Processes Of Preparing A Solid Polymer From At Least One Nitrogen Containing Monomer; Or Compositions Therefore Patents (Class 522/173)
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Patent number: 12187907Abstract: The present invention provides energy curable compositions comprising self-initiating oligomers, amine synergists and Group IV metal chelates. The compositions optionally comprise acrylate monomers having carbonate ester, carbamate, or oxazolidinone groups. The compositions of the present invention exhibit improved cure, and are suitable for packaging, such as food packaging.Type: GrantFiled: July 28, 2021Date of Patent: January 7, 2025Assignee: Sun Chemical CorporationInventors: Mathew C. Mathew, David Biro
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Patent number: 9720136Abstract: This invention relates to a photo-alignment copolymer which enables the formation of an optical anisotropic film that exhibits superior optical anisotropy, an optical anisotropic film using the photo-alignment copolymer and a method of manufacturing the optical anisotropic film. The photo-alignment copolymer includes both of a photo-alignment repeating unit having a photo-reactive functional group such as a cinnamate-based functional group, a chalcone-based functional group, an azo-based functional group or a coumarin-based functional group, and a repeating unit having a specific structure able to increase optical anisotropy.Type: GrantFiled: August 27, 2013Date of Patent: August 1, 2017Assignee: LG CHEM, LTD.Inventors: Dai Seung Choi, Dong Woo Yoo, Sung-Ho Chun, Hyeong Bin Jang, Mi Ra Hong
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Patent number: 9587125Abstract: A photo-curable ink composition including an acrylic polymer or copolymer, a mono-functional monomer, a multi-functional monomer, a photo-initiator and a pigment. Also disclosed herein is a method for forming a printed article and an inkjet printing system using said photo-curable ink composition.Type: GrantFiled: May 22, 2013Date of Patent: March 7, 2017Assignee: Hewlett-Packard Industrial Printing LTD.Inventors: Eytan Cohen, Malan Calitz, Alex Trubnikov, Alona Makarsky
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Patent number: 9540477Abstract: The present invention provides for an ethylenically unsaturated hydroxyl-terminated polyurethane (I) obtained by reacting (i) at least one ethylenically unsaturated compound (A) containing at least two reactive groups capable of reacting with isocyanate groups and at least one ethylenically unsaturated group; with (ii) at least one saturated alcohol component (B) comprising: (iia) at least one saturated hydroxylated compound (B1) containing hydrophilic groups capable of rendering the polyurethane dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, and at least one compound (B2) that is selected from saturated polyester polyols (B21) and/or from saturated polycarbonate polyols (B22); and/or (iib) at least one compound (B3) that is selected from saturated polyester polyols (B31) containing compound (B1) moieties and/or from saturated polycarbonate polyols (B32) containing compound (B1) moieties; and, optionally, one or more of compounds (B1) and/or (BType: GrantFiled: December 16, 2011Date of Patent: January 10, 2017Assignee: ALLNEX BELGIUM S.A.Inventors: Michel Tielemans, Jurgen Van Holen, Marc Decaux, Jean-Yves Salviato
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Patent number: 9534085Abstract: An ene-thiol based curable composition according to the present invention includes: (A) a thiol compound having two or more groups represented by a following general formula (1) in the molecule; and (B) an ene oligomer having an alicyclic or aromatic ring structure and two or more ethylenically unsaturated groups in the molecule, with a number average molecular weight of 500 to 20,000 in terms of polystyrene. In the following general formula (1), each of R1 and R2 independently represents a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, or an aromatic group having 6 to 10 carbon atoms; a is an integer of 0 to 2; and b is 0 or 1.Type: GrantFiled: June 11, 2014Date of Patent: January 3, 2017Assignee: SHOWA DENKO K.K.Inventors: Asuka Toda, Akira Shibuya
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Patent number: 9006306Abstract: In one aspect, the invention relates to crosslinkable, flame retardant polymer compositions are provided comprising a polyamide or polyester; a flame retardant system; a crosslinking agent; and a flame retardant system coagent. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: GrantFiled: May 24, 2013Date of Patent: April 14, 2015Assignee: SABIC Global Technologies B.V.Inventors: Domenico La Camera, Hendrik Kormelink, Jelena Bo{hacek over (z)}ović-Vukić, Yohana Pérez
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Patent number: 9000090Abstract: The present invention relates to processes for making synthetic polyisoprene latex and synthetic polyisoprene condoms. A process for making a compounded synthetic polyisoprene latex suitable for making a latex film comprises (a) compounding a synthetic polyisoprene latex with suitable compounding ingredients, (b) maturing the latex and optionally (c) storing the latex; characterized in that steps (a), (b) and (c) if included are carried out at a low temperature so as to minimize prevulcanization of the latex. Condoms can be made from latexes produced according to the process of the invention.Type: GrantFiled: March 12, 2007Date of Patent: April 7, 2015Assignee: LRC Products LimitedInventors: Julie Attrill, Melissa Jane Ballard, Eman Alsaffar
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Patent number: 8999323Abstract: The present invention relates to a polymerization-curable composition for the preparation of biodegradable, biocompatible, cross-linked polymers on the basis of polyvinyl alcohol comprising: 5 to 100% by weight of (a) vinyl ester monomer(s) of one of the general formulas (I) to (III): wherein X is oxygen, sulfur, nitrogen, or phosphorus; n is 1 to 1000, at least 20% of the n being ?2; the R1 are selected from hydrogen; straight, branched or cyclic, saturated or unsaturated, n-valent hydrocarbon groups having 1 to 30 carbon atoms, which optionally have heteroatoms and are optionally substituted with one or more substituents selected from —OH, —COON, —CN, —CHO, and ?O, and n-valent radicals of biodegradable, biocompatible oligomers and polymers; m is an integer from 1 to 5; the R2 are selected from hydrogen, —OH, ?O, and the options listed for R1; and the R3 are selected from hydrogen, —OH, and the options listed for R1; 0 to 50% by weight of ethylenically unsaturated co-monomers; 0 to 10% by weight of (a)Type: GrantFiled: November 21, 2008Date of Patent: April 7, 2015Assignee: Technische Universität WienInventors: Robert Liska, Jürgen Stampfl, Franz Varga, Heinrich Gruber, Stefan Baudis, Christian Heller, Monika Schuster, Helga Bergmeister, Günter Weigel, Claudia Dworak
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Patent number: 8980406Abstract: In one aspect, inks for use with a 3D printer are described herein. In some embodiments, an ink comprises a polymerizable material and a reactive wax comprising a saturated alkyl moiety bonded to an ethyleneically unsaturated moiety through a urethane, urea, ester, or carbonate ester linkage, wherein the ink is free or substantially free of non-reactive wax.Type: GrantFiled: August 28, 2012Date of Patent: March 17, 2015Assignee: 3D Systems, Inc.Inventor: Pingyong Xu
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Patent number: 8940808Abstract: Disclosed is a curable coating agent composition which exhibits excellent wear resistance and weather resistance when applied as a coating agent to plastic or other substrates to be used outdoors. The curable coating agent composition comprises 95 to 65 parts by mass of a component (A) comprising an urethane adduct compound having weather resistance, 5 to 35 parts by mass of a component (B) comprising a specific organosilicon compound, 0.1 to 10 parts by mass of a component (C) which is a radical polymerization initiator, 1 to 12 parts by mass of a component (D) which is an ultraviolet ray absorber, and 10 to 1,000 parts by mass of a component (E) which is an organic solvent, with respect to 100 parts by mass of the components (A) and (B) in total.Type: GrantFiled: October 13, 2010Date of Patent: January 27, 2015Assignees: Kabushiki Kaisha Toyota Jidoshokki, Toagosei Co., Ltd.Inventors: Tetsuya Mitsuoka, Hidetaka Hayashi, Toshihisa Shimo, Kyoko Kumagai, Naoharu Ueda, Kazumasa Inata, Takeshi Fujita, Yasuyuki Sanai, Eiichi Okazaki, Hiroshi Suzuki, Naomasa Furuta
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Patent number: 8932419Abstract: Disclosed is a urethane (meth)acrylate oligomer which is obtained by reacting at least one polyoxyalkylene polyol (A), at least one monool (B1) soluble in the component (A) and/or at least one silane coupling agent (B2) reactive with an isocyanate group, at least one polyisocyanate (C) and at least one hydroxylated mono (meth)acrylate compound (D) at a ratio at which the equivalent weights of hydroxy groups, active hydrogen groups and isocyanate groups in the respective components satisfy the following formulae (1)-(3). The urethane (meth)acrylate oligomer does not substantially contain an unreacted isocyanate group. B(active hydrogen)+D(OH)=C(NCO)?A(OH) (1) 1.05?C(NCO)/A(OH)?2 (2) {C(NCO)?2A(OH)+2m}×0.35?D(OH)?{C(NCO)?2A(OH)+2m}×0.Type: GrantFiled: December 31, 2013Date of Patent: January 13, 2015Assignee: Hitachi Chemical Company, Ltd.Inventors: Yoshinobu Ogawa, Kazutoshi Doki, Osamu Kawata, Yoshihiro Tani
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Patent number: 8927615Abstract: A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.Type: GrantFiled: May 8, 2013Date of Patent: January 6, 2015Assignees: Immunolight, LLC, Duke UniversityInventors: Frederic Avery Bourke, Jr., Tuan Vo-Dinh
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Patent number: 8921447Abstract: The invention provides a process for manufacturing a polymeric material having a compositional gradient, comprising: forming a mixture comprising a first photopolymerizable polymer precursor and a second photopolymerizable precursor, and subjecting said mixture to an intensity gradient of electromagnetic radiation, wherein said first precursor has a greater reactivity ratio than said second precursor, and/or said first precursor is mono-functional and said second precursor is di-functional, and/or said first precursor is less inhibited by oxygen than said second precursor.Type: GrantFiled: April 8, 2011Date of Patent: December 30, 2014Assignee: The University of Iowa Research FoundationInventors: Clinton J. Cook, C. Allan Guymon
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Publication number: 20140374884Abstract: To provide a photo-curable composition for imprints which can ensure high ratio of mold filling and low defect density during mold releasing, and can provide a resist material with high etching durability. A photo-curable composition for imprints comprising a monofunctional monomer, a polyfunctional monomer and a photo-polymerization initiator, having a viscosity at 25° C. of 15 mPa·s or smaller, an Ohnishi parameter of 3.0 or smaller, and a crosslink density calculated by (Formula 1) of 0.6 mmol/cm3 or larger; Crosslink density={?(Ratio of mixing of polyfunctional monomer (parts by mass)*Number of functional groups of polyfunctional monomer/Molecular weight of polyfunctional monomer)}/Specific gravity.Type: ApplicationFiled: September 11, 2014Publication date: December 25, 2014Applicant: FUJIFILM CorporationInventors: Hirotaka KITAGAWA, Masafumi YOSHIDA
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Publication number: 20140341524Abstract: A coating composition including a reinforcing agent. The coating composition may include one or more radiation-curable monofunctional monomers, one or more radiation-curable multifunctional monomers or oligomers, a photoinitiator, and a reinforcing agent. The monofunctional monomers, multifunctional monomers, and multifunctional oligomers may include acrylate groups. The reinforcing agent may be an acrylic co-polymer that includes two or more repeat units. At least one of the repeat units includes chemical groups that enable self-association of the acrylic co-polymer. Self-association of the acrylic co-polymer may improve the tensile strength of coatings formed from the coating compositions.Type: ApplicationFiled: April 9, 2014Publication date: November 20, 2014Applicant: Corning IncorporatedInventors: Dana Craig Bookbinder, Michelle Dawn Fabian, Kevin Robert McCarthy, Weijun Niu, David Neal Schissel, Michael James Winningham
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Patent number: 8889759Abstract: An object to be attained by the present invention is to provide an active energy ray-curable composition that is capable of producing a cured coating film having high scratch resistance and excellent transparency. The present invention relates to an active energy ray-curable composition containing a reactive particle (A) obtained by reacting a silica fine particle (a-1) and a hydrolysable silane (a-2) having one or more (meth)acryloyloxy groups and one or more isocyanurate ring structures in a molecule. The present invention also provides the active energy ray-curable composition according to the above, containing a photopolymerization initiator (B).Type: GrantFiled: January 5, 2011Date of Patent: November 18, 2014Assignee: Kansai Paint Co., Ltd.Inventors: Yoshinari Matsuura, Akinori Nagai, Atsuya Kato
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Patent number: 8877871Abstract: There is provided a switching element including two electrodes and an organic bistable material sandwiched between the electrodes, which is expected to be applied to an organic memory element or the like. A switching element which includes: two electrodes; and an organic thin film containing a metal fine particle and interposed between the electrodes, and which exhibits such a current bistability that the switching element has two stable resistance values in response to a voltage applied, the switching element characterized in that the metal fine particle is dispersed in the organic thin film with a metal fine particle-dispersing agent containing a polymer having a dithiocarbamate group and having a weight average molecular weight of 500 to 5,000,000.Type: GrantFiled: September 1, 2008Date of Patent: November 4, 2014Assignees: Kyushu University, Nissan Chemical Industries, Ltd.Inventors: Katsuhiko Fujita, Kei Yasui, Masaaki Ozawa, Keisuke Odoi, Hisashi Ichikawa
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Publication number: 20140309327Abstract: [PROBLEM] The present invention provides an acrylic resin composition, which has low viscosity and can be cured even by an LED irradiation device with low illuminance, and which provides a cured product with adequate peel strength without addition of an additive for forced peeling, wherein the cured product has both toughness and bendability.Type: ApplicationFiled: October 30, 2012Publication date: October 16, 2014Inventors: Yasutoshi Nogami, Takanori Wachi
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Patent number: 8859633Abstract: Provided are a temporal fixation method in processing of optical members and a resin composition suitable therefore, which uses a composition which is characterized by containing the following (A3), (B3) and (D3), wherein (A3) is a urethane(meth)acrylate; (B3) is one or more (meth)acrylic acid derivative monomers selected from the group consisting of n-(meth)acryloyloxyalkyl hexahydrophthalimides, carboxyl group-containing (meth)acrylates and (meth)acrylic acid derivative monomers represented by the formula (C3): Z—O—(R2O)p—R1??Formula (C3): wherein Z represents a (meth)acryloyl group, R1 represents a phenyl group or a phenyl group having an alkyl group with 1 to 3 carbon atoms, R2 represents —C2H4—, —C3H6—, —CH2CH(CH3)—, —CH2CH(OH)CH2—, —C4H8— or —C6H12—, and p represents an integer of from 1 to 10; and D(3) is a photopolymerization initiator, along with methods for temporarily fixing a member.Type: GrantFiled: July 7, 2011Date of Patent: October 14, 2014Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Kazuhiro Oshima, Tomoyuki Kanai, Kunio Iriuchijima
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Patent number: 8859636Abstract: An ink composition includes: (Component a) a polymerizable compound having an ethylenically unsaturated double bond; (Component b) a polymerization initiator; (Component c) water; and (Component d) a polyhydric alcohol having an alkyleneoxy chain, wherein the (Component a) polymerizable compound includes a monofunctional polymerizable monomer having a (meth)acrylamide structure, and a content of the monofunctional polymerizable monomer is 5% by mass or more with respect to a total content of the (Component a) polymerizable compound.Type: GrantFiled: November 18, 2011Date of Patent: October 14, 2014Assignee: FUJIFILM CorporationInventors: Toshihiro Kamada, Takahiro Kato
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Patent number: 8859634Abstract: This invention relates to a photo-curing or electron beam-curing adherent resin composition being excellent in the adhesiveness to various adherends such as metal oxide, metal, resin and so on, and more particularly to an adherent resin composition of a photo-curing or electron beam-curing type comprising a difunctional urethane (metha)acrylate oligomer (A) and a monomer component (B), characterized in that the urethane (metha)acrylate oligomer includes a urethane prepolymer portion composed of a polyol and a polyisocyanate wherein repetitive number of urethane prepolymer portion (n) is 10-30, and the monomer component (B) is a cyclic monomer having a (metha)acryloyl group.Type: GrantFiled: December 9, 2008Date of Patent: October 14, 2014Assignee: BRIDGESTONE CorporationInventors: Junji Sakata, Hajime Kitano, Hiroyuki Kanesugi
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Patent number: 8853338Abstract: Presently described are curable dental compositions comprising a polymerizable ionic liquid. The polymerizable ionic liquid comprises one or more ethylenically unsaturated (e.g. free-radically polymerizable) groups. Various embodiments of curable dental compositions are described. In some embodiments, the polymerizable ionic liquid is a monofunctional polymerizable ionic liquid comprising an ethylenically unsaturated group. In other embodiments, the polymerizable ionic liquid is a multifunctional polymerizable ionic liquid comprising at least two ethylenically unsaturated groups. The curable dental compositions describe herein can be utilized as dental primers, dental adhesives, dental sealants, and dental composites. In many embodiments, the curable dental compositions further comprise an initiator such as a photoinitiator.Type: GrantFiled: December 6, 2010Date of Patent: October 7, 2014Assignee: 3M Innovative Properties CompanyInventors: Yizhong Wang, Joel D. Oxman, Larry R. Krepski, Peiwang Zhu, Kevin M. Lewandowski, Brian N. Holmes
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Patent number: 8841064Abstract: Disclosed are a positive photosensitive resin composition that includes (A) an alkali soluble resin; (B) a dissolution controlling agent including the compound represented by Chemical Formula 6; (C) a photosensitive diazoquinone compound; (D) a silane compound; and (E) a solvent, and a photosensitive resin film prepared by using the same.Type: GrantFiled: November 11, 2011Date of Patent: September 23, 2014Assignee: Cheil Industries Inc.Inventors: Myoung-Hwan Cha, Jong-Hwa Lee, Mi-Ra Im, Min-Kook Chung, Ji-Young Jeong, Hyun-Yong Cho, Hwan-Sung Cheon
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Patent number: 8840769Abstract: A catalyst precursor resin composition includes an organic polymer resin; a fluorinated-organic complex of silver ion; a monomer having multifunctional ethylene-unsaturated bonds; a photoinitiator; and an organic solvent. The metallic pattern is formed by forming catalyst pattern on a base using the catalyst precursor resin composition reducing the formed catalyst pattern, and electroless plating the reduced catalyst pattern. In the case of forming metallic pattern using the catalyst precursor resin composition, a compatibility of catalyst is good enough not to make precipitation, chemical resistance and adhesive force of the formed catalyst layer are good, catalyst loss is reduced during wet process such as development or plating process, depositing speed is improved, and thus a metallic pattern having good homogeneous and micro pattern property may be formed after electroless plating.Type: GrantFiled: July 23, 2013Date of Patent: September 23, 2014Assignee: LG Chem, Ltd.Inventors: Min Kyoun Kim, Min Jin Ko, Sang Chul Lee, Jeong Im Roh
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Patent number: 8835530Abstract: A glass printing ink and glass printing lacquer are prepared, which contain at least one photoinitiator, at least one resin and at least one additional substance. The resin is an epoxy resin based on bisphenol A, diluted in a UV-curing monomer, or a resin with functional groups containing free functional amino, hydroxy, epoxy, acid, acid anhydride and/or acrylate groups, or a combination of the epoxy resin with the resin with functional groups. The at least one additional substance is a wax. The use of the glass printing ink and glass printing lacquer in printing a glass substrate and processes for the printing of a glass substrate are also described.Type: GrantFiled: January 4, 2007Date of Patent: September 16, 2014Assignee: Marabu GmbH & Co., KGInventors: Wolfgang Schaefer, Dimitrios Triantafillidis
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Patent number: 8822562Abstract: Ink deposited on a substrate by an ink-jet arrangement to form a protective layer includes hardenable oligomer, hardenable monomer selected from a group including alkoxylated and/or poly-alkoxylated acrylic monomers comprising one or more di- or tri-acrylates, and a photoinitiator. The oligomer has a room temperature viscosity greater than 1 Pa·s. The oligomer to monomer weight ratio is between 1/6 and 1/25. The ink has a room temperature viscosity between 15 and 22 mPa·s and between 5 and 2 mPa·s at 60° C., and a room temperature surface tension between 15 and 28 mN/m. The photoinitiator is activated by a UV source having an appropriate wavelength and intensity.Type: GrantFiled: December 30, 2009Date of Patent: September 2, 2014Assignee: M.G.I. USA, Inc.Inventor: Edmond Abergel
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Patent number: 8822563Abstract: Disclosed is a curable resin composition comprising a polymer (A) that has a main chain comprising carbon atoms and a side chain having a polymerizing unsaturated linking group and has a cyclic structure in the main chain and/or the side chain, and a compound having a polymerizing unsaturated group. The curable resin composition has good optical characteristics, good heat resistance and good moldability.Type: GrantFiled: January 18, 2013Date of Patent: September 2, 2014Assignee: FUJIFILM CorporationInventors: Hiroaki Mochizuki, Naoyuki Morooka, Rie Okutsu, Tatsuhiko Obayashi
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Publication number: 20140240414Abstract: To provide a photopolymerizable inkjet ink, which contains photopolymerizable monomers containing at least one selected from the following compound group (A) compounds of which are negative for skin sensitization, and at least one selected from the following compound group (B) compounds of which are negative for skin sensitization, wherein the compound group (A) is a compound group consisting of caprolactone-modified dipentaerythritol hexaacrylate, polyethoxylated tetramethylol methane tetraacrylate, ethylene oxide-modified bisphenol A diacrylate, caprolactone-modified hydroxy pivalic acid neopentyl glycol diacrylate, polypropylene glycol diacrylate [CH2?CH—CO—(OC3H6)n-OCOCH?CH2 (n?12)], hydroxyethyl acryl amide, trimethylol propane trimethacrylate, and tricyclodecane dimethanol dimethacrylate, and the compound group (B) is a compound group consisting of ethylene oxide-modified phenolacrylate, isostearyl acrylate, ethylene oxide-modified trimethylol propane trimethacrylate, stearyl methacrylate, and glycerinType: ApplicationFiled: October 30, 2012Publication date: August 28, 2014Inventor: Takao Hiraoka
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Publication number: 20140239527Abstract: A composition includes a light-curable viscous mixture that includes: 0-50% by weight of a poly(methyl methacrylate)/methyl methacrylate solution; 5-20% by weight of at least one kind of multifunctional aliphatic (meth)acrylate; 5-40% by weight of at least one kind of aliphatic urethane (meth)acrylate oligomer; 25-65% by weight of at least one kind of difunctional bisphenol-A dimethacrylate; 0.1 to 5% by weight of at least one kind of a photoinitiator; 0.05 to 2% by weight of at least one kind of light stabilizer; and 0.1 to 3% by weight of color pigment based on the total weight of the composition.Type: ApplicationFiled: April 25, 2014Publication date: August 28, 2014Applicant: DENTCA, INC.Inventor: Jae Sik LEE
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Patent number: 8816029Abstract: Presently described are curable compositions comprising a mixture of at least one (e.g. free-radically) polymerizable ionic liquid and at least one other ethylenically unsaturated monomer, oligomer, or polymer. The polymerizable ionic liquid is characterized as having an air to nitrogen curing exotherm ratio of at least 0.70. Also described are articles and methods of making articles from such curable compositions. A monofunctional polymerizable ionic liquid is also described comprising a non-polymerizable substituted imidazolium cationic group and a polymerizable sulfonate anion.Type: GrantFiled: August 26, 2010Date of Patent: August 26, 2014Assignee: 3M Innovative Properties CompanyInventors: Yizhong Wang, Joel D. Oxman, Larry R. Krepski, Peiwang Zhu, Kevin M. Lewandowski, Brian N. Holmes, Richard L. Severance, Joseph D. Rule, Thomas P. Klun
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Patent number: 8815970Abstract: A method of preparing polyurethane prepolymer does not require using a toxic isocyanate monomer (manufactured by harmful phosgene) as a raw material. Epoxy resin and carbon dioxide are used as major raw materials to form cyclic carbonates to be reacted with a functional group oligomer, and then amino groups in a hydrophilic (ether group) or hydrophobic (siloxane group) diamine polymer are used for performing a ring-opening polymerization, and the microwave irradiation is used in the ring-opening polymerization to efficiently synthesize the amino-terminated PU prepolymer, and then an acrylic group at an end is added to manufacture an UV cross-linking PU (UV-PU) oligomer which can be coated onto a fabric surface, and the fabric is dried by UV radiation for a surface treatment to form a washing-resisted long lasting hydrophilic or hydrophobic PU fabric.Type: GrantFiled: September 22, 2011Date of Patent: August 26, 2014Assignee: Tamkang University (A University of Taiwan)Inventors: Jing-Zhong Hwang, Guei-Jia Chang, Jhong-Jheng Lin, Cheng-Wei Tsai, Shih-Chieh Wang, Po-Cheng Chen, Kan-Nan Chen, Kan-Nan Chen
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Publication number: 20140163132Abstract: The present invention relates to a radiation curable coating composition comprising a radiation curable oligomer comprising a backbone derived from polypropylene glycol and a dimer acid based polyester polyol, wherein said coating composition, when cured, is having: a) a hardening temperature (Th) of from ?10° C. to about ?20° C. and a modulus measured at said Th of lower than 5.0 MPa; or b) a hardening temperature (Th) of from ?20° C. to about ?30° C. and a modulus measured at said Th of lower than 20.0 MPa; or c) a hardening temperature (Th) of lower than about ?30° C. and a modulus measured at said Th of lower than 70.0 MPa.Type: ApplicationFiled: October 1, 2013Publication date: June 12, 2014Applicant: DSM IP ASSETS B.VInventors: Sandra Joanna NAGELVOORT, Johannes Adrianus VAN EEKELEN, Adrianus Gijsbertus Maria ABEL, Gouke Dirk-Jan GEUS, Duurt Pieter Willem ALKEMA, Giacomo Stefano ROBA, Marco ARIMONDI, Lidia TERRUZZI, Sabrina FOGLIANI
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Publication number: 20140148525Abstract: There are provided a radical polymerizable composition having a low viscosity suitable for coating, a cured product obtained by curing the composition, the cured product having a high refractive index and high toughness and being not easily cracked or chipped when cutting, and a plastic lens obtained by curing the composition. A radical polymerizable composition includes phenylbenzyl(meth)acrylate (A), a urethane(meth)acrylate (X) having an aromatic ring in its molecular structure, and a radical polymerization initiator (Y) as essential components.Type: ApplicationFiled: March 12, 2012Publication date: May 29, 2014Applicant: DIC CORPORATIONInventors: Nobuo Kobayashi, Akihiro Kondo, Atsuhisa Miyawaki, Naoya Ikushima, Kazuaki Hatsusaka
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Publication number: 20140128496Abstract: Provided is an ultraviolet-curable ink jet ink composition with excellent curability and storage stability, the composition containing a monomer A represented by Formula (I): CH2?CR1—COOR2—O—CH?CH—R3 (wherein R1 represents a hydrogen atom or a methyl group, R2 represents a C2-C20 divalent organic residue, and R3 represents a hydrogen atom or a C1-C11 monovalent organic residue); a (meth)acrylated amine compound; a hindered amine compound other than the (meth)acrylated amine compound; and a photopolymerization initiator.Type: ApplicationFiled: January 15, 2014Publication date: May 8, 2014Applicant: Seiko Epson CorporationInventors: Hiroaki KIDA, Chigusa SATO, Hiroyuki KAJIMOTO, Toru SAITO
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Patent number: 8709552Abstract: The resin composition of the present invention is a resin composition characterized by including (a) a polyimide, a polybenzoxazole, a polyimide precursor or a polybenzoxazole precursor, (b) 1,5-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, or 2,3-dihydroxynaphthalene, and (c) a thermal cross-linking agent having a specific structure. By the use of the resin composition of the present invention, it is possible to reduce the transmittance in the visible region of a cured film while maintaining the transmittance of a resin film before curing.Type: GrantFiled: January 15, 2010Date of Patent: April 29, 2014Assignee: Toray Industries, Inc.Inventors: Kazuto Miyoshi, Mika Koshino, Masao Tomikawa
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Patent number: 8710113Abstract: The invention relates to a dental composition comprising a) a compound (A) with the following features: only one backbone unit (U) with 6 to 20 carbon atoms, at least 6 carbon atoms thereof forming an aromatic or an aliphatic cyclic moiety, the remaining carbon atoms either being part of substituents pending from the cyclic moiety or being part of bridging groups to spacer units, wherein one or more of the remaining carbon atoms can be replaced by an oxygen atom, the backbone unit not comprising a bisphenol structure and halogen atoms, one or two unit(s) (S) being connected to the backbone unit (U) via an ether linkage, at least one unit (S) comprising a —CH2-CH2-CH2-CH2-O—CH2-CH(Q)-OG moiety or a —CH2-CH(OG)-CH2-OM moiety or a mixture of these two types of moieties within one unit (S), with G comprising at least one polymerizable moiety and an urethane moiety, the urethane moiety acting as connecting element to unit(s) (S), and M comprising at least one group selected from acroyl, methacroyl, aryl, mixturesType: GrantFiled: June 24, 2011Date of Patent: April 29, 2014Assignee: 3M Innovative Properties CompanyInventors: Adrian S. Eckert, Michael M. Cub, Bettina Hailand, Marion B. Kestel, Karsten Dede, Uwe H. Hoheisel, Gioacchino Raia, Christoph Thalacker, Reinhold Hecht, Thomas Luchterhandt, Peter Bissinger, Wolf Steiger
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Patent number: 8673994Abstract: The present invention provides: an ink composition which contains at least a polymerizable compound, a photopolymerization initiator and a coloring material, and is free from an aqueous solvent, wherein the polymerizable compound comprises at least a urethane oligomer; a two-pack curing ink composition set comprising an ink composition containing a coloring material and a reaction liquid containing a photopolymerization initiator and capable of forming an image with an ink composition obtained by mixing the ink composition and the reaction liquid, wherein the ink composition after mixing contains at least a polymerizable compound, a photopolymerization initiator and a coloring material, and is free from an aqueous solvent, wherein the polymerizable compound comprises a urethane oligomer.Type: GrantFiled: August 3, 2011Date of Patent: March 18, 2014Assignee: Seiko Epson CorporationInventors: Keitaro Nakano, Takashi Oyanagi
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Patent number: 8658738Abstract: A curable resin composition, comprising 100 parts by mass of a (meth)acrylic polymer (A) having, at a terminal thereof, at least one crosslinkable silyl group; 0.1 to 100 parts by mass of a diamine compound (B) having a monovalent or bivalent aliphatic or alicyclic hydrocarbon group that has 8 or more carbon atoms and may be branched and having at least one primary amino group; and 0.1 to 100 parts by mass of a diamine compound (C) having a monovalent aliphatic or alicyclic hydrocarbon group that has 8 or more carbon atoms and may be branched, and having a crosslinkable silyl group and/or a (meth)acryloyl group.Type: GrantFiled: June 24, 2009Date of Patent: February 25, 2014Assignee: Kaneka CorporationInventors: Jun Kotani, Nobuyuki Kobayashi, Hiroyuki Hosoda, Kazunori Ishikawa
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Patent number: 8637945Abstract: A component having a robust, but acoustically sensitive microphone structure is provided and a simple and cost-effective method for its production. This microphone structure includes an acoustically active diaphragm, which functions as deflectable electrode of a microphone capacitor, a stationary, acoustically permeable counter element, which functions as counter electrode of the microphone capacitor, and an arrangement for detecting and analyzing the capacitance changes of the microphone capacitor. The diaphragm is realized in a diaphragm layer above the semiconductor substrate of the component and covers a sound opening in the substrate rear. The counter element is developed in a further layer above the diaphragm. This further layer generally extends across the entire component surface and compensates level differences, so that the entire component surface is largely planar according to this additional layer.Type: GrantFiled: April 7, 2010Date of Patent: January 28, 2014Assignee: Robert Bosch GmbHInventors: Frank Reichenbach, Thomas Buck, Jochen Zoellin, Franz Laermer, Ulrike Scholz, Kathrin van Teeffelen, Christina Leinenbach
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Patent number: 8603451Abstract: The present invention relates to compositions of cyanoacrylate monomer, a method of improving the viscosity and the curing speed with a single additive and a process of providing sterilized cyanoacrylate adhesive compositions for application in the medical field.Type: GrantFiled: May 22, 2012Date of Patent: December 10, 2013Assignee: Adhezion Biomedical, LLCInventors: Sheng Zhang, Rafael Ruiz
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Publication number: 20130324635Abstract: A dental curable composition includes: a radically polymerizable monomer; a polymerization initiator; and a hyperbranched polymer, in which the hyperbranched polymer includes a unit structure represented by the general formula (I) and unit structures represented by the general formula (IIA) and/or the general formula (IIB) (in the general formula (I), A represents a single bond for bonding C and R1, >C?O, —O—, or —COO—, R1 represents a divalent saturated aliphatic hydrocarbon group or a divalent aromatic hydrocarbon group, and R2 represents a hydrogen atom or a methyl group; and in the general formula (IIA) and the general formula (IIB), R3, R4, and R5 each represent a hydrogen atom, an alkyl group, an alkoxycarbonyl group, an aryl group, or a cyano group, and R6 represents an alkylene group).Type: ApplicationFiled: February 10, 2012Publication date: December 5, 2013Applicant: TOKUYAMA DENTAL CORPORATIONInventors: Tomonao Shimizu, Tatsuya Yamazaki, Hideki Kazama, Hironobu Akizumi
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Patent number: 8597786Abstract: The present invention relates to a pressure-sensitive adhesive composition including, as a main ingredient, a monomer mixture or an acrylic copolymer material obtained by at least partially polymerizing the monomer mixture, the monomer mixture including: at least one monomer (monomer m1) selected from alkyl (meth)acrylates represented by the following formula (I) CH2?C(R1)COOR2 in which R1 is a hydrogen atom or a methyl group, and R2 is an alkyl group having 1 to 20 carbon atoms: at least one monomer (monomer m2) selected from N-hydroxyalkyl(meth)acrylamides represented by the following formula (II) CH2?C(R1)CONHR4 in which R3 is a hydrogen atom or a methyl group, and R4 is a hydroxyalkyl group having 2 to 4 carbon atoms: and at least one monomer (monomer m3) selected from N-vinyl cyclic amides and (meth)acrylamides that may have an N-alkyl group; and the monomer mixture including substantially no carboxyl group-containing monomer.Type: GrantFiled: May 21, 2009Date of Patent: December 3, 2013Assignee: Nitto Denko CorporationInventors: Masahito Niwa, Masayuki Okamoto, Naoaki Higuchi
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Patent number: 8598250Abstract: The present invention relates to a photocurable acrylic viscoelastic material composition including: an acrylic monomer mixture containing an alkyl (meth)acrylate as a main monomer component and a polar group-containing vinyl monomer, or a partial polymerization product thereof; a (meth)acrylate compound having at least one isocyanate group within the molecule thereof; and a photopolymerization initiator. The photocurable acrylic viscoelastic material composition of the present invention has, by virtue of the above-described construction, excellent pot life and excellent storage stability, despite containing an isocyanate compound having at least one isocyanate group within the molecule thereof, and further can form an acrylic viscoelastic material excellent in the holding power at high temperatures through photocuring. Also, the acrylic viscoelastic material and acrylic viscoelastic material layer tape or sheet of the present invention is excellent in the holding power at high temperatures.Type: GrantFiled: January 22, 2009Date of Patent: December 3, 2013Assignee: Nitto Denko CorporationInventors: Akira Hirao, Kunio Nagasaki, Kazuhisa Maeda
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Publication number: 20130309411Abstract: The present invention provides a birefringent lens material for a stereoscopic image display, the birefringent lens material containing two or more liquid crystal compounds each having at least one polymerizable functional group, a birefringent lens for a stereoscopic image display, the birefringent lens being formed by using the lens material, and a method for producing a birefringent lens for a stereoscopic image display using the lens material. The birefringent lens material for a stereoscopic image display and the birefringent lens for a stereoscopic image display of the present invention are good in terms of optical characteristics, durability, and productivity, in particular, productivity. The method for producing a birefringent lens for a stereoscopic image display of the present invention has good productivity.Type: ApplicationFiled: December 20, 2011Publication date: November 21, 2013Applicant: DIC CORPORATIONInventors: Yasuhiro Kuwana, Hiroshi Hasebe
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Patent number: 8580143Abstract: The present invention relates to a lyotropic chromonic liquid crystal composition, a method for manufacturing a lyotropic chromonic liquid crystal coating film and a lyotropic chromonic liquid crystal coating film manufactured thereby. The lyotropic chromonic liquid crystal composition of the present invention includes chromonic liquid crystal compounds and monomers each having opposing acid-base properties. Use of the lyotropic chromonic liquid crystal composition in the formation of optical films leads to improvements in electrical and optical properties such as mechanical strength, an insulating characteristic and a refractive index.Type: GrantFiled: November 5, 2009Date of Patent: November 12, 2013Assignees: Korea Institute of Industrial Technology, Industrial Cooperation Foundation Chonbuk National UniversityInventors: Seung Han Shin, Eu Gene Chang, Myong Hoon Lee, Kwang Un Jeong, Yun Ju Bae
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Patent number: 8575228Abstract: An agent comprising a substituted aromatic azo compound is capable of making a liquid surface express anisotropy in a simplified manner.Type: GrantFiled: June 4, 2012Date of Patent: November 5, 2013Assignee: FUJIFILM CorporationInventors: Kazuhiro Oki, Michitaka Matsuumi, Mitsuyoshi Ichihashi
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Patent number: 8551687Abstract: The present invention relates to a polyimide photosensitive resin composition that is capable of being developed by an alkali aqueous solution, and a dry film that is produced by the same, and more particularly to a photosensitive resin composition which comprises a) a polyamic acid, b) two or more (meth)acrylate—based compounds that include one or more double bonds between carbons, c) a photopolymerization initiator, d) a phosphorus—based flame retardant, and e) an organic solvent, and a dry film that is produced by the same.Type: GrantFiled: August 20, 2008Date of Patent: October 8, 2013Assignee: LG Chem, Ltd.Inventors: Kwang-Joo Lee, Heon-Sik Song, You-Jin Kyung, Joo-Eun Ko, Jung-Il Yoon, Jung-Jin Shim
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Patent number: 8552130Abstract: Presently described are polymerizable ionic liquids comprising a cation and an aromatic carboxylate anion; wherein the cation, anion, or both comprise a free-radically polymerizable group. Also described are curable compositions comprising such polymerizable ionic liquids and at least one other free-radically polymerizable monomer, oligomer, or polymer.Type: GrantFiled: May 16, 2011Date of Patent: October 8, 2013Assignee: 3M Innovative Properties CompanyInventors: Kevin M. Lewandowski, Yizhong Wang, Larry R. Krepski, Joel D. Oxman, Peiwang Zhu
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Patent number: 8552088Abstract: A cement for dental use, containing a first agent and a second agent, wherein both of the first agent and the second agent contain a polymerizable monomer (a) and a filler (b), wherein the first agent and/or the second agent further contains a photopolymerization initiator (c), wherein further as a chemical polymerization initiator (d), either one of the first agent and the second agent contains an oxidizing agent (f) and the other contains a reducing agent (g), the oxidizing agent (f) and the reducing agent (g) constituting a redox polymerization initiator, wherein the photopolymerization initiator (c) contains an ?-diketone, and the photopolymerization initiator (c) is contained in a total amount of from 0.010 to 0.100 parts by weight, based on 100 parts by weight of the total amount of the polymerizable monomer (a), wherein the chemical polymerization initiator (d) is contained in a total amount of from 0.Type: GrantFiled: December 25, 2008Date of Patent: October 8, 2013Assignee: Kuraray Noritake Dental Inc.Inventors: Hiroki Shinoda, Mitsuru Takei, Hidemi Nakayama
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Publication number: 20130245153Abstract: A process of forming microcapsules is described. The microcapsule population is formed by providing an anionic or cationic, solid hydrophilic core material; providing an oil continuous phase, the oil continuous phase comprising one or more esters with chain length up to about 18 carbons. Emulsification is achieved by subjecting the mixture to high shear agitation and heating the mixture for a time sufficient to enable acid or amine acrylate or methacrylate and multifunctional acrylate or methacrylate to form a prepolymer which migrates to the anionic or cationic solid hydrophilic material, thereby forming prepolymers adhered to the hydrophilic core materials. Temperature is held or heating continued for a time sufficient to enable the prepolymer to flow onto and coalesce into a continuous film surface coating on the hydrophilic core material. Heating is carried out or light exposure or both for a time and temperature sufficient to cross link the prepolymers.Type: ApplicationFiled: April 17, 2013Publication date: September 19, 2013Inventor: Todd Arlin Schwantes