Composition Contains A Phenolic, Amine, Or Ketone Condensate With Aldehyde Plus A Polymer Derived From Ethylenic Monomers Only Patents (Class 523/158)
  • Patent number: 11820172
    Abstract: A pneumatic tire comprises a tread rubber with a groove depth at a shoulder portion that comes into contact with a road surface of 10 mm or greater. A rubber composition of the tread rubber contains: 60 to 70 parts by mass of carbon black having a nitrogen adsorption specific surface area of 70 to 130 m2/g, 0.5 parts or greater by mass of sulfur, and a vulcanization accelerator per 100 parts by mass of diene rubber including 50 to 70 mass % of styrene-butadiene rubber, 20 to 30 mass % of butadiene rubber, and 10 to 30 mass % of natural rubber. The diene rubber has an average glass transition temperature of ?65° C. or lower. A ratio of a compounded amount of the vulcanization accelerator to a compounded amount of the sulfur is 1.0 to 1.3. The tread rubber has a rubber hardness of 65 to 70 at 20° C.
    Type: Grant
    Filed: April 11, 2018
    Date of Patent: November 21, 2023
    Assignee: The Yokohama Rubber Co., LTD.
    Inventor: Hiroki Sugiura
  • Patent number: 11312841
    Abstract: The present invention provides a pneumatic tire and a rubber composition for tires, which have improved durability at high temperatures and during high-speed running while ensuring good ice performance. The present invention relates to a pneumatic tire, including a tread, the tread including blocks having an average ripe density of 1.0 cm/cm2 or higher and an average height of 0.6 to 2.0 cm, the blocks containing a rubber composition having a tan ? at 100° C. of 0.179 or less as determined at an initial strain of 10%, a dynamic strain of 2%, and a frequency of 10 Hz, and has a ratio of the modulus at 100° C. to the modulus at room temperature of 69% or greater as determined in accordance with JIS K6251:2010.
    Type: Grant
    Filed: June 26, 2018
    Date of Patent: April 26, 2022
    Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.
    Inventors: Shuichiro Ono, Subaru Toya
  • Patent number: 11118036
    Abstract: The present invention is directed to a pneumatic tire having a tread comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr), (A) from about 40 to about 90 phr of a solution polymerized styrene-butadiene rubber having a glass transition temperature (Tg) ranging from ?40° C. to 0° C.; (B) from about 60 to about 10 phr of polybutadiene; and (C) from 5 to 50 phr of a hydrocarbon resin having a Tg ranging from ?40° C. to 20° C.; (D) optionally, a rubber process oil (E) optionally, a hydrocarbon resin having a Tg ranging above 20° C. wherein the total amount of hydrocarbon resins and oils is less than 65 phr, and the weight ratio of silica to the total of hydrocarbon resins and oils is greater than 2. (F) from 70 to 130 phr of silica.
    Type: Grant
    Filed: November 2, 2016
    Date of Patent: September 14, 2021
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Nihat Ali Isitman, Manuela Pompei, Eric Engeldinger
  • Patent number: 10302165
    Abstract: A non-asbestos frictional material composition is provided, which is capable of provide a frictional material with low environmental load and with excellent friction coefficient, anti-crack properties, and abrasion resistance compared with conventional ones. Furthermore, a frictional material and a friction member formed by using this non-asbestos frictional material composition are provided. The non-asbestos frictional material composition containing a binder, an organic filler, an inorganic filler, and a fiber base material includes: copper in a content of 5 mass % or less as a copper element; a metal fiber other than a copper fiber and a copper alloy fiber in a content of 0.5 mass % or less; and mica and graphite with a particle size of 90 ?m or less but not containing graphite with a particle size of more than 90 ?m.
    Type: Grant
    Filed: November 7, 2011
    Date of Patent: May 28, 2019
    Assignee: HITACHI CHEMICAL COMPANY, LTD.
    Inventors: Takashi Kikudome, Mitsuo Unno, Kazuya Baba
  • Patent number: 9657798
    Abstract: One exemplary embodiment includes a friction material including a base including a plurality of fibers. The base including an engagement surface, and a plurality of binder particles and friction modifying particles at the engagement surface.
    Type: Grant
    Filed: January 9, 2009
    Date of Patent: May 23, 2017
    Assignee: BORGWARNER INC.
    Inventors: Robert C. Lam, Feng Dong
  • Patent number: 8846780
    Abstract: A friction element for a synchronizing device as well as an apparatus for producing a friction element for a synchronizing device are disclosed.
    Type: Grant
    Filed: June 18, 2012
    Date of Patent: September 30, 2014
    Assignee: Schaeffler Technologies AG & Co. KG
    Inventors: Constanze Kuckuck, Stefan Steinmetz
  • Patent number: 8790772
    Abstract: A wound friction coating and a method for the production thereof.
    Type: Grant
    Filed: December 24, 2009
    Date of Patent: July 29, 2014
    Assignee: Schaeffler Technologies AG & Co. KG
    Inventors: Tim-Florian Gerbing, Christian Spandern
  • Publication number: 20120277345
    Abstract: A mix for a structural component of a tyre, having a cross-linkable polymer base; curing agents; 20-100 phr of a reinforcing filler; and 2-16 phr of a methylene acceptor compound combined with a methylene donor compound. The reinforcing filler is defined by a blend of 20-80% by weight of carbon black classified as N1 or N2, and 80-20% by weight of carbon black classified as N5 or N6.
    Type: Application
    Filed: November 17, 2010
    Publication date: November 1, 2012
    Applicant: BRIDGESTONE CORPORATION
    Inventors: Raffaele Di Ronza, Francesco Botti
  • Patent number: 8278370
    Abstract: A friction lining made of a fibrous mixture with fillers and resin for a wet clutch. In order to design the friction lining able to withstand the higher torque to be transmitted, it is proposed to admix further filler with a Mohs hardness greater or equal to 9.0 and smaller or equal to 9.5 in addition to the ingredients of aramid fibers, cellulose fibers, phenol resin and amorphous silicon dioxide and first filler.
    Type: Grant
    Filed: March 1, 2010
    Date of Patent: October 2, 2012
    Assignee: Schaeffler Technologies AG & Co. KG
    Inventors: Firoz Jafri, Martin Fuss, Michael Wilfong
  • Publication number: 20120123018
    Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition, the rubber composition comprising: from 70 to 90 phr of a styrene-butadiene rubber functionalized with an alkoxysilane group and at least one of a primary amine group and thiol group; from 10 to 30 phr of at least one additional diene based elastomer; from 60 to 100 phr of precipitated silica; from 1 to 10 phr of a polyoctenamer; from 5 to 25 phr of a starch/plasticizer composite; and from 10 to 20 phr of a tackifying resin.
    Type: Application
    Filed: November 17, 2010
    Publication date: May 17, 2012
    Inventors: Carlo Kanz, Christian Jean-Marie Kaes, Olivio Jean-Baptiste Pagliarini, Marc Weydert, Uwe Ernst Frank
  • Publication number: 20110144236
    Abstract: A rubber composition for use in tires including from 60 to 120 parts by weight of a silica having a CTAB specific surface area of from 70 to 175 m2/g and from 3 to 25 parts by weight of an aromatic modified terpene resin excluding terpene phenol resins per 100 parts by weight of a diene rubber including from 30 to 80 weight % of a terminal-modified styrene-butadiene rubber and from 10 to 50 weight % of a butadiene rubber. An average glass transition temperature of the diene rubber is ?55° C. or lower and an average glass transition temperature of a component formed from the diene rubber, the aromatic modified terpene resin, and an optional plasticizer is ?45° C. or lower.
    Type: Application
    Filed: December 6, 2010
    Publication date: June 16, 2011
    Applicant: THE YOKOHAMA RUBBER CO., LTD.
    Inventor: Satoshi Mihara
  • Publication number: 20110124771
    Abstract: The present invention is directed to a pneumatic tire having a component comprising a vulcanizable rubber composition comprising, based on 100 parts by weight of elastomer (phr), (A) from about 60 to about 90 phr of a polymer comprising (1) a terminating group provided from a terminating compound XnSi(OR)mR?4-m-n wherein X is a chlorine atom, a bromine atom or an iodine atom, R is an alkyl group with from about 1 carbon to about 7 carbons, R? is a alkyl group with from about 1 carbon to about 20 carbons, an aryl group, a vinyl group or a halogenated alkyl group, m is an integer from about 1 to about 4, n is an integer from about 0 to about 2, and a sum of n and m is from 1 to 4; (2) repeat units comprising: (a) a repeat unit provided from a conjugated diolefin monomer, and (b) a repeat unit provided from an amine monomer; (B) from about 40 to about 10 phr of polybutadiene having a microstructure comprised of about 96 to about 99 percent cis 1,4-isomeric units, about 0.
    Type: Application
    Filed: November 20, 2009
    Publication date: May 26, 2011
    Inventors: Paul Harry Sandstrom, Brad Stephen Gulas, David Mark Frantz, Steven Wayne Cronin, Tang Hong Wong, Michael Joseph Rachita
  • Publication number: 20110112215
    Abstract: The invention provides a rubber composition for studless tire achieving well-balanced abrasion resistance, performance on ice and snow, handling stability, and wet grip performance; and a studless tire including a tread produced from the composition. The composition contains: a rubber component; aromatic oil; silica; carbon black; and a mixture of a zinc salt of aliphatic carboxylic acid and a zinc salt of aromatic carboxylic acid, wherein the total of NR and BR in 100% by mass of the rubber component is 30% by mass or more, the amount of aromatic oil is 12-85 parts by mass, the amount of silica is 12-85 parts by mass, and the amount of mixture is 1 part by mass or more, per 100 parts by mass of the rubber component, and the proportion of silica is 45% by mass or more per 100% by mass of the total of the silica and carbon black.
    Type: Application
    Filed: November 10, 2010
    Publication date: May 12, 2011
    Inventor: Ryoji KOJIMA
  • Patent number: 7696261
    Abstract: The present invention relates to a friction material having a fibrous base material as a primary layer and a secondary layer comprising a mixture of carbonaceous material and friction modifying particles on at least one surface of the primary layer for use as an anti-shudder friction material.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: April 13, 2010
    Assignee: BorgWarner Inc.
    Inventor: Robert C. Lam
  • Patent number: 7297728
    Abstract: A friction material is made by molding and curing a composition containing a fibrous base that includes stainless steel fibers but not other steel fibers, a binder, and a friction modifier that includes at least two types of hard particles having a large Mohs hardness, bronze powder and a specific amount of tin sulfide. The friction material has a excellent balance of properties, including a high strain linearity that provides a excellent brake feel, a high torque linearity and a excellent effectiveness, and also minimizes disc rotor attack, disc pad wear and metal pickup. Such friction materials are particularly suitable for automotive applications, such as disc pads.
    Type: Grant
    Filed: July 1, 2004
    Date of Patent: November 20, 2007
    Assignee: Nisshinbo, Industries, Inc.
    Inventors: Kazuhide Yamamoto, Yasuki Hattori
  • Patent number: 6777461
    Abstract: The polymeric composition for friction elements comprises a co-polymer between (I) a resin containing phenolic groups and a reticulation agent, and (II) an organopolysiloxane resin containing terminal silanol groups. A part at least of the phenolic groups is bound to the terminal silanol groups. A process of the preparation of the above polymeric composition may comprise the following steps: a) mixing (I) a resin containing the phenolic groups and the reticulation agent, (II) resin containing the terminal silanol groups, and (III) an epoxy resin or the epoxidisesd organopolysiloxane; b) curing the mixture for a period of time sufficient to complete substantially the reaction between the phenolic groups and the terminal silanol groups, c) post-heating the product obtained under b).
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: August 17, 2004
    Assignee: Nisshinbo Industries, Inc.
    Inventors: Vasilios Kanellopoulos, Isabelle Louis-Joseph-Dogue, Vincent Daniel McGinniss, Duryodhan Mangaraj, Tomoki Tsuchiya Nakamura
  • Patent number: 6596789
    Abstract: A non-asbestos friction material made by molding and curing a composition comprised of a fibrous base, a binder, and a filler has a 100 Hz vibration damping factor (tan &dgr;) at 300° C. minus tan &dgr; at 50° C. value of at least −0.030. The binder may be a rubber-modified high-ortho phenolic resin, a resin mixture of a rubber-modified high-ortho phenolic resin and a rubber-modified phenolic resin, or a resin mixture of two or more rubber-modified phenolic resins. The friction material has an excellent and long-lasting noise performance, and good wear resistance, functional stability, and fade resistance. The rapid curability of the composition enables a short molding cycle.
    Type: Grant
    Filed: August 26, 1999
    Date of Patent: July 22, 2003
    Assignee: Nisshinbo Industries, Inc.
    Inventors: Tomoki Nakamura, Takeo Nagata, Kazuhiro Takeuchi, Mitsuru Kobayashi
  • Patent number: 6479413
    Abstract: A composite friction unit of a three dimensional composite body is formed of a substantially uniform array of predominately glass strands of primary reinforcing fibers in matrix of phenolic resin material, the reinforcing fibers in the form of fabric distributed throughout the body forming a friction unit having a predetermined size and configuration and uniform distribution and alignment of fibers throughout. An alternate friction unit includes a substantially rigid backing co-pultruded in forming the unit. The units are produced in a pultrusion process wherein the reinforcing fibers and matrix are pulled through a forming die.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: November 12, 2002
    Inventor: Benjamin V. Booher
  • Patent number: 6221475
    Abstract: A friction element is made out of a composite material comprising carbon fiber reinforcement and a matrix which, at least in the vicinity of the or each friction face, comprises: a first phase in the vicinity of the reinforcing fibers and containing pyrolytic carbon obtained by chemical vapor infiltration; a refractory second phase of carbon or ceramic obtained at least in part by pyrolysis of a liquid precursor; and a silicon carbide phase obtained by siliciding, for example. At least in the vicinity of the or each friction face, the composite material is preferably constituted, by volume, at least as follows: 15% to 35% carbon fibers; 10% to 55% first matrix phase containing pyrolytic carbon; 2% to 30% second matrix phase of refractory material; and 10% to 35% silicon carbide. The invention is applicable in particular to braking for rail or road vehicles.
    Type: Grant
    Filed: April 13, 1999
    Date of Patent: April 24, 2001
    Assignee: Societe Nationale d'Etude et de Construction de Moteurs d'Aviation - S.N.E.C.M.A.
    Inventors: Jean-Marc Domergue, Jean-Michel Georges, Michel Laxague
  • Patent number: 6107386
    Abstract: A friction material comprising a filler, a binder, and a lubricant, wherein a part or the whole of the filler is constituted by molybdenum trioxide. Not only is the friction material improved in anti-cracking property and anti-fading property under high-temperature and high-load conditions, but the friction material can be prevented from deterioration due to ashing.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: August 22, 2000
    Assignee: Akebono Brake Industry Co., Ltd.
    Inventors: Osamu Nakajima, Takashi Kudo
  • Patent number: 6080230
    Abstract: In a friction material composition containing a fiber base, and a binder, a novolak type phenolic resin having a mean molecular weight of from 3500 to 5000 is used as the binder.
    Type: Grant
    Filed: November 13, 1998
    Date of Patent: June 27, 2000
    Assignee: Akebono Brake Industry Co., Ltd.
    Inventors: Yosuke Sasaki, Michinori Yanagi, Yuzo Todani, Tadahiro Mita
  • Patent number: 5969001
    Abstract: A friction material for a synchronizer ring which exhibits good heat resistance, wear resistance and scorching resistance properties has 30 to 70% by weight of a carbon material, 10 to 40% by weight of a thermosetting resin, 5 to 30% by weight of metal fibers or metal particles and 5 to 40% by weight of inorganic fibers or inorganic particles, and having a porosity of 10 to 50%. The carbon is porous graphite particles of a size distribution in which not less than 50% of the entire number of said graphite particles have a particle diameter from 44 to 250 .mu.m. The thermosetting resin is a novolac type phenol resin, epoxy modified phenol resin, melamine modified phenol resin, cashew modified phenol resin, hydrocarbon resin modified phenol resin or cresol modified phenol resin.
    Type: Grant
    Filed: September 9, 1996
    Date of Patent: October 19, 1999
    Assignee: Dynax Corporation
    Inventor: Satoshi Kawai
  • Patent number: 5919837
    Abstract: Wet processed friction materials are disclosed wherein the components thereof include blends of a) fibrillated, organic, synthetic polymer, b) organic, synthetic polymer staple and c) organic, synthetic soluble polymer particles.
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: July 6, 1999
    Assignee: Sterling Chemicals International, Inc.
    Inventors: Stanley Sigmund Kaminski, Robert Ellsworth Evans
  • Patent number: 5891933
    Abstract: Alkali and alkali earth metal titanates used for friction stabilization of friction materials such as, but not limited to, disk brake pads, brake drum linings, clutch disks, and other friction applications are described. Examples of suitable alkali and alkali earth metal titanates include, without limitation, potassium titanate, sodium titanate, and calcium titanate. Preferably, the alkali or alkali earth metal titanates are present in an amount from about 3 volume percent to about 25 volume percent based on the total volume of the friction material matrix.
    Type: Grant
    Filed: April 9, 1998
    Date of Patent: April 6, 1999
    Assignee: AlliedSignal Inc.
    Inventors: Sunil Kesavan, Gerhard Burmester
  • Patent number: 5889080
    Abstract: A method for making a dry blend for use in the preparation of a friction material, a dry blend per se and dry friction materials is disclosed wherein the components thereof include a) fibrillated, organic, synthetic polymer, b) organic, synthetic polymer staple and c) organic, synthetic soluble polymer particles.
    Type: Grant
    Filed: June 13, 1997
    Date of Patent: March 30, 1999
    Assignee: Sterling Chemicals International, Inc.
    Inventors: Stanley Sigmund Kaminski, Robert Ellsworth Evans
  • Patent number: 5889082
    Abstract: A method for producing wet processed friction materials are disclosed wherein the components thereof include blends of a) fibrillated, organic, synthetic polymer, b) organic, synthetic polymer staple and c) organic, synthetic soluble polymer particles.
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: March 30, 1999
    Assignee: Sterling Chemicals International, Inc.
    Inventors: Stanley Sigmund Kaminski, Robert Ellsworth Evans
  • Patent number: 5622785
    Abstract: A coating for reducing brake pad noise is provided that includes about 40 to about 90% by weight of a phenolic thermosetting resin, about 1 to about 40% by weight of graphite, about 1 to about 40% by weight of molybdenum disulfide, and, 0 to about 40% by weight of fillers and pigments. The coating is applied to a brake pad and cured. A method for reducing brake noise is also provided which includes the steps of coating a brake pad surface with a coating including about 40 to about 90% by weight of a phenolic thermosetting resin, about 1 to about 40% by weight of graphite, about 1 to about 40% by weight of molybdenum disulfide, and 0 to about 40% by weight of fillers and pigments, and curing the coating.
    Type: Grant
    Filed: January 31, 1994
    Date of Patent: April 22, 1997
    Assignee: Performance Friction Corporation
    Inventors: Dennis A. Gaylor, Donald L. Burgoon
  • Patent number: 5532296
    Abstract: Bismaleimide resin systems and fiber reinforced prepregs prepared therefrom having exceptional toughness are prepared by dispersing into a bismaleimide base resin system preformed functionalized elastomer particles having a T.sub.g of less than 10.degree. C.
    Type: Grant
    Filed: September 24, 1993
    Date of Patent: July 2, 1996
    Assignee: Cytec Technology Corp.
    Inventors: Hans G. Recker, Helmut Tesch, Thomas Weber, Volker Altstaedt, Jack D. Boyd
  • Patent number: 5507850
    Abstract: Abrasive articles and methods of making and using same are presented, the abrasive articles having a peripheral surface adapted to contact and abrade a workpiece. The abrasive articles comprise abrasives particles and a grinding aid composition positioned at an effective location in reference to the abrasive particles, the grinding aid composition comprising:a) a cured grinding aid binder comprising a blend of a thermoplastic resin and a thermoset resin, the thermoplastic resin and thermoset resin being present at an effective weight ratio; andb) an effective amount of a grinding aid dispersed in the grinding aid binder.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: April 16, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Harvey J. Helmin
  • Patent number: 5449704
    Abstract: A liquid composition which on exposure to actinic radiation polymerises to form a heat-curable solid film adhesive, said composition comprising (A) a heat-curable phenol-aldehyde resol resin, (B) a photopolymerisable resin having, on average, more than one polymerisable acrylic group per molecule, (C) a photopolymerisation initiator for (B) and (D) an aminotriazine-formaldehyde resin.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: September 12, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Stuart J. Thompson, Stuart Mansfield
  • Patent number: 5434211
    Abstract: Heat-curable adhesive in powder form and solvent-free, containing a mixture of solid phenolic resin with latent hardener in combination with an inorganic pigment mixture.
    Type: Grant
    Filed: January 11, 1994
    Date of Patent: July 18, 1995
    Assignee: Beiersdorf Aktiengesellschaft
    Inventors: Hans K. Engeldinger, Jurgen Kramer, Jurgen Siepmann
  • Patent number: 5420229
    Abstract: A flushing vehicle for lithographic inks is the reaction product of a tall oil rosin-modified maleic ester resin with an acid number of less than about 30, and about 2-16 wt. %, based on the weight of the ester, of a polyamide resin with an amine number less than about 110. The flushing vehicle is prepared by heating a reaction mixture containing the rosin-modified ester and the polyamide resin to a temperature of about 190.degree.-280.degree. C.; and holding at a temperature of 190.degree.-280.degree. C. until the viscosity of the reaction mixture becomes constant.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: May 30, 1995
    Assignee: Resinall Corporation
    Inventors: Roger E. Burke, J. Gilbert Sprull
  • Patent number: 5384344
    Abstract: A friction material containing dust having bismaleimidetriazine as a major ingredient. The dust is effective when contained in amount of 1 to 20 wt. % in the friction material. Compared with conventional friction material containing cashew dust, the generation rate of noise is reduced drastically, while the frictional performance is equivalent or higher.
    Type: Grant
    Filed: September 13, 1993
    Date of Patent: January 24, 1995
    Assignees: Akebono Brake Industry Co., Ltd., Akebond Research and Development Centre Ltd.
    Inventors: Nobuo Kamioka, Hiroshi Tokumura, Toru Yoshino
  • Patent number: 5292780
    Abstract: This invention relates to a composition suitable for use in friction elements and comprises a frictional material and a binder, the latter being a blend of a polyvinyl alkyl ether with a phenolic resin and optionally a rubber.Compared with conventional friction elements based on organic polymers, the elements produced using the compositions of the present invention shows increases in flexural strength of up to 50% with no loss in wear or friction performance.
    Type: Grant
    Filed: July 11, 1990
    Date of Patent: March 8, 1994
    Assignee: BP Chemicals Limited
    Inventors: Christopher G. Godfrey, Bryan H. McCormick
  • Patent number: 5268398
    Abstract: A friction material is so manufactured that a hygienic environment can be maintained while simultaneously reducing the brake noise without reducing the friction coefficient of the brake pads made of the present material. The friction material is granulated or agglomerated by a first binder which binds one or more inorganic substances having a plane netlike crystal structure into granules which are deformed so that the particles have a flat particle orientation in the resulting granules. The flat particle orientation is achieved by the application pressure and/or heat during the formation. The granules are then embedded in a second binder forming a fibrous matrix for forming the brake pad material. The inorganic substance or substances forming the particles having the plane netlike crystal structure, promote a microseparation in the friction surface in response to the application of a brake force. The microseparation effectively prevents brake noise.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: December 7, 1993
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Mitsuhiko Nakagawa, Yukinori Yamashita, Masanori Ibuki, Hiroya Kishimoto
  • Patent number: 5182166
    Abstract: A wear-resistant composite structure which is especially suitable for use in the formation of sealing components, brake linings, electrical motor brushes, bearings, and like products, is disclosed. This composite structure includes as its primary component vitreous carbon in a continuous phase, and strengthening fibers interspersed throughout the vitreous carbon in a discontinuous phase. These fibers are individually convoluted in configuration, so as to improve the crack-resistance and other physical properties of the vitreous carbon. A suitable method of forming such wear-resistant composite structure is also disclosed.
    Type: Grant
    Filed: May 1, 1991
    Date of Patent: January 26, 1993
    Inventors: Ralph A. Burton, Ralph G. Burton
  • Patent number: 5132065
    Abstract: A railroad brake shoe friction composition is prepared in the absence of a volatile solvent by first preparing a fluid paste bonding matrix containing an uncured rubber compound, a blend of highly polymerized cashew nut shell liquid resin with a reactive diluent and high surface area inorganic fillers, and thereafter adding other fillers and reinforcing fibers.
    Type: Grant
    Filed: April 24, 1991
    Date of Patent: July 21, 1992
    Assignee: Amsted Industries, Inc.
    Inventor: C. Dale Christie
  • Patent number: 5122550
    Abstract: A non-asbestos friction material composition suitable for use as a friction element includes: a binder; a reinforcing material; and a structural integriy imparting amount of cellulose ester fibrils.
    Type: Grant
    Filed: November 21, 1990
    Date of Patent: June 16, 1992
    Assignee: Hoechst Celanese Corporation
    Inventor: Thomas E. Schmitt
  • Patent number: 5080969
    Abstract: The invention relates to a composite friction material for brakes comprising a main friction material containing thermosetting resin as a binder, and a layer of high friction material with a higher friction coefficient than said main friction material for exhibiting a high braking power on initial application, which high friction layer is provided on the surface of said main friction material and contains a phenol resin of not more than 5 wt. %.
    Type: Grant
    Filed: September 18, 1990
    Date of Patent: January 14, 1992
    Assignees: Akebono Brake Industry Co., Ltd., Akebono Research and Development Centre Ltd.
    Inventor: Hiroshi Tokumura
  • Patent number: 4918116
    Abstract: Improved high temperature resistant molding materials containing customary filler materials and additives and a carbon forming bonding agent which is a phenol novolac with a molar ratio of phenol to formaldehyde of 1 to 0.2 to 1 to 0.35 of high quality and free of solvents useful as refractory products, carbon materials, abrasive wheels, friction lining and the like.
    Type: Grant
    Filed: February 17, 1989
    Date of Patent: April 17, 1990
    Assignee: Rutgerswerke AG
    Inventors: Arno Gardziella, Karl-Heinz Schwieger, Peter Adolphs, Josef Suren
  • Patent number: 4886706
    Abstract: An improved fibrous polyacrylonitrile mixture for use in friction products enables the production of low resiliency preforms by mixing an additive with a polyacrylonitrile wet gel. The additive is incorporated into the fiber in extremely large amounts. The additive is a member selected from the group consisting of:(a) polyethylene glycol esters of pelargonic acid; or(b) polyethylene glycol esters of enanthic, caprylic or capric acids; or(c) blends of polyethylene glycol esters of enanthic, caprylic, pelargonic, or capric acids; or(d) blends of polyethylene glycol esters of carboxylic acids derived from natural products containing at least 50% by weight of carboxylic acids containing less than 14 carbon atoms; or(e) reaction products of ethylene oxide and carboxylic acid amides wherein at least 70% of the acids from which the amide is derived contain between 16 and 20 carbon atoms.
    Type: Grant
    Filed: March 11, 1987
    Date of Patent: December 12, 1989
    Assignee: BASF Corporation
    Inventors: Hughey A. Rush, Billy B. Hibbard, Johnson L. Pursoo, John W. Lindsay, Thomas E. Smith, Kenneth Harper, MIchael V. Tullos, James E. Davis
  • Patent number: 4866107
    Abstract: The addition of fibrillated acrylic fiber to non-asbestos type friction material compositions provides marked improvement in the flexural strength, stiffness and structural integrity of preforms used in the manufacture of friction elements. The consequent handling characteristics of the preform provide improvement in the manufacturing of the friction element.
    Type: Grant
    Filed: July 26, 1988
    Date of Patent: September 12, 1989
    Assignee: American Cyanamid Company
    Inventors: Leigh T. Doxsee, Robert E. Evans, Michael P. O'Toole
  • Patent number: 4861809
    Abstract: A friction material containing from about 0.5-29 wt % of carbonaceous fibers with a bond nitrogen content of from about 14 to 21 wt %, an auxiliary material and a thermosetting resin. The material has good wear and temperature resistance characteristics and can be used in power transmissions and brakes.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: August 29, 1989
    Assignee: Toho Rayon Co., Ltd.
    Inventors: Hiroyasu Ogawa, Kenji Shimazaki, Kenji Niijima
  • Patent number: 4855336
    Abstract: In a friction material wherein sponge iron is a principle friction producing component especially on initial engagement during a brake application, the improvement wherein 10-50% of the sponge iron is replaced with mill scale without a substantial change in the operational characteristics of the friction material.
    Type: Grant
    Filed: July 25, 1988
    Date of Patent: August 8, 1989
    Assignee: Allied-Signal Inc.
    Inventor: Charles E. Newell
  • Patent number: 4775705
    Abstract: Non-asbestos brake pads made of reinforcing, temperature resistant, web-forming fibers such as aromatic polyamide pulp, optionally including other fibers and friction and wear modifiers is described. The brake pads have an actual density not greater than 88% and not less than a 60% theoretical density. The pads are made by the slurry process in which the pad-forming constituents are fed as a slurry into a mold, dewattered and compressed, dried to a preform then heated and pressed to consolidate the preform to substantially the finished density without completely curing the binder. The consolidated pad is then baked to fully cure the binder.
    Type: Grant
    Filed: December 19, 1986
    Date of Patent: October 4, 1988
    Assignee: T&N plc
    Inventors: Euan Parker, Bruno Grele
  • Patent number: 4748193
    Abstract: A composition of matter for use as a friction material having soft malleable metallic (zinc) powder therein to attenuate low frequency vibrations that produce undesirable noise during a brake application.
    Type: Grant
    Filed: September 29, 1986
    Date of Patent: May 31, 1988
    Assignee: Allied Corporation
    Inventor: William D. Hays, Jr.
  • Patent number: 4743635
    Abstract: A friction brake material contains fibers, graphite and a binder. All or part of the graphite is physically combined with one or more metals or alloys which are softer than steel to form a first combination or mixture. A separate combination or mixture is formed to include friction increasing fibers in a binder. Both mixtures are then combined to form the friction brake material which has an ability to cause substantially less creaking noise upon brake application as compared to differently prepared friction brake material.
    Type: Grant
    Filed: February 2, 1987
    Date of Patent: May 10, 1988
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Mitsuhiko Nakagawa, Fumiaki Nitto
  • Patent number: 4735975
    Abstract: A friction material comprising 40 to 95% by volume of a granular material and a thermoset binder resin for binding said granular material, said granular material having been produced by binding at least one powder material with a binder resin so that at least 50% by weight of the granules has a particle size between 140 mesh on and 7 mesh pass, which has good fade resistance and wear resistance.
    Type: Grant
    Filed: July 9, 1986
    Date of Patent: April 5, 1988
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Kouichi Iwata, Hiroshi Asano
  • Patent number: 4678818
    Abstract: A friction brake material contains fibers, graphite and a binder. All or part of the graphite is physically combined with one or more metals or alloys which are softer than steel to form a first combination or mixture. A separate combination or mixture is formed to include friction increasing fibers in a binder. Both mixtures are then combined to form the friction brake material which has an ability to cause substantially less creaking noise upon brake application as compared to differently prepared friction brake material.
    Type: Grant
    Filed: November 19, 1985
    Date of Patent: July 7, 1987
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Mitsuhiko Nakagawa, Fumiaki Nitto
  • Patent number: 4672082
    Abstract: A friction material particularly useful for vehicle brakes comprises a friction material body including a plurality of steel fibers. Each steel fiber includes at least 0.07% by weight of sulphur, at least 0.10% by weight of phosphorus, or at least 0.15% by weight of both sulphur and phosphorus. The friction material exhibits high friction coefficients and less abrasion with respect to materials against which it bears as compared to conventional wear materials utilizing steel fibers.
    Type: Grant
    Filed: November 7, 1985
    Date of Patent: June 9, 1987
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Mitsuhiko Nakagawa, Fumiaki Nitto