Phosphorous Or Sulfur Containing Dnrm Patents (Class 522/82)
  • Patent number: 6803014
    Abstract: The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.).
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: October 12, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Thoi H. Ho, Selim Bensason, Rajen M. Patel, Kimberly S. Houchens, Rona L. Reid, Pak-Wing S. Chum, Leonie K. Walsh
  • Patent number: 6794454
    Abstract: Disclosed is a rubber composition for forming a core of a solid golf ball, the composition containing a base rubber (A); a filler (B); an organic peroxide (C); and a dry blend and/or a solvent slurry blend (D) of an unsaturated carboxylic acid metallic salt and a metal-containing organic sulfur compound represented by the following formula (1): (wherein X represents a halogen atom, each of m and n represents an integer of 0 to 5 inclusive, and M represents a divalent metallic atom). The rubber composition exhibits high curing rate, and can be cured within shorter time, whereby productivity of a core can be improved.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: September 21, 2004
    Assignee: Bridgestone Sports Co., Ltd.
    Inventor: Nobuyuki Kataoka
  • Patent number: 6767577
    Abstract: The present invention discloses an ultraviolet light curable electroluminescent composition and method for making such a composition that may be used to produce an electroluminescent active layer. An active layer is a layer that when incorporated in a suitable device emits light when a voltage is applied. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing. It is an advantage of the present invention that the deposition of the dielectric layer in such a device is optional when the disclosed electroluminescent composition is used to deposit the active layer.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: July 27, 2004
    Assignee: Allied PhotoChemical, Inc.
    Inventor: Roy C. Krohn
  • Patent number: 6649669
    Abstract: A single solution bonding formulation for dental applications comprising a plurality of at least one self-polymerizable polyvinyl acidic monomer or at least two different polymerizable polyvinyl acidic monomers, a calcium phosphate filler, at least one photoinitiator, optionally an accelerator, optionally a solvent, and optionally a fluoride additive is provided. Additionally, a method for treating enamel, dentin, and/or pulp with the same single solution bonding formulation is provided. The single solution bonding formulation provides for the release of calcium, phosphate and/or fluoride ions which are sufficient in situ to form hydroxyapatite and/or fluorapatite.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: November 18, 2003
    Assignee: American Dental Association Health Foundation
    Inventor: Sabine Dickens
  • Patent number: 6632853
    Abstract: Dental composites containing hybrid fillers and process for their production. Dental compounds are disclosed which contain two- or multi-phase inorganic fillers in an organic polymer matrix. These are characterized by improved abrasion resistance.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: October 14, 2003
    Assignees: Degussa AG, Forschungszentrum Karlsruhe GmbH
    Inventors: Jochen Alkemper, Joachim Binder, Harald Rentsch, Hans-Joachim Ritzhaupt-Kleissl, Jürgen Hausselt
  • Patent number: 6602601
    Abstract: The disclosed invention includes a composition for an optical fiber coating. The cured composition includes at least one monomer and at least one compound from the following group of compounds that consist of an ultra-violet light absorber, a hindered amine light stabilizer, and an optical brightener. The invention also includes an optical fiber coated with the inventive coating.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: August 5, 2003
    Assignee: Corning Incorporated
    Inventors: Edward J. Fewkes, Himanshu C. Shah, Frederic C. Wagner
  • Patent number: 6387975
    Abstract: A photo-latent initiator for photopolymerization comprises crystalline ion-association substance having the general formula (I): [{C5(R1)n}2mMm]1+[{B(R2)4}−]l Said initiator can polymerize a cationically polymerizable organic substance only with light irradiation without additional heating. It is extremely stable when stored alone or in the form of a mixture with a cationically polymerizable organic substance.
    Type: Grant
    Filed: January 26, 2000
    Date of Patent: May 14, 2002
    Assignee: Autex, Inc.
    Inventor: Shin Hiwasa
  • Patent number: 6369123
    Abstract: Radiation-crosslinkable elastomeric compositions containing: (a) an elastomeric polymer containing abstractable hydrogen atoms in an amount sufficient to enable the elastomeric polymer to undergo crosslinking in the presence of a suitable radiation-activatable crosslinking agent; and (b) a radiation-activatable crosslinking agent of the formula: wherein: X represents CH3—; phenyl; or substituted-phenyl; or substituted-phenyl with the proviso that any substituents on the substituted-phenyl do not interfere with the light-absorbing capacity of the radiation-activatable crosslinking agent and do not promote intramolecular hydrogen abstraction of the radiation activatable crosslinking agent; W represents —O—, —NH—, or —S—; Z represents an organic spacer selected from the group consisting of aliphatic, aromatic, aralkyl, heteroaromatic, and cycloaliphatic groups free of esters, amides, ketones, urethanes, and also free of ethers, thiols, allylic grou
    Type: Grant
    Filed: August 14, 1995
    Date of Patent: April 9, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Peter A. Stark, Edward G. Stewart, Albert I. Everaerts
  • Publication number: 20020031654
    Abstract: There is disclosed a method for manufacturing products through the use of waste materials of various kind, such as heterogeneous plastic materials, wood, minerals, etc., derived from recycling processes, differentiated waste collection systems, solid urban wastes, industrial processing scraps or by-products, and the like, such products being adapted to be used in a wide range of most varied applications, particularly though not exclusively for manufacturing structural parts and decorative finishes for office furniture as well as furniture for cinematoghraph theatres, communities, concert halls and the like.
    Type: Application
    Filed: July 16, 2001
    Publication date: March 14, 2002
    Inventor: Mario Bertoglio
  • Patent number: 6348517
    Abstract: A method of preparing a sterile article is disclosed. A polymer having a halogen-containing repeating unit is prepared that contains about 0.
    Type: Grant
    Filed: September 1, 2000
    Date of Patent: February 19, 2002
    Assignee: Oxy Services, Inc.
    Inventors: Qi Wang, Sandor Nagy
  • Patent number: 6313189
    Abstract: Described herein are methods for preparing bioabsorbable polymerization products having interconnecting pore structure by polymerizing compositions containing ethylene glycol- or glycero-oligoester(meth)acrylates monomers and, optionally, other components. The polymerization products are particularly useful for dental lacquers, dental inlays and shaped articles which are bioabsorbable and exhibit an interconnecting pore structure.
    Type: Grant
    Filed: May 4, 1999
    Date of Patent: November 6, 2001
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Robert Wenz, Berthold Nies
  • Patent number: 6296916
    Abstract: A photopolymerizable composition comprising (A) 100 parts by weight of a mixture of (meth)acrylic acid ester monomers, (B) from 0.1 to 5 parts by weight of a surfactant having a perfluoroalkyl group and represented by the general formula (1) CF3(CF2)nAM  (1) wherein A represents —CO2— or —SO3—, M represents an alkali metal, and n is an integer of 3 to 9, and (C) from 0.2 to 10 parts by weight of a photopolymerization initiator, and a plastic optical disk provided with a cured coating of the photopolymerizable composition on at least one side thereof.
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: October 2, 2001
    Inventors: Juichi Fujimoto, Kouji Furukawa, Takashi Mita, Makoto Tokumizu
  • Patent number: 6294592
    Abstract: The invention provides for pigment preparations containing, as main components, A) at least a finely divided organic or inorganic pigment, B) a dispersing agent composed of formaldehyde-arylsulfonic acid or oxalkylated phenols condensates, C) a radiation curable binder, D) optionally a photoinitiator, and E) water. The invention also provides for the use of said preparations as inks for said ink jet printing method.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: September 25, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Herrmann, Gert Motzkus, Wolfgang Reich, Rüdiger Sens, Bernd Siegel, Karl Siemensmeyer
  • Patent number: 6211262
    Abstract: A corrosion resistant coating for metal surfaces curable with actinic radiation. The blend uses acrylate resin, photoinitiator and a corrosion preventing agent such as a metal surface passivator, overbased calcium sulfonate/calcium carbonate, a barrier pigment, or a combination of two or more of these agents.
    Type: Grant
    Filed: April 20, 1999
    Date of Patent: April 3, 2001
    Assignee: Spectra Group Limited, Inc.
    Inventors: Alexandre Mejiritski, Thomas Marino, Violeta Lungu, Dustin Martin, Douglas Neckers
  • Patent number: 6025017
    Abstract: A coating formulation suitable for use in preparing thermal transfer ribbons is provided which is curable by UV radiation or visible light. The coating formulation forms thermal transfer layers that produce printed images when used in a thermal transfer printer. The coating formulation comprises a photoreactive monomer or oligomer, a photoinitiator and a sensible material. Also provided are printers which use these ribbons and processes for preparing them.
    Type: Grant
    Filed: May 21, 1997
    Date of Patent: February 15, 2000
    Assignee: NCR Corporation
    Inventor: Joseph D. Roth
  • Patent number: 5932625
    Abstract: A photo-curable resin composition suitable as a material for photo-fabricating and capable of producing cured products with excellent mechanical strength and high heat resistance. Further disclosed is a process for molding a resin-based mold which provides superior molding dimensional precision and superb repetition durability. The resin composition contains a monomer component containing (A) 30-70 wt % of a polyfunctional unsaturated monomer having a cyclic structure and (B) 70-30 wt % of a monofunctional unsaturated monomer having a cyclic structure of which the homopolymer has a glass transition temperature (Tg) of 70.degree. C. or higher; (C) a photo-initiator; and (D) an inorganic filler having an average particle diameter or an average fiber length of 1-50 .mu.
    Type: Grant
    Filed: May 30, 1997
    Date of Patent: August 3, 1999
    Assignees: DSM N.V., JSR Corporation, Japan Fine Coatings Co., Ltd.
    Inventors: Tsuyoshi Watanabe, Ayao Matsumura, Yuichi Haruta, Takashi Ukachi
  • Patent number: 5811505
    Abstract: An energy-polymerizable composition derived from ingredients comprising: a cyanate ester monomer or oligomer comprising an organic radical bonded through aromatic carbon atoms to at least two --OCN groups; a low molecular weight polyalkylene glycol; and an organometallic compound in which at least one carbon atom of an organic group is bonded to a metal atom. The composition can be cured by at least one of thermal energy, radiation, and accelerated particles, to produce a cured, homogeneous composition.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: September 22, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Fred B. McCormick
  • Patent number: 5667894
    Abstract: An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct which is of an epoxy resin that has been reacted with an amine, and a blocked polyisocyanate crosslinking agent; wherein the improvement is the use of an alkane sulfonic acid as the neutralizing agent for the epoxy amine adduct to provide an electrocoating composition having improved throw power.
    Type: Grant
    Filed: June 5, 1996
    Date of Patent: September 16, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Joseph Albert Antonelli, Christopher Scopazzi, William Bertus Vanderlinde
  • Patent number: 5521229
    Abstract: A polymer composite is described having a bicontinuous structure of two substantially nonporous phases, one being a hydrophilic polymer and the other being a hydrophobic polymer. The bulk properties of both polymers are retained in the polymer composite. The composite is prepared from a microemulsion comprising a free-radically ethylenically unsaturated polar species in the aqueous phase, a free-radically ethylenically unsaturated hydrophobic monomer in the oil phase, and surfactant.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: May 28, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ying-Yuh Lu, Chung I. Young
  • Patent number: 5491178
    Abstract: This invention relates to vinyl ether-based coatings for which properties such as color stability, thermal stability, mechanical stability, hydrolytic stability, and resistance to embrittlement may be maintained and properties hydrogen generation and blocking are minimized.
    Type: Grant
    Filed: August 19, 1994
    Date of Patent: February 13, 1996
    Assignee: AlliedSignal Inc.
    Inventors: Raymond J. Swedo, George D. Green, James R. Snyder
  • Patent number: 5444104
    Abstract: A polycarbonate dimethacrylate which is the condensation product of 2 parts of hydroxyalkylmethacrylate of the formula. ##STR1## in which A is C.sub.1 -C.sub.6 alkylene, and 1 part of a bis(chloroformate) of the formula ##STR2## in which R is C.sub.2 -C.sub.5 alkylene having at least two carbon atoms in its principal chain and n is an integer from 1 to 4, is usable, admixed with a secondary monomer suitable for dental applications, such as BIS-GMA; UDMA or the like, as an adhesive system for dental restorative materials. Particularly useful is the novel condensation product of 2-hydroxyethylmethacrylate and triethylene glycol bis(chloroformate).Dental adhesives containing these components are suitable for application to enamel, pretreated dentin, porcelain and metallic surfaces. The dentin surfaces are pretreated by application of an alcoholic solution of an alkali metal salt of benzene sulfinic acid.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: August 22, 1995
    Assignee: Jeneric/Pentron, Inc.
    Inventor: Samuel Waknine
  • Patent number: 5429846
    Abstract: The present invention provides a photo-setting conductive coating composition which is used as an antistatic material constituting articles wherein static electrification must be avoided, such as storage vessels for semi-conductor wafers, electronic/electric parts, floor/wall coverings for a production factory of semi-conductors, etc.The photo-setting conductive coating composition comprising 100 parts by weight of an antimony oxide-containing tin oxide powder (a) having a particle size of 0.01 to 0.4 .mu.m, 10 to 100 parts by weight of a (meth)acrylate compound (b) having at least two (meth)acryloyl groups in a molecule, 10 to 100 parts by weight of an acetal resin (c) having a residual hydroxyl group of 20 to 80 molar %, 0.1 to 10 parts by weight of a photopolymerization initiator (d) and 100 to 1000 parts by weight of an organic solvent (e).
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: July 4, 1995
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Toshiya Sugimoto, Minoru Suezaki, Kouji Maruyama
  • Patent number: 5276068
    Abstract: A polycarbonate dimethacrylate which is the condensation product of 2 parts of hydroxyalkylmethacrylate of the formula ##STR1## in which A is C.sub.1 -C.sub.6 alkylene, and 1 part of a bis(chloroformate) of the formula ##STR2## in which R is C.sub.2 -C.sub.5 alkylene having at least two carbon atoms in its principal chain and n is an integer from 1 to 4, is usable, admixed with a secondary monomer suitable for dental applications, such as BIS-GMA; PUDMA or the like, as an adhesive system for dental restorative materials. Particularly useful is the novel condensation product of 2-hydroxyethylmethacrylate and triethylene glycol bis(chloroformate).
    Type: Grant
    Filed: January 28, 1992
    Date of Patent: January 4, 1994
    Assignee: Jeneric/Pentron, Inc.
    Inventor: Samuel Waknine
  • Patent number: 5182786
    Abstract: This invention provides:(i) an acitve energy beam-curable composition for coating the surface of optical fibers therewith, the composition comprising about 100 parts by weight of an active energy beam-curable substance, about 0.5 to about 100 parts by weight of a particulate substance having a mean particle size of about 0.2 to about 200 .mu.m and optionally a photopolymerization initiator;(ii) a coated optical fiber prepared by applying the composition of item (i) to the surface of an optical fiber and curing the coating;(iii) a bundle-type optical fiber cable prepared using the coated optical fiber of item (ii);(iv) an optical fiber unit of the tape type prepared by applying the composition of item (i) to optical fibers and curing the coating; and(v) an optical fiber prepared using the optical fiber unit of item (iv).
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: January 26, 1993
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Yoshimasa Kinaga, Masao Ogawa, Yoshihiro Kiyomura
  • Patent number: 5063137
    Abstract: A resin composition for laser-marking which comprises at least one inorganic compound selected from the group consisting of anhydrous metal borate salt, an anhydrous metal phosphate salt, a phosphoric acid-containing glass, basic zinc carbonate and basic magnesium carbonate, and a resin; and a method for laser-marking the surface of an object composed of the said resin composition by applying laser beams onto the surface.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: November 5, 1991
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Toshiyuki Kiyonari, Satoshi Hirabayashi, Naoto Kidokoro, Futoshi Takimoto
  • Patent number: 4923905
    Abstract: A light curable dental composition is provided. The composition comprises an ethylenic unsaturated compound and a light polymerization initiator. The light polymerization initiator is a combination of an .alpha.-diketone and a polyperoxy ester containing a benzophenone group and represented by the general formula (I) of: ##STR1## wherein R.sub.1 and R.sub.1 ' represent a tertiary alkyl group or a tertiary aralkyl group and R.sub.2 and R.sub.2 ' represent a hydrogen atom, a tertiary alkoxy group or a tertiary aralkyloxy group.
    Type: Grant
    Filed: February 26, 1988
    Date of Patent: May 8, 1990
    Assignee: Nippon Oil and Fats Co., Ltd.
    Inventors: Eiichi Masuhara, Yoshinori Kadoma, Takeo Matsumoto, Takeshi Komai, Eiichi Yamada, Osamu Nakachi, Godo Irukayama
  • Patent number: 4813876
    Abstract: Biocompatible, shelf-stable, polymerizable compositions which are especially useful for applications requiring direct contact with living pulpal tissue, bone or dentin, and methods for using the compositions are disclosed. The compositions are non-toxic, both before and after in situ polymerization, and include at least one polymerizable monomer or prepolymer which polymerized by a mechanism other than chelation or saponification. In one aspect, the compositions comprise at least one non-toxic polymerizable ethylenically unsaturated monomer or prepolymer and a catalytically effective amount of a free radical initiator system, and preferably, from about 5 to about 70% by weight of calcium hydroxide or calcium oxide.
    Type: Grant
    Filed: May 8, 1987
    Date of Patent: March 21, 1989
    Assignee: Dentsply Research & Development Corp.
    Inventor: Wu-Lan Wang
  • Patent number: 4746686
    Abstract: A visible light activated cavity liner which provides an available source of leachable calcium and fluoride to the base of a tooth cavity, said composition comprising a photopolymerizable matrix material, a photo initiator, a reducing agent, a synthetic hydroxyapatite filler and a powdered glass ionomer filler.
    Type: Grant
    Filed: April 17, 1987
    Date of Patent: May 24, 1988
    Assignee: Kerr Manufacturing Company
    Inventor: Duncan E. Waller
  • Patent number: 4668529
    Abstract: A filler composition curable by subjection to ultraviolet radiation and the method of repairing deformities in wall elements by utilization of the composition. The composition is advantageously adapted for use in vehicle body repair. The composition is a single component epoxy system facilitating storage and use on site. Curing of the composition may be effected at relatively low temperatures such as down to approximately 30.degree. F. Curing of the composition is effected rapidly for further improved efficiency in the repair operations utilizing the compound.
    Type: Grant
    Filed: April 12, 1985
    Date of Patent: May 26, 1987
    Assignee: Ronald L. Berry
    Inventor: Doyce T. Blair
  • Patent number: 4604411
    Abstract: An improved process for preparing a sticky water-soluble polymer, e.g. acrylamide polymers and acrylic acid polymers, which comprises polymerizing an aqueous solution of a monomer in a polymerization vessel of which the surface contacting the aqueous monomer solution is covered with a tetrafluoroethylene-ethylene copolymer film, whereby the stickiness of the produced polymer to the vessel is remarkably decreased, namely the peelability of the polymer from the vessel is remarkably improved, and moreover the polymerization conversion is remarkably improved. Also, the use of a metal deposited tetrafluoroethylene-ethylene copolymer film as a covering material improves the efficiency of a photopolymerization and enables to use a polymerization vessel made of an inexpensive material.
    Type: Grant
    Filed: January 4, 1985
    Date of Patent: August 5, 1986
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Akira Yada, Shusaku Matsumoto, Yoshihiro Kawamori, Takao Saito, Tadashi Nishiyama, Yoshitugu Adachi