Polymer Characterized By Defined Size Or Shape Other Than Bead Or Pearl Patents (Class 521/29)
  • Patent number: 4247340
    Abstract: Impure sugar solutions containing charged particulate impurities are treated with strongly basic emulsion anion exchange resin particles to form flocs of the charged particulate impurities and the resin particles. These flocs remove dissolved ionic impurities because of their ion exchange functionality, and also remove color-imparting impurities.
    Type: Grant
    Filed: September 19, 1978
    Date of Patent: January 27, 1981
    Assignee: Rohm and Haas Company
    Inventor: Peter G. Cartier
  • Patent number: 4245053
    Abstract: A novel porous, weakly acidic, itaconic acid ion exchange resin and a process for its preparation are disclosed. The process comprises the copolymerization of the beta-monoalkyl ester of itaconic acid and a cross-linking agent such as divinyl benzene in the presence of a pore forming agent selected from the group consisting of aliphatic hydrocarbons of from 5 to 8 carbon atoms, alicyclic hydrocarbons of from 5 to 8 carbon atoms and halogenated hydrocarbons of from 1 to 3 carbon atoms, followed by hydrolysis of the resulting copolymer. The macroreticular itaconic acid ion exchange resin of this invention is characterized by an excellent combination of exchange capacity, heavy metals capturing capacity, ion exchange rate and gas adsorptive capacity.
    Type: Grant
    Filed: November 30, 1978
    Date of Patent: January 13, 1981
    Assignees: Pfizer Inc., City of Osaka
    Inventors: Susumu Nagai, Akira Ueda, Kuniei Toyoda
  • Patent number: 4228205
    Abstract: An unfoamed permeable material, which absorbs and desorbs moisture satisfactorily and which is suitable for making thin-walled articles having a maximum thickness of 3 mm, is based on plastic and/or rubber mixtures containing macromolecular hydrophilic fillers. The hydrophilic fillers are synthetic, water insoluble, cross-linked macromolecular materials containing pendent polar groups, which are able to bind water reversibly, e.g. hydroxy, amine, amide, carboxylic and sulfonic groups in H.sup.+, Na.sup.+, K.sup.+, Li.sup.+, Ca.sup.++, or Ba.sup.++ form, or quaternary ammonium groups in OH.sup.-, Cl.sup.- or HSO.sub.4.sup.- form.
    Type: Grant
    Filed: January 23, 1979
    Date of Patent: October 14, 1980
    Assignee: Ceskoslovenska akademie ved
    Inventors: Slavko Hudecek, Jaroslav Hnidek, Viktor Heidingsfeld, Jan Kolarik, Jiri Zelinger
  • Patent number: 4224415
    Abstract: 1. In a process for preparing a cation exchange resin having a water-insoluble matrix and cation exchange groups bonded thereto, the improvement comprising employing as said matrix a solid copolymer of macroreticular structure which is permeated by small channels or voids into which liquids are able to penetrate, which matrix is prepared by copolymerizing a mixture consisting essentially of (1) a monovinyl carbocyclic aromatic compound or an ester of acrylic or methacrylic acid, with (2) a polyethylenically unsaturated monomer selected from the group consisting of a polyvinyl carbocyclic aromatic compound, an ester of a dihydric alcohol and an .alpha.-.beta.
    Type: Grant
    Filed: July 18, 1958
    Date of Patent: September 23, 1980
    Assignee: Rohm and Haas Company
    Inventors: Erich F. Meitzner, James A. Oline
  • Patent number: 4221871
    Abstract: Novel, macroreticular cross-linked anion exchange and adsorbent copolymers of at least one monovinylidene ring-containing nitrogen heterocyclic monomer are prepared. Preferred monovinylidene ring-containing heterocyclic monomers are the various vinylpyridines.
    Type: Grant
    Filed: December 16, 1970
    Date of Patent: September 9, 1980
    Assignee: Rohm and Haas Company
    Inventors: Erich F. Meitzner, James A. Oline
  • Patent number: 4202775
    Abstract: An adsorbent comprising a porous copolymer produced by copolymerizing a cross-linkable monomer and a mono-ethylenically unsaturated monomer, said copolymer having pores of an average pore diameter (d) of 500 A to 6,000 A and having such a broad pore diameter distribution that the pore volume having a pore diameter in the range of from 0.5 d to 2 d is not more than 60% of the total pore volume in the copolymer. By the use of such a porous copolymer having a specific composition and pore characteristics, organic compounds (e.g. toxic compounds) adsorbed on the proteins (e.g. plasma proteins) present in intercellular and/or extracellular liquids (e.g. blood) can be effectively adsorption-removed. Especially when the present adsorbent is used for purification of blood, it is advantageously subjected to such a pretreatment that plasma proteins are adsorbed on the adsorbent and then crosslinked with a crosslinking agent.
    Type: Grant
    Filed: June 22, 1978
    Date of Patent: May 13, 1980
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tsutomu Abe, Akihiko Ikeda, Tokio Sakurai
  • Patent number: 4200695
    Abstract: Flocs prepared by mixing cationic and anionic emulsion ion exchange resins are useful as a filtration and deionization medium. Flocs prepared from weakly acidic and weakly basic emulsion ion exchange resins may be regenerated thermally.
    Type: Grant
    Filed: September 18, 1978
    Date of Patent: April 29, 1980
    Assignee: Rohm and Haas Company
    Inventors: Berni P. Chong, Eric G. Isacoff, James W. Neely
  • Patent number: 4187333
    Abstract: An ion-exchange hollow fiber is prepared by introducing into the wall of the fiber polymerizable liquid monomers, and polymerizing the monomers therein to form solid, insoluble, cross-linked, ion-exchange resin particles which embed in the wall of the fiber. Excess particles blocking the central passage or bore of the fiber are removed by forcing liquid through the fiber. The fibers have high ion-exchange capacity, a practical wall permeability and good mechanical strength even with very thin wall dimensions. Experimental investigation of bundles of ion-exchange hollow fibers attached to a header assembly have shown the fiber to be very efficient in removing counterions from solution.
    Type: Grant
    Filed: March 5, 1975
    Date of Patent: February 5, 1980
    Assignee: California Institute of Technology
    Inventors: Alan Rembaum, Shiao-Ping S. Yen, Elias Klein
  • Patent number: 4170696
    Abstract: A diethylaminoethyl derivative or its salt is reacted with a synthetic resin of a macroporous type having functional groups reactive with said diethylaminoethyl derivative or its salt, having a specific area of at least 1 m.sup.2 /g-dry resin and containing macropores of which the total volume of those with pore sizes from 100 A to 2,000 A is at least 0.1 cc/g-dry resin, in the presence of an alkaline compound to give an enzyme-immobilization carrier which can provide an immobilized enzyme high in activity with good activity retentivity and also large in amount of the immobilized enzyme per unit weight of the carrier.
    Type: Grant
    Filed: February 3, 1978
    Date of Patent: October 9, 1979
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hideo Hirohara, Shigeyasu Nabeshima, Tsuneyuki Nagase
  • Patent number: 4151053
    Abstract: Cation exchange membrane comprising a fluorocarbon polymer characterized by the presence of pendant carboxylic acid groups of the formula -- OCF.sub.2 COOH -- and derivatives thereof.
    Type: Grant
    Filed: March 17, 1978
    Date of Patent: April 24, 1979
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Naomi Seko, Yasumichi Yamakoshi, Hirotsugu Miyauchi, Mitsunobu Fukumoto, Kyoji Kimoto, Itaru Watanabe, Toshioki Hane, Sakae Tsushima
  • Patent number: 4139502
    Abstract: Extraction means for the selective extraction of nickel from aqueous solutions thereof, being an open-pore polyurethane foam supporting in its matrix a dioxime of the general formula ##STR1## wherein R and R' each designate an alkyl, aryl, aralkyl, alkaryl or a heterocyclic group, which may be substituted by a non-interfering substituent, or R and R' may form together a ring-structure so as to form cyclohexanedione glyoxime; optionally together with a plasticizer.
    Type: Grant
    Filed: October 25, 1977
    Date of Patent: February 13, 1979
    Assignee: Yeda Research and Development Company, Ltd.
    Inventors: Martin M. Halmann, Dai-Woon Lee
  • Patent number: 4113666
    Abstract: A process for producing strongly acidic cation-exchange fiber, which comprises allowing fibrous polyethylene to react with gaseous sulfur trioxide.
    Type: Grant
    Filed: June 24, 1976
    Date of Patent: September 12, 1978
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takezo Sano, Akira Kobayashi, Haruo Inoue
  • Patent number: 4101460
    Abstract: An ion exchange composition comprising an insoluble substrate of a synthetic resin having ion exchanging sites at least on its available surface; and a finely divided, insoluble material comprising synthetic resin particles of from about 0.1 to about 5 microns median diameter (with respect to volume) having, at least on their outer surfaces, ion exchanging sites which attract the ion exchanging sites of the substrate, irreversibly attached as a monolayer to the available surface of the substrate. The composition is used for removal and separation of ions, and is especially useful in liquid ion exchange chromatography.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: July 18, 1978
    Assignee: The Dow Chemical Company
    Inventors: Hamish Small, Timothy S. Stevens