Heterocyclic Ring Containing Dnrm Patents (Class 522/75)
  • Publication number: 20080268354
    Abstract: A colored photopolymerizable composition including a pigment, a dispersant, a solvent, a polymerizable compound and a photopolymerization initiator, the solvent further including a solvent (A) having a boiling temperature of from 100° C. to 200° C. and a solvent (B) having a boiling temperature of from 150° C. to 330° C. and an SP value according to the Okitsu method of from 9.5 (cal/cm3)1/2 to 11(cal/cm3)1/2, the solvent (B) being included in an amount of at least 5 parts by mass with respect to 100 parts by mass of the colored photopolymerizable composition; a color filter using the colored photopolymerizable composition; and a method for producing a color filter.
    Type: Application
    Filed: April 28, 2008
    Publication date: October 30, 2008
    Applicant: FUJIFILM CORPORATION
    Inventor: Shigekazu Suzuki
  • Patent number: 7436115
    Abstract: The present invention discloses a method for fabricating an electroluminescent lamp that includes a step in which an electroluminescent active layer is formed by curing a UV curable electroluminescent composition. Embodiments of the method of the present invention in which each layer of a multilayer electroluminescent device are fabricated from UV curable compositions are also disclosed. A UV curable dielectric composition suitable for utilization in an electroluminescent lamp is also provided.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: October 14, 2008
    Inventors: Roy C. Krohn, Scott E. Howe, Christopher C. Ryan
  • Publication number: 20080214692
    Abstract: The present invention relates to methods for making oxidation resistant homogenized polymeric materials and medical implants that comprise polymeric materials, for example, ultra-high molecular weight polyethylene (UHMWPE). The invention also provides methods of making antioxidant-doped medical implants, for example, doping of medical devices containing, cross-linked UHMWPE with vitamin E by diffusion and annealing the antioxidant doped UHMWPE in a super critical fluid, and materials used therein.
    Type: Application
    Filed: August 18, 2006
    Publication date: September 4, 2008
    Applicant: The General Hospital Corporation dba Massachusetts General Hospital
    Inventors: Orhun K. Muratoglu, Ebru Oral
  • Patent number: 7417074
    Abstract: There is disclosed an ink jet recording apparatus comprising a color ink container having a capacity V1 accommodating therein a solvent polymerizable in the presence of an acid and a colorant, a reaction liquid container having a capacity V2 (V2<V1) accommodating therein a reaction liquid comprising a solvent, and a photo-acid generating agent capable of generating an acid when irradiated with light, an stirring container mixing the color ink and the reaction liquid at a mixing ratio of S1:S2 (the color ink:the reaction liquid) to prepare a recording ink, a color ink supply means feeding the color ink to the stirring container, a reaction liquid supply means feeding the reaction liquid to the stirring container, an ink jet recording head ejecting the recording ink to a recording medium, and a supply tube feeding the recording ink to the recording head.
    Type: Grant
    Filed: March 22, 2004
    Date of Patent: August 26, 2008
    Assignees: Toshiba Tec Kabushiki Kaisha, Kabushiki Kaisha Toshiba
    Inventors: Masashi Hiroki, Kazuhiko Ohtsu, Yoshito Endo, Toru Ushirogouchi, Ryozo Akiyama
  • Publication number: 20080200579
    Abstract: A photopolymerizable composition including a cationically polymerizable compound and a cation generating agent represented by formula (1): D-L-A ??Formula (1) wherein D represents a light absorption part that shows an absorption having an absorption coefficient of 1000 or more in a wavelength range of 300 nm or longer; A represents an active part which interacts with the light absorption part D to generate a cation when the light absorption part D is excited by light; and L represents a linking group which links the light absorption part D with the active part A.
    Type: Application
    Filed: February 20, 2008
    Publication date: August 21, 2008
    Applicant: FUJIFILM Corporation
    Inventor: Koichi KAWAMURA
  • Publication number: 20080167397
    Abstract: In a cationically curable composition comprising an epoxide, a cationic photoinitiator and a cyclic carbonate, we have found that the use of higher levels of cyclic carbonate than have been used hitherto can lead to much enhanced cure speed and post-cure.
    Type: Application
    Filed: February 16, 2006
    Publication date: July 10, 2008
    Applicant: SUN CHEMICAL CORPORATION
    Inventors: Shaun L. Herlihy, Stephen S. Standing, Robert S. Davidson
  • Publication number: 20080160432
    Abstract: The present invention relates to a photosensitive resin composition and a color filter prepared therefrom, and more particularly to a photosensitive resin composition comprising a zinc-containing, phthalocyanine-based green pigment with superior brightness improvement effect and a color filter prepared therefrom. The photosensitive resin composition of the present invention provides improved developability and chemical resistance, together with outstanding improved brightness.
    Type: Application
    Filed: December 3, 2007
    Publication date: July 3, 2008
    Applicant: Cheil Industries Inc.
    Inventors: Noh Seok BYON, Ju Ho JUNG, Gyu Seok HAN, Cheon Seok LEE
  • Publication number: 20080160209
    Abstract: An actinic radiation curable magenta ink composition containing a quinacridone series pigment, a dispersing agent, a photo-polymerizable compound and a photo-polymerization initiator, wherein a surface of a coated layer with the magenta ink composition on a porous medium exhibits a 60°-glossiness defined in JIS 5600 in the range of 95 to 140, provided that the coated layer is formed by coating the magenta ink composition with a bar coater on the porous medium having a void ratio of 50 to 70% and a 60°-glossiness defined in JIS K 5600 of 30 or more, and then standing still for 30 minutes.
    Type: Application
    Filed: December 6, 2005
    Publication date: July 3, 2008
    Inventor: Toshiyuki Takabayashi
  • Patent number: 7393881
    Abstract: A telecommunication element having a durable color identifying polymeric coating thereon is disclosed. The telecommunication element comprises an elongated communication transmission medium, such as an optical fiber or an optical fiber ribbon, and a radiation cured polymeric coating having an identifying color applied on at least a portion of the transmission medium. The identifying color in the polymeric coating is provided by chromophore molecules that are covalently bonded thereto. Coating compositions and a method are also disclosed.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: July 1, 2008
    Assignee: ALCATEL
    Inventor: Robert W. Greer, IV
  • Publication number: 20080146689
    Abstract: A two-part curable ink composition set includes an ink composition A which contains at least a photopolymerization initiator and a polymerizable compound and which does not contain a coloring material, and an ink composition B which contains at least a coloring material and a polymerizable compound and which does not contain a photopolymerization initiator, wherein either one or each of the ink composition A and the ink composition B contains a resin emulsion dispersed in the polymerizable compound.
    Type: Application
    Filed: December 17, 2007
    Publication date: June 19, 2008
    Inventors: Takashi Oyanagi, Keitaro Nakano, Kiyohiko Takemoto
  • Publication number: 20080146690
    Abstract: The invention relates to di- and tri-carboxylic acid compounds and polyester oligomers and polymers made therefrom. Curable compositions comprising the polyester oligomers and polymers are also described.
    Type: Application
    Filed: June 30, 2005
    Publication date: June 19, 2008
    Applicant: CARGILL, INCORPORATED
    Inventors: Shuang Zhou, Tzyy-Jan Han
  • Publication number: 20080118666
    Abstract: A radiation curable resin composition suitable for making three dimensional objects comprises at least one epoxy compound, and a cationic photoinitiator, wherein the resin composition has a first color or no color before cure and wherein a three dimensional object made from the resin by subjecting the resin to radiation shows a second color which is different from the color of the resin composition before cure.
    Type: Application
    Filed: November 19, 2007
    Publication date: May 22, 2008
    Inventors: Glen A. Thommes, John A. Lawton, Xiaorong You
  • Patent number: 7375145
    Abstract: There is provided an inkjet ink comprising a photo-acid generating agent which is capable of generating an acid as it is irradiated with light, a color component, and an acid-polymerizable compound which can be polymerized in the presence of an acid, wherein at least 40% of the acid-polymerizable solvent is a vinyl ether compound represented by the following general formula (1): R13—R14—(R13)p ??(1) (Wherein R13(s) is a group selected from the group consisting of a vinyl ether group, a group having a vinyl ether skeleton, an alkoxy group, substituted hydroxyl group and hydroxyl group wherein at least one of R13(s) is vinyl ether group or a group having a vinyl ether skeleton, R14 is a group comprising a substituted or unsubstituted cyclic skeleton and having a valence of (p+1), and p is a positive integer including zero).
    Type: Grant
    Filed: October 20, 2004
    Date of Patent: May 20, 2008
    Assignee: Toshiba Tec Kabushiki Kaisha
    Inventors: Ryozo Akiyama, Toru Ushirogouchi, Kazuhiko Ohtsu, Mitsuru Ishibashi, Hiroshi Kiyomoto, Yukiko Kawakami
  • Patent number: 7368485
    Abstract: Inks are disclosed which are used in ink-jet printing. The inks are cured by ultraviolet radiation, preferably free radical initiation. The inks contain a (meth)acrylate monomer, an ?,?-unsaturated ether monomer and a photoinitiator. The inks exhibit a low viscosity and give tough printed images after curing.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: May 6, 2008
    Assignee: Sericol Limited
    Inventor: Carol Noutary
  • Publication number: 20080090928
    Abstract: Disclosed is a radiation curable ink containing a fluorescent material that upon exposure to activating energy fluoresces such that an image that was not visible prior to exposure to the activating energy becomes visible. Also disclosed are an ink jet system and a process printing the disclosed radiation curable ink.
    Type: Application
    Filed: October 12, 2006
    Publication date: April 17, 2008
    Applicant: XEROX CORPORATION
    Inventors: Gabriel IFTIME, Jennifer L. BELELIE, Christopher A. WAGNER, Peter M. KAZMAIER, Peter G. ODELL, Paul F. SMITH
  • Publication number: 20080076043
    Abstract: According to the present invention, there is provided a curable composition, containing a compound (A) having at least one ethylenically unsaturated double bond, a photopolymerization initiator (B), a coloring agent (C), an alkali-soluble resin (D), and a compound (E) having in the molecule a partial structure of urethane, amide or urea.
    Type: Application
    Filed: September 10, 2007
    Publication date: March 27, 2008
    Applicant: FUJIFILM CORPORATION
    Inventors: Hisahiro MORI, Taeko AIZAWA
  • Patent number: 7312254
    Abstract: A composition comprising one or more radiation curable monomers and/or oligomers and one or heat stable composition comprising at least one radiation-curable alpha, beta-ethylenically unsaturated compound, at least one phenolic stabilizer, and at least one non-phenolic stabilizer selected from the group consisting of hydroperoxide decomposers and free radical traps. The compositions and methods are useful in applications such as radiation curable ink jet systems where viscosity is reduced by heating.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: December 25, 2007
    Assignee: Sartomer Technology Company, Inc.
    Inventors: James Goodrich, Jeffrey Allan Klang
  • Patent number: 7304095
    Abstract: A photocurable ink for ink-jet printing, including: a photopolymerizable compound; a pigment; and a dispersing agent, wherein the photopolymerizable compound is a radical polymerizable compound; an amine value of the pigment (AMp) is larger than an acid value of the pigment (ACp); and an acid value of the dispersing agent (ACd) is larger than an amine value of the dispersing agent (AMd).
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: December 4, 2007
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventors: Satoshi Masumi, Daisuke Ishibashi
  • Patent number: 7303787
    Abstract: An active ray curable ink-jet ink composition comprising: (i) a colorant; and (ii) a set of (I) or a set of (II), wherein the set of (I) contains: (a) a photopolymerizable alicyclic epoxy compound; and (b) a diol compound contained in a specific amount; and the set of (II) contains: (a) a photopolymerizable oxetane compound; (b) a photopolymerizable epoxy compound; and (c) a diol compound contained in a specific amount.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: December 4, 2007
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventors: Satoshi Masumi, Daisuke Ishibashi
  • Patent number: 7285310
    Abstract: An active energy ray curable ink which is quickly polymerized by an active energy ray, high in crosslinking degree of a cured material formed, excellent in adhesive property, low in viscosity, excellent in long-term storability and also excellent in ejection stability, and an ink-jet recording process, an ink cartridge, a recording unit and an ink-jet recording apparatus using such an ink are provided. In the active energy ray curable aqueous ink comprising at least water and a polymerizable material which is radically polymerized by an active energy ray, the polymerizable material is a water-soluble polymerizable material represented by the following general formula (I).
    Type: Grant
    Filed: September 6, 2005
    Date of Patent: October 23, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tsuyoshi Kanke, Hiromitsu Kishi, Hiromichi Noguchi, Yutaka Kurabayashi
  • Patent number: 7276544
    Abstract: A process for producing intraocular lenses (IOLs) capable of absorbing blue light and ultraviolet light using photo curing. Intraocular lenses so produced block blue light and ultraviolet light from reaching the retina of an eye implanted with the IOL. By blocking blue light and ultraviolet light from reaching the retina, the IOL thereby prevents potential damage to the retina.
    Type: Grant
    Filed: September 8, 2003
    Date of Patent: October 2, 2007
    Assignee: Bausch & Lomb Incorporated
    Inventors: Yu-Chin Lai, Dominic V. Ruscio, George F. Green
  • Patent number: 7256222
    Abstract: To provide a radiation-curable ink composition that can form a high-quality image on not only liquid absorbing materials to be recorded but also non-liquid absorbing materials to be recorded, is superior in curing properties in air, and is superior in storage stability, color tone, light fastness and water resistance of ink, and also to provide an image recording method. The radiation-curable ink composition comprises a monomer having a polymerizable group selected from the group consisting of an acryloyl group, a methacryloyl group, an allyl group, and a vinyl group, an oil-soluble dye, and from 0.005 to 1% by weight of a storage stabilizer, wherein the oil-soluble dye is dissolved in the ink.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: August 14, 2007
    Assignee: Fujifilm Corporation
    Inventors: Takahiro Ishizuka, Kazue Sano, Junichi Yamanouchi, Keiichi Tateishi
  • Patent number: 7238731
    Abstract: Disclosed are environmentally friendly, substantially all solids coating compositions which are curable using ultraviolet and visible radiation. In addition, the disclosed coating compositions are suitable for coating flexible objects and/or objects having angular features, such as, but not limited to, flexible metal objects with angular features. In addition, methods are disclosed for coating surfaces, or at least a portion of the surfaces, and curing of the coated surface to obtain partially or fully cured coated surfaces. Furthermore, articles of manufacture incorporating fully cured coated surfaces are disclosed, including, for example leaf springs. Also disclosed are methods, processes, production lines, articles of manufacture, and factories which incorporate these environmentally friendly, substantially all solids coating compositions curable using ultraviolet and visible radiation.
    Type: Grant
    Filed: March 8, 2005
    Date of Patent: July 3, 2007
    Assignee: Ecology Coating, Inc.
    Inventor: Sally Judith Weine Ramsey
  • Patent number: 7183335
    Abstract: Compositions for use in the manufacture of three-dimensional objects including compositions for use as a support and/or release material in the manufacture of the three-dimensional objects are provided. There is thus provided, in accordance with an embodiment of the present invention, a composition suitable for building a three-dimensional object. The compositions may include, inter alia, a curable component, having a functional group, wherein if the functional group is a polymerizable reactive functional group, then the functional group is a (meth)acrylic functional group, a photo-initiator, a surface-active agent and a stabilizer; wherein said composition has a first viscosity of about 50–500 cps at a first temperature, wherein said first temperature is ambient temperature, and a second viscosity lower than 20 cps at a second temperature wherein said second temperature is higher than said first temperature, wherein, after curing, the composition results in a solid form.
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: February 27, 2007
    Assignee: Objet Geometries Ltd.
    Inventor: Eduardo Napadensky
  • Patent number: 7173071
    Abstract: Photo-curable coating formulations which comprise a durable and/or red-shifted reactable hydroxyphenylbenzotriazole ultraviolet light absorber (UVA) are effectively photocured employing a combination of ?-hydroxy ketone and bisacylphosphine oxide photoinitiators. The reactable UVA's are reacted into the coating upon curing. The combination of the photoinitiators bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and 1-hydroxycyclohexylphenylketone is especially effective for this purpose.
    Type: Grant
    Filed: May 4, 2004
    Date of Patent: February 6, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Joseph Suhadolnik, Mervin Wood, Ramanathan Ravichandran, Walter Renz, Andrea Roberts, Nancy Cliff, Eugene Sitzman, David Bramer
  • Patent number: 7122247
    Abstract: A radiation-curable fiber optic coating composition for an inner primary coating includes a coloring agent, preferably a dye or a dye precursor, compatible with the fiber of the fiber optic and capable of imparting a pre-selected color to the inner primary coating, or another coating. The coloring agent can be a reactive dye. Any of the dyes preferably is stabilized by a stabiliser in the colored coating layer, or, preferably, in a more exterior layer.
    Type: Grant
    Filed: July 31, 2003
    Date of Patent: October 17, 2006
    Assignee: DSM IP Assets B.V.
    Inventors: Lin Jibing, Montgomery I. Eva, Snowwhite E. Paul, Jr., Petisce R. James, Kotesky Anton
  • Patent number: 7091257
    Abstract: A radiation-curable fiber optic coating composition for an inner primary coating includes a coloring agent, preferably a dye or a dye precursor, compatible with the fiber of the fiber optic and capable of imparting a pre-selected color to the inner primary coating, or another coating. The coloring agent can be a reactive dye. Any of the dyes preferably is stabilized by a stabilizer in the colored coating layer, or, preferably, in a more exterior layer.
    Type: Grant
    Filed: June 1, 2001
    Date of Patent: August 15, 2006
    Assignee: Alcatel
    Inventor: Robert W. Greer, IV
  • Patent number: 7084184
    Abstract: Disclosed are an actinic ray curable composition, an actinic ray curable ink, an image recording method, and an ink jet recording apparatus, the actinic ray curable composition containing a photo acid generator, and an oxetane compound I represented by the following formula 1, wherein R1, R2, R3, R4, R5, and R6 independently represent a hydrogen atom, a fluorine atom, an alkyl group having from 1 to 6 carbon atoms, a fluoroalkyl group having from 1 to 6 carbon atoms, an allyl group, an aryl group, a furyl group or a thienyl group, and wherein the longer C—O bond distance of the two C—O bond distances in formula 1 is from 0.1464 to 0.1500 nm.
    Type: Grant
    Filed: August 21, 2003
    Date of Patent: August 1, 2006
    Assignee: Konica Corporation
    Inventor: Toshiyuki Takabayashi
  • Patent number: 7064155
    Abstract: A radiation-curable composition which includes a cyanoacrylate component or a cyanoacrylate-containing formulation; a metallocene component; a photoinitiator; and a luminescent and/or fluorescent dye.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: June 20, 2006
    Assignee: Henkel Corporation
    Inventor: Stan Wojciak
  • Patent number: 7056959
    Abstract: A dye-containing curable composition contains at least an alkali soluble resin, a dye, and a photosensitive compound, the dye being a phthalocyanine compound represented by the following general formula (I): M-Pc-(Y)l ??General Formula (I) wherein M represents a metallic atom, a metallic oxide, a metallic chloride or a hydrogen atom; Pc represents a phthalocyanine skeleton; Y represents a fluorine-substituted alkoxy group; and l denotes an integer from 1 to 8.
    Type: Grant
    Filed: November 7, 2003
    Date of Patent: June 6, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Nobuo Suzuki
  • Patent number: 7037952
    Abstract: The ink comprises a coloring component, a reactive oligomer and/or a reactive prepolymer, a reactive diluent and a photoinitiator, wherein the reactive oligomer and/or reactive prepolymer unit and the reactive diluent unit have a glass transition point of 0° to 70° C., respectively, in a polymer obtained therefrom. In the present invention, a cured film excellent in adhesion to materials and scratch resistance is obtained, and an image without blurring is formed in ink jet printing of the ultraviolet ray curable ink. An ultraviolet ray curable ink composition having a viscosity of 60 to 800 cps at 25° C. which comprises a coloring component, a reactive diluent, a photoinitiator and an oligomer and/or reactive prepolymer having compatibility with the reactive diluent is used. The ink composition is heated to 40° to 150° C. and applied to a recording medium and cured by ultraviolet rays.
    Type: Grant
    Filed: August 1, 2003
    Date of Patent: May 2, 2006
    Assignee: Seiren Co., Ltd.
    Inventors: Yoshikatsu Itoh, Tomoyuki Nishikawa
  • Patent number: 6946168
    Abstract: This invention provides a reversibly thermochromic ultraviolet ray-hardening type ink having good color change sensitivity and excellent light resistance and fastness, and a reversibly thermochromic laminate produced using the same. The present invention also provides a reversibly thermochromic laminate produced by forming a reversibly thermochromic layer on a support using the same.
    Type: Grant
    Filed: October 17, 2002
    Date of Patent: September 20, 2005
    Assignee: The Pilot Ink Co., Ltd.
    Inventors: Kuniyuki Senga, Hiroki Harata, Makoto Miyamoto
  • Patent number: 6933325
    Abstract: A high refractive index, curable, synthetic resin composition comprising a core resin composition composed of a mixture of ethylenically unsaturated compounds, and an initiation system containing both photo and thermal initiators, particularly a photochromic resin composition which further includes at least one photochromic dye. Also a curing process, which includes a combination of multi-step radiation curing and thermal annealing. Articles produced of cured composition exhibit superior physical and, in appropriate cases, photochromic properties and can be easily mass produced on a commercial scale due to short processing time and use of readily available chemicals.
    Type: Grant
    Filed: October 11, 2002
    Date of Patent: August 23, 2005
    Assignee: Rodenstock GmbH
    Inventors: Qiang Zheng, Donald Scott Nelson, Charles William Carper, Jr., Manfred Melzig, Herbert Schuster, Herbert Zinner
  • Patent number: 6916501
    Abstract: The present invention discloses a method for fabricating an electroluminescent lamp that includes a step in which an electroluminescent active layer is formed by curing a UV curable electroluminescent composition. Embodiments of the method of the present invention in which each layer of a multilayer electroluminescent device are fabricated from UV curable compositions are also disclosed. A UV curable dielectric composition suitable for utilization in an electroluminescent lamp is also provided.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: July 12, 2005
    Assignee: Allied PhotoChemical, Inc.
    Inventors: Roy C. Krohn, Scott E. Howe, Christopher C. Ryan
  • Patent number: 6896937
    Abstract: Radiation-curable ink compositions and methods of printing including the compositions are disclosed. In some embodiments, a radiation-curable hot melt ink composition includes a colorant, a polymerizable monomer, and a photoinitiating system. The photoinitiating system can include 0.5-1.5% by weight of an aromatic ketone photoinitiator, 2-10% by weight of an amine synergist, 3-8% by weight of an alpha-cleavage type photoinitiator, and 0.5-1.5% by weight of a photosensitizer.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: May 24, 2005
    Assignee: Markem Corporation
    Inventor: Richard C. Woudenberg
  • Patent number: 6894082
    Abstract: This invention relates to latent foamable compositions for use in or as adhesives, sealants and/or coatings. The compositions include a curable component or a thermoplastic component, together with a latent foaming agent. In curable versions of the inventive compositions, a cure initiator or catalyst may also be included.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: May 17, 2005
    Assignee: Henkel Corporation
    Inventors: Karen R. Brantl, Philp T. Klemarczyk
  • Patent number: 6890399
    Abstract: Polymerizable compositions for use in or as adhesives, sealants and/or coatings are disclosed herein. The compositions include a (meth)acrylate component together with a dye substantially dissolved in the (meth)acrylate component which imparts a first color to the (meth)acrylate component. Upon curing, a resultant cured composition has a second color. The invention also relates to a method of detecting substantially full cure of the polymerization of the compositions.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: May 10, 2005
    Assignee: Henkel Corporation
    Inventor: Stan Wojciak
  • Patent number: 6872764
    Abstract: Certain essentially phenol antioxidant-free stabilizer systems that comprise either a binary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone system or a ternary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone/organic phosphite or phosphonite system are especially effective towards protecting polyolefins against the deleterious effects of gamma irradiation. Polyolefin articles such as medical packaging, hospital garments, draperies, woven and non-woven fiber products, surgery utensils, blow-molded I.V. bottles, hypodermic syringes, needle shields, laboratory ware such as trays, funnels, Petri dishes and filters, and hygiene related articles may be sterilized with gamma irradiation and are stabilized according to the present invention.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: March 29, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Roswell E. King, III
  • Patent number: 6864299
    Abstract: The present invention is aimed to produce a cured product having excellent photochromism which can be easily polymerized in a short period of time. The cured product is obtained by photopolymerizing a polymerizable composition comprising (A) a radical polymerizable monomer, (B) an ultraviolet polymerization initiator having the main absorption at an ultraviolet range and a molar absorption coefficient for light having a wavelength of 400 nm of 150 liter/(mol·cm) or more, (C) a thermopolymerization initiator such as a thermopolymerization initiator having a temperature at which the half-life thereof is 10 hours of 60° C. or more and (D) a photochromic compound by irradiating activation energy rays having a wavelength of 400 nm or more as the main emission spectrum, preferably to ensure that the temperature of the cured product does not exceed 50° C., and further thermopolymerizing the composition by heating.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: March 8, 2005
    Assignee: Tokuyama Corporation
    Inventors: Yasuko Komuro, Junji Momoda
  • Patent number: 6864301
    Abstract: Methods of forming crosslinked polymer particles in situ from polymer precursors such as monomers or oligomers, comprising exposing a composition comprising at least one polymer precursor, a solvent or solvent mixture, and an antisolvent or antisolvent mixture to photoradiation under conditions whereby particles are formed are provided. The polymer precursor may be photosensitive, or a separate polymerization initiator may be used. In a preferred embodiment, the polymer precursor is insoluble in the antisolvent or antisolvent mixture and the solvent or solvent mixture is soluble in the antisolvent or antisolvent mixture at the concentrations used. Crosslinked polymer particles and crosslinked polymer particles comprising a polymer and a bioactive material are also provided. The polymer may be erodable, and the polymer particles formed may be used in a variety of applications, including controlled release of bioactive materials such as drugs.
    Type: Grant
    Filed: June 3, 2002
    Date of Patent: March 8, 2005
    Assignee: The Regents of the University of Colorado
    Inventors: Theodore Randolph, Kristi Anseth, Jennifer L. Owens, Corinne Lengsfeld
  • Patent number: 6852767
    Abstract: A photo-curing ink composition comprises a photocation-polymerizable substance, a photocation polymerization initiator, and a surfactant having a functional group. The surfactant is selected and the amount thereof is adjusted so that the acid value per 100 g of the ink composition is not more than 150 mg KOH. The surfactant is selected and the amount thereof is adjusted so that the amine value per 100 g of the ink composition is not more than 23 mg KOH. The ink composition is excellent in dispersion performance, storage stability, and curing performance.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: February 8, 2005
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventor: Minobu Maeda
  • Patent number: 6846851
    Abstract: A composition for ink-jet recording is provided. The composition comprises a water miscible resin and a water-soluble ultraviolet curable humectant. The concentration of the water-soluble ultraviolet curable humectant may be in the range of 5% to 50% by weight. Examples of such humectants may include polyalkylen glycol acrylates, polyethers acrylates, and highly ethoxylated derivatives of acrylates.
    Type: Grant
    Filed: April 15, 2003
    Date of Patent: January 25, 2005
    Inventors: Gregory Nakhmanovich, Ilan Hidana, Moshe Frenkel
  • Patent number: 6844373
    Abstract: A radiation-curable composition having a reduced surface energy and including a reactive dye containing at least one radiation-curable substituent and at least one fluorine-containing substituent. The reactive dye may include any anthraquinone, methine, azo, azine, or xanthene dye adapted to contain at least one radiation-curable substituent and at least one fluorine-containing substituent. The radiation-curable substituent may include (meth)acrylate, styrene, vinyl ether, vinyl ester, N-substituted acrylamide, N-vinyl amide, maleate ester, and fumarate ester.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: January 18, 2005
    Assignee: Alcatel
    Inventor: Michael B. Purvis
  • Patent number: 6815468
    Abstract: A radiation-curable composition for use as a base coat in printing on plastic substrates such as polycarbonate. The radiation-curable composition comprises: (i) an ethylenically unsaturated monomer that is capable of being photopolymerized; (ii) a photoinitiator that is capable of initiating the polymerization of the ethylenically unsaturated monomer (i) when irradiated with ultra-voilet light; (iii) an inorganic transfer agent; (iv) an adhesion promoter; and (v) optionally, a pigment. The base coat is suitable for use in printing plastics substrates using electrostatic offset printing.
    Type: Grant
    Filed: October 16, 2002
    Date of Patent: November 9, 2004
    Assignee: Sericol Limited
    Inventors: Keith Edward Nixon, Angelique Catherine Joyce Runacre
  • Publication number: 20040210006
    Abstract: An ultraviolet crosslinking pressure-sensitive adhesive composition showing good pressure-sensitive adhesive characteristics is obtained by using a block copolymer of styrenic polymer component and acrylic polymer component. The pressure-sensitive adhesive composition is produced by conducting living radical polymerization of styrenic monomer and acrylic monomer in a proper order in the presence of a transition metal and its ligand using a polymerization initiator to obtain a block copolymer (a) wherein at least one styrenic polymer block A and at least one acrylic polymer block B are bound to each other and mixing it with a trichloromethyl group-containing triazine derivative (b) or, alternatively, to obtain a block copolymer (a) which contains carboxy precursor groups in the acrylic polymer block B, and converting the precursor groups to carboxyl groups, before or after mixing with the component (b), by heat-treating in the presence of an acid catalyst.
    Type: Application
    Filed: April 19, 2004
    Publication date: October 21, 2004
    Applicant: NITTO DENKO CORPORATION
    Inventors: Tomoko Doi, Michiharu Yamamoto, Yutaka Moroishi, Yoshihide Kawaguchi, Fumiko Nakano
  • Patent number: 6803014
    Abstract: The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.).
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: October 12, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Thoi H. Ho, Selim Bensason, Rajen M. Patel, Kimberly S. Houchens, Rona L. Reid, Pak-Wing S. Chum, Leonie K. Walsh
  • Patent number: 6797740
    Abstract: The invention relates to a radiation curable colored coating composition for coloring a coated optical fiber wherein the coating, when disposed and cured to surround an optical fiber coated with an internal coating, and when said colored fiber is coated with a matrix material and assembled into an optical fiber ribbon, said colored coating has a degree of adhesion to the internal coating which is higher than the degree of adhesion to the matrix material and said optical fiber assembled into said optical fiber ribbon shows, upon aging for at least two weeks in water at 60° C., an increase in the attenuation of the transmitted signal at 1550 nm of less than 0.05 db/km with respect to the attenuation of the assembled optical fiber measured before aging. The invention also relates to said colored coating composition when used in an optical fiber ribbon.
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: September 28, 2004
    Assignee: DSM N.V.
    Inventors: Adrianus G. M. Abel, Albert A Vries De, Gouke D. J. Geus, Johannes C Burg Van Den, Johannes A Eekelen Van, Alessandro Ginocchio, Massimo Pizzorno
  • Patent number: 6784222
    Abstract: An electroconductive coating composition which function as a sealer/primer includes (a) a radiation curable, polymerizable compound, (b) a photoinitiator and (c) a conductive pigment. The conductive pigment may be a mixture of pigment including a blend of conductive pigments as well as conductive pigment. Conductivity enhancers may, also, be added. The polymerizable compound is, preferably, a U curable acrylate functional compound which may be monofunctional or polyfunctional. The composition is particularly useful for sealing and priming SMC panels.
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: August 31, 2004
    Inventors: Frank David Zychowski, Joseph C. Sgro
  • Patent number: 6777459
    Abstract: The present invention relates to a novel photoinitiator system comprising one or more acylphosphine oxide photoinitiators and one or more lightfast red, blue or violet organic pigments. Low yellow color formation results upon curing ethylenically unsaturated compounds with the new photoinitiator system. Particular applications include clear and white coatings, screen inks, gel coats, powder coatings, composites, adhesives and lenses.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: August 17, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Walid Al-Akhdar, David Bramer, Eugene Valentine Sitzmann, Jr., Donald A. Wostratzky
  • Patent number: 6730714
    Abstract: Radiation curable inks with moderate amounts of solvent with low surface tension provide unique processability characteristics that allow ink jetted features to be formed and cured with excellent flow, adhesion, dot gain, compatibility, weatherability, and curing characteristics. In a representative printing method, an ink jettable ink composition is provided that includes one or more oligo/resins, a radiation curable, reactive diluent having a surface tension and 1 to 15 weight percent of a solvent component comprising a solvent having a surface tension. The solvent surface tension is no more than about, and preferably at least 2 dynes/cm less than, the surface tension of the reactive diluent. The ink composition is ink jetted onto the substrate to form an ink jetted feature.
    Type: Grant
    Filed: November 13, 2002
    Date of Patent: May 4, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Caroline M. Ylitalo, Richard L. Severance, Ronald K. Thery