Process Of Treating Scrap Or Waste Product Containing Solid Organic Polymer To Recover A Solid Polymer Therefrom Patents (Class 521/40)
  • Patent number: 11827564
    Abstract: Treating plastic particles for use in concrete includes combining plastic particles with oil to yield a mixture, heating the mixture to yield a heated mixture, cooling the heated mixture to yield a cooled mixture, and removing excess oil from the cooled mixture to yield oil-treated plastic particles (e.g., oil-treated plastic particles for concrete). In one example, the oil is vegetable oil. The vegetable oil can be soybean oil, corn oil, canola oil, safflower oil, peanut oil, olive oil, grape seed oil, cocoa butter, palm oil, rice bran oil, or a combination thereof. The oil can be waste oil (e.g., waste vegetable oil, such as that recovered from restaurants). The plastic particles can be derived from post-consumer plastic, such as recycled plastic. In one example, the post-consumer plastic includes mixed plastics. A concrete composition can include rocks, sand, cement, and the oil-treated plastic particles.
    Type: Grant
    Filed: September 24, 2021
    Date of Patent: November 28, 2023
    Assignee: Arizona Board of Regents on behalf of Arizona State University
    Inventors: Marvin Burton, Christian Hoover, Elham Fini
  • Patent number: 11717989
    Abstract: Preparing hybrid-treated plastic particles from waste plastic includes combining waste plastic particles with bio-oil to yield a mixture, irradiating the mixture with microwave radiation to yield oil-treated plastic particles, and contacting the oil-treated plastic particles with carbon-containing nanoparticles to yield hybrid-treated plastic particles. The hybrid-treated plastic particles have a bio-oil modified surface and a coating comprising carbon-containing nanoparticles on the bio-oil modified surface of the plastic particle. In some examples, a diameter of the plastic particle is in a range between 250 m and 750 m, and a thickness of the coating is in a range of 1 nm to 20 nm. A modified binder includes an asphalt binder or a concrete binder and a multiplicity of the treated plastic particles. The modified binder typically includes 5 wt % to 25 wt % of the hybrid-treated plastic particles.
    Type: Grant
    Filed: November 12, 2020
    Date of Patent: August 8, 2023
    Assignee: Arizona Board of Regents on behalf of Arizona State University
    Inventors: Elham Fini, Sk Faisal Kabir
  • Patent number: 11654599
    Abstract: A method of upcycling fiber reinforced polymer source material by disassembling the source material into sections; planking the sections into longitudinal pieces; separating core material from the source material in the longitudinal pieces to make composite strips; preparing the composite strips; and remanufacturing the prepared composite strips into an article.
    Type: Grant
    Filed: May 27, 2021
    Date of Patent: May 23, 2023
    Assignee: ZED Services LLC
    Inventor: Joshua George Zarecky
  • Patent number: 11649337
    Abstract: A method of recycling a polymer structure includes converting a first polymer structure into feedstock. The first polymer structure comprises particles that are bonded to one another by chemical click bonds to form a first shape. The first polymer structure is converted into feedstock particles by breaking the click bonds. The feedstock particles are formed into a second shape, and the feedstock particles are chemically click-bonded together to form a second polymer structure having a second shape. Breaking the click bonds may include heating the particles. The structures may be formed by causing first particles having dienes to chemically bond to dienophiles of second particles.
    Type: Grant
    Filed: March 26, 2020
    Date of Patent: May 16, 2023
    Assignee: United States of America as represented by the Administrator of NASA
    Inventors: Christopher J Wohl, Samantha I Applin, Hannes Schniepp, Bryce L Horvath
  • Patent number: 11339268
    Abstract: Thermosetting plastics are recycled by process that begins with grinding the plastic into small pieces. This particulate is then mixed with a catalyst and ball mill milled to a fine powder, which can then be reprocessed via molding (e.g., hot-press, injection, etc.).
    Type: Grant
    Filed: July 30, 2020
    Date of Patent: May 24, 2022
    Assignee: CASE WESTERN RESERVE UNIVERSITY
    Inventors: Ica Manas-Zloczower, Liang Yue
  • Patent number: 11286333
    Abstract: A degradation method of thermosetting resin is provided. The method includes the following steps, for example, a first resin composition is provided. The resin in the first resin composition includes a carbon-nitrogen bond, an ether bond, an ester bond or a combination thereof. The first resin composition and a catalyst composition are mixed to perform a degradation reaction to form a second resin composition. The catalyst composition includes a transition metal compound and a group IIIA metal compound. The second resin composition includes a resin monomer or an oligomer thereof having functional groups. The functional group includes an amine group, a hydroxyl group, an ester group, an acid group or a combination thereof. A catalyst composition used in the degradation method and a resin composition obtained by the degradation method are also provided.
    Type: Grant
    Filed: December 26, 2019
    Date of Patent: March 29, 2022
    Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Kuei-Yi Chuang, Kuo-Chan Chiou, Yen-Chun Liu
  • Patent number: 11056688
    Abstract: A lithium compound with which a positive active material containing a decreased amount of magnetically attractable substances can be easily obtained while shortening the total time for production of a positive electrode for a nonaqueous electrolyte secondary battery. The lithium compound is used for producing a positive active material for a nonaqueous electrolyte secondary battery, with which a lithium transition metal composite oxide can be obtained by mixing the lithium compound with a transition metal composite hydroxide or the like obtained by crystallization reaction. A positive active material in which the amount of magnetically attractable substances contained is 0.02 mass ppm or less can be easily obtained while shortening the total time for production of the positive active material.
    Type: Grant
    Filed: June 6, 2017
    Date of Patent: July 6, 2021
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Azusa Tagami, Takeshi Asakawa
  • Patent number: 10857698
    Abstract: The invention relates to a method for manufacturing a pellet, comprising a) providing residual rubber powder from i rubber disintegration process; b) providing a pelletizing system, including a pelletizer and a cooling device; c) feeding the residual rubber powder as at least part of a feed material, into a pelletizer; d) providing the rubber powder in an amount between 50% and 100%; i) applying a pressure to the residual rubber for a predetermined process duration; f) releasing the pelletized rubber and cooling the pelletized rubber at a cooling rate dependent on the operational temperature of the pelletizer.
    Type: Grant
    Filed: June 1, 2017
    Date of Patent: December 8, 2020
    Assignee: Genan Holding A/S
    Inventors: Lars Linnemann, Carsten Sigvert
  • Patent number: 10781404
    Abstract: A method for cleaning a substrate which is or comprises a textile, the method comprising agitating the substrate in the presence of a cleaning composition comprising: i. cleaning particles comprising a thermoplastic polyamide and a particulate inorganic filler having a density of at least 2.5 g/cm3, said cleaning particles having an average particle size of from 1 to 100 mm, wherein the cleaning particles have an average density of at least 1.65 g/cm3 and/or the particulate inorganic filler has a D50 particle size of at least 10 microns and/or a D90 particle size of at least 40 microns; and ii. a liquid medium.
    Type: Grant
    Filed: November 30, 2015
    Date of Patent: September 22, 2020
    Assignee: Xeros Limited
    Inventors: Robert Andrew Bird, Gordon Lee Ellis, Martina Schoemer, Simon Kniesel, Philipp Kloke, Frank Ehret, Matthias Dietrich
  • Patent number: 10633507
    Abstract: The present invention relates to a method for degradation of a phenolic resin-containing material, characterized in that the phenolic resin-containing material is subjected to an aminolysis with a reagent containing at least one amino group, as well as a method for synthesis and degradation of a phenolic resin-containing material, characterized in that the phenolic resin-containing material is created by curing the starting components at a temperature of less than 140° C. and is subjected to aminolysis with a reagent containing at least one amino group for the purpose of degradation.
    Type: Grant
    Filed: November 9, 2016
    Date of Patent: April 28, 2020
    Assignee: Fraunhofer-Gesellschaft zur Foerderung der angewandten Forschung e.V.
    Inventors: Dominik Sothje, Christian Dreyer, Monika Bauer, Jurgen Lang
  • Patent number: 10610911
    Abstract: Processing reinforcing fiber products to recover reinforcing fibers by removing other material, such fiber sizing material and/or matrix material from the reinforcing fibers. The processing includes cosolvent treating the reinforcing fiber product with a cosolvent composition including a normally-liquid first solvent portion and a normally-gaseous second solvent portion under conditions of temperature and pressure at which the cosolvent composition is in the form of a single fluid phase that is a liquid or a supercritical fluid. The processing may be performed in a continuous manner to recover the continuous reinforcing fibers in a continuous form.
    Type: Grant
    Filed: October 2, 2018
    Date of Patent: April 7, 2020
    Assignee: Vartega Inc.
    Inventors: Andrew Timothy Maxey, Jordan Gray Harris, Sean Paul Kline
  • Patent number: 10351924
    Abstract: A hot-dip galvanized steel sheet includes a base steel sheet and a hot-dip galvanized layer formed on the base steel sheet, the base steel sheet including, by wt %, C:0.02% to 0.08%, Mn:1.3% to 2.1%, Si:0.3% or less (excluding 0%), Cr:1.0% or less (excluding 0%), P:0.1% or less (excluding 0%), S: 0.01% or less (excluding 0%), N:0.01% or less (excluding 0%), sol.Al: 0.02% to 0.06%, Mo:0.2% or less (excluding 0%), B:0.003% or less (excluding 0%), and a balance of Fe and inevitable impurities, wherein the base steel sheet has a microstructure comprising 90% or more by area of ferrite, 3% or less by area of bainite as described in Formula 1, and martensite as a remainder.
    Type: Grant
    Filed: May 8, 2015
    Date of Patent: July 16, 2019
    Assignee: POSCO
    Inventors: Sang-Ho Han, Seong-Ho Han
  • Patent number: 10273342
    Abstract: The present patent refers to a process for the recycling and recovery of waste, particularly that of plastified and aluminized packaging, cartoned or not, by means of a method and equipment for extracting and separating the main components present in them for the recovery of waste, avoiding environmental pollution, recycling of waste constituents, and recovery of constituents: Plastic, aluminum and paper in their original form, with the steps A, B, C, D, E, F, G, H, I, J, L, M, O, P, Q e R, bringing advantages of obtaining reusable grade polymer; obtaining isolated aluminum; to make use of a low cost and low energy consuming solvent; to allow the pulp cellulose to be recycled in the production of paperboard for boxes, to be incorporated as part of a mechanical pulp load or even to be incorporated to the bleaching process; to have lower processing and investment costs and to have a lower cost/benefit ratio.
    Type: Grant
    Filed: November 18, 2015
    Date of Patent: April 30, 2019
    Inventor: Juarez Souza De Oliveira
  • Patent number: 9902831
    Abstract: A method is provided for preparing a reprocessed rubber from thermoset rubber particles. The method includes providing a plurality of thermoset rubber particles, inducing dynamic swelling and dynamic compatibilization of the plurality of rubber particles, admixing at least one de-linking agent with the swelled and wetted rubber particles, and wherein the step of admixing the at least one de-linking agent is carried out under thermo-mechanical mixing.
    Type: Grant
    Filed: January 18, 2015
    Date of Patent: February 27, 2018
    Assignee: ECOTECH RECYCLING LTD.
    Inventors: Moshe Rakhman, Tehila Feiglin, Oleg Golobrodsky
  • Patent number: 9758611
    Abstract: Brominated styrene-butadiene copolymers are recovered from solution in an organic solvent. The copolymer solution is mixed with a liquid non-solvent in the presence of a suspension stabilizer to form a dispersion. The dispersion is heated to vaporize the organic solvent. This process produces precipitated copolymer particles having useful particle sizes, which can be easily used in downstream applications.
    Type: Grant
    Filed: December 12, 2014
    Date of Patent: September 12, 2017
    Assignee: Dow Global Technologies LLC
    Inventors: Daniel A. Beaudoin, John W. Hull, Jr., Michal E. Porter, William G. Stobby, Gerald F. Billovitz, Timothy J. Young
  • Patent number: 9617401
    Abstract: The present application provides a polymer composite comprising at least one polymer and a reclaimed pyrolyzed carbon black (pCB), wherein the pCB comprises less than about 10 ?g/g of polycyclic aromatic hydrocarbons (PAH). Also provided are polymer composite and consumer-ready formulations of the low PAH pCB and methods of manufacturing such composites and formulations.
    Type: Grant
    Filed: October 27, 2014
    Date of Patent: April 11, 2017
    Assignee: Berdeko Technologies Inc.
    Inventors: Vincent W. Y. Wong, Rui Resendes, Timothy James Clark
  • Patent number: 9546224
    Abstract: Processes for recovering natural rubber from an aqueous natural rubber latex that contains extractables and one or more additives and that is essentially free of lignocellulosic plant material are described. Natural rubber in the latex is separated from the water. Preferably, the amount of non-rubber extractables in the natural rubber is reduced by one or more extraction steps yielding a dried natural rubber.
    Type: Grant
    Filed: July 23, 2014
    Date of Patent: January 17, 2017
    Assignee: Bridgestone Corporation
    Inventors: William M. Cole, Georg G. A. Bohm, Walter Tomaszewski, Yingyi Huang
  • Patent number: 9458303
    Abstract: Present embodiments provide efficient and cost-effective use of chloramines such as monochloramine, NH2Cl, to degrade styrene butadiene rubber, a material from which tires and other products are made, so that it can be recycled, and do so by overcoming the limitations of monochloramine due to its thermodynamic instability by achieving and maintaining adequate monochloramine concentrations for the degrading process.
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: October 4, 2016
    Assignee: UNIVERSITY OF LOUISVILLE RESEARCH FOUNDATION, INC.
    Inventors: Gerold A. Willing, Patrick Kroeger
  • Patent number: 9458302
    Abstract: The present invention relates generally to the manufacture of vehicular floor mats using recycled content. In particular, the present disclosure identifies the ability to form extrudable floor mats suitable for interior vehicular applications where the recycle content includes recycling of selected amounts of a laminate of crosslinked polyolefin foam and thermoplastic polyolefin resin.
    Type: Grant
    Filed: August 13, 2015
    Date of Patent: October 4, 2016
    Assignee: International Automotive Components Group North America, Inc.
    Inventors: Matt Starling, Joe Bedogne, William J. Tansey, Rose Ann Ryntz
  • Patent number: 9315922
    Abstract: A polyester-based fiber for artificial hair of the present invention is a polyester-based fiber for artificial hair formed of a polyester resin composition. The polyester resin composition contains 5 to 40 parts by weight of a brominated epoxy flame retardant and 0.05 to 5 parts by weight of an acidic compound with respect to 100 parts by weight of a polyester resin. The polyester resin is one or more kind of resin selected from the group consisting of polyalkylene terephthalate and copolymerized polyester containing polyalkylene terephthalate as a main component. The acidic compound is an acidic phosphorus-based compound having a pH of 3.5 or less. A hair ornament product of the present invention contains the polyester-based fiber for artificial hair.
    Type: Grant
    Filed: May 31, 2013
    Date of Patent: April 19, 2016
    Assignee: Kaneka Corporation
    Inventors: Tomomichi Hashimoto, Tomokazu Higami, Mika Yorizane, Kohei Kawamura
  • Patent number: 9309295
    Abstract: The present invention relates to a filamentous fungus comprising a genetic modification in one more hydrophobin genes and the use of the same as host cell for preparing a biosynthetic product. The present invention further pertains to a vector for and methods for generating said filamentous fungus.
    Type: Grant
    Filed: May 28, 2014
    Date of Patent: April 12, 2016
    Assignee: Danmarks Tekniske Universitet
    Inventors: Lars Poulsen, Jette Thykær, Anna Eliasson Lantz
  • Patent number: 9193865
    Abstract: The present invention generally relates to polyamide compositions having improved anti-delamination. More specifically, the present invention relates to novel polyamide compositions demonstrating improved anti-delamination, which can have at least one low purity polyamide.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: November 24, 2015
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Avelino F Lima
  • Patent number: 9175155
    Abstract: A method of functionalizing reclaimed elastomer material is described. The method involves subjecting particles of the reclaimed elastomer material to shear at temperatures less than 100° C. such that inter-chain bonds of the reclaimed elastomer material are cleaved wherein the particles of the reclaimed elastomer material have a size of 60 mesh or smaller. The reclaimed elastomer material can be subjected to shear in the presence of a modifier which selectively promotes the cleavage of inter-chain bonds in the reclaimed elastomer material. A functionalized reclaimed elastomer material made by a method as described above and an elastomer compound which comprises the functionalized reclaimed elastomer material are also described.
    Type: Grant
    Filed: November 1, 2013
    Date of Patent: November 3, 2015
    Assignee: Lehigh Technologies, Inc.
    Inventors: Charles Rosenmayer, Frank Papp, Alan Edward Barton, Kedar D. Murthy
  • Patent number: 9109114
    Abstract: The present invention generally relates to polyamide compositions having improved anti-delamination. More specifically, the present invention relates to novel polyamide compositions demonstrating improved anti-delamination, which have at least one low purity polyamide.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: August 18, 2015
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Avelino F Lima
  • Patent number: 9062412
    Abstract: Backings for carpet and carpet tiles are formed from various post-consumer and/or post-industrial polymeric waste materials, for example, post-consumer textile waste material (e.g., carpet and carpet tiles), post-industrial textile waste material (e.g., carpet and/or carpet tiles), and/or other post-consumer and/or post-industrial polymeric materials.
    Type: Grant
    Filed: January 13, 2014
    Date of Patent: June 23, 2015
    Assignee: Tandus Flooring, Inc.
    Inventors: Paul D. Evans, Jr., Gabe Moore
  • Patent number: 9045612
    Abstract: Methods and systems for reducing the volume of polystyrene foam wherein a foam reducing agent is applied to the foam, the foam reducing agent in some embodiments comprising a branched dibasic ester blend.
    Type: Grant
    Filed: January 10, 2013
    Date of Patent: June 2, 2015
    Assignee: RHODIA OPERATIONS
    Inventors: David Fluck, Ruela Pabalan, Charles Aymes
  • Patent number: 9023903
    Abstract: The present invention generally relates to polyamide compositions having improved anti-delamination. More specifically, the present invention relates to novel polyamide compositions demonstrating improved anti-delamination, in which the compositions have at least one reinforcement agent.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: May 5, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventor: Avelino F Lima
  • Patent number: 9012525
    Abstract: In a tire constituted with a thermoplastic material and a material different from the thermoplastic material, the thermoplastic material and the material different from the thermoplastic material are easily and efficiently separated. While a tire 10 formed of a thermoplastic material is being turned, heated air is ejected from a nozzle 46 of a heating apparatus 44, and the surface of a crown portion 16 is melted. An end portion of a cord 26 embedded in a helical arrangement, which is formed of a material different from the thermoplastic material, is extracted from the melted region, and is sequentially wound onto a reel 58.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: April 21, 2015
    Assignee: Bridgestone Corporation
    Inventors: Yoshihide Kouno, Seiji Kon, Keiichi Hasegawa
  • Patent number: 8993644
    Abstract: Methods of reclaiming plastic from plastic medical waste containers containing medical waste and manufacturing recycled medical devices are described. Recycled medical devices made from plastic medical waste containers containing medical waste are also described.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: March 31, 2015
    Assignee: Becton, Dickinson and Company
    Inventor: Richard Ji
  • Publication number: 20150083025
    Abstract: The present invention relates to a composition for solubilizing a fluoropolymer, comprising a solvent blend of a) Compound of formula (I) R1 C(=0)NR2R3 wherein R1 and R2 and R3 are defined as in the specification and b) DiMethylSulfoxide (DMSO). The invention also relates to the process for the preparation of the composition and its uses. The invention is also of use the fluoropolymer composition for coating applications.
    Type: Application
    Filed: April 16, 2012
    Publication date: March 26, 2015
    Applicant: RHODIA OPERATIONS
    Inventors: Shujing Cheng, Arnaud Bourdette
  • Patent number: 8980963
    Abstract: The invention relates to an article that has been obtained by the melt-process recycling of one or more multi-layer articles, where the multi-layer articles are composed of at least one melt-processible polyvinylidene fluoride layer. The composition of the invention is a compatible blend of the different layers from the multi-layer articles. The other layers of the multi-layer articles are also melt-processible, and include one or more layers chosen from: a) a melt-processible fluoropolymer of a different composition, b) a non-fluoropolymer, and c) a barrier layer. The composition is useful for forming an article in a melt-process operation. The composition may be used by itself, may be blended with other virgin or recycled materials, or may be used at low levels with melt-processible polymers as a process aid.
    Type: Grant
    Filed: July 29, 2014
    Date of Patent: March 17, 2015
    Assignee: Arkema Inc.
    Inventors: Saeid Zerafati, Sean M. Stabler, William J. Hartzel
  • Patent number: 8969425
    Abstract: The present invention relates to a process for separating two or more components of a plastic material for the purposes of recycling, with particular application to purifying poly(ethylene terephthalate) (PET) during recycling procedures. The process comprises contacting a quantity of the plastic material with one or more discrete pre-heated particles.
    Type: Grant
    Filed: February 22, 2013
    Date of Patent: March 3, 2015
    Assignee: Nextek Limited
    Inventor: Edward Kosior
  • Patent number: 8969426
    Abstract: The present invention relates to the recovery of nylon from co-mingled materials (e.g., carpet) with reduced or eliminated ash (e.g., calcium carbonate) contamination.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: March 3, 2015
    Assignee: Dynasep Inc.
    Inventors: Brian J. Waibel, David J. Lawrence
  • Publication number: 20150057379
    Abstract: Methods for the recycling of carpet are disclosed that produce clean face fiber suitable for industrial use. The methods allow the recovery of face fiber material, for example a polyester or a polyamide, from carpets that includes a face fiber material and a backing material, and include the steps of heating the carpet to a temperature lower than the melting point of the face fiber material, but higher than the initial thermal decomposition temperature of the backing material, for a time and at a temperature sufficient to thermally decompose, pyrolyze, or oxidize at least a portion of the backing material, rendering the backing material friable, that is more friable than the untreated backing; and applying mechanical force to the carpet so as to liberate the friable backing material from the face fiber material.
    Type: Application
    Filed: September 12, 2014
    Publication date: February 26, 2015
    Inventors: Joseph E. BORK, Stephen C. PASPEK, SR., Alan F. SCHROEDER, William H. HEISE
  • Patent number: 8961889
    Abstract: A devulcanization apparatus for devulcanizing a plurality of cross-linked elastomer particles. The apparatus includes a first conveyor functioning as a high voltage electrode and a second conveyor functioning as a ground electrode. A generator is operable to apply an alternating electric field between the first and second conveyors. A devulcanization region is provided between the first and second conveyors in which the cross-linked elastomer particles are placed.
    Type: Grant
    Filed: May 21, 2013
    Date of Patent: February 24, 2015
    Assignee: Novation IQ LLC
    Inventor: Michel Marc
  • Patent number: 8957119
    Abstract: Method of devulcanizing rubber and/or elastomers without the need for a chemical agent, in which method the vulcanized rubber and/or elastomers are fed into a planetary roller extruder, which planetary roller extruder has a housing, a central spindle, two groups of planetary roller spindles, and a dispersion ring disposed about the central spindle and between the two groups of planetary spindles. Mechanical and thermal stress is generated on the vulcanized rubber and/or elastomers by kneading and/or crushing the vulcanized rubber and/or elastomers using the central spindle and the planetary spindles, and by forcing the vulcanized rubber and/or elastomers through the dispersion ring, which is designated to substantially restrict passage of the vulcanized rubber and/or elastomers therethrough. The mechanical and thermal stress alone is sufficient to break or destroy the molecular chains or bonds of the vulcanized rubber and/or elastomers.
    Type: Grant
    Filed: July 26, 2012
    Date of Patent: February 17, 2015
    Assignee: Entex Rust & Mitschke GmbH
    Inventor: Harald Rust
  • Publication number: 20150045461
    Abstract: A method enabling a used superabsorbent polymer recovered from used absorbent, etc., to be readily and inexpensively recovered without using acids or alkalies. The used superabsorbent polymer is treated with an aqueous solution of a multivalent metal salt such as calcium chloride, etc., the superabsorbent polymer treated with the aqueous solution of a multivalent metal salt is treated with an aqueous solution of an alkaline metal salt such as sodium chloride, etc., the superabsorbent polymer treated with the aqueous solution of an alkaline metal salt is washed with water, and the superabsorbent polymer washed with water is then dried.
    Type: Application
    Filed: March 22, 2013
    Publication date: February 12, 2015
    Inventors: Naoyuki Funamizu, Ken Ushijima, Nowaki Hijikata, Hiroki Yoshikawa, Takayoshi Konishi, Toru Oba
  • Patent number: 8946309
    Abstract: Process to generate synthesis gas and/or liquid raw materials and/or energy materials from waste and/or biomass by performing the following steps: a) solvolysis of the organic components of waste and/or biomass in an alkaline solution or hydrate smelter at a temperature range of 150° to 250° C. and pressure between 3 and 12 bar, whereby the organic components are converted into at least one liquid phase and the inorganic components are sedimented; b) elimination of the inorganic components from the liquid phase by physical separation methods; c) transfer of the vapors generated during the solvolysis into a rectification column, where the organic components are separated from water; and d) further separation of the organic components by rectification, extraction and sorption and/or conversion by thermal gasification into synthesis gas or burnable gas.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: February 3, 2015
    Inventors: Wenzel Bergmann, Thomas Müller
  • Patent number: 8939755
    Abstract: The invention relates to a device for the implementation of a method for the production of pellets of polyamide 6 or copolyamides. The method can include production of a melt of polyamide 6 or copolyamides by means of polymerization, production of pellets from the melt by means of underwater pelletization into a process fluid, removal of the pellets from a site of underwater pelletization in the process fluid, supply of the pellets in the process fluid to an extraction stage, extraction of low-molecular components as extract, and drying of the pellets after extraction, wherein the underwater pelletization stage and the extraction stage take place using the same process fluid.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: January 27, 2015
    Assignee: Automatik Plastics Machinery GmbH
    Inventor: Stefan Deiss
  • Patent number: 8937104
    Abstract: The cross-linked polyzwitterion/anion for the removal of strontium from aqueous solutions is a polyzwitterion having the following structure: and the corresponding anion formed by treating the polyzwitterion with a base, e.g., sodium hydroxide. The cross-linked polyzwitterion/anion (CPZA) was prepared using Butler's cyclopolymerization protocol. The CPZA resin was found to have a very good adsorption capacity for Sr2+ ions at low concentrations. The relatively strong rapid initial adsorption of 83% Sr2+ ions was followed by slower adsorption of the remaining 17%, which was described by an intraparticle diffusion model. The adsorption followed the Lagergren second-order kinetic model, and Temkin as well as Freundlich isotherm models. The negative ?Gs and ?H ensured the spontaneity and the exothermic nature of the adsorption process. The excellent adsorption and desorption efficiencies implied the efficacy of the resin in removing (as well as recovering) the metal ions from aqueous solution.
    Type: Grant
    Filed: April 29, 2013
    Date of Patent: January 20, 2015
    Assignees: King Fahd University of Petroleum and Minerals, King Abdulaziz City for Science and Technology
    Inventors: Shaikh Asrof Ali, Shamsuddeen Abdullahi Haladu
  • Patent number: 8916618
    Abstract: The invention is directed to a method for recycling an organic-matrix composite material. The organic-matrix composite material comprises a first component comprising at least one organic matrix polymer and at least one solid second component being compatible with said first component and being structurally different from said first component, wherein said at least one organic polymer has thermosetting properties at room temperature and wherein said polymer comprises thermally reversible cross-links The method of the invention comprises —heating the organic-matrix composite material to a temperature at which at least part of the thermally reversible cross-links cleave and at which temperature the first component as a viscosity of at most 500 Pa·s, as measured by oscillatory measurements on an Anton Paar MCR 301 rheometer using parallel plate geometry; and —separating the at least part of said first component from said second component.
    Type: Grant
    Filed: October 13, 2009
    Date of Patent: December 23, 2014
    Assignee: Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Onderzoek TNO
    Inventors: Maria Elizabeth Louise Wouters, Rudolf Hartmut Fischer
  • Patent number: 8912241
    Abstract: A rubber asphalt and a preparation method thereof are disclosed. The rubber asphalt comprises matrix asphalt and rubber powder modifier in a ratio of 4:1-4, wherein the rubber powder modifier comprises waste tire rubber powder and hexanediol in a ratio of 94-96:6-4. The method comprises the following steps: mixing the hexanediol with the waste tire rubber powder according to the ratio and stirring and wetting to obtain the rubber powder modifier; placing the matrix asphalt into a reaction kettle and heating to 90-170° C.; adding the rubber powder modifier into the reaction kettle according to the ratio; and raising the temperature to 190-210° C. under the stirring state to obtain the rubber asphalt. The rubber asphalt has an extensibility of 13-19 cm at 5° C., a penetration of 68-75 at 25° C. and a softening point of 53-90° C. The asphalt-aggregate ratio of a mixed material on the subsequent work section can be reduced to 6-8 from 8-10.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: December 16, 2014
    Inventor: Qiqiang Zhou
  • Patent number: 8906972
    Abstract: An aqueous two-phase system (ATPS) containing a poly(oxyethylene) (POE) and a poly[sodium (diallylamino)alkylphosphonate-alt-sulfur dioxide] form a pH-responsive dianionic polyelectrolyte (DAPE). The two polymers form ATPS's at low concentrations, where the addition of HCl changes the charge types and their densities on the polymer chains.
    Type: Grant
    Filed: December 27, 2013
    Date of Patent: December 9, 2014
    Assignees: King Fahd University of Petroleum and Minerals, King Abdulaziz City of Science and Technology
    Inventors: Othman Charles Sadeq Al-Hamouz, Shaikh Asrof Ali
  • Patent number: 8900492
    Abstract: A process for the preparation of thermal insulation sheets fashioned from certain unseparated mixtures of post-consumer plastic articles and the article, itself, is disclosed. The mixtures of such articles contain polyethylene terephthalate (PET) and polystyrene (PS) and optionally also articles made of high density polyethylene (HDPE). An unseparated mixture of such articles is provided. This mixture is crushed and shredded to form plastic flakes, and these plastic flakes are then homogenized. Homogenization of the flakes can be carried out either by melt-blending them or by further comminution to produce very fine particles of the mixed plastics. The resulting homogenized mixture of plastic types is then compression molded into sheets ranging in thickness from about 3 to 10 mm.
    Type: Grant
    Filed: June 21, 2012
    Date of Patent: December 2, 2014
    Assignee: King Abdulaziz City for Science and Technology
    Inventor: Fares D. Alsewailem
  • Patent number: 8895633
    Abstract: The cross-linked polyaminocarboxylates for the removal of metal ions from aqueous solutions of the present invention are cross-linked anionic polyelectrolytes CAPE 6 and CAPE 9, containing pH-responsive amino acid residues. The cross-linked anionic polyelectrolytes have been synthesized via cycloco-polymerization and ter-polymerization of a diallylammonioethanoate monomer (90 mol %) and a cross-linker, 1,1,4,4-tetraallylpiperazinium dichloride (10 mol %) in the absence of SO2 (CAPE 6) and in the presence of SO2 (CAPE 9), respectively. For the sorbents CAPE 6 and CAPE 9, the efficiency of Cu2+ removal at an initial metal concentration of 200 ppb was found to be 77.5% and 99.4%, respectively. Treatment of real wastewater samples spiked with Cu2+ ions showed the excellent ability of the cross-linked anionic polyelectrolytes to adsorb metal ions.
    Type: Grant
    Filed: March 4, 2013
    Date of Patent: November 25, 2014
    Assignee: King Fahd University of Petroleum and Minerals
    Inventors: Othman Charles Sadeq Othman Al Hamouz, Shaikh Asrof Ali, Nouri Mohammed Hassan
  • Patent number: 8883867
    Abstract: Compositions containing a turpentine liquid and methods are disclosed for dissolving, dissolving via melting, selectively dissolving via melting, decomposing plastic comprising a chlorine-containing polymer or thermosetting polymer, and/or co-dissolving plastic with fossil fuel for purifying, separating, recovering or recycling plastic-containing material.
    Type: Grant
    Filed: September 6, 2011
    Date of Patent: November 11, 2014
    Assignee: Green Source Holdings LLC
    Inventors: Liang-tseng Fan, Shahram Reza Shafie
  • Patent number: 8871822
    Abstract: The cross-linked polyphosphonate-sulfone composition for removal of metal ions from wastewater relates to a cross-linked anionic polyelectrolyte polymer for the removal of metal ions, such as lead (Pb2+) and copper (Cu2+) ions, from wastewater and the like. The cross-linked anionic polyelectrolyte polymer has the formula: The cross-linked anionic polyelectrolyte polymer is made by cyclopolymerization of diallylaminomethylphosphonic acid, 1,1,4,4-tetraallylpiperazinium dichloride (a cross-linker), and sulfur dioxide in the presence of AIBN (an initiator) in DMSO at 65° C. to form a cross-linked polyzwitterionic acid (CPZA). The CPZA is then treated with base (such as sodium hydroxide) to form the cross-linked anionic polyelectrolyte polymer having the formula shown above.
    Type: Grant
    Filed: October 15, 2012
    Date of Patent: October 28, 2014
    Assignee: King Fahd University of Petroleum and Minerals
    Inventors: Shaikh Asrof Ali, Othman Charles Sadeq Othman Al Hamouz
  • Patent number: 8871840
    Abstract: The present application provides a polymer composite comprising at least one polymer and a reclaimed pyrolyzed carbon black (pCB), wherein the pCB comprises less than about 10 ?g/g of polycyclic aromatic hydrocarbons (PAH). Also provided are polymer composite and consumer-ready formulations of the low PAH pCB and methods of manufacturing such composites and formulations.
    Type: Grant
    Filed: February 23, 2013
    Date of Patent: October 28, 2014
    Assignees: Donosti Investments Inc., Kenn Harper
    Inventors: Vincent W. Y. Wong, Rui Resendes, Timothy James Clark
  • Publication number: 20140316018
    Abstract: An object of the present invention is to provide titanium oxide granules that have a novel structure and have a characteristic of highly efficient decomposing capability, and a method of decomposing plastic and organic waste by using the granules. The present invention has been completed based on the finding that a method of decomposing plastic waste by using titanium oxide granules having a transition metal and/or a transition metal oxide, in particular copper, supported thereon enables decomposition of plastic waste at extremely high efficiency in a low-temperature region for a long period of time as compared to methods of decomposing plastic waste by using the related-art titanium oxide granules.
    Type: Application
    Filed: December 14, 2012
    Publication date: October 23, 2014
    Inventors: Hiromitsu Shimizu, Itsushi Kashimoto
  • Patent number: 8865781
    Abstract: A method of processing waste carpet or matting material to separate constituent materials thereof, includes optionally drying the material and then cooling the material to a temperature at which at least one constituent material therein is embrittled. A mechanical force is applied to the cooled material causing the embrittled constituent material to break into fragments. Optionally, the material from the previous step is dried. The material is then separated to separate the fragments of constituent material from other constituent material. The carpet material can be initially shredded into coarse pieces. The procedure may be repeated optionally with different temperatures to selectively embrittle and fragment different components and facilitate their separation.
    Type: Grant
    Filed: November 6, 2009
    Date of Patent: October 21, 2014
    Assignees: Haydale Limited, Desso Group BV
    Inventor: Ian Walters