Printing Ink Composition For Glass Or Ceramic Substrate Or Process Of Preparing Patents (Class 523/160)
  • Patent number: 8415409
    Abstract: The invention provides a radiation-curable ink composition for inkjet recording, the ink composition containing at least: a specific azo compound, a tautomer of the azo compound, a salt of the azo compound, a salt of the tautomer, a hydrate of the azo compound, a hydrate of the tautomer, or any combination thereof; a polymer dispersant; a radical polymerizable compound; and a radical polymerization initiator. The invention further provides an inkjet recording method including ejecting and curing the ink composition. The invention further provides a printed matter formed by the inkjet recording method.
    Type: Grant
    Filed: February 2, 2010
    Date of Patent: April 9, 2013
    Assignee: FUJIFILM Corporation
    Inventor: Kiyoshi Morimoto
  • Patent number: 8410195
    Abstract: A solvent-based dye sublimation ink composition includes specific chemical formulations of production agents for its manufacture in several colors. The sublimation ink composition includes a vinyl chloride-vinyl acetate copolymer, a polymeric amide, 2-methoxy-1-methylethyl acetate, N-butyl acetate, butan-2-OL, petroleum distillate, disperse and/or solvent dyes, propylene glycol and one or more acetates. Once produced, the solvent-based dye sublimation ink of the present invention may be used with ink jet printers and prevents or minimizes paper cockling while exhibiting outstanding stability and high print density capabilities.
    Type: Grant
    Filed: September 6, 2012
    Date of Patent: April 2, 2013
    Assignee: Hilord Chemical Corporation
    Inventors: Iacovos Papaiacovou, Zorka Gallino, Donald H. Balbinder, Daniel Slep
  • Patent number: 8410212
    Abstract: An alcohol-soluble resin and a method for preparing the same, in which the content of vinyl acetate monomer in polymeric raw material is 50% to 90%. In addition, acrylic ester monomer and other reactive functional group-containing compounds have been mixed in the raw material to ensure the performance of resin for special requirements in application. Also provided are products produced by using the resin, such as alcohol-soluble ink, composite adhesive, lustering oil for printing, glazing lacquer for woodware, superficial decorating coatings for plastic materials, safeguard coatings of metal surface and hair colorant, as well as preparation methods.
    Type: Grant
    Filed: January 9, 2006
    Date of Patent: April 2, 2013
    Inventors: Wenjun Zou, Wenjun Zhong, Mingguo Zou, Guangming Li
  • Patent number: 8404761
    Abstract: A white ink for an inkjet, comprising a silica, a resin emulsion, and water, wherein an amount of the resin emulsion, reported as a mass ratio relative to a value of 1 for the silica, is within a range from 0.10 to 0.45.
    Type: Grant
    Filed: January 5, 2010
    Date of Patent: March 26, 2013
    Assignee: Riso Kagaku Corporation
    Inventors: Masami Shinozaki, Hiroyuki Ogawa
  • Patent number: 8399545
    Abstract: An aqueous ink for inkjet recording is provided. The aqueous ink ensures that the ejection accuracy in inkjet recording is excellent and helps suppress generation of density unevenness and streak unevenness, even after storage for a long period of time or exposure to high temperatures. The aqueous ink for inkjet recording contains vinyl polymer particles containing components A and B and a water-soluble solvent. Component A is an azo pigment having a specific structure, its tautomer, or a salt or hydrate thereof; and Component B is a vinyl polymer containing (a) a hydrophobic structural unit having an aromatic ring bonded to the polymer main chain through a linking group and (b) a hydrophilic structural unit.
    Type: Grant
    Filed: August 27, 2009
    Date of Patent: March 19, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Keiichi Tateishi, Kaoru Tojo, Kiyoshi Morimoto
  • Patent number: 8399541
    Abstract: Disclosed is an active energy ray-curable ink composition comprising a coloring agent, a binder resin, and a radically polymerizable varnish and/or a radically polymerizable monomer as main components. The coloring agent is a modified pigment wherein the surface of a pigment (A) is provided with a polymer (P) which is obtained by polymerizing a polymer (B), which is soluble in nonaqueous solvents, with at least one polymerizable unsaturated monomer (C), which is originally soluble in nonaqueous solvents but becomes insoluble or poorly soluble after polymerization. Also disclosed is a printed matter which has a coating film obtained by curing and drying the active energy ray-curable ink composition.
    Type: Grant
    Filed: March 18, 2009
    Date of Patent: March 19, 2013
    Assignee: DIC Corporation
    Inventors: Yukie Suwa, Hiroshi Kinoshita, Tatsushi Okuda, Sei Yamamoto
  • Patent number: 8399540
    Abstract: An ink-jet ink composition comprising: a pigment, a polymer pigment dispersion, polymer particles, a hydrophilic organic solvent, water, and at least one of a water-soluble acidic compound having a molecular weight of 200 or less or a salt thereof in an amount of from 50 ppm to 1,000 ppm; an ink set that includes the ink-jet ink composition and a treatment liquid that forms an aggregate when contacted with the ink-jet ink composition; and an image forming method using the ink set.
    Type: Grant
    Filed: February 24, 2010
    Date of Patent: March 19, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Terukazu Yanagi, Takahiro Ishizuka, Akio Tamura, Takahiro Kato
  • Patent number: 8393728
    Abstract: Provided are an aqueous ink-jet ink and a method for forming an ink-jet image enabling to decrease bleed occurrence during high-speed printing and to realize highly detailed image quality. An aqueous ink-jet ink characterized by containing water, a pigment, an organic or inorganic amine salt, and a water-soluble resin having a higher pKa than an acid component formed by dissociation of the amine salt in an ink.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: March 12, 2013
    Assignee: Konica Minolta Holdings, Inc.
    Inventors: Masashi Ikeda, Hirotaka Iijima, Hisashi Mori
  • Patent number: 8394871
    Abstract: The present invention provides [1] a water dispersion for ink-jet printing containing chain-like particles each containing anionic organic pigment particles and a cationic polymer, wherein the ratio of organic pigment primary particles forming the chain-like particles to all the pigment primary particles contained in the water dispersion is 10% by number or more; [2] a water-based ink for ink-jet printing containing the water dispersion; [3] a method for producing a water dispersion for ink-jet printing as described above in [1]; and [4] a water-based ink for ink-jet printing containing a water dispersion produced through the method. The water dispersion and water-based ink for ink-jet printing of the present invention realize excellent optical density.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: March 12, 2013
    Assignee: KAO Corporation
    Inventors: Atsushi Hiraishi, Masayuki Narita, Takahiro Sato, Kyoichi Shirota, Yasuhiro Doi, Hiroyuki Yoshida, Yusuke Shimizu
  • Patent number: 8389602
    Abstract: An ink composition for ink-jet recording, including: coloring particles containing a pigment that is coated with a water-insoluble polymer dispersant, and self-dispersing polymer particles containing a first polymer which includes a constituent unit derived from a hydrophilic monomer and a constituent unit derived from a hydrophobic monomer, and which has a glass transition temperature from 150° C. to 250° C. and an I/O value of from 0.20 to 0.55; an ink set including the ink composition; and an image forming method using the ink set are provided.
    Type: Grant
    Filed: February 24, 2010
    Date of Patent: March 5, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Terukazu Yanagi, Takahiro Ishizuka, Akio Tamura, Takahiro Kato
  • Patent number: 8389601
    Abstract: The invention is to provide a metal ink composition for ink-jet and more particularly, a metal ink composition which causes no formation of cracks on a PCB substrate, allows a low curing temperature, and provides improved adhesive strength even after coating.
    Type: Grant
    Filed: December 11, 2009
    Date of Patent: March 5, 2013
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Tae-Hoon Kim, Dong-Hoon Kim, Byung-Ho Jun, Joon-Rak Choi, Young-Kwan Seo, Young-Il Lee
  • Patent number: 8389622
    Abstract: A non-aqueous pigment ink comprising a pigment, a pigment dispersant and a non-aqueous solvent, wherein the pigment dispersant is an acrylic polymer comprising, as constituent monomers, (M1) an alkyl (meth)acrylate having an alkyl group of 12 or more carbon atoms, (M2) a (meth)acrylic acid derivative having an amino group, and (M3) (meth)acrylic acid and/or a (meth)acrylic acid derivative having a carboxyl group, in which a combination of all the constituent monomers comprises from 8 to 15 mol % of the monomer (M2) and from 0.6 to 8 mol % of the monomer (M3), and the molar ratio (M2)/(M3) between the monomer (M2) and the monomer (M3) is within a range from 1.3 to 15.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: March 5, 2013
    Assignee: Riso Kagaku Corporation
    Inventors: Shunsuke Uozumi, Ayako Mochizuki
  • Patent number: 8389600
    Abstract: Provided are an ink jet ink set, an ink jet recording method, and an ink jet recording apparatus each of which can reduce the graininess of an image to be recorded and improve the water fastness of the image even in a recording medium such as plain paper. The ink jet ink set has a first ink and a second ink independently, and is used so that the first and second inks overlap each other at least partly upon application of the inks to a recording medium. The first ink contains at least a pigment and a silicone oil. The second ink contains at least a pigment and a graft polymer that includes at least a nonionic unit represented by the general formula (I) and a unit having a polysiloxane structure.
    Type: Grant
    Filed: August 4, 2009
    Date of Patent: March 5, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Katsuhiko Suzuki, Katsuhiro Shirota, Hirofumi Ichinose, Masashi Tsujimura, Hiromitsu Kishi, Takashi Saito, Sayoko Nagashima, Fumihiko Mukae, Yoshihisa Yamashita
  • Patent number: 8383701
    Abstract: The present invention is drawn to a method of forming an encapsulated pigment dispersion and pigment dispersions that can be prepared therefrom. The method includes mixing a pigment particle in liquid vehicle dispersion with a mini-emulsion of monomers. A redox initiating agent is added to the liquid vehicle and the monomers are polymerized on the surface of the pigment particles. The resulting encapsulated pigment dispersion has a total solid content of at least 12 wt %.
    Type: Grant
    Filed: May 4, 2007
    Date of Patent: February 26, 2013
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Hui Liu
  • Patent number: 8383699
    Abstract: A flexographic and/or rotogravure printing ink used on non-woven substrates contains polyurethane resin, solvent, and colorant.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: February 26, 2013
    Assignee: Sun Chemical Corp.
    Inventors: Charles Bryson Williams, Jr., Diane Steiner, Tom DeBartolo
  • Patent number: 8383700
    Abstract: A recording ink containing a pigment dispersion, a surfactant, a water-dispersible resin, a humectant and water. The pigment dispersion contains a pigment dispersant, which is an anionic surfactant or a nonionic surfactant having an HLB value of 10 to 20. The pigment dispersion also contains a polymer dispersion stabilizer, which is an alpha-olefin/maleic anhydride copolymer expressed by the formula (1) below, where R is an alkyl group having 6 to 25 carbon atoms, and where the mass average molecular weight of the copolymer is 5000 to 20000. An ink cartridge, an inkjet recording method, an inkjet recording apparatus, and an ink recorded matter, each employing the recording ink, are also provided.
    Type: Grant
    Filed: June 26, 2012
    Date of Patent: February 26, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Goto, Akihiko Matsuyama, Kiyofumi Nagai
  • Patent number: 8378005
    Abstract: Provided is an active energy ray-curable inkjet ink comprising a pigment and polymerizable monomers that is superior in nozzle ejection stability, adhesiveness to recording medium and storage stability, wherein the polymerizable monomers comprise N-acryloyloxyethyl hexahydrophthalimide.
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: February 19, 2013
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Yasuo Yoshihiro, Yukitoshi Takahashi
  • Patent number: 8378006
    Abstract: The present invention is a method which erase information printed on a recording medium if necessary and thus reuse the recording medium, and includes 1) decolorable ink compositions which are not erased during the use but erased by a dye readily decolorable by a decolorant, 2) a decolorant composition including a thermal initiator or photoinitiator, and 3) a method for coating the decolorant and applying heat or irradiating UV to erase the dye. According to the present invention, it is possible to prepare various writing inks, and particularly, when applied to recording medium with a magnetic stripe as well as the general purpose papers, it is possible to reduce the production cost significantly, obtain a large import substitution effect of the magnetic ink all of which are imported, and largely reduce the environmental pollution.
    Type: Grant
    Filed: October 6, 2008
    Date of Patent: February 19, 2013
    Inventors: Jong-Soo Han, Woon Chang Paik, Hyun-Man Shin, Yeong-Gweon Lim, Yong-Hwan Choi
  • Patent number: 8377516
    Abstract: This invention relates to a radiation-curable ink-jet ink having a viscosity of 30 mPas or less at 25° C., the ink comprising: at least two monofunctional (meth)acrylate monomers which comprise a cyclic monofunctional (meth)acrylate monomer and 2-(2-ethoxyethoxy)ethyl acrylate; a monofunctional monomer selected from an N-vinyl amide, an N-acryloyl amine or a mixture thereof; a multifunctional (meth)acrylate monomer; a polymerisable (meth)acrylate oligomer; a radical photoinitiator; and a colouring agent. The ink is preferably used in reel-to-reel printing and in printing where the substrates are stacked.
    Type: Grant
    Filed: March 26, 2008
    Date of Patent: February 19, 2013
    Assignee: Sericol Limited
    Inventors: Gareth Pratt, Nigel Gould
  • Patent number: 8371687
    Abstract: The invention provides an ink composition containing at least: a water-soluble organic solvent; a pigment; water; and a nonionic polymer thickener. The content of the water-soluble organic solvent is from 5 weight % to 30 weight % relative to the total amount of the ink composition. The ratio of Vhigh/Vlow, in which Vhigh represents 25° C. viscosity (mPa·s) measured at a shear rate of 1.5×105 (s?1) and Vlow represents 25° C. viscosity (mPa·s) measured at a shear rate of 3.0×103 (s?1), is from 0.70 to 0.95. The invention further provides an image formation method including at least ejecting the ink composition onto an image recording medium using an image formation apparatus to form an image on the image recording medium.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: February 12, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Kaoru Tojo, Masao Ikoshi, Teppei Yamamoto
  • Patent number: 8372897
    Abstract: An ink composition, contains: an organic solvent, a metal pigment, and a resin, in which the organic solvent contains, based on the total amount of the ink composition, 60% by mass or more of diethylene glycol diethylether, 24 to 37% by mass of ?-butyrolactone and/or tetraethylene glycol dimethyl ether, and more than 1% by mass and lower than 5% by mass of tetraethylene glycol monobutyl ether, and the 50% average particle diameter in terms of sphere determined by a light scattering method of the metal pigment is 0.8 to 1.2 ?m.
    Type: Grant
    Filed: August 30, 2010
    Date of Patent: February 12, 2013
    Assignee: Seiko Epson Corporation
    Inventors: Takashi Oyanagi, Kiyohiko Takemoto, Kazuaki Tsukiana
  • Patent number: 8372898
    Abstract: The invention relates to an aqueous cyan inkjet ink composition for use in ink jet printers comprising an aqueous carrier, a self dispersed cyan pigment, a polymeric additive, a surfactant, and a specific cosolvent mixture comprising a C2-C8 terminal alkanediol, a cyclic amide compound and its derivative, a polyol/polyalkylene oxide condensate, and a trihydric alcohol. Preferably, the self dispersed cyan pigment is surface modified with bisphosphonate group. The cyan inkjet ink demonstrates excellent stability, superior chroma, good printhead maintenance characteristics and high heater reliability in permanent and semi permanent printheads.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: February 12, 2013
    Assignee: Lexmark International, Inc.
    Inventors: Rahel Bekru Bogale, Susan Hardin Butler, Ann P. Holloway, Qi Yin, Agnes Kam Zimmer
  • Patent number: 8372913
    Abstract: An inkjet printing method includes the steps of a) providing a first radiation curable composition curable by free radical polymerization or cationic polymerization; b) applying a layer of the first radiation curable composition on a substrate; c) curing the layer; d) jetting on the cured layer a second composition curable by a different polymerization than the first composition but selected from the group consisting of free radical polymerization and cationic polymerization; and e) curing the jetted second composition by a different polymerization than the first composition. The first composition includes a cationically polymerizable compound having at least one (meth)acrylate group present in the first curable composition in an amount of at least 25 wt % based upon the total weight of the first curable composition. An inkjet ink set may be used in the above inkjet printing method.
    Type: Grant
    Filed: December 7, 2011
    Date of Patent: February 12, 2013
    Assignee: Agfa Graphics NV
    Inventor: Roland Claes
  • Patent number: 8367750
    Abstract: The invention provides an aqueous ink comprising a polymer having hydroxyl groups and a pigment, which can provide images excellent in scratch resistance and highlighter resistance and can inhibit the seeping out phenomenon of the polymer and the deterioration of ejection characteristics even when it is stored for a long period of time. The aqueous ink comprises a polymer having hydroxyl groups, a pigment and a water-soluble organic solvent, wherein the water-soluble organic solvent comprises a polyhydric alcohol having a value of number of hydroxyl groups/number of carbon atoms in its molecule of 0.50 or less.
    Type: Grant
    Filed: October 18, 2006
    Date of Patent: February 5, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kenji Moribe, Shinichi Hakamada, Takashi Imai, Masako Udagawa
  • Patent number: 8367751
    Abstract: A solid ink that includes an ink carrier and a resinous compound of the formulas or a salt thereof, wherein G1 is —X1C(O)OR1, —X2OC(O)R2, or —X2OH; G2 is R4, R12, —C(O)R2, —C(O)X1C(O)OR1, or —C(O)X2OC(O)R2; R1 is an alkyl having from 10 to 80 carbon atoms; R2 is an alkyl having from 2 to 40 carbon atoms; each R3 and R4 is independently hydrogen, alkyl, arylalkyl or alkylaryl; each R5 and each R6 is independently hydrogen or alkyl; X1 and X2 are both a straight or branched alkylene group; t1 is 1 to 20; t2 and t3 is independently 0 to 20; u1 is 1 to 30; u2 and u3 is independently 0 to 30; each R7 and each R8 is independently hydrogen, alkyl, or alkoxyl; each R9 and each R10 is independently hydrogen, alkyl, or alkoxyl; Ar is a substituted or unsubstituted aromatic moiety; p is 1 to 5; q is 1 to 12; A? is selected from the group consisting of Cl?, Br?, I?, HSO4?, HSO3?, CH3SO3?, NO3?, HCOO?, CH3COO?, H2PO4?, SCN?, ClO4?, SSO3?, PF6?, and SbCl6?; and J is alkyl, arylalkyl, or alkylaryl.
    Type: Grant
    Filed: September 27, 2010
    Date of Patent: February 5, 2013
    Assignee: Xerox Corporation
    Inventors: Maria Birau, C. Geoffrey Allen, Carol A. Jennings, Peter G. Odell
  • Patent number: 8362106
    Abstract: Linear block copolymers that have at least one hydrophilic block and at least one hydrophobic block, wherein the hydrophilic block of the copolymer has at least one carboxylic acid functionality (or salt thereof) that can readily decarboxylate. These copolymers are useful as binders and/or dispersants in inkjet inks.
    Type: Grant
    Filed: December 3, 2008
    Date of Patent: January 29, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Kalindi Dogra, Kenneth Gene Moloy, Richard Douglas Bauer, David T. Williamson
  • Patent number: 8362108
    Abstract: An aqueous ink for a transfer ink jet recording method including applying to an intermediate transfer member a reaction liquid which forms an increased viscosity ink image by coming into contact with a coloring material in the ink, applying the ink to the intermediate transfer member by an ink jet device to form an intermediate image, and bringing a printing object into contact with the intermediate transfer member to transfer the image to the object. The aqueous ink contains a coloring material which is a polymer dispersion pigment dispersed in the aqueous medium with a polymer having a hydroxyl group in its structure as a dispersant, a nonionic surfactant which is an alcohol ether surfactant a 1% aqueous solution of which has a cloud point of 33° C. or less and which has a C4-C30 alkyl group and a propyleneoxy group in its structure, and an aqueous medium.
    Type: Grant
    Filed: April 5, 2011
    Date of Patent: January 29, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventor: Takashi Imai
  • Patent number: 8362107
    Abstract: An ink set includes at least a cyan ink composition containing a self-dispersible pigment, a magenta ink composition containing a self-dispersible pigment, and a yellow ink composition containing a pigment coated with a water-insoluble polymer.
    Type: Grant
    Filed: March 2, 2011
    Date of Patent: January 29, 2013
    Assignee: Seiko Epson Corporation
    Inventors: Chie Maruyama, Miharu Kanaya, Daisuke Ishihara, Ayako Nishiki
  • Patent number: 8362137
    Abstract: A pigment dispersion including a pigment and a block polymer including a repeating unit including a hetero ring residue or an anthraquinone ring residue of a colorant is disclosed.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: January 29, 2013
    Assignee: FUJIFILM Corporation
    Inventor: Koji Yasuda
  • Patent number: 8362138
    Abstract: A dispersion of a water-insoluble colorant, having: fine particles of at least one kind of water-insoluble colorant dispersed in a water-containing medium; and a polymer compound or surfactant having a structural unit represented by formula (I): wherein R1 represents a hydrogen atom or a substituent; one of R2 to R5 represents a single bond which bonds to W, and the others each independently represent a hydrogen atom or a substituent; Q represents a group of atoms necessary for forming, with the carbon atoms, a ring; J represents —CO—, —COO—, —CONR6—, —OCO—, a methylene group, a phenylene group, or —C6H4CO—; R6 represents a hydrogen atom, an alkyl group, an aryl group or an aralkyl group; W represents a single bond or a divalent linking group.
    Type: Grant
    Filed: January 28, 2010
    Date of Patent: January 29, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Satoshi Sano, Ryo Saito, Yohei Ishiji, Jun Matsumoto
  • Patent number: 8362124
    Abstract: The present invention relates to coating and printing ink compositions containing silylated polyether compounds comprising a hydrolysis-resistant bis-silyl hydrocarbylene group. More particularly, the silylated polyether compound comprising a bis-silyl hydrocarbylene group provides to the coating and ink compositions formulation flexibility over the entire pH range, leveling-and-flow and surface wetting, and are non-reactive with the other components of the coating and ink compositions, thereby providing long-term shelf-stability of formulated coatings and inks. These coating and ink compositions containing silylated polyether compounds do not release silicone materials and thereby provide articles treated with these coatings and ink compositions with uniform appearance and gloss.
    Type: Grant
    Filed: February 25, 2010
    Date of Patent: January 29, 2013
    Assignee: Momentive Performance Materials Inc.
    Inventors: Suresh K. Rajaraman, Eric R. Pohl, Mark D. Leatherman, George A. Policello
  • Patent number: 8349917
    Abstract: The ink of the invention comprises a mixture of finely subdivided polyethylene powder, an aliphatic or aromatic hydrocarbon solvent, a dispersing agent, an indicia material additive such as a dye or pigment and/or a physical property enhancing additive such as alumina, glass beads, silica, metal flakes, etc. Preferably high and very high molecular weight polyethylene is used, alone or in mixture with lower density polyethylene in amounts from 25 to 45 weight percent in the ink. The polyethylene can have a particle size from 1 nanometer to 150 microns, preferably from 0.1 to 100 microns. The printing ink can be used to prepare a transfer having a decorative layer printed onto a carrier sheet. Various printing methods can be used to prepare the transfer such as gravure printing with etched or engraved chrome-plated or copper rolls; flexography printing with a flexible printing plate; and screen printing. The preferred method is screen printing.
    Type: Grant
    Filed: July 28, 2010
    Date of Patent: January 8, 2013
    Inventors: Michael J. Stevenson, Robert A. Reeves
  • Patent number: 8349916
    Abstract: The present invention provides an actinic energy radiation curable ink-jet ink exhibiting excellent ink storage stability, nozzle ink repellency, and ejection stability, and also exhibiting excellent curability, anti-abrasion properties, solvent resistance, flexibility, weather resistance, and substrate adhesion properties even under various ambience factors and irradiation conditions, as well as an ink-jet recording method and printed matter using the same. In an actinic energy radiation curable ink-jet ink containing a cationically polymerizable compound and a photo-cationic polymerization initiator, an actinic energy radiation curable ink-jet ink wherein a cationically polymerizable compound having a vinyl ether group as a reactive group is contained at 50.0% by mass or more and the halogen ion content is 1.0 ?g/g of the ink-100 ?g/g of the ink.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: January 8, 2013
    Assignee: Konica Minolta IJ Technologies, Inc.
    Inventors: Kouki Kawashima, Masaki Nakamura, Atsushi Nakajima, Yusuke Takaku
  • Patent number: 8349915
    Abstract: Provided are an encapsulated colorant, a method of preparing the same, and an ink composition including the encapsulated colorant.
    Type: Grant
    Filed: December 30, 2008
    Date of Patent: January 8, 2013
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Heung-Sup Park, Jong-In Lee
  • Patent number: 8348410
    Abstract: An ink set for inkjet recording including an ink composition including a dispersion of a pigment dispersed by a water-insoluble polymer which is formed by copolymerizing a monomer mixture containing a styrenic macromer, as well as self-dispersing polymer particles, a water-soluble organic solvent, and water; and a reactive liquid which forms an aggregate when contacted with the ink composition; and an image recording method using the ink set, are provided.
    Type: Grant
    Filed: August 19, 2009
    Date of Patent: January 8, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Tomoyuki Ohzeki, Terukazu Yanagi
  • Patent number: 8344046
    Abstract: The present invention provides a chemical ink comprises a solvent, a binder polymer, a colorant and optionally a crosslinker. The ink of the invention has one or more of the following characteristics: a viscosity lower than about 50 centipoises; a surface tension of from about 20 mN/m to about 60 mN/m; a particle size of less than about 5 ?m; prolonged stability; an appropriate color level (visible by eye); uniform drop formation; jet stability; good adhesion to contact lenses; good transfer from a mold to a lens made in the mold; and stability of ink in inkjet nozzles. The ink of the invention is useful for inkjet printing of a high-quality color image on a contact lens or a mold so as to produce a colored contact lens.
    Type: Grant
    Filed: March 18, 2010
    Date of Patent: January 1, 2013
    Assignee: Novartis AG
    Inventors: Robert Carey Tucker, Sandra Corti
  • Patent number: 8344047
    Abstract: A dispersing agent characterized in that said dispersing agent is prepared by reacting primary and/or secondary amino groups of an amine compound comprising a polyamine (C) with isocyanate groups of a urethane prepolymer (E) having two isocyanate groups in one terminal region, wherein said urethane prepolymer (E) has been prepared by reacting hydroxyl groups in a vinyl polymer (A) having two hydroxyl groups in one terminal region with isocyanate groups in diisocyanates (B), and in that an amine number of said dispersing agent is 1 to 100 mgKOH/g is disclosed. The dispersing agent of the present invention has excellent dispersibility, flowability, and storage stability when used in small quantities. A pigment-dispersed product can be prepared therefrom, independently of the kinds of binder resin or solvent used. Further, the present invention is suitable for offset ink, gravure ink, resist ink for a color filter, inkjet ink, coating composition, and colored resin composition.
    Type: Grant
    Filed: March 24, 2009
    Date of Patent: January 1, 2013
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Kazunori Shigemori, Tomoko Tachibana, Yasushi Ariyoshi, Ken Yamazaki, Atsushi Yoda, Daisuke Fujiwara, Atsushi Nakazato, Tsutomu Hiroshima
  • Patent number: 8344045
    Abstract: An ink composition is provided that includes (A) a polymerizable silicone compound having an ethylenically unsaturated group and a silicone chain, (B) tetrahydrofurfuryl (meth)acrylate, and (C) a radical polymerization initiator. There are also provided an inkjet recording method that includes (a1) a step of discharging onto a recording medium the ink composition and (b1) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material obtained by the inkjet recording method, and a process for producing a formed printed material that includes (a2) a step of forming an image on a support by discharging the ink composition by an inkjet method, (b2) a step of obtaining a printed material having a cured image on the support by irradiating the obtained image with actinic radiation so as to cure the ink composition, and (c2) a step of molding the printed material.
    Type: Grant
    Filed: March 17, 2010
    Date of Patent: January 1, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Hironori Ohnishi, Kazuhiro Yokoi
  • Patent number: 8338499
    Abstract: A radiation curable composition comprising a curable compound, a photo-initiator and a co-initiator characterized in that said co-initiator is represented by Formula I, wherein MA is the residue of a mono- or oligofunctional Michael acceptor; L is a divalent linking group positioning the two tertiary amines in a 1-3 to 1-10 position, with the proviso that both amines are aliphatic; R1, R2 and R3 independently represent an optionally substituted alkyl group, an optionally substituted alkenyl group , an optionally substituted alkynyl group or an optionally substituted (hetero) alkaryl group; any two of R1, R2 and R3 may represent the necessary atoms to form a ring; any two of R1, R2 and R3 may represent the necessary atoms to form a ring with any of the atoms of the linking group L; n is an integer ranging from 1 to 6.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: December 25, 2012
    Assignee: Agfa Graphics NV
    Inventors: Johan Loccufier, Roland Claes, Jaymes Van Luppen
  • Patent number: 8334329
    Abstract: Disclosed herein are inks including an aqueous vehicle; at least one encapsulant-dispersed pigment; and at least one block copolymer binder dispersed throughout the aqueous vehicle and having Structure I and comprising a hydrophobic block (A) and a hydrophilic block (B).
    Type: Grant
    Filed: May 11, 2010
    Date of Patent: December 18, 2012
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Howard A. Doumaux, Zeying Ma, Sivapackia Ganapathiappan
  • Patent number: 8328341
    Abstract: The invention provides an ink jet recording ink containing a self-dispersion pigment, to the surface of which an anionic functional group represented by the following general formula (I) has been bonded directly or through another atomic group, water, a water-soluble substance having a coefficient of hydrophilicity-hydrophobicity of 0.37 or more as defined by the following equation (A) and a water-soluble substance having a coefficient of hydrophilicity-hydrophobicity of 0.25 or less as defined by the equation (A), and having a surface tension of 34 mN/m or less.
    Type: Grant
    Filed: July 22, 2008
    Date of Patent: December 11, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shoji Koike, Ryota Kato, Hitoshi Yoshino
  • Patent number: 8329780
    Abstract: Provided are an encapsulated colorant including a polymer resin and a colorant coated with the polymer resin, wherein the encapsulated colorant includes at least two types of colorants which have different average particle diameters with different distributions. The encapsulated colorant has two types of colorants which have different average particle diameters with different distributions. In the preparation of an encapsulated colorant, a supplementary colorant is added to the preparation of an initially added colorant after a specific period of time. Thus, a polymer resin growing on the colorants has a different size. Thus, the present general inventive concept provides an encapsulated colorant having at least two average particle diameters with different distributions and has beneficial miscibility since the colorants are coated with a polymer resin.
    Type: Grant
    Filed: July 9, 2008
    Date of Patent: December 11, 2012
    Assignee: SAMSUNG Electronics Co., Ltd.
    Inventor: Jong-in Lee
  • Patent number: 8329067
    Abstract: A method of producing a color filter by using the ink jet system. The method includes a step of preparing a specific ink-jet ink for color filter, the ink containing a pigment, a pigment dispersing agent, a binder forming system and a solvent, a step of forming an R ink layer, a G ink layer and a B ink layer respectively by the ink jet system and a step of curing each of the ink layer to form an R pixel, a G pixel and a B pixel, which each have an average film thickness range from 1.5 ?m to 2.5 ?m and a film thickness distribution range from 1.0 ?m to 3.0 ?m, wherein the ratio of the total area of the regions having a film thickness of 1.5 ?m or less or 2.5 ?m or more in one pixel is 5% or less.
    Type: Grant
    Filed: April 2, 2007
    Date of Patent: December 11, 2012
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Tomonori Nishida, Hiroyuki Honda
  • Patent number: 8329777
    Abstract: A value document, such as a banknote, is printed using a printing ink or varnish comprising an aqueous dispersion of a preferably aliphatic polycarbonate polyurethane and/or a polyether or polyester polycarbonate polyurethane copolymer having a particle size range from 10 to 400 nm and an acid value no greater than 10 mg KOH/g.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: December 11, 2012
    Assignee: Sun Chemical B.V.
    Inventor: Clive Edward Lawrence
  • Publication number: 20120309866
    Abstract: The present invention relates to a solder ink and an electronic device package using the same. The solder ink includes: a solder powder including an alloy including tin (Sn); a binder including a first resin comprising rosin resin or rosin modified resin; an active agent; and a solvent.
    Type: Application
    Filed: March 10, 2010
    Publication date: December 6, 2012
    Applicant: DUK SAN TEKOPIA CO., LTD.
    Inventors: Yong Un Jang, Sung Chul Kim, Yong Cheol Chu, Seung Jun Jang, Yoon Sang Son
  • Patent number: 8324294
    Abstract: High performing nanoparticle compositions suitable for printing, such as by inkjet printing, are provided herein. In particular, there is provided a conductive ink formulation comprising silver nanoparticles which has optimal performance, such as, reduced coffee ring effect, improved adhesion to substrates, and extended printhead de-cap time or latency time. The ink formulation comprises two or more solvents and a resin.
    Type: Grant
    Filed: March 7, 2011
    Date of Patent: December 4, 2012
    Assignee: Xerox Corporation
    Inventors: Yiliang Wu, Jenny Eliyahu, Ping Liu, Nan-Xing Hu
  • Patent number: 8324293
    Abstract: An aqueous ink comprising a polymer having hydroxyl groups and a pigment, which can provide images excellent in scratch resistance and highlighter resistance and can inhibit the seeping out phenomenon of the polymer and the deterioration of ejection characteristics even when it is stored for a long period of time. The aqueous ink comprises a polymer having hydroxyl groups, a pigment and a water-soluble organic solvent, wherein the water-soluble organic solvent comprises a poor medium for a polymer that is not adsorbed on the pigment (out of the polymer having hydroxyl groups), and wherein when the segment constituting the polymer that is not adsorbed on the pigment (out of the polymer having hydroxyl groups) is comprised of a segment A having hydroxyl groups and a segment B having no hydroxyl group, at least one of the poor medium is a good medium for either one of the segment A and the Segment B.
    Type: Grant
    Filed: October 18, 2006
    Date of Patent: December 4, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takashi Imai, Shinichi Hakamada, Kenji Moribe, Masako Udagawa
  • Patent number: 8317913
    Abstract: The present invention provides an inkjet ink containing at least a colorant, water, a water insoluble resin, a fluorine surfactant, and a polyether-modified silicone oil, wherein the polyether-modified silicone oil has a hydrophobic value of 0.40 to 1.5, and the hydrophobic value is expressed by Equation 1: Hydrophobic value=A/B??Equation 1 where “A” represents an integration value of a peak area from 0 ppm to 0.3 ppm in a 1H-NMR spectrum of the polyether-modified silicone oil using tetramethylsilane as a reference substance; and “B” represents an integration value of a peak area from 3.5 ppm to 4.0 ppm in the 1H-NMR spectrum.
    Type: Grant
    Filed: August 13, 2008
    Date of Patent: November 27, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Shigeo Hatada, Keishi Taniguchi, Shigeru Kusakata, Ichiroh Fujii, Akihiko Matsuyama, Yuuki Yokohama
  • Patent number: 8313666
    Abstract: There is provided novel curable ink compositions comprising polymer-coated magnetic metal nanoparticles. In particular, there is provided ultraviolet (UV) curable gel inks comprising at least the coated magnetic metal nanoparticles, one curable monomer, a radiation activated initiator that initiates polymerization of curable components of the ink, a gellant. The inks may also include optional colorants and one or more optional additives. These curable gel UV ink compositions can be used for ink jet printing in a variety of applications.
    Type: Grant
    Filed: March 17, 2011
    Date of Patent: November 20, 2012
    Assignee: Xerox Corporation
    Inventors: Gabriel Iftime, Naveen Chopra, Barkev Keoshkerian, Peter G. Odell, Marcel P. Breton
  • Patent number: 8314163
    Abstract: The present invention is drawn to steric stabilized latex particulates, methods of forming such particulates, inks containing such particulates, and methods of ink-jetting inks containing such particulates. A steric stabilized latex particulate for use in an ink-jet ink can comprise a random copolymer of a steric stabilization oligomer and a hydrophobic monomer.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: November 20, 2012
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Sivapackia Ganapathiappan