Abstract: An adhesive composition is described comprising a tetrahydrofurfuryl (meth)acrylate copolymer; an epoxy resin; a polyether polyol; and a hydroxy-functional film-forming polymer. The adhesive may be used in structural and semi-structural bonding applications.

Abstract: An anaerobically curable composition comprising an anaerobically curable component that is a combination of a solid resin component and a solid anaerobically curable monomer. A curing component for curing the anaerobically curable component is included. The composition is solid and has a melting point in the range from 30° C. to 100° C. The composition is dry to touch and can be used to form articles of manufacture such as a tape, an elongate filament, a gasket, a patch.

Abstract: An ultraviolet curable primer for a radio-wave transmission cover of a vehicle may include about 20 wt % to about 30 wt % of urethane acrylate oligomer, about 35 wt % to about 60 wt % of monomer, about 1 wt % to about 5 wt % of photopolymerization initiator, about 0.1 wt % to about 1.0 wt % of wetting additive, and about 10 wt % to about 30 wt % of solvent, wherein the urethane acrylate oligomer comprises about 7.5 wt % to about 12.5 wt % of two-function urethane acrylate oligomer based on the total weight of the ultraviolet curable primer, and about 12.5 wt % to about 17.5 wt % of six-function urethane acrylate oligomer based on the total weight of the ultraviolet curable primer, and wherein the ultraviolet curable primer is applied to a radio-wave transmission cover comprising a multilayered oxide optical film.

Abstract: A method for determining an ultraviolet (UV) cure level of a material is disclosed. For example, the method includes receiving an object with the material that is cured via a UV light source, controlling a heat source to heat the material, measuring a parameter of the material in response to the heat, determining the UV cure level of the material based on the parameter that is measured and a predefined response of the material at a temperature associated with the heat, and generating a signal to display the UV cure level in response to the determining.

Abstract: In a first aspect, the present invention concerns a kit for a polymerizable composition comprising a portion A constituted by a composition comprising at least one monomer (a1) that is reactive towards a cationic species (b) or a Lewis or Brönsted acid species, and at least one co-initiator, and a portion B comprising at least one cationic salt (e) selected from the salts with formula S1, S3, and S4 shown and defined in claim 1. In a second aspect, the present invention concerns a method of producing a coating or a composite material starting from polymerizable composition comprising at least one salt (e) selected from the salts with formula S1, S2, S3, and S4 shown and defined in claim 10, said composition being polymerized without adding external heat thereto.

Abstract: Articles are described such as optical films and optical film stacks 2000. The articles include a substrate 2070 and a primer layer 2075 disposed on the substrate wherein the primer layer comprises a polyacrylate and a nitrogen-containing polymer. The article further includes an adhesive layer 2060 disposed onto the primer layer wherein the adhesive layer comprises a polyacrylate component. In some embodiments, the adhesive is further bonded to a second substrate 2010 or a release liner.

Abstract: The present invention relates to a dental curable composition that can be suitably used as a dental material that can substitute part or all of a natural tooth, in particular, a resin material for dental cutting and machining in the field of dental care. An object of the present invention is to provide a dental curable composition in which, when a block shape usable as a resin material for dental cutting and machining is produced while mechanical properties such as hardness, bending strength and compressive strength as well as aesthetic property required for a crown prosthetic appliance are maintained, the dental curable composition can be molded and processed with pressure and heating while strain generated in the block is reduced and no cracks and chipping occur. There is provided a dental curable composition including (a) a polymerizable monomer and (b) a filler in a weight ratio of 10:90 to 70:30, and including 0.01 to 10 parts by weight of (c) a polymerization initiator and 0.

Abstract: Disclosed is a photo-curable resin composition for an adhesive film comprising a (meth)acrylic acid ester-based photo-curable resin which is end-capped and cross-linked with a multifunctional molecular weight regulator.

Abstract: Photopolymer resin formulation for 3D printing enhancing the performance of 3D printed objects. In one example, additives comprising two photoinitiators with different absorption spectrums are used to achieve printing and post-curing processes. A thermal initiator can also be used to complete the post-curing process by baking at appropriate temperature. Additive combinations balanced to absorb some light in the near UV range of about 400 nm to about 420 nm absorption wavelength band or spectrum while fluorescing light at frequencies higher than their absorption wavelength allowing the creation of clear transparent materials using only near UV light sources (i.e., about 400 nm to about 420 nm) instead of deep UV (<400 nm) light sources.

Abstract: A reactive mixture for coating mouldings by means of reaction injection moulding, containing at least 40% by weight of (meth)acrylates having at least two double bonds. The reactive mixture contains at least one photoinitiator and at least one thermal initiator. The present invention furthermore describes a coated moulding including a moulding which is obtainable by injection moulding processes and includes at least one polymer selected from polymethyl methacrylate, polymethylmethacrylimide, styrene-acrylonitrile copolymer, styrene-maleic acid copolymer and polymethyl methacrylate copolymers, and a coating which is obtainable by polymerization of (meth)acrylates having at least two double bonds. The coating has an adhesive strength rating of not more than 1 according to the cross hatch test and a decrease in gloss at 20° after a scratch resistance test according to ASTM 1044 (12/05) (applied weight 500 g, number of cycles=100) of not more than 10%.

Abstract: Provided are an adhesive for a polarizing plate and a polarizing plate comprising the same, and more particularly, an adhesive composition for a polarizing plate comprising one or more acrylic monomers having a hydrophilic group, a radical polymerization initiator, an epoxy resin, and a cationic photopolymerization initiator, as well as a polarizing plate comprising a polarizer, a polymer film adhered to one side or both sides of the polarizer, and an adhesive layer for bonding the polarizer and the polymer film, in which the adhesive layer is formed of an adhesive composition comprising one or more acrylic monomers having a hydrophilic group, a radical polymerization initiator, an epoxy resin, and a cationic photopolymerization initiator.

Abstract: The present disclosure provides a method of providing an adhesive composition comprising the steps of combining crosslinkable composition including: a) a (meth)acryloyl monomer mixture with the b) photocrosslinking agent mixture, and irradiating with UVC radiation to polymerize and crosslink the composition.

Abstract: A composition, suitable for use in producing hydrogel polymer films from which biomedical devices such as contact lenses can be made, comprising at least one hydrophilic silicone macromer.

Abstract: A durable ambient light curable waterproof liquid rubber coating with volatile organic compound (VOC) content of less than 450 grams per liter made from ethylene propylene diene terpolymer (EPDM) in a solvent, a photoinitiator, an additive, pigments, and fillers, and a co-agent and a method for making the formulation, wherein the formulation is devoid of thermally activated accelerators.

Abstract: A two part high solids low volatile organic compounds durable curable waterproof liquid rubber formulation with a solids content of at least 60 percent solids by volume based on the total coating formulation, wherein a first component has EPDM, a solvent, a curative, an additive, and a blend of a pigment and a filler. The second component contains solvent and a metal drier.

Abstract: Various embodiments of the present invention generally relate to a light-cure and dual-cure resin that have low color and is color stable over conventional light, self and dual-cured resins. Additionally, the light-cure resin has enhanced degree of cure over conventional light-cure resins. Finally, due to the low color and enhanced color stability of the dual-cure resins, their inherent property of having lower shrinkage stress as compared to light-cure resins can now be utilized in various dental applications and other resin applications.

Abstract: Photolytically induced redox curable compositions, which show a delayed onset of cure resulting in controllable “open times” for the end user consumer, are provided. These compositions are activated by exposure to electromagnetic radiation, such as UV/VIS radiation with a wavelength in the range of 254-470 nm, but show a commercially meaningful “open time” prior to cure. This property is particularly attractive when opaque substrates and/or substrates with low transmissivity are to be assembled.

Abstract: A radiation curable composition for UV LED curing includes at least one co-initiator selected from the group consisting of an aliphatic tertiary amine and a dialkyl aniline derivative; and at least one specific carbazole photoinitiator. The radiation curable composition can be advantageously used to prevent unstable yellowing behavior in an image upon storage.

Abstract: A light-curable dental material is provided, comprising a polymerizable compound having at least one ethylenically unsaturated bond, a photopolymerization initiator for polymerizing said polymerizable compound, and a 1,3-dipolar compound as a polymerization inhibitor.

Abstract: A dual-curing, multi-component dental composition is described. The dental composition can include: (a) one or more photopolymerizable monomers selected from the group consisting of acrylates and methacrylates; (b) one or more photoinitiators, selected from the group consisting of alpha-diketones, benzoin alkyl ethers, thioxanthones, benzophenones, acylphosphinoxides, acetophenones, ketals, titanocenes, borates and sensitizing colorants; (c) one or more molecular weight regulators selected from the group consisting of compounds which can be converted with a radical of a monomer of component (a), wherein the conversion takes place by abstraction of an H-radical from the molecular weight regulator in the allyl position; (d) one or more polymerization inhibitors for increasing the storage stability of the composition; (e) one or more inorganic fillers; (f) one or more initiators for a chemical curing at ambient temperature, and if necessary one or more further additives.

Abstract: The present invention relates to a photochromic composition comprising multifunctional (meth)acrylate-based monomers having two or more functional groups, a photochromic dye and an aromatic vinyl compound, in which the content of the aromatic vinyl compound is more than 30% by weight and 70% by weight or less, a photochromic film produced by using the same, and a method for producing the photochromic film.

Abstract: A photocrosslinkable composition has polyorganosiloxane P having a viscosity of at least 10 000 mPa·s at 25° C., wherein the polyorganosiloxane P has an acrylated silicone oil as a crosslinking agent, and a photoinitiator, the chemical structure of which comprises a diaryl ketone group.

Abstract: This invention describes an adhesive used for bonding dental and medical biomaterials to hard tissues via a molecular bridge formed from calcium-reactive amines and acrylic or methacrylic ester monomers to hard tissues such as enamel, dentin, and bone. This formulation consists of an acid-stable polymerizable compound with multi-functional acrylate cross-linkers. This formula provides good self-adherence without prior preparation of the hard tissue substrates. The formulation can contain chemical- and/or light-activated free-radical initiators.

Abstract: A photocationically polymerizable adhesive composition and an optical member, the photocationically polymerizable adhesive composition including about 75 to about 99.8 parts by weight of a compound including one of aliphatic epoxy, alicyclic epoxy, oxetane, and vinyl ether compounds, about 0.1 to about 5 parts by weight of a titanate coupling agent, and about 0.1 to about 20 parts by weight of a photopolymerization initiator, wherein a sum of weights of the compound, the titanate coupling agent, and the photopolymerization initiator is 100 parts by weight.

Abstract: A process for polymerization of diethylene glycol bis allyl carbonate which may advantageously be employed for producing plastic lenses having a low refractive index comprising in the step of subjecting diethylene glycol bis allyl carbonate to the step of gamma radiation in the presence of diiso propyl peroxydicarbonate as a catalyst.

Abstract: This invention relates to a photosensitive composition characterized by comprising components A, B and C, and a photosensitive film and a stencil for screen printing using the photosensitive composition; Component A: a poly(vinyl alcohol) polymer represented by formula (1) or (2) wherein R1 represents a hydrogen atom, an alkyl or aralkyl group having 1 to 10 carbon atoms, wherein the alkyl and aralkyl groups may be substituted by a hydroxyl or carbamoyl group and the bond between carbon atoms thereof may be present through an oxygen atom or an unsaturated bond; R2 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms; m is an integer of 1 to 6; n is 0 or 1; and X? represents a halogen ion, a phosphate ion, a methosulfate ion, or a sulfonate ion, or a mixture of the anions; component B: a radical polymerizable monomer containing at least one ethylenically unsaturated bond and possesses an anion dissociating capability; and component C: a radical photoinitiator.

Abstract: A photo-curable adhesive composition includes oligourethane acrylate in a range of about 11 to about 23% by weight, reactive monomer-diluent in a range of about 11 to about 24% by weight, silicate filler in a range of about 50 to about 65% by weight, photoinitiator in a range of about 2.5 to about 5.0% by weight, organic peroxide in a range of about 0.1 to about 0.5% by weight, thixotropic agent in a range of about 0.5 to about 3.5% by weight, antioxidant in a range of about 0.005 to about 0.02% by weight, silane finishing agent in a range of about 0.1 to about 2.5% by weight, and oxalic acid in a range of about 0.5 to about 1.5% by weight, based on the total weight of the composition.

Abstract: A photocrosslinkable composition has polyorganosiloxane P having a viscosity of at least 10 000 mPa·s at 25° C., wherein the polyorganosiloxane P has an acrylated silicone oil as a crosslinking agent, and a photoinitiator, the chemical structure of which comprises a diaryl ketone group.

Abstract: The present invention relates to a novel composition for dental, orthopedic and drug delivery purpose. Specifically, it relates to composition comprising an admixture of a resorbable bone substitute and a crosslinkable prepolymer. It also relates to the composition formed by crosslinking the admixture.

Abstract: A method for curing a chemical composition, the composition containing at least one or more binders having ethylenically unsaturated groups, as well as one or more initiators for triggering a radical polymerization. The method includes a thermal curing step, in which the curing of the composition is effected by a radical polymerization of the binder, which is triggered by a thermal initiator and is carried out under protective gas. Paint films having improved mechanical properties can be produced using the method according to the present invention.

Abstract: The present invention relates to free-radically curable coating compositions, to methods of curing such coating compositions, and to their use.

Abstract: Self-photoinitiating liquid oligomeric compositions are disclosed. The oligomeric compositions are formed from multifunctional mercaptans and Michael addition polyacrylate resins, synthesized from multifunctional acrylates and ?-dicarbonyl Michael donors, specifically ?-keto esters, ?-diketones, ?-ketoamides or ?-ketoanilides or combinations thereof The oligomeric compositions are provided along with uses thereof and methods of fabricating.

Abstract: The present invention is directed to curable acrylate coating compositions and coated articles resulting therefrom. The curable acrylate coating composition comprises at least two polyfunctional acrylate derivatives, at least one photoinitiator and at least one nanoscale filler.

Abstract: A high refractive index, curable, synthetic resin composition comprising a core resin composition composed of a mixture of ethylenically unsaturated compounds, and an initiation system containing both photo and thermal initiators, particularly a photochromic resin composition which further includes at least one photochromic dye. Also a curing process, which includes a combination of multi-step radiation curing and thermal annealing. Articles produced of cured composition exhibit superior physical and, in appropriate cases, photochromic properties and can be easily mass produced on a commercial scale due to short processing time and use of readily available chemicals.

Abstract: This invention relates to a visible light or UV/visible light and anaerobically curable composition for encapsulating the surface of the primer mix disposed in the primer cup, particularly for use in center fire ammunition.

Abstract: Disclosed is a gas-generating, pressure-sensitive adhesive composition comprising a pressure-sensitive, ultraviolet irradiation-curable adhesive (A) containing a photoinitiator, wherein the adhesive (A) transmits therethrough an ultraviolet radiation, and a gas generator compound (B) which generates a gas upon irradiation thereof with an ultraviolet radiation, wherein the gas generator compound (B) is operably combined with the pressure-sensitive, ultraviolet irradiation-curable adhesive (A), so that, in operation, when the gas-generating, pressure-sensitive adhesive composition which is adhered to an adherend is irradiated with an ultraviolet radiation, the gas generator compound (B) generates a gas and the gas effuses at an interface between the gas-generating, pressure-sensitive adhesive composition and the adherend to thereby facilitate release of the adherend from the gas-generating, pressure-sensitive adhesive composition.

Abstract: The present invention is aimed to produce a cured product having excellent photochromism which can be easily polymerized in a short period of time. The cured product is obtained by photopolymerizing a polymerizable composition comprising (A) a radical polymerizable monomer, (B) an ultraviolet polymerization initiator having the main absorption at an ultraviolet range and a molar absorption coefficient for light having a wavelength of 400 nm of 150 liter/(mol·cm) or more, (C) a thermopolymerization initiator such as a thermopolymerization initiator having a temperature at which the half-life thereof is 10 hours of 60° C. or more and (D) a photochromic compound by irradiating activation energy rays having a wavelength of 400 nm or more as the main emission spectrum, preferably to ensure that the temperature of the cured product does not exceed 50° C., and further thermopolymerizing the composition by heating.

Abstract: Novel benzophenone derivatives and methods of making and using the same are disclosed. The novel compounds can display highly active photoinitiation and photopolymerization properties.

Abstract: Novel benzophenone derivatives and methods of making and using the same are disclosed. The novel compounds can display highly active photoinitiation and photopolymerization properties.

Abstract: New photocationic photoinitiator combinations are described that consist of 2,4,6-triarylpyrylium salts with non-nucleophilic anions and electron donors, that are able rapidly to crosslink unpigmented as well as pigmented mixtures based on cycloaliphatic epoxides to form colourless layers such as lacquers and printing inks without generating interfering and toxic emissions.

Abstract: Novel benzophenone derivatives and methods of making and using the same are disclosed. The novel compounds can display highly active photoinitiation and photopolymerization properties.

Abstract: Dental bonding compositions and methods for promoting adhesion of an amalgam-based restorative material to a dental substrate. The inventive compositions include one or more polymerizable resins that are able to adhere to a dental substrate when at least partially polymerized, one or more polymerization photoinitiators in an amount so as to result in partial polymerization of the resin when the compositions are irradiated with radiant energy, and one or more chemical initiators (e.g., benzoyl peroxide) that cause further polymerization of the resin when the composition is contacted with an amalgam restorative. A bonding composition applied to a dental substrate and irradiated with radiant energy is more polymerized in a region adjacent to the dental substrate, while a less polymerized inhibition layer forms in the region of the surface. Packing an uncured amalgam into the dental preparation mechanically disrupts the inhibition layer so as to form peaks, troughs and other irregularities.

Abstract: A novel adhesive formed in situ in a microcapsule and method for forming such a pressure sensitive or flowable adhesive in situ in a microcapsule is disclosed. The method for forming the novel adhesive comprises providing an aqueous mixture of wall material in water; adding a substantially water insoluble core material, free radical initiator, and a solvent for the pre-polymers to the aqueous mixture. The core material comprises a first addition polymerizable pre-polymer having a Tg of less than about 0° C., a flash point of at least 75° C., and a boiling point of at least 175° C. These are typically selected from acrylate or methacrylate type materials. Optionally included is a second addition polymerizable pre-polymer for providing cross-linking or interaction between polymer chains. High shear agitation is provided to the aqueous mixture to achieve a particle size of about 0.1 to 250 microns.

Abstract: This invention relates to a curable coating composition which comprises: (A) a compound represented by the formula wherein in formula (A-I) each R independently is hydrogen or a hydrocarbyl group of 1 to about 8 carbon atoms, and n is a number that is about 4 or higher; and (B) a reactive vinyl or unsaturated monomer or oligomer, provided said reactive vinyl or unsaturated monomer or oligomer is not the same as (A). In one embodiment the inventive composition further comprises (C) a photoinitiator. In one embodiment, the inventive composition further comprises (D) a thermal initiator. In one embodiment, the inventive composition further comprises (E) a latent acid catalyst. The invention also relates to a method of coating a substrate utilizing the foregoing coating composition, as well as to a substrate coated in accordance with foregoing method.

Abstract: New photocationic photoinitiator combinations are described that consist of 2,4,6-triarylpyrylium salts with non-nucleophilic anions and electron donors, that are able rapidly to crosslink unpigmented as well as pigmented mixtures based on cycloaliphatic epoxides to form colourless layers such as lacquers and printing inks without generating interfering and toxic emissions.

Abstract: A single component liquid heat-curable adhesive formulation that is stable at room temperature. The formulation includes from about 5 to about 70 wt % of at least one acrylate monomer, from about 5 to about 94 wt % of an acrylate oligomer, and from about 0.1 to about 10 wt % of a thermal initiator selected from the group consisting of diacyl peroxides, benzoyl peroxides and peroxy esters. A photo initiator may be included thereby rendering the stable liquid formulation to be both heat-curable and UV-curable.

Abstract: A cationically polymerizable resin composition which comprises (A) a compound containing at least one ring selected from the group consisting of an oxirane ring and an oxetane ring; (B) an onium salt; (C) an organic peroxide; and (D) an alkaline filler except for a hydroxide.

Abstract: This invention relates to a photopolymerizable resin composition containing resin component (A) composed of a resin and/or a resin-forming ingredient and a photopolymerization initiator (B) wherein the component (A) comprises an addition-polymerizable compound (A1) having at least two ethylenically unsaturated groups and the photopolymerization initiator (B) comprises a diaminobenzophenone compound (B1), an N-phenylglycine compound (B2), and at least one kind of compound selected from a group of a 3,3′,4,4′-tetra(alkylperoxycarbonyl)benzophenone (B3), 2-methyl-1-[4-(thiomethyl)phenyl]- 2-morpholinopropan-1-one (B4), and a 1,3,5-triazine derivative (B5) containing at least one trihalomethyl group as substituent.

Abstract: Novel benzophenone derivatives and methods of making and using the same are disclosed. The novel compounds can display highly active photoinitiation and photopolymerization properties.

Abstract: A radiation—and/or heat-curable adhesive with high thermal conductivity includes the following recipe: 19 to 40 wt % of a difunctional acrylated, aromatic polyurethane; 9 to 25 wt % of (2-hydroxypropyl) acrylate or methacrylate; 1 to 5 wt % of one or more photoinitiators; 35 to 70 wt % of one or more mineral fillers; 0.5 to 3 wt. % of an SiO2-containing thixotropizing agent; and 0.5 to 2 wt % of an organic peroxide.