Treating With Organic Chalcogen-containing Material Patents (Class 521/42.5)
  • Patent number: 9123842
    Abstract: A photoreceptor includes a multilayer blocking structure to reduce dark discharge of the surface voltage of the photoreceptor resulting from electron injection from an electrically conductive substrate. The multilayer blocking structure includes wide band gap semiconductor layers in alternating sequence with one or more narrow band gap blocking layers. A fabrication method of the photoreceptor includes transfer-doping of the narrow band gap blocking layers, which are deposited in alternating sequence with wide band gap semiconductor layers to form a blocking structure. Suppression of hole or electron injection can be obtained using the method.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: September 1, 2015
    Assignee: International Business Machines Corporation
    Inventors: Bahman Hekmatshoartabari, Jeehwan Kim, Devendra K. Sadana, Ghavam G. Shahidi, Davood Shahrjerdi
  • Patent number: 8912241
    Abstract: A rubber asphalt and a preparation method thereof are disclosed. The rubber asphalt comprises matrix asphalt and rubber powder modifier in a ratio of 4:1-4, wherein the rubber powder modifier comprises waste tire rubber powder and hexanediol in a ratio of 94-96:6-4. The method comprises the following steps: mixing the hexanediol with the waste tire rubber powder according to the ratio and stirring and wetting to obtain the rubber powder modifier; placing the matrix asphalt into a reaction kettle and heating to 90-170° C.; adding the rubber powder modifier into the reaction kettle according to the ratio; and raising the temperature to 190-210° C. under the stirring state to obtain the rubber asphalt. The rubber asphalt has an extensibility of 13-19 cm at 5° C., a penetration of 68-75 at 25° C. and a softening point of 53-90° C. The asphalt-aggregate ratio of a mixed material on the subsequent work section can be reduced to 6-8 from 8-10.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: December 16, 2014
    Inventor: Qiqiang Zhou
  • Patent number: 8901252
    Abstract: A method of decomposing an organic compound includes decomposing an organic compound by alkyl carbonate at 250° C. or more. The organic compound includes a cross-linked polymer. The cross-linked polymer includes a polymer cross-linked by organic peroxide cross-linking, radiation cross-linking, or silane cross-linking The alkyl carbonate includes dimethyl carbonate or diethyl carbonate.
    Type: Grant
    Filed: June 22, 2009
    Date of Patent: December 2, 2014
    Assignee: Hitachi Metals, Ltd.
    Inventors: Shingo Ashihara, Toshiharu Goto, Takanori Yamazaki
  • Publication number: 20140336288
    Abstract: Processes for recovering natural rubber from an aqueous natural rubber latex that contains extractables and one or more additives and that is essentially free of lignocellulosic plant material are described. Natural rubber in the latex is separated from the water. Preferably, the amount of non-rubber extractables in the natural rubber is reduced by one or more extraction steps yielding a dried natural rubber.
    Type: Application
    Filed: July 23, 2014
    Publication date: November 13, 2014
    Applicant: Bridgestone Corporation
    Inventors: William M. COLE, Georg G.A. BOHM, Walter TOMASZEWSKI, Yingyi HUANG
  • Patent number: 8852718
    Abstract: Surface coating composition, method and apparatus for coating a surface. The surface coating composition comprises a recycled rubber product, one or more binding agent and optionally one or more additional agent.
    Type: Grant
    Filed: February 15, 2013
    Date of Patent: October 7, 2014
    Inventors: Mathieu Malboeuf, Dorian Braun
  • Patent number: 8304460
    Abstract: The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 ?m or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 ?m in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials.
    Type: Grant
    Filed: June 17, 2009
    Date of Patent: November 6, 2012
    Assignee: Rohm and Haas Company
    Inventors: Willie Lau, Donald C. Schall, Harry R. Heulings, IV, Kimberly B. Kosto, Joseph M. Rokowski
  • Publication number: 20120184634
    Abstract: This invention proposes a method for thermal regeneration of waste rubber; add rough powder particle of waste rubber/environmental softener/powder material with weight ratio ranging among 100/8˜150/20˜1500 into mixing heater; first carry out oxygen-free heating and then divert into mixing cooler to cool below 100° C.; the discharge material is product; or set aside some or all powder material and then slowly add into mixing heater or/and add the same when the hot material has been diverted into mixing cooler; when the mixture has been cooled below 100° C., the discharged material is product; after initial mixing of the prepared material, directly divert the same into screw extruder and heat and get into mixing section; when the mixture has been cooled below 100° C.
    Type: Application
    Filed: September 30, 2010
    Publication date: July 19, 2012
    Inventors: Huihong Chen, Jiaqing Hu
  • Patent number: 8153699
    Abstract: A surfacing composition made of recycled paint, which requires no priming, has a non-reflective “flat” appearance, and is partially composed of dried paint. The composition provides a useful application for used or excess household paint, which would otherwise require special methods of disposal and potentially create future toxic cleanup problems. The composition is made of granular dried paint and a water-based sealer, which can be spread on a surface to repair imperfections. The surface can then be finished, and no priming is required. Due to the composition's flat appearance, the patch does not display any characteristic sheen where the repair has been made. The composition provides a simple means of recycling paint, and provides a simple and inexpensive means of repairing imperfections in walls and other surfaces while saving the step of priming the patch before painting or repainting.
    Type: Grant
    Filed: April 13, 2009
    Date of Patent: April 10, 2012
    Inventor: Larry Allen Holloway
  • Publication number: 20110054051
    Abstract: Processes for recovering natural rubber from an aqueous natural rubber latex that contains extractables and one or more additives and that is essentially free of lignocellulosic plant material are described. Natural rubber in the latex is separated from the water. Preferably, the amount of non-rubber extractables in the natural rubber is reduced by one or more extraction steps yielding a dried natural rubber.
    Type: Application
    Filed: April 14, 2009
    Publication date: March 3, 2011
    Inventors: William M. Cole, Georg G.A. Bohm, Walter Tomaszewski, Yingyi Huang
  • Patent number: 7893120
    Abstract: A pulverized thermoplastic resin product such as a pulverized thermoplastic product containing a black pigment, a mixture of a pulverized thermoplastic product containing a colored pigment and a pulverized thermoplastic product containing a colored pigment, or a pulverized thermoplastic product containing two or more different colored pigments can be converted into colored reclaimed resin particles by a method comprising the steps of mixing the pulverized resin product with a white pigment and a black pigment, melting the resulting mixture, and converting the molten mixture into solid particles. The colored reclaimed resin products can be utilized in various field.
    Type: Grant
    Filed: February 4, 2008
    Date of Patent: February 22, 2011
    Assignee: UBE Industries, Ltd.
    Inventors: Yoshiki Suzuki, Tatsushi Ako, Yukimasa Tanaka, Saburou Hinenoya, Yasuo Kita
  • Patent number: 7790777
    Abstract: Process for recovering at least one polymer in solution in a solvent by precipitation by means of a non-solvent fluid, whereby the precipitation takes place in a precipitation medium comprising two dispersants of which one [dispersant(I)] has a greater affinity for the non-solvent and the other [dispersant (II)] has a greater affinity for the solvent.
    Type: Grant
    Filed: July 14, 2004
    Date of Patent: September 7, 2010
    Assignee: Solvay S.A.
    Inventors: Eric Fassiau, Denis Geets
  • Patent number: 7547734
    Abstract: Recycled resin is produced by a method including a dismantling/recovery step of dismantling products containing resin moldings and recovering the resin moldings, a removal step of removing unwanted matter including metal components from the resin moldings, a sorting step of discriminating the materials of the resin moldings, and a crushing step of crushing the resin moldings. The method further includes, prior to the crushing step, detecting the metal components, and, after the crushing step, separating out and thus removing metal remaining in crushed material.
    Type: Grant
    Filed: September 9, 2005
    Date of Patent: June 16, 2009
    Assignee: Fujitsu Limited
    Inventors: Koichi Kimura, Takamitsu Nakamura
  • Publication number: 20080227876
    Abstract: A method produces polar-modified rubber and olefin thermoplastic waste by grafting during a grinding process, for treatment, usable as compatibility agents in various plastic blends and composites, without the disadvantages of known functionalized recycled plastics, particularly the mechanical characteristics that are insufficient for their use. The waste is simultaneously ground and graft-modified in a temperature range between 40° C. and 140° C., in one method step. Scrap parts of vulcanized elastomer or olefin thermoplastic are comminuted to a particle size diameter of approximately 4 and 8 mm. The waste should be sorted by type, if possible. The shredded material is mixed with at least one organic peroxide and an ?,?-ethylene compound possessing at least one unsaturated polar group. The mixture is simultaneously ground and grafted at a specified dwell time and temperature range to a particle size diameter <1 mm. Residual components and byproducts are removed via nitrogen flushing.
    Type: Application
    Filed: March 11, 2008
    Publication date: September 18, 2008
    Inventors: Klaus Thiele, Cristel Rom, Ute Winkler
  • Patent number: 7425584
    Abstract: The present invention relates generally to the delulcanization of rubber. More specifically, the present invention relates to a process for the hydro-devulcanization of vulcanized rubber utilizing a rubber swelling solvent, a source of reactive hyrogen and elevated temperature and, optimally, also uses a dispersed molecular-scale hydrogenation catalyst that is introduced into the vulcanized rubber in a catalytically inert form that is soluable in the rubber swelling solvent.
    Type: Grant
    Filed: November 29, 2004
    Date of Patent: September 16, 2008
    Assignee: Alberta Research Council
    Inventors: Richard Anthony McFarlane, Roger Kai Lott, Haibo Huang
  • Patent number: 6992116
    Abstract: The present invention discloses a process for devulcanizing cured rubber into devulcanized rubber that is capable of being recompounded and recured into useful rubber products, said process comprising heating the cured rubber to a temperature which is within the range of about 150° C. to about 300° C. under a pressure of at least about 3.4×106 Pascals in the presence of a mixture of carbon dioxide and 2-butanol.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: January 31, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: David Andrew Benko, Roger Neil Beers, Sunggyu Lee, Kelly Lee Clark
  • Patent number: 6831109
    Abstract: The invention provides a modifier for devulcanization of cured elastomers, and especially vulcanized rubber, said modifier containing a first chemical substance, which is disposed towards on and the formation of an organic cation and amine, and further containing a second chemical substance as promotor of dissociation of the first chemical substance, said promotor containing a functional group constituting an acceptor of said amine.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: December 14, 2004
    Assignee: Lev-Gum LTD
    Inventors: Lev Beirakh, Michael Kopylov, Vadim Goldstein
  • Patent number: 6664303
    Abstract: An elastomer blend that is similar to thermoplastic elastomers is produced from powered reclaimed rubber or waste rubber. The powdered rubber is processed to compounds by subjecting it to a melt-mixing process in a mixer together with a thermoplastic material and at least one stabilizer. A mixture that consists of two phases that are usualy incompatible, namely the powdered rubber and a thermoplastic material, is processed to a blend that is characterized by the properties of the rmoplastic elastomers. To this end, at least one polypropylene copolymer or a mixture thereof with at least one polypropylene type is melted in the mixer and powered rubber, at least part of which has been pre-swelled in a radical donor, is dosed to the melt. The powered rubber is dispersed in the plastic matrix by applying high shearing strains and admixing radical-forming agents in order to couple the two phase.
    Type: Grant
    Filed: July 18, 2001
    Date of Patent: December 16, 2003
    Inventors: Hannes Michael, Henrik Scholz
  • Patent number: 6573303
    Abstract: Materials ranging from impact-modified thermoplastics to thermoplastic elastomers (TPE) can be obtained from blends of phase compatibility-treated recycled thermoset rubber with thermoplastic polymers by varying the ratio of components in the blend, or by changing the components themselves. The rubber component may include carbon black, or other fillers and additives, and it may be selected from among a variety of thermoset rubbers, both natural and synthetic. The thermoset rubber component can be obtained from a rubber material recycled according to a variety of known techniques. The thermoplastic component can be virtually any suitable polymer, the properties of which can be advantageously modified by combination with a rubber. Polyolefins are among the more preferred thermoplastic components.
    Type: Grant
    Filed: September 21, 2001
    Date of Patent: June 3, 2003
    Assignee: University of Massachusetts
    Inventors: Helen S. Liu, Joey L. Mead, Ross G. Stacer
  • Patent number: 6555588
    Abstract: A method for producing a polypropylene blend from a plastic packaging materials containing high molecular weight polypropylene, other high molecular weight polymers such as polyethylene, low molecular weight polymers and other contaminants. The method includes extraction, solid-liquid separation and liquid-liquid phase separation using various organic solvents. The polypropylene blend has a purity of 95% and has favorable melt flow characteristics, while retaining satisfactory mechanical properties.
    Type: Grant
    Filed: December 17, 2001
    Date of Patent: April 29, 2003
    Assignee: Der Grune Punkt - Duales System Deutschland AG
    Inventors: Guido Gorski, Andreas Thiele
  • Patent number: 6548559
    Abstract: A new composition is formed by combining a reduced waste rubber, a heavy paraffin and a reduced waste thermoplastic, and then further reducing the resulting material while holding it at an elevated temperature. In preferred embodiments the rubber and thermoplastic are pre-processed by reduction to mesh sizes of about 0.25 inch and 0.5 inch respectively, and the paraffin is pre-processed by being fluidizing to have a viscosity of at most about 1.0 Centipoise. It is also contemplated that the rubber and paraffin can be advantageously combined with each other prior to inclusion of the thermoplastic, with the paraffin/rubber combination being heated to a temperature of about 220° F. to about 250° F. for about 3 minutes. It is still further contemplated that the combination of rubber, paraffin and thermoplastic can be heated to between about 360° F. and about 500° F.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: April 15, 2003
    Inventor: Robert Fish
  • Patent number: 6489372
    Abstract: Polymer are removed from organic solvent-polymer mixtures by preparing a liquid-liquid dispersion of finely dispersed solvent droplets containing polymer in water, adding this liquid-liquid dispersion to a stirred vessel containing water or other suitable liquid and rapidly evaporating the solvent to produce a slurry of the polymer in a liquid from which the solid polymer particles are recovered.
    Type: Grant
    Filed: October 17, 2000
    Date of Patent: December 3, 2002
    Assignee: General Electric Company
    Inventors: Qiwei He, Paul Russell Wilson, Paul William Buckley, Allen Wai Yee Ko, Larry Allen Divins, William Lee Gately, Ganesh Kailasam
  • Patent number: 6384093
    Abstract: A method of enhancing the melt-processibility of crosslinked plastic or recycling crosslinked plastic and the products formed by these methods. The melt processibility of a crosslinked thermoplastic resin may be enhanced by mixing it with a low viscosity polymeric resin having a specified melt flow index relative to the melt flow index of the crosslinked thermoplastic resin, and exposing the mixture to mechanical shearing energy to produce a processed mixture having enhanced melt flow characteristics. The processed mixture may be subsequently mixed with thermoplastic polymer.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: May 7, 2002
    Assignee: Cryovac, Inc.
    Inventors: Larry Bourland, Richard A. Freundlich, Rudolph G. Nwana, Vincent W. Herran
  • Patent number: 6344493
    Abstract: A melt tension enhancer for polyolefin resins that contains polytetrafluoroethylene and a polymer of an alkyl (meth)acrylate of 5-30 carbon atoms, and a process for its production. Its addition to polyolefin resins enhances the melt tension of the polyolefin resins without impairing the surface appearance of their molds.
    Type: Grant
    Filed: February 22, 2000
    Date of Patent: February 5, 2002
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Atsunori Koshirai, Akira Yanagase
  • Patent number: 6329436
    Abstract: A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about ¼ inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125° C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.
    Type: Grant
    Filed: November 5, 1992
    Date of Patent: December 11, 2001
    Assignee: The University of Chicago
    Inventors: Bassam J. Jody, Edward J. Daniels, Patrick V. Bonsignore
  • Publication number: 20010036969
    Abstract: This invention provides a process for producing fine rubber powders by using waste rubber, comprising the steps of pre-pulverizing waste rubber into particles with a size of 1-4 mm; soaking the particles in a solvent selected from one or more alcohols and/or ethers; and pulverizing the soaked rubber particles into rubber powders with a size of less than 180 &mgr;m. The process according to the invention is an ideal method in industry due to its low costs and without pollution.
    Type: Application
    Filed: April 20, 2001
    Publication date: November 1, 2001
    Inventor: Shuhua Pang