Phosphorous Or Sulfur Containing Dnrm Patents (Class 522/82)
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Patent number: 9296914Abstract: An anti-finger print hard coating resin composition is described that includes a high hardness ultra-violet (UV) curable resin having a weight percent of about 5% to about 99% and including at least one of siloxane compound and urethane acrylate compound; a UV curable fluoro-based compound having a weight percent of about 0.02% to about 2% with respect to the high hardness UV curable resin; an optical initiator having a weight percent of about 0.1% to about 10% with respect to the high hardness-UV curable resin; and an acrylate monomer of residual amount.Type: GrantFiled: December 11, 2013Date of Patent: March 29, 2016Assignee: LG Display Co., Ltd.Inventors: Hye-Ran Park, Won-Jin Choi
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Patent number: 8809413Abstract: Various radiation-curable compositions for making optically clear high refractive index materials are provided. The radiation-curable compositions include: one or more aryl-containing compounds including one or more ethylenically unsaturated moieties: one or more reactive diluent compounds including an ethylenically unsaturated moiety; one or more heat-stabilizing compounds; and one or more photo initiators. Various methods of making optically clear high refractive index coatings are also provided.Type: GrantFiled: June 29, 2011Date of Patent: August 19, 2014Inventor: Chau Ha
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Patent number: 8796347Abstract: The present invention presents methods for making oxidation-resistant and wear-resistant polyethylenes and medical implants made therefrom. Preferably, the implants are components of prosthetic joints, e.g., a bearing component of an artificial hip or knee joint. The resulting oxidation-resistant and wear-resistant polyethylenes and implants are also disclosed.Type: GrantFiled: April 27, 2001Date of Patent: August 5, 2014Assignee: Orthopaedic HospitalInventors: Harry A. McKellop, Fu-Wen Shen
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Publication number: 20140205771Abstract: The present invention provides a bezel sealant for use in a polymer stabilized vertical alignment liquid crystal display. The bezel sealant includes at least the following compositions: epoxy resin 20-60% by weight, curing agent 5-50% by weight, methacrylate resin or acrylate resin 20-60% by weight, photoinitiator 0.1-1% by weight, filler 5-35% by weight, and silane coupling agent 0.05-5% by weight. The molecular weight of the methacrylate resin or the acrylate resin is greater than or equal to 500. According to the embodiment of the present invention, the dissolution of the methacrylate resin or acrylate resin in the bezel sealant by the liquid crystal medium is prevented to avoid the over-sized bumps formed in the periphery of the bezel. Light leakage phenomenon in the periphery of the bezel is decreased to increase product yield rate.Type: ApplicationFiled: January 31, 2013Publication date: July 24, 2014Applicant: Shenzhen China Star Optoelectronics Technology Co. Ltd.Inventors: Hong-Ji Huang, Xinhui Zhong, Chihhsien Li
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Patent number: 8372894Abstract: A method for producing a graft polymer comprises the steps of: a) irradiating a base polymer with an electron beam or a source of ?-radiation, b) contacting a grafting solution with the base polymer, wherein the grafting solution contains at least one oxygen scavenger and at least one graft monomer selected from the group consisting of styrene and styrene derivatives, and c) graft polymerizing the mixture of the base polymer and the grafting solution obtained in step b).Type: GrantFiled: February 23, 2009Date of Patent: February 12, 2013Assignee: Belenos Clean Power Holding AGInventor: Dirk Henkensmeier
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Publication number: 20130004676Abstract: Various radiation-curable compositions for making optically clear high refractive index materials are provided. The radiation-curable compositions include: one or more aryl-containing compounds including one or more ethylenically unsaturated moieties: one or more reactive diluent compounds including an ethylenically unsaturated moiety; one or more heat-stabilizing compounds; and one or more photo initiators. Various methods of making optically clear high refractive index coatings are also provided.Type: ApplicationFiled: June 29, 2011Publication date: January 3, 2013Inventor: Chau Ha
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Patent number: 8329772Abstract: This invention provides a screen printable dielectric composition comprising finely divided particles of talc dispersed in a curable liquid composition containing an acrylated urethane resin oligomer, an alkyl acrylate, and phosphoric acid.Type: GrantFiled: May 20, 2010Date of Patent: December 11, 2012Assignee: E I du Pont de Nemours and CompanyInventor: Jay Robert Dorfman
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Publication number: 20120287213Abstract: A 1K UV-ink jet printing ink composition comprising effect pigments, wherein the composition comprises: a) at least one difunctional (meth)acrylate monomer, b) at least one photoinitiator, c) effect pigments having a volume averaged particle size distribution with a D98<10 ?m, d) optionally trifunctional and/or polyfunctional (meth)acrylate monomers, and wherein the viscosity of the ink jet printing ink composition is at maximum 30 mPas, measured at 25° C. for 10 minutes with a Brookfield R/S rheometer using a double gap cylinder according to DIN 53453 (German Industrial Standards) at 150 rpm and wherein the total concentration of the at least one difunctional (meth)acrylate monomer of a) and the trifunctional and/or polyfunctional (meth)acrylate monomers of d) is in a range of 75 to 100 wt.-%, based on the total amount of (meth)acrylate monomers.Type: ApplicationFiled: May 13, 2011Publication date: November 15, 2012Inventors: Stefan ENGEL, Dieter PRÖLSS, Jörg MÄNNIG
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Publication number: 20120220682Abstract: Methods for making a crosslinked elastomeric composition and articles made of the same are provided. In at least one specific embodiment, an elastomeric composition comprising at least one propylene-based polymer is blended with at least one component selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, functionalized polybutadiene resins, functionalized cyanurate, and allyl isocyanurate; and blended with at least one component selected from the group consisting of hindered phenols, phosphites, and hindered amines. The propylene-based polymer can include propylene derived units and one or more dienes, and have a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g. The blended composition can then be extruded and crosslinked. The extruded polymer can be crosslinked using electron beam radiation having an e-beam dose of about 100 KGy or less. The crosslinked polymers are particularly useful for making fibers and films.Type: ApplicationFiled: April 13, 2012Publication date: August 30, 2012Inventor: Sunny Jacob
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Publication number: 20120205136Abstract: Provided is a flame-retardant resin composition that can achieve both mechanical properties and flame retardancy and satisfy stringent heat resistance requirement such as heat resistance with a conductor attached, and an insulated wire, a flat cable, and a molded article made using the flame-retardant resin composition. The flame-retardant resin composition contains a thermoplastic resin, a polyfunctional monomer, and an organic phosphorus-based flame retardant. The thermoplastic resin contains 5% by mass or more of a resin having a carbon-carbon unsaturated bond or a resin having a carbonyl group relative to the entire thermoplastic resin. The organic phosphorus-based flame retardant is at least one selected from the group consisting of a metal phosphinate, a melamine phosphate compound, an ammonium phosphate compound, and a polyphosphazene compound obtained by ring-opening polymerization of cyclophosphazene.Type: ApplicationFiled: October 1, 2010Publication date: August 16, 2012Inventors: Kiyoaki Moriuchi, Hiroshi Hayami
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Publication number: 20120199029Abstract: There is provided an intaglio printing ink that causes little set-off, exhibits improved chalking resistance, and attains improved print quality, and which permits low-cost prevention of blocking by low-dose irradiation with ultraviolet light. The intaglio printing ink comprises at least an ultraviolet curable composition, an oxidation polymerizable composition, a photopolymerization initiator, an oxidation polymerization catalyst, and a pigment. An acid-modified epoxy-acrylate prepared by reacting a polybasic acid anhydride with an epoxy-acrylate obtained by reacting an acrylate, having two or more acryloyl groups and one carboxyl group in one molecule, with an epoxy compound, having two or more epoxy rings in one molecule, is used as the ultraviolet curable composition.Type: ApplicationFiled: October 8, 2010Publication date: August 9, 2012Applicant: NATIONAL PRINTING BUREAU INCORPORATEDInventor: Asao Fukuura
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Publication number: 20120168215Abstract: Provided is a curable resin composition which exhibits improved developability even in through holes and can suppress the generation of development residue and which can yield a cured product with excellent heat resistance and hardness. A curable resin composition which comprises a carboxyl-containing resin, a photopolymerization initiator, and barium sulfate that has been pretreated with a dispersant having an acid group and/or a dispersant having a block copolymer structure, a graft polymer structure, and/or a star polymer structure.Type: ApplicationFiled: August 27, 2010Publication date: July 5, 2012Applicant: TAIYO HOLDINGS CO., LTDInventors: Touko Shiina, Masao Arima, Shuichi Yamamoto, Masato Yoshida
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Patent number: 8207240Abstract: A method to reduce or minimize the reduction in molecular weight of a stent during processing is disclosed. The stent has a scaffolding including a polymer formulation comprising PLLA and polymandelide. The polymandelide reduces the molecular weight drop during processing, particularly during sterilization. The stent scaffolding can further include one or more additional stabilizing agents that additionally reduce the molecular weight drop during processing.Type: GrantFiled: September 14, 2009Date of Patent: June 26, 2012Assignee: Abbott Cardiovascular Systems IncInventors: Byron Lambert, Yunbing Wang, James Oberhauser
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Publication number: 20120148833Abstract: Radiation-curable coating compositions for a surface such as a concrete floor, which include one or more acrylate monomers or oligomers having at least four crosslinkable double bonds, at least one photoinitiator, one or more fillers, and at least one pigment or dye are described and claimed. These coating compositions allow for application of at least 0.10 mm (4 mil) thickness of the coating composition over an area larger than a radiation source, without the formation of wrinkles along the shoulder area of each pass of the radiation source in the areas where weak intensity light from a side edge of the radiation source is capable of partially curing only a portion of the coating composition thickness. The coating compositions optionally further comprise one or more tertiary amine compounds comprising zero or one crosslinkable double bonds, the one or more tertiary amine compounds providing an amine value of at least 7.5 mg KOH per gram of the total radiation-curable resins of the coating composition.Type: ApplicationFiled: June 30, 2011Publication date: June 14, 2012Inventors: Huimin CAO, Wenguang LI, Tia Yeon LEE
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Publication number: 20120129970Abstract: The present invention provides polymer composites reinforced with high aspect ratio reinforcing fillers selected from calcium phosphate nanofibers, nanoplates, submicron fibers, submicron plates, and combinations thereof. The mechanical and biological properties of the inventive composites are enhanced significantly over current polymer composites and may be employed in various biomedical applications, such as dental restorations.Type: ApplicationFiled: July 14, 2011Publication date: May 24, 2012Applicant: THE CURATORS OF THE UNIVERSITY OF MISSOURIInventors: Hao Li, Qingson Yu, Liang Chen, Meng Chen
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Patent number: 8106109Abstract: The invention concerns a dental filling material with dual hardening mechanism, wherein i) a first hardening mechanism is based on a photocuring reaction, preferably a radical reaction, and ii) a second hardening mechanism is dependent on H2O as a reactant, especially as a ligand. Preferably, the second hardening mechanism is a gypsum-type reaction. Owing to the expansion of the composition an excellent marginal seal can be achieved, while the first hardening mechanism allows for a rapid cure on demand.Type: GrantFiled: May 12, 2008Date of Patent: January 31, 2012Assignee: Coltene Whaledent AGInventors: Ralf Böhner, Dierk Lübbers, Silvan Benz
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Patent number: 8071195Abstract: The present invention provides a multi-layered object having a hard coat layer capable of improving anti-staining property, anti-staining durability, scratch resistance, abrasion resistance and the like. A multi-layered object comprising a hard coat layer and a light transmitting layer, wherein the hard coat layer is formed from a composition for hard coat comprising: an active energy ray-curable silicone-acrylic copolymer (A); and an active energy ray-curable polyfunctional compound (B), and wherein the active energy ray-curable silicone-acrylic copolymer (A) contains: a polysiloxane block (a-1), an acrylic block (a-2) containing an active energy ray-curable double bond group and a fluoroalkyl group-containing acrylic block (a-3).Type: GrantFiled: December 11, 2008Date of Patent: December 6, 2011Assignee: TDK CorporationInventors: Kenji Yoneyama, Kazushi Tanaka, Hiroyuki Hashiguchi, Akira Yamamoto, Koichi Ueda
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Publication number: 20110245365Abstract: A method for producing a graft polymer comprises the steps of: a) irradiating a base polymer with an electron beam or a source of ?-radiation, b) contacting a grafting solution with the base polymer, wherein the grafting solution contains at least one oxygen scavenger and at least one graft monomer selected from the group consisting of styrene and styrene derivatives, and c) graft polymerizing the mixture of the base polymer and the grafting solution obtained in step b).Type: ApplicationFiled: February 23, 2009Publication date: October 6, 2011Applicant: Belenos Clean Power Holding AGInventor: Dirk Henkensmeier
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Patent number: 7980596Abstract: the invention provides a composition having laser engraving properties, comprising a host material and a laser enhancing additive. The host material comprises a material, such as a polymer, modified by a first process, whereby the host material as modified by the first process has increased thermal conductivity as compared to the host material before the first process. The laser enhancing additive comprises a first quantity of at least one of copper potassium iodide (CuKI3), Copper Iodide (CuI), potassium iodide (KI), sodium iodide (NaI), and aluminum iodide (AlI), and a second quantity of at least one substance selected from the group consisting of zinc sulfide (ZnS), barium sulfide (BaS), alkyl sulfonate, and thioester.Type: GrantFiled: January 14, 2010Date of Patent: July 19, 2011Assignee: L-1 Secure Credentialing, Inc.Inventor: Brian C. Labrec
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Publication number: 20110123722Abstract: Light-guide ink comprising: scattering particles of 2-25 parts by weight; a resin of 10-50 parts by weight; a pigment of 0.01-0.5 parts by weight; a solvent of 20-75 parts by weight; a photoinitiator of 0-8.5 parts by weight; and an additive of 0.01-3.5 parts by weight.Type: ApplicationFiled: November 24, 2010Publication date: May 26, 2011Applicant: BOE TECHNOLOGY GROUP CO., LTD.Inventors: Jiuxia YANG, Yanying LV
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Publication number: 20110123723Abstract: A photosensitive resin composition comprises: 0.01 wt %-10 wt % of reflective particles; 0 wt %-12 wt % of pigment; 1 wt %-10 wt % of dispersant; 1.5 wt %-5 wt % of dispersion resin; 2 wt %-25 wt % of optically active polymer; 1 wt %-22 wt % of optical active monomer; 0.4 wt %-5 wt % of epoxy resin; 5 wt %-85 wt % of solvent; 0.1 wt %-3 wt % of photoinitiator; and 0.01 wt %-3.5 wt % of additives.Type: ApplicationFiled: November 24, 2010Publication date: May 26, 2011Applicant: BOE TECHNOLOGY GROUP CO., LTD.Inventor: Jiuxia YANG
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Patent number: 7897651Abstract: A method for rapidly depolymerizing a polyester and an unsaturated polyester by irradiating the polyester with microwaves in the presence of an alkylene glycol in which a titanium oxide fine powder having a bulk density of not more than 0.3 g/cm3 has been dispersed. Another embodiment comprises irradiating a polyester or an unsaturated polyester with microwaves in the presence of a monohydric alcohol or polyhydric alcohol containing an alkali metal and/or an alkaline earth metal. As a result, raw materials of a polyester, an unsaturated polyester or a polyurethane, such as an alkylene glycol and an unsaturated dibasic acid, can be recovered efficiently.Type: GrantFiled: September 29, 2006Date of Patent: March 1, 2011Inventor: Kazutoshi Ikenaga
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Patent number: 7893125Abstract: The present invention relates to a method of forming a crosslinked polymer gel, to a polymer gel produced by such method and to uses of such polymer gel.Type: GrantFiled: March 19, 2007Date of Patent: February 22, 2011Assignee: Sony Deutschland GmbHInventors: Gabriele Nelles, Silvia Rosselli, Tzenka Miteva, Akio Yasuda, Christo Tsvetanov, Rayna Stamenova, Iliyana Berlinova, Petar Petrov
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Patent number: 7875362Abstract: An absorbent member and a method for making such an absorbent member. The absorbent member includes a modified water absorbent resin having good production efficiency, absorbency against pressure, absorption speed, gel strength, and liquid permeability. The modified water absorbent resin may be made by mixing a water absorbent resin, water, and a water-soluble radical polymerization initiator without addition of an ethylenically unsaturated monomer to obtain a water absorbent resin composition, and irradiating the water absorbent resin composition with active energy rays. During irradiation, the surface water content of the water absorbent resin is at least 3.0 wt %.Type: GrantFiled: May 20, 2010Date of Patent: January 25, 2011Assignee: The Procter & Gamble CompanyInventors: Yoshiro Mitsukami, Makoto Matsumoto, Taku Iwamura
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Patent number: 7872058Abstract: An object of the present invention is to provide a photopolymerizable dental composition which causes less change in a color tone before and after curing and exhibits excellent photopolymerizability to irradiation in a wide wavelength range, and has also excellent thin-layer surface curability, and to provide a photopolymerization initiator used therefor. Disclosed is a visible light-polymerizable dental composition which does not substantially contain an amine compound as a photosensitizer, comprising 0.01 to 10 parts by weight of a (bis)acylphosphine oxide compound, 0.01 to 10 parts by weight of an ?-diketone compound and 100 parts by weight of a polymerizable monomer.Type: GrantFiled: March 4, 2009Date of Patent: January 18, 2011Assignee: Kabushiki Kaisha ShofuInventors: Jun Uchida, Mitsuharu Mizuno, Mitsuji Teramae
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Patent number: 7863345Abstract: A process for producing a microparticulate hardening catalyst, comprising the steps of jetting a liquid composition containing epoxy resin hardening catalyst (A), monomer having an ethylenically unsaturated group (B) and photopolymerization initiator (C) through a minute nozzle into a gas so as to form microparticles; and while the microparticles are floating, irradiating the same with high-energy rays to thereby effect polymerization of the monomer having an ethylenically unsaturated group (B).Type: GrantFiled: July 6, 2006Date of Patent: January 4, 2011Assignee: Nippon Kayaku Kabushiki KaishaInventors: Hiroo Koyanagi, Makoto Uchida, Shigeru Moteki
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Publication number: 20100330297Abstract: A radiation-curable composition comprising a radiation-curable compound, a free acid and a halogenated polyolefin is disclosed. The compositions are useful in the repair of damaged motor vehicle body parts.Type: ApplicationFiled: September 8, 2010Publication date: December 30, 2010Inventor: David N. Walters
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Patent number: 7855241Abstract: The invention includes embodiments that relate to a method of improving the abrasion resistance of a plastic article. The method comprises: (a) providing a composition comprising at least one e-beam active nanoparticle compound and at least one thermoplastic polymeric material; (b) forming an article from the composition of step (a); and (c) exposing the article formed in step (b) to an electron beam source. The invention also includes embodiments that relate to an article comprising an abrasion resistant surface.Type: GrantFiled: October 18, 2005Date of Patent: December 21, 2010Assignee: Sabic Innovative Plastics IP B.V.Inventors: Ryo Tamaki, Steven Thomas Rice, Hieu Minh Duong
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Patent number: 7812063Abstract: The invention relates to a flame-retardant resin formulation comprising respectively at least one flame-retardant component, one alkali-soluble component, one polymerizable monomer, one photoinitiator, and one epoxy component, which comprises, as flame-retardant component, a phosphinic salt of the formula (I), in which R1 and R2 are identical or different and, independently of one another, are C1-C6-alkyl, linear or branched, and/or aryl; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base, and m is from 1 to 4. This novel flame-retardant resin formulation is preferably used as solder resist.Type: GrantFiled: January 11, 2008Date of Patent: October 12, 2010Assignee: Clariant Finance (BVI) LimitedInventors: Mathias Dietz, Harald Bauer, Werner Krause
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Patent number: 7750079Abstract: Compositions, such as lens precursor compositions, and methods for producing lens precursor compositions have been invented. The present methods include forming a premix composition, which can include one or more monomeric components, forming a macromer composition, which includes one or more silicon containing macromers, forming a premix/initiator composition, which can include a photoinitiator, and contacting the premix/initiator composition with the macromer composition to form a polymerizable monomer-containing composition useful in the production of producing silicone hydrogel contact lenses.Type: GrantFiled: August 7, 2006Date of Patent: July 6, 2010Assignee: CooperVision International Holding Company, LPInventors: Sarah L. Almond, John H. D. Browning
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Publication number: 20100168267Abstract: The present subject matter relates to processes for irradiating visbroken propylene polymer compositions or extrudates of propylene polymer compositions containing a propylene polymer having a low polydispersity index and a non-phenolic stabilizer.Type: ApplicationFiled: December 30, 2008Publication date: July 1, 2010Applicant: Basell Poliolefine Italia s.r.l.Inventors: Vu A. Dang, Dinshong Dong, Theodore Dziemianowicz
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Publication number: 20100075062Abstract: There is described a process for preparing a hybrid organic inorganic nano-composite used to prepare high (nD?1.Type: ApplicationFiled: October 31, 2007Publication date: March 25, 2010Applicant: CYTEC SURFACE SPECIALITIES S.A.Inventors: Zhikai (Jeffrey) Wang, Harrell Tweedy
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Publication number: 20100028660Abstract: The present invention provides a polymerizable composition, which comprises: (a) at least one monomer of formula (I): (b) a photo-initiator, wherein X1, X2, Y1, Y2, Y3, Y4, a, and b are as defined in the specification and the amount of the monomer of formula (I) is at least 1 wt %, based on the total weight of the polymerizable composition. The present invention also provides an optical film comprising a coating layer formed from the above polymerizable composition. The optical film can be used in backlight modules of displays as a brightness enhancement film.Type: ApplicationFiled: July 30, 2009Publication date: February 4, 2010Inventors: Kun-Ming YEH, Po-Wen LIN, Shih-Yi CHUANG, Yi-Chung SHIH
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Patent number: 7632874Abstract: A hardcoat agent composition comprising a fluorine-containing polyether compound (A) having a perfluoropolyether unit, urethane bond and active energy ray reactive group and a curable compound (B) having equal to or more than 2 active energy ray polymerizing groups in the molecule. An optical information medium having a film substance composed of single or multiple layers containing at least the recording layer 4 or the reflecting layer on the supporting substrate 20, the optical information medium wherein at least either the surface of the supporting substrate 20 or that of the above-mentioned film substance is formed by the hardcoat layer 8 containing a curable substance of the above-mentioned hardcoat agent composition.Type: GrantFiled: October 21, 2004Date of Patent: December 15, 2009Assignee: TDK CorporationInventors: Naoki Hayashida, Rie Ihara, Hidetake Itoh, Kazushi Tanaka
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Patent number: 7632880Abstract: The invention provides a single phase, essentially solvent-free polymerizable liquid composition comprising a polymerizable liquid with dissolved therein an organogroup 4, 5 or 6 compound selected from the group consisting of organolead, organophosphorus, organoarsenic, organoantimony, organobismuth and organselenium compounds, said position being polymerizable under the action of an externally applied influence.Type: GrantFiled: February 20, 2004Date of Patent: December 15, 2009Assignee: Microsharp Corporation Ltd.Inventors: Zhi Li, Rifat Iqbal, Jun Wang
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Publication number: 20090298964Abstract: Methods for making a crosslinked elastomeric composition and articles made of the same are provided. In at least one specific embodiment, an elastomeric composition comprising at least one propylene-based polymer is blended with at least one component selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, functionalized polybutadiene resins, functionalized cyanurate, and allyl isocyanurate; and blended with at least one component selected from the group consisting of hindered phenols, phosphites, and hindered amines. The propylene-based polymer can include propylene derived units and one or more dienes, and have a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g. The blended composition can then be extruded and crosslinked. The extruded polymer can be crosslinked using electron beam radiation having an e-beam dose of about 100 KGy or less. The crosslinked polymers are particularly useful for making fibers and films.Type: ApplicationFiled: May 30, 2008Publication date: December 3, 2009Inventors: Sunny Jacob, Alistair D. Westwood, Tonson Abraham
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Publication number: 20090163615Abstract: The present application provides a latent ink-jet ink formulation suitable as solder mask. The composition generally comprises: (a) at least one compound capable of self cross-linking (USM); (b) at least one phenolic resin; (c) at least one solvent; (d) at least one mineral filler; (e) at least one polyol; and (f) at least one photoinitiator.Type: ApplicationFiled: August 31, 2006Publication date: June 25, 2009Inventors: Izhar Halahmi, Shalom Luski, Michal Cohen
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Patent number: 7462651Abstract: A radiation-curable desiccant-filled adhesive/sealant composition comprising a radiation-curable resin, one or more desiccant fillers, one or more photoinitiators or photosensitizers, and optionally, one or more inorganic or organic fillers.Type: GrantFiled: March 30, 2006Date of Patent: December 9, 2008Assignee: National Starch and Chemical Investment Holding CorporationInventors: Jie Cao, Donald E. Herr
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Publication number: 20080300336Abstract: The present invention discloses a method of making high performance UV cross-linked polymer functionalized molecular sieve/polymer mixed matrix membranes (MMMs) with either no macrovoids or voids of less than several angstroms at the interface of the polymer matrix and the molecular sieves. These UV cross-linked MMMs were prepared by incorporating polyethersulfone (PES) functionalized molecular sieves such as AlPO-14 and UZM-25 small pore microporous molecular sieves into a continuous UV cross-linkable polyimide polymer matrix followed by UV cross-linking. The UV cross-linked MMMs in the form of symmetric dense film, asymmetric flat sheet membrane, or asymmetric hollow fiber membranes have good flexibility, high mechanical strength, and exhibit significantly enhanced selectivity and permeability over polymer membranes made from corresponding continuous polyimide polymer matrices for carbon dioxide/methane and hydrogen/methane separations.Type: ApplicationFiled: June 1, 2007Publication date: December 4, 2008Inventors: Chunqing Liu, Jeffrey J. Chiou, Stephen T. Wilson
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Publication number: 20080295692Abstract: The present invention discloses high performance UV cross-linked polymer functionalized molecular sieve/polymer mixed matrix membranes (MMMs), the method of making these membranes, and the use of such membranes for separations. These UV cross-linked MMMs were prepared by incorporating polyethersulfone functionalized molecular sieves such as AlPO-14 and UZM-25 into a continuous UV cross-linkable polymer matrix followed by UV cross-linking. The UV cross-linked MMMs in the form of symmetric dense film, asymmetric flat sheet membrane, or asymmetric hollow fiber membranes described in the current invention have good flexibility and high mechanical strength, and exhibit significantly enhanced selectivity and permeability over the polymer membranes made from the corresponding continuous polyimide polymer matrices for carbon dioxide/methane (CO2/CH4) and hydrogen/methane (H2/CH4) separations.Type: ApplicationFiled: June 1, 2007Publication date: December 4, 2008Inventors: Chunqing Liu, Jeffrey J. Chiou, Stephen T. Wilson
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Publication number: 20080258345Abstract: The present invention relates to liquid radiation-curing compositions having flexible and elastic material properties in the cured state, consisting of the following components: a) from 5.0 to 99.0% by weight of a di- or polyfunctional polyether (meth)-acrylate compound having a molecular weight of more than 1000 g/mol; b) from 1.00 to 90.0% by weight of a mono-, di- or polyfunctional radiation-curing (meth)acrylate compound having a molecular weight of less than 1000 g/mol as a reactive component or reactive thinner or cross-linking agent for the formation of polymer networks; c) from 0.05 to 10.0% by weight of a free-radical forming photoinitiator; d) from 0.001 to 5.0% by weight of further components; with the proviso that the sum of components a) to d) amounts to 100% by weight.Type: ApplicationFiled: July 15, 2005Publication date: October 23, 2008Inventors: Arthur Thomas Bens, Hermann Seitz, Carsten Tille
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Publication number: 20080227884Abstract: A flame retardant suitable for manufacturing a polymer composition is provided. The polymer composition is used for forming a cured film in which a balance among flame retardancy, adhesion, chemical resistance, heat resistance, and elasticity, and so on, is provided. A flame-retardant polymer composition with an excellent balance among the above properties is also provided. The flame retardant of the invention has a structure of Formula (1), (2), or (3): (in which, R1 is hydrogen or methyl, R2 is C2-20 alkylene or C2-20 alkylene in which any —CH2— is replaced by —O—, R3 and R4 are C1-20 alkyl, phenyl, and phenyl substituted by C1-5 alkyl or phenyl, R3 and R4 may also be an integrally-formed cyclic group, and p and q are 0 or 1).Type: ApplicationFiled: March 5, 2008Publication date: September 18, 2008Applicant: CHISSO CORPORATIONInventors: RYOTA MINEO, TOMOHIRO ETO, YOSIHIRO DEYAMA, HIROYUKI SATOU
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Publication number: 20080171800Abstract: The invention relates to a flame-retardant resin formulation comprising respectively at least one flame-retardant component, one alkali-soluble component, one polymerizable monomer, one photoinitiator, and one epoxy component, which comprises, as flame-retardant component, a phosphinic salt of the formula (I), in which R1 and R2 are identical or different and, independently of one another, are C1-C6-alkyl, linear or branched, and/or aryl; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base, and m is from 1 to 4. This novel flame-retardant resin formulation is preferably used as solder resist.Type: ApplicationFiled: January 11, 2008Publication date: July 17, 2008Inventors: Mathias Dietz, Harald Bauer, Werner Krause
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Patent number: 7384989Abstract: A liquid coating material in the form of a water-in-oil dispersion which is curable with actinic radiation, is substantially or completely free from organic solvents and has a pH<5, comprising (A) at least one constituent selected from the group consisting of low molecular mass, oligomeric, and polymeric organic compounds which contain at least one group which can be activated with actinic radiation, and also air-drying and oxidatively drying alkyd resins, (B) at least one acidic ester of polyphosphoric acid and at least one compound (b1) containing at least one hydroxyl group and at least one group which can be activated with actinic radiation, (C) at least one acidic ester of monophosphoric acid and at least one compound (c1) containing at least one hydroxyl group and at least one group which can be activated with actinic radiation, and (D) at least one acidic, corrosion-inhibiting pigment based on polyphosphoric acid; process for its preparation, and its use as a coil coating primer.Type: GrantFiled: November 5, 2003Date of Patent: June 10, 2008Assignee: BASF Coatings AGInventors: Maxime Allard, Thomas Reher, Dominique Kauffer
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Publication number: 20070197677Abstract: A sulfonium salt is provided that has a cation represented by Formula (II) (R1? to R13? in Formula (II) independently denote a hydrogen atom or a substituent, and may be bonded to each other to form a ring, provided that at least one of R1? to R8? denotes a halogen atom or a haloalkyl group). There are also provided a curable composition that includes the sulfonium salt, and an ink composition that includes the curabie composition. Furthermore, there are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.Type: ApplicationFiled: January 30, 2007Publication date: August 23, 2007Applicant: FUJIFILM CorporationInventors: Tomotaka Tsuchimura, Yasutomo Kawanishi
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Patent number: 7202285Abstract: Compositions suitable for use as base coats and varnishes, preferably for use in combination with electrostatic of set inks printed onto plastics substrates, particularly polycarbonate compact discs. They contain a photopolymerisable material, a photoinitiator, an inorganic transfer agent and heavy metal salt, preferably a metallic carboxylate. They have a good shelf life and good adhesion after hardening with ultraviolet light.Type: GrantFiled: March 27, 2001Date of Patent: April 10, 2007Assignee: Sericol LimitedInventors: Angelique Runacre, Paul Geoffrey Day
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Patent number: 7129281Abstract: The present invention provides a one-bottle dental bonding composition that provides a bonding layer excellent in bonding strength, independent of the skill of the practitioners, and, more preferably, that releases fluoride ion gradually into oral cavity over an extended period of time. The one-bottle dental bonding composition comprises a radical polymerizable monomer (A) having an acidic group in the molecule, another radical polymerizable monomer (B), a photopolymerization initiator (C) and a water-soluble organic solvent (D), and is substantially free of water.Type: GrantFiled: March 18, 2003Date of Patent: October 31, 2006Assignee: Dentsply-Sankin K.K.Inventor: Satoshi Fujiwara
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Patent number: 6946498Abstract: A coating composition comprising (1) an anionic surfactant comprising a sulfonic acid salt, (2) a sol of fine inorganic oxide particles, (3) a silicon compound having one acryl or methacryl group and a hydrolyzable group or a product of hydrolysis of the compound, (4) a compound having at least two photopolymerizable unsaturated groups, and (5) a photopolymerization initiator; and a coated article obtained by applying the coating composition to a base and then photocuring the coating. The coated article combines antifogging properties with abrasion resistance sufficient for practical use.Type: GrantFiled: June 6, 2002Date of Patent: September 20, 2005Assignee: Nippon Arc Co., Ltd.Inventor: Hisayuki Kayanoki
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Patent number: 6864301Abstract: Methods of forming crosslinked polymer particles in situ from polymer precursors such as monomers or oligomers, comprising exposing a composition comprising at least one polymer precursor, a solvent or solvent mixture, and an antisolvent or antisolvent mixture to photoradiation under conditions whereby particles are formed are provided. The polymer precursor may be photosensitive, or a separate polymerization initiator may be used. In a preferred embodiment, the polymer precursor is insoluble in the antisolvent or antisolvent mixture and the solvent or solvent mixture is soluble in the antisolvent or antisolvent mixture at the concentrations used. Crosslinked polymer particles and crosslinked polymer particles comprising a polymer and a bioactive material are also provided. The polymer may be erodable, and the polymer particles formed may be used in a variety of applications, including controlled release of bioactive materials such as drugs.Type: GrantFiled: June 3, 2002Date of Patent: March 8, 2005Assignee: The Regents of the University of ColoradoInventors: Theodore Randolph, Kristi Anseth, Jennifer L. Owens, Corinne Lengsfeld
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Patent number: 6846852Abstract: This invention provides for compositions, which can be crosslinked by radiation to give elastomeric coatings, which comprises: (a) high-molecular weight siloxanes with multiple (meth)acrylate functional groups; and (b) reinforcing fillers selected from the group consisting of silicone resins and silicone dioxide fillers, wherein the siloxanes (a) have the general structure: [R3SiO1/2]a[(Z)nG—Ym—R2SiO1/2]a?[R2SiO2/2]b[(Z)nG—Ym—RSiO2/2]b?[RSiO3/2]c[SiO4/2]d.Type: GrantFiled: August 16, 2001Date of Patent: January 25, 2005Assignee: Goldschmidt AGInventors: John Allen, Thomas E. Hohenwarter, Jr., Peter Lersch, Ernest D. Moore, Angela Dawn Paez, Jörg Simpelkamp, Steven Paul Smith