: GrantFiled: March 22, 2010Date of Patent: February 22, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Dennis Edward Curtin, Edward George Howard, Jr.
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Patent number: 7833687Abstract: The present invention provides an aqueous dispersion of nonspherical fine resin particles having excellent storage stability and processability such as aggregation and adherence to other substances, a method for producing the aqueous dispersion of fine resin particles, and a method for producing toner particles using the aqueous dispersion of fine resin particles. The present invention relates to an aqueous dispersion of fine resin particles characterized in that the fine resin particles are nonspherical particles with an average minor axis being 0.02 ?m or more and 1.00 ?m or less and an average ratio of a major axis to a minor axis being 2.0 or more and 5.0 or less, a method for producing the aqueous dispersion of fine resin particles, and a method for producing toner particles using the aqueous dispersion of fine resin particles.Type: GrantFiled: October 6, 2009Date of Patent: November 16, 2010Assignee: Canon Kabushiki KaishaInventors: Masayoshi Kato, Takayuki Toyoda, Ryuji Higashi, Ryo Natori, Takaho Shibata, Yuya Chimoto, Takeshi Miyazaki
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Patent number: 7771891Abstract: Disclosed herein are an ionic conductor including a proton conductor, a process for production thereof, and an electrochemical device (such as fuel cell) with said ionic conductor, said ionic conductor being superior in ionic conductivity, water resistance, and film forming properties. The ionic conductor is formed from a polymer in which carbon clusters having ion dissociating functional groups are bonded to each other through connecting groups. The polymer is less water-soluble and more chemically stable than a derivative composed solely of carbon clusters; therefore, it permits many ion dissociating functional group to be introduced thereinto. Moreover, if ion dissociating functional groups are introduced into also the connecting group, it is possible to prevent the concentration of ion dissociating functional groups from decreasing as the result of polymerization. The polymer can be easily synthesized by simple condensation, substitution, and hydrolysis.Type: GrantFiled: December 19, 2008Date of Patent: August 10, 2010Assignee: Sony CorporationInventors: Koichiro Hinokuma, Bjoern Pietzak, Constance Gertrud Rost, Masafumi Ata, Yongming Li, Kazuaki Fukushima
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Publication number: 20100130626Abstract: A method for manufacturing an anion exchange resin, in which remaining of impurities and generation of decomposition products are suppressed and leachables are reduced, the method including the following steps (1-a) to (1-e) of: (1-a) obtaining a cross-linked copolymer by copolymerizing a monovinyl aromatic monomer and a cross-linkable aromatic monomer; (1-b) specifying the content of a specific leachable compound to be 400 ?g or less relative to 1 g of the cross-linked copolymer; (1-c) haloalkylating the cross-linked copolymer so as to introduce 80 percent by mole or less of haloalkyl group relative to the monovinyl aromatic monomer; (1-d) removing a specific leachable compound from the haloalkylated cross-linked copolymer; and (1-e) subjecting the haloalkylated cross-linked copolymer to a reaction with an amine compound.Type: ApplicationFiled: April 15, 2008Publication date: May 27, 2010Applicants: KURITA WATER INDUSTRIES LTD., MITSUBISHI CHEMICAL CORPORATIONInventors: Takeo Fukui, Tetsuo Mizuniwa, Kazuhiko Tokunaga, Masako Yasutomi
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Patent number: 7714028Abstract: Solid and liquid compositions containing particles of highly fluorinated ion-exchange polymer having sulfonate functional groups with an ion exchange ratio of less than about 33. The compositions contain at least about 25% by weight of polymer particles having a particle size of about 2 nm to about 30 nm.Type: GrantFiled: February 27, 2008Date of Patent: May 11, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Dennis Edward Curtin, Edward George Howard
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Patent number: 7709542Abstract: A proton-exchange composite includes a polymer matrix formed from a proton-exchange polymer and ionomer particles distributed therein. The polymer has side chains with ionic groups. The particles have an average particle size of less than 20 nm and include an oligomeric ionomer that interacts with the polymer and attracts the ionic groups on its side chains. The composite may be formed by a method in which an initiator is bonded to silica particulates. The initiator is used to initiate polymerization of a precursor monomer to form a salt form of the oligomeric ionomer bonded to the silica particulates, which is then reacted with an acid to produce the oligomeric ionomer, thus forming the ionomer particles. The ionomer particles are dispersed in a solution containing a solvent and the polymer dissolved therein. The solvent is removed. The residue is cured to form the composite.Type: GrantFiled: March 23, 2007Date of Patent: May 4, 2010Assignee: Agency for Science, Technology and ResearchInventors: Liang Hong, Zhaolin Liu, Xinhui Zhang, Bing Guo
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Publication number: 20090227693Abstract: To provide a gas adsorbent which has sufficient gas adsorptivity for noxious gas components in a cigarette when brought into contact with a gas stream having a high flow rate as that when it passes through a cigarette filter, and which releases a small amount of bad odor components such as amine impurities and free noxious components which adversely affect health such as aromatic compounds derived from the gas adsorbent itself.Type: ApplicationFiled: August 10, 2006Publication date: September 10, 2009Applicant: MITSUBISHI CHEMICAL CORPORATIONInventor: Hirohisa Kubota
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Patent number: 7582684Abstract: Ion exchange resins are described that are hydrophilic, crosslinked (meth)acrylic copolymers. The ion exchange resins are macroporous, have a surface area of at least 50 m2/g, and an average particle size of at least 20 micrometers. Additionally, chromatographic columns containing the ion exchange resins, composite materials containing the ion exchange resin, filtration elements containing the ion exchange resin, methods of preparing the ion exchange resins, and methods of separating or purifying negatively or positively charged materials with the ion exchange resins are described.Type: GrantFiled: February 17, 2005Date of Patent: September 1, 2009Assignee: 3M Innovative Properties CompanyInventors: Jerald K. Rasmussen, James I. Hembre
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Publication number: 20090166295Abstract: The invention discloses an adsorptive ion-exchange material, including a polymer of formulas land II. The material has adsorption ability as well as ion-exchange ability for absorbing metal ions, and can be directly spun into fibers of varying diameters. The invention also discloses a method for treating wastewater containing metal ions using the disclosed adsorptive ion-exchange material.Type: ApplicationFiled: October 8, 2008Publication date: July 2, 2009Inventors: Wen-Yi CHEN, Shu-Hui Cheng
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Patent number: 7544278Abstract: The invention includes novel anion exchange membranes formed by in situ polymerization of at least one monomer, polymer or copolymer on a woven support membrane and their methods of formation. The woven support membrane is preferably a woven PVC membrane. The invention also includes novel cation exchange membranes with or without woven support membranes and their methods of formation. The invention encompasses a process for using the membranes in electrodialysis of ionic solutions and in particular industrial effluents or brackish water or seawater. The electrodialysis process need not include a step to remove excess ions prior to electrodialysis and produces less waste by-product and/or by-products which can be recycled.Type: GrantFiled: April 19, 2004Date of Patent: June 9, 2009Assignee: Seventy-Seventh Meridian Corporation, LLCInventors: Tejraj Aminabhavi, Padmakar V. Kulkarni, Mahadevappa Y. Kariduraganavar
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Publication number: 20090105357Abstract: Disclosed herein are an ionic conductor including a proton conductor, a process for production thereof, and an electrochemical device (such as fuel cell) with said ionic conductor, said ionic conductor being superior in ionic conductivity, water resistance, and film forming properties. The ionic conductor is formed from a polymer in which carbon clusters having ion dissociating functional groups are bonded to each other through connecting groups. The polymer is less water-soluble and more chemically stable than a derivative composed solely of carbon clusters; therefore, it permits many ion dissociating functional group to be introduced thereinto. Moreover, if ion dissociating functional groups are introduced into also the connecting group, it is possible to prevent the concentration of ion dissociating functional groups from decreasing as the result of polymerization. The polymer can be easily synthesized by simple condensation, substitution, and hydrolysis.Type: ApplicationFiled: December 19, 2008Publication date: April 23, 2009Applicant: SONY CORPORATIONInventors: Koichiro Hinokuma, Bjoern Pietzak, Constance Gertrud Rost, Masafumi Ata, Yongming Li, Kazuaki Fukushima
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Patent number: 7501380Abstract: A blended composition of hydrogel polymer granules capable of selectively removing toxic dissolved metal species from water containing abundant innocuous species, and spacer particles which minimize contact between contiguous polymer granules is provided for reducing the impedance of water caused to flow through a confined bed of the composition.Type: GrantFiled: May 14, 2007Date of Patent: March 10, 2009Inventor: Norman B. Rainer
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Publication number: 20080119576Abstract: Size-selective hemocompatible porous polymeric adsorbents are provided with a pore structure capable of excluding molecules larger than 50,000 Daltons, but with a pore system that allows good ingress and egress of molecules smaller than 35,000 Daltons. The pore system in these porous polymeric adsorbents is controlled by the method of synthesis so that 98% of the total pore volume is located in pores smaller than 300 Angstroms (?) in diameter with a working pore size range within 100 to 300 ? in diameter. The porous polymeric adsorbents of this invention are very selective for extracting midsize proteins, such as cytokines and ?2-microglobulin, from blood and other physiologic fluids while keeping the components required for good health such as cells, platelets, albumin, hemoglobin, fibrinogen, and other serum proteins intact.Type: ApplicationFiled: November 20, 2006Publication date: May 22, 2008Inventors: Wei-Tai Young, Robert L. Albright, Thomas D. Golobish
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Patent number: 7279542Abstract: Polymeric micro- and nano-capsules formed of a spherical single hydrophobic polymer, chemically functionalised at their surface so as to comprise hydrophilic moieties thereon are disclosed. The capsules are susceptible of absorbing a perfume and of being optionally coated with an amphiphilic copolymer. They allow the preparation of perfume delivery systems, which provide a slow release of perfuming materials while improving the substantivity of the perfume on a substrate.Type: GrantFiled: June 7, 2005Date of Patent: October 9, 2007Assignee: Firmenich SAInventors: Lahoussine Ouali, Djamila Latreche
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Patent number: 7098253Abstract: Ion exchange resins are described that are hydrophilic, crosslinked (meth)acrylic copolymers. The ion exchange resins are macroporous, have a surface area of at least 50 m2/g, and an average particle size of at least 20 micrometers. Additionally, chromatographic columns containing the ion exchange resins, composite materials containing the ion exchange resin, filtration elements containing the ion exchange resin, methods of preparing the ion exchange resins, and methods of separating or purifying negatively or positively charged materials with the ion exchange resins are described.Type: GrantFiled: May 20, 2004Date of Patent: August 29, 2006Assignee: 3M Innovative Properties CompanyInventors: Jerald K. Rasmussen, James I. Hembre
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Patent number: 7094469Abstract: A porous or non-porous polymeric substrate having its surface modified with an immobilized fluorocarbon such as perfluorocarbon, polymeric composition is provided. The immobilized fluorocarbon is formed from a monomer having formula: [T—SO2Y—SO2T?]?M+ in which —T and T? are identical or different and comprise an organic radical bearing at least one active polymerization function such as an unsaturation or a ring that can be opened; —M+ comprises an inorganic cation.Type: GrantFiled: August 28, 2001Date of Patent: August 22, 2006Assignee: Mykrolis CorporationInventor: Wilson Moya
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Patent number: 7045057Abstract: A process for preparing an ion-exchangeable media within a moving-bed or simulated moving-bed device, which can create a true or simulated media flow, comprising the steps of packing the bed with ion-exchangeable media and passing a solution, containing a mixture of ionic species, through the media, wherein the solution is passed partly or completely counter-current to the media flow direction such that the ionic species are loaded to a desired level upon equilibration.Type: GrantFiled: April 11, 2003Date of Patent: May 16, 2006Assignee: Calgon Carbon CorporationInventors: Mark A. Bollinger, Chen-Chou Chiang
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Patent number: 6992115Abstract: Crosslinked particles are provided that are useful in the manufacture of dielectric materials for use in electronic devices such as integrated circuits. The crosslinked particles are prepared by activating crosslinkable groups on synthetic polymer molecules, where the crosslinkable groups are inert until activated and, when activated, undergo an irreversible intramolecular crosslinking reaction to form crosslinked particles.Type: GrantFiled: February 9, 2004Date of Patent: January 31, 2006Assignee: International Business Machines CorporationInventors: Craig Jon Hawker, Robert Dennis Miller, James Lupton Hedrick, Victor Yee-Way Lee
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Patent number: 6984669Abstract: The present invention provides a fluorinated cation exchange membrane comprising at least two layers, a first layer made of a fluoropolymer having sulfonic acid groups and a second layer made of a fluoropolymer having carboxylic acid groups on the cathode side thereof, wherein when an electrolytic soda process is conducted using the cation exchange membrane as a diaphragm between an anode compartment and a cathode compartment, the water transport number through the cation exchange membrane is at least 4.8 mol/F (F: Faraday) under operating conditions such that the brine concentration in the anode compartment is 200 g/L, the sodium hydroxide concentration in the cathode compartment is 32 mass %, the current density is 5 kA/m2, and the temperature is 90° C. The fluorinated cation exchange membrane of the present invention gives an excellent effect such that a uniform catholyte concentration can be maintained even when installed in an electrolytic cell having no special circulating means.Type: GrantFiled: November 10, 2003Date of Patent: January 10, 2006Assignee: Asahi Glass Company, LimitedInventors: Takuo Nishio, Yoshihiko Saito, Tetsuji Shimohira
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Patent number: 6930133Abstract: Low density polymeric beads made by polymerizing monomeric building blocks into large crosslinked polymer molecules in porous, spherical bead form by droplet or suspension polymerization in the presence of a porogen.Type: GrantFiled: May 30, 2003Date of Patent: August 16, 2005Inventors: Robert L. Albright, Richard Mapp
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Patent number: 6919382Abstract: The invention provides novel solid supports comprising dihydroxyalkyl aminoalkyl and dihydroxyalkylaminobenzyl groups, and methods for making and using them. The supports are particularly useful for immobilizing and derivatizing functionalized boronic acids for use in solid phase synthesis, such as those used in combinatorial chemistries. The compositions and methods of the invention are also useful as scavenger solid supports, e.g., in solution-phase parallel synthesis of small molecule libraries, and for use in resin-to-resin transfer reactions via phase transfer of solid supported boronic acids under both aqueous and anhydrous conditions. The methods of the invention provide convergent solid-phase synthesis of symmetrically or unsymmetrically functionalized compounds, such as biphenyl compounds. Also provided are synthesizer devices, e.g., semiautomated parallel synthesizers.Type: GrantFiled: August 31, 2001Date of Patent: July 19, 2005Assignee: The Governors of the University of AlbertaInventor: Dennis G. Hall
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Patent number: 6916853Abstract: Solid and liquid compositions containing particles of highly fluorinated ion-exchange polymer having sulfonate functional groups with an ion exchange ratio of less than about 33. The compositions contain at least about 25% by weight of polymer particles having a particle size of about 2 nm to about 30 nm.Type: GrantFiled: December 20, 2002Date of Patent: July 12, 2005Assignee: E. I. du Pont de Nemours and CompanyInventors: Dennis Edward Curtin, Edward George Howard, Jr.
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Patent number: 6881761Abstract: Disclosed are (1) a porous polymer particle comprising a polymer substrate having ester bonds connected to a group containing a quaternary ammonium structure through a spacer molecule, (2) an alkali-resistant, high-strength porous polymer particle having ester bonds connected to a group containing a quaternary ammonium structure through a spacer molecule, a part of the ester bonds being saponified and converted to a hydroxyl group(s), (3) a porous polymer particle comprising a polymer substrate having ester bonds connected to a group containing a quaternary ammonium structure through a spacer molecule, the porous polymer particles being treated with an alkaline solution to generate a hydroxyl and/or a carboxyl group on a surface of the substrate, (4) an anion exchanger comprising any one of the particles (1) to (3) above, (5) a packing material for anion chromatography comprising the anion exchanger (4) above, (6) a column for anion chromatography using the anion exchanger (4) above, and (7) a method for measType: GrantFiled: March 7, 2001Date of Patent: April 19, 2005Assignee: Showa Denko K.K.Inventors: Takashi Kotsuka, Kuniaki Shimbo, Hiroshi Suzuki, Hisako Sakuma, Toshio Tokuda
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Patent number: 6815466Abstract: A colloidally and sedimentation stable coating composition containing ion exchange resins is disclosed. A method of using a colloidally and sedimentation stable coating composition containing ion exchange resins is also disclosed.Type: GrantFiled: November 18, 2002Date of Patent: November 9, 2004Assignee: Rohm and Haas CompanyInventor: Paul Ralph Van Rheenen
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Patent number: 6712895Abstract: A method of producing a bituminous foam includes supplying a bitumen in water emulsion from a tank (2) into primary and secondary heating circuits (8, 34), whereby the emulsion is heated (via heating coils 12 and 12′) and its pressure raised such that, on discharge to ambient conditions via outlet pipes (30 or 30′), the emulsion foams as water evaporates therefrom.Type: GrantFiled: June 3, 2002Date of Patent: March 30, 2004Assignee: Totalfinaelf Bitumen LimitedInventor: Leslie Hoad
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Patent number: 6663775Abstract: A charge mosaic membrane having excellent selective permeability comprises a cationic polymer component, an anionic polymer component and a matrix component. Both of the cationic polymer component and the anionic polymer component are crosslinked particulate polymers. The matrix component is at least one polymer selected from a polysulfone resin, a polyarylate resin, a polyamide resin, a polyimide resin, a polyamideimide resin, a polyurethane resin, a fluorinated resin or a silicone resin. The charge mosaic membrane can be easily produced by conducting formation of the membrane by using a composition in which the cationic polymer component and the anionic polymer component are both dispersed in a solution of the matrix component in an organic solvent.Type: GrantFiled: February 22, 1999Date of Patent: December 16, 2003Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.Inventors: Takashi Fukutomi, Yoshifumi Sugito, Minoru Takizawa, Naomi Oguma, Seiji Doi, Michiei Nakamura
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Publication number: 20030130362Abstract: A colloidally and sedimentation stable coating composition containing ion exchange resins is disclosed. A method of using a colloidally and sedimentation stable coating composition containing ion exchange resins is also disclosed.Type: ApplicationFiled: November 18, 2002Publication date: July 10, 2003Inventor: Paul Ralph Van Rheenen