With Ethylenic Reactant Patents (Class 522/107)
  • Patent number: 4710523
    Abstract: Acylphosphine oxide compounds of the general formula ##STR1## where R.sup.1 is alkyl, cyclohexyl, cyclopentyl, aryl which is unsubstituted or substituted by halogen, alkyl or alkoxy, or an S-containing or N-containing five-membered or six-membered heterocyclic radical,R.sup.2 has one of the meanings of R.sup.1 (but R.sup.1 and R.sup.2 may be identical or different) or is alkoxy, aryloxy or aralkoxy, or R.sup.1 and R.sup.2 together form a ring andR.sup.3 is an at least disubstituted phenyl, pyridyl, furyl or thienyl radical which carries, at least at the two carbon atoms adjacent to the linkage point of the carbonyl group, the substituents A and B, which may be identical or different, and each of which is alkyl, alkoxy or alkylthio of 1 to 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenyl or halogen, or R.sup.3 is .alpha.-naphthyl substituted by A and B at least in the 2- and 8-positions or is .beta.
    Type: Grant
    Filed: January 18, 1984
    Date of Patent: December 1, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Lechtken, Ingolf Buethe, Manfred Jacobi, Werner Trimborn
  • Patent number: 4663424
    Abstract: The present invention relates to aromatic polyester(carbonate)s with end groups of the formula (Ib) ##STR1## optionally mixed with known aromatic polyester(carbonate)s, their preparation by the phase boundary process or in homogeneous solution and their modification by irradiation.
    Type: Grant
    Filed: November 20, 1985
    Date of Patent: May 5, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Stix, Ludwig Bottenbruch
  • Patent number: 4649062
    Abstract: Vehicles for ultraviolet radiation-curable ceramic enamels comprise (a) acrylate- or methacrylate-modified oligomers; (b) acrylate or methacrylate monomers, the functionality of (a) and (b) being selected to provide desired film and firing characteristics; (c) a combination of photoinitiators to provide a balance of surface and through cure; and an inhibitor to enhance shelf life. Printing media comprising pigmented frits and the vehicles are described, as are methods for their application to heat-resistant substrates, especially glass.
    Type: Grant
    Filed: April 25, 1985
    Date of Patent: March 10, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Raymond S. Kosiorek, Leslie R. Gatechair
  • Patent number: 4639500
    Abstract: A resin composition curable by active energy rays characterized in containing a compound represented by a following structural formula (I).
    Type: Grant
    Filed: July 27, 1984
    Date of Patent: January 27, 1987
    Assignee: Sanyo-Kokusaku Pulp Company, Limited
    Inventor: Motonobu Kubo
  • Patent number: 4639472
    Abstract: An actinically curable composition containing (1) an oligomer having a molecular weight within the range of from about 200 to about 3000 and which is end capped with reactive functional groups to provide sites for free radical polymerization by actinic radiation and (2) as a reactive diluent, an N-vinyl-2-oxazolidinone in which the number 4 and 5 carbon atoms each have two constituents which are all independently selected from hydrogen and alkyl radicals having from 1 to 4 carbon atoms.
    Type: Grant
    Filed: July 9, 1985
    Date of Patent: January 27, 1987
    Assignee: The Dow Chemical Company
    Inventors: John G. Green, David G. Hunt
  • Patent number: 4632944
    Abstract: A polymerizable fluid for sealing and locking engineering parts contains components which allow 2 mechanisms of polymerization, the first of the mechanisms being initiatable by radiation such as ultraviolet light, and an opacifier such as a powder dispersed in the fluid, the opacifier rendering the fluid opaque to the radiation. A coating of the fluid is applied to one of the engineering parts and the coating is exposed to the radiation which initiates the first of said polymerization mechanisms, so that polymerization occurs only in a surface layer of the coating to form a dry tack free crust thereon. Due to the presence of the opacifier, the radiation is obstructed from passing beyond the surface layer and the subcutaneous fluid is unaffected by the radiation. The second polymerization mechanism, suitably a free radical addition polymerization of known type, is initiatable when two engineering parts are assembled together.
    Type: Grant
    Filed: October 15, 1982
    Date of Patent: December 30, 1986
    Assignee: Loctite Corporation
    Inventor: William H. Thompson
  • Patent number: 4615968
    Abstract: Novel compositions of matter which crosslink under the action of light and which contain(A) an aliphatically unsaturated polycondensation product which can contain structural elements of the formula I ##STR1## (B) a bisimide of the formula II ##STR2## and a sensitizer and can, if desired, also contain a further crosslinking agent, where R, R', R.sub.1, Y, Y' and R.sub.4 are as defined in claim 1, are suitable, inter alia, for preparing printing plates or for use as photoresist materials.
    Type: Grant
    Filed: October 26, 1983
    Date of Patent: October 7, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph Berger, Friedrich Lohse
  • Patent number: 4599274
    Abstract: A photo-curable adhesive composition for glass lamination, which comprises:(A) 100 parts by weight of a (meth)acrylate monomer represented by the formula: ##STR1## where R.sub.1 is a hydrogen atom or a CH.sub.3 -- group, each of R.sub.2, R.sub.3 and R.sub.4 is a straight-chained or branched alkylene group, each of n.sub.1 and n.sub.4 is an integer of at least 1 and each of n.sub.2 and n.sub.3 is an integer of 0 or at least 1, and having a molecular weight of from about 116 to about 5,000;(B) from 0.1 to 5 parts by weight of a photosensitizer;(C) from 0 to 5 parts by weight of a silane coupling agent; and(D) from 0 to 100 parts by weight of a plasticizer.
    Type: Grant
    Filed: March 1, 1984
    Date of Patent: July 8, 1986
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Toshihiro Ando, Yutaka Nakanishi, Kenkichi Ukita
  • Patent number: 4591522
    Abstract: Novel fire-retardant and hydrolysis resistant, liquid, photosensitive compositions are disclosed comprising(1) the reaction product of(a) an aliphatic unsaturation containing chlorendate, and(b) a non-ester containing polythiol, said (a) and (b) being reacted non-stoichiometrically;(2) a member of the group consisting of either (a) or (b) in an amount up to that sufficient to react with the excess of the other in (1) and a liquid acrylate monomer or oligomer, and(3) at least one photoinitiator.Acrylates or methacrylate monomers are optionally added to the composition.
    Type: Grant
    Filed: January 4, 1985
    Date of Patent: May 27, 1986
    Assignee: W. R. Grace & Co.
    Inventors: Uan G. Kang, Richard W. Bush, Arthur D. Ketley, Clifford A. Ferrin, Jr.