Specified Rate-affecting Material Contains Phosphorous Patents (Class 522/64)
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Publication number: 20120207945Abstract: A photocurable ink contains a colorant dissolved or dispersed within a solvent, a photoinitiator, an organic phosphite, an aldehyde, and a photocurable compound. The organic phosphite is present in a molar excess relative to the aldehyde moieties that are present. The photocurable ink can be used for imaging or other applications where a uniform or patterned image is desired. The photocurable ink can be cured partially before application, or totally cured after application.Type: ApplicationFiled: February 14, 2011Publication date: August 16, 2012Inventor: Deepak Shukla
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Publication number: 20120208914Abstract: The photocuring efficiency of a photoinitiator is increased by mixing it with an organic phosphite and an aldehyde. This mixture or photoinitiator composition can be used to cure acrylates or other photocurable compounds, particularly in an oxygen-containing environment.Type: ApplicationFiled: February 14, 2011Publication date: August 16, 2012Inventor: Deepak Shukla
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Publication number: 20120207939Abstract: The photocuring efficiency of a photoinitiator is increased by mixing it with an organic phosphite and an aldehyde. This mixture or photoinitiator composition can be used to cure acrylates or other photocurable compounds, particularly in an oxygen-containing environment.Type: ApplicationFiled: February 14, 2011Publication date: August 16, 2012Inventor: Deepak Shukla
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Publication number: 20120205043Abstract: Provided is an adhesive (meth)acrylic resin composition being high in adhesiveness and capable of affording an adhered body which can be used at high temperatures of 250° C. or higher, and possessing low outgassing property and heat resistance. A (meth)acrylic resin composition including (A) a polyfunctional (meth)acrylate, and (B) a photopolymerization initiator that exhibits a mass loss on heating of 15% by mass or less when increasing temperature from 30° C. to 250° C. at a temperature increase rate of 10° C./min. under nitrogen flow, wherein the glass transition temperature of a cured body obtained from the composition is 250° C. or higher.Type: ApplicationFiled: October 20, 2010Publication date: August 16, 2012Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHAInventors: Hiroyuki Kurimura, Isamu Ichikawa, Takayuki Nagumo, Takako Hoshino, Jun Watanabe
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Patent number: 8242185Abstract: The present invention is directed to an adhesive composition comprising a crosslinkable acrylic copolymer, a multi-functionalized crosslinkable oligomer and a photoinitiator wherein the composition exhibits excellent wet out characteristics as reflected in a tan delta value of at least 0.5, preferably greater than 0.5, more preferable greater than 0.8 as measured at 20° C. resulting from a first curing stage, and improved stiffness and temperature resistance as reflected in a storage elastic modulus of at least 300,000 Pa at 20° C. and a shear adhesion failure temperature of at least 425° F. (218.3° C.) at 1 Kg/in2 (0.155 Kg/cm2), respectively, which result from a second sequential curing stage.Type: GrantFiled: August 3, 2009Date of Patent: August 14, 2012Assignee: Morgan Adhesives CompanyInventors: Timothy Michael Smith, Gary Allan McMaster
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Publication number: 20120202912Abstract: The present invention relates to a process for surface treatment of a solid substrate in which photopolymerisation and covalent grafting are performed in situ on said substrate of a biocidal copolymer, wherein steps are taken in which: a) said solid substrate is put in contact with a formulation comprising: 1—at least one monomer comprising a biocidal group, 2—at least one copolymerisable compound with said biocidal monomer comprising a multifunctional monomer or oligomer mono- di- or selected amongst acrylate, epoxide or vinyl ether monomers or oligomers, 3—at least one photoprimer selected amongst radical and/or cationic photoprimers, and 4—at least one grafting agent on said substrate, and b) photocopolymerisation and covalent grafting of the copolymers obtained are carried into effect by subjecting said formulation in contact with said solid substrate to ultraviolet radiation.Type: ApplicationFiled: June 28, 2011Publication date: August 9, 2012Applicant: DESARROLLO DEL GRAFTING S.L.Inventors: Alain PERICHAUD, Monica ARNAUTU
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Publication number: 20120202911Abstract: Disclosed is a curable coating agent composition which exhibits excellent wear resistance and weather resistance when applied as a coating agent to plastic or other substrates to be used outdoors. The curable coating agent composition comprises 95 to 65 parts by mass of a component (A) comprising an urethane adduct compound having weather resistance, 5 to 35 parts by mass of a component (B) comprising a specific organosilicon compound, 0.1 to 10 parts by mass of a component (C) which is a radical polymerization initiator, 1 to 12 parts by mass of a component (D) which is an ultraviolet ray absorber, and 10 to 1,000 parts by mass of a component (E) which is an organic solvent, with respect to 100 parts by mass of the components (A) and (B) in total.Type: ApplicationFiled: October 13, 2010Publication date: August 9, 2012Applicants: TOAGOSEI CO., LTD., KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Tetsuya Mitsuoka, Hidetaka Hayashi, Toshihisa Shimo, Kyoko Kumagai, Naoharu Ueda, Kazumasa Inata, Takeshi Fujita, Yasuyuki Sanai, Eiichi Okazaki, Hiroshi Suzuki, Naomasa Furuta
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Patent number: 8236870Abstract: A curable solid ink composition including a curable component, a non-curable component including an ethoxylated octylphenol derivative, a photoinitiator, and a colorant. The curable solid ink composition has a viscosity in the range of less than 10 cPs at 90° C., a shrinkage value of less than 3%, and a superior curing rate compared to existing curable solid ink compositions. The ethoxylated octylphenol derivatives may be prepared by reacting an ethoxylated octylphenol, a linear alcohol, and diisocyanates or polyisocyanates.Type: GrantFiled: February 11, 2010Date of Patent: August 7, 2012Assignee: Xerox CorporationInventors: Marcel P. Breton, Michelle N. Chretien, Jeffrey H. Banning, Stephan V. Drappel, Ian R. Duffy, Christopher A. Wagner
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Publication number: 20120190766Abstract: The invention relates to pellets of ?-olefin-vinyl acetate copolymers with a vinyl acetate content of ?40% by weight, based on the total weight of the ?-olefin-vinyl acetate copolymer, as an embedding material for solar modules, wherein the pellets comprise, as additives, at least one UV activator and at least one silane coupling reagent, and to the use thereof for the production of films for solar modules.Type: ApplicationFiled: August 3, 2010Publication date: July 26, 2012Applicant: LANXESS DEUTSCHLAND GMBHInventors: Andreas Roos, Michael Herrmann, Rainer Kalkofen, Stefan Kelbch, Hans-Jürgen Frommont, Gerd Bergmann, Ralf Tappe
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Publication number: 20120190765Abstract: Curable solid inks which are solid at room temperature and molten at an elevated temperature at which the molten ink is applied to a substrate. In particular, the curable solid inks of the present embodiments retain the advantages of handling, safety, and print quality usually associated with conventional curable solid phase change inks but have replaced the petroleum-based materials generally used in the conventional inks with renewable “green” materials to provide a robust and environmentally-friendly curable solid ink.Type: ApplicationFiled: January 20, 2011Publication date: July 26, 2012Applicant: XEROX CORPORATIONInventors: Naveen Chopra, Michelle Chretien, Barkev Keoshkerian, Daryl W. Vanbesien, Valerie M. Farrugia
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Patent number: 8227050Abstract: The present invention is directed to a UV curable coating composition, which includes one or more monomers, one or more multifunctional oligomers, one or more pigments, one or more photoinitiators, and volatile organic solvent. The coating composition can be used as a primer in repairing and refinishing automobiles. The coating composition provides short drying times and a cured coating that does not need to be wiped. A method of applying the coating composition is also provided.Type: GrantFiled: October 12, 2006Date of Patent: July 24, 2012Assignee: E I du Pont de Nemours and CompanyInventor: James William O'Neil
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Publication number: 20120172478Abstract: The invention provide a method for making silicone hydrogel based on the Lightstream Technology from a monomer mixture with a curing time of less than about 100 seconds. The present invention is also related to silicone hydrogel contact lenses made according to methods of the invention.Type: ApplicationFiled: March 14, 2012Publication date: July 5, 2012Inventors: Frank Chang, Jürgen Vogt, John Dallas Pruitt, Xinming Qian, Dawn A. Smith, Angelika Maria Domschke, Troy Vernon Holland, Richard Charles Turek, Daqing Wu
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Publication number: 20120154496Abstract: Curable solid inks and low shrinkage curable solid inks which are solid at room temperature and molten at an elevated temperature at which the molten ink is applied to a substrate. In particular, the solid inks of the present embodiments retain the advantages of handling, safety, and print quality usually associated with conventional solid phase change inks but provide additional breakthrough performance characteristics such as enhanced robustness, lower jetting temperature, and ultra-low shrinkage upon crystallization, which allow the inks to be used as novel materials in inkjet-based Braille and raised print applications.Type: ApplicationFiled: December 17, 2010Publication date: June 21, 2012Applicant: XEROX CORPORATIONInventors: Marcel P. Breton, Michelle N. Chretien, Barkev Keoshkerian, Jennifer L. Belelie, Naveen Chopra
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Patent number: 8202679Abstract: An oxime ester compound of formula (I) useful as a photopolymerization initiator. A photopolymerization initiator having the oxime ester compound as an active ingredient is activated through efficient absorption of light of long wavelength, e.g., 405 nm or 365 nm, to exhibit high sensitivity. In formula (I), R1 and R2 are each R11, OR11, COR11, SR11, CONR12R13, or CN; R11, R12, and R13 are each hydrogen, a C1-C20 alkyl group, C6-C30 aryl group, a C7-C30 arylalkyl group, or a C2-C20 heterocyclic group; R3 and R4 are each R11, OR11, SR11, COR11, CONR12R13, NR12COR11, OCOR11, COOR11, SCOR11, OCSR11, COSR11, CSOR11, CN, halogen, or a hydroxyl group; a and b is each 0 to 4; X is oxygen, sulfur, selenium, CR31R32, CO, NR33, or PR34; and R31, R32, R33, and R34 each have the same meaning as R1.Type: GrantFiled: December 25, 2007Date of Patent: June 19, 2012Assignee: Adeka CorporationInventors: Daisuke Sawamoto, Nobuhide Tominaga
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Publication number: 20120149797Abstract: The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B?) an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.Type: ApplicationFiled: February 14, 2012Publication date: June 14, 2012Applicant: FUJIFILM CORPORATIONInventors: Ippei Nakamura, Masaharu Sugai
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Publication number: 20120148833Abstract: Radiation-curable coating compositions for a surface such as a concrete floor, which include one or more acrylate monomers or oligomers having at least four crosslinkable double bonds, at least one photoinitiator, one or more fillers, and at least one pigment or dye are described and claimed. These coating compositions allow for application of at least 0.10 mm (4 mil) thickness of the coating composition over an area larger than a radiation source, without the formation of wrinkles along the shoulder area of each pass of the radiation source in the areas where weak intensity light from a side edge of the radiation source is capable of partially curing only a portion of the coating composition thickness. The coating compositions optionally further comprise one or more tertiary amine compounds comprising zero or one crosslinkable double bonds, the one or more tertiary amine compounds providing an amine value of at least 7.5 mg KOH per gram of the total radiation-curable resins of the coating composition.Type: ApplicationFiled: June 30, 2011Publication date: June 14, 2012Inventors: Huimin CAO, Wenguang LI, Tia Yeon LEE
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Publication number: 20120142805Abstract: The invention pertains to an oligomer or polymer substituted by one or more bisacylphosphine oxide moieties, characterized in that said bisacylphosphine oxide moiety is linked via the phosphorous atom, optionally via a spacer group, to the oligomer or polymer backbone; as well as to specifically functionalized bisacylphosphine oxides, suitable to prepare said polymers or oligomers.Type: ApplicationFiled: June 29, 2010Publication date: June 7, 2012Applicant: BASF SEInventors: Hansjorg Grutzmacher, Timo Ott, Kurt Dietliker
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Patent number: 8192673Abstract: The disclosure provides a new photopolymerizable resin system for dental restorative materials. The resin system utilizes a thiol-ene component as the reactive diluent in dimethacrylate systems. The ternary resin system comprises a thiol monomer, an ene monomer and a dimethacrylate monomer. Use of an off-stoichiometric ratio of thiol:ene functional groups in favor of excess thiols results in enhanced overall functional group conversion, improved polymer mechanical properties, and reduced shrinkage stress of the ternary system when compared to either traditional dimethacrylate or thiol-ene resin systems.Type: GrantFiled: March 31, 2009Date of Patent: June 5, 2012Assignee: University of KansasInventors: Christopher N. Bowman, Neil B. Cramer
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Patent number: 8193258Abstract: A sealant composition is provided. The sealant composition includes (a) an oligomer including an unsaturated mono-carboxylic acid modified bisphenol A epoxy resin and an unsaturated mono-carboxylic acid modified bisphenol F epoxy resin, wherein an equivalence ratio of the bisphenol A epoxy resin to the bisphenol F epoxy resin is 0.05:0.95 to 0.3:0.7, the bisphenol A epoxy resin has a melting point higher than 40° C. and the bisphenol F epoxy resin has a melting point lower than 40° C.; (b) an epoxy resin having at least two or more than two epoxy groups; and (c) a photoinitiator.Type: GrantFiled: August 25, 2009Date of Patent: June 5, 2012Assignee: Industrial Technology Research InstituteInventors: Jauder Jeng, Man-Lin Chen, Pei-Ching Liu, Tien-Shou Shieh
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Publication number: 20120133059Abstract: The invention provides a radiation curable ink jet ink composition including: a monomer equal to or more than 20% by mass and equal to or less than 50% by mass with respect to the total mass of the ink composition, which is represented by the following formula (I); and N-vinylcaprolactam equal to or more than 5% by mass and equal to or less than 15% by mass with respect to the total mass of the ink composition: CH2?CR1—COOR2—O—CH?CH—R3??(I) wherein, R1 is a hydrogen atom or a methyl group, R2 is a divalent organic residue having 2 to 20 carbon atoms, and R3 is a hydrogen atom or monovalent organic residue having 1 to 11 carbon atoms.Type: ApplicationFiled: November 30, 2011Publication date: May 31, 2012Applicant: SEIKO EPSON CORPORATIONInventors: Jun Ito, Hiroki Nakane
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Publication number: 20120133060Abstract: A radiation-curable ink jet ink composition contains a polymerizable compound, an photopolymerization initiator and polysiloxane, in which the ink composition is used for recording on a package substrate as a recording medium; the polymerizable compound contains one or more kinds of compound having a pentaerythritol skeleton; an HLB value of the polysiloxane is 5 to 12; and the polysiloxane content is 0.1 to 2% by mass with respect to the total amount of the ink composition.Type: ApplicationFiled: November 30, 2011Publication date: May 31, 2012Applicant: SEIKO EPSON CORPORATIONInventors: Hiroki Nakane, Jun Ito
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Publication number: 20120128313Abstract: The invention relates to radiation curable compositions. The invention provides radiation curable optical fiber primary coating compositions comprising an oligomer, a reactive diluent monomer blend comprising at least two reactive diluents monomers, and at least one photoinitiator, wherein each of said monomers in said blend has the formula (I) wherein x is an integer of from 1 to 6; n is an integer of from 1 to 5; and each Y, which may be the same or different, is independently selected from the group consisting of hydrogen, a C1 to C12 alkyl group and an alkarylalkoxylated acrylate radical; and at least one photoinitiator; said reactive diluent monomer blend being substantially free of non-aryl reactive diluent monomers; wherein when an aryl reactive diluent monomer is present that has a molecular weight less than about 300, it is present at no more than about 10 wt. % of the total formulation.Type: ApplicationFiled: October 8, 2010Publication date: May 24, 2012Inventors: Xiaosong Wu, Timothy Edward Bishop, Joan Monroe Zimmerman, Long Han
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Publication number: 20120129969Abstract: The invention relates to radiation curable compositions comprising a liquid 0/s(acyl)phosphine photo initiators of formula (Ï): wherein each of Ar1, Ar2 and Ar3 is independently a substituted or unsubstituted aryl group. The invention also relates to stabilized forms of liquid bis(acyl)phosphines of formula (I) and radiation curable composition comprising said stabilized photoinitiators. The radiation curable compositions are selected from the group consisting of an optical fiber coating composition and a coating composition capable of radiation cure on concrete and a coating composition capable of radiation cure on metal.Type: ApplicationFiled: June 21, 2011Publication date: May 24, 2012Inventors: Timothy Edward Bishop, Edward Joseph Murphy, John Edmond Southwell, Satyendra Sarmah, TaiYeon Lee
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Publication number: 20120129968Abstract: The invention relates to a liquid bis(acyl)phosphine oxide of formula (I): wherein R is C1-C18 alkyl, and wherein R is optionally substituted as described herein. The invention also relates to radiation curable compositions comprising liquid bis(acyl)phosphine oxide of formula (I).Type: ApplicationFiled: June 21, 2011Publication date: May 24, 2012Inventor: Timothy Edward Bishop
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Publication number: 20120123012Abstract: The present invention relates to microcapsules composed of a shell of polymers and of a core comprising photoinitiators which exhibit acylphosphine oxides, their derivatives or amine coinitiators or mixtures of these compounds, and also to the preparation of these microcapsules and to their use for dental materials.Type: ApplicationFiled: October 23, 2007Publication date: May 17, 2012Inventors: Volker Rheinberger, Ulrich Salz, Jörg Zimmermann, Katharina Landfester, Ulrich Ziener, Marissa Volz
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Publication number: 20120113201Abstract: Provided is a UV curable type ink-jet ink composition containing a monomer A which is expressed by the following general formula (I): CH2?CR1—COOR2—O—CH?CH—R3??(I) (in the formula, R1 is a hydrogen atom or methyl radical, R2 is a bivalent organic residue radical having a carbon number in a range of 2 to 20, and R3 is a hydrogen atom or a univalent organic residue radical having a carbon number in a range of 1 to 11), a compound B containing five or more (meth)acryloyl radicals per molecule, and a monofunctional (meth)acrylate C having an aromatic ring skeleton, wherein the monofunctional (meth)acrylate C which is in a range of 5 to 35 wt % with respect to the total weight of the ink composition is contained.Type: ApplicationFiled: November 9, 2011Publication date: May 10, 2012Applicant: SEIKO EPSON CORPORATIONInventors: Taketoshi KAGOSE, Hiroki NAKANE, Chigusa SATO, Hiroaki KIDA, Toru SAITO
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Publication number: 20120115963Abstract: A process for the preparation of a polymer nanoparticle by a photoinduced emulsion polymerization includes preparing an emulsion comprising at least one surfactant, a dispersed phase and a continuous phase. The dispersed phase comprises at least one polymerizable monomer and the continuous phase comprises water and at least one photoinitiator. The at least one polymerizable monomer is polymerized by exposing the emulsion to an electromagnetic radiation having a wavelength so as to induce a generation of radicals from the at least one photoinitiator.Type: ApplicationFiled: April 16, 2010Publication date: May 10, 2012Applicant: ETH ZUERICHInventors: Hansjoerg Gruetzmacher, Timo Ott
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Publication number: 20120107523Abstract: A UV photoactivatable curable paint formation for providing a cured paint coating of a desired appearance on a substrate by UV irradiation, comprises a UV curable film-forming compound; a UV photoinitiator; a particulate UV reflective material in an effective rate of curing enhancing amount without affecting the resultant desired appearance of the cured paint coating.Type: ApplicationFiled: June 29, 2010Publication date: May 3, 2012Applicant: HONDA MOTOR CO., LTD.Inventor: Nirupama Karunaratne
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Patent number: 8153195Abstract: The present invention provides a printing method for printing radiation-curable ink jet ink printing comprising a clear coat primer composition comprising: a low surface tension monofunctional alkyl acrylate monomer with a surface tension in the range of 23 to 31 dynes/cm in which the alkyl group has at least 8 carbon atoms; a photoinitiator; and other UV curable monomers and oligomers. The clear coat primer composition is applied first onto a substrate and cured with actinic radiation or cationic curable ink jet ink is printed on the surface of the clear coat primer coating.Type: GrantFiled: September 7, 2007Date of Patent: April 10, 2012Assignee: Electronics For Imaging, Inc.Inventors: Matt Tennis, Joshua Samuel, Paul A. Edwards
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Publication number: 20120083547Abstract: The present disclosure relates to a nail coating system comprising a basecoat, a color layer, and a topcoat. The system of the present disclosure may be applied to natural and/or pre-existing artificial nail coatings. The present disclosure relates generally to compositions for natural and artificial nail coatings, and particularly, but not by way of limitation, to polymerizable compositions and color layers polymerized therefrom. The disclosure further relates to methods of making a polymerized color layer.Type: ApplicationFiled: November 23, 2011Publication date: April 5, 2012Applicant: Creative Nail Disign, Inc.Inventors: Thong H. VU, Diane Marie Larsen, Chad Conger
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Patent number: 8148444Abstract: To provide a composition useful for forming a heat conductive sheet that satisfies both high heat conductivity and sufficient softness, has sufficient cohesive strength at a surface portion of a heat conductive sheet and does not cause remaining paste and breakage of an electronic appliance when the sheet is peeled. The composition comprises (A) a photo polymerizable component consisting of a (meth)acryl type monomer or its partial polymer; (B) a heat conductive filler; (C) a photo reaction initiator for initiating the polymerization of the photo polymerizable component; and (D) a photo absorber for absorbing and removing a predetermined wavelength band from electromagnetic rays used for the polymerization of the photo polymerizable component.Type: GrantFiled: October 19, 2007Date of Patent: April 3, 2012Assignee: 3M Innovative Properties CompanyInventors: Masaki Yoda, Yoshinao Yamazaki
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Publication number: 20120076950Abstract: Provided is a curable composition for imprints excellent in pattern transferability. Disclosed is a curable composition for imprints comprising a polymerizable monomer (A) and a polymerization initiator (B), which is substantially free from a polymer which contains at least one species of the polymerizable monomer (A) as a repeating unit.Type: ApplicationFiled: April 1, 2011Publication date: March 29, 2012Applicant: FUJIFILM CORPORATIONInventor: Kunihiko Kodama
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Publication number: 20120076468Abstract: [Problem] Provided include: a resin composition for forming an optical waveguide, the resin composition having high productivity and being capable forming a thick film with high accuracy excellent in transparency, heat resistance and toughness; a resin film for forming an optical waveguide; and an optical waveguide excellent in transparency, environmental reliability and heat resistance. [Means for Solution] A resin composition for forming an optical waveguide, containing (A) a polyhydroxy polyether having an ethylenically unsaturated group on a side chain and an aromatic ring on a main chain, (B) a polymerizable compound having an ethylenically unsaturated group, and (C) a radical polymerization initiator; a resin film for forming an optical waveguide; and an optical waveguide having a core part formed by using the resin film for forming an optical waveguide.Type: ApplicationFiled: April 28, 2010Publication date: March 29, 2012Inventors: Tatsuya Makino, Toshihiko Takasaki, Masami Ochiai, Atsushi Takahashi
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Patent number: 8142557Abstract: Radiation curable phase change ink comprising an ink vehicle that includes at least one curable carrier, at least one gellant, at least one curable wax and at least one photoinitiator. In a method of forming an image with the ink, the radiation curable phase change ink is melted, then jetted onto an image receiving substrate, wherein the radiation curable phase change ink forms a gel state, and exposed to ultraviolet light to cure the curable components of the radiation curable phase change ink. The wax cures into the structure of the ink, thereby generating a robust image of excellent gloss.Type: GrantFiled: June 28, 2006Date of Patent: March 27, 2012Assignee: Xerox CorporationInventors: Jennifer L. Belelie, Peter G. Odell, Eniko Toma, Christopher A. Wagner, C. Geoffrey Allen, Stephan V. Drappel
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Publication number: 20120059080Abstract: A coating composition is provided comprising (A) a co-hydrolytic condensate of a UV-absorbing alkoxysilane, a UV-curable alkoxysilane, and a tetraalkoxysilane, (B) a polyfunctional poly(meth)acrylate, and (C) a photobleachable photopolymerization initiator. Upon exposure to UV, the composition cures briefly at low temperature to form a cured film having durability, adhesion and transparency.Type: ApplicationFiled: August 23, 2011Publication date: March 8, 2012Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Motoo Fukushima, Yuji Yoshikawa, Kazuharu Sato
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Publication number: 20120046376Abstract: A polymerizable polymeric photoinitiator according to Formula (I): wherein: PL represents an n+m+p-functional polymeric core; n and m independently represent an integer from 1 to 30; p represents an integer from 0 to 10; o is 0 or 1; INI represents a group selected from the group consisting of a benzophenone, a thioxanthone, a carbazole, a anthraquinone, a camphor quinone, an ?-hydroxyalkylphenone, an ?-aminoalkylphenone, an acylphosphine oxide, a bisacyl phosphine oxide, an acylphosphine sulfide, a phenyl glyoxalate, a benzoin ether, a benzyl ketal, an ?-dialkoxyacetophenone, a carbazolyl-O-acyl-oxime, an ?-haloarylketone and an ?-haloaryl sulfone; L3 and L4 represent a substituted or unsubstituted divalent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable functional group selected from the group consisting of an acrylate, a methacrylate, a styrene, an acryl amide, a methacryl amide, a maleate, a fumarate, an itaconate, an vinyl ether, an allyl ether, an allyl esterType: ApplicationFiled: January 22, 2010Publication date: February 23, 2012Applicant: AGFA GRAPHICS NVInventors: Johan Loccufier, Luc Vanmaele, Hedwige Docx, Nadine Willems
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Publication number: 20120041092Abstract: A coating composition includes a UV curable film forming resin; a thixotropic and/or pseudoplastic anti-settling agent selected from at least one of an amine salt of a synthetic wax, a microcrystalline cellulose compound (MCC), a urea urethane, or a urethane enzymatically modified starch; a mar/scratch resistant additive selected from at least one of a mineral abrasive, glass particles, and ceramic particles; and water.Type: ApplicationFiled: August 10, 2010Publication date: February 16, 2012Applicant: Valspar SourcingInventor: James Madison Bohannon
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Publication number: 20120021383Abstract: A radically curable polyurethane composite for dental restorations, including provisional restorations, includes polyurethane dimethacrylate prepolymers that have at least one flexible unit within a polyurethane dimethacrylate backbone, and one or more dimethacrylate monomers. Composite materials made with polyurethane dimethacrylate prepolymers of the invention exhibit superior and optimal properties of flexural strength and deflection-at-break relative to conventional dental resin composites. Composite materials of the invention also provide improved melt-resistance in response to the heat of grinding or finishing, thereby improving the fit of restorations made from the composite and preserving the finishing instruments. Methods of treating a tooth using the radically curable polyurethane composite and methods of making the polyurethane dimethacrylate prepolymers with flexible units is also provided. A kit including the radically curable polyurethane composite is also described.Type: ApplicationFiled: July 23, 2010Publication date: January 26, 2012Applicant: PULPDENT CORPORATIONInventors: Sunny Skaria, Kenneth Berk
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Publication number: 20120021142Abstract: The present invention relates to a liquid crystal alignment layer composition showing excellent adhesive strength to a substrate and a liquid crystal layer and excellent homeotropic alignment of liquid crystals, a liquid crystal alignment layer prepared with the same, a preparation method of the liquid crystal alignment layer, an optical film including the liquid crystal alignment layer, and a display device including the same. According to the present invention, provided are a liquid crystal alignment layer composition which comprises 1-50 wt % of a photocurable resin binder, 0.01-5 wt % of an amine compound selected from the group consisting of primary and secondary amino-based coupling agents, 0.Type: ApplicationFiled: April 8, 2010Publication date: January 26, 2012Inventors: Dae-Hee Lee, Moon-Soo Park
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Publication number: 20120013690Abstract: This disclosure is generally directed to curable solid inks, such as radiation-curable solid inks, and their use in forming images, such as through transfuse printing. More specifically, this disclosure is directed to radiation-curable solid inks, such as ultraviolet-light-curable phase-change inks, that comprise curable and non-curable waxes.Type: ApplicationFiled: July 13, 2010Publication date: January 19, 2012Applicant: XEROX CORPORATIONInventors: Marcel P. BRETON, Michelle N. Chrétien, Christopher A. Wagner, Ian R. Duffy, Peter G. Odell
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Publication number: 20110319515Abstract: A curable divinylarene dioxide resin composition including (a) at least one divinylarene dioxide, (b) at least one cationic photoinitiator, and (c) optionally, at least one pigment material; a process for making the curable divinylarene dioxide resin composition; and a cured divinylarene dioxide resin composition made therefrom. The cured product made from the above curable divinylarene dioxide resin composition offers improved properties and are useful for various applications including ink formulations.Type: ApplicationFiled: June 27, 2011Publication date: December 29, 2011Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: James Wells Carter, Maurice J. Marks, Ludovic Valette, Gyongi Gulyas
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Patent number: 8076393Abstract: An ink composition includes (A) at least one polymerizable compound selected from the group consisting of a monofunctional radically polymerizable monomer having an aliphatic cyclic structure, an N-vinyllactam, and an aromatic monofunctional radically polymerizable monomer, (B) a radical polymerization initiator, (C) a pigment, and (D) a graft copolymer having a repeating unit represented by the formula below in a graft chain: wherein R denotes a hydrogen atom or a methyl group, X denotes a single bond, —O—, —CO—, —COO—, —CONR1—, —OCO—, or a phenylene group, R1 denotes a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, L denotes a single bond or a divalent linking group, Z denotes —NR2R3, R2 and R3 independently denote a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, and R2 and R3 may be bonded to each other to form a ring.Type: GrantFiled: August 26, 2008Date of Patent: December 13, 2011Assignee: FUJIFILM CorporationInventors: Kaoru Tojo, Norihide Shimohara
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Patent number: 8053486Abstract: The invention provides a coating composition comprising a thermal plastic resin selected from the group consisting of a polycycloolefin resin, polyester resin, polyacrylate resin, and a mixture thereof; and a radiation curable resin comprising a radiation polymer containing at least one mono- or multi-functional acrylic acid based monomer as a polymerization unit, an oligomer containing an ethylenically unsaturated functional group, and a photoinitiator, wherein the radiation curable resin is used in an amount of 220-1000% by weight on the basis of the weight of the thermal plastic resin. The invention improves the hardness of the coating composition, prevent the coated substrate from being scratched or impaired, and impart the substrate with high transparency without causing warping problem.Type: GrantFiled: December 19, 2008Date of Patent: November 8, 2011Assignee: Eternal Chemical Co., Ltd.Inventors: Lung-Lin Hsu, Sue-Hong Liu
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Publication number: 20110262711Abstract: Curable, phase-change compositions and inks used for printing three-dimensional objects including a curable monomer, a photoinitiator, a wax and a gellant, where the composition of the cured formulation has a room temperature modulus of from about 0.01 to about 5 Gpa. The curable monomer includes acrylic monomer, polybutadiene adducted with maleic anhydride, aliphatic urethane acrylate, polyester acrylate, 3-acryloxypropyltrimethoxysilane, or acryloxypropyl t-structured siloxane.Type: ApplicationFiled: April 22, 2010Publication date: October 27, 2011Applicant: XEROX CORPORATIONInventors: Naveen CHOPRA, Michelle N. Chretien, Barkev Keoshkerian
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Patent number: 8034455Abstract: Multilayer radiation curable liquid coating compositions are provided that include one or more UV oligomers including at least one aliphatic urethane acrylic oligomer; at least one acrylate diluent monomer selected from a mono-, bi-, and tri-functional reactive acrylate diluent monomers; at least one photo-initiator; at least one UV absorber; at least one hindered amine light stabilizer; and at least one antioxidant, where the liquid composition does not comprise a solvent and does not comprise an adhesion promoter. The UV oligomer in the base coat composition has elongation higher than 200% and tensile strength lower than 1000 psi. The UV oligomer in the top coat composition has tensile strength higher than 5000 psi. A coating system is provided that includes a liquid primer coat composition, a liquid base coat composition and a liquid top coat composition.Type: GrantFiled: June 6, 2008Date of Patent: October 11, 2011Assignee: NovaSolar Holdings LimitedInventors: Fei Wang, Philip Chihchau Liu
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Publication number: 20110244203Abstract: A UV curable intermediate transfer media, such as a belt, that includes a first supporting substrate, such as a polyimide substrate layer, and a second surface layer of a mixture of a carbon nanotube component, a photoinitiator component, and an organic inorganic hybrid component.Type: ApplicationFiled: March 30, 2010Publication date: October 6, 2011Applicant: XEROX CORPORATIONInventors: Jin Wu, Yuhua Tong, Brian P. Gilmartin, Jonathan H. Herko
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Publication number: 20110245363Abstract: The present invention relates to a photo-sensitive resin composition having superior heat-resistant and mechanical property, and a protective film for printed circuit board, and particularly provides a photo-sensitive resin composition including an acid-modified oligomer, a photo-polymerizable monomer, a photo-initiator, an epoxy resin, and a butadiene-modified epoxy resin including epoxy group and at least one double bond in the main chain, and a protective film for printed circuit board prepared by using the composition.Type: ApplicationFiled: June 20, 2011Publication date: October 6, 2011Applicant: LG CHEM, LTD.Inventors: Bo-Yun CHOI, Byung-Ju CHOI, Woo-Jae JEONG, Kwang-Joo LEE, Min-Su JEONG
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Patent number: 8030227Abstract: A photocurable fixture for orthopedic surgery has a base material and a photocurable resin retained in the base material and containing a urethane (meth)acrylate oligomer and a photopolymerization initiator which absorbs a light within a range of 400 to 700 nm. The urethane (meth)acrylate oligomer being represented by the following formula (I), where A denotes a diisocyanate residue, and each of X and Y denotes a residue obtained by removing a hydroxy group from a (meth)acrylate having a hydroxy group. In formula (I) at least 40 mol % of X and Y is a residue obtained by removing a hydroxy group from a (meth)acrylate having a hydroxy group represented by the following formula (II), where in Formula (II) each of R1 to R6 denotes a hydrogen atom or a methyl group.Type: GrantFiled: February 13, 2006Date of Patent: October 4, 2011Assignee: Alcare Co., Ltd.Inventors: Nobuyasu Nakasugi, Yoshikazu Matsumoto
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Publication number: 20110237700Abstract: A photopolymerizable polymer micelle includes a spherical micelle that encapsulates a hydrophobic photopolymerization initiator, the spherical micelle being formed by a block copolymer having a hydrophilic block segment and a hydrophobic block segment, the block copolymer having a number average molecular weight exceeding 10000, and the hydrophobic block segment at least partially having a radically polymerizable group.Type: ApplicationFiled: March 24, 2011Publication date: September 29, 2011Applicant: Seiko Epson CorporationInventor: Toshiyuki Miyabayashi
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Publication number: 20110234680Abstract: [Object] To provide a recording method by which the occurrence of bleeding and repelling in a cured layer can be suppressed during overprinting. [Solution] In a recording method, a first ink composition containing a colorant, a photopolymerizable compound, and a photopolymerization initiator is ejected from a recording head onto a recording medium; light is emitted from a light source to the first ink composition that has adhered to the recording medium with the result that the first ink composition is cured at a cure rate that is in the range from 70 to 95%; a second ink composition containing a colorant, a photopolymerizable compound, and a photopolymerization initiator is ejected from a recording head to the first ink composition that has been cured on the recording medium; and light is emitted from a light source to the second ink composition.Type: ApplicationFiled: March 17, 2011Publication date: September 29, 2011Inventors: Tetsuya AOYAMA, Keitaro NAKANO