System Contains Two Or More Solid Polymers Or Contains At Least One Solid Polymer And At Least One Polymer-forming System Patents (Class 521/75)
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Patent number: 9339994Abstract: Embodiments of a new foamed surface covering are disclosed, wherein a primary layer of polymeric foam features at least one coherent layer consisting of a water-resistant blend of styrene-maleic anhydride and acrylic resin. The coherent layer facilitates the secured and reusable application of the surface covering after repeated washings.Type: GrantFiled: September 21, 2012Date of Patent: May 17, 2016Assignee: KITTRICH CORPORATIONInventor: Mark A Calkins
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Patent number: 9006303Abstract: The invention provides a particulate material comprising porous polymeric microparticles having a mesoporous structure. A process for making the particles is also presented. The process comprises impregnating a porous microparticulate template material with a liquid comprising one or more monomers. The one or more monomers are then polymerized in and/or on the template material to form a polymer, and the template material is then removed to produce the particulate material.Type: GrantFiled: March 8, 2007Date of Patent: April 14, 2015Assignee: Agency for Science, Technology and ResearchInventors: Yugen Zhang, Jackie Y. Ying, Pranab K. Singapore
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Patent number: 8664286Abstract: To provide a vibration damping composition: excellent in vibration damping property and thermal drying property in a wide temperature range; and sufficiently suppressing sagging of a vibration damping coating film on the vertical surface; and therefore useful for vibration damping materials of various structures. A vibration damping composition comprising an emulsion for vibration damping materials, a foaming agent, and an inorganic pigment, wherein the emulsion for vibration damping materials comprises a particle having a core part formed from an acrylic copolymer (A) and a shell part formed from an acrylic copolymer (B), and at least one of the acrylic copolymers (A) and (B) is prepared by copolymerizing a monomer component comprising methacrylic acid.Type: GrantFiled: September 19, 2006Date of Patent: March 4, 2014Assignees: Nippon Shokubai Co., Ltd., Nihon Tokushu Toryo Co., Ltd.Inventors: Yoshihiko Yasui, Hiroshi Suzuki, Dai Nagaishi
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Patent number: 8497316Abstract: It concerns a crosslinkable and foaming polyester-polyurethane resin moulding composition, comprising: an A component, comprising: A1) at least one poly-functional isocyanate compound, and A2) at least one free radical polymerization initiator a B component, comprising by weight: B1) 100 parts of at least one polyol resin comprising: —B11) 50 to 80 parts of at least one ethylenically unsaturated polyester polyol—B 12) 20 to 50 parts of at least one ethylenically unsaturated monomer, with, B11), being the reaction product of: a) an acid component comprising: a1) at least one ethylenically unsaturated diacid, and a2) at least one saturated diacid with a1/a2 molar ratio so varying to have an unsaturation content in B11) from 0.25/1 to 5/1, and, b) a diol component in excess with respect to component a) B2) from 0.01 to 1.Type: GrantFiled: September 29, 2008Date of Patent: July 30, 2013Assignee: CCP Composites UK LtdInventors: Paul Darby, Phil Dean
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Patent number: 8436105Abstract: The invention relates to a composition that can be thermally cured, containing relative to the total composition, a) 5 to 90% by weight of a diene-based polymer or copolymer containing an olefinic double bond and/or an aromatically substituted olefin, wherein the polymer or copolymer is liquid, or paste-like, at 22° C. and has a glass transition temperature between ?30° C. and +15° C., measured according to a DSC method; b) a vulcanization system selected from the group consisting of: b1) sulfur, and one or more accelerator(s), b2) peroxidic or disulfidic vulcanization systems, b3) quinones, quinone dioximes, or dinitrosobenzene.Type: GrantFiled: November 29, 2011Date of Patent: May 7, 2013Assignee: Henkel AG & Co. KGaAInventors: Rainer Kohlstrung, Takehito Yamada
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Publication number: 20130078445Abstract: A foam comprises (a) starch, (b) plasticizer, (c) compatibilizer, and (d) polyolefin selected from one or more of ethylene homopolymer, ethylene/alpha-olefin copolymer, ethylene/vinyl ester of aliphatic carboxylic acid copolymer, propylene homopolymer, and propylene copolymers. The ratio of A to B is at least 0.01, where A is the sum of the weights of components (a) and (b), and B is the sum of the weights of components (a) though (d). The foam may have a density of at most 10 pounds/cubic foot.Type: ApplicationFiled: September 22, 2011Publication date: March 28, 2013Applicant: Sealed Air Corporation, Cryovac, Div.Inventors: Natarajan S. Ramesh, Emanuel M. DaSilva
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Patent number: 8277719Abstract: A process for the preparation of thermoplastic auxetic foams comprising the steps of: a) taking conventional thermoplastic foam; b) subjecting said foam to at least one process cycle wherein the foam is biaxially compressed and heated; c) optionally subjecting the foam to at least one process cycle wherein the biaxial compression is removed and the foam mechanically agitated prior to reapplying biaxial compression and heating; d) cooling said foam to a temperature below the softening temperature of said foam; and e) removing said compression and heat.Type: GrantFiled: November 6, 2006Date of Patent: October 2, 2012Assignee: Auxetic Technologies Ltd.Inventors: Andrew Alderson, Kim Lesley Alderson, Philip John Davies, Gillian Mary Smart
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Patent number: 8227547Abstract: This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 120° C. or more; and (b) a second propylene polymer component comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120° C.; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%, and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec?1 and temperature of 180° C.Type: GrantFiled: January 7, 2011Date of Patent: July 24, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Peijun Jiang, Abdelhadi Sahnoune, Armenag Dekmezian
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Patent number: 7879922Abstract: Expanded products, more specifically, rigid or semi-flexible foams of low density from 1.5 to 12 lbs/ft3 or more, with closed cells can be manufactured. The products have a PVC backbone with branches with methacrylate crosslinked with isocyanate through a reaction activated by ultraviolet or microwave radiation. The use of polyfunctional monomers that are sensitive to irradiation yields a higher cross-link density, which improves the physical and mechanical properties such as hardness, resistance to abrasion, ductility, and resistance to friction. The selection of monomers and oligomers allows the manufacturer to determine of the final properties of the foam. The process yields foams with extreme hardness and better shear factors making the foam an ideal product for aerospace and windmill use. These physical properties emerge during the post-curing process, preferably by use of compounds based on methacrylates in dispersion with PVC and isocyanates.Type: GrantFiled: November 20, 2007Date of Patent: February 1, 2011Assignee: PolyuMAC Inc.Inventor: Juan Miguel Vazquez
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Patent number: 6861476Abstract: Compositions of elastoplastic ionomeric polymers having hardness below 92 points Shore A. comprising polar elastomers (10-45 wt. %), such as polyacrylic and nitrile rubbers, apolar crystalline polyolefins (15-40 wt. %) and elastoplastic polyolefins (25-75 wt. %). These compositions are used for making single-layer and multilayer laminar products that can be bonded by radio-freqeuncy welding, and manufactured articles possessing antistatic properties.Type: GrantFiled: May 19, 2001Date of Patent: March 1, 2005Assignee: Basell Poliolefine Italia S.p.A.Inventors: Vittorio Braga, Virginie Lietard
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Patent number: 6803417Abstract: Slush moldable polyolefin powders are prepared by blending a crosslinkable silane-grafted, olefinic interpolymer, optionally containing a crystalline polypropylene homopolymer or interpolymer; and a crosslinked silane-grafted, olefinic interpolymer containing a cure catalyst, the blend optionally containing a crystalline polyolefin powder. The resulting compositions can be slush molded to make a variety of articles of manufacture, especially automotive interior components, having good hot tear properties, low hardness and no glossing after heat aging.Type: GrantFiled: September 25, 2002Date of Patent: October 12, 2004Assignee: Dupont Dow Elastomers L.L.C.Inventors: Stephen H. Cree, Timothy E. Clayfield
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Patent number: 6582811Abstract: A method of purification of physiological liquids of organism has the step of passing a physiological liquid through a material which has a size, a shape, and a structure selected so as to remove toxic compounds from the physiological liquid and is composed of a partially chloromethylated porous highly crosslinked styrene or divinylbenzene copolymer which initially have surface exposed chloromethyl groups in which thereafter chlorine is replaced with an element which forms different surface exposed functional groups with a greater hydrophilicity and greater biocompatibility than that of the chloromethyl group.Type: GrantFiled: July 13, 1999Date of Patent: June 24, 2003Assignee: Renal Tech International LLCInventors: Vedirn Davankov, Maria Tsyurupa, Ludmilla Pavlova, Dzidra Tur
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Patent number: 6559193Abstract: Disclosed is an acrylic sol for a sound insulating underbody coating. It includes acrylic polymer fine particles, a plasticizer, a filler, a plasticizer, a blocking type urethane resin, a curing agent and a foaming agent. Since it includes the acrylic polymer particles as a major constituent unit, it does not generate a hydrogen chloride gas and dioxins when it is burned. Moreover, since the paint film resulting from the acrylic sol has a net-shaped structure by the cross-linkage reactions of the urethane resin, and since the bulkiness of the paint film is increased by the foaming agent, it has a good cold resistance and adhesion property toward automotive steel plates, and effects a superb chipping resistance and sound insulating performance.Type: GrantFiled: May 2, 2001Date of Patent: May 6, 2003Assignees: Aisin Kako Kabushiki Kaisha, Toyota Jidosha Kabushiki KaishaInventors: Akira Nonoyama, Hiroshi Torii, Kazunori Ito, Yutaka Ohashi, Ayumi Takata
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Patent number: 6465535Abstract: The present invention provides a vibration reducing grip material that includes a closed-cell poly(vinyl chloride) foam material having a Shore durometer of about 50 to about 70. According to one embodiment of the present invention, there is provided a vibration reducing handle cover for an impact tool.Type: GrantFiled: February 29, 2000Date of Patent: October 15, 2002Assignee: Estwing Manufacturing CompanyInventor: Daniel M. Eisman
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Patent number: 6187427Abstract: Three-phase composite materials system having a low dielectric constant and physico-chemical properties suitable for IC fabrication conditions, and a method for making such materials, are disclosed. The three-phase composite material includes an organic phase, an inorganic phase and a void phase. The organic phase is in the form of an organic polymer matrix, the void phase is represented by microporosity present in the matrix, and the inorganic phase is implemented as inorganic particles that are coupled, via a coupling agent, to the organic matrix. The low dielectric constant of the composite is attributable to the microporous organic polymer matrix. The inorganic particles are responsible, at least in part, for providing thermal stability and other required physico-chemical properties to the composite.Type: GrantFiled: March 27, 1999Date of Patent: February 13, 2001Assignee: Lucent Technologies, Inc.Inventors: Ralph E. Taylor-Smith, Jorge Luis Valdes
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Patent number: 6127440Abstract: A method of producing an extruded plastics foam of enhanced physical strength includes intimately mixing a blowing agent incorporation CO.sub.2, the major portion of which is a natural gas, in a plastics resin melt to form a homogenous resin mix, and extruding the resin mix through an exit die into a region of lower pressure. At the point of extrusion out of the exit die, the temperature of the resin mix is adjusted so that it is below the critical temperature.Type: GrantFiled: October 31, 1997Date of Patent: October 3, 2000Assignee: ACI Operations PTY LTDInventor: Graham Ramlu Sanyasi
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Patent number: 6048909Abstract: The present invention pertains to improved alkenyl aromatic polymer foams (and processes for their preparation) having increased heat distortion temperature and improved dimensional stability while maintaining good tensile/tear, creep and environmental dimensional change properties.The closed cell low density alkenyl aromatic polymer foams exhibit increased heat distortion temperature, when substantially random interpolymers of about 21 to about 65 mol % styrene are blended in. When these same alkenyl aromatic polymer foams are made without these interpolymers, the heat distortion temperature is not improved.Type: GrantFiled: December 4, 1998Date of Patent: April 11, 2000Assignee: The Dow Chemical CompanyInventors: Bharat I. Chaudhary, Russell P. Barry, Stephanie C. Cirihal
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Patent number: 5976434Abstract: Polypropylene (PP) membranes having a hydrophilic surface have been prepared by extracting a fugitive hydrophilic pore-forming agent from a gelled film prepared by evaporating the solvent from a homogeneous solution of isotactic polypropylene, functionalized polypropylene and the fugitive agent in a solvent, such as xylene. Most of the functional groups, such as --OH, --NH.sub.2 and --COOH, in the functionalized polypropylene are located on the surfaces of the membrane, including pore surfaces. The resulting membranes, especially membranes having an asymmetric structure, are useful for ultrafiltration, dialysis and/or microfiltration.Type: GrantFiled: April 6, 1998Date of Patent: November 2, 1999Assignee: The Penn State Research FoundationInventor: Tze-Chiang Chung
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Patent number: 5872155Abstract: The present invention relates to vinyl chloride copolymers, in the latex form, the particles of which are composed of a core, of an outer layer and optionally of an intermediate layer. It also relates to the process for the manufacture of this latex by seeded miscosuspension polymerization and to its applications in paints and plastisols.Type: GrantFiled: May 30, 1997Date of Patent: February 16, 1999Assignee: Elf Atochem S.A.Inventors: Philippe Espiard, Richard Peres, Benoit Ernst
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Patent number: 5776993Abstract: This invention relates to a thermoplastic PVC foam composition and more particularly, to the thermoplastic PVC foam composition suitable for a shoe material, which is characterized by the following fabrication and advantages. Some plasticizer and additive are added to the PVC base, plasticized by dioctyl phthalate (hereinafter called as "DOP") or epoxide soybean oil (hereinafter called as "ESO") to obtain the thermoplastic PVC foam composition. Then, one type of compound, selected from rubber thermoplastic urethane compound (hereinafter called as "TPU") and ethylenevinyl acetate copolymer (hereinafter called as "EVA"), was added to the mixture for modification.Type: GrantFiled: September 3, 1996Date of Patent: July 7, 1998Assignees: Korea Institute of Footwear & Leather Technology, HS CorporationInventors: Bong Sub Shin, Jae Yeon Lee, Dong Keun Kim, Seoun Jun Kim, Sung Ok Cho
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Patent number: 5756555Abstract: Plastisol compositions based on vinyl chloride/vinyl acetate copolymers produced by suspension polymerization have a low viscosity, even with low polymer-to-plasticizer ratios, so that they may be used for plastisol formulations suitable for airless spraying. The compositions are stable in storage and show good gelation properties. Coatings based on these plastisols have a good noise-damping effect, even with high vinyl acetate contents.Type: GrantFiled: December 20, 1996Date of Patent: May 26, 1998Assignee: Henkel Teroson GmbHInventors: Karl Wesch, Klaus Ruch
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Patent number: 5753717Abstract: A method of producing an extruded plastics foam of enhanced physical strength includes intimately mixing a blowing agent incorporation CO.sub.2, the major portion of which is a natural gas, in a plastics resin melt to form a homogenous resin mix, and extruding the resin mix through an exit die into a region of lower pressure. At the point of extrusion out of the exit die, the temperature of the resin mix is adjusted so that it is below the critical temperature.Type: GrantFiled: March 9, 1995Date of Patent: May 19, 1998Assignee: ACI Operations Pty Ltd.Inventor: Graham Ramlu Sanyasi
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Patent number: 5741824Abstract: The invention relates to acoustically active sprayable plastisol compositions based on styrene copolymers and/or alkyl methacrylate homopolymers and/or copolymers of methyl methacrylate which, in addition to the favorable abrasion properties and corrosion-preventing properties of the plastisols, have a good vibration-damping effect and distinctly reduce the noise caused by particle impact (chippings, water, sand).Type: GrantFiled: December 7, 1995Date of Patent: April 21, 1998Assignee: Teroson GmbHInventors: Gunter Butschbacher, Manfred Rein, Klaus Ruch, Karl Wesch
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Patent number: 5677356Abstract: An expandable poly(vinyl chloride) resin composition for use in powder molding process containing a granular poly(vinyl chloride) resin, a fine-granular poly(vinyl chloride) resin, a plasticizer, a stabilizer, a foaming agent and an alkyl phosphate gives by a powder molding process an expansion-molded article having remarkably strengthened foamed cells and free from the occurrence of surface unevenness caused by polyurethane backing.Type: GrantFiled: March 17, 1995Date of Patent: October 14, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Hikaru Shimizu, Toshio Igarashi, Akira Wakatsuki, Yoshihiro Nakatsuji, Yuu Shida
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Patent number: 5677360Abstract: A hydrophilic polymer alloy which has a permanent hydrophilic nature, a sufficient mechanical strength and a high safety and which is suitable for the formation of hydrophilic porous membranes manufacturable by an industrially advantageous process can be prepared by blending an amorphous hydrophilic copolymer (X) containing 10 mole % or more of an ethylene unit, 10 to 60 mole % of a vinyl alcohol unit and 1 mole % or more of a vinyl acetate unit with a polyolefin (Y). Furthermore, this polymer alloy is also suitable for the formation of hydrophilic (porous) fibers having a sufficient mechanical strength and antistatic function.Type: GrantFiled: June 2, 1995Date of Patent: October 14, 1997Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Hisayoshi Yamamori, Makoto Uchida, Kenji Niikawa, Toshinobu Koshoji
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Patent number: 5434194Abstract: A method for making a cellular rubber is described, in which water is added to a high water absorption resin, followed by allowing the resulting mixture to stand and form a hydrous gel. The hydrous gel, with or without a foaming agent, is added to a rubber compound and subjected to foaming under conditions sufficient for vulcanization thereby obtaining a cellular rubber having a closed cell structure. Cosmetic puffs using the cellular rubber are also described.Type: GrantFiled: March 29, 1993Date of Patent: July 18, 1995Assignee: Nishikawa Rubber Co., Ltd.Inventors: Satoshi Fujimoto, Masafumi Sugiyama
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Patent number: 5321090Abstract: Disclosed is a polyvinyl chloride resin powder composition containing (A) a granular polyvinyl chloride resin and (B) a fine granular vinyl chloride copolymer resin containing a copolymer composed of a vinyl chloride monomer and a carbonyloxy group-containing vinyl monomer, along with a stabilizer and a plasticizer. The composition is suitable for powder molding to produce covering materials of automotive interiors.Type: GrantFiled: November 4, 1992Date of Patent: June 14, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshihiro Nakatsuji, Toshio Igarashi, Akira Wakatsuki, Yuu Shida, Hikaru Shimizu
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Patent number: 5292565Abstract: An ink roll made of a microporous thermoplastic structure impregnated with an ink has sufficient strength, toughness and flexibility to deliver ink to a transfer roll without substantial misting of the ink from the ink roll surface as the ink roll is driven by a drive roll at peripheral speeds of 200 ips or more. The microporous plastic structure of the roll may be formed from a blend of a first polymer having particles sizes in the range of 1 to 100 .mu.m, and a second polymer having particles sizes from more than 100 .mu.m to 600 .mu.m. The second polymer is selected to impart greater strength and abrasion resistance to the roll than the first polymer. Both of the first and second polymers may be copolymers of PVC and polyvinyl acetate. The second copolymer has more acetate groups than the first polymer, giving it significantly greater strength.Type: GrantFiled: June 7, 1991Date of Patent: March 8, 1994Assignee: Porelon, Inc.Inventors: Lisa A. Napier, Stephanie S. Hinton, Sherron F. Stanton
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Patent number: 5229428Abstract: The present invention provides a method of lining a plastic closure top with a thermoplastic, non-cross linked curable, vinyl chloride copolymer plastisol composition that is plasticized with an effective low temperature fusing amount of (A) an epoxidized natural oil, (B) an organic diglycidyl ether and (C) a curing agent for the diglycidyl ether, the plastisol being stable with a shelf life of at least about four months, the method including heating, without preheating, the lining and the closure top at a temperature not over about 300.degree. F. for about 90 to 120 seconds using convection heating without pressure and without conductive heating, to fuse the composition and thereafter solidifying the fused composition and thereafter cure the composition to provide the lining with tensile and elongation measurements sufficient for a stable closure assembly.Type: GrantFiled: March 25, 1991Date of Patent: July 20, 1993Assignee: Owens-Illinois Closure Inc.Inventor: John W. Bayer
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Patent number: 5187203Abstract: A composition and foam insulation for copper tubing is described herein which is formulated to retard copper oxidation and eliminate or reduce stress corrosion in the copper tubing. The copper compatible, elastomeric foam insulation is made from a composition comprising 100 parts by weight of rubber, vinyl chloride polymer at about 15 to about 85 pphr, a plasticizer selected from the group consisting of an alkyl phosphate ester and an oxyalkyl phosphate ester at about 10 to about 100 pphr, a fire retardant in an amount of at least about 100 pphr, a stabilizer in an amount effective to prevent degradation of the rubber and vinyl chloride polymer, a preservative at from about 0.1 to about 10 pphr, and a lubricant at about 10 to about 85 pphr, wherein the composition and foamed product contains no more than about 5 parts of free phenol per million.Type: GrantFiled: October 23, 1991Date of Patent: February 16, 1993Assignee: Armstrong World Industries, Inc.Inventors: Ronald S. Lenox, Kim S. Boyd, William S. Vought, Jr.
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Patent number: 5137926Abstract: Polyaromatic fibers or microbeads which are swollen with solvent and crosslinked while swollen in such a way that the expanded, or macronet, structure of the swollen fiber or microbead is stabilized and retained even after drying exhibit high surface area and significant adsorptive capacity.Type: GrantFiled: May 8, 1991Date of Patent: August 11, 1992Assignee: Rohm and Haas CompanyInventors: Stephen G. Maroldo, Richard M. Kopchik, Eric J. Langenmayr
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Patent number: 5037857Abstract: Polyaromatic fibers or microbeads which are swollen with solvent and crosslinked while swollen in such a way that the expanded, or macronet, structure of the swollen fiber or microbead is stabilized and retained even after drying exhibit high surface area and significant adsorptive capacity.Type: GrantFiled: August 28, 1989Date of Patent: August 6, 1991Assignee: Rohm and Haas CompanyInventors: Stephen G. Maroldo, Richard M. Kopchik, Eric J. Langenmayr
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Patent number: 4956222Abstract: The present invention relates to a foamable vinyl chloride resin composition for powder molding containing a foaming agent and method for the production thereof.Type: GrantFiled: December 27, 1988Date of Patent: September 11, 1990Assignee: Sumitomo Chemical Company, LimitedInventors: Isao Matsuura, Akira Wakatsuki, Yuu Shida
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Patent number: 4485192Abstract: A container sealing composition made from a plastisol having a mass of hollow discrete microspheres incorporated therein. The composition is characterized by having increased shelf life, as manifested in reduced separation of the hollow discrete microspheres from the plastisol, and improved viscosity stability. The container sealing composition also exhibits uniform void volume which is essential for good sealability and seal quality.Type: GrantFiled: June 14, 1983Date of Patent: November 27, 1984Assignee: W. R. Grace & Co.Inventors: David A. Gibbs, Robert H. Hofeldt, Charles A. Billings
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Patent number: 4477599Abstract: A method of preparing a foamable polyvinyl system resin composition which renders a non-flammable, high strength to weight ratio foam product comprises, reacting at least 0.05 parts by weight of an organic radical initiator per 1 part by weight of polyvinyl system resin with the components consisting essentially of (a) at least one polyvinyl system resin (b) 2-100 parts by weight of at least one inorganic filler per 1 part by weight of polyvinyl system resin (c) an effective amount of at least one blowing agent.Type: GrantFiled: November 8, 1982Date of Patent: October 16, 1984Assignee: Hirosuke KojimaInventors: Takayuki Otsu, Hirosuke Kojima
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Patent number: 4454250Abstract: A blend is provided which is suitable for preparing low density cellular products of the closed cell type, said blend comprising a vinyl chloride resin, e.g., polyvinyl chloride; a butadiene rubber, e.g., butadiene-acrylonitrile; and a liquid polyfunctional or monofunctional monomer, e.g., styrene. Insulation products such as sheets or tubes (for pipe insulation) are easily fabricated by freely expanding (i.e., without employing forming molds) blends of the invention which contain heat-activatable blowing agents.Type: GrantFiled: June 27, 1983Date of Patent: June 12, 1984Assignee: Armstrong World Industries, Inc.Inventors: David M. Florence, Wayne E. Smith
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Patent number: 4434251Abstract: This invention provides a method of continuously manufacturing a cross-linked polyvinyl chloride resin foam sheet which has a low density, uniformly fine cell, excellent thermal moldability and high heat resistance and is neither deformed nor deteriorated even by long storage characterized by uniformly kneading the polyvinyl chloride resin with a blowing agent, stabilizer, plasticizer and cross-linking promoter without causing the blowing agent to decompose itself, thereby providing an unfoamed kneaded composition in which the polyvinyl chloride resin is gelled and forming said composition into a continuing sheet, irradiating said sheet with ionizing radiation to cross-link the resin; and thermally foaming the cross-linked sheet.Type: GrantFiled: January 25, 1982Date of Patent: February 28, 1984Assignee: The Furukawa Electric Co., Ltd.Inventors: Junnosuke Sasajima, Hiroshi Nagai, Kenji Mogi, Akio Nojiri, Naonori Shiina
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Patent number: 4434252Abstract: New rigid polyvinyl chloride foam having a density of less than 200 kg/m.sup.3 and having a uniform, fine-celled cell-structure consisting of a rigid vinyl chloride homopolymer containing per 100 parts by weight of polyvinyl chloride 0.1-15 parts by weight of a homo- or copolymer of an alkyl methacrylate having an alkylgroup of 1-10 carbon atoms having a viscosity of the solution .eta..sub.0.1 of between 1.times.10.sup.-6 and 4.times.10.sup.-6 m.sup.2 /s measured at 293 K in 1,2 dichloro ethylene and a method for the preparation of such a new rigid polyvinyl chloride foam.Type: GrantFiled: December 14, 1982Date of Patent: February 28, 1984Assignee: Stamicarbon B.V.Inventors: Antoon Dorrestijn, Pieter J. Lemstra, Lambert H. T. Van Unen
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Patent number: 4427795Abstract: New rigid polyvinyl chloride foam having a density of between 10 and 50 kg/m.sup.3 and having a uniform, fine-celled cell-structure consisting of a rigid vinyl chloride homopolymer containing per 100 parts by weight of polyvinyl chloride 0.1-15 parts by weight of a homo- or copolymer of an alkyl methacrylate having an alkyl group of 1-10 carbon atoms and a method for the preparation of such a rigid polyvinyl chloride foam.Type: GrantFiled: December 14, 1982Date of Patent: January 24, 1984Assignee: Stamicarbon B.V.Inventors: Antoon Dorrestijn, Pieter J. Lemstra, Lambert H. T. Van Unen
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Patent number: 4425449Abstract: A mixture of vinyl plastisol, suspension grade resin and expanded perlite is prepared in a manner such that the particles of perlite are not significantly damaged. The mixture is placed on a substrate and fused, thereby producing a foam-like material which is usable as a decorative covering. Alternatively, the mixture can be cast on a release surface and allowed to stand until the majority of the perlite particles have migrated to the top surface, thus leaving a layer of material containing substantially no perlite along the lower surface which interfaces with the release surface. Upon fusing this stratified mixture and separating the release surface, the fused material is inverted. The layer of material which contains substantially no perlite becomes the protective surface and the remaining portion of the fused material, which is foam-like in nature, becomes the resilient support. Such syntactic foams may be used as replacements or substitutes for mechanically frothed or chemically blown foams.Type: GrantFiled: April 19, 1982Date of Patent: January 10, 1984Assignee: Armstrong World Industries, Inc.Inventor: William C. Dorsey
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Patent number: 4381962Abstract: A process for producing an open cell foam comprising the steps of:(a) forming a compound comprising polyvinyl chloride resin produced by suspension polymerization, at least one organic stabilizer containing at least one Group I metal and at least one organic stabilizer containing at least one Group II metal, at least one surface active agent, and a heat decomposable blowing agent; and(b) heating the compound to decompose the blowing agent thereby producing the foam.A foamable compound comprising polyvinyl chloride resin produced by suspension polymerization, at least one organic stabilizer containing at least one Group I metal and at least one organic stabilizer containing at least one Group II metal, at least one surface active agent, and a heat decomposable blowing agent.The foam formed exhibits high breathability as well as a high water permeability when desired.Type: GrantFiled: November 28, 1980Date of Patent: May 3, 1983Assignee: Lonseal CorporationInventors: Akira Sato, Tatsuo Waki
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Patent number: 4351911Abstract: A foamable thermoplastic injection moldable composition comprising in admixture (a) a polyester resin, (b) a filler selected from the group consisting of fibrous glass or a mineral or mixtures thereof in an amount of from about 5 to about 50 weight percent, and (c) a minor amount of foaming agent.Type: GrantFiled: August 1, 1980Date of Patent: September 28, 1982Assignee: General Electric CompanyInventor: Daniel W. Fox
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Patent number: 4245055Abstract: An expandable resin/rubber blend comprising a butadiene-acrylonitrile rubber, a vinyl chloride resin, and a polymethylmethacrylate, adapted to form chemically blown, predominantly closed cell foam in a density range of about 1.8-4 pounds/cu. ft.Type: GrantFiled: December 14, 1979Date of Patent: January 13, 1981Assignee: Armstrong Cork CompanyInventor: Wayne E. Smith
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Patent number: 4237239Abstract: Reticulated polyvinyl chloride plastisol foams which can be produced using mechanical frothing techniques are disclosed. These reticulated foams are sufficiently open or porous to facilitate screen printing with plastisol inks to produce thru color, decorative, cushioned floor coverings.Type: GrantFiled: November 5, 1979Date of Patent: December 2, 1980Assignee: Armstrong Cork CompanyInventor: George L. Lilley
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Patent number: 4228245Abstract: Foamed polyblends comprising a filled styrene-butadiene rubber are rendered attractively flame-resistant (e.g. for use as carpet underlay) without loss of "green strength" needed during processing (e.g. in a Banbury mixer) by blending therewith about 10-50 parts per hundred, based on the rubber, of a pre-fused vinyl chloride polymer plastisol.Type: GrantFiled: July 2, 1979Date of Patent: October 14, 1980Assignee: Monsanto CompanyInventors: Albert W. Morgan, Roland G. Ribaudo
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Patent number: 4226943Abstract: This invention provides a foamable composition of vinyl chloride polymers comprising a vinyl chloride polymer, a plasticizer, a synthetic hydrocarbon wax, an alkali metal-zinc stabilizer and a decomposable organic blowing agent; and a method of producing an open cell sheet of vinyl chloride polymers comprising shaping the foamable composition into a sheet-like body and heating the resulting shaped body.Type: GrantFiled: November 21, 1978Date of Patent: October 7, 1980Assignee: Otsuka Kagaku Yakuhin Kabushiki KaishaInventors: Normitsu Tsurushige, Toshinori Takao, Shinichi Yamada
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Patent number: 4225643Abstract: Reticulated polyvinyl chloride plastisol foams which can be produced using mechanical frothing techniques are disclosed. These reticulated foams are sufficiently open or porous to facilitate screen printing with plastisol inks to produce thru color, decorative, cushioned floor coverings.Type: GrantFiled: October 23, 1978Date of Patent: September 30, 1980Assignee: Armstrong Cork CompanyInventor: George L. Lilley
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Patent number: 4180447Abstract: A process for the production of hard plastic foams, using a polyvinylchloride base, from a mixture of polyvinylchloride, at least one temporary softener and at least one expansion agent, wherein the mixture is heated, cooled and expanded. A polymerizable ethylenically unsaturated monomer having at least one double linkage is used as the softener. The polymerization of such monomer is carried out after complete expansion by means of ionizing rays.Type: GrantFiled: September 11, 1978Date of Patent: December 25, 1979Assignee: Lonza Ltd.Inventor: Drago Sencar