Including Step Of Surface Coating A Particle Or Process Of Expanding A Surface Coated Particle Patents (Class 521/57)
  • Patent number: 4278731
    Abstract: Expandable styrene polymer particles which have fast cooling rates during molding are produced by dry blending styrene polymer particles in the presence of 0.06 to 0.60 parts of a mixture of alkyl esters of fatty acids per 100 parts of polymer particles. The ester mixture may be added as sole fast cool agent or in addition to the known internal additives which impart fast cool properties.
    Type: Grant
    Filed: October 1, 1980
    Date of Patent: July 14, 1981
    Assignee: Arco Polymers, Inc.
    Inventors: John P. Spicuzza, Jr., John G. Klepic, III
  • Patent number: 4277567
    Abstract: Vinyl aromatic polymer compositions contain a flame-retarding amount of 1,1,2,3,4,4-hexabromobutene-2.
    Type: Grant
    Filed: December 10, 1973
    Date of Patent: July 7, 1981
    Assignee: Tenneco Chemicals, Inc.
    Inventors: Donald A. Keyworth, David C. Purpi
  • Patent number: 4272583
    Abstract: Particulate expandable styrene polymers which contain an organic bromine compound as the flameproofing agent and an organic compound possessing a labile C--C, O--O or N.dbd.N bond as the synergistic agent for flameproofing. The flameproofing agent is applied to the surface of the particles while the synergistic agent is homogeneously incorporated into the particles.The polymers can be converted to self-extinguishing foams.
    Type: Grant
    Filed: July 21, 1980
    Date of Patent: June 9, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Hahn, Herbert Naarmann, Klaus Penzien, Heinz Weber
  • Patent number: 4269871
    Abstract: Expandable styrene polymer particles are surface-coated with conjugated diene elastomers to prevent the particles from lumping together during expansion. The coating is applied by adding 0.05-0.25 part of conjugated diene elastomer to an aqueous suspension containing 100 parts of polymer particles during the impregnation of the mixture with a blowing agent.
    Type: Grant
    Filed: June 30, 1980
    Date of Patent: May 26, 1981
    Assignee: Arco Polymers, Inc.
    Inventors: Elizabeth A. Blommers, William J. Poole, Alvin R. Ingram
  • Patent number: 4255372
    Abstract: A process for the production of polyolefin foam materials from crosslinked polyolefin foam scraps includes the steps of comminuting scraps of crosslinked polyolefin-containing foam; admixing the comminuted scraps with a synthetic resin on a polyolefin basis; compressing the resulting admixture at a temperature lying below the decomposition temperature of the crosslinking agent to form an aggregate product; comminuting this product to form a particulate material; plasticizing the particulate material at a temperature lying below the decomposition temperature of the crosslinking agent to form a shaped article; and crosslinking and expanding, i.e. foaming, the shaped article by heating the article to above the decomposition temperatures of the crosslinking agent and of the blowing agent.
    Type: Grant
    Filed: October 26, 1979
    Date of Patent: March 10, 1981
    Assignee: Dynamit Nobel Aktiengesellschaft
    Inventors: Werner Kuhnel, Paul Spielau
  • Patent number: 4255525
    Abstract: Small particulate expandable styrene polymer molding compositions are prevented from acquiring static charges by coating with betaines.
    Type: Grant
    Filed: August 29, 1979
    Date of Patent: March 10, 1981
    Assignee: Chemische Werhe Huls AG
    Inventors: Josef K. Rigler, Wolfgang Schafer, Horst Leithauser, Karl Trukenbrod, Werner Bollmann
  • Patent number: 4247649
    Abstract: A molded mass containing granules of expanded thermoplastic resin mixed with a mineral binder is manufactured by preparing a molding mass in a single operation by mixing expanded thermoplastic resin granules with water, water soluble resin and a mineral binder and then pouring the resultant mixture into a mold until the mixture solidifies into the desired molded mass.
    Type: Grant
    Filed: December 28, 1979
    Date of Patent: January 27, 1981
    Assignee: Fresse S.A.
    Inventor: Gerard Damiens
  • Patent number: 4245054
    Abstract: A process for the manufacture of a thermally insulating light stucco or plaster mixture which consists of expanded polystyrene particles coated with an aqueous solution of methyl cellulose in addition to cement, wall binder and dispersion powders.
    Type: Grant
    Filed: December 12, 1979
    Date of Patent: January 13, 1981
    Assignee: BASF Aktiengesellschaft
    Inventor: Frieder Hohwiller
  • Patent number: 4238570
    Abstract: Expandable particles of a styrene polymer which comprise on the surface thereof an ester of an aliphatic carboxylic acid with an aliphatic alcohol, the ester having no hydroxyl group in the molecule and being a solid at room temperature, or a mixture of said ester and a finely divided lubricant, and a process for preparing the same.
    Type: Grant
    Filed: February 23, 1979
    Date of Patent: December 9, 1980
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Hideaki Shibata, Michihisa Osawa
  • Patent number: 4230808
    Abstract: Solid materials having a flash point of less than 500.degree. C. are rendered fire alarming by providing for the presence thereon of micro capsules containing a bromofluoroalkane having a critical temperature of at least 100.degree. C., the micro capsules having an external diameter of from 200 to 260 microns, and the wall of the capsules consisting of a polymer, treated to release the bromofluoralkane suddenly at a predetermined temperature to provide a detonation having a maximum sound level of 10-12 kHz.
    Type: Grant
    Filed: November 29, 1978
    Date of Patent: October 28, 1980
    Inventor: Anthonius H. Pietersen
  • Patent number: 4218511
    Abstract: Particulate self-extinguishing thermoplastic molding compositions based on styrene polymers containing volatile blowing agents are surface-coated with an organic bromine compound and, to stabilize the bromine compound against photodegradation, a N-hydroxyphenylbenzotriazole or a hydroxybenzophenone. The molding compositions may be used for the manufacture of foams by expanding the blowing agents at elevated temperatures.
    Type: Grant
    Filed: December 1, 1978
    Date of Patent: August 19, 1980
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Hahn, Manfred Walter, Karl Stange, Heinz Weber
  • Patent number: 4198485
    Abstract: Pre-expanded styrene polymer particles, which may contain one or more pre-expanded styrene polymer beads, are coated with sufficient water glass so that the particles, when dried to a reversible, tack-free pourable state, comprise from about 30% to 80% styrene polymer solids. The particles may be shaped into a desired article configuration and then dried to a tack-free state, the particles adhering together through the water glass, and the resulting article having a bulk density of from about 1.25 lbs. to 3 lbs. per cubic foot. The water glass or the pourable particles may be treated to decrease alkalinity and to cause irreversible precipitation of water glass solids, rendering the final product essentially waterproof.
    Type: Grant
    Filed: October 31, 1977
    Date of Patent: April 15, 1980
    Assignee: Rubber Research Elastomerics, Inc.
    Inventor: Fred J. Stark, Jr.
  • Patent number: 4191803
    Abstract: Expandable particles of a styrene polymer containing therein 3 to 8% by weight of a blowing agent and having a particle size of 0.8 to 0.25 mm. in diameter, or their pre-expanded particles, which comprises an ester of sucrose represented by the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent a hydrogen atom, an alkanoyl group having 6 to 22 carbon atoms or an alkenoyl group having 6 to 22 carbon atoms; and all of R.sub.1, R.sub.2 and R.sub.3 are not hydrogen atoms at the same time, or its derivative, said ester of sucrose or its derivative being coated on the surface of said particles.
    Type: Grant
    Filed: November 17, 1978
    Date of Patent: March 4, 1980
    Assignee: Hitachi Chemical Company, Ltd.
    Inventor: Tetsuya Katoh
  • Patent number: 4174427
    Abstract: Expandable-polystyrene beads suitable for use in making impervious containers are made from a recipe including styrene, free-radical initiator and polyvinyl pyrrolidone, and this practice includes a step of washing the beads in a warm aqueous solution to which an alkoxylated nonionic surfactant having 70-90 percent of its molecular weight accounted for by oxyethylene units is added in an amount effective to cause the washing to remove contaminating grafted polyvinyl pyrrolidone from the surface of the beads and cause them to become expandable into impervious product containers.
    Type: Grant
    Filed: July 21, 1978
    Date of Patent: November 13, 1979
    Assignee: BASF Wyandotte Corporation
    Inventors: Pauls Davis, Herbert H. Gahmig, Irving R. Schmolka
  • Patent number: 4158031
    Abstract: This invention relates to electrically conductive foam moulding manufactures from electrically conductive polystyrene beads containing blowing agent.
    Type: Grant
    Filed: March 28, 1977
    Date of Patent: June 12, 1979
    Assignee: Reuter Technologie GmbH, AM Rauhen Berge
    Inventors: Franz G. Reuter, Tankred Menzel
  • Patent number: 4153763
    Abstract: Disclosed is a process for producing expandable beads of vinyl aromatic polymer resin which provide cellular materials having a smaller and more uniform cell size, comprising the steps of suspension polymerizing beads of the vinyl aromatic polymer resin, and impregnating the beads while in suspension with a liquid blowing agent in the presence of an emulsifier comprising a diethanolamide of a fatty acid containing from 12 to 20 carbon atoms, and having a hydrophilic-lipophilic balance lower than 15.
    Type: Grant
    Filed: May 18, 1978
    Date of Patent: May 8, 1979
    Assignee: Labofina S. A.
    Inventor: William J. I. Bracke
  • Patent number: 4110267
    Abstract: Expandable ethylenically unsaturated polymer particle compositions containing an expanding agent, said polymer particles having the surfaces thereof coated with a layer of a compound comprising calcium carbonate having a particle size of from 0.02 to 0.2 microns and the surfaces of said calcium carbonate particles having chemically attached thereto organic compounds selected from the group consisting of higher fatty acids, resin acid, lignin sulfonic acid and mixtures thereof.
    Type: Grant
    Filed: July 17, 1975
    Date of Patent: August 29, 1978
    Assignee: Sekisui Kaseihin Kogyo Kabushiki Kaisha
    Inventors: Toshiki Ikeda, Yoshitsugu Beppu
  • Patent number: 4098759
    Abstract: Bromine-containing phosphonic acid esters of the formula ##STR1## in which R represents a halogen-containing linear or branched aliphatic or cycloaliphatic hydrocarbon radical having from 1 to 8 carbon atoms and R' and R" are hydrogen, halogen or alkyl groups having from 1 to 4 carbon atoms which may be closed to form a ring and/or substituted by halogen, at least one substituent being a bromine atom, are suitable as flame retardants for plastic materials, especially polystyrene and styrene copolymers.
    Type: Grant
    Filed: January 27, 1976
    Date of Patent: July 4, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Siegfried Noetzel, Horst Jastrow, Edgar Fischer