Treating A Cellular Solid Polymer By Adding A Material Thereto Which Forms A Composition Therewith Patents (Class 521/55)
  • Patent number: 5393794
    Abstract: An insulating material consisting essentially of fly ash particles and a binder and a method for making the same. In one embodiment of the present invention, fly ash particles are mixed with a dissipating foam which contains a binder. The foam acts to spread the binder and separate the fly ash particles, thereby coating the fly ash particles with the binder. When the foam dissipates the binder acts to bind the fly ash particles together in clusters. The clusters of fly ash particles are then suitable to be used as blown-in insulation.
    Type: Grant
    Filed: April 19, 1993
    Date of Patent: February 28, 1995
    Inventor: Henry Sperber
  • Patent number: 5382602
    Abstract: Flexible, slabstock polyurethane foam compositions useful for a rapid-cool process are disclosed. The foams are produced in the presence of a tetravalent tin catalyst, preferably at a relatively low isocyanate index, and preferably with a polyol that contains a non-volatile inhibitor. The foams of the invention eliminate or greatly reduce the amount of visible smoke produced in a rapid-cool process.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: January 17, 1995
    Inventors: Robert D. Duffy, George Combs
  • Patent number: 5360825
    Abstract: A pulp molding is formed by molding a feedstock consisting of, as principal components, pulp and some binder. The feedstock contains plastic microspheres which form uniformly distributed voids in the pulp molding. The pulp molding has cushioning characteristics higher than those of the conventional pulp molding and equivalent to those of a foam styrene board, and moisture absorbing characteristics lower than those of the conventional pulp molding. The pulp molding can be deflocculated in water for reclamation without causing environmental pollution.
    Type: Grant
    Filed: February 11, 1993
    Date of Patent: November 1, 1994
    Assignee: Sony Corporation
    Inventors: Tsutomu Noguchi, Mayumi Miyashita
  • Patent number: 5356958
    Abstract: Typical embodiments of the syntactic foam panel construction which characterize the intention have (1), at least one face sheet of thermoplastic resin reinforced with microballoons and (2) a foam core prepared from thermoplastic syntactic foam flakes consisting of a mixture of hollow glass microballoons, short reinforcing fibers and thermoplastic resin.
    Type: Grant
    Filed: August 20, 1993
    Date of Patent: October 18, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Abraham M. Matthews
  • Patent number: 5328756
    Abstract: A composite article comprising a fibrillated polytetrafluoroethylene (PTFE) matrix, electrically conductive particles, and energy expandable, electrically nonconductive hollow polymeric particles, which composite is conductive and allows for the flow of electricity and which, upon attaining a temperature which causes expansion of the expandable polymeric particles, becomes insulating and causes the flow of electricity to cease. The articles are thin and can be used as electrical circuit breaking elements.
    Type: Grant
    Filed: January 31, 1992
    Date of Patent: July 12, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Robin E. Wright, William V. Balsimo
  • Patent number: 5308898
    Abstract: The invention relates to bituminous compositions obtained by the incorporation of thermoplastic polymer residues, particularly sterile car waste, containing polyurethane foams and thermoset resins, as well as their preparation process. The process consists of mixing previously ground polymer residues, so as to obtain an average particle size below 10 mm with melted asphalt or bitumen. The mixture is stirred at a temperature between 150.degree. and 300.degree. C., the presence of ground polyurethane foam and thermoset resin particles helping to increase the dissolving rate of the polymers. Preferably addition takes place of a catalyst and/or a reagent aiding a coupling reaction between the polymers and certain constituents of the bitumen or asphalt, which gives the final bituminous mixture improved properties. The bituminous compositions according to the invention can advantageously be used for coating solid materials.
    Type: Grant
    Filed: February 21, 1991
    Date of Patent: May 3, 1994
    Assignee: Institut Francais du Petrole
    Inventor: Francois Dawans
  • Patent number: 5308396
    Abstract: In producing an additive for a building material, lightweight granules (e.g., polystyrene beads) are first coated with a waterproof adhesive by mixing in a suitable mixer. When the granules are satisfactorily coated, they are further coated with a wet cementitious material, for example aggregate and wet cement, or with wet plaster, which is added to the mixture. Only sufficient moisture is added to allow the cement or plaster to initiate the chemical reaction which results in the curing of the coating material on the granules. The wet material acts to separate the granules while forming a coating thereon. The granules are then removed from the mixture and allowed to dry and set. The dry granules may then be added to a conventional concrete or plaster mix.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: May 3, 1994
    Assignee: Mazedawn Limited
    Inventor: Laszlo Kovacs
  • Patent number: 5302633
    Abstract: An optical resolution agent which is prepared by polymerizing a polysaccharide derivative having vinyl groups introduced into the hydroxyl groups thereof through an ester or urethane linkage on the surface of a porous support or by copolymerizing such a polysaccharide derivative having vinyl groups introduced thereinto with a porous support having vinyl groups introduced thereinto and which enables an efficient optical resolution of a racemic modification by chromatography.
    Type: Grant
    Filed: January 26, 1993
    Date of Patent: April 12, 1994
    Assignee: Nacalai Tesque, Inc.
    Inventors: Kazuhiro Kimata, Riyo Tsuboi
  • Patent number: 5277915
    Abstract: A three dimensional porous matrix, such as a reticulated open-cell foam, having within its matrix structure a mechanically-fractured hydrogel containing a network of fracture channels. The mechanically-fractured hydrogel may be a gel that has been partially dewatered by compression of the gel in situ.The porosity of the gel-in-matrix makes it useful for chromatographic applications and for immobilization of biologically-active components, where efficient, intimate contact of the hydrogel with a liquid medium is important.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: January 11, 1994
    Assignee: FMC Corporation
    Inventors: Richard B. Provonchee, Francis H. Kirkpatrick
  • Patent number: 5278194
    Abstract: A syntactic foam product having a desired configuration is set forth. The product comprises a plurality of rigid gas filled bubbles arranged in the desired configuration. The bubbles are defined by respective individual and discrete substantially spherical shells preferably formed of a biodegradable shell material. The shells abut one another. They define open spaces where they are not abutting. Attaching material attaches the abutting shells to one another. The open spaces between the shells are not filled by the attaching material. The attaching material is environmentally degradable. It releases the bubbles under ambient conditions after a selected time interval. The shells are in contact with their surroundings and can relatively rapidly biodegrade.
    Type: Grant
    Filed: March 25, 1993
    Date of Patent: January 11, 1994
    Assignee: Microsome
    Inventors: E. Glenn Tickner, Robert E. Short
  • Patent number: 5272001
    Abstract: A low-density, open-cell flexible polyurethane foam body that is modified to impart resilience and enhanced shock-absorbency properties thereto. Modification is effected by implanting in the open cells of the body expandable microspheres having particle sizes in the micron range, each microsphere being formed by a gas proof polymeric shell encapsulating a drop of liquid isobutane. The microspheres are expanded by heat to more than fifty times their initial volume and are entrapped in the open cells of the body. The expanded microspheres are constituted by a soft polymeric shell enclosing a compressible gas, the expanded microspheres behaving as miniature springs dispersed throughout the body.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: December 21, 1993
    Inventor: Morey Weisman
  • Patent number: 5270108
    Abstract: An insulated building panel for use in residential or commercial construction comprising a core of expanded polystyrene (EPS) bonded to at least two exterior skins of oriented strand board by a urethane laminating adhesive and treated with a sodium borate, such as disodium octaborate tetrahydrate, to preserve and protect the building panels from attack by many types of insects, molds, and fungi is disclosed. In an alternative embodiment, EPS for a variety of construction and insulating uses so protected are disclosed.
    Type: Grant
    Filed: December 28, 1989
    Date of Patent: December 14, 1993
    Assignee: AFM Corporation
    Inventor: Thomas L. Savoy
  • Patent number: 5266396
    Abstract: A method for recycling expanded polystyrene foam materials. Unexpanded virgin polystyrene beads having pentane gas contained therein are thermally expanded to produce a supply of expanded beads. Next, a supply of used expanded polystyrene foam is obtained and ground into small portions, preferably of the same size as the expanded beads. The used polystyrene foam pieces are then placed in contact with pentane gas. The expanded beads and the pentane-treated foam pieces are thereafter combined to form a mixture which preferably contains not less than about 50% by weight foam pieces. The mixture is then placed in a mold, followed by the application of heat and pressure thereto in order to produce a final product with a high degree of structural integrity. The pentane gas treatment of the foam pieces enables the fusion thereof to the expanded beads, resulting in a highly durable product.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: November 30, 1993
    Assignee: Hewlett-Packard Company
    Inventor: Kevin A. Howard
  • Patent number: 5252616
    Abstract: In this process, a polyurethane foam web with a thickness of 5 mm to 30 mm is passed continuously through a dipping bath and is thereby impregnated with 10% to 1000% by weight of a polymer dispersion consisting of the components A) and B) defined below:A) 30% to 65% by weight, preferably 40% to 60% by weight and particularly preferably 45% to 50% by weight of a cationic styrene/butadiene copolymer latex containing about 50% of dry substance, or of an anionic butadiene/acrylonitrile copolymer latex, andB) 10% to 50% by weight, preferably 15% to 40% by weight and particularly preferably 25% to 35% by weight of an inorganic and/or organic pulverulent filler,and the foam web treated in this way is compressed to remove excess liquid and then dried in a drying oven at temperatures of 80.degree. C. to 120.degree. C.
    Type: Grant
    Filed: February 9, 1993
    Date of Patent: October 12, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Edmund Giez, Imre Pascik, Joachim Priemer
  • Patent number: 5240966
    Abstract: A granular colorant for coloring thermoplastic resins such as polypropylene, composed of dye/pigment-containing porous thermoplastic resin grains, which is characterized that a dye/pigment composition containing a dispersing agent and/or a carrier resin having a lower softening point than the porous thermoplastic resin grains and dye/pigment is filled in and/or adhered on the pores and/or surfaces of the porous thermoplastic resin grains, is disclosed. The granular colorant is hardly deteriorated by heat and has excellent handlability, meterability, dispersibility and dilutability.
    Type: Grant
    Filed: September 19, 1991
    Date of Patent: August 31, 1993
    Assignees: Dainippon Ink and Chemicals, Inc., Himont Incorporated
    Inventors: Hirotomo Iwasaki, Isao Kitajima, Giampaolo Barbi, Enrico Constantini
  • Patent number: 5207705
    Abstract: An implantable medical prosthesis is provided having a uniform mixture of foam polyurethane and collagen. The prosthesis can be shaped into an elongated hollow body tube useful for implantation in an animal. Alternatively, the prosthesis can be shaped into biocompatible units useful as soft-tissue replacements or as matrices for sustained-release vehicles.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: May 4, 1993
    Assignee: Brigham and Women's Hospital
    Inventors: Leonard A. Trudell, Anthony D. Whittemore
  • Patent number: 5188890
    Abstract: A metallized porous fluorinated polymer in which at least the inside surfaces are coated with a hydrophilic fluorinated polymer and the surface of the hydrophilic polymer coated with a metal film and a process for its manufacture.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: February 23, 1993
    Assignee: Japan Gore-Tex, Inc.
    Inventors: Kazuhiko Ohashi, Hiroshi Kato, Takayuki Wani
  • Patent number: 5180752
    Abstract: Microsphere wet cake is mixed with a surface barrier coating effective to prevent agglomeration and surface bonding of the microspheres, and removing water by drying with continuous mixing at high shear. In a subsequent step, by the control of the application of heat and balancing temperature and low shear mixing, it is possible to also control expansion of the microspheres.The surface barrier coating in the present invention is any one of a wide diversity of materials which meet the requirements of the intended function, i.e., to prevent the agglomeration of the microspheres during the process. Suitable materials include, by way of example, dry inorganic pigments or filler materials, and the like, and related organic materials.
    Type: Grant
    Filed: March 8, 1990
    Date of Patent: January 19, 1993
    Assignee: Pierce & Stevens Corporation
    Inventors: George E. Melber, Leon E. Wolinski, William A. Oswald
  • Patent number: 5175194
    Abstract: A flame retardant composition and process which is particularly useful for rebonded foam products. The composition of the present invention includes a solid component of magnesium sulfate, boric acid, decabromodiphenylethylene oxide (DECA) and antimony trioxide and a liquid component of halogenated phosphorous. The present invention is based upon the discovery of the synergism between boric acid and DECA. The process, according to the present invention, includes the steps of forming a dispersion of the solid portion of the flame retardant composition along with a small amount of water based adhesive to a mass of foam chips. The treated chips are then dried to permit handling and storage. The dried foam chips subsequently are mixed with a conventional urethane prepolymer binder and the liquid halogenated phosphorous flame retardant compound. After mixing the foam mass is transferred to molds and steamed to allow the binder to cure.
    Type: Grant
    Filed: May 11, 1992
    Date of Patent: December 29, 1992
    Assignee: Triad-Fabco, Inc.
    Inventors: Robert W. Ward, Rogelio Tornero, Freeman J. Henderson
  • Patent number: 5171756
    Abstract: A process for rapidly cooling porous foam material to prevent oxidation or autoignition of said foam. The process includes a first cooling step wherein cooled ambient air is drawn through the foam block thereby cooling, dehumidifying and removing fumes from said block before being vented, a second cooling step wherein cooled ambient air is drawn through the block for further cooling thereof, with sublimates in the block being condensed and redeposited within the block, and a third cooling step wherein ambient air is drawn through the material so as to remove remaining fumes, heat and moisture therefrom. The process of the present invention advantageously utilizes a foam formulation which includes an increased percentage of water for providing adequate foaming of the material while minimizing or obviating the need for including toxic auxiliary blowing agents in the formulation.
    Type: Grant
    Filed: July 31, 1991
    Date of Patent: December 15, 1992
    Assignee: Crain Industries, Inc.
    Inventors: Michael A. Ricciardi, Dzung G. Dai
  • Patent number: 5162397
    Abstract: A foamable silicone composition comprises a polysiloxane having silicon-bonded hydrogen atoms, a polysiloxane having siloxane units including unsaturated groups, a polysiloxane having silicon-bonded hydroxyl groups, a noble metal catalyst and from 3 to 40 parts by weight per 100 parts by weight of the composition of entities of borosilicate or silicate glass or mixtures thereof. The composition comprises first and second Parts A and B having viscosities which are sufficiently similar to each other to permit facile machine mixing of the Parts; the first Part comprises the noble metal catalyst and a portion of the entities and the second Part comprises the polysiloxane having silicon-bonded hydrogen atoms and a portion of the entities pretreated with a compatible silane or a polysiloxane having silicon-bonded hydrogen atoms. Preferred entities comprise hollow spherical particles or hollow entities which have an irregular configuration.
    Type: Grant
    Filed: March 11, 1992
    Date of Patent: November 10, 1992
    Assignee: Dow Corning S.A.
    Inventors: Pierre Descamps, Andreas T. F. Wolf
  • Patent number: 5141972
    Abstract: An insulation material made of rigid microballons within the pores of a porous polymeric base material.
    Type: Grant
    Filed: April 29, 1991
    Date of Patent: August 25, 1992
    Assignee: W. L. Gore & Associates, Inc.
    Inventor: Yoshiaki Sato
  • Patent number: 5124365
    Abstract: Expandable styrene polymers having a particle diameter of from 0.025 to 0.3 mm and coated with 0.5% by weight or more of a finely divided solid having a melting point above 120.degree. C. are used as a heat-insulating filler for lightweight plaster.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: June 23, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Kurt Rappold, Horst Steinbrecher, Manfred Walter
  • Patent number: 5124364
    Abstract: A composite foam of low thermal conductivity comprisesa) 20-80% by volume of silica aerogel particles having a mean diameter of from 0.1 to 20 mm and a density of from 0.08 to 0.40 g/cm.sup.3,b) 20-80% by volume of styrene polymer foam which surrounds the particles of component a) and binds them to one another and has a density of from 0.01 to 0.15 g/cm.sup.3, and, if desired,c) conventional additives in effective amounts.
    Type: Grant
    Filed: December 2, 1991
    Date of Patent: June 23, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernardo Wolff, Frieder Hohwiller, Guenther Seybold
  • Patent number: 5120769
    Abstract: Compositions are disclosed which are suitable for the preparation of thermoplastic syntactic foam intermediate and final products. These compositions comprise a slurry or putty containing thermoplastic particles, microballoons, and a non-solvent, optionally in the presence of suitable thickeners, binders, and surfactants. In a preferred embodiment, the composition contains particles of an engineering thermoplastic having a mean particle size less then about 100 .mu.m, microballoons, water as the non-solvent, and a thickener/binder which is a lightly crosslinked polyacrylic acid.
    Type: Grant
    Filed: April 30, 1990
    Date of Patent: June 9, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Joel Dyksterhouse, Alan C. Handermann, George E. Husman, Peter G. Ittemann
  • Patent number: 5114981
    Abstract: A flame retardant composition and process which is particularly useful for rebonded foam products. The composition of the present invention includes a solid component of magnesium sulfate, boric acid, decabromodiphenylethylene oxide (DECA) and antimony trioxide and a liquid component of halogenated phosphorous. The present invention is based upon the discovery of the synergism between boric acid and DECA. The process, according to the present invention, includes the steps of forming a dispersion of the solid portion of the flame retardant composition along with a small amount of water based adhesive to a mass of foam chips. The treated chips are then dried to permit handling and storage. The dried foam chips subsequently are mixed with a conventional urethane prepolymer binder and the liquid halogenated phosphorous flame retardant compound. After mixing the foam mass is transferred to molds and steamed to allow the binder to cure.
    Type: Grant
    Filed: November 13, 1991
    Date of Patent: May 19, 1992
    Assignee: Triad-Fabco, Inc.
    Inventors: Robert W. Ward, Rogelio Tornero, Freeman J. Henderson
  • Patent number: 5106881
    Abstract: A water base pigment ink composition for use in marking pens which contain an absorbent ink reservoir and a pen tip connected thereto, the ink composition comprising:(a) water in amounts of not less than 50% by weight;(b) an aqueous emulsion of hollow resin particles in amounts of 0.5-40% by weight as solids;(c) a white pigement in amounts of 1-40% by weight; and(d) a water-solubilized .alpha.-methylstyrene/styrene/acrylic acid copolymer which has a weight average molecular weight of 1000-10000 and a distribution of molecular weight of 0.5-3.3, but which contains substantially no components having a weight average molecular weight of not more than 500, in amounts of 0.1-30% by weight, based on the ink compositions, respectively.The ink composition may contain chromatic or achromatic (other than white) pigments in amounts of 0.1-30% by weight based on the ink composition.
    Type: Grant
    Filed: March 11, 1991
    Date of Patent: April 21, 1992
    Assignee: Sakura Color Products Corp.
    Inventors: Hiroshi Inoue, Wataru Yokono, Yasuji Okuda
  • Patent number: 5096623
    Abstract: A flame retardant composition and process which is particular useful for rebounded foam products. The composition of the present invention includes a solid component of magnesium sulfate, boric acid, decabromodiphenylethylene oxide (DECA) and antimony trioxide and a liquid component of halogenated phosphorous. The present invention is based upon the discovery of the synergism between boric acid and DECA. The process, according to the present invention, includes the steps of forming a dispersion of the solid portion of the flame retardant composition along with a small amount of water based adhesive to a mass of foam chips. The treated chips are then dried to permit handling and storage. The dried foam chips subsequently are mixed with a conventional urethane prepolymer binder and the liquid halogenated phosphorous flame retardant compound. After mixing the foam mass is transferred to molds and steamed to allow the binder to cure.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: March 17, 1992
    Assignee: Triad-Fabco, Inc.
    Inventors: Robert W. Ward, Rogelio Tornero, Freeman J. Henderson
  • Patent number: 5093030
    Abstract: A dispersion containing minute polymer beads possessing a thermosensitive characteristic is produced by a method which comprises preparing an aqueous solution of an acrylamide type vinyl compound, the homopolymer of which exhibits a hydrophilicity-hydrophobicity thermoreversible solubility characteristic, adding a cationic or anionic surfactant in a ratio equaling or exceeding the micelle concentration to the aqueous solution, adjusting the resultant aqueous solution to a temperature not lower than the clouding point thereof and, at the same time, polymerizing the acrylamide type vinyl compound in the aqueous solution thereby forming a polymer emulsion, exposing the emulsion to an ionizing radiation thereby cross-linking minute polymer beads in the emulsion, and thereafter depriving the resultant polymer emulsion of the surfactant.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: March 3, 1992
    Assignees: Agency of Industrial Science and Technology, Ministry of International Trade and Industry
    Inventors: Shoji Ito, Okihiko Tlirasa, Shouei Fujishige, Aizo Yamauchi
  • Patent number: 5066683
    Abstract: Microporous waterproof and moisture vapor permeable products are described which are formed from a matrix having an internal microstructure which is coated with a hydrophobic material. A process is described including the steps of (1) applying to the surface of the matrix a liquid hydrophobic material, (2) allowing the liquid to penetrate into the microstructure and then (3) drying, vulcanizing or curing the product.
    Type: Grant
    Filed: May 1, 1990
    Date of Patent: November 19, 1991
    Assignee: Tetratec Corporation
    Inventors: Joseph E. Dillon, Mark E. Dillon
  • Patent number: 5047436
    Abstract: A method of improving the flame resistance of foams, such as open cell polyimide foams, through the introduction of finely divided non-metallic inorganic particles which are gel forming and insoluble in water and polar organic liquids into the foam cells. A stable liquid suspension or gel, preferably aqueous is prepared using these particles. An opacifier such as finely divided titanium dioxide or tin oxide may also be added. An open cell foam product is placed in the gel until the cells fill with the gel. Excess gel is removed and the foam is dried, leaving the particles trapped in the cells. If desired, the foam may be post treated, such as by compression at the stabilizing temperature, resulting in a densified foam which further mechanically traps the particles and further improves the flame resistance.
    Type: Grant
    Filed: February 12, 1990
    Date of Patent: September 10, 1991
    Assignee: Sorrento Engineering Corporation
    Inventors: Francis U. Hill, Lola E. Crosswhite
  • Patent number: 5041472
    Abstract: An expendable syntactic foam energy absorber having application to vehicles comprising first hollow ceramic microspheres and substantially smaller hollow ceramic microspheres distributed to fill the interstices between the first microspheres. An elastomeric binder is blended into the microsphere intermix to fill in any residual interstices between the microspheres while binding the microspheres in substantially abutting contact and leaving substantially no room for the binder to move.
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: August 20, 1991
    Assignee: Hughes Aircraft Company
    Inventor: Jon H. Myer
  • Patent number: 5037859
    Abstract: Composite foams are provided comprising a first rigid, microcellular, open-celled organic polymer foam having a density of from about 0.015 g/cm.sup.3 to about 0.20 g/cm.sup.3 and a pore size of from about 1 micron to about 30 microns, said first foam containing a second polymer having a density of from about 0.015 g/cm.sup.3 to about 0.20 g/cm.sup.3 or a second polymer foam having a density of from about 0.015 g/cm.sup.3 to about 0.20 g/cm.sup.3 and a pore size of from about 0.01 microns to about 1.0 micron within the open cells of said first foam.
    Type: Grant
    Filed: August 24, 1990
    Date of Patent: August 6, 1991
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Joel M. Williams, Jr., Alice M. Nyitray, Mark H. Wilkerson
  • Patent number: 5034222
    Abstract: A solid composite air freshening article is provided which comprises a granular foam phase dispersed throughout a gelled phase in an amount effective to provide a sustained release of an effective amount of volatile air freshening ingredients present in both the foam and gelled phases. The foam phase comprises granules of a hydrophilic, polyurethane foam incorporating a volatile air freshening ingredient, a surfactant, and a solid filler material, while the gelled phase comprises water, a gelling agent, an organic solvent, and the same or a different air freshening ingredient as the granular foam phase.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: July 23, 1991
    Assignee: Creative Products Resource Associates, Ltd.
    Inventors: George W. Kellett, James A. Smith, Bonnie Johanning
  • Patent number: 5032619
    Abstract: Systems for storing and dispensing gases. The gas storage systems are two-phase gas/solid or gas/liquid, or three-phase gas/liquid/solid, functioning by reversible sorption. In gas storage systems having a solid phase, use is made of a polymeric material, preferably a hydrogel, having microvoids functioning as interstitial stores for gas. Reversible gas sorption in the microporous polymer is improved by treatment with a swelling promoter. The stored gas may be a propellant, and reversible sorption propellant storage may be used in all types of pressure pack dispenser. Cryogenic techniques facilitate preparation of propellant systems with standardized parameters. The invention enables use of safe and environmentally benign gases as propellants.
    Type: Grant
    Filed: March 2, 1990
    Date of Patent: July 16, 1991
    Assignee: Rocep-Lusol Holdings Limited
    Inventors: Bernard D. Frutin, Peter G. Perkins
  • Patent number: 5009536
    Abstract: A water base pigment ink composition for use in marking pens which contain an absorbent ink reservoir and a pen tip connected thereto, the ink composition comprising:(a) water in amounts of not less than 50% by weight;(b) an aqueous emulsion of hollow resin particles in amounts of 0.5-40% by weight as solids;(c) a white pigment in amounts of 1-40% by weight; and(d) a water-solubilized .alpha.-methylstyrene/styrene/acrylic acid copolymer which has a weight average molecular weight of 1000-10,000 and a distribution of molecular weight of 0.5-3.3, but which contains substantially no components having a weight average molecular weight of not more than 500, in amounts of 0.1-30% by weight, based on the ink compositions, respectively.The ink composition may contain chromatic or achromatic (other than white) pigments in amounts of 0.1-30% by weight based on the ink composition.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: April 23, 1991
    Assignee: Sakura Color Products Corp.
    Inventors: Hiroshi Inoue, Wataru Yokono, Yasuji Okuda
  • Patent number: 4992481
    Abstract: The new fire retardant elements are characterized in that they are foam mouldings which are elastic in the moist state and contain a liquid flameproofing impregnation, and the fire retardant elements are protected against moisture loss before installation and solidify on drying after installation. A process for the production of such fire retardant elements and mouldings which comprise such fire retardant elements are likewise described and claimed.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: February 12, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wulf von Bonin, Ulrich von Gizycki
  • Patent number: 4988739
    Abstract: A method of improving the flame resistance of foams, such as open cell polyimide foams, through the introduction of finely divided metal oxide particles into the foam cells. A stable water suspension or gel is prepared using particles of metal oxides, such as aluminum oxide and silicon dioxide. An opacifier such as titanium dioxide may also be added. An open cell foam product is placed in the gel until the cells fill with the gel. Excess gel is removed and the foam is dried, leaving the metal oxide particles trapped in the cells. If desired, the foam may be post treated, such as by compression at the stabilizing temperature, resulting in a densified foam which further mechanically traps the particles.
    Type: Grant
    Filed: February 12, 1990
    Date of Patent: January 29, 1991
    Assignee: Sorrento Engineering, Inc.
    Inventor: Francis U. Hill
  • Patent number: 4972000
    Abstract: Hollow polymer particles having at least two polymer layers, wherein (1) the particles have an average particle diameter in the range of 0.15 to 20 micrometers, (2) each of the particles has an average equivalent hollow diameter/equivalent particle diameter in the range of 0.2 to 0.8, (3) the proportion of a toluene-insoluble portion of the particles is 20 to 90% by weight, (4) the polymer particles have a melt flow rate at 180.degree. C. under 10 kgf/cm.sup.2 of 0.1 to 1 g/10 min., (5) the inside layer of the two polymer layers is composed of a crosslinked polymer and (6) the outside layer of the two polymer layers is composd of a non-crosslinked polymer. This invention also provides hollow crosslinked polymer particles wherein the proportion of a toluene-insoluble portion of the particles exceeds 85% by weight, the melt flow rate of the polymer particles at 180.degree. C. under 10 kgf/cm.sup.2 is less than 0.2 g/10 min., and the outside layer is composed of a crosslinked polymer.
    Type: Grant
    Filed: February 24, 1989
    Date of Patent: November 20, 1990
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Nobuo Kawashima, Fujio Sakurai, Hiroshi Tadenuma
  • Patent number: 4962132
    Abstract: A method of improving the flame resistance of foams, such as open cell polyimide foams, through the introduction of finely divided non-metallic inorganic particles which are gel forming and insoluble in water and polar organic liquids into the foam cells. A stable liquid suspension or gel, preferably aqueous is prepared using these particles. An opacifier such as finely divided titanium dioxide or tin oxide may also be added. An open cell foam product is placed in the gel until the cells fill with the gel. Excess gel is removed and the foam is dried, leaving the particles trapped in the cells. If desired, the foam may be post treated, such as by compression at the stabilizing temperature, resulting in a densified foam which further mechanically traps the particles and further improves the flame resistance.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: October 9, 1990
    Assignee: Sorrento Engineering Corporation
    Inventors: Francis U. Hill, Lola E. Crosswhite
  • Patent number: 4942185
    Abstract: A water base pigment ink composition for use in marking pens which contain an absorbent ink reservoir and a pen tip connected thereto, the ink composition comprising:(a) water in amounts of not less than 50% by weight;(b) an aqueous emulsion of hollow resin particles in amounts of 0.5-40% by weight as solids;(c) a white pigment in amounts of 1-40% by weight; and(d) a water-solubilized .alpha.-methylstyrene/styrene/acrylic acid copolymer which has a weight average molecular weight of 1000-10,000 and a distribution of molecular weight of 0.5-3.3, but which contains substantially no components having a weight average molecular weight of not more than 500, in amounts of 0.1-30% by weight, based on the ink compositions, respectively.The ink composition may contain chromatic or achromatic (other than white) pigments in amounts of 0.1-30% by weight based on the ink composition.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: July 17, 1990
    Assignee: Sakura Color Products Corp.
    Inventors: Hiroshi Inoue, Wataru Yokono, Yasuji Okuda
  • Patent number: 4935452
    Abstract: A method of improving the flame resistance of foams, such as open cell polyimide foams, through the introduction of finely divided metal oxide particles into the foam cells. A stable water suspension or gel is prepared using particles of metal oxides, such as aluminum oxide and silicon dioxide. An opacifier such as titanium dioxide may also be added. An open cell foam product is placed in the gel until the cells fill with the gel. Excess gel is removed and the foam is dried, leaving the metal oxide particles trapped in the cells. If desired, the foam may be post treated, such as by compression at the stabilizing temperature, resulting in a densified foam which further mechanically traps the particles.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: June 19, 1990
    Assignee: Sorrento Engineering, Inc.
    Inventor: Francis U. Hill
  • Patent number: 4923907
    Abstract: A method of making thermal insulating products comprising porous, lightweight, high temperature resistant inorganic particles in a polyimide foam matrix and the product thereof. A polyimide precursor powdered is mixed with about equal weight of flake-like porous inorganic particles to substantially uniformly coat the particles with powder. The mixture is placed in a mold and compressed slightly. The assembly is heated to the foaming temperature of the polyimide precursor for a period suitable to product uniform foaming. Then the temperature is raised to the curing and crosslinking temperature of the precursor for a time period sufficient to product complete cure. A high temperature and flame resistant, light weight, highly insulating product results. If desired, protective sheets of material may be bonded to selected product surfaces during or after the molding operation.
    Type: Grant
    Filed: July 24, 1989
    Date of Patent: May 8, 1990
    Assignee: Sorrento Engineering, Inc.
    Inventor: Francis U. Hill
  • Patent number: 4905439
    Abstract: This invention provides improved strength structural building elements having improved insulation properties. The element comprises a monolithic form with at least a pair of opposed faces and at least one aperture which extends between the opposed faces. In one embodiment, the building element is formed of a mixture of expanded cellular synthetic material, sand of a particular finus modulus to impart improved strength, and cementitious material with the cellular material being distributed throughout the structural element. In another embodiment, the building element is formed of expanded cellular material of three approximately equal particle size distribution ranges to provide expanded strength characteristics, sand and cementitious material. Both embodiments can be dry cast.
    Type: Grant
    Filed: October 13, 1988
    Date of Patent: March 6, 1990
    Assignee: Sparfil International, Inc.
    Inventor: Jacques Filteau
  • Patent number: 4886836
    Abstract: A porous chemically activated medium having a low affinity for peptide group-containing materials is provided comprising a porous polymeric medium having a low affinity for peptide group-containing materials covalently bound to a residue of an activating agent which is capable of reacting with an acceptor molecule.
    Type: Grant
    Filed: June 3, 1987
    Date of Patent: December 12, 1989
    Assignee: Pall Corporation
    Inventors: Thomas C. Gsell, Richard F. Salinaro, Peter J. Degen
  • Patent number: 4876288
    Abstract: Carrier material for the immobilization of microorganisms, particularly for use in connection with microbiological conversion and/or separation of constituents from gaseous or liquid media, is disclosed. The carrier material comprises a dimensionally stable macroporous skeleton comprised of relatively coarse-grain granular material such as sinterable thermoplastic granules, and relatively fine grain microporous material, such as activated charcoal, which are bonded together. The carrier material thus comprises both macropores having a pore size of from about 10 to 200 .mu.m and micropores having a pore size of up to about 0.1 .mu.m depending upon the identity of the five grain microporous material that is used. Additional finely divided materials, such as catalytic agents or density modifying agents, may also be disposed within the macroporous skeleton. The preparation and use of the carrier material is also disclosed.
    Type: Grant
    Filed: April 7, 1987
    Date of Patent: October 24, 1989
    Assignee: Herding GmbH Entstaubungsanlagen
    Inventors: Walter Herding, Walter Rausch
  • Patent number: 4861804
    Abstract: A compound type silicone gel material which uses silicone gel having a penetration of 50 to 200 as basic material and contains a number of fine hollow cells.
    Type: Grant
    Filed: August 17, 1987
    Date of Patent: August 29, 1989
    Assignee: Kabushiki Kaisha Cubic Engineering
    Inventor: Motoyasu Nakanishi
  • Patent number: 4859710
    Abstract: A lead accumulator using dilute sulfuric acid as an electrolyte liquor is disclosed, in which the electrolyte liquor is fixed by absorption or impregnation into an ethylene copolymer resin or a molding thereof comprising from 40 to 90% by weight of an ethylene unit and from 10 to 60% by weight of at least one comonomer unit selected from (A) and ethylenically unsaturated comonomer unit having an amido group and an amino group in the molecule thereof and (B) an ethylenically unsaturated comonomer unit having an ester group and an amino group in the molecule thereof and having an average molecular weight of from 5,000 to 50,000. The lead accumulator can be produced easily and at a low cost without limitations of shape and volume and has high performance reliability.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: August 22, 1989
    Assignee: Sumitomo Chemical Co., Limited
    Inventors: Tadayuki Ohmae, Tadashi Sakurai, Noboru Yamaguchi, Mitsuyuki Okada, Kouichiro Asao
  • Patent number: 4857394
    Abstract: A flame retardant polymeric foam having a flame retarding amount of heat set carbonaceous fibers derived from stabilized acrylic fibers or pitch based fibers, said fibers having an LOI value greater than 40.
    Type: Grant
    Filed: January 29, 1988
    Date of Patent: August 15, 1989
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., R. Vernon Snelgrove, Bhuvenesh C. Goswami
  • Patent number: 4853420
    Abstract: Foamed products are prepared by subjecting a crosslinked polymer such as an ethylene-carbon monoxide copolymer susceptible to heating by high frequency electromagnetic radiation such as microwave or radio frequency which has been imbibed or impregnated with a suitable mechanical or physical blowing agent such as a halogenated hydrocarbon to sufficient high frequency electromagnetic radiation to cause foaming of the polymer.
    Type: Grant
    Filed: May 4, 1987
    Date of Patent: August 1, 1989
    Assignee: The Dow Chemical Company
    Inventors: Tu-Anh Pham, Gerald M. Lancaster