Processes Of Preparing A Solid Polymer From At Least One Oxygen Containing Monomer; Or Compositions Therefore Patents (Class 522/178)
  • Patent number: 7687552
    Abstract: An epoxy resin composition, including: an epoxy resin (A) represented by Formula (1); an epoxy resin (B) having an epoxy equivalent of 220 or less and having twice or more epoxy groups in a molecule than epoxy groups of the epoxy resin (A); and a photocationic polymerization initiator (C), in which: the epoxy resins (A) and (B) constitute main components; and a weight of the epoxy resin (A) is 40% or more and a weight of the epoxy resin (B) is 30% or more with respect to a total weight of the epoxy resins (A) and (B): where: R represents a hydrogen atom, a methyl group, an ethyl group, a propyl group, or a t-butyl group; represents an integer of 0 or more and 4 or less; and m represents an integer of 1 or more and 3 or less.
    Type: Grant
    Filed: November 4, 2009
    Date of Patent: March 30, 2010
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shimpei Otaka, Kazunari Ishizuka, Isamu Horiuchi, Isao Imamura
  • Patent number: 7687550
    Abstract: One embodiment of a composition includes a radiation-curable pre-polymer and at least one stabilizing additive contained in the radiation-curable pre-polymer. The stabilizing additive is configured to reduce shrinkage caused by radiation curing of the radiation-curable pre-polymer.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: March 30, 2010
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Mehrgan Khavarl, Vladek Kasperchik
  • Patent number: 7683103
    Abstract: A dental polymerizable composition comprising (a) a fluorine compound comprising a chain polymer having a main chain comprising a monomer unit having a hydrophilic group, and terminal groups comprising a fluoroalkyl group at each of both ends of the main chain; (b) a polymerizable monomer; and (c) a polymerization initiator.
    Type: Grant
    Filed: August 11, 2005
    Date of Patent: March 23, 2010
    Assignee: Kuraray Medical Inc.
    Inventors: Hideo Sawada, Junji Tagami, Toru Nikaido, Khairul Matin, Yoshinori Kadoma, Eiichi Masuhara, Koichi Okada, Junichi Yamauchi
  • Patent number: 7683105
    Abstract: A UV-A-curable, solvent-containing composition composed of (A) 1% to 50% by weight of a UV-A-curable constituent containing isocyanate-reactive groups; (B) 0.01% to 10% by weight of a colorless photoinitiator having an absorption maximum in the wavelength range of ?=300 to 400 nm; (C) 10% to 70% by weight of an alkyl and/or cycloalkyl acetate having 3 to 10 carbon atoms in the alkyl radical and/or in the cycloalkyl radical; (D) 10% to 70% by weight of an alkoxyalkyl, alkoxycycloalkyl, cycloalkoxyalkyl and/or cycloalkoxycycloalkyl acetate; (E) 0.01% to 5% by weight of a constituent that lowers the interfacial tension; (F) 0 to 50% by weight of an alkylaromatic having at least two alkyl radicals having 1 to 6 carbon atoms in the molecule; and (G) 0 to 50% by weight of an additive different from constituents (A) to (F); processes for preparing it, and its use as a spot blender in automotive refinishing, especially in spot repair, or for preparation thereof.
    Type: Grant
    Filed: January 28, 2006
    Date of Patent: March 23, 2010
    Assignee: BASF Coatings AG
    Inventors: Bernhard Lettmann, Klaus-Udo Reize, Egbert Nienhaus
  • Patent number: 7678843
    Abstract: To provide a dental restorative material composition using an organic-inorganic composite filler having excellent surface smoothness like a natural tooth, low polymerization shrinkage, excellent X-ray contrast imaging property, similar transparency to that of a natural tooth, and no variation of transparency before and after the composition is hardened, the dental restorative material composition includes (a) a (meth)acrylate monomer, (b) an organic-inorganic composite filler having an average particle diameter of 5 to 50 ?m which is made by mixing a (meth)acrylate monomer and a fine particle filler having an average primary particle diameter of 0.005 to 0.3 ?m and having X-ray impermeability, (c) a fine particle filler having an average primary particle diameter of 0.005 to 0.04 ?m, and (d) a photopolymerization initiator.
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: March 16, 2010
    Assignee: GC Corporation
    Inventors: Futoshi Fusejima, Naoko Jimbo, Shinji Kaga
  • Patent number: 7671107
    Abstract: It has been discovered that an initiation reaction is efficiently progressed to a propagation reaction by adding a compound that potentially or directly generates a carbocation to the polymerization system of a cationic ring-opening polymerizable compound, and thus the activation of polymerization is rendered. Namely, the present invention relates to a cationic polymerizable resin composition which is characterized by comprising (A) a compound having at least one functional group capable of cationic ring-opening polymerization in one molecular chain, (B) a cationic polymerization initiator, and (C) a compound to generate a carbocation by the action of active species generated from (B) the cationic polymerization initiator by electromagnetic wave or particle beam.
    Type: Grant
    Filed: November 25, 2004
    Date of Patent: March 2, 2010
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yuichi Ito, Yasushi Mizuta
  • Patent number: 7666920
    Abstract: The present invention relates to a radiation curable resin composition which comprises epoxy (meth)acrylate, a monofunctional (meth)acrylate, a bifunctional (meth)acrylate having a specific structure, and a bifunctional (meth)acrylate obtained from an aliphatic dihydric alcohol having an oxyalkylene structure and (meth)acrylic acid and further contains a thermoplastic resin, thereby causing satisfactory adhesion to plastic substrates, sufficient shape retention, and excellent shape recovery properties, and satisfaction in moldability including casting efficiency and shape reproducibility, as well as a high refractive index and appropriateness for use as a lens sheet.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: February 23, 2010
    Assignees: Dai Nippon Ink and Chemicals, Inc., Dai Nippon Printing Co., Ltd.
    Inventors: Hiroyuki Tokuda, Yasunari Kawashima, Yasuhiro Doi
  • Patent number: 7662867
    Abstract: The invention relates to the use of an infrared absorber for accelerating the UV curing of a mass to be cured. The infrared absorber is preferably selected from ATO, ITO, ZnO, LaB6 and a mixture of said substances. A casting resin is preferably used as the mass to be cured, in particular a resin based on an acrylic resin or an acrylate resin. The invention permits the production of laminated panes, in which the starting mass is applied between the panes and converted to form the laminate.
    Type: Grant
    Filed: February 7, 2006
    Date of Patent: February 16, 2010
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Detlef Burgard
  • Patent number: 7662224
    Abstract: A curable ink composition for digitally printing onto plastic substrates that can be formed into three-dimensional objects is provided. Generally, the ink composition comprises a pigment, an acrylic polymer or copolymer, a diluent, and a mono-functional monomer.
    Type: Grant
    Filed: November 8, 2006
    Date of Patent: February 16, 2010
    Inventor: Donald D. Sloan
  • Patent number: 7660427
    Abstract: A curable composition and method for producing a tear resistant, yet soft and deformable in-the-ear product yielding the user greater comfort and durability. The curable composition incorporated into a hearing aid apparatus provides a deformable, yet tear resistant housing, which may be mated to a soft tip component. The hearing aid housing provides better comfort, durability and acoustic performance for a variety of ear canal shapes. The curable composition that provides these properties includes at least one urethane acrylate oligomer, at least one reactive diluent and a cure system. The composition when cured desirably produces a tear strength of at least about 75 pli and a hardness of about Shore A 60 to about 75.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: February 9, 2010
    Assignee: Henkel Corporation
    Inventors: Alan Edward Litke, JoAnn DeMarco, Victor Karol Kadziela
  • Patent number: 7659324
    Abstract: Dental materials which contain a radically polymerizable organic binder, at least one radical polymerization initiator and at least one radical polymerization accelerator, both the initiator and the accelerator each having at least one radically polymerizable group.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: February 9, 2010
    Assignee: Ivoclar Vivadent AG
    Inventors: Norbert Moszner, Urs Karl Fischer, Peter Burtscher, Jörg Angermann, Volker M. Rheinberger
  • Patent number: 7659322
    Abstract: The invention provides a method for preparing a polyanhydride by irradiating one or more diacids with microwave radiation in the presence of a carboxylic anhydride so as to acylate the one or more diacids to yield at least one prepolymer, and irradiating the prepolymer with microwave radiation so as to polymerize said prepolymer to yield the polyanhydride, as a homopolymer or a copolymer. High purity polyanhydrides can be prepared by this method. Reaction times compared to conventional melt polycondensations can be significantly reduced. Copolymer polyanhydrides can also be prepared by the microware radiation techniques described herein.
    Type: Grant
    Filed: December 16, 2005
    Date of Patent: February 9, 2010
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Brandon M. Vogel, Surya K Mallapragada
  • Patent number: 7655174
    Abstract: A fully curable jettable composition having a viscosity less than 30 cps at a temperature within the range of 15-180° C., more preferably at a temperature of 15-100° C., e.g. 60-80° C. the composition comprising: (A) at least one low viscosity reactive resin selected from the group consisting of compounds containing an oxetane ring, cycloaliphatic epoxy resins, tetrahydrofurans, hexahydropyrans and mono-functional (meth)acrylates, said resin having a molecular weight of not greater than 300 Daltons, e.g. 250 Daltons or less, and a viscosity at a temperature in the said range of less than 30 cps, e.g.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: February 2, 2010
    Assignee: Huntsman Advanced Materials Americas LLC
    Inventors: Ranjana C Patel, Yong Zhao, Richard John Peace
  • Patent number: 7642299
    Abstract: A multi-functional (meth)acrylate compound containing at least three F atoms and at least three Si atoms per molecule is provided. A photocurable resin composition comprising the compound can endow support substrates with antifouling properties with respect to organic stains such as oil mist and fingerprints, without detracting from surface mar resistance.
    Type: Grant
    Filed: November 22, 2006
    Date of Patent: January 5, 2010
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yuji Yoshikawa, Koichi Higuchi, Masaaki Yamaya
  • Patent number: 7635725
    Abstract: Highly crystalline, oxidation resistant crosslinked polymeric materials such as crosslinked ultrahigh molecular weight polyethylenes having high wear resistance, enhanced stiffness, enhanced tensile strength, a high level of fatigue and crack propagation resistance, and enhanced creep resistance can be manufactured by the new methods described herein.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: December 22, 2009
    Assignee: The Brigham and Women's Hospital, Inc.
    Inventors: Anuj Bellare, Thomas S. Thornhill
  • Patent number: 7632880
    Abstract: The invention provides a single phase, essentially solvent-free polymerizable liquid composition comprising a polymerizable liquid with dissolved therein an organogroup 4, 5 or 6 compound selected from the group consisting of organolead, organophosphorus, organoarsenic, organoantimony, organobismuth and organselenium compounds, said position being polymerizable under the action of an externally applied influence.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: December 15, 2009
    Assignee: Microsharp Corporation Ltd.
    Inventors: Zhi Li, Rifat Iqbal, Jun Wang
  • Patent number: 7632875
    Abstract: The present invention provides novel hybrid polymer useful for alignment layers for inducing alignment of a liquid crystal medium. Hybrid polymers of this invention are prepared from at least one component selected from the group consisting of monomer, oligomer and polymer within the class of polyimides, poly(amic acids) and esters thereof and at least one component selected from the group consisting of addition monomer and functionalized addition polymer wherein the two components are covalently bonded to form a copolymer. The invention further describes liquid crystal optical elements such as all liquid crystal display products or modes, liquid crystal devices and liquid crystal optical films comprising the novel hybrid polymer alignment layers.
    Type: Grant
    Filed: July 18, 2005
    Date of Patent: December 15, 2009
    Assignee: Elsicon, Inc.
    Inventors: Wayne M. Gibbons, Michael G. P. Reppy, Patricia A. Rose, Hanxing Zheng
  • Patent number: 7629394
    Abstract: The present invention describes a process of preparing microcapsules in a UV curable water immiscible phase. The microcapsules formed according to the invention contain an aqueous phase core. The process comprises dispersing a water soluble or dispersible core material along with at least one wall forming prepolymer and a polycondensation polymerization catalyst into an aqueous solution. The aqueous phase is then dispersed into the water immiscible phase comprising UV curable monomers or oligomers forming droplets of the aqueous phase solution in the water immiscible phase. Polycondensation of the prepolymers is initiated to form polymeric wall material or microcapsules at or near the interface of the water immiscible solvent and droplets of aqueous phase solution. Following capsule formation, a UV initiator is dispersed in the water immiscible phase. The UV curable dispersion containing aqueous microcapsules can be coated on a substrate.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: December 8, 2009
    Assignee: Appleton Papers Inc.
    Inventor: Nianxi Yan
  • Patent number: 7622511
    Abstract: A method and kit for providing a tack-free artificial nail surface. The tack-free artificial nail surface may include an acrylic layer and a barrier layer. The acrylic layer may comprise an odorless monomer. The barrier layer may be of any material impervious to oxygen. The tack-free nail surface may be formed by application of the acrylic layer to a fingernail nail bed. The barrier layer may then be applied over the acrylic layer. The barrier layer blocks oxygen from the acrylic layer so that the acrylic layer may polymerize in the absence of oxygen.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: November 24, 2009
    Assignee: OPI Products, Inc.
    Inventors: Sunil J. Sirdesai, Lauren M. Breese, George W. Schaeffer
  • Patent number: 7618565
    Abstract: Lipobeads (liposome-encapsulated hydrogels) combine properties of hydrogels and liposomes to create systems that are sensitive to environmental conditions and respond to changes in those conditions in a fast time scale. Lipobeads may be produced by polymerizing anchored or unanchored hydrogels within liposomes or by mixing anchored or unanchored hydrogels with liposomes. Giant lipobeads may be produced by shrinking unanchored nanogels in lipobeads and fusing the resulting lipobead aggregates, long-term aging of anchored or unanchored lipobeads, or mixing anchored or unanchored aggregated nanogels with liposomes. Poly(acrylamide), poly(N-isopropylacrylamide), and poly(N-isopropylacrylamide-co-1-vinylimidazole) lipobeads were produced and characterized.
    Type: Grant
    Filed: August 14, 2002
    Date of Patent: November 17, 2009
    Assignee: Polytechnic Institute of New York University
    Inventors: Sergey Kazakov, Marian Kaholek, Kalle Levon
  • Patent number: 7615258
    Abstract: A method of reducing unreacted monomer in a water-soluble or water swellable polymer comprising the steps, i) applying an ultraviolet initiator to the surface of the polymer and ii) irradiating the polymer with ultraviolet light, wherein the ultraviolet initiator is dissolved or dispersed in a liquid medium and in which the liquid medium comprises an organic compound. The method is useful for reducing in the amount of unreacted acrylamide in polyacrylamide. Also claimed is a liquid initiator composition comprising, i) an ultraviolet initiator, and ii) a liquid medium comprising an organic compound. The initiator system is useful for applying to the surface of a polymer, such as polyacrylamide, in the removal of unreacted monomer, such as acrylamide.
    Type: Grant
    Filed: July 8, 2005
    Date of Patent: November 10, 2009
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd.
    Inventors: Gareth Ian Naylor, Anne Flisher
  • Patent number: 7615582
    Abstract: A hydrophobic acidic group-containing polymeric monomer (a); a water-soluble polymeric monomer (b); water (c); a photopolymerization initiator (d); an aromatic tertiary amine (e) having an electron-withdrawing group; a cross-linkable polymeric monomer (f); and a basic compound (g) for producing a water-soluble salt through a reaction with a part of the hydrophobic acidic group-containing polymeric monomer (a) are included as essential compounding ingredients. A one-part dental adhesive composition that exhibits high adhesive strength and high storage stability in adhesion between a teeth, and more particularly enamel or dentine, and a dental repairing material, and more particularly a resin material, is provided.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: November 10, 2009
    Assignee: Kuraray Medical Inc.
    Inventors: Kazumitsu Nakatsuka, Naoki Nishigaki
  • Patent number: 7615110
    Abstract: An intaglio printing ink, curing by free radical acrylate chemistry, which does not fluoresce in at least the visible region under ultraviolet light is prepared by using an acylphosphine oxide as the photoinitiator.
    Type: Grant
    Filed: March 30, 2005
    Date of Patent: November 10, 2009
    Assignee: Sun Chemical Corporation
    Inventors: Michael W. Leonard, John A. Dyer, James R. Tucker, Shaun L. Herlihy
  • Patent number: 7612122
    Abstract: Compounds of formula (I): [where: the substituents R1 are individually selected from C1-C10 alkyl groups and optionally substituted benzyl groups; the substituents R2 are individually selected from alkyl groups or, together with the nitrogen atom to which they are attached, represent a nitrogen-containing heterocyclic group; Z is selected from C6-C10 arylene groups and groups of formula —(CHR3)n—, where R3 is hydrogen, hydroxy or a C1-C4 alkyl group, and n is 0 to 6; Y is carbonyl or —CH2—; Q is a residue of a mono- or poly-hydroxy compound; and x is 1 to 6; and esters thereof] are useful as multi-functional photoinitiators for use in coating compositions to be cured by radiant energy.
    Type: Grant
    Filed: November 9, 2005
    Date of Patent: November 3, 2009
    Assignee: Sun Chemical Corporation
    Inventors: Shaun Lawrence Herlihy, Brian Rowatt, Robert Stephen Davidson
  • Patent number: 7605191
    Abstract: The invention provides a photosensitive resin which can readily form, through photo-crosslinking, a surface coating which has hydrophilicity and high bioadaptability; a photosensitive composition containing the photosensitive resin; and a photo-crosslinked structure obtained from the photosensitive composition.
    Type: Grant
    Filed: March 31, 2006
    Date of Patent: October 20, 2009
    Assignee: Toyo Gosei Co., Ltd.
    Inventors: Takeshi Ikeya, Toru Shibuya, Kana Miyazaki
  • Patent number: 7605190
    Abstract: Composition with at least one polymerizable binder and at least one polymerization initiator, which contains at least one acylgermanium compound according to general Formula (I), in which R0 is a substituted or unsubstituted C1-18-alkyl radical or an acyl group; R1 and R2 are H, an acyl group or have one of the meanings given for R3; R3 is a branched or linear C1-18-alkyl radical which can be unsubstituted or substituted one or more times by —O—, —NH—, —NR—, —S— or interrupted by other groups, trimethylsilyl, hal-(CH3)2Si—[OSi(CH3)2]r?, (CH3)3Si—[OSi(CH3)2]r—, —COOH, —COO—R10, —CO—NR11R12, —CO-vinyl, —CO-phenyl, phenyl-C1-4-alkyl, phenyl, naphthyl or biphenyl, C5-12 cycloalkyl, a 5 or 6-membered O, S or N-containing heterocyclic ring, halogen, OH, an aromatic C6-30 radical which can be substituted or unsubstituted and/or interrupted by O, S or —NR—, or a branched, cyclic or linear C1-20 alkyl, -alkenyl, -alkoxy or -alkenoxy radical; m is 1, 2 or 3; n is 0 or 1 and p is 0 or 1; wherein in each case two of
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: October 20, 2009
    Assignee: Ivoclar Vivadent AG
    Inventors: Norbert Moszner, Ulrich Salz, Urs Karl Fischer, Robert Liska, Heinrich Gruber, Beate Ganster
  • Patent number: 7601765
    Abstract: The present invention relates to processes for preparing actinic-radiation-curable and/or dual-cure poly(meth)acrylates by preparing a poly(meth)acrylate containing hydroxy-functional side chains and transesterifying or esterifying the poly(meth)acrylate containing hydroxy-functional side chains with a (meth)acrylate or (meth)acrylic acid. The present invention further relates to the actinic-radiation-curable and/or dual-cure poly(meth)acrylates themselves and to the use of the actinic-radiation-curable and/or dual-cure poly(meth)acrylates in the preparation of dispersions or as a component in coating formulations and topcoats comprising at least one actinic-radiation-curable and/or dual-cure poly(meth)acrylate.
    Type: Grant
    Filed: November 5, 2003
    Date of Patent: October 13, 2009
    Assignee: BASF Coatings AG
    Inventors: Heinz-Peter Rink, Susanne Neumann, Uwe Meisenburg, Karl-Heinz Joost, Dietmar Häring, Bernhard Hauer
  • Patent number: 7595353
    Abstract: The invention provides a photocurable polymer composition having a fluorine-containing polymer and a fluorine-free polymer, and preferably further having a polymerizable double bond-containing compound and a photopolymerization initiator. The fluorine-containing polymer preferably includes a fluorosilsesquioxane skeleton.
    Type: Grant
    Filed: September 28, 2006
    Date of Patent: September 29, 2009
    Assignee: Chisso Corporation
    Inventors: Hisanobu Minamisawa, Mikio Yamahiro, Akira Meguro
  • Publication number: 20090234041
    Abstract: Curable monomer that is liquid at 25° C., curable wax and colorant together form a radiation curable ink. This ink may be used to form images by providing the radiation curable ink at a first temperature; applying the radiation curable ink to the substrate to form an image, the substrate being at a second temperature, which is below the first temperature; and exposing the radiation curable ink to radiation to cure the ink.
    Type: Application
    Filed: May 20, 2009
    Publication date: September 17, 2009
    Applicant: Xerox Corporation
    Inventors: Jennifer Lynne BELELIE, Peter Gordon Odell, Christopher A. Wagner, C. Geoffrey Allen
  • Patent number: 7579388
    Abstract: Radiation curable ink compositions that include a curable component having a functionality that is greater than two, is present in the ink composition in an amount greater than 30 percent by weight, and has a molecular weight in the range of about 400 g/mole to about 10,000 g/mole; a component that has a functionality that is less than or equal to 2; and an initiator component. A solvent component, pigment, a surface tension modifier and other materials also can be included. The radiation curable inks are employed in ink jet printers and are particularly suited for use in printing on large-scale substrates. The printed images described herein have good adhesion to polymeric substrates such as styrene-based, polycarbonates, polyolefins, polyethylene terephthalate glycol ester, acrylic and others.
    Type: Grant
    Filed: April 27, 2008
    Date of Patent: August 25, 2009
    Assignee: Electronics for Imaging, Inc.
    Inventor: Laura A. Kiefer
  • Patent number: 7576138
    Abstract: A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The method is carried out in a so-called drum reactor, which comprises a hollow drum and an irradiation source. The drum has a longitudinal axis and a cross-section. Superabsorbent polymer particles are fed into the drum and are irradiated while they move within the drum, which is rotated around its longitudinal axis. The irradiation source is provided such that the radiation emitted by the irradiation source is able to reach superabsorbent polymer particles within said drum. The irradiation source for use in the method is able to emit UV radiation of a wavelength between about 100 nm and about 200 nm.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: August 18, 2009
    Assignee: The Procter & Gamble Company
    Inventors: Andreas Flohr, Torsten Lindner, Esther Oliveros, Yoshiro Mitsukami
  • Patent number: 7576143
    Abstract: A polyurethane acrylate (A), comprises, as synthesis components, (a) at least one polyisocyanate which comprises isocyanurate groups, based on 1-isocyanato-3,3,5-trimethyl-5-(isocyanatomethyl)cyclohexane, (b) at least one polyisocyanate which comprises isocyanurate groups, based on hexamethylene diisocyanate, (c) at least one aliphatic and/or cycloaliphatic diisocyanate, (d1) at least one polyetherdiol or polyesterdiol having a molecular weight ranging from 500 to 2000, (d2) optionally, at least one diol having a molecular weight of less than 220 g/mol, (e) at least one compound having at least one group reactive toward isocyanate and at least one unsaturated group capable of free radical polymerization, and (f) optionally, at least one compound having exactly one group reactive toward isocyanate.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: August 18, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhold Schwalm, Erich Beck, Klaus Menzel
  • Patent number: 7576141
    Abstract: An adhesive composition containing: (a) a thermoplastic resin; (b) a radical-polymerizable compound including two or more (meth)acryloyl groups; (c) a curing agent that generates a radical by photoirradiation of 150 to 750 nm and/or heating at 80 to 200° C.; and (d) a liquid rubber having a viscosity of 10 to 1000 Pa·s at 25° C.
    Type: Grant
    Filed: May 27, 2005
    Date of Patent: August 18, 2009
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Shigeki Katogi, Hoko Suto, Masami Yusa
  • Patent number: 7576139
    Abstract: The present invention provides a thermosetting and photocurable coating composition obtained by incorporating a copolymer of a maleimide group-containing monomer with other monomer(s) or a specific maleimide compound into a composition comprising a hydroxyl-containing resin and a curing agent and optionally containing an unsaturated compound; and a method of forming a coating film using the coating composition.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: August 18, 2009
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Kazutoshi Sugiura, Hiromi Katoh, Yoshizumi Matsuno
  • Patent number: 7572840
    Abstract: The present invention relates to a method for manufacturing super-absorbent polymers, comprising providing a reaction mixture which comprises at least a first monomer and a second monomer and a radical-forming polymerization initiator, and subsequently causing the monomers to polymerize under the influence of an energy source, wherein radical formation occurs and the polymerization is started, wherein the first monomer is neutralized with an inorganic base before polymerization, in addition to the manufactured super-absorbent polymers. The invention further relates to a method for applying a coating of super-absorbent polymers to a carrier.
    Type: Grant
    Filed: October 5, 2004
    Date of Patent: August 11, 2009
    Assignee: Vepetex B.V.
    Inventors: Paul Kleijn, Herman Reezigt
  • Patent number: 7569618
    Abstract: A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The method is carried out in a so-called drum reactor, which comprises a hollow drum and an irradiation source. The drum has a longitudinal axis and a cross-section. Radical former molecules are applied on the surface of superabsorbent polymer particles. These superabsorbent polymer particles are fed into the drum and are irradiated while they move within the drum, which is rotated around its longitudinal axis. The irradiation source is provided such that the radiation emitted by the irradiation source is able to reach superabsorbent polymer particles within said drum. The irradiation source for use in the method is able to emit UV radiation of a wavelength between about 201 nm and about 400 nm.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: August 4, 2009
    Assignee: The Procter & Gamble Company
    Inventors: Andreas Flohr, Torsten Lindner, Esther Oliveros, Yoshiro Mitsukami
  • Patent number: 7566745
    Abstract: A subject for the invention is to provide a method of refractive index regulation by which the refractive index of an optical polymer molding can be efficiently changed without necessitating a complicated step, such as the step of oxidizing beforehand, and which when used for producing an optical device, imparts excellent transparency thereto. Another subject is to provide a photochemically refractive-index-changing polymer or photochemically refractive-index-changing polymer composition for use in the method.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: July 28, 2009
    Assignee: Nitto Denko Corporation
    Inventors: Yoshihide Kawaguchi, Yutaka Moroishi, Tetsuo Inoue, Kazunori Mune
  • Patent number: 7547735
    Abstract: The present invention provides a UV curable composition comprising an acrylate component, comprising an acrylate-functionalized hydrogenated polybutadiene, and at least one mono-functional acrylate, and a photoinitiator combination triggered upon exposure to radiation at 365 nm of the electromagnetic spectrum comprising a bisacyl phosphine oxide and benzophenone, where when dispensed at a thickness of about 1 mm and exposed to UV radiation generated at a wavelength of 365 nm the composition cures through the thickness of the dispensed composition at a speed between 40 mm/sec to 100 mm/sec.
    Type: Grant
    Filed: December 4, 2006
    Date of Patent: June 16, 2009
    Assignee: Henkel Corporation
    Inventors: Mark M. Konarski, Joel D. Schall
  • Patent number: 7544721
    Abstract: A photosensitive adhesive composition of the polymerizable resin type, the hardening of which occurs by polymerization and/or reticulation, includes:—initiators for at least one chain polymerization reaction to guarantee the hardening of the composition and a sufficient quantity of at least one bifunctional monomer, including a photolabile center with at least one photolabile entity and at least two polymerizable units, connected by covalent skeletons to the photolabile center and located away from the cleavage sites of the photolabile center, such that the composition loses the integrity and adhesivity thereof under the influence of a reticulating radiation causing the cleavage of the photolabile sites. The composition is particularly of application in dentistry.
    Type: Grant
    Filed: April 2, 2003
    Date of Patent: June 9, 2009
    Assignee: Produits Dentaires Pierre Rolland
    Inventors: Vincent Gaud, Yves Gnanou, Jean-Pierre Desvergne, Francis Dieras, Alexandrine Roubiere
  • Patent number: 7541391
    Abstract: Disclosed is an optical device structure comprising a low shrinkage mixture wherein the shrinkage of the mixture is limited after the curing of the mixture during optical device formation. Disclosed also are methods for forming optical devices which comprise the low shrinkage mixture.
    Type: Grant
    Filed: September 2, 2005
    Date of Patent: June 2, 2009
    Assignee: General Electric Company
    Inventors: Thomas Bert Gorczyca, Renato Guida, Kung-Li Justin Deng, Hua Xia
  • Patent number: 7538145
    Abstract: The phase change, curable composition comprises curable monomer, photoinitiator that initiates polymerization of the curable monomer, and phase change agent that provides the composition with an increase in viscosity of at least four orders of magnitude, from a first temperature, the first temperature being from 50° C. to 130° C., to a second temperature, the second temperature being from 0° C. to 70° C., wherein the second temperature is at least 10° C. below the first temperature. A coating over an image may be applied by providing a composition comprising curable monomer at a first temperature; applying the composition over the image, the image being at a second temperature; and exposing the composition to radiation to initiate polymerization of the curable monomer. In this process, the composition has a viscosity at the second temperature that is at least four orders of magnitude greater than its viscosity at the first temperature.
    Type: Grant
    Filed: November 30, 2005
    Date of Patent: May 26, 2009
    Assignee: Xerox Corporation
    Inventors: Jennifer L. Belelie, Peter G. Odell, Darly Vanbesien, Marcel P. Breton
  • Patent number: 7538144
    Abstract: A novel photoreactive polymer is disclosed comprising a dendritic polymer core with at least one initiating functional group and at least one co-initiating functional group. The photoreactive polymers are useful in radiation curable compositions are varnishes, lacquers, printing inks and radiation curable ink-jet inks. The dendritic polymeric core is preferably a hyperbranched polymer.
    Type: Grant
    Filed: June 29, 2005
    Date of Patent: May 26, 2009
    Assignee: Agfa Graphics, N.V.
    Inventors: Luc Vanmaele, Johan Loccufoer, Yu Chen, Holger Frey
  • Patent number: 7537452
    Abstract: The invention features a photopolymerizable composition that comprises a cationically polymerizable resin, and a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and one or more anthracene-based compounds as electron donors. Electron donor combinations used in the invention include multiple substituted anthracene compounds or a combination of at least one substituted anthracene compound with unsubstituted anthracene.
    Type: Grant
    Filed: August 16, 2007
    Date of Patent: May 26, 2009
    Assignees: Curators of the University of Missouri, 3M Innovative Properties Company 3M Center, 3M ESPE AG
    Inventors: Joel D. Oxman, Karsten Dede, Craig A. Dykstra, Victoria A. Russell, Christoph Thalacker, Wolfgang Weinmann
  • Publication number: 20090128767
    Abstract: It is an object of the present invention to provide a curable resin composition for a column spacer which has excellent developability and solubility and is capable of forming a clearly patterned column spacer without leaving a development residue at the time of pattern formation of the column spacer to be used in producing a liquid crystal display panel. The present invention is directed to a curable resin composition for a column spacer, which contains a compound having two or more polymerizable unsaturated bonds in a molecule, an alkali-soluble polymer compound, and a photo-reaction initiator, the compound having two or more polymerizable unsaturated bonds in a molecule being an oxide-modified compound having two or more polymerizable unsaturated bonds in a molecule.
    Type: Application
    Filed: May 30, 2006
    Publication date: May 21, 2009
    Inventors: Minoru Suezaki, Yoshio Nishimura, Toru Takahashi, Sayaka Kobayashi, Tatsuya Matsukubo
  • Patent number: 7531580
    Abstract: (A) a polycarbonatediol, (B) a trifunctional alcohol, and (C) a diisocyanate are subjected to reaction in the presence of (D) a (meth)acrylate compound represented by the general formula CH2?CRCO(OCnH2n)pR? or CH2?CRCO(OCmH2m)qOCOCH?CH2, and (E) a di(meth)acrylate compound of alkylene glycol whose alkylene group is substituted as a lower alkyl group, and then (F) a hydroxyl group-containing (meth)acrylate is added to the resulting solution of urethane oligomers in (meth)acrylate to conduct terminal (meth)acrylating reaction of the urethane oligomers, thereby producing a UV-curable liquid polyurethane resin having a viscosity (25° C.) of preferably 150,000-1,000,000 mPa·s, where before or after the terminal (meth)acrylating reaction of the urethane oligomers (G) a photopolymerization initiator and (H) a hindered phenol-based antioxidant having a molecular weight of 500-2,000 are added thereto to form the UV-curable liquid polyurethane resin.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: May 12, 2009
    Assignee: Unimatec Co., Ltd.
    Inventors: Tetsuya Watanabe, Takashi Chiba, Shuzo Yamada
  • Patent number: 7521487
    Abstract: A process for preparing a polyacrylate-based shaped article, a polyacrylate being polymerized by a conventional method, wherein the polyacrylate comprises copolymerized comonomers having thermally crosslinkable groups and comonomers having attached photoinitiators, and the polyacrylate is crosslinked thermally in a first step and by irradiation with UV light in a second step.
    Type: Grant
    Filed: April 29, 2005
    Date of Patent: April 21, 2009
    Assignee: tesa Aktiengesellschaft
    Inventors: Sven Hansen, Marc Husemann, Kay Brandes, Stephan Zollner
  • Patent number: 7521486
    Abstract: Fluoropolymers are made by admixing tetrafluoroethylene, hexfluoropropylene, and vinylidene fluoride; reacting the reaction admixture to generate a set of fluoropolymeric oligomers; irradiating the fluoropolymeric oligomeric precursor admixture (preferably with electron beam radiation) to form free radical sites on individual fluoropolymeric oligomers of the set and generate thereby a set of free radical oligomer derivatives in the fluoropolymeric oligomeric precursor admixture; and reacting the fluoropolymeric oligomeric precursor admixture to derive the fluoropolymer compound from the free radical oligomer derivatives. In a second approach, fluoropolymers are made by admixing tetrafluoroethylene, hexfluoropropylene, and vinylidene fluoride and irradiating the admixture.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: April 21, 2009
    Assignee: Freudenberg-NOK General Partnership
    Inventor: Edward Hosung Park
  • Publication number: 20090093563
    Abstract: A dental adhesive composition comprising (i) at least one non-acidic polymerizable monomer having at least one ethylenically unsaturated group, (ii) optionally one or more acidic compounds, (iii) at least one photoinitiator, (iv) at least one solvent, and (v) about 0-40% by weight of one or more fillers; wherein the weight ratio of non-acidic polymerizable monomers/acidic compounds in the adhesive composition is more than about 4.5; the viscosity of the adhesive composition is less than about 350 centipoise (cP) at 25° C.; and the adhesive composition excluding solvent and filler has an acid number of less than about 0.75 mmol NaOH/g. The dental adhesive composition is used with a dental primer composition, which may be provided together in a kit.
    Type: Application
    Filed: October 8, 2007
    Publication date: April 9, 2009
    Applicant: KERR CORPORATION
    Inventor: Xuejun Qian
  • Patent number: 7514479
    Abstract: An active energy ray curable coating composition comprising a mixture (A) of compounds each having a (meth)acryloyl group and a colloidal silica (B), wherein the mixture (A) contains from 22 to 62% of a copolymer (A1) having (meth)acryloyl groups and obtained by reacting a specific amount of a radical polymerizable monomer (a1) having a quaternary ammonium salt group, a radical polymerizable monomer (a2) having a hydroxyl group and a radical polymerizable monomer (a3) having a lactone ring-opening addition structure. A molded product having a coating film made of a cured product of the coating composition. To form a coating film made of a cured product which provides excellent abrasion resistance, transparency and antistatic property and undergoes little decrease in the antistatic property even when kept at a high humidity.
    Type: Grant
    Filed: September 26, 2006
    Date of Patent: April 7, 2009
    Assignee: Asahi Glass Company, Limited
    Inventor: Satoshi Kondo
  • Patent number: 7514482
    Abstract: Coating compositions yielding cured coatings that exhibit excellent abrasion-resistance and hardness for use on polymeric substrates such as the front side of optical lenses, in a manner that meets or exceeds the stringent requirements for such use. The compositions include the hydrolysis product of an epoxy functional alkoxy silane, a viscosity-reducing amount up to 50% by weight, solids basis, of a monomeric (silanol free) epoxy functional epoxy silane, and colloidal silica present in an amount sufficient to improve abrasion resistance as compared to a composition lacking the colloidal silica.
    Type: Grant
    Filed: July 25, 2005
    Date of Patent: April 7, 2009
    Assignee: The Walman Optical Company
    Inventor: Gerald D. Treadway