Nitrogen Compound Contains A Nitrogen Atom Bonded To A Nitrogen Or Oxygen Atom Patents (Class 521/95)
  • Patent number: 11945927
    Abstract: [Problem] An object of the present invention is to provide a foam including a thermoplastic resin and rubber as a main component, in which a micronized product of a cellulose fiber is uniformly dispersed, and uniformity and mechanical properties are excellent. [Solution] A foam includes a modified cellulose fiber (A) covalently bonded with a diene-based polymer, a thermoplastic resin and/or rubber (B), and a diene-based polymer (C) having a functional group capable of covalently bonding with a cellulose fiber, in which the fiber (A) is micronized, the fiber (A) has a content of 0.05 to 20% by mass, and the thermoplastic resin and/or rubber (B) has a glass transition point of ?130° C. to 120° C.
    Type: Grant
    Filed: February 26, 2020
    Date of Patent: April 2, 2024
    Assignee: SEIKO PMC CORPORATION
    Inventors: Ryo Miyamori, Daisuke Kuroki, Hideya Sekiguchi, Akihiro Sato
  • Patent number: 11441004
    Abstract: The present application relates to a thermally expandable composition containing at least one peroxide cross-linking polymer, at least one peroxide, at least one polysaccharide and at least one endothermic, chemical blowing agent; as well as to shaped bodies containing said composition and to a method for sealing and filling voids in components, for strengthening or reinforcing components, in particular hollow components, and for bonding mobile components using shaped bodies of this type.
    Type: Grant
    Filed: March 26, 2018
    Date of Patent: September 13, 2022
    Assignee: Henkel AG & Co. KGaA
    Inventors: Rainer Kohlstrung, Klaus Rappmann
  • Patent number: 11149138
    Abstract: Components for articles of footwear and athletic equipment are provided including a foam. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.
    Type: Grant
    Filed: May 29, 2019
    Date of Patent: October 19, 2021
    Assignee: NIKE, Inc.
    Inventor: Hossein A. Baghdadi
  • Patent number: 11098188
    Abstract: Disclosed herein is a foam composition comprising an olefin copolymer that comprises ethylene and an ?-olefin or propylene and an ?-olefin; an unneutralized carboxylated olefin copolymer; a crosslinking agent; and a blowing agent; where the foam composition is substantially free from neutralized carboxylated ethylene copolymer. Disclosed herein too is a method of manufacturing a foam composition comprising blending together an olefin copolymer that comprises ethylene and an ?-olefin or propylene and an ?-olefin; an unneutralized carboxylated olefin copolymer; a crosslinking agent; and a blowing agent to form the foam composition; where the foam composition is substantially free from neutralized carboxylated ethylene copolymer; heating the foam composition to activate the blowing agent to form a foam; and crosslinking the foam.
    Type: Grant
    Filed: September 29, 2016
    Date of Patent: August 24, 2021
    Assignee: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Chao Zhang, Haiyang Yu, Xiaolian Hu, Hongyu Chen, Yi Zhang, Xiaochun Liu
  • Patent number: 10752746
    Abstract: Disclosed is a thermally expandable composition, comprising at least one polymer P, cross-linkable by peroxide, and between 1 wt.-% and 2.5 wt.-%, based on the total weight of the composition, of at least one acrylate A, and between 0.2 wt.-% and 2.5 wt.-%, based on the total weight of the composition, of at least one peroxide, and at least one blowing agent, characterised in that the equivalent ratio of said peroxide to said acrylate A is between 0.01 and 0.5, preferably between 0.13 and 0.41, and the weight ratio of said peroxide to said acrylate A is lower than 0.33 and said polymer P comprises or essentially consists of at least two polymers PI and P2, wherein PI exhibits a melt flow index (MFI) of between 100 and 200 g/10 min, and P2 exhibits a melt flow index of between 0.1 and 60 g/10 min, wherein MFI is determined by ASTM D1238.
    Type: Grant
    Filed: July 9, 2015
    Date of Patent: August 25, 2020
    Assignee: SIKA TECHNOLOGY AG
    Inventors: Karsten Frick, Dusko Paripovic, Engin Cil, Leslie Michele Wolschleger, Jena Mabilia
  • Patent number: 10344150
    Abstract: Components for articles of footwear and athletic equipment are provided including a foam. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.
    Type: Grant
    Filed: December 6, 2017
    Date of Patent: July 9, 2019
    Assignee: NIKE, INC.
    Inventor: Hossein A. Baghdadi
  • Patent number: 9879133
    Abstract: Components for articles of footwear and athletic equipment are provided including a foam. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.
    Type: Grant
    Filed: March 14, 2017
    Date of Patent: January 30, 2018
    Assignee: NIKE, Inc.
    Inventor: Hossein A. Baghdadi
  • Patent number: 9701803
    Abstract: Disclosed are foam compositions and processes to form closed-cell tannin-based foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a tannin-based resin derived from a tannin, a first monomer, and a second monomer, wherein the first monomer comprises formaldehyde, paraformaldehyde, furfural, glyoxal, acetaldehyde, 5-hydroxymethylfurfural, acrolein, levulinate esters, sugars, 2,5-furandicarboxylic acid, 2,5-furandicarboxylic aldehyde, urea, difurfural (DFF), or mixtures thereof, and the second monomer comprises furfuryl alcohol, glycerol, sorbitol, lignin, or mixtures thereof, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: July 11, 2017
    Assignee: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Michael W Cobb, Vincent Galante, Mark Andrew Harmer, Vivek Kapur, Sharlene Renee Williams
  • Patent number: 9481786
    Abstract: Disclosed is a thermoplastic rubber composition comprising, based on 100 parts by weight of a block terpolymer (A) of an aromatic vinyl compound and an alkene compound, 50 to 100 parts by weight of a paraffin oil (B), 30 to 70 parts by weight of an inorganic additive (C), 5 to 30 parts by weight of a polyolefin-based resin (D), and 30 to 70 parts by weight of an acryl-based resin (E). The hardness of the thermoplastic rubber composition may be freely adjusted and the thermoplastic rubber composition has a bonding strength of 2 to 4 N/mm as measured using a UTM according to a KS M 6518 peeling test method. Accordingly, bonding strength thereof to a thermoplastic resin is increased even without addition of an adhesive.
    Type: Grant
    Filed: June 26, 2013
    Date of Patent: November 1, 2016
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jung Wook Kim, Chan Gyun Shin, Jong Cheol Lim
  • Publication number: 20150137408
    Abstract: A method of producing a rubber molded article, involving utilizing a compound different from a compound that has been used as a crosslinking agent. The method of producing a rubber molded article includes a crosslinking step of crosslinking a rubber component by decomposing a compound to be used as a crosslinking agent for the rubber component, the compound including a structure represented by the following formula (I), in a rubber composition containing the rubber component and the compound, the rubber composition including a sulfur content of 2.0 wt % or less: ?-?-? . . . (I) (in the formula (I), ? represents a monovalent organic group, ? represents —N?N—, and ? represents hydrogen or a monovalent organic group).
    Type: Application
    Filed: April 25, 2013
    Publication date: May 21, 2015
    Inventors: Tomokazu Watanabe, Tetsuo Oohinata, Nahoko Kitajima
  • Publication number: 20150133572
    Abstract: A composition for a sealing material which comprise a rubber component comprising copolymer rubbers of ethylene, ?-olefin having 3 or more carbon atoms and unconjugated diene, a vulcanizing agent and a blowing agent, wherein the copolymer rubber consists of copolymer rubber A and copolymer rubber B, the copolymer rubber A being derived from ethylene, ?-olefin having 3 or more carbon atoms and 3 to 5% by mass of unconjugated diene, and the copolymer rubber B being derived from ethylene, ?-olefin having 3 or more carbon atoms and 9 to 15% by mass unconjugated diene, and a mass ratio (copolymer rubber B/copolymer rubber A) of the copolymer rubber B to the copolymer A is in the range of 1/99 to 50/50, and a sealing material composed of a vulcanized foam of the composition.
    Type: Application
    Filed: May 22, 2012
    Publication date: May 14, 2015
    Applicant: BRIDGESTONE CORPORATION
    Inventor: Tomohiro Yamamoto
  • Patent number: 9006301
    Abstract: A formulation for foaming a thermoplastic polymer, for example PVC, comprises a carrier, exothermic and endothermic chemical blowing agents and 1 wt %, preferably less than 0.2 wt % of water. The liquid formulation can readily be used for foaming PVC and other thermoplastics.
    Type: Grant
    Filed: April 16, 2012
    Date of Patent: April 14, 2015
    Assignee: Colormatrix Holdings, Inc.
    Inventors: Stephen Leeming, Mark Dixon, Andrew Overend
  • Publication number: 20150094385
    Abstract: Provided are a rubber foam composition from which a rubber foam having low metal corrosive properties, low fogging properties and reduced odor and causing no poor foaming or tackiness of the rubber foam surface can be obtained, and a rubber foam using the same. The rubber foam composition comprises: a rubber component including a copolymer rubber of ethylene, an ?-olefin having three or more carbon atoms and a non-conjugated diene, a vulcanizing agent, and a foaming agent, the composition being characterized in that the vulcanizing agent comprises ?,??-di(t-butylperoxy)diisopropylbenzene and a quinoid-based vulcanizing agent, and characterized by being substantially free of urea-based foaming auxiliary, and the rubber foam uses the same.
    Type: Application
    Filed: April 9, 2013
    Publication date: April 2, 2015
    Applicant: BRIDGESTONE CORPORATION
    Inventors: Koji Achiha, Takahiro Sakami, Tsuyoshi Itoyama
  • Patent number: 8978721
    Abstract: A heat-expandable rubber layer is provided to an inner all of a pneumatic tire when the tire is in an uncured state. The rubber layer is expanded when the tire is in a vulcanized state. Once expanded, the rubber layer is capable of reducing rolling noises of the tire. The rubber layer includes an elastomer composition based on at least an elastomer, e.g., natural rubber or butyl rubber; a reinforcing filler, e.g., silica and/or carbon black; between 10 and 80 phr of a blowing agent, e.g., an azodicarbonamide compound; and between 10 and 50 phr of a hot-melt compound with a melting point between 70° C. and 150° C., e.g., urea. The combination of the blowing agent and the hot-melt compound, at recommended high contents, makes it possible to very greatly reduce an expansion ratio and therefore a thickness of the rubber layer once the pneumatic tire is vulcanized, without affecting noise absorption properties provided by the blowing agent.
    Type: Grant
    Filed: October 25, 2010
    Date of Patent: March 17, 2015
    Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.
    Inventors: Mitsue Tanaka, Salvatore Pagano
  • Publication number: 20150025163
    Abstract: The present invention is directed to a polyalkylene carbonate resin composition for producing a decorating material and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom. More particularly, the invention is directed to polyalkylene carbonate resin composition for producing a decorating material in which including a polymer additive to impart heat resistance and shape stability to the decorating material, a crosslinker and a chain extender to improve the processability at the processing temperature, and a flame retardant agent to impart a flame retardant effect, and an environment-friendly polyalkylene carbonate resin decorating material produced therefrom. The environment-friendly polyalkylene carbonate resin decorating material produced using the inventive composition has excellent thermal stability, processability, and dimensional stability.
    Type: Application
    Filed: May 28, 2014
    Publication date: January 22, 2015
    Applicant: SK INNOVATION CO., LTD.
    Inventors: Younghyo Park, Inhun Son, Kangmin Jung, Jaekoo Kim, Kwangjin Chung, Myungahn Ok
  • Publication number: 20140316021
    Abstract: A composition for sportswear, includes a rubber component (a) which contains an epihalohydrin rubber, a vulcanizing agent (b) in an amount of 0.1 to 10 parts by weight for 100 parts by weight of the rubber component (a), and a foaming agent (c) in an amount of 0.5 to 20 parts by weight therefor. The composition for sportswear is preferably includes a colorant (d).
    Type: Application
    Filed: February 6, 2012
    Publication date: October 23, 2014
    Applicant: DAISO CO., LTD.
    Inventors: Taro Ozaki, Toshiyuki Funayama, Toyofumi Otaka, Koshiro Hamaguchi, Motoki Kitagawa, Tadahiro Ono
  • Publication number: 20140295169
    Abstract: The present invention relates to a foam sheet using cross-linked polylactic acid and method of manufacturing the same, and more particularly a foam sheet using cross-linked polylactic acid and method of manufacturing the same with not only excellent waterproofing and workability but also relatively high foaming ratio and a uniform closed foam cell structure, by producing cross-linked polylactic acid resin in a fixed condition using composites comprising polylactic acid, cross linking agents, and/or co-crosslinking agents, and then forming a sheet shape in a fixed condition using composites comprising the cross-linked polylactic acid and foaming agents, and then foaming at relatively high temperature conditions.
    Type: Application
    Filed: December 6, 2012
    Publication date: October 2, 2014
    Applicant: LG Hausys, Ltd.
    Inventors: Chang Won Kang, Cheng Zhe Huang, Ji Hyang Son
  • Publication number: 20140234611
    Abstract: An ethylene-propylene-diene rubber foamed material is obtained by foaming a rubber composition containing an ethylene-propylene-diene rubber. The ethylene-propylene-diene rubber foamed material has a 50% compressive load value of 0.1 to 2.0 N/cm2 and the content ratio of a sulfur atom calculated based on the measurement result of a fluorescent X-ray measurement, based on mass, is 1000 ppm or less.
    Type: Application
    Filed: September 18, 2012
    Publication date: August 21, 2014
    Applicant: NITTO DENKO CORPORATION
    Inventors: Takayuki Iwase, Joji Kawata
  • Publication number: 20140228459
    Abstract: A vehicle tyre includes a tread formed of a heat-expandable rubber composition when in an unvulcanized state. The composition includes: from 50 to 100 phr of a copolymer based on styrene and butadiene; optionally from 0 to 50 phr of another diene elastomer, such as a polybutadiene or natural rubber; more than 50 phr of a reinforcing filler, such as silica and/or carbon black; between 5 and 25 phr of a blowing agent, such as an azodicarbonamide compound; and between 5 and 25 phr of a heat-fusible compound having a melting point between 70° C. and 150° C., such as urea or a heat-fusible urea derivative. A total content of the blowing agent and the heat-fusible compound is greater than 15 phr. Use of the composition enables, after the tyre is vulcanized, a significant reduction in noise emitted by the tyre during running.
    Type: Application
    Filed: May 31, 2012
    Publication date: August 14, 2014
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Nanae Shimanaka, Salvatore Pagano
  • Patent number: 8759410
    Abstract: This invention aims to provide a thermally foamable microsphere which is excellent in heat resistance, has a high expansion ratio, and shows stable foaming behavior; a method of producing the thermally foamable microsphere; and suitable use thereof. This invention provides a thermally foamable microsphere in which an outer shell encapsulating a foaming agent is formed of a copolymer having a polymethacrylimide structure. In particular, this invention provides a thermally foamable microsphere in which monomers capable of forming the polymethacrylimide structure by a copolymerization reaction are methacrylonitrile and methacrylic acid. Moreover, this invention provides a method of producing the thermally foamable microsphere and use of the thermally foamable microsphere as an additive.
    Type: Grant
    Filed: December 18, 2006
    Date of Patent: June 24, 2014
    Assignee: Kureha Corporation
    Inventor: Tetsuo Ejiri
  • Publication number: 20140142208
    Abstract: A foaming composition for filling contains a polymer, an organic peroxide, and azodicarbonamide, and a viscosity thereof measured at a temperature of 120° C. and under a pressure of 500 MPa with a flow tester is in a range of 1050 to 4950 Pa·s.
    Type: Application
    Filed: January 22, 2014
    Publication date: May 22, 2014
    Applicant: NITTO DENKO CORPORATION
    Inventors: Takehiro UI, Youhei HAYASHI
  • Patent number: 8726956
    Abstract: A heat-expandable rubber layer is provided to an inner all of a pneumatic tire when the tire is in an uncured state. The rubber layer is expanded when the tire is in a vulcanized state. Once expanded, the rubber layer is capable of reducing rolling noises of the tire. The rubber layer includes an elastomer composition based on at least an elastomer, e.g., natural rubber or butyl rubber; a reinforcing filler, e.g., silica and/or carbon black; between 10 and 80 phr of a blowing agent, e.g., an azodicarbonamide compound; and between 10 and 50 phr of a hot-melt compound with a melting point between 70° C. and 150° C., e.g., urea. The combination of the blowing agent and the hot-melt compound, at recommended high contents, makes it possible to very greatly reduce an expansion ratio and therefore a thickness of the rubber layer once the pneumatic tire is vulcanized, without affecting noise absorption properties provided by the blowing agent.
    Type: Grant
    Filed: October 25, 2010
    Date of Patent: May 20, 2014
    Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.
    Inventors: Mitsue Tanaka, Salvatore Pagano
  • Patent number: 8722750
    Abstract: A halogenated polymer containing a functionalized polymer and optionally a blowing agent.
    Type: Grant
    Filed: September 17, 2008
    Date of Patent: May 13, 2014
    Assignee: Rohm and Haas Company
    Inventors: Paul Van Rheenen, Eric G. Lundquist, Brian H. Clare, Ling Li
  • Publication number: 20140113983
    Abstract: A thermohardenable structural adhesive material that upon curing has an elongation at break of at least 10% and has a glass transition temperature (Tg) of 80° C. or higher and is useful as a structural adhesive in automobiles to reduce the deformation of bonds particularly during accidents, the adhesive is dry to the touch at ambient temperature and can be melt processed at temperature below that at which thermohardening occurs. The adhesives are useful in applications requiring a combination of high strain to failure, glass transition temperature more than 80° C., high stiffness and high strength. This combination is of particular interest in the aerospace and automotive industries.
    Type: Application
    Filed: February 15, 2012
    Publication date: April 24, 2014
    Applicant: ZEPHYROS INC.
    Inventors: Michael Czaplicki, Ira Miller, Vincent Duclos
  • Patent number: 8673423
    Abstract: A foaming composition for filling contains a polymer, an organic peroxide, and azodicarbonamide, and a viscosity thereof measured at a temperature of 120° C. and under a pressure of 500 MPa with a flow tester is in a range of 1050 to 4950 Pa·s.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: March 18, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Takehiro Ui, Youhei Hayashi
  • Publication number: 20140069686
    Abstract: A foamed resin molded product includes not less than two fluorine resins that have a different melting point from each other. One of the not less than two fluorine resins comprises a fluorine resin that has a melting point of not more than 230 degrees C. An other of the not less than two fluorine resins comprises a fluorine resin that has a melting point of not less than 40 degrees C. higher than the fluorine resin having the melting point of not more than 230 degrees C.
    Type: Application
    Filed: March 16, 2013
    Publication date: March 13, 2014
    Applicant: Hitachi Cable, Ltd.
    Inventors: Masahiro ABE, Masafumi Nagano, Akinari Nakayama
  • Publication number: 20140045959
    Abstract: To provide a fluorinated elastomer composition which can improve, in production of a fluorinated foamed rubber by foaming and crosslinking a fluorinated elastomer using an organic peroxide as a crosslinking agent, the foamed state and physical properties of the fluorinated foamed rubber. A fluorinated elastomer composition which comprises 100 parts by mass of a fluorinated elastomer, from 0.1 to 20 parts by mass of a blowing agent and from 0.05 to 10 parts by mass of a crosslinking agent comprising a peroxide compound, and which contains no crosslinking aid or contains a crosslinking aid comprising a compound having at least two carbon-carbon double bond-containing groups in the same molecule, in a content of at most 0.3 part by mass, is foamed and crosslinked to produce a fluorinated foamed rubber.
    Type: Application
    Filed: October 14, 2013
    Publication date: February 13, 2014
    Applicant: Asahi Glass Company, Limited
    Inventors: Makoto HONDA, Hiroshi Funaki, Yasuhiko Matsuoka
  • Publication number: 20140030539
    Abstract: A foaming composition for filling and sealing contains a vinyl copolymer having an ester bond in a side chain thereof, an organic peroxide, a foaming agent, a hydrophobic resin, and a hydrophilic resin. A content ratio of the hydrophobic resin is in a range of 5 to 25 parts by mass based on 100 parts by mass of the vinyl copolymer. A content ratio of the hydrophilic resin is in a range of 1 to 20 parts by mass based on 100 parts by mass of the vinyl copolymer.
    Type: Application
    Filed: April 13, 2012
    Publication date: January 30, 2014
    Applicant: NITTO DENKO CORPORATION
    Inventors: Takehiro Ui, Youhei Hayashi
  • Publication number: 20130303643
    Abstract: Disclosed herein are methods and pressure vessels for solid-state microcellular processing of thermoplastic rolls and sheets. In one embodiment, the present invention is directed to a method for making a gas impregnated interleaved roll, which method comprises: providing a pressure vessel having an internal pressure chamber and a rotatable shaft horizontally positioned within the pressure chamber; placing an interleaved roll about the rotatable shaft and within the pressure chamber, wherein the interleaved roll is made from a thermoplastic material sheet interleaved together with a gas-channeling material sheet; pressurizing the pressure chamber to a selected pressure; rotating the rotatable shaft having the interleaved roll thereabouts (thereby rotating the interleaved roll) while under pressure for a selected period of time; and depressurizing the internal chamber to yield the gas impregnated interleaved roll.
    Type: Application
    Filed: July 23, 2013
    Publication date: November 14, 2013
    Inventors: Krishna V. Nadella, Steven Powers, Thomas Malone
  • Publication number: 20130253083
    Abstract: The present invention relates to a polymer supported reagent comprising a novel crosslinked mesoporous polymer, enabling a simple and easy production of an azoxy compound or an azo compound from an aromatic nitro compound, and a method of selectively reducing an aromatic nitro compound by using the same. The polymer supported reagent comprises a certain acrylamide mesoporous crosslinked polymer.
    Type: Application
    Filed: March 16, 2012
    Publication date: September 26, 2013
    Applicants: IUCF-HYU (Industry-University Cooperation Foundation Hanyang University), LG Chem, Ltd.
    Inventors: Yang-Kyoo Han, Jin Cho, Sang-Mi Lee, Seung-Hoon Shin
  • Publication number: 20130210945
    Abstract: The invention relates to a cross-linked elastomer composition including: an ethylene/alpha-olefin multiblock copolymer comprising polymerized ethylene and alpha-olefin units, an elastomer including a block copolymer having at least two, identical or different, aromatic blocks which are separated by at least one elastomer block, and a cross-linkable polymer, for example, a diene elastomer. The invention also relates to a product including the composition, and to the use of such a product as a seal.
    Type: Application
    Filed: June 20, 2011
    Publication date: August 15, 2013
    Inventors: Fabrice Picot, Démosthène Sakkas, Aline Grudet
  • Publication number: 20130210621
    Abstract: A breathable film formed from a thermoplastic composition that contains a rigid renewable polyester and has a voided structure is provided. To achieve such a structure, a thermoplastic composition that contains a renewable polyester and polymeric toughening additive is extruded onto a surface to form a precursor film in which the toughening additive can be dispersed as discrete physical domains within a continuous matrix of the renewable polyester. The precursor film is thereafter stretched or drawn at a temperature below the glass transition temperature of the polyester (i.e., “cold drawn”). Without intending to be limited by theory, the present inventors believe that the deformation force and elongational strain of the drawing process causes debonding to occur in the renewable polyester matrix at those areas located adjacent to the discrete domains. This creates a network of voids located adjacent to the discrete domains.
    Type: Application
    Filed: February 10, 2012
    Publication date: August 15, 2013
    Applicant: Kimberly-Clark Worldwide, Inc.
    Inventors: Vasily A. Topolkaraev, Ryan J. McEneany, Neil T. Scholl, Thomas A. Eby
  • Publication number: 20130082412
    Abstract: A foaming composition for filling and sealing contains a polymer, 4,4?-oxybis(benzene sulfonyl hydrazide) and/or azodicarbonamide, and a hydrocalumite.
    Type: Application
    Filed: September 27, 2012
    Publication date: April 4, 2013
    Applicant: NITTO DENKO CORPORATION
    Inventor: Nitto Denko Corporation
  • Publication number: 20120273474
    Abstract: The present invention relates to a connecting apparatus used for connecting underground pipes and to a composition for preparing a foamed sheet for the same. Specifically, the present invention relates to a sheet composition for pipe connection which comprises 1 to 10 parts by weight of a masterbatch including low-density polyethylene, high-density polyethylene, a maleic anhydride graft copolymer, a metallocene polyethylene elastomer, a foaming agent, and an additive, based on 100 parts by weight of a base resin including low-density polyethylene, high-density polyethylene, a maleic anhydride graft copolymer, and a metallocene polyethylene elastomer. When using the composition according to the present invention, a non-foamed sheet is produced during melt extrusion, and a foamed sheet is obtained at a high temperature by laminating the non-foamed sheet with a heater line and applying electricity thereto. Therefore, the sheet composition can be fused and filled into a pipe.
    Type: Application
    Filed: November 17, 2010
    Publication date: November 1, 2012
    Inventor: Soo Young Joo
  • Publication number: 20120252915
    Abstract: A tyre is formed of a tread that includes, in the unvulcanized state, a heat-expandable rubber composition. The rubber composition includes at least a diene elastomer, 70 to 120 phr of a reinforcing filler, between 5 and 25 phr of a blowing agent, and between 5 and 25 phr of a thermofusible compound. The melting point of the thermofusible compound is between 70° C. and 150° C. and the total amount of the blowing agent and the thermofusible compound is greater than 15 phr. The rubber composition provides improved grip for the tread on melting ice.
    Type: Application
    Filed: November 17, 2010
    Publication date: October 4, 2012
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., CAMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Masayuki Maesaka, Salvatore Chiyoda-ku
  • Publication number: 20120252913
    Abstract: A formulation for foaming a thermoplastic polymer, for example PVC, comprises a carrier, exothermic and endothermic chemical blowing agents and 1 wt %, preferably less than 0.2 wt % of water. The liquid formulation can readily be used for foaming PVC and other thermoplastics.
    Type: Application
    Filed: April 16, 2012
    Publication date: October 4, 2012
    Inventors: Stephen Leeming, Mark Dixon, Andrew Overend
  • Patent number: 8268905
    Abstract: A composition containing poly(lactic acid), at least one bacteriocin (e.g., nisin, generally in the form of Nisaplin®), and at least one plasticizer (e.g., lactic acid, lactide, triacetin, glycerol triacetate), and optionally at least one pore forming agent. A method of making the composition, involving mixing about 100% of the total of the poly(lactic acid), about 50% to about 90% of the total of the at least one plasticizer, and optionally at least one pore forming agent at a first temperature of about 150° to about 170° C. to form a mixture, cooling the mixture to a second temperature of about 115° to about 125° C., adding at least one bacteriocin and about 10% to about 50% of the total of the at least one plasticizer and the remainder of the total of the poly(lactic acid) to the mixture and mixing to form the composition.
    Type: Grant
    Filed: August 14, 2009
    Date of Patent: September 18, 2012
    Assignee: The United States of America, as represented by the Secretary of Agriculture
    Inventors: LinShu Liu, David R. Coffin, Kevin B. Hicks, Zhonglin T. Jin
  • Publication number: 20120208911
    Abstract: A method of making a foamable polystyrene composition includes combining a styrenic monomer and a co-monomer containing a polar functional group to obtain a mixture, subjecting the mixture to polymerization to obtain a styrenic co-polymer, and combining the styrenic co-polymer with a blowing agent in a foaming process to obtain foamed articles.
    Type: Application
    Filed: January 11, 2012
    Publication date: August 16, 2012
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: Wei Wang, David W. Knoeppel, Melissa Greenberg
  • Patent number: 8227547
    Abstract: This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 120° C. or more; and (b) a second propylene polymer component comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120° C.; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%, and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec?1 and temperature of 180° C.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: July 24, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Abdelhadi Sahnoune, Armenag Dekmezian
  • Publication number: 20120184636
    Abstract: Process for the preparation of beads of expandable vinyl aromatic polymers by means of polymerization in aqueous suspension, which comprises polymerizing at least one vinyl aromatic monomer in aqueous suspension in the presence of a peroxide initiator system, active at a temperature higher than 800 C, an expanding agent, and in the presence of:—an amide having the general formula R1CONHCH2—CH2NHCOR2 (I) a flame retardant system comprising a brominated additive with a bromine content higher than 30% by weight.
    Type: Application
    Filed: August 6, 2010
    Publication date: July 19, 2012
    Applicant: POLIMERI EUROPA S.p.A.
    Inventors: Dario Ghidoni, Alessandra Simonelli, Antonio Ponticiello, Andrea La Piccirella
  • Publication number: 20120123003
    Abstract: A sealing material is provided, which maintains excellent sealing property for a long period of time. The sealing material of the invention is characterized by being prepared by vulcanizing and foaming a mixture containing a rubber component containing a copolymer rubber of ethylene, an ?-olefin having 3 or more carbon atoms, and a conjugated diene, a vulcanizing agent, and a blowing agent, wherein the mixture contains a thermoplastic resin having a melting point of 80° C. or less.
    Type: Application
    Filed: July 14, 2010
    Publication date: May 17, 2012
    Applicant: Bridgestone Corporation
    Inventors: Masaru Otsuka, Katsuya Seki, Tomohiro Yamamoto, Youhei Takeda
  • Publication number: 20120061867
    Abstract: A process for the manufacture of a plastic part, the process comprising providing a polymer, heating the polymer, introducing a gas or supercritical fluid into the polymer, mixing the polymer and the gas to produce a first melt, extruding the first melt, pelletizing the extruded first melt to form pellets, transforming the pellets into a second melt, and molding the second melt to form the plastic part. In pelletizing the first melt, individual cells of gas are included in the resulting pellets. Before the cells can nucleate, the polymer is solidified to keep the gas contained therein. After the polymer is pelletized, the pellets are considered to be unfoamed. In molding the second melt to form the plastic part, nucleation of the cells is initiated through favorable process conditions and/or additional cell nucleating agents, thereby resulting in the second melt being foamed.
    Type: Application
    Filed: September 10, 2010
    Publication date: March 15, 2012
    Applicant: PLAYTEX PRODUCTS LLC
    Inventors: Eugene P. Dougherty, JR., Lih-Sheng Turng, Chris Lacey, Jungjoo Lee, Patrick J. Gorton
  • Publication number: 20110287260
    Abstract: Process for the production of nanoporous polymer foams, comprising the stages a) loading of a single-phase, thermoplastic polymer melt with a gas under a pressure and at a temperature at which the gas is in the supercritical state, b) heating of the laden polymer melt to a temperature which lies in the range from 40° C. under to 40° C. over the glass transition temperature of the unladen polymer melt determinable by means of DSC according to DIN-ISO 11357-2 at a heating rate of 20 K/min, c) depressurization of the polymer melt loaded in stage a) and heated in stage b) with a depressurization rate in the range from 15,000 to 200,000 MPa/sec, and the nanoporous polymer foams with a cell count in the range from 1,000 to 100,000 cells/mm and a density in the range from 10 to 500 kg/m3 obtainable according to the process.
    Type: Application
    Filed: May 20, 2011
    Publication date: November 24, 2011
    Applicant: BASF SE
    Inventors: Jan Kurt Walter Sandler, Timothy Francis, Pedro Manuel Sampaio Lopes
  • Publication number: 20110263735
    Abstract: Optionally reinforced, lightweight microcellular polyamide shaped articles, e.g., automotive body or interior parts, are produced by injection molding a polyamide matrix in the presence of a fluid in the supercritical state.
    Type: Application
    Filed: February 21, 2008
    Publication date: October 27, 2011
    Inventor: Gérard Bradley
  • Publication number: 20110244212
    Abstract: A foaming composition for filling contains a polymer, an organic peroxide, and azodicarbonamide, and a viscosity thereof measured at a temperature of 120° C. and under a pressure of 500 MPa with a flow tester is in a range of 1050 to 4950 Pa·s.
    Type: Application
    Filed: March 22, 2011
    Publication date: October 6, 2011
    Applicant: Nitto Denko Corporation
    Inventors: Takehiro Ui, Youhei Hayashi
  • Publication number: 20110178194
    Abstract: Provided is a modified blowing agent, wherein the surface of a blowing agent powder is coated with a metallic siloxylated compound. When the modified blowing agent is included in a polymer resin, dispersibility of the modified blowing agent is excellent in the polymer resin and fluidity of the polymer resin is improved in an extrusion molding machine and an injection molding machine, and thus productivity and processability can be improved. In addition, the foam that is formed using the polymer resin composition including the modified blowing agent has excellent tear strength, durability, and masking sound properties due to fine and uniform size of foam cells and increased number of foam cells per unit surface area.
    Type: Application
    Filed: March 29, 2011
    Publication date: July 21, 2011
    Inventors: Yong Yon Jo, Heung Oh Son
  • Publication number: 20110118370
    Abstract: This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 120° C. or more; and (b) a second propylene polymer component comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120° C.; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%, and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec?1 and temperature of 180° C.
    Type: Application
    Filed: January 7, 2011
    Publication date: May 19, 2011
    Inventors: Peijun JIANG, Abdelhadi Sahnoune, Armenag Dekmezian
  • Patent number: 7939573
    Abstract: Provided is a modified blowing agent, wherein the surface of a blowing agent powder is coated with a metallic siloxylated compound. When the modified blowing agent is included in a polymer resin, dispersibility of the modified blowing agent is excellent in the polymer resin and fluidity of the polymer resin is improved in an extrusion molding machine and an injection molding machine, and thus productivity and processability can be improved. In addition, the foam that is formed using the polymer resin composition including the modified blowing agent has excellent tear strength, durability, and masking sound properties due to fine and uniform size of foam cells and increased number of foam cells per unit surface area.
    Type: Grant
    Filed: October 16, 2007
    Date of Patent: May 10, 2011
    Assignee: J & J Chemical Co.
    Inventors: Yong Yon Jo, Heung Oh Son
  • Patent number: 7906561
    Abstract: The invention pertains to a process for producing a cross-linked polyolefin foam in a continuous process using standard processing equipment without using a moisture cross-linking step after processing. In this method, a vinyl functional silane compound is melt grafted onto a low density polyethylene in the presence of a free radical generator. The resulting silane grafted polyethylene resin is mixed and melted with a blowing agent in a continuous process in the presence of water to form a vinyl functional silane foam.
    Type: Grant
    Filed: December 3, 2007
    Date of Patent: March 15, 2011
    Assignee: Ingenia Polymers, Inc.
    Inventors: Jianzhong Hu, Salvatore D'Uva, Arthur Tinson
  • Publication number: 20110028579
    Abstract: The continuous or quasi-continuous process for lightening organic polyisocyanates with ozone-containing gas, the treatment of the organic polyisocyanate being effected with an ozone-containing gas which furthermore comprises at least one further inert and/or reactive gas can be carried out, according to the invention, in a stirred tank with connected storage tank, in a sieve tray column or in a packed column.
    Type: Application
    Filed: March 31, 2009
    Publication date: February 3, 2011
    Applicant: BASE SE
    Inventors: Michael Zoellinger, Johannes Adam, Markus Kraemer, Johannes Jacobs, Oliver Bey, Peter Zehner, Walter Van Gysel, Claudia Huang Ruobin, Matthias Kroner