Specified Rate-affecting Material Contains Phosphorous Patents (Class 522/64)
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Publication number: 20110230582Abstract: An energy ray-curable inkjet ink composition comprising polymerizable compounds containing a monofunctional monomer, (A) a reactive oligomer having a rate of elongation of 130% or more and a weight average molecular weight of not less than 800 and less than 3,000 and (B) a reactive oligomer having a rate of elongation of 130% or more and a weight average molecular weight of not less than 3,000 and not more than 8,000, provided that one of the reactive oligomers (A) and (B) is not more than difunctional and the other is not less than difunctional, at least one polymerization initiator selected from the group consisting of (C) an acylphosphine oxide initiator and (D) an ?-aminoalkylphenone initiator, a surface tension modifier, and a colorant.Type: ApplicationFiled: November 19, 2009Publication date: September 22, 2011Inventors: Katsuyuki Kito, Satoshi Kobayashi, Kunihiko Koyama
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Publication number: 20110223391Abstract: The invention provides an ink composition for ink jet recording of the active energy beam curing type that comprises 30 to 80% by mass of a monofunctional acrylate having a monoalicyclic structure, 1 to 10% by mass of an urethane acrylate oligomer and 5 to 30% by mass of N-vinylcaprolactam together with a polymerization initiator and a coloring agent, and has a viscosity at 40° C. of 5 to 20 mPa·s and a surface tension of 20 to 50 mN/m. The ink composition exhibits good ejection capability and curability, is less smelling and of great safety, and has good adhesion to a variety of substrate materials.Type: ApplicationFiled: December 5, 2008Publication date: September 15, 2011Applicant: THE INCTEC INC.Inventors: Keiji Nishimura, Fumie Yamazaki, Syoichi Kumamoto
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Publication number: 20110214717Abstract: Provided are photovoltaic modules that can include a liquid encapsulant formulation. Also provided are such liquid encapsulant formulations.Type: ApplicationFiled: November 12, 2009Publication date: September 8, 2011Applicant: PYTHAGORAS SOLAR INC.Inventors: Izhar Halahmi, Pasha Solel, Itay Baruchi
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Patent number: 8013314Abstract: The present invention relates to curable silicone compositions which include a fluorescent agent for detection purposes and which have a cure system which enables the silicone compositions to possess improved depth of cure. The silicone compositions are photocurable, and may also be moisture or heat curable.Type: GrantFiled: November 18, 2005Date of Patent: September 6, 2011Assignee: Henkel CorporationInventors: Michael P. Levandoski, Hsien-Kun Chu, Richard Corrao
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Patent number: 8013032Abstract: Disclosed is a dental composition comprising 0.01 to 10 parts by weight of at least one kind of (a) a visible light-photopolymerization catalyst compound and one or more kinds of (b) di(meth)acrylate compounds represented by the general formula (I): wherein R1 and R2 each independently represent hydrogen or a methyl group, and a repeating unit number n of an ethylene oxide group is from 9 to 50.Type: GrantFiled: March 4, 2009Date of Patent: September 6, 2011Assignee: Kabushiki Kaisha ShofuInventors: Jun Uchida, Mitsuharu Mizuno, Mitsuji Teramae
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Publication number: 20110201718Abstract: The UV-curable resin compositions for optical discs are characterized in that they comprise (A) 15-70 wt % of a (meth)acrylate monomer that has an ethylene oxide chain in the molecule, (B) 5-50 wt % of a urethane (meth)acrylate, (C) 2-50 wt % of an epoxy (meth)acrylate, and (D) 1-10 wt % of a photopolymerization initiator, in the resin composition. The glass transition temperature of cured films thereof is 10-65° C., and the maximum value of the dynamic loss factor tan ? of the cured films is in the range of 0.35-0.73.Type: ApplicationFiled: November 4, 2009Publication date: August 18, 2011Applicant: NIPPON KAYAKU KABUSHIKI KAISHAInventors: Masahiro Naitou, Daisuke Kobayashi, Jun Kidoba, Hiroki Tsutsumi, Yuichiro Matsuo
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Publication number: 20110201717Abstract: A photocurable adhesive composition is disclosed herein that has high adhesive strength and optical clarity and which in the cured state is reworkable and exhibits low propensities for exhibiting glow mark and pooling effects. The composition contains a chain transfer agent, an urethane (meth)acrylate having a plurality of ethylenically unsaturated groups, a (meth)acrylate monomer and a photoinitiator. The composition may optionally contain a light stabilizer.Type: ApplicationFiled: December 29, 2008Publication date: August 18, 2011Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: Robert Paul Held, Hassan Modamed Farah
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Publication number: 20110196057Abstract: A curable solid ink composition including a curable component, a non-curable component including an ethoxylated octylphenol derivative, a photoinitiator, and a colorant. The curable solid ink composition has a viscosity in the range of less than 10 cPs at 90° C., a shrinkage value of less than 3%, and a superior curing rate compared to existing curable solid ink compositions. The ethoxylated octylphenol derivatives may be prepared by reacting an ethoxylated octylphenol, a linear alcohol, and diisocyanates or polyisocyanates.Type: ApplicationFiled: February 11, 2010Publication date: August 11, 2011Applicant: XEROX CORPORATIONInventors: Marcel P. BRETON, Michelle N. CHRÉTIEN, Jeffrey H. BANNING, Stephan V. DRAPPEL, Ian R. DUFFY, Christopher A. WAGNER
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Publication number: 20110183081Abstract: A photocurable ink composition includes (A) a polymerizable compound, (B) an acylphosphine oxide-based photopolymerization initiator, and (C) at least one compound selected from a hindered amine-based compound with a mass-average molecular weight of 2000 to 4000 and a hydroxyphenyltriazine-based compound of formula (1): (wherein R1, R2, and R3 each independently represent an organic group). The proportion of the component (C) is in the range of 0.2% by mass to 2.0% by mass.Type: ApplicationFiled: January 21, 2011Publication date: July 28, 2011Applicant: Seiko Epson CorporationInventors: Hiroki Nakane, Hiroyuki Kajimoto, Chigusa Sato, Taketoshi Kagose, Jun Ito, Hiroaki Kida, Akira Kooguchi, Toru Saito, Toshiyuki Miyabayashi, Hiroyuki Onishi
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Publication number: 20110165539Abstract: A dental adhesive composition has an adhesive component and an activator component. The adhesive composition has a volatile organic solvent component, one or more polymerizable (meth)acrylate compounds optionally containing fillers, and a polymerization photoinitiator. The adhesive component may also be a substantially homogeneous mixture of one or more polymerizable (meth)acrylate compounds and an effective amount of a photoinitiator, without a solvent. The activator component includes an aromatic sulfinate salt and an activator component solvent. A method for adhering a restorative to a dental surface includes preparing the surface for restoration; applying a mixture of an adhesive component and an activator component to the prepared cavity, thereby forming a coated cavity surface; and, applying a direct or indirect dental restorative to the coated cavity surface.Type: ApplicationFiled: October 8, 2010Publication date: July 7, 2011Inventors: JUNJIE SANG, Paul D. Hammesfahr
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Patent number: 7968618Abstract: A one-component self-etching self-priming dental adhesive composition is disclosed. The composition comprises glycerol phosphate di(meth)acrylate monomer, at least one mono-functional polymerizable monomer having just one ethylenically unsaturated group, at least one multi-functional polymerizable monomer having at least two ethylenically unsaturated groups, at least one aprotic solvent, at least one protic solvent, and at least one polymerization initiator.Type: GrantFiled: July 13, 2010Date of Patent: June 28, 2011Assignee: Kerr CorporationInventors: Xiangxu Chen, Xuejun Qian
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Publication number: 20110152397Abstract: A radiation curable solid ink composition comprising at least one curable wax that is curable by free radical polymerization; at least one monomer, oligomer, or prepolymer; at least one non-curable wax; at least one free-radical photoinitiator or photoinitiating moiety; and a colorant; wherein the components form a curable ink composition that is a solid at a first temperature of from about 20 to about 25° C.; and wherein the components form a liquid composition at a second temperature of greater than about 40° C.Type: ApplicationFiled: December 18, 2009Publication date: June 23, 2011Applicant: Xerox CorporationInventors: Marcel P. Breton, Michelle N. Chrétien, Peter G. Odell, Christopher Wagner
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Publication number: 20110136932Abstract: Polymers, methods of use thereof, and methods of decomposition thereof, are provided. One exemplary polymer, among others, includes, a photodefinable polymer having a sacrificial polymer and a photoinitiator.Type: ApplicationFiled: October 28, 2010Publication date: June 9, 2011Applicant: GEORGIA TECH RESEARCH CORPORATIONInventors: Paul A. Kohl, Sue Ann Bidstrup-Allen, Clifford Lee Henderson
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Publication number: 20110123732Abstract: Exemplary embodiments provide an intermediate transfer member that can include a plurality of carbon nanotubes dispersed in an ultraviolet (UV) curable polymer in an amount to allow a bulk curing of the UV curable polymer and to provide the cured polymer an electrical resistivity and/or a mechanical modulus useful for electrostatographic devices and processes.Type: ApplicationFiled: November 24, 2009Publication date: May 26, 2011Applicant: XEROX CORPORATIONInventors: Geoffrey M. T. Foley, Jin Wu, Satchidanand Mishra
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Publication number: 20110123723Abstract: A photosensitive resin composition comprises: 0.01 wt %-10 wt % of reflective particles; 0 wt %-12 wt % of pigment; 1 wt %-10 wt % of dispersant; 1.5 wt %-5 wt % of dispersion resin; 2 wt %-25 wt % of optically active polymer; 1 wt %-22 wt % of optical active monomer; 0.4 wt %-5 wt % of epoxy resin; 5 wt %-85 wt % of solvent; 0.1 wt %-3 wt % of photoinitiator; and 0.01 wt %-3.5 wt % of additives.Type: ApplicationFiled: November 24, 2010Publication date: May 26, 2011Applicant: BOE TECHNOLOGY GROUP CO., LTD.Inventor: Jiuxia YANG
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Publication number: 20110109849Abstract: The present invention relates to an acrylic composition for optical elements, a protective film for optical elements, a polarizer, and a liquid crystal display (LCD). According to the present invention, by adding a proper amount of an antistatic agent to a composition including a photo-polymerizable acrylic polymer, which is cured by irradiation of radial rays such as ultraviolet rays (UVs), and a polymerization initiator at a predetermined ratio, an aging process can be skipped during curing, thereby simplifying a preparation process and providing an acrylic composition for optical elements, a protective film for optical elements, a polarizer, and an LCD, which have excellent anti-static property during peeling or use, and superior endurance reliability, workability, adhesive property, wettability, and optical characteristics.Type: ApplicationFiled: July 1, 2009Publication date: May 12, 2011Inventors: Hyun Jee Yoo, Hyun Ju Cho, Hak Lim Kim, Jang Soon Kim, Mun Seop Song
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Publication number: 20110104453Abstract: The invention provides an aqueous liquid composition containing a water-soluble monomer, a photopolymerization initiator and an aqueous medium and further containing a polymer emulsion, wherein the water-soluble monomer is a monomer that has two or more ethylenically unsaturated bonds and is curable with an active energy ray.Type: ApplicationFiled: September 22, 2010Publication date: May 5, 2011Applicant: CANON KABUSHIKI KAISHAInventors: Kenji Shinjo, Shinsuke Tsuji, Kouji Harada, Yutaka Kurabayashi
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Publication number: 20110086937Abstract: Disclosed is a sealant composition for liquid crystal display device, the sealant composition including a monomer as expressed in Chemical Formula 1 below wherein X is O, S, or NH, R1 is H or CH3, and R2 is an alkyl group or an aryl group of C2-30.Type: ApplicationFiled: May 27, 2010Publication date: April 14, 2011Inventors: Ki In SON, Joo Hyun Park, Gyu Won Cho
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Publication number: 20110086936Abstract: Disclosed is a sealant composition for a liquid crystal display device, the sealant composition including a (meta) acrylate compound as expressed in Chemical Formula 1 belowType: ApplicationFiled: May 27, 2010Publication date: April 14, 2011Inventors: Ki In SON, Joo Hyun Park, Gyu Won Cho
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Publication number: 20110082228Abstract: The present disclosure relates generally to compositions for nail coatings, and particularly, but not by way of limitation, to polymerizable compositions. The disclosure further relates to methods of making a polymerizable, protective and scratch resistant topcoat layer that can be easily removed.Type: ApplicationFiled: October 5, 2009Publication date: April 7, 2011Applicant: Creative Nail Design, Inc.Inventor: Thong Vu
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Publication number: 20110071232Abstract: The invention relates to a method of increasing the dark storage stability of a UV-curable composition comprising a) at least one oligomer, co-oligomer, polymer or copolymer having at least one ethylenically unsaturated bond or a mixture thereof; or a mixture of at least one ethylenically unsaturated monomer with at least one oligomer, co-oligomer, polymer or copolymer having at least one ethylenically unsaturated bond; or at least one ethylenically unsaturated monomer or mixture of said monomers, and one or more ?-hydroxycycloalkylphenyl ketone or bisacylphosphine oxide photoinitiators, which method comprises adding b) at least one stable sterically hindered nitroxyl free-radical or at least one compound of the benzofuran-2-one type or a mixture of the two compounds.Type: ApplicationFiled: October 20, 2010Publication date: March 24, 2011Inventors: TUNJA JUNG, ANDREAS VALET
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Publication number: 20110057983Abstract: The invention provides an aqueous ink composition including: a) a water-based medium; b) a compound having an ethylenically unsaturated bond; and c) resin particles including a water-insoluble vinyl polymer and a water-insoluble photoinitiator.Type: ApplicationFiled: September 1, 2010Publication date: March 10, 2011Applicant: FUJIFILM CORPORATIONInventors: Takahiro KATO, Takahiro ISHIZUKA, Tomoko KUWABARA, Yasufumi OOISHI
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Publication number: 20110060065Abstract: The present disclosure relates generally to compositions for natural and artificial nail coatings, and particularly, but not by way of limitation, to polymerizable compositions and adhesion-promoting basecoats polymerized therefrom. The disclosure further relates to methods of making a polymerized basecoat that are more easily removed than artificial nail enhancements and more durable and long lasting than nail polish coatings.Type: ApplicationFiled: September 8, 2009Publication date: March 10, 2011Applicant: Creative Nail Design, Inc.Inventors: Thong Vu, Chad Conger
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Publication number: 20110060069Abstract: Energy curable inks formulations are disclosed having improved resistance properties.Type: ApplicationFiled: January 30, 2009Publication date: March 10, 2011Inventors: Ramesh Arora, Percy Agboat
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Publication number: 20110054061Abstract: A sealant for a one drop fill process of the invention contains the following components (1), (2), (3), and (4): (1) a curing agent composed of a reaction product produced by reacting an acid compound and a polyamine containing, within its molecule, at least one active hydrogen and at least two nitrogen atoms; (2) a heat-curable resin; (3) an acylphosphine-based photoinitiator; and (4) a photo-curable resin. A heat-curable resin containing a bisphenol A propylene oxide-modified epoxy resin is preferably used as the heat-curable resin (2), and a photo-curable resin containing a bisphenol A acrylate-modified resin is preferably used as the photo-curable resin (4).Type: ApplicationFiled: January 5, 2010Publication date: March 3, 2011Applicant: ADEKA CORPORATIONInventors: Kazuyuki Itano, Hiroya Fukunga, Hirokatsu Shinano, Rieko Hamada, Takahiro Otsuka
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Publication number: 20110052855Abstract: The present invention relates to an ultraviolet-curable resin composition for an optical disk containing a sulfur-containing compound (A) represented by the following formula (1): (wherein, R1 and R2 each dependently represent a hydrogen atom, a hydroxy group, an alkyloxy group, an alkyl group, an aryl group, a carboxy group, an alkylthio ether group or a halogen atom) a photopolymerizable compound (B) and a photopolymerization initiator (C), and an optical disk having a thin film of the cured product of said resin composition, particularly an optical disk having a reflective film comprising silver or a silver alloy; and said optical disk is prevented from changing the properties of its reflective film comprising silver or a silver alloy, and thus has a higher durability.Type: ApplicationFiled: May 27, 2009Publication date: March 3, 2011Applicant: NIPPONKAYAKU KABUSHIKIKAISHAInventors: Daisuke Kobayashi, Masahiro Naitou, Go Mizutani, Hitoshi Takahashi, Kiyohisa Tokuda
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Patent number: 7896484Abstract: An ink jet recording apparatus comprising a color ink container having a capacity V1 accommodating therein a solvent polymerizable in the presence of an acid and a colorant, a reaction liquid container having a capacity V2 (V2<V1) accommodating therein a reaction liquid comprising a solvent, and a photo-acid generating agent capable of generating an acid when irradiated with light, a stirring container mixing the color ink and the reaction liquid at a mixing ratio of S1:S2 (the color ink:the reaction liquid) to prepare a recording ink, a color ink supply means feeding the color ink to the stirring container, a reaction liquid supply means feeding the reaction liquid to the stirring container, an ink jet recording head ejecting the recording ink to a recording medium, and a supply tube feeding the recording ink to the recording head.Type: GrantFiled: June 5, 2008Date of Patent: March 1, 2011Assignees: Kabushiki Kaisha Toshiba, Toshiba Tec Kabushiki KaishaInventors: Masashi Hiroki, Kazuhiko Ohtsu, Yoshito Endo, Toru Ushirogouchi, Ryozo Akiyama
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Publication number: 20110028586Abstract: The present invention provides an energy ray-curable inkjet ink composition which is excellent in stretchability for a printed film and, at the same time, is excellent in curability, adherability and the continuous discharge property. The present invention relates to an energy ray-curable inkjet ink composition containing at least a coloring material, 8 to 60% by mass of a monofunctional monomer (A) having a glass transition temperature of lower than ?25° C., 25 to 40% by mass of a difunctional oligomer (B) having an elongation rate of 130% or more at 25° C. when a single oligomer is polymerized, at least one kind of a photopolymerization initiator (C) selected from the group consisting of an acylphosphine oxide initiator (C-1), and a mixed initiator (C-2) of an ?-aminoalkylphenone initiator and a thioxanthone initiator, and a surface tension conditioner (D).Type: ApplicationFiled: May 15, 2009Publication date: February 3, 2011Inventors: Katsuyuki Kito, Satoshi Kobayashi, Kunihiko Koyama
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Publication number: 20110028583Abstract: The present invention is directed to an adhesive composition comprising a crosslinkable acrylic copolymer, a multi-functionalized crosslinkable oligomer and a photoinitiator wherein the composition exhibits excellent wet out characteristics as reflected in a tan delta value of at least 0.5, preferably greater than 0.5, more preferable greater than 0.8 as measured at 20° C. resulting from a first curing stage, and improved stiffness and temperature resistance as reflected in a storage elastic modulus of at least 300,000 Pa at 20° C. and a shear adhesion failure temperature of at least 425° F. (218.3° C.) at 1 Kg/in2 (0.155 Kg/cm2), respectively, which result from a second sequential curing stage.Type: ApplicationFiled: August 3, 2009Publication date: February 3, 2011Applicant: Morgan Adhesives CompanyInventors: Timothy Michael Smith, Gary Allan McMaster
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Patent number: 7872058Abstract: An object of the present invention is to provide a photopolymerizable dental composition which causes less change in a color tone before and after curing and exhibits excellent photopolymerizability to irradiation in a wide wavelength range, and has also excellent thin-layer surface curability, and to provide a photopolymerization initiator used therefor. Disclosed is a visible light-polymerizable dental composition which does not substantially contain an amine compound as a photosensitizer, comprising 0.01 to 10 parts by weight of a (bis)acylphosphine oxide compound, 0.01 to 10 parts by weight of an ?-diketone compound and 100 parts by weight of a polymerizable monomer.Type: GrantFiled: March 4, 2009Date of Patent: January 18, 2011Assignee: Kabushiki Kaisha ShofuInventors: Jun Uchida, Mitsuharu Mizuno, Mitsuji Teramae
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Patent number: 7872057Abstract: A liquid radiation and thermally curing composition characterized in, that said composition comprises at least one ester between at least one tri or polyalcohol and acrylic and/or methacrylic acid, which ester has at least two hydroxyl groups, at least one acrylic or methacrylic double bond, a hydroxyl value of 50-500 mg KOH/g and a double bond concentration of 1-10 mmoles/g, at least one crosslinking agent for hydroxyl functional compounds, which crosslinking agent optionally has at least one olefinic double bond, and an additive package comprising at least one photoinitiator, radical scavenger, light stabilizer, wetting agent and/or leveling agent, and optionally at least one monomeric or oligomeric reactive diluent.Type: GrantFiled: October 2, 2006Date of Patent: January 18, 2011Assignee: Perstorp Specialty Chemicals ABInventors: David James, Kent Sörensen, Henrik Bernquist
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Publication number: 20100324164Abstract: The present invention relates to a photocurable resin composition including the following ingredients (A), (B) and (C): (A) a linear chain epoxy resin represented by the following general formula (1), in which m indicates an integer of from 2 to 10, and R1 and R2 each represent a hydrogen atom or a fluorine atom; (B) an alicyclic epoxy resin having at least two epoxy groups in one molecule thereof; and (C) a phosphorus fluoride-based photopolymerization initiator.Type: ApplicationFiled: June 18, 2010Publication date: December 23, 2010Applicant: NITTO DENKO CORPORATIONInventors: Yukiko HIGO, Hiroshi NORO
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Publication number: 20100304630Abstract: A photocurable resin composition is provided that exhibits an excellent storage stability, that can be easily cured by ultraviolet radiation, and that cures to form a cured film that exhibits an excellent ultraviolet absorbing performance at around the 300 nm wavelength, an excellent physical strength, an excellent stain resistance, an excellent film uniformity, and an excellent adherence by the film. This photocurable resin composition comprises the following components (A) to (E): (A) 100 weight parts of a multifunctional acrylate or a multifunctional methacrylate, (B) 1 to 100 weight parts of an aliphatically unsaturated bond-containing organoalkoxysilane, (C) 1 to 300 weight parts colloidal silica, (D) 0.01 to 20 weight parts of an ultraviolet absorber that has an absorption wavelength at 220 to 400 nm, and (E) 0.01 to 30 weight parts of a photopolymerization initiator that has an absorption wavelength at 300 to 450 nm.Type: ApplicationFiled: September 1, 2008Publication date: December 2, 2010Inventors: Ikutaro Morikawa, Mari Wakita, Motoshi Sasaki
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Publication number: 20100291327Abstract: A UV-curing primer contains barium sulfate, methods for manufacturing same, methods for coating substrates therewith and the coated substrates.Type: ApplicationFiled: April 27, 2007Publication date: November 18, 2010Inventors: Thomas Rentschler, Horst Van Beek, Reinhold Kopp
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Publication number: 20100260941Abstract: The present disclosure is directed to a process for forming a reinforced ultraviolet (UV) radiation-curable composite. The composite may be formed by applying reinforcing layers and resin layers to a substrate. The resin composition may include an aliphatic urethane acrylate oligomer, a polyfunctional acrylate monomer, and a photoinitiator. The composite formed on the substrate may be exposed to UV radiation to cure the composite on the substrate. The composite may be characterized in that it is cured within 10 minutes of exposure to UV radiation and does not exhibit oxygen inhibition effects, such as, for example, surface tack. The reinforced UV-curable composite may find utility, for example, as a rapid field repair patch in aerospace applications, among others.Type: ApplicationFiled: April 8, 2009Publication date: October 14, 2010Applicant: Bayer MaterialScience LLCInventors: Alan D. Bushmire, Jan L. Clatty, Michael J. Dvorchak, Charles A. Gambino, Christine Mebane
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Patent number: 7806050Abstract: The invention provides an ink composition which includes a polymerization initiator, a polymerizable compound, a colorant, and a high molecular compound having a repeating unit represented by the following formula (I). In formula (I), n represents an integer of from 1 to 5.Type: GrantFiled: February 5, 2007Date of Patent: October 5, 2010Assignee: FUJIFILM CorporationInventor: Ippei Nakamura
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Publication number: 20100247940Abstract: The invention provides an optical resin composition being transparent, having suitable adhesion and necessary impact absorption for protection of an image display device etc., not affecting constituent materials of a image display panel, and being excellent in reliability, and an optical resin material using the same. Disclosed is an optical resin composition containing (A) a first acrylate derivative that is a compound having one polymerizable unsaturated bond in its molecule, (B) a second acrylate derivative that is a compound having two or more polymerizable unsaturated bonds in its molecule, and (C) an acrylate derivative polymer, and an optical resin material produced by curing reaction of the optical resin composition.Type: ApplicationFiled: October 31, 2007Publication date: September 30, 2010Applicant: Hitachi Chemical Co., Ltd.Inventors: Tooru Takahashi, Yasuhisa Ishida, Hisashige Kanbara, Hidekazu Kondou
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Publication number: 20100249261Abstract: The present invention provides an ink composition containing: a radical polymerizable compound; a photopolymerization initiator, and a chain transfer agent; and the radical polymerizable compound includes a monofunctional monomer at a ratio of 85% by weight or more in the total weight of the radical polymerizable compound.Type: ApplicationFiled: March 15, 2010Publication date: September 30, 2010Applicant: FUJIFILM CORPORATIONInventor: Kazuhiro YOKOI
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Publication number: 20100249262Abstract: An oxime ester compound of formula (I) useful as a photopolymerization initiator. A photopolymerization initiator having the oxime ester compound as an active ingredient is activated through efficient absorption of light of long wavelength, e.g., 405 nm or 365 nm, to exhibit high sensitivity. In formula (I), R1 and R2 are each R11, OR11, COR11, SR11, CONR12R13, or CN; R11, R12, and R13 are each hydrogen, a C1-C20 alkyl group, C6-C30 aryl group, a C7-C30 arylalkyl group, or a C2-C20 heterocyclic group; R3 and R4 are each R11, OR11, SR11, COR11, CONR12R13, NR12COR11, OCOR11, COOR11, SCOR11, OCSR11, COSR11, CSOR11, CN, halogen, or a hydroxyl group; a and b is each 0 to 4; X is oxygen, sulfur, selenium, CR31R32, CO, NR33, or PR34; and R31, R32, R33, and R34 each have the same meaning as R1.Type: ApplicationFiled: December 25, 2007Publication date: September 30, 2010Applicant: ADEKA CORPORATIONInventors: Daisuke Sawamoto, Nobuhide Tominaga
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Publication number: 20100247797Abstract: A photocurable composition is provided that includes a compound represented by Formula (I) below, in Formula (I), X denotes O, S, or NRa, n1 denotes 0 or 1, and R1 to R14 and Ra independently denote a hydrogen atom, a halogen atom, or a monovalent substituent, at least one of R1 to R14 and Ra not being a hydrogen atom.) There is also provided an inkjet recording method that includes (a1) a step of discharging the photocurable composition onto a recording medium and (b1) a step of curing the photocurable composition by irradiating the discharged photocurable composition with light.Type: ApplicationFiled: March 26, 2010Publication date: September 30, 2010Applicant: FUJIFILM CORPORATIONInventor: Tsutomu UMEBAYASHI
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Patent number: 7803850Abstract: A compound that exhibits excellent color tone stability and physical properties as well as excellent photopolymerization activity over a wide region from near-ultraviolet to visible region, permitting relaxed operation under ambient light, so that wide application can be found in the dental field and photopolymerization industry; and a relevant photopolymerization initiator and hardenable composition. In particular, there is provided a novel camphorquinone derivative having an acylphosphine oxide group [—(C?O)—(P?O)<] in each molecule. Further, there is provided a photopolymerization initiator comprising the camphorquinone derivative having an acrylphosphine oxide group [—(C?O)—(P?O)<] in each molecule as an indispensable component, loaded with at least one member selected from among a polymerization accelerator, a photoacid generator, a photosensitizer and a (bis)acylphosphine oxide, and provided a hardenable composition comprising the initiator.Type: GrantFiled: March 13, 2006Date of Patent: September 28, 2010Assignee: Kabushiki Kaisha ShofuInventors: Kunio Ikemura, Kensuke Ichizawa, Yoshiyuki Jogetsu
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Patent number: 7795324Abstract: A novel polymeric initiator is disclosed comprising a dendritic polymer core with at least one initiating functional group as an end group. The dendritic polymeric core is preferably a hyperbranched polymer. The polymeric initiators are useful in radiation curable compositions such as varnishes, lacquers and printing inks and are especially useful in radiation curable inkjet inks.Type: GrantFiled: June 28, 2005Date of Patent: September 14, 2010Assignee: Agfa Graphics, N.V.Inventors: Johan Loccufier, Luc Vanmaele, Jaymes Van Luppen, Roland Claes, Yu Chen, Holger Frey
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Publication number: 20100222447Abstract: A photo-crosslinkable polyolefin composition comprises a polyolefin, a source of functionality receptive to crosslinking by UV radiation, a cationic photoinitiator and optionally includes a free-radical photoinitiator, a crosslinking accelerator or sensitizer, and other additives such as compatibilizers, inorganic fillers, nanofillers, glass, polymeric and ceramic microspheres, glass fibres, flame retardants, antioxidants, stabilizers, processing aids, foaming agents and pigments. A method for manufacturing a UV-crosslinked polyolefin article comprises forming an article by extruding, moulding or otherwise forming the UV-crosslinkable polyolefin composition and subjecting the article to UV radiation on-line with the extrusion, moulding or other forming operation.Type: ApplicationFiled: May 14, 2010Publication date: September 2, 2010Applicant: SHAWCOR LTD.Inventors: Peter Jackson, Eileen Wan
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Publication number: 20100222448Abstract: Disclosed is an aqueous polyurethane dispersion obtained by dispersing in water a reaction product obtained by reacting a reaction mixture comprising at least one organic, aliphatic, cycloaliphatic or aromatic di, tri or poryisocyanate, at least one isocyanate reactive polycarbonate diol, triol or polyol, at least one compound comprising at least one isocyanate reactive group and at least one free radically polymerisable unsaturated group, and at least one compound comprising at least one isocyanate reactive group and at least one at least dispersing active group, and optionally at least one compound comprising at least two isocyanate reactive groups and having a molecular weight of less than 1000 g/mol.Type: ApplicationFiled: March 16, 2006Publication date: September 2, 2010Applicant: PERSTORP SPECIALTY CHEMICALS ABInventors: Göran Ziegler, David James, Kent Sörensen
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Publication number: 20100212824Abstract: The present invention relates to photocurable elastomer compositions and methods of preparation and use of such compositions for cure-in-place applications such as gaskets. The curable compositions generally include an elastomer component, a monofunctional and/or multifunctional reactant and a photoinitiator that in various aspects may be a visible and/or UV curing initiator. The various components may be present in different amounts, depending on the combination of components and composition desired.Type: ApplicationFiled: June 19, 2006Publication date: August 26, 2010Applicant: HENKEL CORPORATIONInventors: James E. Lionberger, John G. Woods, Joel D. Schall
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Publication number: 20100196704Abstract: [Problem] To provide a composite film having light-curing property and weather resistance. [Means for solving] A composite film is one that comprises at least a urethane polymer, wherein both an initial b* value of the composite film measured by a spectrocolorimeter (value at an angle of 15 degrees) and a b* value after performing an accelerated weathering test for 120 hours (value at an angle of 15 degrees) are 4.0 or less, and a non-volatile component after heating the composite film at 130° C. for two hours is 96% or more.Type: ApplicationFiled: April 8, 2009Publication date: August 5, 2010Applicant: Nitto Denko CorporationInventors: Hidenori Suzuki, Masanori Uesugi, Makoto Kai, Mitsuyoshi Shirai
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Patent number: 7767731Abstract: A one-component self-etching self-priming dental adhesive composition is disclosed. The composition comprises glycerol phosphate di(meth)acrylate monomer, at least one mono-functional polymerizable monomer having just one ethylenically unsaturated group, at least one multi-functional polymerizable monomer having at least two ethylenically unsaturated groups, at least one aprotic solvent, at least one protic solvent, and at least one polymerization initiator.Type: GrantFiled: December 29, 2005Date of Patent: August 3, 2010Assignee: Kerr CorporationInventors: Xiangxu Chen, Xuejun Qian
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Patent number: 7754779Abstract: An ink for an ink jet printer includes an ink vehicle of at least one radically curable, multifunctional acrylate monomer or oligomer, at least one colorant, and at least one photoinitiator. The ink has a low viscosity at low jetting temperatures of 30 to 50° C. and is curable upon exposure to ultraviolet radiation.Type: GrantFiled: January 13, 2005Date of Patent: July 13, 2010Assignee: Xerox CorporationInventors: Peter G. Odell, Adela Goredema
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Patent number: 7750079Abstract: Compositions, such as lens precursor compositions, and methods for producing lens precursor compositions have been invented. The present methods include forming a premix composition, which can include one or more monomeric components, forming a macromer composition, which includes one or more silicon containing macromers, forming a premix/initiator composition, which can include a photoinitiator, and contacting the premix/initiator composition with the macromer composition to form a polymerizable monomer-containing composition useful in the production of producing silicone hydrogel contact lenses.Type: GrantFiled: August 7, 2006Date of Patent: July 6, 2010Assignee: CooperVision International Holding Company, LPInventors: Sarah L. Almond, John H. D. Browning
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Patent number: 7750064Abstract: An antibacterial measure using titanium oxide includes mixing titanium oxide in a resin to form a coating resin, and then coating a key surface with the coating resin. This method requires formation of a coating layer on a resin molding and thus increases the number of the production steps and cost. Furthermore, in the method, a coating film containing an antibacterial agent is scraped off light by little at each time of keying, and thus the film is finally completely removed to lose its antibacterial function. A conceivable measure against this includes directly mixing a resin and an antibacterial agent. However, titanium oxide used as an antibacterial agent degrades a raw material resin. It has recently be thought that photocatalytic apatite as a substitute for titanium oxide also causes chalking, and an antibacterial coating layer has been formed on a surface of a resin molding.Type: GrantFiled: January 5, 2006Date of Patent: July 6, 2010Assignee: Fujitsu LimitedInventors: Masato Wakamura, Noriyasu Aso