Processes Of Chemically Modifying A Blend Of Two Or More Solid Polymers In The Presence Of A Chemical Reactant; Or Compositions Therefore Patents (Class 522/109)
  • Publication number: 20030236318
    Abstract: A curable resin composition with excellent thermal adhesiveness is constituted of the following components (A) to (C):
    Type: Application
    Filed: April 14, 2003
    Publication date: December 25, 2003
    Applicant: Kuraray Co., Ltd.
    Inventors: Takahiro Kitano, Hirokazu Suzuki, Keiji Kubo, Masayasu Ogushi, Kazutoshi Terada, Tsuneo Kawabata, Masaki Kojima
  • Publication number: 20030199604
    Abstract: The invention is directed to a radiation curable adhesive composition comprising at least one vinyl modified block copolymer having a first polyvinyl aromatic block and a second polydiene block having vinyl functionality, and at least one tackifier. Optionally, the composition may comprises at least one second block copolymer that has not been vinyl modified, at least one platicizer, and at least one wax. The invention is also directed to a double-faced label formed from the composition and the method of producing said label.
    Type: Application
    Filed: April 29, 2003
    Publication date: October 23, 2003
    Inventors: Mark S. Kroll, Margarita Acevedo, Janelle C. Cameron, Thomas F. Kauffman, Jeffrey S. Lindquist, Eugene R. Simmons, David B. Malcolm, Kathryn A. Coleman
  • Patent number: 6596787
    Abstract: The present invention is directed to low intensity UV curable adhesives formulated using a blend of acrylate oligomers and monomers which are capable of bonding glass, provide improved low-yellowing properties and fast cure speed over current glass bonding adhesives, while maintaining good bond strength lo and durability comparable to, or better than, state-of-the-art glass bonding adhesives.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: July 22, 2003
    Assignee: Henkel Loctite Corporation
    Inventors: Susan Levandoski, JoAnn DeMarco
  • Publication number: 20030134925
    Abstract: A method of preparing fiber sheet molding compounds with a fabric of continuous fiber reinforcement that can be molded under low pressures and temperatures to provide thermoset articles, wherein liquid reactive components are slowly absorbed in solid acrylic resin. The acrylic resin functions as a thickener which delays the viscosity build allowing the fabric of continuous fiber reinforcement to be incorporated before molding.
    Type: Application
    Filed: September 26, 2002
    Publication date: July 17, 2003
    Applicant: REINFORCED POLYMERS, INC.
    Inventor: Robert Guzauskas
  • Patent number: 6579915
    Abstract: The invention is directed to a radiation curable adhesive composition comprising at least one vinyl modified block copolymer having a first polyvinyl aromatic block and a second polydiene block having vinyl functionality, and at least one tackifier. Optionally, the composition may comprises at least one second block copolymer that has not been vinyl modified, at least one platicizer, and at least one wax. The invention is also directed to a double-faced label formed from the composition and the method of producing said label.
    Type: Grant
    Filed: January 29, 2001
    Date of Patent: June 17, 2003
    Assignee: H.B. Fuller Licensing & Financing Inc.
    Inventors: Mark S. Kroll, Margarita Acevedo, Janelle C. Cameron, Thomas F. Kauffman, Jeffrey S. Lindquist, Eugene R. Simmons, David B. Malcolm, Kathryn A. Coleman
  • Patent number: 6579661
    Abstract: A photopolymerizable composition for the preparation of flexographic printing forms for corrugated board direct printing comprising a radial (polystyrene-polybutadiene)nX block copolymer, with X=Sn or Si and n=2 or 4, with an average molecular weight (Mw) of 80,000-300,000, a molecular weight distribution (Mw/Mn) of 1.00-1.40, a content of di- block copolymers of less than 15% by weight, which is extended with up to 50% by weight of a paraffinic oil.
    Type: Grant
    Filed: January 20, 1998
    Date of Patent: June 17, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Ursula Kraska, Reimund Simon
  • Patent number: 6573312
    Abstract: The invention relates to a photo-cured dental pit and fissure sealant composition for caries prevention: i) based on the multifunctional prepolymer mixture of 2,2-bis-(4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl)propane (“Bis-GMA”), which has conventionally been used as dental pit and fissure sealant for caries prevention, and a multifunctional prepolymer formed by substituting hydrogen atoms in hydroxyl group with methacrylate groups in the Bis-GMA molecules; and ii) comprising a diluent, an inorganic filler, a photoinitiation system, and other additives. The dental pit and fissure sealant composition of the present invention is based on a multifunctional prepolymer mixture and has better physical and mechanical properties and biocompatibility than a conventional composition based on Bis-GMA only.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: June 3, 2003
    Assignee: Dentkist Co. Ltd.
    Inventors: Dong-Keun Han, Kwang-Duk Ahn, Jin-Hee Jeong
  • Patent number: 6562878
    Abstract: Heat-expandable molded synthetic resin seal and baffle components adapted for use in automobile body cavities or the like are provided which are designed to preferentially expand upon heating in desired directions and to a desired degree, in order to properly seal irregular or special cavity shapes. The molded components of the invention have selected body surface portions thereof UV crosslinked to a depth of up to about 0.5 mm, while other portions of the molded body are not crosslinked; upon heating, the crosslinked portions expand at a slower rate and to a lesser extent than non-crosslinked body portions. The preferred synthetic resin includes a grafted anhydride polymer, a terminal epoxide polymer additive, a blowing agent, a UV photoinitiator and a UV crosslinkable resin system.
    Type: Grant
    Filed: November 14, 2001
    Date of Patent: May 13, 2003
    Assignee: Sika Corporation
    Inventors: Norman E. Blank, Cheong Kow
  • Patent number: 6548568
    Abstract: A radiation-curable release composition comprises: (a) from about 50 to about 100 parts by weight of an organopolysiloxane of the formula (I)  wherein R is CH2═CH—C(O)—O—CH2—CH(OH)—CH2—O—CH2—CH2—CH2—, n is 5 to 15, and p is 50 to 150; (b) from 0 to about 50 parts by weight of one or more organopolysiloxanes comprising organopolysiloxanes selected from the group consisting of those of formulae (II) and (III)  wherein R is CH2═CH—C(O)—O—CH2—CH(OH)—CH2—O—CH2—CH2—CH2—, m is 1 to 10, and q is 151 to 300; and  wherein R is CH2═CH—C(O)—O—CH2—CH(OH)—CH2—O—CH2—CH2—CH2—, and r is 20 to 500; (c) from 0 to about 10 parts by weight of an organopolysiloxane of formula (IV)  wherein R is CH2═CH—C(O)—O—CH2—CH(OH
    Type: Grant
    Filed: April 11, 2000
    Date of Patent: April 15, 2003
    Assignee: Rhodia Inc.
    Inventors: Olivier Pinto, Stuart Kerr, III, Basil A. Behnam
  • Publication number: 20030060530
    Abstract: The present invention relates to shape deformable materials, which are capable of (1) being deformed, (2) storing an amount of shape deformation, and (3) recovering at least a portion of the shape deformation when exposed to a humid environment. The shape deformable materials can advantageously be in the form of films, fibers, filaments, strands, nonwovens, and pre-molded elements. The shape deformable materials of the present invention may be used to form products, which are both disposable and reusable. More specifically, the shape deformable materials of the present invention may be used to produce products such as disposable diapers, training pants, incontinence products, and feminine care products.
    Type: Application
    Filed: July 24, 2001
    Publication date: March 27, 2003
    Inventors: Vasily A. Topolkaraev, Dave A. Soerens
  • Patent number: 6539152
    Abstract: The present invention relates to a composition for preparing optical fiber coatings, the composition including a polymerizable base composition, containing at least one monomer and optionally at least one oligomer, wherein the polymerizable base composition is substantially free of unsaturated epoxidized diene polymers, and a tackifier present in an amount effective to modify a time-sensitive rheological property of a polymerization product of the composition. Another aspect of the present invention relates to a method of modifying a time-sensitive rheological property of an optical fiber coating by introducing into a polymerizable composition a tackifier in an amount effective to modify a time-sensitive rheological property of the polymerization product of the polymerizable composition. Also disclosed are an optical fiber, a fiber optic ribbon, and a fiber bundle that contain coating(s) prepared from a composition of the present invention.
    Type: Grant
    Filed: December 21, 2000
    Date of Patent: March 25, 2003
    Assignee: Corning Incorporated
    Inventors: Edward J. Fewkes, Gregory F. Jacobs, Kenneth R. Jones, Huan-Hung Sheng, Frederic C. Wagner, Michael J. Winningham
  • Patent number: 6528554
    Abstract: This invention relates to a process for making polymer blends and copolymers by ultrasonic treatment during or after mixing the polymers. In the process of the present invention, an unexpected phenomenon occurs. The process brings about enhancement of the mechanical properties when compared with identical blends not subjected to ultrasonic treatment. The ultrasonic treatment of the blends is believed to enhance intermolecular interaction and improve adhesion between dissimilar polymers and make chemical bonds between polymers that otherwise are incompatible or immiscible with each other.
    Type: Grant
    Filed: February 15, 2001
    Date of Patent: March 4, 2003
    Assignee: The University of Akron
    Inventors: Avraam Isayev, Chang Kook Hong
  • Publication number: 20030040550
    Abstract: An objective is to provide a pressure-sensitive adhesive composition which shows pressure-sensitive adhesive properties at ordinary temperature, has the ability to cure upon irradiation and after photocure exhibits improved bond strength relative to high-polarity adherends, such as PET, PVC and metals, and improved moist heat-resisting bond strength, a pressure-sensitive adhesive and a pressure-sensitive adhesive sheet obtained from the aforementioned pressure-sensitive adhesive composition.
    Type: Application
    Filed: September 13, 2001
    Publication date: February 27, 2003
    Inventors: Hideaki Ishizawa, Munehiro Hatai, Masakazu Nakata, Motohiro Yagi
  • Patent number: 6509389
    Abstract: The present invention discloses an ultraviolet light curable mar resistant composition and method for making such a composition that may be used to produce an mar resistant layer. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: January 21, 2003
    Assignee: UV Specialties, Inc.
    Inventor: Roy C. Krohn
  • Patent number: 6500877
    Abstract: The present invention discloses an ultraviolet light curable paint composition and method for applying and making such a composition to a substrate. Suitable substrates include glass, metals, and various plastics such as polycarbonates. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the coating or are released to ambient after curing.
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: December 31, 2002
    Assignee: Krohn Industries, Inc.
    Inventor: Roy C. Krohn
  • Publication number: 20020183416
    Abstract: A melt extrudable low temperature curable powder coating composition for application onto heat sensitive substrates. The final cured coating produces a low gloss finish on the target substrate. The composition consists of an unsaturated polyester resin combined with a glycidyl functional acrylic resin, a crystalline or semi-crystalline polycarboxylic acid or anhydride and a free radical initiator. Optionally, if a harder, more wear-resistant surface is desired, the cure may be catalyzed by either a photoinitiator or a redox compound.
    Type: Application
    Filed: January 9, 2002
    Publication date: December 5, 2002
    Inventors: Andrew Thomas Daly, Richard Paul Haley, James R. Knaub, Carryll A. Seelig, Navin B. Shah, Gordon L. Tullos
  • Patent number: 6475701
    Abstract: There is provided an active energy beam curable composition, which is useful for forming a solder resist film for a printed wiring board, which can be developed through an ultraviolet exposure and a dilute alkali aqueous solution, and is excel lent in heat resistance, adhesivity and chemical resistance. There is also proposed a printed wiring board provided with a cured film of such an active energy beam curable composition. This composition is featured in that it comprises not only an active energy beam curable vinyl copolymer modified resin wherein an epoxy compound having an ethylenic unsaturated group is added to a copolymer comprising styrene, (metha)acrylic acid, and, as an optional component, (metha)acrylate; but also an active energy beam curable bisphenol type epoxyacrylate resin.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: November 5, 2002
    Assignee: Tamura Kaken Corporation
    Inventors: Takao Ohno, Ken Ito, Ichiro Miura
  • Patent number: 6476142
    Abstract: Composition which can be crosslinked under the effect of an ionizing radiation comprising a thermoplastic copolymer of vinylidene fluoride and of chlorotrifluoroethylene and an effective amount of a crosslinking promoter, such as a triallyl cyanurate or triallyl isocyanurate. Process for the crosslinking by irradiation of the crosslinkable composition under air by means of an ionizing radiation, such as &bgr;-radiation, at a dose of 10 to 100 kGray. Crosslinkable and crosslinked shaped articles, such as sheaths for electrical cables and pipes for oil products.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: November 5, 2002
    Assignee: Solvay (Societe Anonyme)
    Inventors: Yves-Julien Lambert, Vincent Thulliez, Guy Laurent
  • Patent number: 6455226
    Abstract: The present invention provides photoresist polymers and photoresist compositions comprising the same. In one aspect, the photoresist polymer is of the Formula: where Y, R1, a, b and c are as described herein. Photoresist compositions of the present invention have good transmittance at wavelengths of 193 nm and 157 nm, etching resistance, heat resistance, and adhesiveness. In addition, photoresist compositions of the present invention can be developed easily in aqueous TMAH solution, and are therefore suitable for lithography processes using VUV (157 nm) and EUV (13 nm) wavelength-light sources for fabricating a minute circuit of a high integration semiconductor device.
    Type: Grant
    Filed: November 1, 2000
    Date of Patent: September 24, 2002
    Assignee: Hyundai Electronics Industries Co., Ltd.
    Inventors: Geun Su Lee, Jae Chang Jung, Hyeong Soo Kim, Ki Ho Baik
  • Patent number: 6436540
    Abstract: A co-mingled polyurethane-polyvinyl ester composition can be used as a coating, which has good scratch, mar and solvent resistance. The coating is derived from a waterborne polyurethane solution containing free radically polymerizable monomers such as acrylate, ultraviolet light initiators, and optionally urethane crosslinking agents. A process for forming the co-mingled polyurethane-polyvinyl ester composition comprises drying the waterborne polyurethane containing the polymerizable monomers therein and radiation polymerizing, as by ultraviolet light, the free radically polymerizable monomers on a substrate such as a plastic sheet to form a laminate. Subsequently, the laminate can be utilized to form a coating on a product as by thermoforming, where if urethane crosslinking agents are utilized, the polyurethane will be crosslinked.
    Type: Grant
    Filed: February 18, 2000
    Date of Patent: August 20, 2002
    Assignee: OMNOVA Solutions Inc.
    Inventors: Guillermina C. Garcia, Raymond J. Weinert, Martin J. Fay
  • Patent number: 6433037
    Abstract: A method of preparing fiber reinforced acrylic thickened compositions which can be molded under low pressures and temperatures to provide thermoset articles, wherein liquid reactive components are slowly absorbed in high molecular weight solid acrylic resin in the form of large particles. The acrylic resin functions as a thickener which delays the viscosity build allowing fiber reinforcement to be incorporated before molding. The molding composition is well suited for use in dentistry and other fields where small amounts or molding composition are used occasionally.
    Type: Grant
    Filed: May 12, 2000
    Date of Patent: August 13, 2002
    Assignee: Reinforced Polymers, Inc.
    Inventor: Robert Guzauskas
  • Patent number: 6420451
    Abstract: Curable compositions that are particularly suitable for coating plastic ophthalmic lenses includes (a) 20% to 80% of a first acrylated aliphatic urethane; (b) 5% to 50% of a monofunctional acrylate; (c) (i) 2% to 30% of a second acrylated aliphatic urethane or (ii) 2% or 25% of a multifunctional acrylate or (iii) a combination of (i) and (ii); (d) 1% to 30% of a colloidal metal oxide; (e) 1% to 20% of a photoinitiator; and (f) a solvent, with the percentages based on weight. The cured composition provides superior abrasion and impact resistance as well as protection against environmental and chemical agents. In addition, the UV curable compositions are capable of forming films on various substrates; the film has excellent compatibility and adhesion to AR coatings that are applied thereon. No primer coating is required.
    Type: Grant
    Filed: December 11, 2000
    Date of Patent: July 16, 2002
    Assignee: Sola International, Inc.
    Inventors: Shi Lin, Sunder Ram
  • Patent number: 6420449
    Abstract: A resin composition comprises a thermoplastic resin, a non-terpene-series higher fatty acid or a derivative thereof and a black pigment. As the higher fatty acid or derivative thereof, use can be made of, for example, a saturated higher fatty acid having about 12 to 30 carbon atoms or a metal salt thereof. As the thermoplastic resin, use can be made of, for example, an acrylic resin A and a styrenic resin B. As the black dye or pigment, use can be made of, for example, carbon black. The resin composition may contain a dye or pigment such as titanium oxide. A clearly defined white marking is developed on the above resin composition by laser irradiation.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: July 16, 2002
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hiroshi Sagane, Shinichiro Imanishi, Katsuhiko Sumida
  • Patent number: 6413629
    Abstract: An easy adhesion film for a transparent conductive thin film comprises a transparent polymer film and an easy adhesion layer formed on the transparent polymer film, wherein the easy adhesion layer comprises at least an ionizing radiation curable resin binder, a (meth)acrylate copolymer binder and polymethyl methacrylate resin particles. The easy adhesion film has high durability, transparency and anti-Newton ring property when provided with a transparent conductive thin film.
    Type: Grant
    Filed: February 29, 2000
    Date of Patent: July 2, 2002
    Assignee: Kimoto Co., Ltd.
    Inventor: Yoshihisa Kimura
  • Patent number: 6413696
    Abstract: The present invention relates to novel resin compositions containing at least one solid or liquid actinic radiation-curable and cationically polymerizable organic substance, an actinic radiation-sensitive initiator for cationic polymerization, an actinic radiation-curable and radical-polymerizable organic substance and an actinic radiation-sensitive initiator for radical polymerization. The actinic radiation-curable and cationically polymerizable organic substance is at least one glycidylether of a polyhydric aliphatic, alicyclic or aromatic alcohol having at least three epoxy groups with epoxy equivalent weight between 90 and 800 grams per equivalent, at least one solid or liquid alicyclic epoxide with an epoxy equivalent weight between 90 and 330 grams per equivalent having at least two epoxy groups and monomer purity greater than about 90% by weight, or at least a solid or liquid epoxycresol novolac or epoxyphenol novolac having epoxy equivalent weight between 130 and 350, or mixtures thereof.
    Type: Grant
    Filed: June 22, 2000
    Date of Patent: July 2, 2002
    Assignee: Vantico Inc.
    Inventors: Thomas H. Pang, Anastasios P. Melisaris, Wang Renyi, John W. Fong
  • Patent number: 6410206
    Abstract: An epoxy-containing copolymer resin having 0 to 55% by mole of formula (1), 5 to 95% by mole of formula (2), and 5 to 95% by mole of formula (3), the formula (1) units having been partially reacted, through carboxyl groups, with a (meth)acryloylalkyl isocyanate compound, the formula (2) units having been partially reacted, through hydroxyl groups, with a (meth)acryloylalkyl isocyanate compound, the copolymer resin containing 5 to 95% by mole of (meth)acryloyl groups, an acid value of 0 to 400 mg KOH/g, and a weight average molecular weight of 5,000 to 1,000,000: wherein R is hydrogen or a C1 to C5 alkyl group; R1 represents a C2 to C4 alkylene group; R2 represents a C1 to C4 alkylene group having 1 to 4 carbon atoms; Z is 1,2-epoxy,1,3-epoxy, or 1,4-epoxy; and a, b, and c are integers respectively corresponding to the molar percentages.
    Type: Grant
    Filed: February 24, 2000
    Date of Patent: June 25, 2002
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Kenji Ueda, Shunsuke Sega
  • Patent number: 6384102
    Abstract: Radiation-curable powder compositions, usable as paint or varnish, which comprise a mixture of at least one semi-crystalline polyester containing end methacryloyl groups and of at least one acrylic copolymer containing ethylenically unsaturated groups, these polyesters comprising the reaction products of a glycidyl methacrylate and of a semi-crystalline polyester containing end carboxyl groups.
    Type: Grant
    Filed: April 21, 2000
    Date of Patent: May 7, 2002
    Assignee: UCB S.A.
    Inventors: Luc Moens, Jean-Marie Loutz, Daniel Maetens, Patrick Loosen, Marc Van Kerckhove
  • Patent number: 6380279
    Abstract: Radiation-curable powder compositions, usable as paint or varnish, which comprise a mixture of at least one semi-crystalline polyester containing end methacryloyl groups and of at least one amorphous polyester containing end methacryloyl groups, comprising the reaction products of a glycidyl methacrylate and of a semi-crystalline or amorphous polyester containing end carboxyl groups.
    Type: Grant
    Filed: April 17, 2000
    Date of Patent: April 30, 2002
    Assignee: UCB S.A.
    Inventors: Luc Moens, Jean-Marie Loutz, Daniel Maetens, Patrick Loosen, Marc Van Kerckhove
  • Patent number: 6359027
    Abstract: A coated abrasive article comprises a backing, a first binder on the backing, and a plurality of abrasive particles in the first binder. The first binder precursor is an energy-curable preferably, melt-processable resin containing an epoxy resin, an ethylene-vinyl acetate copolymer, and a curing agent for crosslinking the epoxy resin that is cured to provide a crosslinked make coating. The above binder precursors of the invention are preferably free of homopolymers and copolymers of olefinic monomers. In another aspect, the invention also describes an energy curable first binder precursor containing an epoxy resin, an ethylene-vinyl acetate copolymer, a polyfunctional acrylate component and a curing agent for crosslinking the epoxy resin that is cured to provide a crosslinked make coating. The invention also relates to a method of producing such coated abrasive articles and a surface-treated backing material.
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: March 19, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Gregg D. Dahlke, Robert J. DeVoe, Clayton A. George, Naimul Karim
  • Patent number: 6350792
    Abstract: A radiation-curable composition in a liquid or solid form comprises at least one solid, non-crystalline radiation-transmissible material, dispersed in at least one cationic-curable or free-radical curable composition or mixture thereof. The solid, non-crystalline radiation-transmissible materials comprise glasses and other suitable materials that transmit (i.e., are transparent to) at least about 40% of radiation having a wavelength from about 180 to about 600 nanometers. The solid forms of the radiation-curable compositions of the invention are useful as powder coatings for coating decorative and functional objects and that would be cured by a thermal heating flow process followed by radiation exposure. The cured compositions of the invention are useful as coatings and inks for metal, paper, plastics, glass, ceramics, and wood, as adhesives, as sealants, and as composite materials and other articles and in biomedical and dental applications.
    Type: Grant
    Filed: July 13, 2000
    Date of Patent: February 26, 2002
    Assignee: Suncolor Corporation
    Inventors: David A. Smetana, Joseph V. Koleske
  • Publication number: 20020016381
    Abstract: The invention is directed to a radiation curable adhesive composition comprising at least one vinyl modified block copolymer having a first polyvinyl aromatic block and a second polydiene block having vinyl functionality, and at least one tackifier. Optionally, the composition may comprises at least one second block copolymer that has not been vinyl modified, at least one platicizer, and at least one wax. The invention is also directed to a double-faced label formed from the composition and the method of producing said label.
    Type: Application
    Filed: January 29, 2001
    Publication date: February 7, 2002
    Inventors: Mark S. Kroll, Margarita Acevedo, Janelle C. Cameron, Thomas F. Kauffman, Jeffrey S. Lindquist, Eugene R. Simmons, David B. Malcolm, Kathryn A. Coleman
  • Publication number: 20020006979
    Abstract: A method of reducing the flow viscosity of a polyacrylate composition, which comprises adding
    Type: Application
    Filed: January 25, 2001
    Publication date: January 17, 2002
    Inventors: Marc Husemann, Stephan Zollner
  • Patent number: 6339113
    Abstract: The invention relates to a photopolymerizable composite resin composition for dental restoration i) based on the multifunctional prepolymer mixture of 2,2-bis-(4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl)propane (“Bis-GMA”) and multifunctional prepolymer formed by substituting hydrogen atoms in hydroxyl group with methacrylate groups in this Bis-GMA molecules, and ii) comprising a diluent, an inorganic filler, a photoinitiation system, and other additives. The photopolymerizable composite resin composition for dental restoration based on multifunctional prepolymer mixture has better physical and mechanical properties and biocompatibility than the conventional composition based on only Bis-GMA itself.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: January 15, 2002
    Assignee: Dentkist Co., Ltd.
    Inventors: Dong-Keun Han, Kwang-Duk Ahn, Jong-Man Kim, Jin-Hee Jeong
  • Patent number: 6319964
    Abstract: Heat-expandable molded synthetic resin seal and baffle components adapted for use in automobile body cavities or the like are provided which are designed to preferentially expand upon heating in desired directions and to a desired degree, in order to properly seal irregular or special cavity shapes. The molded components of the invention have selected body surface portions thereof UV crosslinked to a depth of up to about 0.5 mm, while other portions of the molded body are not crosslinked; upon heating, the crosslinked portions expand at a slower rate and to a lesser extent than non-crosslinked body portions. The preferred synthetic resin includes a grafted anhydride polymer, a terminal epoxide polymer additive, a blowing agent, a UV photoinitiator and a UV crosslinkable resin system.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: November 20, 2001
    Assignee: Sika Corporation
    Inventors: Norman E. Blank, Cheong Kow
  • Patent number: 6309502
    Abstract: To produce a conductive epoxy resin composition with improvement in the characteristics of rapid-curability, heat resistance and moisture resistance, adhesion reliability, storage properties and low-temperature curability that can be used effectively for production of conductive adhesive films. The conductive epoxy resin composition comprises an alicyclic epoxy resin, optional diols, a styrenic thermoplastic elastomer with an epoxy group in the molecule, an ultraviolet activated cationic polymerization catalyst, an optional tackifier having an aromatic ring in the molecule, and conductive particles.
    Type: Grant
    Filed: December 29, 1999
    Date of Patent: October 30, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Yuji Hiroshige, Koji Ito
  • Patent number: 6306970
    Abstract: A polymer blend having a high melt strength and a low Young's modulus after irradiation of the polymers contains (1) a propylene homopolymer or copolymer having an isotactic index of greater than 90 and (2) a propylene homopolymer or copolymer having a crystallinity of <24% made using a metallocene catalyst. The blend can be used for extrusion coating (including fabric coating), foam extrusion, blow molding, and thermoforming applications.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: October 23, 2001
    Assignee: Montell Technology Company BV
    Inventors: Vu A. Dang, Dinshong Dong
  • Patent number: 6265460
    Abstract: A hot-melt adhesive composition, which has a high curing rate, requires no water for a curing reaction or no solvent for the formation of a film, has good storage stability, and is suitable for adhering electronic parts or producing integrated circuit (IC) packages is provided. Specifically, a thermosetting hot-melt adhesive composition comprising a polyethylene copolymer having epoxy groups in a molecule as an epoxy component, which further comprises a cationic polymerization catalyst, is provided herein. Also disclosed are heat-bonding film adhesives and adhering methods using the hot-melt adhesive composition.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: July 24, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Kohichiro Kawate, Shigeyoshi Ishii, Mario A. Perez
  • Patent number: 6262137
    Abstract: Polymer articles including ethylene-vinyl acetate and maleic anhydride are described. The ethylene-vinyl acetate can be a high vinyl acetate content ethylene-vinyl acetate. The articles include foamed articles and non-foamed articles. The foamed articles have improved characteristics and properties, such as surface bonding properties.
    Type: Grant
    Filed: January 6, 1998
    Date of Patent: July 17, 2001
    Assignee: Sentinel Products Corp.
    Inventors: Matthew L. Kozma, John D. Bambara, Robert F. Hurley, Scott C. Smith
  • Publication number: 20010006759
    Abstract: Radiation sensitive compositions, processes for using the compositions, and articles of manufacture comprising the compositions. The compositions of the invention are use to form flexible coatings having a dielectric constant of 3 or less. The compositions comprise a resin binder and a polybutadiene that comprises one or more internal epoxide groups. In preferred aspect of the invention, the compositions of the invention further comprise a crosslinking agent capable of solvating the remaining constituents of the composition. The coatings are used for the manufacture of electronic and other devices.
    Type: Application
    Filed: September 8, 1998
    Publication date: July 5, 2001
    Applicant: Charles R. Shipley Jr.
    Inventors: CHARLES R. SHIPLEY, JAMES G. SHELNUT, WADE SONNENBERG
  • Patent number: 6254954
    Abstract: The invention relates to a pressure-sensitive adhesive tape with improved room temperature handleability comprising an adhesive layer with at least one exposed surface and optionally a backing, wherein the pressure-sensitive adhesive layer comprises an epoxy/polyester based pressure sensitive adhesive which is crosslinkable upon exposure to actinic or e-beam irradiation and optionally heat, and comprises (i) 30-80% by weight of a polyester component comprising one or more amorphous polyesters compounds, (ii) 20-70% by weight of an epoxy component comprising one or more epoxy resins and/or monomers, (iii) 0-50% by weight of a hydroxyl-functional component containing one or more hydroxyl-containing compounds having a hydroxyl functionality of at least 1, and (iv) an effective amount of a photoinitiator component for crosslinking the pressure-sensitive adhesive, whereby the weight percentages refer to the total mass of components (i)-(iv) and add up to 100 wt.
    Type: Grant
    Filed: August 26, 1999
    Date of Patent: July 3, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Greggory S. Bennett, Clayton A. George, Guido Hitschmann, Alain H. Lamon
  • Publication number: 20010005569
    Abstract: Printing plate stock comprising a base, a photosensitive resin layer overlying the base, and a covering layer overlying the photosensitive resin layer, characterized in that said photosensitive resin layer comprises (i) a matrix phase comprising a hydrophobic polymer, and (ii) a dispersed phase, surrounded by said matrix phase, comprised of particles, wherein each of said particles comprises a hydrophobic polymer surrounded by a hydrophilic polymer, wherein said hydrophilic polymer is 5-30% wt of said photosensitive resin layer.
    Type: Application
    Filed: December 7, 2000
    Publication date: June 28, 2001
    Inventors: Masaru Nanpei, Akira Tomita, Keizo Kawahara, Toshihiko Kajima
  • Publication number: 20010003759
    Abstract: A photo curable resin composition, which comprises (A) an acid-modified, vinyl group-containing epoxy resin, (B) an elastormer, (C) a photopolymerization initiator, (D) a diluent and (E) a curing agent, can gives a high performance cured film having distinguished heat resistance, humidity-heat resistance, adhesibility, mechanical characteristics and electrical characteristics, and a photosensitive element, which comprises a support and a layer of the photo curable resin composition laid on the support, has distinguished heat resistance, humidity-heat resistance, adhesibility, mechanical characteristics and electrical characteristics.
    Type: Application
    Filed: November 24, 1998
    Publication date: June 14, 2001
    Inventors: KUNIAKI SATO, HIROAKI HIRAKURA, TOSHIHIKO ITO, TAKAO HIRAYAMA, TOSHIZUMI YOSHINO
  • Patent number: 6242503
    Abstract: Polymer articles including ethylene-vinyl acetate and maleic anhydride are described. The ethylene-vinyl acetate can be a high vinyl acetate content ethylene-vinyl acetate. The articles include foamed articles and non-foamed articles. The foamed articles have improved characteristics and properties, such as surface bonding properties.
    Type: Grant
    Filed: April 28, 1999
    Date of Patent: June 5, 2001
    Assignee: Sentinel Products Corp.
    Inventors: Matthew L. Kozma, John D. Bambara, Robert F. Hurley, Scott C. Smith
  • Patent number: 6232363
    Abstract: A method of forming a diffusion barrier on an article of a polymer blend of (i) a high surface energy polymer and (ii) a low surface energy polymer. Most commonly the low surface energy polymer is an organosilicon polymer, as a polysilane or a polysiloxane. The surface of the article is exposed to ozone and ultraviolet radiation to form a diffusion barrier.
    Type: Grant
    Filed: April 25, 2000
    Date of Patent: May 15, 2001
    Assignee: International Business Machines Corporation
    Inventors: Frank Daniel Egitto, Luis Jesus Matienzo, Bruce Otho Morrison, Jr.
  • Patent number: 6210862
    Abstract: According to the present invention, an improved photoimagable cationically polymerizable epoxy based solder mask is provided that contains a non-brominated epoxy resin system and from about 0.1 to about 15 parts, by weight per 100 parts of resin system, of a cationic photoinitiator. The non-brominated epoxy-resin system has solids that are comprised of from about 10% to about 80% by weight, of a polyol resin having epoxy functionality; from about 0% to about 90% by weight of a polyepoxy resin; and from about 25% to about 85% by weight of an difunctional epoxy resin. Since the photosensitive cationically polymerizable epoxy based solder mask does not contain bromine, it is particularly advantageous halogens in waste processing chemicals or in incinerated scrap circuit boards are regulated by environmental concerns. The photosensitive cationically polymerizable non-brominated epoxy based solder mask has a glass transition temperature greater than about 100° C., preferably greater than about 110° C.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: April 3, 2001
    Assignee: International Business Machines Corporation
    Inventors: Richard Allen Day, David John Russell, Donald Herman Glatzel
  • Patent number: 6210517
    Abstract: A radiation curable precursor coating composition for the preparation of a non-blocking, heat activatable adhesive includes a curable acrylic material, a curable elastomeric material, and a hydrocarbon tackifier material having a softening temperature ranging from approximately 50° C. to approximately 200° C., wherein when the acrylic material and the elastomeric material are cured, the coating composition is non-blocking at room temperature, but when the coating composition is heated to a temperature above both the softening temperature of the hydrocarbon tackifier and the Tg of the coating composition, the coating composition becomes adhesive.
    Type: Grant
    Filed: April 13, 1999
    Date of Patent: April 3, 2001
    Assignee: Diversified Chemical Technologies, Inc.
    Inventors: Rajan Eadara, Mooil Chung, David Wen-Lung Chang, Weichen Chi
  • Patent number: 6211262
    Abstract: A corrosion resistant coating for metal surfaces curable with actinic radiation. The blend uses acrylate resin, photoinitiator and a corrosion preventing agent such as a metal surface passivator, overbased calcium sulfonate/calcium carbonate, a barrier pigment, or a combination of two or more of these agents.
    Type: Grant
    Filed: April 20, 1999
    Date of Patent: April 3, 2001
    Assignee: Spectra Group Limited, Inc.
    Inventors: Alexandre Mejiritski, Thomas Marino, Violeta Lungu, Dustin Martin, Douglas Neckers
  • Patent number: 6207758
    Abstract: Compositions containing fluorinated thermoplastic elastomers with different moelcular weight and with different plastomeric phase/elastomeric phase ratio, essentially formed by: (a) 30-80% by weight, preferably 50-80%, of a fluorinated thermoplastic elastomer, having a block structure of A-B-A type, wherein A is a plastomeric segment and B is an elastomeric segment; (b) 10-50% by weight, preferably 20-40% of a fluorinated thermoplastic elastomer having a block structure of A-B-A type; (c) 0-30% by weight, preferably 0-15%, of a fluorinated plastomer preferably of the same kind as that contained in the component (a) and/or (b).
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: March 27, 2001
    Assignee: Ausimont S.p.A.
    Inventors: Giulio Brinati, Vincenzo Arcella
  • Patent number: 6204305
    Abstract: A method of forming a diffusion barrier on an article of a polymer blend of (i) a high surface energy polymer and (ii) a low surface energy polymer. Most commonly the low surface energy polymer is an organosilicon polymer, as a polysilane or a polysiloxane. The surface of the article is exposed to ozone and ultraviolet radiation to form a diffusion barrier.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: March 20, 2001
    Assignee: International Business Machines Corporation
    Inventors: Frank Daniel Egitto, Luis Jesus Matienzo, Bruce Otho Morrison, Jr.
  • Patent number: 6194482
    Abstract: UV-hardenable and thermally hardenable epoxy resins for the underfilling process in electrical and electronic components are provided. A new casting resin component has an increased storage stability at room temperature of at least 6 months and improved characteristics for the underfilling process including faster hardening and lower viscosity. Filler material with a maximum grain size of 20 &mgr;m and a siloxane component are provided in addition to the casting resin formulation.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: February 27, 2001
    Assignee: Siemens Aktiengesellschaft
    Inventors: Barbara Lehner, Recai Sezi