Printing Ink Composition For Glass Or Ceramic Substrate Or Process Of Preparing Patents (Class 523/160)
  • Patent number: 8048939
    Abstract: The present invention relates to a water-based ink for ink-jet printing which is excellent in rubbing resistance upon printing on coated papers such as photographic papers, and also exhibits a high optical density upon printing on plain papers. The water-based ink for ink-jet printing according to the present invention includes a dispersion of a pigment wherein the number of pigment-containing polymer particles in the pigment dispersion which have a particle size of 0.57 ?m or more among the pigment-containing polymer particles contained in the pigment dispersion in the ink is 1.2×107/mL or less.
    Type: Grant
    Filed: August 10, 2006
    Date of Patent: November 1, 2011
    Assignee: Kao Corporation
    Inventor: Kazunari Takemura
  • Patent number: 8044115
    Abstract: An inkjet ink composition comprising water, pigment particles dispersed with a polymeric dispersant, at least one water-dispersible polyurethane, at least one pyrrolidinone compound, glycerol, and a 1,2-alkanediol having from four to eight carbon atoms.
    Type: Grant
    Filed: September 22, 2008
    Date of Patent: October 25, 2011
    Assignee: Eastman Kodak Company
    Inventors: Thomas B. Brust, Paul D. Yacobucci, Yongcai Wang, Catherine A. Falkner, Thanhchau T. Nguyen
  • Patent number: 8044114
    Abstract: There is provided an ink for recording, which contains: a coloring agent; a water-dispersible resin; a wetting agent; a surfactant; and water, wherein a total solid content of the coloring agent and the water-dispersible resin is 10% by mass to 30% with respect to a total mass of the ink, a ratio B/C is 0.1 to 1.6 where B is a solid content of the coloring agent in the ink, and C is a solid content of the water-dispersible resin in the ink, a viscosity of the ink is 5 mPa·s to 20 mPa·s at 25° C., and a surface tension of the ink is 35 mN/m or less.
    Type: Grant
    Filed: August 22, 2006
    Date of Patent: October 25, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Hisashi Habashi, Michihiko Namba, Mariko Kojima, Akihiko Gotoh, Tamotsu Aruga, Kiyofumi Nagai
  • Patent number: 8039542
    Abstract: Disclosed is a pigment dispersion containing a polymer compound having a partial structure represented by the following formula (1) at a terminal end of a main chain of the polymer compound, and a pigment. In formula (1), R1 and R2 each independently represent a hydrogen atom or a monovalent substituent; R1 and R2 may form a ring by bonding with each other; and * represents a position that is directly or indirectly bonded to the main chain structure of the compound.
    Type: Grant
    Filed: July 31, 2009
    Date of Patent: October 18, 2011
    Assignee: FUJIFILM Corporation
    Inventor: Koji Yasuda
  • Patent number: 8038254
    Abstract: The invention provides an ink set having at least an ink composition and a maintenance liquid. The ink composition comprises a pigment (i). The maintenance liquid comprises one or more solvents (ii) having a solubility parameter value of 27.5 or less. The content of the one or more solvents (ii) is 50 weight % or more with respect to a total solvent content of the maintenance liquid. The invention further provides a method of forming an image using the ink set including at least applying, with a liquid applying device, the ink composition to a recording medium, and applying a maintenance liquid to the liquid applying device.
    Type: Grant
    Filed: July 31, 2009
    Date of Patent: October 18, 2011
    Assignee: FUJIFILM Corporation
    Inventors: Yoshimitsu Arai, Mika Imamura, Hiroshi Inoue
  • Patent number: 8030373
    Abstract: Provided is a pigment distribution system. The pigment distribution system includes a pigment encapsulated by physically adsorbing a diblock copolymer to the pigment. The diblock copolymer is represented by Formula 1 below: where -A- denotes a hydrophilic monomer, -B- denotes a hydrophobic monomer, m denotes an integer ranging from 1 to 10, and n denotes an integer ranging from 3 to 30, wherein hydrophilic monomers of neighboring diblock copolymer chains are crosslinked using a crosslinker.
    Type: Grant
    Filed: April 1, 2008
    Date of Patent: October 4, 2011
    Assignee: Samsung Electronics Co., Ltd
    Inventors: Tae-woon Cha, Sung-woong Kim
  • Patent number: 8026306
    Abstract: Described are compositions and methods effective to improve the security obtainable for red phosphorescent inks printed, such as by ink jet printing. Specially designed polymeric chelating agents are water soluble and have a high chelating efficiency for lanthanide cations and are themselves strongly adsorbed on polymeric substrates, especially paper. The polymeric chelating agents comprise a polymer chain of either general formulae (1) or (2) containing pyridine-N-oxide, quinoline-N-oxide or isoquinoline-N oxide pendent ligand groups A, where m and n are independent integers in the range of from 1 to 10, and the number average molecular weight of the polymers lies in the range from 1×103 to 5×105: In one aspect a polymeric chelate as described is produced in situ in an aqueous ink formulation and is subsequently printed onto a substrate and dried.
    Type: Grant
    Filed: December 31, 2007
    Date of Patent: September 27, 2011
    Assignee: Pitney Bowes Inc.
    Inventors: Judith D. Auslander, John Griffiths, Penelope C. Myers
  • Patent number: 8022117
    Abstract: A non-aqueous pigment dispersion includes a color pigment, a polymeric dispersant, and a dispersion synergist wherein the molecular weight of the anionic part of the dispersion synergist containing at least one carboxylate anion is smaller than 98% of the molecular weight of the color pigment and that the anionic part of the dispersion synergist has a similarity coefficient SIM of at least 0.5 with the similarity coefficient defined by: SIM = t · C S + P - C wherein, S represents the number of atoms in the anionic part of the dispersion synergist; P represents the number of atoms in the color pigment; C represents the largest number of atoms in common between the anionic part of the dispersion synergist and the color pigment as one continuous structure; and t is an integer representing the number of times that the largest number of atoms in common C fits into the organic color pigment, without using atoms of the color pigment twice.
    Type: Grant
    Filed: November 28, 2006
    Date of Patent: September 20, 2011
    Assignee: Agfa Graphics NV
    Inventors: Geert Deroover, Nicolas Point
  • Patent number: 8022111
    Abstract: Compounds of formula (I) [in which: A and B are terminal groups; R1 represents a group of formula (II) or (III); R2 is alkyl or aryl; Z is a group —(CHR3)n, where R3 is hydrogen, hydroxy or alkyl, and n is a number from 0 to 6; Y is carbonyl or a group —CH2—; Q represents a residue of a dihydroxy compound; and x is a number from 1 to 100] are useful sensitisers for use with Type II photoinitiators in the formulation of printing inks and other energy curable coatings.
    Type: Grant
    Filed: January 28, 2005
    Date of Patent: September 20, 2011
    Assignee: Sun Chemical Corporation
    Inventors: Shaun Lawrence Herlihy, Brian Rowatt
  • Patent number: 8017669
    Abstract: A color filter ink is adapted to be used to manufacture a color filter by an inkjet method. The color filter ink includes a colorant, a liquid medium that dissolves and/or disperses the colorant, and a resin material. The resin material includes a polymer X and a polymer Y. The polymer X has a monomer component x1 represented by a prescribed chemical formula, a monomer component x2 represented by a prescribed chemical formula, a monomer component x3 represented by a prescribed chemical formula, and a monomer component x4 represented by a prescribed chemical formula. The polymer Y has a monomer component y1 represented by a prescribed chemical formula and a monomer component y2 represented by a prescribed chemical formula.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: September 13, 2011
    Assignee: Seiko Epson Corporation
    Inventors: Masaya Shibatani, Hidekazu Moriyama, Hiroshi Takiguchi, Mitsuhiro Isobe, Homare Kuribayashi
  • Patent number: 8013035
    Abstract: A recording liquid is provided. The recording liquid includes particles A including a water-insoluble colorant and a compound containing a hydrophilic group, the particles A having a dispersion average particle diameter from 5 to 50 nm; and a self-dispersible polymer particles B including a constituent unit derived from an aromatic group-containing acrylate monomer.
    Type: Grant
    Filed: March 13, 2009
    Date of Patent: September 6, 2011
    Assignee: Fujifilm Corporation
    Inventors: Ryo Saito, Terukazu Yanagi
  • Patent number: 8013033
    Abstract: An emulsion stabilizer is disclosed having a water tolerance value of between more than about 1.0 and equal or less than about 11.0.
    Type: Grant
    Filed: October 15, 2007
    Date of Patent: September 6, 2011
    Assignee: Sun Chemical Corporation
    Inventors: Nobuo Harui, Hideo Ishii
  • Patent number: 8013034
    Abstract: A printing ink is disclosed containing: an emulsion stabilizer having a water tolerance value of between more than about 1.0 and equal or less than about 11.0 and water as a dispersed phase, wherein said emulsion stabilizer stabilizes the water to form a stabilized emulsion printing ink.
    Type: Grant
    Filed: October 15, 2007
    Date of Patent: September 6, 2011
    Assignee: Sun Chemical Corporation
    Inventors: Nobuo Harui, Hideo Ishii
  • Patent number: 8013053
    Abstract: The present invention relates to a water-based ink for ink-jet printing which exhibits a high optical density even upon one-pass printing on plain papers and is suitable for high-speed printing, and a dispersion used in the water-base ink. There are provided a water dispersion for ink-jet printing, including water-insoluble polymer particles containing a colorant, and a nonionic organic compound satisfying the following conditions I and II: I: Water containing 0.001% by weight of the nonionic organic compound has a surface tension of 70 mN/m or less as measured at 25° C.; and II: A solubility of the nonionic organic compound in 100 g of water is 0.30 g or less as measured at 25° C., a water-based ink containing the water dispersion, and a method of conducting a one-pass printing using the water-based ink.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: September 6, 2011
    Assignee: Kao Corporation
    Inventors: Hiroyuki Yoshida, Isao Tsuru, Ryuma Mizushima
  • Patent number: 8007578
    Abstract: An ink having infrared (IR) absorptivity includes an ink vehicle and an IR absorptive pigment having low visible color. According to one exemplary embodiment, the IR absorptive pigment includes an antimony-containing tin oxide.
    Type: Grant
    Filed: October 7, 2005
    Date of Patent: August 30, 2011
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Jayprakash C. Bhatt
  • Patent number: 8008368
    Abstract: An oil-based ink composition for inkjet recording capable of exhibiting desired properties of drying after print, rubfastness and re-solubility is achieved by performing solubilization on an acrylic resin which is not easily dissolved conventionally. The oil-based ink composition for inkjet printing comprises glycol ether dialkyl ethers as a prime solvent; and an acrylic resin that results from solution polymerization in a solvent of the glycol ether dialkyl ethers by use of a radical polymerization initiator.
    Type: Grant
    Filed: December 21, 2006
    Date of Patent: August 30, 2011
    Assignees: Seiko Epson Corporation, The Inctec Inc.
    Inventors: Seiji Mochizuki, Makoto Otsuki, Masahiro Nakamura, Yukio Sugita, Mitsuyoshi Tamura, Fumie Yamazaki, Tamayo Okahira
  • Patent number: 8008369
    Abstract: An ink set includes an ink composition including an encapsulated black pigment in which a black pigment is coated with a polymer resin.
    Type: Grant
    Filed: October 29, 2008
    Date of Patent: August 30, 2011
    Assignee: SAMSUNG Electronics Co., Ltd.
    Inventors: Jae-yoon Jung, Seung-min Ryu
  • Patent number: 8003714
    Abstract: An ink comprising a pigment, a dispersant, a penetrating agent, water, a compound having two hydroxyl groups in the molecule, a compound having three hydroxyl groups in the molecule, and a compound having four or more hydroxyl groups in the molecule, the content of the pigment being in the range of from about 7% by weight to about 20% by weight; the content of the compound having two hydroxyl groups in the molecule being in the range of from about 1% by weight to about 10% by weight; the content of the compound having three hydroxyl groups in the molecule being in the range of from about 2% by weight to about 20% by weight; and the content of the compound having four or more hydroxyl groups in the molecule being in the range of from about 25% by weight to about 50% by weight.
    Type: Grant
    Filed: November 12, 2007
    Date of Patent: August 23, 2011
    Assignee: Fuji Xerox Co., Ltd.
    Inventor: Yoshiro Yamashita
  • Patent number: 8002399
    Abstract: A solid phase change ink composition that includes at least one colorant and an ink vehicle. The ink vehicle further includes at least one polyhydroxyalkanoate compound of the below formula wherein R is independently selected from the group consisting of a hydrogen atom, a hydrocarbon group, a heteroatom, and combinations thereof, and wherein n represents the number of repeating units of from 1 to about 35,000, and wherein x represents an integer from 1 to about 5.
    Type: Grant
    Filed: December 2, 2009
    Date of Patent: August 23, 2011
    Assignee: Xerox Corporation
    Inventors: Caroline M. Turek, Gwynne Evelyn McAneney Lannen, C. Geoffrey Allen, Everett Alan Ness
  • Patent number: 7994232
    Abstract: The invention provides a photo-curable composition that addresses degradation in dispersibility caused by the use of a pigment, and has good color tone and high light fastness. The photo-curable composition includes: a polymerizable compound; a polymerization initiator; and a dye represented by Formula (1): in which, A1, A2 and A3 each represent a monovalent group, and Z represents a nitrogen atom, an oxygen atom, a sulfur atom, or a monovalent group-bonded carbon atom, the dye represented by Formula (1) having two azo groups in a molecule thereof.
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: August 9, 2011
    Assignee: FUJIFILM Corporation
    Inventors: Hideo Hanawa, Yoshiharu Yabuki
  • Patent number: 7985785
    Abstract: An ink composition of the present invention is disclosed, which contains (i) a sensitizing dye represented by the following Formula (I); (ii) at least one polymerization initiator selected from the group consisting of ?-aminoketones and acyl phosphine oxides; and (iii) an ethylenically unsaturated bond-containing polymerizable compound. In Formula (I), X represents O, S or NR; n represents an integer of 0 or 1; R represents a hydrogen atom, an alkyl group or an acyl group; R1 to R8 each independently represent a hydrogen atom or a monovalent substituent; R1 and R2, R2 and R3, and R3 and R4 may be connected to each other to form a ring; and R5 or R6 may be connected to R7 or R8 to form an aliphatic ring but not to form an aromatic ring.
    Type: Grant
    Filed: January 14, 2008
    Date of Patent: July 26, 2011
    Assignee: FUJIFILM Corporation
    Inventors: Tokihiko Matsumura, Ippei Nakamura
  • Patent number: 7985784
    Abstract: An ink set includes: at least one black ink composition that contains at least a self-dispersing pigment and a resin emulsion; and at least one color ink composition that contains at least an organic pigment covered with water-insoluble polymer and a resin emulsion.
    Type: Grant
    Filed: August 11, 2006
    Date of Patent: July 26, 2011
    Assignee: Seiko Epson Corporation
    Inventors: Miharu Kanaya, Tetsuya Aoyama, Masahiro Hanmura
  • Patent number: 7985782
    Abstract: The present invention provides an ink for a color filter comprising a polymer binder, a crosslinking monomer, a solvent, a pigment, and a polymerization initiator. The polymer binder comprises acrylate or methacrylate including a hydroxy group. The polymer binder may comprise 2-hydroxyethyl acrylate or 2-hydroxyethyl methacrylate.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: July 26, 2011
    Assignees: Samsung Electronics Co., Ltd., Dongjin Semichem Co., Ltd.
    Inventors: Kwang Ho Lee, Byoung Joo Kim, Jang Sub Kim, Chang Hun Kwak, Seong Gyu Kwon, Chan Seok Park, Kyung Ah Kim, Hyun Il Cho, Gil Lae Kim, Yoon Ho Kang
  • Patent number: 7984983
    Abstract: The invention provides an inkjet recording method having applying, by an inkjet system, an ink containing 8 mass % or more of a water-soluble solvent having an SP value of 24 (MPa)1/2 or less measured by a Hoy method onto an outermost surface layer, which contains an organic fine particle having an SP value of 25 (MPa)1/2 or less measured by the Hoy method, of an inkjet recording medium having a support and one or more ink receiving layers including the outermost surface layer.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: July 26, 2011
    Assignee: FUJIFILM Corporation
    Inventors: Hiroshi Kawakami, Masamichi Kobayashi
  • Patent number: 7981950
    Abstract: A process for preparing a modified particulate solid comprising reacting a dispersant with a compound in the presence of a particulate solid and a liquid medium, characterised in that: a) the dispersant has at least one reactable group selected from keto, aldehyde and beta-diketoester groups, b) the compound has at least two groups reactive towards said keto, aldehyde and/or beta-diketoester groups. The process provides a modified particulate solid having improved stability which is particularly useful for liquid vehicles having and range of polarities and for incorporation into ink jet printing inks.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: July 19, 2011
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: John Patrick O'Donnell, Stephen George Yeates, Tom Annable
  • Patent number: 7981947
    Abstract: An aqueous ink composition comprising: a pigment, having a particle diameter as determined by the light scattering method of no less than 20 nm and no more than 200 nm; and a water dispersible polymer, having a styrene-equivalent number average molecular weight of as determined by gel permeation chromatography no less than 5000 and no more than 200000, having a surface tension of no less than 20 mN/m and no more than 40 mN/m, and wherein the abovementioned pigment is a polymer-coated pigment that is coated with the abovementioned water dispersible polymer, is provided. The water-dispersible polymer may be a copolymer of monomers, mainly comprising acrylic acid and/or methacrylic acid and an acrylate and/or methacrylate. With this ink composition, the printing quality can be improved.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: July 19, 2011
    Assignee: Seiko Epson Corporation
    Inventor: Masahiro Yatake
  • Patent number: 7977408
    Abstract: It is an object of the present invention to provide a recording ink which contains at least a pigment, a dispersant, a water-soluble solvent, a wetting agent and water, wherein the pigment contains at least one of diketopyrrolopyrrole red pigment and phthalocyanine green pigment in order to obtain a recording ink and ink set which excel in discharge stability with no head clogging during printing and can obtain high quality images with good color tone on the regular paper as well as on an exclusive recording paper; and ink cartridge, ink record, inkjet recording apparatus and inkjet recording method which utilize the recording ink and ink set respectively.
    Type: Grant
    Filed: February 2, 2006
    Date of Patent: July 12, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Akihiko Matsuyama, Masanori Hirano, Hiroshi Adachi
  • Patent number: 7977402
    Abstract: Radiation curable ink compositions for impulse printheads are described. The compositions include a photoinitiator system, containing both a photocation polymerization initiator and a free-radical photoinitiator, an acrylate ester of a carboxylic acid ester, and at least one radiation curable material.
    Type: Grant
    Filed: October 10, 2007
    Date of Patent: July 12, 2011
    Assignee: Collins Ink Corporation
    Inventors: Sudhakar Madhusoodhanan, Devdatt S. Nagvekar
  • Patent number: 7977409
    Abstract: Provided is an ink jet ink capable of achieving both high colorability and excellent bleeding resistance of an image. The ink jet ink includes at least a pigment and a star polymer in which at least three copolymer chains of ?,?-ethylenically unsaturated monomers are bonded to a central skeleton, in which the copolymer chains of the ?,?-ethylenically unsaturated monomers are copolymers of at least one first monomer selected from the group consisting of aromatic (meth)acrylates and aromatic (meth)acrylamides and at least one second monomer selected from the group consisting of acid monomers and salts of the acid monomers.
    Type: Grant
    Filed: October 2, 2009
    Date of Patent: July 12, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kenji Nishiguchi, Katsuhiro Hayashi
  • Patent number: 7973098
    Abstract: Described are new custom postage printing stocks, coating compositions, processes for preparing and utilizing these and resulting postage products. Disclosed ink formulations comprise: invisible fluorescent dye and/or pigment (preferably red-fluorescent dye), which is fluorescent in the range of 580 to 640 nm when illuminated with light at 254 nm; water-soluble binder; substrate penetrant, fluorescence stabilizer; substrate anticurl agent and water. The inks, when coated on substrates and dried, can improve the quality and color of images printed as compared to images printed without the aid of the invention.
    Type: Grant
    Filed: September 18, 2007
    Date of Patent: July 5, 2011
    Assignee: Pitney Bowes Inc.
    Inventor: Jay Reichelsheimer
  • Patent number: 7973097
    Abstract: An ink jet pigment ink containing water, a pigment, a water-soluble organic solvent and a graft copolymer, wherein the graft copolymer has a hydrophilic segment and a hydrophobic segment, the hydrophobic segment is being obtained by copolymerizing an anionic monomer and an aromatic monomer represented by the following formula (1), and the hydrophilic segment is being obtained by polymerizing an anionic monomer wherein Ar is an aromatic ring selected from a benzene ring, a condensed benzene ring and a hetero-aromatic ring, or a derivative thereof, R is H or CH3, and X is O or NH.
    Type: Grant
    Filed: April 21, 2008
    Date of Patent: July 5, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kenji Nishiguchi, Yuko Nishiwaki
  • Patent number: 7968622
    Abstract: An ink-jet composition for a color filter excellent in storage stability, straightness and sustainability at the time of ejection from a head, wherein a cured layer thereof is excellent in heat resistance, adhesive property, and solvent resistance. The ink-jet ink composition for a color filter is a specific epoxy group-containing polymer (A), a specific epoxy group-containing compound (B) having two or more specific epoxy groups and a polycarboxlic acid derivative (C) in which specific carboxylic acid (c1) having alicyclic hydrocarbon is rendered latent by vinyl ether (c2), wherein the equivalence ratio of carboxyl groups rendered latent by the polycarbonoxylic acid derivative (C) to the total epoxy groups contained in the epoxy-group containing polymer (A) and the epoxy-group containing compound (B) is in the range from 0.7 to 1.1.
    Type: Grant
    Filed: March 20, 2006
    Date of Patent: June 28, 2011
    Assignees: Dai Nippon Printing Co., Ltd., NOF Corporation
    Inventors: Tomonori Nishida, Masashi Nishiyama, Masato Tezuka, Atsushi Sato, Yukihiro Kato
  • Patent number: 7968621
    Abstract: Pigment dispersed liquid contains, at least: a colorant; a dispersant; and a polymerizable compound, the pigment dispersed liquid contain a substantial amount of a polymerization inhibitor.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: June 28, 2011
    Assignee: Seiko Epson Corporation
    Inventors: Takashi Oyanagi, Keitaro Nakano, Chiyoshige Nakazawa
  • Patent number: 7964032
    Abstract: The present invention relates to coating and printing ink compositions possessing silicone surfactants compositions comprising fluorine-free organomodified trisiloxanes which are resistant to hydrolysis between a pH of about 3 to a pH of about 12. The coatings and printing ink composition of the present invention exhibit enhanced wetting, flow and leveling properties.
    Type: Grant
    Filed: October 17, 2006
    Date of Patent: June 21, 2011
    Assignee: Momentive Performance Materials Inc.
    Inventors: Suresh K. Rajaraman, Alain Lejeune, Alexander Borovik, George A. Policello, Mark D. Leatherman, Wenqing Peng, Zijun Xia
  • Patent number: 7964655
    Abstract: Disclosed is a liquid composition that, while maintaining good color developing properties and gloss, can realize good cleaning operation without staying of the liquid composition in a cleaning cap. The liquid composition is adapted for use with an ink composition for deposition on a recording medium and comprises a modified polyallylamine, a water soluble organic solvent, and water and is free from any colorant. The liquid composition and an ink composition each are deposited onto a recording medium to perform recording. A polymer comprising a recurring unit represented by formula (I) is used as the modified polyallylamine.
    Type: Grant
    Filed: February 17, 2004
    Date of Patent: June 21, 2011
    Assignee: Seiko Epson Corporation
    Inventors: Shuichi Kataoka, Kiyohiko Takemoto, Mitsumasa Hashimoto, Minoru Takeuchi
  • Patent number: 7964660
    Abstract: The present invention relates to a process for producing a water-based pigment dispersion which includes a first step of mixing (A) an emulsion composition including a water-insoluble polymer having a specific weight-average molecular weight and containing a salt-forming group, an organic solvent having a specific solubility in water, a neutralizing agent and water, with (B) a pigment to obtain a preliminary dispersion having a content of non-volatile components of from 5 to 50% by weight and a weight ratio of the organic solvent to water [organic solvent/water] of from 0.1 to 0.
    Type: Grant
    Filed: September 5, 2006
    Date of Patent: June 21, 2011
    Assignee: Kao Corporation
    Inventors: Toshiyuki Matsumoto, Tsuyoshi Oda, Koji Kamei, Toshiya Iwasaki
  • Patent number: 7963646
    Abstract: Compositions for use in ink jet printing onto a substrate comprising a water based dispersion including metallic nanoparticles and appropriate stabilizers. Also disclosed are methods for the production of said compositions and methods for their use in ink jet printing onto suitable substrates.
    Type: Grant
    Filed: October 28, 2002
    Date of Patent: June 21, 2011
    Assignee: Yissum Research Development Company of the Hebrew University of Jerusalem Israell Company
    Inventors: Shiomo Magdassi, Alexander Kamyshny, Yelena Vinetsky, Amal Bassa, Raim Mokh Abo
  • Patent number: 7956097
    Abstract: Various embodiments related to curable printing fluids are disclosed. One example embodiment provides a curable printing fluid composition for a thermal fluid ejection device, the composition comprising a curable liquid-phase monomer, a substantially nonaqueous volatile driver fluid capable of being vaporized by a thermal fluid ejection printhead, an initiator, a phosphate ester resistor protectant, and a colorant comprising a dye.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: June 7, 2011
    Assignee: ImTech, Inc.
    Inventors: Kenneth E. Trueba, William Allen Buskirk
  • Patent number: 7956103
    Abstract: To provide an ink composition capable of forming a metallic material which is excellent in adhesion to a substrate and free from ion migration. An ink composition having fine metallic copper particles and/or fine copper hydride particles, and fine silver oxide particles or fine metallic silver particles, dispersed in a water-insoluble organic liquid, which composition has a solid content concentration of from 10 to 80 mass % and contains from 5 to 90 parts by mass of the fine metallic copper particles and/or fine copper hydride particles, and from 10 to 95 parts by mass of the fine silver oxide particles or fine metallic silver particles, per 100 parts by mass of the total solid content in the ink composition.
    Type: Grant
    Filed: October 12, 2007
    Date of Patent: June 7, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Hideyuki Hirakoso, Keisuke Abe, Yasuhiro Sanada
  • Patent number: 7956102
    Abstract: The invention provides an ink which comprises: a metal oxide precursor, a stress reliever, and a solvent.
    Type: Grant
    Filed: April 9, 2007
    Date of Patent: June 7, 2011
    Assignee: The Board of Trustees of the University of Illinois
    Inventors: Jennifer A. Lewis, Eric B. Duoss, Mariusz Twardowski
  • Patent number: 7956096
    Abstract: The invention relates to thermally expandable thermoplastic microspheres comprising a polymer shell made from ethylenically unsaturated monomers encapsulating a propellant, said ethylenically unsaturated monomers comprising from 40 to 70 wt % of acrylonitrile, from 5 to 40 wt % of methacrylonitrile, from 10 to 50 wt % of monomers selected from the group consisting of esters of acrylic acid, esters of methacrylic acid and mixtures thereof, and said propellant comprising at least one of methane, ethane, propane, isobutane, n-butane and neo-pentane. The invention further relates to the production and use of the microspheres.
    Type: Grant
    Filed: February 9, 2007
    Date of Patent: June 7, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Ove Nordin, Heléne Ström, Christina Nyholm, Claes Hammer
  • Patent number: 7951854
    Abstract: An ink composition includes: first particles which are insoluble and dispersed in an aqueous dispersion medium, a polarity of the first particles being one of positive and negative; and second particles which are insoluble and dispersed in the aqueous dispersion medium, the second particles including both a cationic group and an anionic group, the second particles having a zeta potential that changes along with a change in pH of the aqueous dispersion medium, percentage of a water-soluble component in the second particles being not higher than 5% by mass.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: May 31, 2011
    Assignee: FUJIFILM Corporation
    Inventors: Terukazu Yanagi, Akio Tamura, Takahiro Ishizuka, Takashi Hirakawa, Katsuyuki Hirato
  • Patent number: 7951868
    Abstract: Disclosed is a carboxyl group-containing polyurethane containing a structure derived from a polycarbonate diol (B), the polycarbonate diol (B) having: (i) a number-average molecular weight of 500 to 50,000; (ii) an alkylene group of 8 to 18 carbon atoms in its structure; and (iii) hydroxyl groups at both ends. The carboxyl group-containing polyurethane is suitable as materials of cured products that are excellent in adhesion with substrates, low warpage, flexibility, plating resistance, soldering heat resistance and long-term reliability.
    Type: Grant
    Filed: July 4, 2006
    Date of Patent: May 31, 2011
    Assignee: Showa Denko K.K.
    Inventors: Hiroshi Uchida, Ritsuko Azuma
  • Patent number: 7947762
    Abstract: The invention provides an aqueous ink comprising a polymer having hydroxyl groups and a pigment, which can provide images excellent in scratch resistance and highlighter resistance and can inhibit the seeping out phenomenon of the polymer and the deterioration of storage stability and ejection characteristics even when it is stored for a long period of time. The aqueous ink comprises a polymer having hydroxyl groups and a pigment, wherein a proportion of a content of a polymer that is not adsorbed on the pigment out of the polymer having hydroxyl groups to the content of the pigment in the ink is 2.0 mass % or more, and a content (mass %) of the polymer that is not adsorbed on the pigment out of the polymer having hydroxyl groups is 0.20 mass % or less based on the total mass of the ink.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: May 24, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masako Udagawa, Shinichi Hakamada, Takashi Imai, Kenji Moribe
  • Patent number: 7947761
    Abstract: The present invention relates to an inkjet ink composition comprising a liquid vehicle, a pigment, and a polymeric dispersant. In one embodiment, the pigment comprises a colorant having the formula A-(B)x or is a carbon black pigment and the polymeric dispersant comprises a polymeric group and at least one group having the formula -A?-(B)y(C)z, wherein A and A? are organic chromophore groups. In a second embodiment, the polymeric dispersant comprises a polymeric group and an organic chromophore group capable of interacting with the pigment.
    Type: Grant
    Filed: January 31, 2007
    Date of Patent: May 24, 2011
    Assignee: Cabot Corporation
    Inventors: Alexander I. Shakhnovich, Darryl S. Williams, Joseph B. Carroll
  • Patent number: 7947126
    Abstract: A method for preparing an organic pigment dispersion, such as a flush pigment or ink product, comprises steps of introducing into a twin screw extruder a stable, water-borne pigment dispersion, an organic medium, and a destabilizing agent; mixing together the stable, water-borne pigment dispersion, the organic medium, and the destabilizing agent to produce a pigment flush phase and a water phase; and removing at least a part of the water phase. A twin-screw extruder for carrying out the flushing method has an addition and flushing zone, a water removal zone, and a zone for rinsing the crude organic pigment dispersion or flush with water and removing the rinse water. Additional materials may be added to form a finished pigmented product such as an ink product, masterbatch, or toner.
    Type: Grant
    Filed: August 15, 2005
    Date of Patent: May 24, 2011
    Assignee: Flint Group Incorporated
    Inventors: Christopher M. Teeley, David Kassin, Douglas L. Cochran, Christopher B. Palmer, Norman E. Pratt
  • Patent number: 7947760
    Abstract: Polymer emulsion compositions for use in printing inks and printing inks made from the compositions are provided. The emulsion compositions include an aqueous continuous phase containing water and a dissolved carboxylic acid-functional support polymer. The dispersed phase of the emulsion composition contains crosslinked, dispersed polymer particles. The emulsion compositions also include at least one multivalent metal crosslinker and at least one stabilizing agent. The polymer emulsion compositions display superior printability properties in inks and other coatings formulated with them, yet are stable at elevated temperatures for long periods of time.
    Type: Grant
    Filed: September 19, 2005
    Date of Patent: May 24, 2011
    Assignee: BASF Corporation
    Inventors: Rein J. Janmaat, James W. Taylor, Mark van den Brink, Andre van Meer
  • Patent number: 7943681
    Abstract: Low viscosity, radiation curable fluid formulations that can be used advantageously as radiation curable, inks. The formulations are easily prepared for use in ink jet systems. The viscosity of the compositions is low enough so that conventional solvent is not required in order to satisfy the requisite low ink jet viscosity specifications. After curing, the compositions form durable, weatherable, abrasion resistant, printed images on a wide variety of porous and nonporous substrates. The formulations are very suitable for outdoor printing applications, especially for printing outdoor graphics onto a variety of surfaces, including vinyl or other polymer films commonly used for signage, retroreflective signage or other retroreflective items.
    Type: Grant
    Filed: August 5, 2008
    Date of Patent: May 17, 2011
    Assignee: 3M Innovative Properties Company
    Inventors: Jennifer L. Lee, Ronald K. Thery, Caroline M. Ylitalo, Richard L. Severance, Dong Wu, Bruce A. Nerad, Verna J. LeMire, James G. Carlson, William J. Hunt
  • Patent number: 7942960
    Abstract: The present invention provides a white ink composition that can give a white image having excellent abrasion resistance. The white ink composition according to the invention is a white ink composition containing hollow resin particles and a polyurethane resin characteristically having a glass transition temperature of 50° C. or less.
    Type: Grant
    Filed: December 5, 2008
    Date of Patent: May 17, 2011
    Assignee: Seiko Epson Corporation
    Inventors: Tsuyoshi Sano, Takayoshi Kagata
  • Patent number: 7939164
    Abstract: Pigment layer intended particularly for the permanent marking of glass, based on a polymer matrix which reacts predominantly with pulverization to a high-energy beam, more particularly to laser irradiation, comprising at least one titanium donor and a carbon donor which provides free carbon under energy irradiation.
    Type: Grant
    Filed: January 8, 2009
    Date of Patent: May 10, 2011
    Assignee: tesa SE
    Inventors: Arne Koops, Sven Reiter, Jochen Stähr