Abstract: A method of three-dimensional (3D) printing is provided. Print data is received, which defines patterns of at least one agent to be applied to a layer of build material. The print data is modified to add a further pattern of a detailing agent to be selectively applied to the layer of build material to generate fracture regions in a processed volume of build material.
Type:
Grant
Filed:
May 12, 2016
Date of Patent:
October 26, 2021
Assignee:
Hewlett-Packard Development Company, L.P.
Inventors:
Scott A. White, Justin M. Roman, Xavier Alonso Becerro, Ismael Chanclon Fernandez, Samuel A. Stodder, Glenn Thomas Haddick
Abstract: A cross-linkable thermoplastic resin coating that is suitable for use in a coated proppant material used in sand control in oil and gas wells. The cross-linkable thermoplastic exhibits improved stability and low temperature and pressure strength compared to current thermosetting resin formulations.
Abstract: A foundry mix includes a major amount of a foundry aggregate and an effective binding amount of a binder system. The binder system cures in the presence of sulfur dioxide and a free radical initiator. The binder system may include (1) 10 to 70 parts by weight of an epoxy novolac resin; (2) 0.5 to 10 parts by weight of resorcinol; (3) 20 to 70 parts by weight of a monomeric or polymeric acrylate; and (4) an effective amount of a free radical initiator. Notably, (1), (2), (3) and (4) are separate components or mixed with another of said components, provided (4) is not mixed with (3), where said parts by weight are based upon 100 parts of the binder system.
Abstract: The invention provides protein adhesives and methods of making and using such adhesives. One type of protein adhesive described herein contains lignin and ground plant meal or an isolated polypeptide composition obtained from plant biomass. Other types of protein adhesives described herein contain a plant protein composition and either a hydroxyaromatic/aldehyde, urea/aldehyde, or amine/aldehyde component.
Abstract: It is an object of the present invention to provide an electrode capable of maintaining superior capacity retention without destruction of an electrode structure, even in the case of using an active material including silicon.
Type:
Grant
Filed:
October 25, 2013
Date of Patent:
August 7, 2018
Assignees:
TOKYO UNIVERSITY OF SCIENCE FOUNDATION, WAKO PURE CHEMICAL INDUSTRIES, LTD.
Abstract: Provided is an article, particularly culinary, comprising a cast iron support having two opposite sides. The article comprises a vitreous coating in the form of at least a continuous layer of a sol-gel material comprising a matrix formed from at least a metal polyalkoxylate and at least a reactive or unreactive silicone oil, the layer of sol-gel material being deposited directly on one at least of the sides of said support, and the side provided with a vitreous coating has a surface roughness Ra ranging between 3 and 15 ?m with a peak count per centimeter RPc ranging between 50 and 200. A method for manufacturing such an article is also provided.
Type:
Grant
Filed:
November 12, 2013
Date of Patent:
July 10, 2018
Assignee:
SEB S.A.
Inventors:
Pierre Jean Muller, Aurelien Dubanchet, Jean-Luc Perillon
Abstract: An alumina-based filling sand for sliding nozzle comprising at least 50 wt % of mixed sand including 20 to 90 vol % of alumina sand and 80 to 10 vol % of silica sand, wherein the alumina sand has surface irregularities of 1.3 or less and comprises 50 wt % or more of an Al2O3 component.
Abstract: This mixed powder for powder metallurgy, the powder having excellent fluidity and minimal graphite powder scattering, can be obtained relatively conveniently by mixing fine graphite having an average grain diameter of 4 ?m or less with an iron based powder. The process is performed without the addition of a binder and while shearing force is applied. It is preferable that the fine graphite have an average grain diameter of 2.4 ?m or less and be wet-milled. A portion of the fine graphite is preferably added in place of at least one constituent selected from the group consisting of carbon black, fullerene, carbon compounds carbonized by baking, and graphite having an average grain diameter of 5 ?m or more.
Abstract: In an illustrative implementation of this invention, a 3D object comprises substrate layers infiltrated by a hardened material. The 3D object is fabricated by a method comprising the following steps: Position powder on all or part of a substrate layer. Repeat this step for the remaining substrate layers. Transform the powder into a substance that flows and subsequently hardens into the hardened material. The hardened material solidifies in a spatial pattern that infiltrates positive regions in the substrate layers and does not infiltrate negative regions in the substrate layers.
Type:
Grant
Filed:
August 29, 2012
Date of Patent:
November 28, 2017
Assignee:
Impossible Objects, LLC
Inventors:
Robert Swartz, Buckley Crist, Joseph Fallon
Abstract: A description is provided of a mixture which is preparable by allowing the reaction of a premixture of (av), methanesulfonic acid (bv), one or more esters of one or more phosphorous-oxygen acids and (cv) one or more silanes. The invention also concerns the use of said mixtures as additives for the polyisocyanate component of a two-component binding agent system for preparation of a polyurethane resin. The invention further concerns a solution containing polyisocyanate for use as a component of a molding material binding agent system, and the use of a solution containing polyisocyanate as the polyisocyanate component of a two-component binding agent system for preparation of a polyurethane resin and corresponding two-component binding agent systems for preparation of a polyurethane resin.
Type:
Grant
Filed:
February 8, 2013
Date of Patent:
January 19, 2016
Assignee:
HUTTENES-ALBERTUS CHEMISCHE WERKE GMBH
Inventors:
Gérard Ladégourdie, Markus Dörschel, Ursula Wichmann, Amine Serghini Anbari, David Strunk
Abstract: Certain embodiments disclosed herein relate to a smooth finish composite structure and methods for making the composite structure. In particular, in one embodiment, a method is provided that includes creating a first layer of a composite structure. The creation of the first layer includes positioning the first layer in a mold and curing the first layer. Additional layers of the composite structure are created and bonded to the first layer.
Abstract: Preparation of a masterbatch of diene elastomer and silica including preparing at least one silica dispersion in water; bringing into contact and mixing an elastomer latex and the aqueous silica dispersion in the presence of a metal salt having an at least divalent metal element, in order to obtain a coagulum; and recovering the coagulum and drying same in order to obtain the masterbatch. The metal cation molar ration, defined as the number of moles of metal cations of the metal salt per BET unit area of the silica, is between 9.375*10?7 and 1.875*10?5 mol/m2.
Type:
Grant
Filed:
October 10, 2012
Date of Patent:
August 25, 2015
Assignees:
COMPAGNIE GENERAL DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE
Inventors:
Benoit De Gaudemaris, Geraldine Laffargue, Julien Berriot
Abstract: A foundry mixture for making molds used for molding cast metal parts includes foundry sand, a non-aqueous binder, and a cleaning agent that includes calcium oxide. Residual foundry mixture remaining on the cast part after removal from the mold is removed by electrolytic cleaning of the cast part.
Type:
Grant
Filed:
October 10, 2014
Date of Patent:
May 26, 2015
Assignee:
Newton Engine Corporation
Inventors:
John E. Hoffman, Jr., Richard A. Hoffman, Sr.
Abstract: A curing agent composition for making foundry molds, comprising 2,6-dihydroxybenzoic acid. In a sand composition for making foundry molds, it is preferable to use simultaneously: an acid-hardening resin which contains both a binder composition for making foundry molds which comprises one or more 5-position-substituted furfural compounds selected from the group consisting of 5-hydroxymethylfurfural and 5-acetoxymethylfurfural, and the curing agent composition for making foundry molds which comprises 2,6-dihydroxybenzoic acid. It is preferable that the content of 2,6-dihydroxybenzoic acid in the curing agent composition is 10 to 80 wt %.
Abstract: Casting compound suitable for casting an electronic module, in particular a large-volume coil such as a gradient coil, which is composed of a support material forming a matrix, one or more fillers made of inorganic microparticles, and at least one filler made of polymer nanoparticles.
Type:
Grant
Filed:
November 5, 2010
Date of Patent:
October 21, 2014
Assignee:
Siemens Aktiengesellschaft
Inventors:
Peter Groeppel, Juergen Huber, Gerhard Piecha, Lothar Schoen, Matthias Uebler
Abstract: Molding sand containing (i) 100 parts by weight of refractory quartz or olivine matrix and (ii) 1 to 5 parts by weight of organic binder. The organic binder contains a mixture of (a) 40-50% w/w aqueous solution of sodium poly(acrylate) in the amount of 30-70% by weight and (b) 40-50% w/w aqueous solution of dextrin in the amount of 30-70% by weight.
Type:
Application
Filed:
March 1, 2013
Publication date:
September 4, 2014
Applicant:
AKADEMIA GORNICZO-HUTNICZA IM. STANISLAWA STASZICA W KRAKOWIE
Inventor:
AKADEMIA GORNICZO-HUTNICZA IM. STANISLAWA STASZICA W KRAKOWIE
Abstract: A binder composition for self-curing mold formation, comprising at least one condensate (A) selected from furfuryl alcohol condensate and furfuryl alcohol/formaldehyde condensate, and an acid-curable resin (B), wherein about the condensate(s) (A), the presence ratio by mole of its/their furan rings (a) to the total of its/their methylol groups (b), methylene groups (c) and oxymethylene groups (d), a:(b+c+d), is from 1:1.00 to 1:1.08, and the content by percentage of the at least one condensate (A) is from 0.3 to 8.0% by weight.
Abstract: The subject matter of the invention relates to coating compositions comprising formic acid esters, an aqueous carrier liquid and pulverulent refractory material, and to the use thereof for casting molds, in particular those produced using water glass as a binder.
Type:
Application
Filed:
October 5, 2012
Publication date:
August 28, 2014
Inventors:
Michael Kloskowski, Peter Wachtarczyk, Carolin Wallenhorst
Abstract: A system for use in forming polymer compositions, including as a replacement for phenolic based resin systems, for instance, in preparing foundry molds. In a preferred embodiment, the system includes the use of a) a polyermizable hydroxyl-containing component comprising a humic substance (as can be provided by lignite), b) an isocyanate component, and c) a catalyst, and preferably amine catalyst, component adapted to catalyze the polymerization of a) and b). The system is optionally used as binder system in the presence of a filler, such as, in combination with a foundry aggregate such as sand. A polymer system of this invention can be substantially free of formaldehyde or phenol, and preferably contains little or no aromatic solvents.
Type:
Grant
Filed:
November 14, 2008
Date of Patent:
August 26, 2014
Assignee:
University of Northern Iowa Research Foundation
Abstract: The invention relates to a molding material mixture for production of molded products for the foundry industry, comprising at least one fire-resistant base molding material and a polyurethane-based binder system comprising a polyisocyanate component and a polyol component. According to the invention, the polyurethane-based binder system comprises a portion of a carboxylic acid diester of a branched alkane diol, said portion being at least 3 weight-%, and a portion of aromatic solvent of less than 10 weight-% of the binder system. A preferable carboxylic acid diester is 2,2,4-trimethyl-1,3-pentandiol-diisobutyrate. The molded products produced from the molding material mixture for the foundry industry are characterized by a high strength and a lower generation of fumes and smoke during pouring.
Abstract: Described herein, in the preferred embodiment, is a leonardite-based polyurethane resin binder that may be used, among other applications, as a binder in combination with foundry aggregate, e.g., sand, for molding or casting metal parts. The binders described herein comprise a humic substance, preferably leonardite, combined with a polymerizable polyol, an isocyanate, and a polymerization catalyst to make a polyurethane resin binder in situ in a foundry aggregate, such as sand. The lignite is mixed with the polymerizable polyol and dispersing agents as additives to improve the suspension quality and binder performance of the lignite-containing part of the binder components.
Abstract: A phenol-formaldehyde novolac resin having a low concentration of free phenol prepared by distilling residual phenol from a molten novolac resin and replacing at least a portion of the phenol with a solvent having a volatility equal to or less than phenol. Such modified novolac resins are suitable for the production of resin coated molding sands for shell molding and sand cores, as well as for the production of resin coated proppants for use in oil and gas recovery operations.
Abstract: A curing agent composition for a water-soluble phenol resin used to produce a mold, which comprises a branched ester compound that is derived from a carboxylic acid having a branched chain, and an alcohol, and has 5 to 13 carbon atoms.
Abstract: Described herein, in the preferred embodiment, is a leonardite-based polyurethane resin binder that may be used, among other applications, as a binder in combination with foundry aggregate, e.g., sand, for molding or casting metal parts. The binders described herein comprise a humic substance, preferably leonardite, combined with a polymerizable polyol, an isocyanate, and a polymerization catalyst to make a polyurethane resin binder in situ in a foundry aggregate, such as sand. The lignite is mixed with the polymerizable polyol and dispersing agents as additives to improve the suspension quality and binder performance of the lignite-containing part of the binder components.
Abstract: Described herein, in the preferred embodiment, is a leonardite-based polyurethane resin binder that may be used, among other applications, as a binder in combination with foundry aggregate, e.g., sand, for molding or casting metal parts. The binders described herein comprise a humic substance, preferably leonardite, combined with a polymerizable polyol, an isocyanate, and a polymerization catalyst to make a polyurethane resin binder in situ in a foundry aggregate, such as sand. The lignite is mixed with the polymerizable polyol and dispersing agents as additives to improve the suspension quality and binder performance of the lignite-containing part of the binder components.
Abstract: Disclosed is a foundry mix containing a sulfate and/or nitrate salt and its use to make foundry shapes by the warm-box, hot-box, no-bake, and cold-box process, the use of these foundry shapes to make metal castings, and the metal castings prepared by the process.
Abstract: Described herein, in a preferred embodiment, is a leonardite-based polyurethane resin binder that may be used, among other applications, as a binder in combination with foundry aggregate, e.g., sand, for molding or casting metal parts. The binders described herein comprise a humic substance, preferably leonardite, first mixed with a foundry aggregate and then the humic-aggregate mixture is combined with a polymerizable polyol, an isocyanate, and a polymerization catalyst to make a polyurethane resin binder in situ in a foundry aggregate, such as sand. The lignite is added as a solid to the foundry aggregate, and improves the binder performance of the lignite-containing part of the binder components.
Abstract: The invention relates to microspheres coated with a phenolic novolak resin, a process for preparing them, and their use in making foundry shapes, e.g. molds, cores, sleeves, pouring cups, etc., which are used in casting metal parts.
Abstract: The present invention provides a plate brick having a low amount of generation of smoke and a gas with a pungent odor during use, and exhibiting high durability. A plate brick of the present invention is obtained by: adding an organic binder to a refractory raw material mixture containing 0.5 to 20 mass % of aluminum and/or aluminum alloy; kneading the mixture with the organic binder; forming the kneaded mixture into a shaped body; and subjecting the shaped body to a heat treatment at a temperature of 400 to 1000° C., wherein the plate brick is obtained without being impregnated with a carbon-containing liquid material comprising tar or pitch, after the heat treatment. The plate brick has a compressive strength of 180 MPa or more, and a weight-increasing rate of 1% or less as measured in a hydration test using an autoclave.
Abstract: A foundry mix composition including silica sand, unexpanded perlite ore, and a binder material. The unexpanded perlite ore is present in the foundry mix composition from about 0.5 wt % to about 5.0 wt %. Exemplary embodiments of the present invention also contemplate methods of making a sand mold/core from such a foundry mix composition.
Type:
Application
Filed:
February 4, 2011
Publication date:
August 9, 2012
Applicant:
ASK CHEMICALS L.P.
Inventors:
Ralph E. Showman, Stacey L. Clifford, Sean B. Harmon
Abstract: A composition for use in investment casting shells and a method of making the composition is disclosed. The composition includes an engineered binder and a refractory flour. The engineered binder comprises a siliceous material and at least one organic component selected from: at least one type of wood pulp; at least one species of cellulose fiber; and combinations thereof. A particular benefit of the investment shell composition is simultaneously increased permeability and load bearing capacity.
Abstract: Phenolic resin binder systems for sand molds, used in metal casting, which improve the quality of thermally reclaimed sand, are described. The substantial or complete elimination of calcium compounds (e.g., calcium stearate and calcium hydroxide, conventionally employed as a mold lubricant and a resin curing catalyst, respectively) allows the thermally reclaimed sand to be reused over multiple thermal reclamation cycles without the adverse effects previously encountered.
Abstract: A molding process which comprises mixing together a particulate aggregate, plural kinds of water-soluble binders, a crosslinking agent causing crosslinking reaction with the binders, a phenol resin, and water, agitating the obtained mixture to prepare a bubbled fluid aggregate mixture, filling the aggregate mixture into a molding cavity, and solidifying the aggregate mixture through the evaporation of water from the mixture to give a mold made from the mixture.
Abstract: Compositions comprising (1) a refractory and/or a binder, and (2) bis-cyclopentadienyl iron cyclopentadienyl manganese tricarbonyl, derivatives thereof, and mixtures thereof.
Type:
Grant
Filed:
January 26, 2009
Date of Patent:
December 6, 2011
Assignee:
ASK Chemicals L.P.
Inventors:
Ronald C. Aufderheide, Michael T. Brown, Jorg Kroker, Xianping Wang
Abstract: A process for producing casting cores or molds from a mold material, based on mold base material and organic or inorganic binder, an additive composed of pore former, icing sugar and/or a similar carbon compound, and dye being admixed to the mold material and/or the binder.
Abstract: An additive to foundry sand molding and core aggregates is used to produce sand cores and molds comprising kyanite, spodumene, titanium dioxide, ilmenite and black iron oxide. The additive produces a sand-based foundry molding and core aggregate which resists the formation of some of the defects commonly associated with the production of castings produced by silica sand-based molding and core aggregates. In particular, the additive improves the quality of castings poured at temperatures higher than those of the pouring temperatures of molten iron, such as in steel castings, and in iron castings with “hot spots.
Type:
Grant
Filed:
November 6, 2008
Date of Patent:
August 30, 2011
Assignee:
IGC Technologies, LLC
Inventors:
Jeffrey J. Cieplewski, Andrew Callan, Rebecca Roti
Abstract: Disclosed is a foundry mix containing an organic salt and its use to make foundry shapes by the warm-box, hot-box, no-bake, and cold-box process, the use of these foundry shapes to make metal castings, and the metal castings prepared by the process.
Abstract: Casting compound suitable for casting an electronic module, in particular a large-volume coil such as a gradient coil, which is composed of a support material forming a matrix, one or more fillers made of inorganic microparticles, and at least one filler made of polymer nanoparticles.
Type:
Application
Filed:
November 5, 2010
Publication date:
May 19, 2011
Inventors:
Peter Groeppel, Juergen Huber, Gerhard Piecha, Lothar Schoen, Matthias Uebler
Abstract: To provide resin-coated sand for a multilayer mold in which the consolidation strength of the casting mold obtained by using it and gas permeability thereof are improved at the same time, the amount of occurrence of pyrolytic products (tar, soot and the like) derived from organic substances is effectively inhibited, when molding is performed using such a casting mold, and further, the casting mold after molding can exhibit excellent collapsibility. Disclosed is resin-coated sand for a multilayer mold, in which surfaces of refractory particles are coated with a binder composition containing a phenolic novolak resin having an ortho/para bond ratio of methylene groups of 1.5 or more and an aromatic amine as indispensable constituents, and the grain fineness number is from 80 to 150.
Type:
Grant
Filed:
August 13, 2007
Date of Patent:
April 5, 2011
Assignees:
Asahi Organic Chemicals Industry Co., Ltd., Honda Motor Co., Ltd.
Abstract: The invention relates to a size composition (coating composition) for casting moulds and cores, comprising at least one metal additive which contains a metal or a compound of a metal, wherein the metal is selected from one of groups 7 or 9 to 12 of the Periodic Table of the Elements. The invention also relates to a process for producing a casting mould, which comprises a mould coating of the size (coating) according to the invention, and to the use of said mould for the casting of metals.
Type:
Application
Filed:
May 27, 2009
Publication date:
March 31, 2011
Applicant:
Ashland-Südchemie-Kernfest GmbH
Inventors:
Reinhard Stötzel, Matthias Schrod, Michael Kloskowski
Abstract: A bio-based binder system for use in preparing foundry molds. In a preferred embodiment, the system includes the use of a) a polyermizable hydroxyl-containing component comprising a saccharide, b) an isocyanate component, and c) a catalyst, and preferably amine catalyst, component adapted to catalyze the polymerization of a) and b), in the presence of a foundry aggregate such as sand. The system can be used in any suitable manner, including in either a cold box process or no bake process as described herein.
Type:
Application
Filed:
November 14, 2008
Publication date:
December 23, 2010
Applicant:
UNIVERSITY OF NORTHERN IOWA RESEARCH FOUNDATION
Inventors:
Gerard R. Thiel, Shoshanna R. Coon, Mitchell Patterson, Andrew Simonson, Ian Williams, Ryan Jones
Abstract: The present invention provides a structure for producing cast articles containing one or more inorganic particles selected from amorphous and artificial graphites, an inorganic fiber and a thermosetting resin and having a gas permeability of 1 to 500.
Abstract: An object is to provide a nonaqueous hot casting repair mix which, while enjoying simple and convenient installation, can substantially reduce hardening time after installation. The hot casting repair mix according to the invention is characterized by containing 5 to 30% by weight of a binder capable of forming a carbon bond in hot condition and 1 to less than 5% by weight of an iron powder and the balance consisting of a refractory aggregate.
Abstract: This invention relates to a process for making foundry shapes (e.g. cores and molds) using epoxy-acrylate cold-box binders containing an oxidizing agent and elevated levels of an organofunctional silane, which are cured in the presence of sulfur dioxide, and to a process for casting metals using the foundry shapes. The metal parts have fewer casting defects because the foundry shapes made with the binder are more resistant to erosion.
Type:
Grant
Filed:
July 5, 2007
Date of Patent:
May 25, 2010
Assignee:
Ashland Licensing and Intellectual Property, LLC
Inventors:
Xianping Wang, H. Randall Shriver, Jorg Kroker
Abstract: The invention relates to coating material comprising a water-soluble salt as a filler. Such materials are especially suitable as core washes for salt cores for using in foundry technology.
Abstract: A composition has a water dispersible esterified trimer acid (ETA) and a block co-polymer, especially a polyoxyalkylene block copolymer having EO and PO blocks. The composition may also have a polymeric surfactant antifoaming agent and an oil (especially a mineral oil or ester oil).
Abstract: The invention relates to microspheres coated with a phenolic novolak resin, a process for preparing them, and their use in making foundry shapes, e.g. molds, cores, sleeves, pouring cups, etc., which are used in casting metal parts.
Abstract: The invention relates to microspheres coated with a phenolic novolak resin, a process for preparing them, and their use in making foundry shapes, e.g. molds, cores, sleeves, pouring cups, etc., which are used in casting metal parts.
Type:
Grant
Filed:
August 7, 2006
Date of Patent:
February 9, 2010
Assignee:
Ashland Licensing and Intellectual Property, LLC
Abstract: A method for the production of cores and molds for casting molds, based on a base molding material and an organic or inorganic binding agent and an additive. According to the method, pre-forming substances are used in order to dispense with the use of sizing substances and to prevent the formation of ribs.
Type:
Grant
Filed:
April 19, 2003
Date of Patent:
January 12, 2010
Assignee:
Georg Fischer AG
Inventors:
Alexander Schrey, Gotthard Wolf, Rolf Rietzscher
Abstract: The present invention relates to binders for pulverulent metals or pulverulent metal alloys, thermoplastic compositions comprising these binders for producing shaped metallic bodies, a process for producing them, their use and a process for producing shaped bodies therefrom.
Type:
Application
Filed:
July 5, 2007
Publication date:
November 26, 2009
Applicant:
BASF SE
Inventors:
Hans Wohlfromm, Jens Assmann, Johan Herman Hendrik ter Maat, Martin Blömacher