Contains Compound Containing Keto Group Not Part Of A Ring And A Specified Rate-affecting Material; Or Contains A Specified Rate-affecting Material And A Nonspecified Photoinitiator Or Photosensitizer Patents (Class 522/12)
  • Patent number: 11828996
    Abstract: An optical fiber ribbon comprises a plurality of optical fibers arranged in parallel and a connecting resin layer containing a ribbon resin for coating and connecting the plurality of optical fibers, wherein each of the plurality of optical fibers has an outer diameter of 220 ?m or less; each of the plurality of optical fibers includes a glass fiber, a primary resin layer, and a colored secondary resin layer; the colored secondary resin layer contains a cured product of a resin composition containing 2,4,6-trimethylbenzoyldiphenylphosphine oxide; and a content of phosphorus in the colored secondary resin layer is 0.03 mass % or more and 0.30 mass % or less, and an amount of a phosphorus-tin complex at the surface of the colored secondary resin layer is 300 ppm or more and 7000 ppm or less.
    Type: Grant
    Filed: January 18, 2021
    Date of Patent: November 28, 2023
    Assignee: SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Noriaki Iwaguchi, Takashi Fujii, Fumiaki Sato
  • Patent number: 11739221
    Abstract: Polymerizable liquids are described herein which, in some embodiments, can produce 3D printed articles of high resolution and desirable mechanical properties. In one aspect, a polymerizable liquid comprises an acrylate component, and a composite resin comprising a curable carrier and polymeric particles dispersed in the curable carrier. The polymerizable liquid also comprises a photoinitiator component.
    Type: Grant
    Filed: November 10, 2021
    Date of Patent: August 29, 2023
    Assignee: 3D SYSTEMS, INC.
    Inventor: John Fong
  • Patent number: 11685841
    Abstract: Cure in place pressure sensitive adhesive compositions are described that comprise one or more of a bodying component, a structural diluent, a radical diluent as well as additives such as crosslinkers, external catalysts, photoinitiators and stabilizers/process aids. The bodying component can be acrylic or non-acrylic.
    Type: Grant
    Filed: April 29, 2021
    Date of Patent: June 27, 2023
    Assignee: Avery Dennison Corporation
    Inventors: Michael Zajaczkowski, Michael T. Waterman, Kyle R. Heimbach, Eric L. Bartholomew, Brandon S. Miller
  • Patent number: 11339256
    Abstract: A composition contains (a) a silicon-free mercapto compound comprising 2 or more mercapto groups; (b) a linear polyorganosiloxane containing one or more than one terminally unsaturated alkenyl group, 40 mole-percent or more phenyl groups relative to moles of silicon atoms and at least one alkoxysilyl group per molecule; (c) a resinous polyorganosiloxane containing one or more than one terminally unsaturated alkenyl group and 20 mole-percent or more phenyl groups relative to moles of silicon atoms; (d) a photoinitiator; and (e) a moisture cure catalyst; and wherein the molar ratio of mercapto groups to terminally unsaturated alkenyl groups in the composition is in a range of 0.3 to 2.0.
    Type: Grant
    Filed: August 3, 2020
    Date of Patent: May 24, 2022
    Assignee: Dow Silicones Corporation
    Inventors: Junying Liu, David M. Altergott, Steven Swier
  • Patent number: 11198804
    Abstract: A transparent sealing compound, in particular for use in a wall penetration of lines or in a splice site of a cable set. In order to have greater flexibility the sealing compound consists of a radiation crosslinked, in particular UV-crosslinked, poly (alkyl acrylate). The sealing compound is crosslinked such that its elongation amounts to more than 1000% for a material thickness of 1.5 mm according to ISO 527-2/1BA/300 and its shear strength is less than 1000 min according to DIN EN 1943 (tested per method A, 625 mm2 contact surface area).
    Type: Grant
    Filed: January 12, 2017
    Date of Patent: December 14, 2021
    Assignee: Coroplast Fritz Müller GmbH & Co. KG
    Inventors: Christoph Frigge, Nina Putsch, Torsten Fieselmann
  • Patent number: 11041026
    Abstract: Disclosed are methods, compositions, kits, and reagents to prepare compounds (e.g. polymers and small molecules) via radical reactions by utilizing thermoresponsive and photoresponsive gels. This invention discloses the preparation of polymers via controlled radical polymerizations from an iniferter or initiator, one or more reactant monomer, and a thermoresponsive and photoresponsive gel. Embodiments of the invention show that the polymerization is reversibly activated and/or deactivated by controlling one or more of the following external control stimuli: temperature, light, and catalyst presence. This invention also relates the preparation of Gel-PTH, a heterogeneous thermoresponsive and photoresponsive gel.
    Type: Grant
    Filed: January 30, 2018
    Date of Patent: June 22, 2021
    Assignee: Massachusetts Institute of Technology
    Inventors: Jeremiah A. Johnson, Mao Chen
  • Patent number: 10597560
    Abstract: Cure in place pressure sensitive adhesive compositions are described that comprise one or more of a bodying component, a structural diluent, a radical diluent as well as additives such as crosslinkers, external catalysts, photoinitiators and stabilizers/process aids. The bodying component can be acrylic or non-acrylic.
    Type: Grant
    Filed: June 28, 2018
    Date of Patent: March 24, 2020
    Assignee: Avery Dennison Corporation
    Inventors: Michael Zajaczkowski, Michael T. Waterman, Kyle R. Heimbach, Eric L. Bartholomew, Brandon S. Miller
  • Patent number: 10533117
    Abstract: Cure in place pressure sensitive adhesive compositions are described that comprise one or more of a bodying component, a structural diluent, a radical diluent as well as additives such as crosslinkers, external catalysts, photoinitiators and stabilizers/process aids. The bodying component can be acrylic or non-acrylic.
    Type: Grant
    Filed: June 28, 2018
    Date of Patent: January 14, 2020
    Assignee: Avery Dennison Corporation
    Inventors: Michael Zajaczkowski, Michael T. Waterman, Kyle R. Heimbach, Eric L. Bartholomew, Brandon S. Miller
  • Patent number: 10038113
    Abstract: A moldable photovoltaic module is provided. The module includes a flexible polymeric flex-circuit substrate having an electrically conductive printed wiring pattern and solder pads defined on it. Small photovoltaic cells are affixed to the flex-circuit substrate by back-surface contacts in electrical contact with the solder pads. At least one thermoformable polymeric film is joined to the flex-circuit substrate. Each said solder pad comprises a solder composition that, after an initial melt, has a melting point that lies above at least a portion of the temperature range for thermoforming the polymeric film.
    Type: Grant
    Filed: November 24, 2015
    Date of Patent: July 31, 2018
    Assignee: National Technology & Engineering Solutions of Sandia, LLC
    Inventors: Jeffrey S. Nelson, Michael Hibbs, Gregory N. Nielson, Murat Okandan, Jose Luis Cruz-Campa, Paul J. Resnick, Carlos Anthony Sanchez, Vipin P. Gupta, Peggy J. Clews
  • Patent number: 10005872
    Abstract: The present invention provides an active energy ray-curable composition exhibiting high curability and having excellent offset printability when used for a printing ink, an active energy ray-curable printing ink having both excellent curability and offset printability, and a printed matter using the same. An active energy ray-curable composition includes a urethane (meth)acrylate resin (A) and a polymerization initiator (B), wherein the urethane (meth)acrylate resin (A) is produced by using an aromatic polyisocyanate (a), a hydroxyl group-containing mono(meth)acrylate (b), and a polyol (c) as essential reaction raw materials so that the ratio [(b?)/(a?)] of the number of moles (b?) of hydroxyl groups contained in the hydroxyl group-containing mono(meth)acrylate (b) to the number of moles (a?) of isocyanate groups contained in the aromatic polyisocyanate (a) is within a range of 0.99 to 0.40, and the urethane (meth)acrylate resin (A) has a (meth)acryloyl group concentration within a range of 1.5 to 4.0 mmol/g.
    Type: Grant
    Filed: August 27, 2015
    Date of Patent: June 26, 2018
    Assignee: DIC CORPORATION
    Inventors: Yumiko Nakamura, Yoshinobu Deguchi, Keisuke Wakahara, Koichi Yamaguchi, Tatsushi Okuda
  • Publication number: 20150080490
    Abstract: The invention relates to a composition with at least one polymerizable binder, wherein the composition contains a photoinitiator mixture which contains (a) at least one diacylgermanium compound of general formula (I) in which R1, R2 independently of each other are a linear C1-4-alkyl, or C2-4-alkenyl radical, which can be substituted by one or more polymerizable groups; R3, R4 independently of each other are in each case H, halogen, a branched or linear C1-4-alkyl or —O—C1-4-alkyl radical; R5, R6, R7 independently of each other are in each case H, halogen, a linear C1-20-alkyl, -alkenyl, -alkoxy or -alkenoxy radical, which can be interrupted by one or more —O—, —S— or —NR8— radicals and substituted by one or more polymerizable groups; and R8 independently is in each case H, a C1-20-alkyl, -alkenyl, -alkoxy or -alkenoxy radical, (b) at least one ?-diketone and (c) at least one accelerator, as well as the use of the composition for example for producing a filling composite.
    Type: Application
    Filed: April 11, 2013
    Publication date: March 19, 2015
    Inventors: Peter Burtscher, Norbert Moszner, Volker Rheinberger
  • Patent number: 8980967
    Abstract: The present disclosure provides a method of providing an adhesive composition comprising the steps of combining crosslinkable composition including: a) a (meth)acryloyl monomer mixture with the b) photocrosslinking agent mixture, and irradiating with UVC radiation to polymerize and crosslink the composition.
    Type: Grant
    Filed: March 27, 2012
    Date of Patent: March 17, 2015
    Assignee: 3M Innovative Properties Company
    Inventors: Larry R. Krepski, Babu N. Gaddam, Marie Aloshyna ep Lesuffleur, Arlin L. Weikel, Kathleen S. Shafer
  • Patent number: 8901191
    Abstract: A durable ambient light curable waterproof liquid rubber coating with volatile organic compound (VOC) content of less than 450 grams per liter made from ethylene propylene diene terpolymer (EPDM) in a solvent, a photoinitiator, an additive, pigments, and fillers, and a co-agent and a method for making the formulation, wherein the formulation is devoid of thermally activated accelerators.
    Type: Grant
    Filed: February 12, 2014
    Date of Patent: December 2, 2014
    Assignee: Lion Copolymer Geismar, LLC
    Inventors: Michael J. Molnar, Arthur J. Fontenot, III, Harold William Young, Jr., Daniel S. Nelson, Augusto Caesar Ibay
  • Publication number: 20140228465
    Abstract: A durable ambient light curable waterproof liquid rubber coating with volatile organic compound (VOC) content of less than 450 grams per liter made from ethylene propylene diene terpolymer (EPDM) in a solvent, a photoinitiator, an additive, pigments, and fillers, and a co-agent and a method for making the formulation, wherein the formulation is devoid of thermally activated accelerators.
    Type: Application
    Filed: February 12, 2014
    Publication date: August 14, 2014
    Applicant: LION COPOLYMER GEISMAR, LLC
    Inventors: Michael J. Molnar, Arthur J. Fontenot, III, Harold William Young, Jr., Daniel S. Nelson, Augusto Caesar Ibay
  • Patent number: 8785514
    Abstract: Various embodiments of the present invention generally relate to a light-cure and dual-cure resin that have low color and is color stable over conventional light, self and dual-cured resins. Additionally, the light-cure resin has enhanced degree of cure over conventional light-cure resins. Finally, due to the low color and enhanced color stability of the dual-cure resins, their inherent property of having lower shrinkage stress as compared to light-cure resins can now be utilized in various dental applications and other resin applications.
    Type: Grant
    Filed: November 28, 2008
    Date of Patent: July 22, 2014
    Assignee: The Board of Regents of The University of Texas System
    Inventors: H. Ralph Rawls, Kyumin Whang, Nasser Barghi, Dong-Hoon Shin, Richard Plymale, Janice Plymale
  • Publication number: 20140039083
    Abstract: The present disclosure provides a method of providing an adhesive composition comprising the steps of combining crosslinkable composition including: a) a (meth)acryloyl monomer mixture with the b) photocrosslinking agent mixture, and irradiating with UVC radiation to polymerize and crosslink the composition.
    Type: Application
    Filed: March 27, 2012
    Publication date: February 6, 2014
    Applicant: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Larry R. Krepski, Babu N. Gaddam, Marie Aloshyna ep Lesuffleur, Arlin L. Weikel, Kathleen S. Shafer
  • Patent number: 8633258
    Abstract: The invention relates to a liquid bis(acyl)phosphine oxide of formula (I): wherein R is C1-C18 alkyl, and wherein R is optionally substituted as described herein. The invention also relates to radiation curable compositions comprising liquid bis(acyl)phosphine oxide of formula (I).
    Type: Grant
    Filed: June 21, 2011
    Date of Patent: January 21, 2014
    Assignee: DSM IP Assets B.V.
    Inventor: Timothy Edward Bishop
  • Patent number: 8569393
    Abstract: A radiation curable composition for UV LED curing includes at least one co-initiator selected from the group consisting of an aliphatic tertiary amine and a dialkyl aniline derivative; and at least one specific carbazole photoinitiator. The radiation curable composition can be advantageously used to prevent unstable yellowing behavior in an image upon storage.
    Type: Grant
    Filed: December 6, 2010
    Date of Patent: October 29, 2013
    Assignee: AGFA-Gevaert N.V.
    Inventor: Johan Loccufier
  • Patent number: 8557889
    Abstract: The invention provides an ink composition including a sensitizer represented by the following Formula (I), a photopolymerization initiator, and a polymerizable compound having an ethylenic unsaturated bond. In the Formula (I), R1, R6 and R8 each independently represent a hydrogen atom, a hydroxyl group, a halogen atom, a linear or branched alkyl group which may be substituted, or an alkoxy group which may be substituted. R2, R4, R5 and R7 each independently represent a hydrogen atom, a halogen atom, or a cyano group. R3 represents a hydrogen atom, a linear or branched alkyl group which may be substituted, or a cycloalkyl group which may be substituted.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: October 15, 2013
    Assignee: FUJIFILM Corporation
    Inventor: Tokihiko Matsumura
  • Patent number: 8507570
    Abstract: A light-curable dental material is provided, comprising a polymerizable compound having at least one ethylenically unsaturated bond, a photopolymerization initiator for polymerizing said polymerizable compound, and a 1,3-dipolar compound as a polymerization inhibitor.
    Type: Grant
    Filed: January 6, 2012
    Date of Patent: August 13, 2013
    Assignee: DENTSPLY International Inc.
    Inventor: Gordan Blackwell
  • Publication number: 20130123380
    Abstract: The present invention provides an oxygen-absorbing resin composition that allows the miniaturization of an ultraviolet irradiation apparatus for initiating oxygen absorption, and rapidly initiates oxygen absorption by irradiation of an ultraviolet ray having a particular wavelength. The present invention is an oxygen-absorbing resin composition comprising an initiator, a transition metal catalyst, and an oxidizable resin, wherein the oxygen-absorbing resin composition initiates oxygen absorption by irradiation of an ultraviolet ray having a peak wavelength within the range of 300 to 400 nm.
    Type: Application
    Filed: May 16, 2011
    Publication date: May 16, 2013
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Makoto Sumitani, Emiko Yokose, Kimitaka Nakao
  • Patent number: 8426020
    Abstract: The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%; B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about ?25° C. to about ?55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: April 23, 2013
    Assignee: DSM IP Assets B.V.
    Inventors: Steven R. Schmid, Petrus Jacobus Hubertus Niels, Paulus Antonius Maria Steeman, Xiaosong Wu, Wendell Wayne Cattron, Tyson Dean Norlin, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello
  • Publication number: 20120207939
    Abstract: The photocuring efficiency of a photoinitiator is increased by mixing it with an organic phosphite and an aldehyde. This mixture or photoinitiator composition can be used to cure acrylates or other photocurable compounds, particularly in an oxygen-containing environment.
    Type: Application
    Filed: February 14, 2011
    Publication date: August 16, 2012
    Inventor: Deepak Shukla
  • Publication number: 20120208914
    Abstract: The photocuring efficiency of a photoinitiator is increased by mixing it with an organic phosphite and an aldehyde. This mixture or photoinitiator composition can be used to cure acrylates or other photocurable compounds, particularly in an oxygen-containing environment.
    Type: Application
    Filed: February 14, 2011
    Publication date: August 16, 2012
    Inventor: Deepak Shukla
  • Publication number: 20120207945
    Abstract: A photocurable ink contains a colorant dissolved or dispersed within a solvent, a photoinitiator, an organic phosphite, an aldehyde, and a photocurable compound. The organic phosphite is present in a molar excess relative to the aldehyde moieties that are present. The photocurable ink can be used for imaging or other applications where a uniform or patterned image is desired. The photocurable ink can be cured partially before application, or totally cured after application.
    Type: Application
    Filed: February 14, 2011
    Publication date: August 16, 2012
    Inventor: Deepak Shukla
  • Patent number: 8217095
    Abstract: The object of the present invention is to provide an active energy ray-curable ink-jet printing ink, including: a coloring agent; a compound having an ethylenic double bond; and a photo-polymerization initiator, wherein the photo-polymerization initiator includes a compound represented by general formula (1): (wherein A represents any one of —O—, —CH2—, —CH(CH3)—, and —C(CH3)2—; and each of R1 and R2 independently represents a hydrogen atom, a methyl group, or a trimethylsilyl group), and an ?-aminoketone-based compound and/or an acyl phosphine oxide-based compound, and 40% by mass or more of the compound represented by general formula (1) is included with respect to the total photo-polymerization initiator.
    Type: Grant
    Filed: October 28, 2005
    Date of Patent: July 10, 2012
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Hisao Yamaguchi, Yutaka Yamada, Naohito Saito, Osamu Oshima
  • Publication number: 20120157561
    Abstract: The present invention provides a method comprising: applying a UV-curable ink to a substrate; partially curing the ink by exposing the ink to UV radiation from an LED source; and exposing the partially cured ink to UV radiation from a flash lamp. The flash lamp is a xenon or krypton flash lamp. An apparatus for performing the method and an ink adapted for use in the method are also provided.
    Type: Application
    Filed: June 25, 2010
    Publication date: June 21, 2012
    Inventors: Nigel Gould, Barry Michael McGregor
  • Patent number: 8092869
    Abstract: There is provided an ink composition for ink jet recording, including (A) N-vinyllactam, (B) a compound having a partial structure represented by the following formula (I) and a polymerizable unsaturated bond, and (C) a radical polymerization initiator. In formula (I), R1 represents a hydrogen atom or an alkyl group, and R2 to R5 each independently represent a methyl group or an ethyl group.
    Type: Grant
    Filed: September 15, 2008
    Date of Patent: January 10, 2012
    Assignee: Fujifilm Corporation
    Inventors: Ippei Nakamura, Yuuichi Hayata
  • Publication number: 20110278797
    Abstract: A curable sealant composition free from volatile organic compounds. The composition comprises a urethane acrylate oligomer present in an amount from about 20% to about 60% by weight. A liquid elastomer is present in an amount from about 20% to about 60% by weight, and at least one photoinitiator present in an amount from about 0.5% to about 10% by weight. A process for sealing a dynamic seal assembly in a housing bore is also provided.
    Type: Application
    Filed: May 12, 2010
    Publication date: November 17, 2011
    Applicant: Freudenberg-NOK General Partnership
    Inventor: Michael J. MOORE
  • Patent number: 8030401
    Abstract: The present invention is directed to photoinitiated cationic epoxy compositions including: (a) at least one substantially saturated epoxy material comprising at least two glycidyl ether groups; (b) about 0.1 to about 20 weight percent on a basis of total weight of the composition of at least one polymer comprising at least one vinyl chloride segment and at least one vinyl acetate segment; and (c) at least one cationic photoinitiator; and bonded substrates and methods of bonding including the same.
    Type: Grant
    Filed: August 3, 2006
    Date of Patent: October 4, 2011
    Assignee: Henkel Corporation
    Inventors: Philip T. Klemarczyk, Anthony F. Jacobine
  • Publication number: 20110196056
    Abstract: The invention relates to light-curable dental materials comprising at least one polymerizable compound, a photopolymerization initiator and a polymerization inhibitor.
    Type: Application
    Filed: November 8, 2010
    Publication date: August 11, 2011
    Inventor: Gordon Blackwell
  • Publication number: 20110170209
    Abstract: Compounds of the formula I or (I?), wherein R1 and R?1 for example are hydrogen, C3-C8cycloalkyl or C1-C12alkyl, R2 and R2? for example are hydrogen; unsubstituted C1-C20alkyl or substituted C1-C20alkyl; and R8 and R9 for example are hydrogen, C1-C12alkyl which optionally is substituted, or phenyl which optionally is substituted; exhibit an unexpectedly good performance in photopolymerization reactions.
    Type: Application
    Filed: May 27, 2009
    Publication date: July 14, 2011
    Applicant: BASF SE
    Inventors: Akira Matsumoto, Hisatoshi Kura
  • Publication number: 20110160689
    Abstract: The present invention relates to a High Internal Phase Emulsion (HIPE) and HIPE foams produced therefrom comprising two or more layers and having a photoinitiator.
    Type: Application
    Filed: June 7, 2010
    Publication date: June 30, 2011
    Inventors: Steven Ray Merrigan, Thomas Allen Desmarais
  • Patent number: 7935741
    Abstract: An ink composition is provided that includes a condensed polycyclic aromatic compound, a polymerization initiator, and a polymerizable compound, and the condensed polycyclic aromatic compound is a compound selected from the group consisting of a compound represented by the formula below, a compound having at least three hydroxy groups, alkoxy groups, and/or aryloxy groups on a condensed polycyclic aromatic ring, and a compound having at least one atom having an atomic weight of 32 or greater bonded to a condensed polycyclic aromatic ring and/or one group bonded to the condensed polycyclic aromatic ring via an atom having an atomic weight of 32 or greater. There are also provided a printed material obtained by employing the ink composition, a process for producing a lithographic printing plate employing the ink composition, and a lithographic printing plate obtained by the production process.
    Type: Grant
    Filed: August 21, 2006
    Date of Patent: May 3, 2011
    Assignee: FUJIFILM Corporation
    Inventor: Tomotaka Tsuchimura
  • Patent number: 7923483
    Abstract: An optical fiber ribbon includes a plurality of optical fibers encapsulated within a matrix material, where the optical fiber coating(s) and the matrix material(s), and optionally any ink layers thereon, are characterized by compatible chemical and/or physical properties, whereby the fiber coating and matrix and any ink layers therebetween can be reliably stripped from the optical fibers to afford a suitable strip cleanliness. Novel ink formulations that can be used in the making of such fiber optic ribbons, methods of making such ribbons, and their use are also described.
    Type: Grant
    Filed: March 26, 2007
    Date of Patent: April 12, 2011
    Assignee: Corning Incorporated
    Inventors: Ching-Kee Chien, Michelle Dawn Fabian, Edward John Fewkes, Michael James Winningham
  • Patent number: 7872058
    Abstract: An object of the present invention is to provide a photopolymerizable dental composition which causes less change in a color tone before and after curing and exhibits excellent photopolymerizability to irradiation in a wide wavelength range, and has also excellent thin-layer surface curability, and to provide a photopolymerization initiator used therefor. Disclosed is a visible light-polymerizable dental composition which does not substantially contain an amine compound as a photosensitizer, comprising 0.01 to 10 parts by weight of a (bis)acylphosphine oxide compound, 0.01 to 10 parts by weight of an ?-diketone compound and 100 parts by weight of a polymerizable monomer.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: January 18, 2011
    Assignee: Kabushiki Kaisha Shofu
    Inventors: Jun Uchida, Mitsuharu Mizuno, Mitsuji Teramae
  • Publication number: 20100227940
    Abstract: The invention provides a photo-crosslinkable composition comprising: a base polymer selected from olefin homopolymers or copolymers, or mixtures thereof; a cross-linking agent; and a photoinitiator; characterized in that said photoinitiator is a compound with formula I: in which: X1 to X8 respectively represent CR1 to CR8; R1 to R8 are identical or different and represent a hydrogen atom or a halogen atom or OH or C(?O)R9 or C(?O)OR10 or SO3? or an aryl group, preferably a phenyl group, or an acryloyloxy group or a linear or branched C1-12 alkyl group; R9 and R10 are identical or different and represent a hydrogen atom or a linear or branched C1-12 alkyl group; n represents an integer equal to 0, 1 or 2; when n equals 0, formula I is selected from 9-fluorenone and its derivatives; when n equals 1; either Y represents a methylene group or a CHR11 group, R11 representing a hydrogen atom or a halogen atom or OH or C(?O)R9 or C(?O)OR10 or a linear or branched C1-12 alkyl group; or Y and X4 or Y and
    Type: Application
    Filed: March 19, 2007
    Publication date: September 9, 2010
    Applicant: NEXANS
    Inventors: Olivier Pinto, Jérôme Alric
  • Publication number: 20100198168
    Abstract: The invention relates to a coating formulation for preparing a hydrophilic coating, wherein the hydrophilic coating formulation comprises a supporting monomer and/or polymer comprising at least 2 reactive moieties capable of undergoing polymerization reactions, a polyelectrolyte, a Norrish Type I photoinitiator, and a Norrish Type II photoinitiator.
    Type: Application
    Filed: February 27, 2008
    Publication date: August 5, 2010
    Applicant: DSM IP ASSETS B.V.
    Inventor: Marnix Rooijmans
  • Publication number: 20100184880
    Abstract: The present invention provides a photocurable pressure-sensitive adhesive composition which has sufficient adhesion before being irradiated with light, and after being irradiated with light, keeps a sufficient pot life and has a short cure-completion time at a room temperature. A cured product produced from the composition has high adhesion force to adherends difficult to be attached, and excellent durability. The photocurable pressure-sensitive adhesive composition comprises a crosslinking compound (A) that is crosslinkable by the action of a base, a photobase generator (B) which becomes active upon light irradiation to generate a base, and a tackifying component (C).
    Type: Application
    Filed: June 4, 2008
    Publication date: July 22, 2010
    Inventor: Hiroji Fukui
  • Patent number: 7709547
    Abstract: The present invention provides an ink composition, and inkjet recording method, a printed material, a production method of a planographic printing plate, and a planographic printing plate. The ink composition of the present invention contains a cationically polymerizable compound, a compound that generates an acid when irradiated with a radiation ray, and an onium salt compound that generates an organic acid compound having a basic nitrogen atom when irradiated with a radiation ray.
    Type: Grant
    Filed: November 21, 2006
    Date of Patent: May 4, 2010
    Assignee: FUJIFILM Corporation
    Inventors: Kazuhiro Yokoi, Ippei Nakamura, Kenji Wada
  • Patent number: 7601465
    Abstract: A holographic recording medium has a recording layer including a radical-polymerizable compound, a first photo-radical polymerization initiator (A) containing a titanocene compound, and a second photo-radical polymerization initiator (B) containing at least one compound selected from the group consisting of an amino acetophenone derivative, an acylphosphine oxide derivative, a benzyl derivative, and a thioxanthone derivative.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: October 13, 2009
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Rumiko Hayase, Akiko Hirao, Kazuki Matsumoto, Norikatsu Sasao
  • Patent number: 7563831
    Abstract: A method for curing a chemical composition, the composition containing at least one or more binders having ethylenically unsaturated groups, as well as one or more initiators for triggering a radical polymerization. The method includes a thermal curing step, in which the curing of the composition is effected by a radical polymerization of the binder, which is triggered by a thermal initiator and is carried out under protective gas. Paint films having improved mechanical properties can be produced using the method according to the present invention.
    Type: Grant
    Filed: December 23, 2005
    Date of Patent: July 21, 2009
    Assignee: Daimler AG
    Inventors: Markus Bischof, Elisabeth Gemmler, Fritz Mezger, Thomas Raith, Christoph Ruechardt
  • Patent number: 7556843
    Abstract: A photopolymerization process for producing pigmented and non-pigmented articles comprises irradiating with electromagnetic radiation in the range from 190 to 600 nm, or with electron beam or with X-rays a photosensitive composition which can be developed by alkali solution which composition comprises (A) a polymer containing at least one carboxylic acid group in the molecule and having a molecular weight of 200,000 or less, (B) selected ?-aminoalkylphenone compounds as photoinitiators and (C) an ester of a polyol, wherein the polyol is partially or fully esterified with an ethylenically unsaturated carboxylic acid a monomeric, oligomeric or polymeric compound having at least one olefinic double bond.
    Type: Grant
    Filed: June 13, 2007
    Date of Patent: July 7, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hisatoshi Kura, Hidetaka Oka, Masaki Ohwa
  • Publication number: 20080280144
    Abstract: A coating composition based upon at least partially hydrolyzed epoxy-functional alkoxy silanes and having particular utility in forming tintable, abrasion resistant coatings on lenses. Incorporation in the composition of a non-hydrolyzed epoxy-functional alkoxy silane provides a desired reduction in viscosity. Incorporation in the composition of a polyether surfactant provides a cured coating of the composition with increased tintability.
    Type: Application
    Filed: June 9, 2008
    Publication date: November 13, 2008
    Applicant: THE WALMAN OPTICAL COMPANY
    Inventor: Gerald D. Treadway
  • Publication number: 20080274201
    Abstract: This invention provides novel methods for the formation of biocompatible membranes around biological materials using photopolymerization of water soluble molecules. The membranes can be used as a covering to encapsulate biological materials or biomedical devices, as a “glue” to cause more than one biological substance to adhere together, or as carriers for biologically active species. Several methods for forming these membranes are provided. Each of these methods utilizes a polymerization system containing water-soluble macromers, species, which are at once polymers and macromolecules capable of further polymerization. The macromers are polymerized using a photoinitiator (such as a dye), optionally a cocatalyst, optionally an accelerator, and radiation in the form of visible or long wavelength UV light. The reaction occurs either by suspension polymerization or by interfacial polymerization.
    Type: Application
    Filed: July 11, 2008
    Publication date: November 6, 2008
    Applicant: Board of Regents, The University of Texas System
    Inventors: Jeffrey A. Hubbell, Chandrashekhar P. Pathak, Amarpreet S. Sawhney, Neil P. Desai, Syed F.A. Hossainy
  • Patent number: 7425585
    Abstract: Photosensitive compositions which can be developed by alkali solution, comprise (A) a polymer containing at least one carboxylic acid group in the molecule and having a molecular weight of 200,000 or less, (B) selected ?-aminoalkylphenone compounds as photoinitiators and (C) an ester of a polyol, wherein the polyol is partially or fully esterified with an ethylenically unsaturated carboxylic acid a monomeric, oligomeric or polymeric compound having at least one olefinic double bond.
    Type: Grant
    Filed: June 13, 2007
    Date of Patent: September 16, 2008
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hisatoshi Kura, Hidetaka Oka, Masaki Ohwa
  • Publication number: 20080160300
    Abstract: A composition, including a polymer binder resin A, a UV-curing acrylate B, a heat curing agent C, and a photopolymerization initiator D. The composition includes about 20 to about 150 parts by weight of the UV-curing acrylate B per 100 parts by weight of the polymer binder resin A, and the UV-curing acrylate B is a solid or near-solid at room temperature and has a viscosity of about 10,000 cps or more at 40° C.
    Type: Application
    Filed: December 27, 2007
    Publication date: July 3, 2008
    Inventors: Yong Ha Hwang, Gyu Seok Song, Hee Yeon Ki, Kyoung Jin Ha, Jae Hyun Cho, Jun Suk Kim, Chang Beom Chung
  • Patent number: 7323499
    Abstract: The present invention discloses an ultraviolet light curable silver chloride composition and method for making such a composition that may be used to produce an silver coating on a substrate. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.
    Type: Grant
    Filed: March 22, 2005
    Date of Patent: January 29, 2008
    Assignee: Allied Photochemical, Inc.
    Inventor: Roy C. Krohn
  • Patent number: 7247659
    Abstract: A photosensitive composition comprising, (A) an oligomer or polymer containing at least one carboxylic acid group in the molecule and having a molecular weight of 200?000 or less; (B) at least one photoinitiator compound of formula I ?wherein R1 is linear or branched C1–C12alkyl; R2 is linear or branched C1–C4alkyl; R3 and R4 independently of one another are linear or branched C1–C8alkyl; and (C) a monomeric, oligomeric or polymeric compound having at least one olefinic double bond, is especially suitable for preparting photoresists, in particular color filters.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: July 24, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hisatoshi Kura, Hidetaka Oka, Masaki Ohwa
  • Patent number: 7112616
    Abstract: A two-photon absorbing polymerizable composition contains at least a two-photon absorbing compound, a polymerization initiator and a polymerizable compound, the composition being photopolymerizable upon non-resonant two-photon absorption, wherein the two-photon absorbing compound is a methine dye containing a compound represented by the formula (1): wherein R1 to R5 each represents a hydrogen atom or a substituent and some of R1 to R4 may combine with each other to form a ring; n and m each independently represents an integer of 0 to 4, provided that n and m are not 0 at the same time; X1 and X2 each represents an aryl group, a heterocyclic group or a group represented by formula (2); R6 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or a heterocyclic group, and Z1 represents an atomic group for forming a 5- or 6-membered ring.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: September 26, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroo Takizawa, Masaharu Akiba, Takeharu Tani