Nitrogen Containing Reactant Contains A N-c=o Or N-c=o Moiety Patents (Class 522/174)
  • Patent number: 10338408
    Abstract: Described herein is a cost-effective and time-efficient method for making UV-absorbing contact lenses. In contrast to the conventional method for making UV-absorbing contact lenses which involves copolymerizing a lens forming composition including a UV-absorbing vinylic monomer, a method of the invention involves dipping a contact lens in a solution of UV-absorbing polymer comprising carboxyl-containing monomeric units, UV-absorbing monomeric units and covalently bound radical-initiating moieties to form a UV-absorbing coating on the contact lens.
    Type: Grant
    Filed: December 16, 2013
    Date of Patent: July 2, 2019
    Assignee: Novartis AG
    Inventors: Harald Bothe, Peter Hagmann
  • Patent number: 10131820
    Abstract: The present invention relates to a pressure-sensitive adhesive composition, a protective film, an optical element, and a display device. A pressure-sensitive adhesive sheet formed using the pressure-sensitive adhesive composition according to the present invention can have proper high-speed and low-speed peel strengths and simultaneously can exhibit an excellent balance between the high-speed and low-speed peel strengths. The pressure-sensitive adhesive sheet formed using the pressure-sensitive adhesive composition according to one exemplary embodiment of the present invention exhibits a proper level of surface resistance and excellent electrostatic discharge characteristics, and has no contaminants with respect to an adherend even when the pressure-sensitive adhesive sheet is peeled from the adherend after the pressure-sensitive adhesive sheet is attached to the adherend for a long period of time.
    Type: Grant
    Filed: August 3, 2015
    Date of Patent: November 20, 2018
    Assignee: LG Chem, Ltd.
    Inventors: Sang Ha Son, Sung Soo Yoon, Kee Young Kim, Jeong Sik Bae
  • Patent number: 10066133
    Abstract: Provided are a pressure-sensitive adhesive composition, a protective film, an optical device, and a display device. The pressure-sensitive adhesive composition may exhibit excellent storage stability, suitable low speed and high speed peel-off strengths after forming a crosslinking structure, and have an excellent balance between them. Accordingly, the pressure-sensitive adhesive composition may exhibit an excellent protective effect when applied to a protective film, may be easily peeled in a high speed peel-off and thus advantageous for a high speed process, and may exhibit an excellent antistatic characteristic.
    Type: Grant
    Filed: June 19, 2014
    Date of Patent: September 4, 2018
    Assignee: LG Chem, Ltd.
    Inventors: Jeong Sik Bae, Sung Soo Yoon, Kee Young Kim
  • Patent number: 9631113
    Abstract: An UV- and thermally curable, solventborne clearcoat material suitable for automotive refinishing comprises: (A) at least one polyhydroxy-functional poly(meth)acrylate having grafted-on unsaturated (meth)acrylate side groups, (B) at least one polyisocyanate-functional, poly(meth)acrylate-functional aliphatic urethane, (C) at least one (meth)acrylate-functional aliphatic urethane free from isocyanate groups, (D) at least one hydroxy-functional, (meth)acrylate-functional aliphatic component free from isocyanate groups and from urethane groups and having a molecular weight of not more than 1000 g/mol and a (meth)acrylate functionality of at least 4, (E) at least one aliphatic polymercaptan, (F) at least one phosphoric acid or phosphonic acid blocked with an amine, the amine possessing a pKb of ?3 and a boiling point under atmospheric pressure of >100° C., and (G) at least one photoinitiator selected from the group consisting of ?-hydroxyalkyl phenyl ketones and monoacylphosphine oxides.
    Type: Grant
    Filed: July 4, 2013
    Date of Patent: April 25, 2017
    Assignee: BASF Coatings GmbH
    Inventors: Josef Rademacher, Egbert Nienhaus, Sibylle Schöps, Alexandra Steffens
  • Patent number: 9346941
    Abstract: A polycarbonate resin composition includes a polycarbonate resin, an inorganic filler, and a Tg regulator and can have improved appearance and flowability. The polycarbonate resin composition can be used as exterior materials for electronic devices such as cellular phones.
    Type: Grant
    Filed: December 11, 2014
    Date of Patent: May 24, 2016
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Eun Taek Woo, Jae Hyun Han, Eric Arifin, Jung Ki Kim, Jong Cheol Lim
  • Publication number: 20150148441
    Abstract: The present invention provides polymeric photoinitiators being co-polymers of photoinitiator monomers and at least one further monomer, as well as photoinitiator monomers being intermediates in the preparation of such polymeric photoinitiators. Additionally, there is provided polyacrylate obtained by radical polymerization of at least one acrylate monomer (Ac) in the presence of such polymeric photoinitiators. In the photoinitiator monomers and polymeric photoinitiators, a photoinitiator moiety, a hydrolytic stable linker and two polymerisable functional groups are incorporated into the photoinitiator structure.
    Type: Application
    Filed: May 14, 2013
    Publication date: May 28, 2015
    Inventors: Niels Joergen Madsen, Petr Sehnal, David George Anderson, Bo Rud Nielsen
  • Publication number: 20150138740
    Abstract: An integrated silicone for protecting electronic devices includes a base resin, a thermal initiator, and a photoinitiator.
    Type: Application
    Filed: November 10, 2014
    Publication date: May 21, 2015
    Inventors: Kyungjae SHIN, Kiwoong KIM
  • Patent number: 9034471
    Abstract: The invention relates to a powder resin with amp from 60 to 110° C., and a particle size from 10 to 250 ?m, which comprises the reaction product of a reactive composition comprising: a) an isocyanate component comprising a polyisocyanate with functionality of at least 2, b) an alcoholic component, comprising: b1) at least one polyol with OH functionality from 2 to 4, b2) a monoalcohol component comprising: b2.1) a monoalcohol, bearing an ethylenic unsaturation b2.2) a saturated alcohol selected from the group of fatty alcohols, b2.3) optionally, an additional saturated monoalcohol from non fatty monoalcohols the molar ratios of OH functional groups, of the said alcoholic components b2.2) (possibly b2.3)) and b2.1) being defined so that the OH molar ratio of b2.2)/b2.1) or of [b2.2)+b2.3)]/b2.1) ranges from higher than 0.
    Type: Grant
    Filed: September 6, 2011
    Date of Patent: May 19, 2015
    Assignee: Arkema Coatings Resins S.A.U.
    Inventors: Enrique Grau, Lluis Casadevall
  • Patent number: 9034941
    Abstract: The present invention relates to the use of polymeric photoinitiators based on polyalkyletherurethane backbones in the production of hydrophilic gels, in particular hydrogels. The invention relates to methods for manufacturing hydrophilic gels using said polymeric photoinitiators, and the hydrophilic gels thus obtained.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: May 19, 2015
    Assignee: Coloplast A/S
    Inventors: Christian B. Nielsen, Niels Joergen Madsen, David George Anderson, Petr Sehnal
  • Patent number: 9034937
    Abstract: A method of treating a surface of a substrate using modified urushiol derived from Toxicodendron vernicifluum is provided. More particularly, the reactivity of a hydroxyl group of urushiol extracted from fresh Toxicodendron vernicifluum is removed before the lacquer is used as a UV coating agent for a substrate such as a steel sheet. Therefore, the substrate may have high antibacterial activity, and excellent appearance and functionalities such as far-infrared radiation, blocking of electromagnetic waves, enhanced corrosion resistance, high crosslinking speed when a low content of a photoinitiator is used, excellent surface gloss and high scratch resistance.
    Type: Grant
    Filed: December 28, 2010
    Date of Patent: May 19, 2015
    Assignee: POSCO
    Inventors: Hye Jin Yoo, In Woo Cheong, Chang Se Byeon, Jae Ryung Lee, Jin Tae Kim, Jung Hwan Lee, Yang Ho Choi
  • Patent number: 9006306
    Abstract: In one aspect, the invention relates to crosslinkable, flame retardant polymer compositions are provided comprising a polyamide or polyester; a flame retardant system; a crosslinking agent; and a flame retardant system coagent. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Grant
    Filed: May 24, 2013
    Date of Patent: April 14, 2015
    Assignee: SABIC Global Technologies B.V.
    Inventors: Domenico La Camera, Hendrik Kormelink, Jelena Bo{hacek over (z)}ović-Vukić, Yohana Pérez
  • Patent number: 8999509
    Abstract: This invention relates to film composites with a single coating of hard coat material which have a significant improved adhesion together with improved weather resistance while also increasing resistance to abrasion and cracking. In one embodiment, this film composite is comprised of a transparent base sheet having on one side thereof a weather resistant hard coat comprised of: at least one multifunctional acrylate monomer or oligomer; a dual-curable resin comprising an aliphatic urethane acrylate resin having isocyanate functional groups and an aliphatic urethane acrylate having hydroxyl functional groups; an ultraviolet (UV) stabilizer; and a photoinitiator.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: April 7, 2015
    Assignee: CPFilms Inc.
    Inventors: Anthony B. Port, Scott E. Pickett, Steven A. Barth
  • Patent number: 8999323
    Abstract: The present invention relates to a polymerization-curable composition for the preparation of biodegradable, biocompatible, cross-linked polymers on the basis of polyvinyl alcohol comprising: 5 to 100% by weight of (a) vinyl ester monomer(s) of one of the general formulas (I) to (III): wherein X is oxygen, sulfur, nitrogen, or phosphorus; n is 1 to 1000, at least 20% of the n being ?2; the R1 are selected from hydrogen; straight, branched or cyclic, saturated or unsaturated, n-valent hydrocarbon groups having 1 to 30 carbon atoms, which optionally have heteroatoms and are optionally substituted with one or more substituents selected from —OH, —COON, —CN, —CHO, and ?O, and n-valent radicals of biodegradable, biocompatible oligomers and polymers; m is an integer from 1 to 5; the R2 are selected from hydrogen, —OH, ?O, and the options listed for R1; and the R3 are selected from hydrogen, —OH, and the options listed for R1; 0 to 50% by weight of ethylenically unsaturated co-monomers; 0 to 10% by weight of (a)
    Type: Grant
    Filed: November 21, 2008
    Date of Patent: April 7, 2015
    Assignee: Technische Universität Wien
    Inventors: Robert Liska, Jürgen Stampfl, Franz Varga, Heinrich Gruber, Stefan Baudis, Christian Heller, Monika Schuster, Helga Bergmeister, Günter Weigel, Claudia Dworak
  • Patent number: 8993114
    Abstract: Provided is a hard coat film having high hardness and excellent restorability in view of the above circumstances. A hard coat film comprising: a light-transmitting substrate; and a hard coat layer, the hard coat layer comprising a cured product of a composition for a hard coat layer, the composition including an isocyanuric skeleton-containing urethane(meth)acrylate.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: March 31, 2015
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Kana Yamamoto, Toshiki Iwasaki, Masayuki Tsunekawa
  • Patent number: 8993649
    Abstract: Provided is a pressure-sensitive adhesive for polarizing plates which can adhere a polarizing plate on a liquid crystal cell with good adhesion durability and has the characteristic that a liquid crystal display device obtained therefrom is less liable to cause light leakage even under the environment of high temperature and high humidity and which makes it possible remove the polarizing plate.
    Type: Grant
    Filed: December 18, 2006
    Date of Patent: March 31, 2015
    Assignee: Lintec Corporation
    Inventors: Koichi Nagamoto, Kentaro Kusama, Mikihiro Kashio, Kazuhiro Kon, Motoyuki Hayakawa
  • Patent number: 8980970
    Abstract: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ?130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ?2, in the presence of D) a catalyst containing one or more zinc compounds, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.
    Type: Grant
    Filed: September 1, 2005
    Date of Patent: March 17, 2015
    Assignee: ALLNEX IP S.a.r.L.
    Inventors: Jan Weikard, Dorota Greszta-Franz, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock, Christophe Detrembleur
  • Publication number: 20150072083
    Abstract: A method for shielding a metal substrate surface during the application of heat to the surroundings of the substrate which comprises. A liquid maskant composition is formed which comprises: a) at least one of a polycarbonate urethane diacrylate oligomer, a polycarbonate urethane dimethacrylate oligomer, a polycarbonate caprolactone urethane diacrylate oligomer, or a polycarbonate caprolactone urethane dimethacrylate oligomer; b) a reactive diluent capable of free radical polymerization; and c) a photoinitiator capable of generating free radicals when exposed to actinic radiation. The maskant composition is applied onto a surface of the substrate. The maskant composition is then exposed to sufficient actinic radiation to polymerize or crosslink the composition into a dried maskant. In use the dried maskant is heated on the substrate to a temperature of from about 400° F. to about 600° F. for from about 20 minutes to about 30 minutes, and then the maskant is removed.
    Type: Application
    Filed: September 9, 2013
    Publication date: March 12, 2015
    Inventors: Ahmet Nebioglu, Michael A. Morin, Christopher Alan Cayer, Marufur Rahim
  • Publication number: 20150053643
    Abstract: Hot melt compositions include non-aromatic cyclic (alkyl)acrylates and low acid number waxes. Upon application of actinic radiation, the hot melt compositions cure to form resists. They may be stripped from substrates with high alkaline strippers. The hot melt compositions may be used in the manufacture of printed circuit boards and photovoltaic devices.
    Type: Application
    Filed: August 20, 2013
    Publication date: February 26, 2015
    Inventors: Krishna BALANTRAPU, Robert K. BARR
  • Publication number: 20150056421
    Abstract: An inkjet printing method and inkjet compositions are disclosed. The method includes selectively depositing by inkjet printing, layer by layer, a first composition and a second composition onto a receiving media from different dispensers to form polymerizable deposited layers. The first composition includes one or more free-radical polymerizable compounds and a cationic photoinitiator and is devoid of compounds able to undergo cationic photopolymerization within the first composition. The second composition includes one or more cationic polymerizable compounds and is devoid of cationic photoinitiators. At least one of the compositions includes a radical photoinitiator. The method further includes exposing the deposited layers to actinic radiation to initiate polymerization of the free-radical polymerizable compounds and the cationic polymerizable compounds within the deposited layers.
    Type: Application
    Filed: February 28, 2013
    Publication date: February 26, 2015
    Inventors: Ira Yudovin-Farber, Eduardo Napadensky, Avi Levy, Daniel Dikovsky
  • Patent number: 8946322
    Abstract: Thermosetting resins are provided that are toughened with an irradiated thermoplastic toughening agent and which have reduced levels of solvent-induced micro crack formation. The thermoplastic toughening agent is treated with a sufficient amount of high-energy radiation (e.g. electron beam or gamma rays) to cause a reduction in solvent-induced micro crack formation in the cured resin when compared to the same toughened thermosetting resin in which the non-irradiated version of the thermoplastic toughening agent is used.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: February 3, 2015
    Assignee: Hexcel Composites Ltd
    Inventors: John L. Cawse, Stephen Mortimer, Chrisopher J. Wade
  • Patent number: 8940808
    Abstract: Disclosed is a curable coating agent composition which exhibits excellent wear resistance and weather resistance when applied as a coating agent to plastic or other substrates to be used outdoors. The curable coating agent composition comprises 95 to 65 parts by mass of a component (A) comprising an urethane adduct compound having weather resistance, 5 to 35 parts by mass of a component (B) comprising a specific organosilicon compound, 0.1 to 10 parts by mass of a component (C) which is a radical polymerization initiator, 1 to 12 parts by mass of a component (D) which is an ultraviolet ray absorber, and 10 to 1,000 parts by mass of a component (E) which is an organic solvent, with respect to 100 parts by mass of the components (A) and (B) in total.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: January 27, 2015
    Assignees: Kabushiki Kaisha Toyota Jidoshokki, Toagosei Co., Ltd.
    Inventors: Tetsuya Mitsuoka, Hidetaka Hayashi, Toshihisa Shimo, Kyoko Kumagai, Naoharu Ueda, Kazumasa Inata, Takeshi Fujita, Yasuyuki Sanai, Eiichi Okazaki, Hiroshi Suzuki, Naomasa Furuta
  • Publication number: 20150022740
    Abstract: A touch panel, comprises a substrate, a sensing layer disposed on the substrate, wherein the sensing layer includes a plurality of electrode patterns disposed on at least one surface of the substrate, and arranged in interval; an optical matching glue disposed on the sensing layer and filled in the intervals, wherein the refractive index of the optical matching glue matches the refractive index of the sensing layer. The present invention further comprises an optical matching glue and the manufacturing method thereof. When using the touch panel of the present invention, the defects of appearance caused by the refractive index difference between the electrode pattern and the intervals can be reduced without any additional process.
    Type: Application
    Filed: July 17, 2014
    Publication date: January 22, 2015
    Inventors: Yuh-Wen Lee, Chun-Min Hu, Congming Chen, Yea-Wan Chen, Lichun Yang, Qiong Yuan, Xianbin Xu, Kwan-Sin Ho, Hua Yun, Feng Zhao
  • Patent number: 8933138
    Abstract: The present invention provides photolatent Ti-chelate catalyst compounds of formula (I), wherein R1 is for example C6-C14 aryl which is substituted by one or more R?2, R?3 or R?4; or the two R1 together are unsubstituted linear or branched C1-C12alkylene; R2, R3, R4, R?2, R?3, and R?4 independently of each other are for example hydrogen, halogen or linear or branched C1-C20alkyl; R5, R6 and R7 independently of each other are hydrogen, linear or branched C1-C20alkyl, C6-C14aryl, Br or Cl, provided that not more than one of R5, R6 and R7 is hydrogen; as well as formulations comprising said compounds and defined 1,3-diketones.
    Type: Grant
    Filed: September 1, 2010
    Date of Patent: January 13, 2015
    Assignee: BASF SE
    Inventors: Tobias Hintermann, Didier Bauer, Antoine Carroy, Caroline Lordelot, Rachel Kohli Steck
  • Patent number: 8933146
    Abstract: The present invention describes the preparation of an aqueous polyurethane dispersion which is cured by radiation, and its use as binder.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: January 13, 2015
    Assignee: Bayer MaterialScience AG
    Inventors: Stefan Sommer, Richard Kopp, Harald Blum, Christoph Irle, Jan Weikard, Erhard Luehmann
  • Patent number: 8927615
    Abstract: A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.
    Type: Grant
    Filed: May 8, 2013
    Date of Patent: January 6, 2015
    Assignees: Immunolight, LLC, Duke University
    Inventors: Frederic Avery Bourke, Jr., Tuan Vo-Dinh
  • Publication number: 20150000825
    Abstract: The present invention relates to a fire resistant glazing unit (10), and in particular to novel curable gelling compositions which may form a fire-resistant hydrogel interlayer (3) between the glass panes (1) of the glazing unit (10). The gelling compositions of the invention comprise 5-40% w/w of a curable hydrogel-forming component (typically an acidic vinyl monomer such as acrylic acid or its metal salt); 20-60% w/w of one or more salts (e.g. magnesium salts); 40-90% w/w of an aqueous vehicle; and the gelling compositions have an acidic p H between p H 1 and 7. Such gelling compositions, when cured to form a hydrogel interlayer, provide excellent fire-resistant properties and also an excellent radiation barrier in the event of a fire.
    Type: Application
    Filed: February 21, 2013
    Publication date: January 1, 2015
    Applicant: C.G.I. International
    Inventors: Vincent Crook, Muhammad I. Ali
  • Patent number: 8901198
    Abstract: Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
    Type: Grant
    Filed: November 5, 2010
    Date of Patent: December 2, 2014
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Charles M. Kania, Kenneth T. Phelps, Kurt A. Humbert, Todd M. Roper, Jiping Shao, David C. Martin
  • Publication number: 20140349028
    Abstract: Methods and compositions for precoating a substrate. The method comprises: applying to the substrate a curable precoat forming high solids composition comprising: UV curable resin forming components and a photoinitiator system; and applying UV radiation to cure the curable precoat forming component. The curable precoat forming component is not thermally cured. The high solid compositions may comprise a surface-cure photoinitiator and a through-cure photoinitiator and the UV radiation cures the precoat through its entire depth. A conductive additive in the form of a polymer, fiber, filler, powder etc can be added to facilitate and improve electrostatic adhesion of powders to the substrate.
    Type: Application
    Filed: December 6, 2012
    Publication date: November 27, 2014
    Inventor: Kaluachchi Gamage Karnika De Silva
  • Patent number: 8889759
    Abstract: An object to be attained by the present invention is to provide an active energy ray-curable composition that is capable of producing a cured coating film having high scratch resistance and excellent transparency. The present invention relates to an active energy ray-curable composition containing a reactive particle (A) obtained by reacting a silica fine particle (a-1) and a hydrolysable silane (a-2) having one or more (meth)acryloyloxy groups and one or more isocyanurate ring structures in a molecule. The present invention also provides the active energy ray-curable composition according to the above, containing a photopolymerization initiator (B).
    Type: Grant
    Filed: January 5, 2011
    Date of Patent: November 18, 2014
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Yoshinari Matsuura, Akinori Nagai, Atsuya Kato
  • Publication number: 20140327334
    Abstract: The corona shield can be applied in electric machines in a faster manner by using radiation-cured materials.
    Type: Application
    Filed: December 15, 2011
    Publication date: November 6, 2014
    Inventors: Mario Brockschmidt, Stefan Kempen, Friedhelm Pohlmann, Guido Schmidt
  • Publication number: 20140313267
    Abstract: The present invention provides an inkjet ink comprising at least 30% by weight of organic solvent based on the total weight of the ink, a radiation curable material, a photoinitiator and optionally a colourant. The invention also provides an apparatus for printing the ink wherein the apparatus comprises at least one printhead, a means for evaporating solvent from the printed ink and a source of actinic radiation. Furthermore, the invention provides a method of inkjet printing comprising i) inkjet printing the inkjet ink as defined above on to a substrate; ii) evaporating at least a portion of the solvent from the printed ink; and iii) exposing the printed ink to actinic radiation to cure the radiation curable material.
    Type: Application
    Filed: June 30, 2014
    Publication date: October 23, 2014
    Applicant: SERICOL LIMITED
    Inventors: Robert Augustus Fassam, Nigel Gould, Jeremy Ward, Barry McGregor
  • Publication number: 20140309326
    Abstract: Provided are a polymerizable compound, a photocurable composition, and a photocurable moisture-proof insulating coating material for mounting circuit boards, which reduce environmental impact, excel in surface curability at low irradiation dose, and have high adhesion to substrate materials. The compound according to the present invention has a structural unit derived from a dimerdiol and has, as an end group, a group represented by formula (1): wherein R1 represents H or CH3 and R2 represents a hydrocarbon group having 2 to 12 carbon atoms, at an end thereof. Preferably, the compound has, as end groups, the group represented by formula (1) and a group represented by formula (2): wherein R3s each independently represent CH3 or CH2CH3, and R4 represents a hydrocarbon group having 3 to 9 carbon atoms, at the end thereof.
    Type: Application
    Filed: June 27, 2014
    Publication date: October 16, 2014
    Applicant: SHOWA DENKO K.K.
    Inventors: Kazuhiko OOGA, Ritsuko AZUMA
  • Patent number: 8859634
    Abstract: This invention relates to a photo-curing or electron beam-curing adherent resin composition being excellent in the adhesiveness to various adherends such as metal oxide, metal, resin and so on, and more particularly to an adherent resin composition of a photo-curing or electron beam-curing type comprising a difunctional urethane (metha)acrylate oligomer (A) and a monomer component (B), characterized in that the urethane (metha)acrylate oligomer includes a urethane prepolymer portion composed of a polyol and a polyisocyanate wherein repetitive number of urethane prepolymer portion (n) is 10-30, and the monomer component (B) is a cyclic monomer having a (metha)acryloyl group.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: October 14, 2014
    Assignee: BRIDGESTONE Corporation
    Inventors: Junji Sakata, Hajime Kitano, Hiroyuki Kanesugi
  • Patent number: 8859633
    Abstract: Provided are a temporal fixation method in processing of optical members and a resin composition suitable therefore, which uses a composition which is characterized by containing the following (A3), (B3) and (D3), wherein (A3) is a urethane(meth)acrylate; (B3) is one or more (meth)acrylic acid derivative monomers selected from the group consisting of n-(meth)acryloyloxyalkyl hexahydrophthalimides, carboxyl group-containing (meth)acrylates and (meth)acrylic acid derivative monomers represented by the formula (C3): Z—O—(R2O)p—R1??Formula (C3): wherein Z represents a (meth)acryloyl group, R1 represents a phenyl group or a phenyl group having an alkyl group with 1 to 3 carbon atoms, R2 represents —C2H4—, —C3H6—, —CH2CH(CH3)—, —CH2CH(OH)CH2—, —C4H8— or —C6H12—, and p represents an integer of from 1 to 10; and D(3) is a photopolymerization initiator, along with methods for temporarily fixing a member.
    Type: Grant
    Filed: July 7, 2011
    Date of Patent: October 14, 2014
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kazuhiro Oshima, Tomoyuki Kanai, Kunio Iriuchijima
  • Patent number: 8853295
    Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: October 7, 2014
    Assignee: ALLNEX IP S.a.r.L.
    Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
  • Publication number: 20140256842
    Abstract: The present invention relates to a method for producing an optical member wherein an optical substrate having a light-blocking part on the surface is bonded to an optical substrate for bonding. The method for producing an optical member uses a UV-curable resin composition and comprises specific (Process 1) through (Process 3). The present invention also relates to the use of a UV-curable resin composition comprising a (meth)acrylate (A) and a photopolymerization initiator (B) for the production method, and a UV-curable resin composition. It is possible to produce a bonded optical member having good curability and adhesiveness, such as a touch panel or display unit having an optical substrate comprising a light-blocking part, with good productivity but with little damage to the optical substrate. It is thereby possible to obtain an optical member having a high degree of resin curing at the light-blocking part and high reliability.
    Type: Application
    Filed: October 19, 2012
    Publication date: September 11, 2014
    Inventors: Daisuke Kobayashi, Hayato Motohashi, Yuichiro Matsuo
  • Patent number: 8822562
    Abstract: Ink deposited on a substrate by an ink-jet arrangement to form a protective layer includes hardenable oligomer, hardenable monomer selected from a group including alkoxylated and/or poly-alkoxylated acrylic monomers comprising one or more di- or tri-acrylates, and a photoinitiator. The oligomer has a room temperature viscosity greater than 1 Pa·s. The oligomer to monomer weight ratio is between 1/6 and 1/25. The ink has a room temperature viscosity between 15 and 22 mPa·s and between 5 and 2 mPa·s at 60° C., and a room temperature surface tension between 15 and 28 mN/m. The photoinitiator is activated by a UV source having an appropriate wavelength and intensity.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: September 2, 2014
    Assignee: M.G.I. USA, Inc.
    Inventor: Edmond Abergel
  • Patent number: 8822563
    Abstract: Disclosed is a curable resin composition comprising a polymer (A) that has a main chain comprising carbon atoms and a side chain having a polymerizing unsaturated linking group and has a cyclic structure in the main chain and/or the side chain, and a compound having a polymerizing unsaturated group. The curable resin composition has good optical characteristics, good heat resistance and good moldability.
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: September 2, 2014
    Assignee: FUJIFILM Corporation
    Inventors: Hiroaki Mochizuki, Naoyuki Morooka, Rie Okutsu, Tatsuhiko Obayashi
  • Patent number: 8809415
    Abstract: Compositions for golf balls that include polyurethane and/or polyurea linkages and that are crosslinked in the soft segments of the polymer backbone to improve the crosslink density and effect a hardness gradient throughout the molded article.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: August 19, 2014
    Assignee: Acushnet Company
    Inventors: Randy Petrichko, Shawn Ricci, Edmund A. Hebert, Brian Comeau, David A. Bulpett
  • Publication number: 20140228472
    Abstract: Soluble or colloidal nanoparticles of molecularly imprinted polymer are produced reliably and consistently in a photoreactor with a reaction vessel (18) containing a solid phase (14) bearing immobilised template. Parameters such as temperature, fluid flows and irradiation time are controlled by a computer (52).
    Type: Application
    Filed: September 20, 2012
    Publication date: August 14, 2014
    Inventors: Sergey Piletsky, Olena Piletska, Antonio Guerreiro, Michael Whitcombe, Alessandro Poma
  • Publication number: 20140194549
    Abstract: A method for polymerizing monomer units and/or oligomer units is disclosed. Said method is characterized in that the energy required for polymerization is introduced into the monomer units and/or oligomer units to be polymerized by means of infrared light pulses, wherein the infrared light pulses have a wavelength of 2500 to 20000 nm, an intensity of more than 1014 W/m2, a duration of more than 8 fs and less than 3 ps and a substantially linear polarization.
    Type: Application
    Filed: June 6, 2012
    Publication date: July 10, 2014
    Inventors: Karsten Heyne, Anja Heyne
  • Publication number: 20140167333
    Abstract: Methods of forming a curable pre-impregnated composite precursor material with radiation (e.g., actinic or electron-beam) curable resin composition systems are provided, as are the curable pre-impregnated composite precursor materials themselves. The resin systems have reversible temperature-viscosity control, which are advantageously used to form curable pre-impregnated composite precursor materials (pre-preg) that can be cured to form a composite article. The uncured resin composition comprises: (a) an acrylate or a methacrylate monomer; (b) an oligomer species selected from the group consisting of: polyethers, polyesters, epoxies, and combinations thereof; and (c) a photoinitiator. The uncured resin has a first viscosity at 21° C. (70° F.) of ?about 200,000 centipoise (cP) and a second viscosity of ?about 5,000 cP at 65° C. (149° F.) or above.
    Type: Application
    Filed: December 18, 2012
    Publication date: June 19, 2014
    Applicant: Autoliv ASP, Inc.
    Inventors: Michael P. Jordan, Bradley W. Smith, Geoffrey A. Russell
  • Publication number: 20140134349
    Abstract: The present invention describes a method for repairing defects on a surface of an optical substrate. The method includes a step of providing a radiation curable coating and then applying the coating onto a surface of the optical substrate. The coating is then cured with a UV light source causing the refractive index of the coating to be less than ±10% of the refractive index of the substrate. The cured coating exhibits a viscosity less than about 315 CP at 25° C. The present invention also describes a novel coating composition for repairing optical substrates.
    Type: Application
    Filed: July 13, 2012
    Publication date: May 15, 2014
    Inventor: Russell Anderson
  • Patent number: 8710113
    Abstract: The invention relates to a dental composition comprising a) a compound (A) with the following features: only one backbone unit (U) with 6 to 20 carbon atoms, at least 6 carbon atoms thereof forming an aromatic or an aliphatic cyclic moiety, the remaining carbon atoms either being part of substituents pending from the cyclic moiety or being part of bridging groups to spacer units, wherein one or more of the remaining carbon atoms can be replaced by an oxygen atom, the backbone unit not comprising a bisphenol structure and halogen atoms, one or two unit(s) (S) being connected to the backbone unit (U) via an ether linkage, at least one unit (S) comprising a —CH2-CH2-CH2-CH2-O—CH2-CH(Q)-OG moiety or a —CH2-CH(OG)-CH2-OM moiety or a mixture of these two types of moieties within one unit (S), with G comprising at least one polymerizable moiety and an urethane moiety, the urethane moiety acting as connecting element to unit(s) (S), and M comprising at least one group selected from acroyl, methacroyl, aryl, mixtures
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: April 29, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Adrian S. Eckert, Michael M. Cub, Bettina Hailand, Marion B. Kestel, Karsten Dede, Uwe H. Hoheisel, Gioacchino Raia, Christoph Thalacker, Reinhold Hecht, Thomas Luchterhandt, Peter Bissinger, Wolf Steiger
  • Patent number: 8697932
    Abstract: Switchable adhesives comprising a mixture, in proportions by weight, of 20% to 98% of an adhesive, 2% to 80% of curable molecules and 0.05% to 10% of photoinitiator. Preferably, the adhesive and curable molecules are mutually soluble when dry or the curable molecules and adhesive may be uniformly dispersed in each other. Preferably the amount of adhesive in the mixture is in the range 40% to 98% by weight, more preferably 60% to 95% by weight, even more preferably 70% to 85% by weight. Preferably the proportion of curable molecules in the mixture ranges from 2% to 60% by weight, more preferably 5% to 40% by weight, even more preferably 15% to 30% by weight. Preferably, the photoinitiator is present in the mixture in the proportions 0.5% to 5% by weight, more preferably 1% to 3% by weight. Such switchable adhesives are useful in medical dressings and other removable sheet products, and may be simply prepared by stirring the adhesive, the curable molecules and the photoinitiator together at room temperature.
    Type: Grant
    Filed: September 24, 2009
    Date of Patent: April 15, 2014
    Assignee: Lumina Adhesives AB
    Inventor: Mats Tunius
  • Patent number: 8673994
    Abstract: The present invention provides: an ink composition which contains at least a polymerizable compound, a photopolymerization initiator and a coloring material, and is free from an aqueous solvent, wherein the polymerizable compound comprises at least a urethane oligomer; a two-pack curing ink composition set comprising an ink composition containing a coloring material and a reaction liquid containing a photopolymerization initiator and capable of forming an image with an ink composition obtained by mixing the ink composition and the reaction liquid, wherein the ink composition after mixing contains at least a polymerizable compound, a photopolymerization initiator and a coloring material, and is free from an aqueous solvent, wherein the polymerizable compound comprises a urethane oligomer.
    Type: Grant
    Filed: August 3, 2011
    Date of Patent: March 18, 2014
    Assignee: Seiko Epson Corporation
    Inventors: Keitaro Nakano, Takashi Oyanagi
  • Patent number: 8669301
    Abstract: The present invention relates to urethane(meth)acrylate resins obtained from the reaction, in a first step, of at least one polyisocyanate (I) with at least one compound (II) containing at least two reactive groups capable to react with isocyanate groups and at least one (meth)acrylate (III) containing essentially one reactive group capable to react with isocyanate groups, and, in a subsequent step, reacting the product obtained from the first step with at least one polyisocyanate (IV) different from the poly-isocyanate (I) used in the first step, and their use for making radiation cured pressure sensitive adhesives.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: March 11, 2014
    Assignee: Allnex Belgium S.A.
    Inventors: Ming Zhao, Leo Ternorutsky, Patrice Mariucci, Victor Xynia Lu
  • Publication number: 20140024737
    Abstract: A mill base composition includes a compound comprising a divinyl ester of a dicarboxylic acid, a dispersing agent, and a pigment. The divinyl ester of the carboxylic acid includes from 2 to about 8 carbon atoms. The mill base composition is subjected to milling with milling beads to produce a milled mill base composition that functions as a pigment concentrate that may be added to an ink vehicle to form an ink composition suitable for use in inkjet ink devices. The milled mill base composition is particularly suited for UV curable ink compositions. A UV curable ink composition includes the pigment concentrate, one or more UV curable monomers, and one or more UV initiators.
    Type: Application
    Filed: April 12, 2011
    Publication date: January 23, 2014
    Inventors: Or Brandstein, Alex Trubnikov, Eytan Cohen, Ziv Belman, Kobi Cohen
  • Publication number: 20130337161
    Abstract: An organic-inorganic composite film containing an organic-inorganic composite including an inorganic compound particle and a polymer bonded to the inorganic compound particles. A percentage of voids in the film is 3 to 70 volume % with reference to a volume of the film.
    Type: Application
    Filed: February 20, 2012
    Publication date: December 19, 2013
    Inventors: Mitsuyo Akimoto, Kenya Tanaka
  • Publication number: 20130331478
    Abstract: In one aspect, the invention relates to crosslinkable, flame retardant polymer compositions are provided comprising a polyamide or polyester; a flame retardant system; a crosslinking agent; and a flame retardant system coagent. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Application
    Filed: May 24, 2013
    Publication date: December 12, 2013
    Inventors: Domenico La Camera, Hendrik Kormelink, Jelena Bozovic-Vukic, Yohana Pérez